CN108033808A - A kind of method for improving porous concrete product hole anti-clogging ability - Google Patents

A kind of method for improving porous concrete product hole anti-clogging ability Download PDF

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Publication number
CN108033808A
CN108033808A CN201711295479.6A CN201711295479A CN108033808A CN 108033808 A CN108033808 A CN 108033808A CN 201711295479 A CN201711295479 A CN 201711295479A CN 108033808 A CN108033808 A CN 108033808A
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CN
China
Prior art keywords
surfactant
concrete product
porous concrete
solution
hole anti
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Pending
Application number
CN201711295479.6A
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Chinese (zh)
Inventor
张磊
宋林柯
荣辉
杨久俊
王雪平
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Tianjin Chengjian University
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Tianjin Chengjian University
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Priority to CN201711295479.6A priority Critical patent/CN108033808A/en
Publication of CN108033808A publication Critical patent/CN108033808A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/64Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/47Oils, fats or waxes natural resins
    • C04B41/478Bitumen, asphalt, e.g. paraffin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/483Polyacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4857Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B41/4869Polyvinylalcohols, polyvinylacetates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/4922Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
    • C04B41/4927Alkali metal or ammonium salts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/63Macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Abstract

The invention discloses a kind of method for improving porous concrete product hole anti-clogging ability;This method is by the way that molding porous concrete product is immersed in the surfactant solution, surfactant is set to adhere to form new surface texture in porous concrete product pore surface, to improve the adhesive ability for reducing fine particle in hole, so as to effectively prevent tiny particle from blocking pervious concrete;The present invention can solve the blockage problem that current porous concrete product is generally faced using process, can extend the service life of porous concrete product, ensure the water permeable ability of porous concrete product.

Description

A kind of method for improving porous concrete product hole anti-clogging ability
Technical field
The invention belongs to building material technical field, and in particular to one kind improves porous concrete product hole anti-clogging energy The method of power.
Background technology
Permeable concrete is a kind of ecological method environment-friendly concrete, is that one kind has continuous aperture by special process is manufactured The concrete of gap;Not only there is certain intensity, but also have certain ventilative water permeability.Permeable concrete, which is mated formation, can alleviate city Rain flood, reduces rainy day skidding, dazzle, improves the security and comfort of running car, sqouynd absorption lowering noise, alleviates urban heat island effect Should.
But general porous concrete product road surface or water-permeable brick, due to the requirement of water penetration, porosity generally compared with Greatly, after pervious concrete pavement is built up, because of a large amount of suspended particulates such as mud contained in the rainwash of the reasons such as rainfall generation Sand, chip etc. can be entered constantly in the hole of porous concrete product with current, pore plugging be caused, so as to cause road surface Permeance property reduces the drain function for being difficult to play porous pavement, shortens porous concrete product service life of road surface, causes Waste economically.
Also there are various discussions for this way to solve the problem at present, be concentrated mainly on from porous concrete product road surface Structure and source material mixture ratio etc. solve the problems, such as.
To solve the above-mentioned problems, the present inventor after various experiments and analysis testing result by having found, above problem production The reason for raw one is important is due to that the porosity of pervious concrete itself is larger, and tamper can be detained hole during use It is interior.Therefore, the present inventor is from material angle, by the way that the porous concrete product of forming is immersed in some surface-actives In agent solution, surfactant adheres to form new surface texture in pervious concrete pore surface, and it is fine to be effectively improved reduction Adhesive ability of the particulate matter in hole, so as to avoid tamper from being trapped in pervious concrete hole, with reach prevent it is permeable Concrete block, it is ensured that its draining it is unobstructed.
The content of the invention
The object of the present invention is to provide a kind of method for improving porous concrete product hole anti-clogging ability.
The method of the present invention includes:It is molded and is conserved to the porous concrete product of 28 day age by preparing, is immersed in surface In activator solution 24 it is small when;
The surfactant is one kind in following material:
(1) organic silicon emulsion class surfactant, solid content are 25-40%;
(2) polypropylene esters emulsification surfactants, mass percent concentration are 0.5-5%;
(3) polyethylene esters emulsification surfactants, mass percent concentration are 0.5-5%;
(4) paraffin wax emulsions class surfactant, solid content are 30-50%;
Using surfactant solution soak method be:
1) water soluble surfactant active's organic silicon emulsion
It is 1 in mass ratio by surfactant and water:8—1:10 ratio mixing, is configured to surfactant solution, will Prepare molding concrete product be completely soaked wherein 24 it is small when;
2) water-insoluble surfactant polypropylene esters lotion, polyethylene esters lotion, paraffin wax emulsions
By the alcoholic solution in mass ratio 1 that surfactant and mass concentration are 75%~95%:8—1:10 ratios mix Be formed uniformly mixed solution, will prepare molding concrete product be completely soaked wherein 24 it is small when.
Porous concrete product prepared by the present invention is passed through with normal concrete product in the case where other conditions are identical Overtesting is proved to final anti-clogging result:Product of the present invention is far superior to common porous concrete product.
The condition of present invention selection surfactant:
A. there is good dispersiveness:It can be uniformly dispersed in pervious concrete;
B. there is good compatibility:Keep pervious concrete original raw material and proportioning, process for producing constant, ` tables Face activating agent can coexist with other raw materials of pervious concrete, and chemical change does not occur, to the mechanical property shadow of pervious concrete Ring very little;
C. there is good hydrophobicity:The water absorption rate of pervious concrete can be greatly lowered;
D. there is good application property:Powder powder or liquid surfactant can be directly added into pervious concrete raw material Using or immersion, be not required to extra construction technology.
The principle of the invention:The present invention is keeping the original material of common pervious concrete and proportioning, process for producing constant On the basis of, common porous concrete product is soaked with prepared surfactant solution, surfactant can be dispersed In porous concrete product, including it is dispersed in the pore surface on inside porous concrete product and surface.During rainfall, due to hole The surfactant component on gap surface exists, and the surface texture of the internal void of pervious concrete is improved, reduced fine Adhesive ability of the particulate matter in hole, so as to reduce the tamper being trapped in hole, ensures the permeable energy of pervious concrete Power.
The advantages and features of the present invention:
1. the present invention prevents from blocking from the surface texture for improving pervious concrete internal void, solve permeable at present mixed The anti-clogging technical barrier that solidifying soil promotes and applies.
2. the method for the present invention can extend the service life of pervious concrete;With good social and economic benefit.
Embodiment
For a better understanding of the present invention, it is described further below with embodiment, but limit is not formed to the present invention System.
Embodiment 1:The Contrast on effect of the method for the present invention
1 porous concrete product match ratio of table
Each material is taken by table 1.
After above-mentioned raw materials are mixed, stirred 3 minutes with concrete mixer, vibrate into method;Then by the mixing after stirring Thing is inverted in the die trial of 100 × 100 × 100mm, 24 it is small when after demould and be put into standard curing room that (temperature is 20 DEG C, humidity 90%) to conserve 28 days.Measure 28 days compression strength of porous concrete product, 1/6h, 1h, 4h, 24h, porosity, infiltration coefficient As shown in table 2.
Clay is taken as material is blocked, every time respectively takes tamper 1g to be uniformly applied to test block surface, blend rubber hammer is light Pat and place 3 days after reality in natural environment, continuous 10 times, to simulate porous concrete product in actual use stifled Plug process.And the coefficient of permeability of each test block is measured after the stipulated time, the results are shown in Table 2.
The common porous concrete product mechanics of table 2, water permeability test
Keep raw material type, proportioning and other treatment process of the normal concrete product constant, will be obtained permeable mixed Solidifying soil product is immersed in organic silicon emulsion class surfactant in method of the present invention (quality proportioning is as shown in table 3), gathers 24 is small in acrylic acid ester emulsion class surfactant, polyethylene esters emulsification surfactants and paraffin wax emulsions class surfactant When.Gained porous concrete product intensity, water absorption rate, porosity, infiltration coefficient are as shown in table 3.
Table 3 fills surfactant porous concrete product mechanics, water permeability test
Organic solvent refers to 75%~95% alcoholic solution.

Claims (2)

1. it is a kind of improve porous concrete product hole anti-clogging ability method, it is characterised in that will prepare be molded and conserve to The porous concrete product of 28 day age, be immersed in surfactant solution 24 it is small when;
The surfactant is one kind in following material:
(1) organic silicon emulsion class surfactant, solid content are 25-40%;
(2) polypropylene esters emulsification surfactants, mass percent concentration are 0.5-5%;
(3) polyethylene esters emulsification surfactants, mass percent concentration are 0.5-5%;
(4) paraffin wax emulsions class surfactant, solid content are 30-50%.
2. a kind of method for improving porous concrete product hole anti-clogging ability according to claim 1, its feature exist It is in the method soaked using surfactant solution:
1) water soluble surfactant active's organic silicon emulsion
It is 1 in mass ratio by surfactant and water:8—1:10 ratio mixing, is configured to surfactant solution, will prepare Molding concrete product be completely soaked wherein 24 it is small when;
2) water-insoluble surfactant polypropylene esters lotion, polyethylene esters lotion, paraffin wax emulsions
By the alcoholic solution in mass ratio 1 that surfactant and mass concentration are 75%~95%:8—1:10 ratios are uniformly mixed Formed mixed solution, will prepare molding concrete product be completely soaked wherein 24 it is small when.
CN201711295479.6A 2017-12-08 2017-12-08 A kind of method for improving porous concrete product hole anti-clogging ability Pending CN108033808A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711295479.6A CN108033808A (en) 2017-12-08 2017-12-08 A kind of method for improving porous concrete product hole anti-clogging ability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711295479.6A CN108033808A (en) 2017-12-08 2017-12-08 A kind of method for improving porous concrete product hole anti-clogging ability

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Publication Number Publication Date
CN108033808A true CN108033808A (en) 2018-05-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110818446A (en) * 2019-11-13 2020-02-21 顾肇忠 Movable marble wax baking device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786901A (en) * 2010-03-05 2010-07-28 浙江凌志精细化工有限公司 Organosilicon emulsion-type waterproofing agent for building material surfaces and preparation method thereof
CN102557726A (en) * 2011-12-27 2012-07-11 华南理工大学 High-permeability multi-effect concrete water-proofing agent and preparation method thereof
CN102898065A (en) * 2012-10-24 2013-01-30 北京工业大学 Cracking and hollowing resistant aerated concrete water repellent and use method thereof
CN103043946A (en) * 2013-01-05 2013-04-17 于化平 Organosilicon waterproof emulsion and preparation method and application of organosilicon waterproof emulsion
CN107162473A (en) * 2017-07-23 2017-09-15 四川华西绿舍建材有限公司 A kind of pervious concrete special additive and its application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786901A (en) * 2010-03-05 2010-07-28 浙江凌志精细化工有限公司 Organosilicon emulsion-type waterproofing agent for building material surfaces and preparation method thereof
CN102557726A (en) * 2011-12-27 2012-07-11 华南理工大学 High-permeability multi-effect concrete water-proofing agent and preparation method thereof
CN102898065A (en) * 2012-10-24 2013-01-30 北京工业大学 Cracking and hollowing resistant aerated concrete water repellent and use method thereof
CN103043946A (en) * 2013-01-05 2013-04-17 于化平 Organosilicon waterproof emulsion and preparation method and application of organosilicon waterproof emulsion
CN107162473A (en) * 2017-07-23 2017-09-15 四川华西绿舍建材有限公司 A kind of pervious concrete special additive and its application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110818446A (en) * 2019-11-13 2020-02-21 顾肇忠 Movable marble wax baking device
CN110818446B (en) * 2019-11-13 2021-12-17 北京石管家石材护理科技有限公司 Movable marble wax baking device

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Application publication date: 20180515

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