JPH0718576A - Softening agent composition - Google Patents
Softening agent compositionInfo
- Publication number
- JPH0718576A JPH0718576A JP18888793A JP18888793A JPH0718576A JP H0718576 A JPH0718576 A JP H0718576A JP 18888793 A JP18888793 A JP 18888793A JP 18888793 A JP18888793 A JP 18888793A JP H0718576 A JPH0718576 A JP H0718576A
- Authority
- JP
- Japan
- Prior art keywords
- polypeptide
- alkyl
- hydrolyzing
- quaternary ammonium
- softening agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、繊維や衣料に柔軟性を
付与する為の柔軟剤組成物に関し、特に羊毛や絹等の動
物性天然繊維に対する風合い付与効果に優れた柔軟剤組
成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a softener composition for imparting flexibility to fibers and clothes, and more particularly to a softener composition having an excellent texture-providing effect on animal natural fibers such as wool and silk. .
【０００２】[0002]
【従来の技術】従来、洗濯後の衣料に柔軟性を付与する
為に、ジ長鎖ヒドロカルビル第４級塩を主成分とするも
のが一般的に用いられているが、ジ長鎖ヒドロカルビル
第４級塩は、綿に対する柔軟性付与効果は優れている
が、羊毛や絹などの動物性天然繊維に対する風合い性の
面では充分ではなかつた。なお、「ヒドロカルビル」と
は、エステル基等で分離されていてもよいアルキルまた
はアルケニルを指す。そこで、羊毛や絹などの動物性天
然繊維に対する柔軟性、特に風合い性に優れた柔軟剤の
開発が望まれている。2. Description of the Related Art Conventionally, in order to impart flexibility to clothes after washing, those containing a di-long chain hydrocarbyl quaternary salt as a main component are generally used. Although the graded salt has an excellent effect of imparting flexibility to cotton, it is not sufficient in terms of the feel to animal natural fibers such as wool and silk. In addition, "hydrocarbyl" refers to alkyl or alkenyl which may be separated by an ester group or the like. Therefore, there is a demand for the development of a softening agent which is excellent in flexibility, particularly in texture, with respect to natural animal fibers such as wool and silk.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、洗濯後の衣
料、特に羊毛や絹などの動物性天然繊維に対して柔軟性
を付与すると同時に風合い性に優れた柔軟剤組成物を提
供するものである。DISCLOSURE OF THE INVENTION The present invention provides a softener composition which imparts flexibility to clothes after washing, especially animal natural fibers such as wool and silk, and at the same time has excellent texture. Is.
【０００４】[0004]
【課題を解決するための手段】本発明の柔軟剤組成物
は、以下の（Ａ）および（Ｂ）成分を含有することを特
徴とする。 （Ａ） 下記化２の一般式（Ｉ）で表される第４級アン
モニウム塩：３〜３０重量％。 （Ｂ） 蛋白質を加水分解して得られる重量平均分子量
２００〜１５００のポリペプタイドまたはその誘導体：
０．００１〜１重量％。The softener composition of the present invention is characterized by containing the following components (A) and (B). (A) Quaternary ammonium salt represented by the following general formula (I): 3 to 30% by weight. (B) Polypeptide having a weight average molecular weight of 200 to 1500 obtained by hydrolyzing a protein or a derivative thereof:
0.001-1% by weight.
【０００５】[0005]
【化２】 （Ｒ1，Ｒ2：分断基も含めて炭素数が１８〜２１の、エ
ステル基またはアミド基で分断されたアルキル基または
アルケニル基、あるいは炭素数１６〜２０のアルキル基
またはアルケニル基 Ｒ3，Ｒ4：炭素数１〜３のアルキル基またはヒドロキシ
アルキル基 Ｘ- ：陰イオン）[Chemical 2] (R 1, R 2: the number of carbon atoms of 18 to 21, including cutting group, an ester group or amide shed alkyl or alkenyl group with a group or an alkyl or alkenyl group R 3 of 16 to 20 carbon atoms, R 4: an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group X -: an anion)
【０００６】[0006]
【発明の実施態様】本発明の（Ａ）成分としては、下記
化３の一般式（Ｉ）で表される第４級アンモニウム塩が
用いられる。BEST MODE FOR CARRYING OUT THE INVENTION As the component (A) of the present invention, a quaternary ammonium salt represented by the following general formula (I) is used.
【０００７】[0007]
【化３】 （Ｒ1，Ｒ2：分断基も含めて炭素数が１８〜２１の、エ
ステル基またはアミド基で分断されたアルキル基または
アルケニル基、あるいは炭素数１６〜２０のアルキル基
またはアルケニル基 Ｒ3，Ｒ4：炭素数１〜３のアルキル基またはヒドロキシ
アルキル基 Ｘ- ：陰イオン）[Chemical 3] (R 1, R 2: the number of carbon atoms of 18 to 21, including cutting group, an ester group or amide shed alkyl or alkenyl group with a group or an alkyl or alkenyl group R 3 of 16 to 20 carbon atoms, R 4: an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group X -: an anion)
【０００８】一般式（Ｉ）中のＲ1，Ｒ2炭素数が規定よ
り少ないと柔軟性が低下し、一方、規定範囲を越えると
カチオン界面活性剤としての融点が高くなり、製造性が
悪化する。When the number of carbon atoms of R 1 and R 2 in the general formula (I) is less than the specified value, the flexibility is lowered, while when it exceeds the specified range, the melting point as a cationic surfactant is increased and the productivity is deteriorated. To do.
【０００９】（Ａ）成分の第４級アンモニウム塩の具体
例としては、以下に示すものが例示され、これら１種を
単独で使用しても２種以上を混合して使用してもよい。
ジステアリルジメチル第４級アンモニウムクロライド、
ステアリルオレイルジメチル第４級アンモニウムクロラ
イド、ジオレイルジメチル第４級アンモニウムクロライ
ド、ジ（ステアロイルオキシエチル）ジメチル第４級ア
ンモニウムクロライド、ジ（オレオイルオキシイソプロ
ピル）ジメチル第４級アンモニウムメチルサルフェー
ト、Ｎ−硬化牛脂アミノメチル−Ｎ−オレオイルオキシ
メチル−Ｎ，Ｎ−ジメチル第４級アンモニウムクロライ
ド、Ｎ−オレオイルオキシエチル−Ｎ−エライジルオキ
シ−Ｎ，Ｎ−ジメチル第４級アンモニウムエチルサルフ
ェート、Ｎ−ステアロイルオキシエチル−Ｎ−オレオイ
ルオキシエチル−Ｎ，Ｎ−ジメチル第４級アンモニウム
クロライド。Specific examples of the quaternary ammonium salt as the component (A) include those shown below, and one of these may be used alone or two or more of them may be used in combination.
Distearyl dimethyl quaternary ammonium chloride,
Stearyl oleyl dimethyl quaternary ammonium chloride, dioleyl dimethyl quaternary ammonium chloride, di (stearoyloxyethyl) dimethyl quaternary ammonium chloride, di (oleoyloxyisopropyl) dimethyl quaternary ammonium methyl sulfate, N-cured beef tallow Aminomethyl-N-oleoyloxymethyl-N, N-dimethyl quaternary ammonium chloride, N-oleoyloxyethyl-N-elaidyloxy-N, N-dimethyl quaternary ammonium ethyl sulfate, N-stearoyloxy Ethyl-N-oleoyloxyethyl-N, N-dimethyl quaternary ammonium chloride.
【００１０】（Ａ）成分の第４級アンモニウム塩は、本
発明の柔軟剤組成物中に３〜３０重量％、好ましくは５
〜１５重量％配合され、この配合量が３重量％未満で
は、充分な柔軟性効果を得る為に多量の柔軟剤組成物を
使用しなければならないことから、商品価値上好ましく
ない。また、３０重量％を越えると、柔軟剤組成物の溶
液安定性が悪化し、製造性の面で好ましくない。The quaternary ammonium salt as the component (A) is contained in the softener composition of the present invention in an amount of 3 to 30% by weight, preferably 5%.
If the amount is less than 3% by weight, a large amount of the softener composition must be used in order to obtain a sufficient softening effect, which is not preferable in terms of commercial value. On the other hand, if it exceeds 30% by weight, the solution stability of the softening agent composition deteriorates, which is not preferable in terms of manufacturability.
【００１１】本発明の（Ｂ）成分としては、蛋白質を加
水分解して得られる平均重量分子量２００〜１５００、
好ましくは４００〜１０００のポリペプタイドまたはそ
の誘導体が用いられる。（Ｂ）成分のポリペプタイドの
具体例としては、羊毛等に由来するケラチンを加水分解
して得られるポリペプタイドとその誘導体、コラーゲン
を加水分解して得られるコラーゲンポリペプタイドとそ
の誘導体、カゼインを加水分解して得られるポリペプタ
イドとその誘導体、大豆蛋白（植物蛋白）を加水分解し
て得られるポリペプタイド、これらポリペプタイドと脂
肪酸との縮合物又はその無機塩、有機塩等が例示され、
これら１種を単独で使用しても、２種以上を混合使用し
ても良い。The component (B) of the present invention includes an average weight molecular weight of 200 to 1500 obtained by hydrolyzing a protein,
Preferably 400 to 1000 polypeptides or their derivatives are used. Specific examples of the polypeptide as the component (B) include a polypeptide obtained by hydrolyzing keratin derived from wool or the like and a derivative thereof, a collagen polypeptide obtained by hydrolyzing collagen and a derivative thereof, and casein. Polypeptides and derivatives thereof obtained by decomposition, polypeptides obtained by hydrolyzing soybean protein (vegetable protein), condensation products of these polypeptides and fatty acids or their inorganic salts, organic salts and the like are exemplified.
These 1 type may be used individually or may be used in mixture of 2 or more types.
【００１２】（Ｂ）成分のポリペプタイド類は、本発明
の柔軟剤組成物中に０．００１〜１重量％、好ましくは
０．０１〜０．９重量％配合される。この配合量が０．
００１重量％未満では、繊維への吸着量が少なく、風合
い性向上効果が得られない。また、１重量％を越える
と、柔軟剤組成物の安定性、特に分離、増粘等に悪影響
を及ぼすので好ましくない。The component (B), a polypeptide, is added to the softener composition of the present invention in an amount of 0.001 to 1% by weight, preferably 0.01 to 0.9% by weight. This blending amount is 0.
If it is less than 001% by weight, the amount adsorbed on the fiber is small and the effect of improving the texture cannot be obtained. On the other hand, if it exceeds 1% by weight, the stability of the softening agent composition, particularly separation and thickening, are adversely affected, which is not preferable.
【００１３】本発明の柔軟剤組成物には、上記成分以外
にその他任意成分として、通常柔軟剤組成物に配合され
る公知の成分を本発明の効果を妨げない範囲で配合する
ことができる。任意成分としては、例えば、ジ長鎖アル
キルジ短鎖アルキル第４級アンモニウム塩、ステアリン
酸等の高級脂肪酸、２−エチルヘキサン酸とグリセリン
またはペンタエリスリトールとの部分エステル化物や、
高級脂肪酸、高級アルコールまたはモノアルキルアミン
のアルキレンオキシド付加物等の非イオン界面活性剤、
食塩、塩化アンモニウム、塩化カルシウム、塩化マグネ
シウム、塩化カリウム等の水溶性塩、エチルアルコー
ル、イソプロピルアルコール、エチレングリコール、プ
ロピレングリコール、イソプロピレングリコール、ヘキ
シレングリコール等の溶剤、尿素、殺菌剤、酸化防止
剤、染料、顔料、シリコーン類、炭化水素、セルロース
誘導体、紫外線吸収剤、蛍光増白剤、香料等が挙げられ
る。In addition to the above-mentioned components, the softener composition of the present invention may contain, as other optional components, known components which are usually incorporated in the softener composition, within a range that does not impair the effects of the present invention. As the optional component, for example, a di long chain alkyl di short chain alkyl quaternary ammonium salt, a higher fatty acid such as stearic acid, a partial esterification product of 2-ethylhexanoic acid and glycerin or pentaerythritol,
Nonionic surfactants such as higher fatty acids, higher alcohols or alkylene oxide adducts of monoalkylamines,
Salts, water-soluble salts such as ammonium chloride, calcium chloride, magnesium chloride, potassium chloride, solvents such as ethyl alcohol, isopropyl alcohol, ethylene glycol, propylene glycol, isopropylene glycol, hexylene glycol, urea, bactericides, antioxidants , Dyes, pigments, silicones, hydrocarbons, cellulose derivatives, ultraviolet absorbers, optical brighteners, and fragrances.
【００１４】[0014]
【発明の効果】本発明によれば、（Ａ）一般式（Ｉ）で
表される第４級アンモニウム塩３〜３０重量％と、
（Ｂ）蛋白質を加水分解して得られる平均分子量２００
〜１５００のポリペプタイドまたはその誘導体０．００
１〜１重量％とを併用して柔軟剤組成物とすることによ
り、洗濯後の衣料、特に羊毛や絹などの動物性天然繊維
に対して柔軟性を付与すると同時に優れた風合いを与え
ることができる。According to the present invention, (A) a quaternary ammonium salt represented by the general formula (I) in an amount of 3 to 30% by weight,
(B) Average molecular weight 200 obtained by hydrolyzing protein
~ 1500 polypeptides or their derivatives 0.00
By using 1 to 1% by weight of the softening agent composition in combination, it is possible to impart flexibility to clothes after washing, especially to animal natural fibers such as wool and silk, and at the same time provide excellent texture. it can.
【００１５】[0015]
【実施例】以下、実施例および比較例を示して本発明を
具体的に説明するが、本発明は下記実施例に制限される
ものではない。なお各例中の％はいずれも重量％であ
る。また評価法は下記方法によつた。The present invention will be specifically described below with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples. In addition,% in each example is% by weight. The evaluation method was as follows.
【００１６】（１） 柔軟化処理方法 市販の綿タオルを市販衣料用洗剤「ハイトツプ」（商品
名、ライオン（株）製）により、電気式二槽洗濯機を用
いて２回繰り返し洗濯後、常温の水道水で充分にすす
ぎ、これを試験布とした。次に２５℃の水道水３０リツ
トルに対し柔軟基剤の（Ａ）成分を１ｇになるように加
え均一溶液とした。この溶液中に浴比３０倍で綿タオル
とウールジャージの比率を重量で１／１として浸して３
分間処理した後、２分間脱水した。このように処理した
後、２０℃、４０％ＲＨの条件で２４時間放置し、評価
試験に用いた。(1) Softening treatment method A commercially available cotton towel is repeatedly washed twice with an electric two-tank washing machine using a commercially available laundry detergent "HITOPUP" (trade name, manufactured by Lion Co., Ltd.), and then at room temperature. It was thoroughly rinsed with tap water and used as a test cloth. Next, the component (A) of the soft base material was added to 30 liters of tap water at 25 ° C. so that the content was 1 g to make a uniform solution. Immerse the solution in the solution at a bath ratio of 30 and the ratio of cotton towel and wool jersey 1/1 by weight.
After treating for 1 minute, it was dehydrated for 2 minutes. After the treatment as described above, it was left for 24 hours under the conditions of 20 ° C. and 40% RH and used for the evaluation test.
【００１７】（２） 柔軟性評価方法 表−２に示すジステアリルジメチル４級アンモニウムク
ロライドを柔軟基剤として配合した柔軟剤組成物（対
照）で処理した布を対照として一対比較を行い、下記基
準にて評価した。 ＋２：対照より柔らかい ＋１：対照よりやや柔らかい ０：対照と同等 −１：対照の方がやや柔らかい −２：対照の方が柔らかい(2) Softness Evaluation Method A pair of comparisons were carried out with a cloth treated with a softener composition (control) containing distearyldimethyl quaternary ammonium chloride as a soft base shown in Table 2 as a control, and the following criteria were used. Was evaluated. +2: Softer than control +1: Slightly softer than control 0: Equivalent to control -1: Slightly softer control -2: Softer control
【００１８】（３） 風合い性評価方法 表−２に示すジステアリルジメチル４級アンモニウムク
ロライドを柔軟基剤として配合した柔軟剤組成物（対
照）で処理した布を対照として、風合い（特に滑り性）
について一対比較を行い下記基準にて評価した。 ＋２：対照より風合い（滑り性）が良い ＋１：対照より風合い（滑り性）がやや良い ０：対照と同等 −１：対照の方が風合い（滑り性）がやや良い −２：対照の方が風合い（滑り性）が良い(3) Texture evaluation method Texture (especially slipperiness) of a cloth treated with a softener composition (control) containing distearyldimethyl quaternary ammonium chloride shown in Table 2 as a soft base, was used as a control.
A pair of comparisons were performed and the following criteria were evaluated. +2: The texture (sliding) is better than the control +1: The texture (sliding) is slightly better than the control 0: Equivalent to the control -1: The texture is slightly better (sliding) -2: The control is better Good texture (sliding)
【００１９】（４） 溶液安定性評価方法 柔軟剤組成物を５℃及び４５℃に恒温保存し、目視によ
り判定した。判定基準は下記に示す。 ◎：３０日間以上安定 ○：１５〜３０日間安定 △：１０〜１５日間安定 ×：１０日以内に不安定(4) Solution Stability Evaluation Method The softener composition was thermostated at 5 ° C. and 45 ° C. and visually evaluated. The judgment criteria are shown below. ◎: Stable for 30 days or more ○: Stable for 15 to 30 days △: Stable for 10 to 15 days ×: Unstable within 10 days
【００２０】実施例１〜６、比較例１〜７ 以下表１に示した（Ａ）成分と（Ｂ）成分とを表２に示
した配合量で用い、非イオン系の界面活性剤により分散
させて柔軟剤組成物を調製して柔軟性、風合い性、溶液
安定性を評価し、その結果を表２に示した。Examples 1 to 6 and Comparative Examples 1 to 7 Components (A) and (B) shown in Table 1 below were used in the blending amounts shown in Table 2 and dispersed with a nonionic surfactant. Then, a softener composition was prepared and evaluated for flexibility, texture and solution stability, and the results are shown in Table 2.
【００２１】[0021]
【表１】表１：（Ａ）成分及び（Ｂ）成分 記号 化合物名 Ａ成分： Ａ−１ ジステアリルジメチル第４級アンモニウムクロライド Ａ−２ ステアリルオレイルジメチル第４級アンモニウムクロライド Ａ−３ ジ（ステアロイルオキシ）エチルジメチル第４級アンモニウム クロライド Ａ−４ Ｎ−ステアロイルアミノエチル−Ｎ−オレオイルオキシエチル −Ｎ，Ｎ−ジメチル第４級アンモニウムクロライド Ａ−５ ジオレイルジメチル第４級アンモニウムメチルサルフェート Ａ−６ ジラウリルジメチル第４級アンモニウムクロライド（比較品） Ａ−７ ジベヘニルジメチル第４級アンモニウムクロライド（比較品） Ｂ成分： Ｂ−１ 羊毛を加水分解したケラチンポリペプタイド：分子量約400 （プロモイスＷＫ：商品名／成和化成（株）製） Ｂ−２ 大豆蛋白を加水分解したポリペプタイド：分子量約700 （プロモイスＷＳ：商品名／成和化成（株）製） Ｂ−３ コラーゲンを加水分解したコラーゲンポリペプタイド：分子量約1000 （プロモイスＷ−４２：商品名／成和化成（株）製） Ｂ−４ コラーゲンを加水分解したコラーゲンポリペプタイド：分子量約4000 （プロモイスＷ−４０００：商品名／成和化成（株）製）（比較品） [Table 1]Table 1: (A) component and (B) component symbol Compound name A component: A-1 distearyl dimethyl quaternary ammonium chloride A-2 stearyl oleyl dimethyl quaternary ammonium chloride A-3 di (stearoyloxy) ethyl dimethyl quaternary ammonium chloride A-4 N-stearoylaminoethyl-N -Oleoyloxyethyl-N, N-dimethyl quaternary ammonium chloride A-5 Dioleyldimethyl quaternary ammonium methylsulfate A-6 Dilauryldimethyl quaternary ammonium chloride (comparative product) A-7 Dibehenyldimethyl quaternary ammonium chloride (comparative product) B component: B-1 Keratin polypeptide hydrolyzed with wool: molecular weight about 400 (Promois WK: trade name / made by Seiwa Kasei Co., Ltd.) B-2 Polypeptide hydrolyzed with soybean protein: molecular weight about 700 (Promois WS: trade name / made by Naruwa Kasei Co., Ltd. B-3 collagen hydrolyzed collagen polypeptide: molecular weight of about 1000 (Promois W-42: trade name / made by Seiwa Kasei Co., Ltd.) B-4 collagen Hydrolyzed collagen polypeptide: molecular weight about 4000 (Promois W-4000: trade name / made by Seiwa Kasei Co., Ltd.) (comparative product)
【００２２】[0022]
【表２】 評価結果 Ａ成分 Ｂ成分 柔軟性 風合い性 溶液 化合物 配合量 化合物 配合量 綿 ウール 綿 ウール 安定性 実施例１ Ａ−１ 15.0 Ｂ−１ 0.1 ０ ＋１ ０ ＋１ ◎ 比較例１ Ａ−１ 15.0 − − ０ ０ ０ ０ ◎ （対照） 比較例２ − − Ｂ−２ 0.1 −２ −２ −２ −２ ◎ 比較例３ Ａ−１ 15.0 Ｂ−１ 0.0001 ０ ０ ０ ０ ◎ 比較例４ Ａ−１ 15.0 Ｂ−１ 2.0 ０ ＋１ ０ ＋２ △ 比較例５ Ａ−７ 15.0 Ｂ−２ 0.2 ０ ０ ０ ＋１ △ 比較例６ Ａ−１ 15.0 Ｂ−４ 0.5 ０ ＋１ ０ ＋１ △ 比較例７ Ａ−６ 15.0 Ｂ−２ 0.5 −２ −１ −２ −２ ◎ 実施例２ Ａ−２ 15.0 Ｂ−２ 0.5 ０ ＋１ ０ ＋２ ◎ 実施例３ Ａ−３ 5.0 Ｂ−２ 0.5 ０ ＋１ ０ ＋２ ◎ 実施例４ Ａ−３ 15.0 Ｂ−２ 0.1 ０ ＋１ ０ ＋１ ◎ 実施例５ Ａ−４ 15.0 Ｂ−１ 0.5 ０ ＋２ ０ ＋２ ◎ 実施例６ Ａ−５ 5.0 Ｂ−３ 0.5 ０ ＋１ ０ ＋１ ◎ [Table 2]Evaluation results A component B component Flexibility Texture SolutionCompound Compounding amount Compound Compounding amount cotton wool cotton wool Stability Example 1 A-1 15.0 B-1 0.1 0 +1 0 +1 ◎ Comparative Example 1 A-1 15.0 − − 0 0 0 0 0 ◎ (Control) Comparative Example 2 − − B-2 0.1 −2 −2 −2 −2 ◎ Comparative Example 3 A-1 15.0 B-1 0.0001 0 0 0 0 0 ◎ Comparative Example 4 A-1 15.0 B-1 2.0 0 +1 0 +2 △ Comparative Example 5 A-7 15.0 B-2 0.2 0 0 0 +1 △ Comparative Example 6 A-1 15.0 B-4 0.5 0 +1 0 +1 △ Comparative Example 7 A-6 15.0 B-2 0.5 -2 -1 -2 -2 ◎ Example 2 A-2 15.0 B-2 0.5 0 +1 0 +2 ◎ Example 3 A-3 5.0 B-2 0.5 0 +1 0 +2 ◎ Example 4 A-3 15.0 B-2 0.1 0 +1 0 +1 ◎ Example 5 A-4 15.0 B-1 0.5 0 +2 0 +2 ◎ Example 6 A-5 5.0 B-3 0.5 0 +1 0 +1 ◎
Claims (1)
れる第４級アンモニウム塩を３〜３０重量％と、 （Ｂ） 蛋白質を加水分解して得られる重量平均分子量
２００〜１５００のポリペプタイドまたはその誘導体：
０．００１〜１重量％とを含有することを特徴とする柔
軟剤組成物。 【化１】 （Ｒ1，Ｒ2：分断基も含めて炭素数が１８〜２１の、エ
ステル基またはアミド基で分断されたアルキル基または
アルケニル基、あるいは炭素数１６〜２０のアルキル基
またはアルケニル基 Ｒ3，Ｒ4：炭素数１〜３のアルキル基またはヒドロキシ
アルキル基 Ｘ- ：陰イオン）1. (A) 3 to 30% by weight of a quaternary ammonium salt represented by the following general formula (I), and (B) a weight average molecular weight of 200 to 200 obtained by hydrolyzing a protein. 1500 polypeptides or their derivatives:
0.001 to 1% by weight of a softener composition. [Chemical 1] (R 1, R 2: the number of carbon atoms of 18 to 21, including cutting group, an ester group or amide shed alkyl or alkenyl group with a group or an alkyl or alkenyl group R 3 of 16 to 20 carbon atoms, R 4: an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group X -: an anion)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18888793A JP3256748B2 (en) | 1993-06-30 | 1993-06-30 | Liquid softener composition for clothing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18888793A JP3256748B2 (en) | 1993-06-30 | 1993-06-30 | Liquid softener composition for clothing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0718576A true JPH0718576A (en) | 1995-01-20 |
| JP3256748B2 JP3256748B2 (en) | 2002-02-12 |
Family
ID=16231625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18888793A Expired - Fee Related JP3256748B2 (en) | 1993-06-30 | 1993-06-30 | Liquid softener composition for clothing |
Country Status (1)
| Country | Link |
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| JP (1) | JP3256748B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143655A (en) * | 2002-09-30 | 2004-05-20 | Sanyo Chem Ind Ltd | Liquid softener composition |
| WO2017038814A1 (en) * | 2015-08-31 | 2017-03-09 | 株式会社島精機製作所 | Method for manufacturing processed fiber, processed fiber, method for suppressing damage to animal fiber, and method for processing animal fiber |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241198B (en) * | 2010-05-12 | 2013-12-11 | 北京美科艺数码科技发展有限公司 | Spray head control plate and spray head driving voltage control method |
| WO2023104752A1 (en) * | 2021-12-07 | 2023-06-15 | Amsilk Gmbh | Use of a structural polypeptide for treating or finishing textiles |
-
1993
- 1993-06-30 JP JP18888793A patent/JP3256748B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143655A (en) * | 2002-09-30 | 2004-05-20 | Sanyo Chem Ind Ltd | Liquid softener composition |
| WO2017038814A1 (en) * | 2015-08-31 | 2017-03-09 | 株式会社島精機製作所 | Method for manufacturing processed fiber, processed fiber, method for suppressing damage to animal fiber, and method for processing animal fiber |
| JPWO2017038814A1 (en) * | 2015-08-31 | 2018-08-16 | 株式会社島精機製作所 | Processed fiber manufacturing method, processed fiber, animal fiber damage suppressing method, and animal fiber processing method |
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| Publication number | Publication date |
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| JP3256748B2 (en) | 2002-02-12 |
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