JPH07173468A - Method of producing composition for preventing erosion and flowout of red earth and method of laying same - Google Patents

Method of producing composition for preventing erosion and flowout of red earth and method of laying same

Info

Publication number
JPH07173468A
JPH07173468A JP10216991A JP10216991A JPH07173468A JP H07173468 A JPH07173468 A JP H07173468A JP 10216991 A JP10216991 A JP 10216991A JP 10216991 A JP10216991 A JP 10216991A JP H07173468 A JPH07173468 A JP H07173468A
Authority
JP
Japan
Prior art keywords
formula
soil
composition
latex
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10216991A
Other languages
Japanese (ja)
Inventor
Takashi Hashimoto
孝 橋本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP10216991A priority Critical patent/JPH07173468A/en
Publication of JPH07173468A publication Critical patent/JPH07173468A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a composition excellent in an effect of preventing the flowout of red earth into a sea by e.g. rainfall by mixing an aqueous solution of a specified polymer compound with a specified latex and a specified emulsion. CONSTITUTION:An aqueous solution of a compound of formula I is mixed with a latex of formula II and an emulsion of formula III to produce this composition. This composition is sprayed over the surface of red earth or mixed with the earth by means of a stabilizer to convert the earth into water-resistant crumbles. A combination of a compound of formula I with a latex of formula II, a combination of a compound of formula I with an emulsion or formula III and a combination of a latex of formula II with an emulsion of formula III are also effective. The obtained composition is inexpensive, readily soluble in water at ordinary temperature, has high adsorptivity for inorganic matter, is a typical hydrophilic colloid, has viscosity characteristic of a polymer in the form of an aqueous solution and has a function of quickly flocculating soil to prevent its flowout.

Description

【発明の詳細な説明】 る組成物を製造し、該組成物をスタビライザーに着装し
たタンクに入れてスタビライザーの進行と共に土壌表面
と当該液を噴霧か起し混合撹拌又は噴霧機にて土壌表面
に当該液を噴霧し、土壌を団粒耐水化させ降雨等による
滲食流出を防止するものである。即ち本発明による組成
物は他の土壌改良剤に比して低廉であるほか 1)常温において水易溶性であること 2)強力な無機質吸着性を有すること 3)典型的な親水性コロイドであること 4)水溶液の状態において高分子特有の粘性を有するこ
と 等土質改良のための不可欠の性質を完全に具備しておる
から土壌団粒化のための上記組成物を水溶液として地表
に可及的均等に散布すれば、上記組成物は速めに土壌の
表面及び内部に滲透拡散すると同時にその固有の無機質
吸着力と粘性との作用によって容易つつ速やかに土壌を
団粒化し、しかもこうように一旦形成された団粒とはそ
の内部に吸着された前記組成物が親水性コロイドとして
その性質を発揮して団粒形態の安定に欠くことのできな
い適量の水分を常時包食保有させることができるほか土
壌粒子に対する強度の吸着力がある。その結果雨水等に
よって流出することなく、したがって生成した団粒は長
期間にわたってそのままの状態を持続することができ
る。殊に一度形成された団粒が崩壊する事なく長時間持
続することは 水溶液を土壌添加剤として使用する場合の一大特徴であ
って、赤土と施用すると数年にわたってその効果が持続 すると団粒化された赤土の個々と細粒化されたコロイド
間に粘着力を与えシート状に結合させ雨水による流出を
防止する。又 を加えてやることにより対働画性を強め風等による外圧
に対して網目のように赤土を被覆し、やはり風雨からの
流出を防止できる。このように三様の相爽効果により完
全に降雨等から赤土の滲食流出を防止することができ
る。その他 5)耐腐食性であること 6)生物に対して完全無害であること 7)本溶液の形態で酸性でもアルカリ性でもなく中性で
あるから土壌に対して悪影響を与える恐れがないこと 等の性質がある。又、本発明に使用する は通常の公知の方法によって製造されるもののなかから
完全鹸化,部分鹸化に規定されるものでなく所謂カマ底
と稍されるものでメーカとしては廃棄物若しくは規格外
製品で低廉である。然し物性的には酢酸基が残存するこ
とがその特徴であって本発明に充分使用できるものがあ
る。又 ラテックスの粒子の水中分散構造は上図の如くなってお
りゴムラテック中のゴム炭化水素粒子は非極性の疏水物
質からラテックス中の水分となじみが悪く比重差で浮上
して分離してしまう。それを防止して活発なブラウン運
動をさせるためにはゴム粒子の表面に吸着された蛋白質
の保護皮膜(保護コロイド)が必要かつ有効となる。ゴ
ム分の表面と吸着される蛋白のC母体とゴムのC母体間
と接触し外側と向って末端基のカルボシキ基 COOH
とアミノ基 NH基がクリのイガの様にならんでい
る。そして装水液の中のHOからHで吸引すべき盛
んに負号の送電を送る。ゴム粒子を取巻く水和層を生成
による保護コロイド的効果となる。水和層は、溶液中で
溶質分子またはイオンのその周囲を数個の水分を引きつ
けて結合し一つの分子郡をつくる現象である。このこと
は土壌中の水分を以上の現象で長期的に土壌水を保留す
る働きがある。 実施例 上記組成物を使って沖縄県名護市許田に実施実例の試験
団地にて実験を行った。沖縄県地方の多くの土壌は赤黄
色土であり、これらの土壌は降雨による土壌滲食流出を
受け易い物理的特性を有している又同地域の地形は緩傾
斜であり、急岐で谷密度が高く河川は急勾配で短小であ
る。更に滲食の能動的要因である降雨のエネルギーも高
い。従ってこの地域での土地改変によって土地構成が破
壌露出される場合のポテンシャルが高くなる。その結果
降雨による土地滲食が起き流出は赤土砂を運んで流下し
て河海を汚濁し流域環境の悪化を著起している。 東沖縄赤色黄土土質分析 イ)土質分類 粘性土又は粘土 ロ) 土質試験 (粘 土) エンシステンシー 土の分類 土の性状 a.試験内容 (1)含水の変化に従うコーン貫入試験均一軸元縮試験 採取土のトアフィカビリティーを知る為同一土で含水量
を変化させて試験を行う。 1) コーン貫入試験 設定含水量 10% 15% 20% 22% 2
4% 25%26% 28% 30% 32% 2) 突 き 固 め 15モールド 56回 3層 (KODAN 110−1995に従う) 3) 養 生 突き固め後即時試験 4) 試 験 方 法 2.5cmと5cm貫入後の
平均的数値一供誠体で4点測定し、その平均値をもとに
次式からコーン指数を求める。 実 施 例 実験地説明 (A工区) スタビライザーによる路上混合方式にによ
る転圧工法 深度 厚 10cm 薬剤散布量 6.2/cm 転 圧 2.5tタイヤローラー (B工区) 噴霧機による被覆工法 薬剤散布量 3.2/cm (C工区) 路上混合と転圧工法 単なる路上混合 路上混合+転圧工法 (A工区) 路上混合方法による転圧工法 深 度 厚 10cm 薬剤散布量 6.2l/m 転圧 2.5tタイヤローラー (B工区) 被 覆 工 法 薬剤散布量 3.2l/m (C工区) 路上混合と転圧工法 単なる路上混合 路上混合と転圧工法 以上試験の結果台風(100mm/h,25mm/h)
q 2回の経験を経て赤色黄土の流出は認められなかっ
た。9m本薬剤目的は充分評価できるものである。
Detailed Description of the Invention To produce a composition, put the composition in a tank equipped with a stabilizer and spray or raise the soil surface and the liquid with the progress of the stabilizer, and spray the liquid on the soil surface with a mixing agitator or a sprayer, The aggregates are made water resistant to prevent erosion and runoff due to rainfall. That is, the composition according to the present invention is less expensive than other soil conditioners and 1) it is easily soluble in water at room temperature 2) it has a strong inorganic adsorption property 3) it is a typical hydrophilic colloid 4) Since it has the essential properties for soil improvement, such as having a polymer-specific viscosity in the state of aqueous solution, it is possible to use the above composition for soil aggregation as an aqueous solution on the ground surface as much as possible. If applied evenly, the above composition will quickly permeate and diffuse into the surface and inside of the soil, and at the same time easily and quickly aggregate the soil by the action of its inherent inorganic adsorption force and viscosity, and once it is formed like this. The agglomerated aggregates have the property that the above-mentioned composition adsorbed inside thereof exerts its properties as a hydrophilic colloid, and can always hold an appropriate amount of water that is indispensable for stable aggregated granules in addition to soil. There are suction force strength to particle. As a result, it does not flow out due to rainwater or the like, and thus the produced aggregate can be maintained as it is for a long period of time. Especially, once the aggregate is formed, it does not collapse and lasts for a long time. This is one of the main characteristics of using an aqueous solution as a soil additive. When applied with red soil, its effect lasts for several years. Then, an adhesive force is applied between the aggregated red soil and the finely divided colloids to bond them in a sheet form to prevent runoff by rainwater. or By adding this, the action image is strengthened and the red soil is covered like a mesh against external pressure due to wind, etc., and it is also possible to prevent outflow from wind and rain. In this way, the three different effects can completely prevent erosion and outflow of red soil from rainfall or the like. Others 5) Corrosion resistance 6) Being completely harmless to living organisms 7) Being neither neutral nor acidic or alkaline in the form of this solution, there is no possibility of adversely affecting the soil. There is a property. Also used in the present invention Among the products produced by the usual publicly known methods, those which are not regulated to complete saponification or partial saponification but are so-called sesame bottoms are waste products or nonstandard products which are inexpensive as a manufacturer. However, in terms of physical properties, some of them are characterized in that an acetic acid group remains and can be sufficiently used in the present invention. or The dispersion structure of latex particles in water is as shown in the above figure, and the rubber hydrocarbon particles in the rubber latex are separated from the non-polar hydrophobic substance by the difference in specific gravity because they are not well compatible with the water in the latex. A protective film (protective colloid) of the protein adsorbed on the surface of the rubber particles is necessary and effective in order to prevent it and to make active Brownian motion. When the surface of the rubber is in contact with the C matrix of the protein to be adsorbed and the C matrix of the rubber, the end of the carboxyl group is COOH toward the outside.
And the amino group NH 2 group is arranged like a chestnut moth. Then, negative power transmission is sent from H 2 O in the water filling liquid to be sucked with H 2 . It produces a protective colloidal effect by forming a hydrated layer surrounding the rubber particles. The hydration layer is a phenomenon in which a solute molecule or ion in a solution attracts and binds several water molecules to form one molecular group. This has a function of retaining the water in the soil for a long term by the above phenomenon. Example Using the above composition, an experiment was conducted in Kyoda, Nago City, Okinawa Prefecture, in an experimental park of practical examples. Many soils in the Okinawa region are red-yellow soils, and these soils have physical characteristics that are susceptible to soil erosion and runoff due to rainfall. The rivers are dense and the rivers are steep and short. Furthermore, the energy of rainfall, which is an active factor of erosion, is high. Therefore, the potential is high when the land composition is exposed to the destruction by land modification in this area. As a result, land erosion due to rainfall occurs, and the runoff carries red earth and sand, which flows down and pollutes the river and sea, causing the deterioration of the basin environment. East Okinawa Red Loess Soil analysis a) Soil classification Cohesive soil or clay b) Soil test (soil) Consistency Classification of soil Properties of soil a. Test contents (1) Cone penetration test according to changes in water content Uniform axial compression test In order to know the toafability of the soil, the water content is changed in the same soil and the test is conducted. 1) Cone penetration test setting water content 10% 15% 20% 22% 2
4% 25% 26% 28% 30% 32% 2) Tightening 15 molds 56 times 3 layers (according to KODAN 110-1995) 3) Curing Immediately after tamping 4) Test method 2.5 cm and The average value after 5 cm penetration is measured at 4 points with a single specimen, and the cone index is calculated from the following formula based on the average value. Example Experiment site explanation (A section) Rolling compaction method depth by the road mixing method by the stabilizer Thickness 10 cm Drug spraying amount 6.2 / cm 2 Rolling pressure 2.5t Tire roller (B section) Coating method chemical spraying amount by sprayer 3. 2 / cm 2 (C section) Road mixing and rolling method Simple road mixing Road mixing + rolling method (A section) Rolling method depth by road mixing method Thickness 10 cm Chemical spraying amount 6.2 l / m 2 Rolling pressure 2.5 t Tire roller (B section) Covering method Chemical spraying amount 3.2 l / m 2 (C Section) Road mixing and rolling method Simple road mixing Road mixing and rolling method Results of the above test Typhoon (100 mm / h, 25 mm / h)
q After 2 times of experience, no outflow of red loess was observed. 9m The purpose of this drug can be sufficiently evaluated.

Claims (1)

【特許請求の範囲】 エマルジョンを添加混合してなる組成物を赤土土壌表面
に噴霧若しくはスタビライザーによる路上混合し、赤土
土壌の滲食流出を防止することを特徴とする組成物の製
造並びに施工法に関する。 の組合せを特許請求の範囲と包食するものである。
[Claims] The present invention relates to a method for manufacturing and applying a composition, characterized in that a composition obtained by adding and mixing an emulsion is sprayed on the surface of red soil soil or mixed on the road by a stabilizer to prevent erosion and outflow of red soil soil. The combination of is included in the claims.
JP10216991A 1991-02-06 1991-02-06 Method of producing composition for preventing erosion and flowout of red earth and method of laying same Pending JPH07173468A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10216991A JPH07173468A (en) 1991-02-06 1991-02-06 Method of producing composition for preventing erosion and flowout of red earth and method of laying same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10216991A JPH07173468A (en) 1991-02-06 1991-02-06 Method of producing composition for preventing erosion and flowout of red earth and method of laying same

Publications (1)

Publication Number Publication Date
JPH07173468A true JPH07173468A (en) 1995-07-11

Family

ID=14320207

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10216991A Pending JPH07173468A (en) 1991-02-06 1991-02-06 Method of producing composition for preventing erosion and flowout of red earth and method of laying same

Country Status (1)

Country Link
JP (1) JPH07173468A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007217973A (en) * 2006-02-17 2007-08-30 Asahi Kasei Fibers Corp Red soil runoff preventive method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4835706A (en) * 1971-09-10 1973-05-26

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4835706A (en) * 1971-09-10 1973-05-26

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007217973A (en) * 2006-02-17 2007-08-30 Asahi Kasei Fibers Corp Red soil runoff preventive method
JP4703428B2 (en) * 2006-02-17 2011-06-15 旭化成せんい株式会社 How to prevent red soil runoff

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