JPH07169493A - Combustible gas purge device for fuel cell power plant - Google Patents

Combustible gas purge device for fuel cell power plant

Info

Publication number
JPH07169493A
JPH07169493A JP5317172A JP31717293A JPH07169493A JP H07169493 A JPH07169493 A JP H07169493A JP 5317172 A JP5317172 A JP 5317172A JP 31717293 A JP31717293 A JP 31717293A JP H07169493 A JPH07169493 A JP H07169493A
Authority
JP
Japan
Prior art keywords
gas
plant
exhaust gas
fuel cell
cell power
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5317172A
Other languages
Japanese (ja)
Inventor
Shuichi Yoshida
修一 吉田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP5317172A priority Critical patent/JPH07169493A/en
Publication of JPH07169493A publication Critical patent/JPH07169493A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04231Purging of the reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

PURPOSE:To purge a combustible gas in a system without using nitrogen gas by providing an exhaust gas purge line for purging a plant internal combustible gas with the plant exhaust gas in a fuel cell power plant. CONSTITUTION:The exhaust gas of a fuel cell power plant 1 is sucked by the exhaust cylinder 2 of the plant 1. The exhaust gas is passed through an oxygen adsorber 3, whereby the concentration of the oxygen in the exhaust gas is reduced to zero or a low concentration lower than the ignition concentration. To confirm this, an oxygen densitometer 4 is set on the outlet port of the oxygen adsorber 3 for monitoring and protection. The inactivated exhaust gas is raised in pressure by a booster 5, and stored in a reservoir tank 7 after the moisture is removed by a dehumidifier 6. When the plant is stopped, the exhaust gas stored in the reservoir tank 7 is used to purge the combustible gas in the plant. This combustible gas purge device allows to set a fuel cell power plant in a place difficult to supply nitrogen gas.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、燃料電池発電プラント
の可燃性ガスパージ装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a combustible gas purging device for a fuel cell power plant.

【0002】[0002]

【従来の技術】燃料電池発電プラントは、自家用発電と
して電力源として利用されるほかに、需用地に近い点を
生かし、排熱を給湯、冷暖房、その他熱利用に使用され
ている。
2. Description of the Related Art A fuel cell power plant is used not only as an electric power source for private power generation but also as a hot water supply, cooling and heating, and other heat utilization by taking advantage of the fact that it is close to the place of demand.

【0003】燃料電池を使用した発電プラントは、小型
サイズでも高効率であること、燃料の多様化が計れるこ
と、排熱の有効利用が実施しやすいこと、特にオンサイ
ト型はビルの地下等需用地近くに設置できること、等い
くつかのすぐれた特徴を持っている。そのため、各分野
で積極的に導入が計画されており、実証プラントの設置
も盛んである。
A power plant using a fuel cell is highly efficient even in a small size, can diversify fuels, and can effectively utilize exhaust heat. It has some excellent features such as being able to be installed near the site. Therefore, the introduction is planned actively in each field, and the installation of demonstration plants is also active.

【0004】排気中のNOX,SOX,ばいじん等も他
発電設備に比較して、極めて低い値であることも、将来
の発電装置として有望である。燃料電池にも燃料に使用
する可能性ガスを系内に滞留させている。運転中は、電
池本体により消費しているが、停止した時点は、未反応
の可燃性ガスが機器及び配管内に滞留したままになって
しまう。安全を確保するために、この可燃性ガスは不活
性ガスを使用して系内より系外へ放出している。
It is also promising as a future power generator that NOX, SOX, dust and the like in the exhaust gas have extremely low values as compared with other power generation facilities. Gas that can be used as fuel is also retained in the fuel cell. Although it is consumed by the battery main body during operation, unreacted combustible gas remains in the equipment and the pipes when stopped. In order to ensure safety, this flammable gas is released from the inside of the system to the outside of the system by using an inert gas.

【0005】[0005]

【発明が解決しようとする課題】不活性ガスは通常窒素
ガスが使用されている。そのため燃料電池発電プラント
には、大小を取わず窒素ガスボンベ又は、液化窒素貯蔵
装置を有している。この発明の目的は、この窒素ガス貯
蔵装置を削減し、N2 ガス(窒素ガス)を使用せずに系
内の可燃性ガスをパージする装置を有する燃料電池発電
プラントを提供することにある。
Nitrogen gas is usually used as the inert gas. Therefore, the fuel cell power generation plant has a nitrogen gas cylinder or a liquefied nitrogen storage device regardless of its size. An object of the present invention is to provide a fuel cell power plant having a device for reducing the nitrogen gas storage device and for purging combustible gas in the system without using N 2 gas (nitrogen gas).

【0006】[0006]

【課題を解決するための手段】燃料電池発電プラントの
排気ガスは、取り扱っている全ガスのうち最も酸素濃度
の低いガスである。この排気ガス中の酸素分をゼロ又は
発火の恐れのない低濃度に低減させ、不活性ガスとして
窒素ガスの代用としてパージに使用する。
Exhaust gas from a fuel cell power plant is the gas with the lowest oxygen concentration of all the gases handled. The oxygen content in the exhaust gas is reduced to zero or a low concentration without fear of ignition, and is used for purging as a substitute for nitrogen gas as an inert gas.

【0007】[0007]

【作用】排気ガス中の酸素を吸着器により除去し、不活
性ガスとする。
[Function] Oxygen in the exhaust gas is removed by an adsorber to form an inert gas.

【0008】[0008]

【実施例】この発明の実施例を図1に示す。燃料電池発
電プラント1の排気筒2よりプラントの排気ガスを吸引
する。排気ガスは酸素吸着器3を通過することにより、
排気ガス中の酸素はゼロ又は発火濃度以下の低濃度へ低
下させられる。確認のため、酸素吸着器3の出口に酸素
濃度計4を設置し、監視・保護を設ける。不活性化され
た排気ガスは昇圧器5により、昇圧され、除湿器6にて
水分を除去された後に、リザーバタンク7に貯蔵され
る。プラント停止時にリザーバタンク7に貯蔵された排
気ガスによりプラント内の可燃性ガスのパージに使用さ
れる。
FIG. 1 shows an embodiment of the present invention. The exhaust gas of the plant is sucked from the exhaust stack 2 of the fuel cell power generation plant 1. By passing the exhaust gas through the oxygen adsorber 3,
Oxygen in the exhaust gas is reduced to zero or a low concentration below the ignition concentration. For confirmation, an oxygen concentration meter 4 is installed at the outlet of the oxygen adsorber 3 for monitoring and protection. The inactivated exhaust gas is boosted by the booster 5, has its moisture removed by the dehumidifier 6, and is then stored in the reservoir tank 7. The exhaust gas stored in the reservoir tank 7 when the plant is stopped is used to purge the combustible gas in the plant.

【0009】不活性ガスとして使用する窒素ガスが不用
となり、その貯蔵設備が不要となった。排気ガスに水素
ガス等の可燃性ガスを注入し、触媒酸化器8により酸化
させ酸素濃度を低下させる。さらに、リサイクルブロワ
9により、入口に還流させ、さらに酸素濃度を低下させ
る。監視のために酸素濃度計4と可燃性ガス計10により
監視保護を行なう。
The nitrogen gas used as the inert gas is no longer needed, and the storage facility for it becomes unnecessary. A combustible gas such as hydrogen gas is injected into the exhaust gas and is oxidized by the catalytic oxidizer 8 to reduce the oxygen concentration. Further, the recycle blower 9 is used to recirculate to the inlet to further reduce the oxygen concentration. For monitoring, the oxygen concentration meter 4 and the combustible gas meter 10 provide monitoring protection.

【0010】[0010]

【発明の効果】この発明により、窒素ガスの供給が困難
な場所においても燃料電池発電プラントが設置可能とな
った。
According to the present invention, a fuel cell power plant can be installed even in a place where it is difficult to supply nitrogen gas.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の一実施例による可燃性ガスパージ装
置の構成図
FIG. 1 is a configuration diagram of a flammable gas purging device according to an embodiment of the present invention.

【図2】この発明の他の実施例による可燃性ガスパージ
装置の構成図
FIG. 2 is a configuration diagram of a flammable gas purging device according to another embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1…燃料電池発電プラント 2…排気筒 3…酸素吸着器 4…酸素濃度計 5…昇圧器 6…除湿器 7…リザーバタンク 8…触媒酸化器 9…リザーバタンク 10…可燃性ガス計 1 ... Fuel cell power plant 2 ... Exhaust stack 3 ... Oxygen adsorber 4 ... Oxygen concentration meter 5 ... Booster 6 ... Dehumidifier 7 ... Reservoir tank 8 ... Catalytic oxidizer 9 ... Reservoir tank 10 ... Combustible gas meter

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 燃料電池発電プラントにおいて、プラン
ト内可燃性ガスをプラント排気ガスでパージする排ガス
パージラインを設けたことを特徴とする燃料電池発電プ
ラントの可燃性ガスパージ装置。
1. A combustible gas purge device for a fuel cell power plant, comprising an exhaust gas purge line for purging the combustible gas in the plant with the plant exhaust gas in the fuel cell power plant.
【請求項2】 前記排気ガスパージラインに、可燃性ガ
ス除去器、昇圧器、除湿器、リザーバタンクを設けるこ
とを特徴する請求項1に記載の燃料電池発電プラントの
可燃性ガスパージ装置。
2. The flammable gas purging apparatus for a fuel cell power plant according to claim 1, wherein a flammable gas remover, a booster, a dehumidifier, and a reservoir tank are provided in the exhaust gas purge line.
JP5317172A 1993-12-17 1993-12-17 Combustible gas purge device for fuel cell power plant Pending JPH07169493A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5317172A JPH07169493A (en) 1993-12-17 1993-12-17 Combustible gas purge device for fuel cell power plant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5317172A JPH07169493A (en) 1993-12-17 1993-12-17 Combustible gas purge device for fuel cell power plant

Publications (1)

Publication Number Publication Date
JPH07169493A true JPH07169493A (en) 1995-07-04

Family

ID=18085263

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5317172A Pending JPH07169493A (en) 1993-12-17 1993-12-17 Combustible gas purge device for fuel cell power plant

Country Status (1)

Country Link
JP (1) JPH07169493A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2834586A1 (en) * 2002-01-04 2003-07-11 Peugeot Citroen Automobiles Sa Generation of electricity from a fuel cell to drive a vehicle, uses purge circuit to deliver inert gas to anode to stop fuel cell operation and prevent fuel build up, and diverts combustive material away from anode
WO2004001885A1 (en) * 2002-06-24 2003-12-31 Delphi Technologies, Inc. Oxygen getters for anode protection in a solid-oxide fuel cell stack
WO2004012288A2 (en) * 2002-07-31 2004-02-05 Fuel Cell Technologies Ltd. Fuel cell system with degradation protected anode
EP1522114A2 (en) * 2002-06-24 2005-04-13 Delphi Technologies, Inc. Oxygen isolation and collection for anode protection in a solid-oxide fuel cell stack
JP2008123864A (en) * 2006-11-13 2008-05-29 Idemitsu Kosan Co Ltd Fuel cell system and its operation control method
JP2008123865A (en) * 2006-11-13 2008-05-29 Idemitsu Kosan Co Ltd Fuel cell system
US7387650B2 (en) 2002-05-02 2008-06-17 Mitsubishi Heavy Industries, Ltd. Fuel cell power generation system and method for operating the same
DE102005052535B4 (en) * 2005-04-12 2011-04-21 Mitsubishi Denki K.K. Fuel cell power generation system with deoxidizer tank
US8053128B2 (en) 2008-04-10 2011-11-08 Delphi Technologies, Inc. Apparatus for solid-oxide fuel cell shutdown having a timing circuit and a reservoir
US20120315557A1 (en) * 2007-07-19 2012-12-13 Ford Motor Company Oxygen removal systems during fuel cell shutdown

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2834586A1 (en) * 2002-01-04 2003-07-11 Peugeot Citroen Automobiles Sa Generation of electricity from a fuel cell to drive a vehicle, uses purge circuit to deliver inert gas to anode to stop fuel cell operation and prevent fuel build up, and diverts combustive material away from anode
US7387650B2 (en) 2002-05-02 2008-06-17 Mitsubishi Heavy Industries, Ltd. Fuel cell power generation system and method for operating the same
WO2004001885A1 (en) * 2002-06-24 2003-12-31 Delphi Technologies, Inc. Oxygen getters for anode protection in a solid-oxide fuel cell stack
EP1522114A4 (en) * 2002-06-24 2008-11-12 Delphi Tech Inc Oxygen isolation and collection for anode protection in a solid-oxide fuel cell stack
EP1522114A2 (en) * 2002-06-24 2005-04-13 Delphi Technologies, Inc. Oxygen isolation and collection for anode protection in a solid-oxide fuel cell stack
US7435490B2 (en) * 2002-06-24 2008-10-14 Delphi Technologies, Inc. Oxygen getters for anode protection in a solid-oxide fuel cell stack
WO2004012288A3 (en) * 2002-07-31 2005-02-03 Fuel Cell Technologies Ltd Fuel cell system with degradation protected anode
US7226679B2 (en) 2002-07-31 2007-06-05 Siemens Power Generation, Inc. Fuel cell system with degradation protected anode
WO2004012288A2 (en) * 2002-07-31 2004-02-05 Fuel Cell Technologies Ltd. Fuel cell system with degradation protected anode
US7465509B2 (en) 2002-07-31 2008-12-16 Siemens Energy, Inc. Fuel cell system with degradation protected anode
DE102005052535B4 (en) * 2005-04-12 2011-04-21 Mitsubishi Denki K.K. Fuel cell power generation system with deoxidizer tank
JP2008123865A (en) * 2006-11-13 2008-05-29 Idemitsu Kosan Co Ltd Fuel cell system
JP2008123864A (en) * 2006-11-13 2008-05-29 Idemitsu Kosan Co Ltd Fuel cell system and its operation control method
US20120315557A1 (en) * 2007-07-19 2012-12-13 Ford Motor Company Oxygen removal systems during fuel cell shutdown
US8053128B2 (en) 2008-04-10 2011-11-08 Delphi Technologies, Inc. Apparatus for solid-oxide fuel cell shutdown having a timing circuit and a reservoir

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