JPH07167575A - Hybrid thermal storage tank - Google Patents
Hybrid thermal storage tankInfo
- Publication number
- JPH07167575A JPH07167575A JP5316403A JP31640393A JPH07167575A JP H07167575 A JPH07167575 A JP H07167575A JP 5316403 A JP5316403 A JP 5316403A JP 31640393 A JP31640393 A JP 31640393A JP H07167575 A JPH07167575 A JP H07167575A
- Authority
- JP
- Japan
- Prior art keywords
- water
- heat storage
- storage tank
- thermal storage
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
- F28D20/025—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being in direct contact with a heat-exchange medium or with another heat storage material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
- F28D20/026—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat with different heat storage materials not coming into direct contact
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Other Air-Conditioning Systems (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、伝熱流体を介して蓄熱
するハイブリッド蓄熱槽に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hybrid heat storage tank that stores heat via a heat transfer fluid.
【０００２】[0002]
【従来の技術】安価な夜間電力を利用して蓄熱したり、
排熱を回収して再活用をしたり、熱の緊急バックアップ
のために蓄熱したりするために、種々の熱回収システム
が考えられている。蓄熱槽は、このような熱回収システ
ムで回収した熱を蓄熱する手段として大きな役割を果た
すものである。この蓄熱槽には、潜熱蓄熱方式のものと
顕熱蓄熱方式のものに大別される。潜熱蓄熱方式の蓄熱
槽には、水を凍らせてその氷の潜熱で蓄熱するものや、
水にフロンを充填してこれらをよく攪拌して混合するこ
とによってシャーベット状の所謂クラスレートを生成し
そのクラスレートの潜熱で蓄熱するものとがあり、顕熱
蓄熱方式の蓄熱槽には、水を例えば１０℃から５℃に冷
したり、４０℃から５０℃の温水にして蓄熱するものが
ある。2. Description of the Related Art Heat is stored using inexpensive nighttime electricity,
Various heat recovery systems have been considered in order to recover exhaust heat and reuse it, or to store heat for emergency backup of heat. The heat storage tank plays a major role as a means for storing the heat recovered by such a heat recovery system. This heat storage tank is roughly classified into a latent heat storage type and a sensible heat storage type. In the latent heat storage type heat storage tank, one that freezes water and stores heat with the latent heat of the ice,
There is one that fills water with CFCs and mixes them by stirring well and generates so-called clathrate so-called clathrate and stores heat with latent heat of the clathrate. For example, there is one that cools to 10 ° C. to 5 ° C. or makes warm water at 40 ° C. to 50 ° C. to store heat.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、上記の
各蓄熱槽には、それぞれ有利な点もあるが欠点も多い。
例えば氷による潜熱蓄熱方式の蓄熱槽では、高密度で蓄
熱できるが、普通の水を使って氷にするためには０℃以
下の低温度にしなければならないため、冷やすための熱
源機としてのヒートポンプの効率が低くなるという問題
がある。また、クラスレートによる潜熱蓄熱方式の蓄熱
槽では、５〜８℃程度の比較的高温、高密度の蓄熱が可
能であるため、蓄熱のためのスペースを少なくすること
ができ、熱源機の運転効率も高めることができるが、フ
ロン回収等に手間がかかるという問題がある。そして、
水による顕熱蓄熱方式の蓄熱槽では、イニシャルコスト
を安くすることができるが、水の腐食に対するメンテナ
ンス、取替えの手間が問題になると共に蓄熱密度が小さ
い等の問題がある。However, each of the heat storage tanks described above has some advantages but many drawbacks.
For example, a latent heat storage type heat storage tank using ice can store heat at a high density, but since it must be kept at a low temperature of 0 ° C or lower in order to use ordinary water to make ice, a heat pump as a heat source device for cooling There is a problem that the efficiency of is low. Further, in the latent heat storage type heat storage tank based on the clathrate, since it is possible to store heat at a relatively high temperature of about 5 to 8 ° C. and high density, it is possible to reduce the space for heat storage and to improve the operating efficiency of the heat source device. However, there is a problem that it takes time to collect CFCs. And
Although the initial cost can be reduced in the sensible heat storage type heat storage tank using water, there are problems such as maintenance and replacement work against water corrosion and a small heat storage density.
【０００４】本発明は、上記の課題を解決するものであ
って、高温度、高密度での蓄熱が可能でありメンテナン
スが容易なハイブリッド蓄熱槽を提供することを目的と
するものである。The present invention has been made to solve the above problems, and an object of the present invention is to provide a hybrid heat storage tank which can store heat at high temperature and high density and is easy to maintain.
【０００５】[0005]
【課題を解決するための手段】そのために本発明は、伝
熱流体を介して蓄熱するハイブリッド蓄熱槽であって、
空気と水と高温高密度の蓄熱媒体を充填封入したゴム球
体を潜熱蓄熱体として水槽に入れると共に、水槽内に攪
拌手段を設けたことを特徴とするものであり、さらに、
蓄熱媒体としてフロンを用い、伝熱流体の水とゴム球体
との容積比を１対１にしたことを特徴とするものであ
る。To this end, the present invention provides a hybrid heat storage tank for storing heat via a heat transfer fluid,
A rubber sphere filled with air and water and a high-temperature and high-density heat storage medium is enclosed in a water tank as a latent heat storage body, and a stirring means is provided in the water tank.
It is characterized in that chlorofluorocarbon is used as the heat storage medium and the volume ratio of the heat transfer fluid, water, and the rubber spheres is set to 1: 1.
【０００６】[0006]
【作用】本発明のハイブリッド蓄熱槽では、空気と水と
高温高密度の蓄熱媒体を充填封入したゴム球体を潜熱蓄
熱体として水槽に入れると共に、水槽内に攪拌手段を設
けたので、高温度でのゴム球体による潜熱蓄熱を利用す
ると共に水による顕熱蓄熱も併用することができ、しか
もクラスレートを密封するので、メンテナンスやフロン
の回収が容易になる。In the hybrid heat storage tank of the present invention, since rubber spheres filled with air and water and a high-temperature and high-density heat storage medium are enclosed as a latent heat storage body in the water tank and a stirring means is provided in the water tank, the temperature is kept high. The latent heat storage by the rubber sphere can be used together with the sensible heat storage by water, and since the clathrate is sealed, the maintenance and the recovery of CFCs are facilitated.
【０００７】[0007]
【実施例】以下、本発明の実施例を図面を参照しつつ説
明する。図１は本発明に係るハイブリッド蓄熱槽の１実
施例を示す図であり、１は水槽、２は給水パイプ、３は
送水パイプ、４は送水ポンプ、５はゴム球体、６は攪拌
機、１１は球状ゴム、１２は空気、１３は水、１４はフ
ロンを示す。Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a view showing one embodiment of a hybrid heat storage tank according to the present invention, 1 is a water tank, 2 is a water supply pipe, 3 is a water supply pipe, 4 is a water supply pump, 5 is a rubber ball, 6 is an agitator, and 11 is Spherical rubber, 12 is air, 13 is water, and 14 is CFC.
【０００８】図１（ａ）において、水槽１は、ゴム球体
５と水を１対１で収納し、伝熱流体としての水を給水パ
イプ２から導入して送水パイプ３から送水ポンプ４によ
り送り出すものである。ゴム球体５は、その１つ１つが
ミニクラスレート蓄熱槽を構成するものであり、中に空
気と水と高温高密度の蓄熱媒体を充填封入したものであ
る。また、水槽１の中には、水とゴム球体５とをよく攪
拌して熱交換を効率よく行うようにするために攪拌機６
を設けている。攪拌機６には、水中ポンプや攪拌羽根を
使うことができる。このように本発明に係るハイブリッ
ド蓄熱槽は、水蓄熱槽とクラスレート蓄熱槽とを組み合
わせたシステムを構成したものであり、攪拌機６で水槽
１の中の攪拌と柔らかいゴム球体５の中の攪拌を行って
いる。In FIG. 1 (a), a water tank 1 stores a rubber sphere 5 and water in a one-to-one correspondence, introduces water as a heat transfer fluid from a water supply pipe 2 and sends it out from a water supply pipe 3 by a water supply pump 4. It is a thing. Each of the rubber spheres 5 constitutes a mini clathrate heat storage tank, and is filled with air, water and a high temperature and high density heat storage medium. In addition, in the water tank 1, a stirrer 6 is provided in order to stir the water and the rubber spheres 5 well to efficiently perform heat exchange.
Is provided. A submersible pump or a stirring blade can be used for the stirrer 6. As described above, the hybrid heat storage tank according to the present invention constitutes a system in which a water heat storage tank and a clathrate heat storage tank are combined, and the stirring in the water tank 1 and the stirring in the soft rubber sphere 5 are performed by the stirrer 6. It is carried out.
【０００９】ゴム球体５は、図１（ｂ）に示すように密
閉した球状ゴム１１の中に空気１２と水１３と共に蓄熱
媒体として例えばフロン１４を充填封入したものであ
る。球状ゴム１１は、ゴムや合成樹脂その他の所謂ゴム
状の柔らかい弾性体であればよく、さらに熱伝導率の高
いものを混入したものでもよい。このように柔らかいゴ
ム球体５とすると、攪拌機６により攪拌されたとき、ゴ
ム球体５が相互に衝突して変形するので、空気１２と水
１３とフロン１４がよくシェイクされて空気１２と水１
３とフロン１４を混合したシャーベット状のクラスレー
トの反応が促進され、ゴム球体５での高温、高密度の蓄
熱が可能になる。As shown in FIG. 1 (b), the rubber sphere 5 is a hermetically sealed spherical rubber 11 in which air 12 and water 13 are filled and filled with, for example, Freon 14 as a heat storage medium. The spherical rubber 11 may be made of rubber, synthetic resin or other so-called rubber-like soft elastic body, and may be a mixture of materials having high thermal conductivity. With such a soft rubber sphere 5, when agitated by the agitator 6, the rubber spheres 5 collide with each other and are deformed, so that the air 12, the water 13 and the flon 14 are shaken well and the air 12 and the water 1 are stirred.
The reaction of the sherbet-like clathrate in which 3 and Freon 14 are mixed is promoted, and high-temperature and high-density heat storage in the rubber sphere 5 becomes possible.
【００１０】なお、本発明は、上記の実施例に限定され
るものではなく、種々の変形が可能である。例えば上記
の実施例では、ゴム球体の中に空気、水と共に充填封入
する蓄熱媒体としてフロンを用いたが、他の高温、高密
度蓄熱が可能な物質を用いてもよい。また、ゴム球体と
水との比を１対１にしたが、ゴム球体の割合をさらに大
きくしてもよいし、小さくしてもよい。The present invention is not limited to the above embodiment, but various modifications can be made. For example, in the above-mentioned embodiment, chlorofluorocarbon was used as a heat storage medium to be filled and sealed together with air and water in the rubber sphere, but another substance capable of storing high temperature and high density heat may be used. Although the ratio of the rubber spheres to water is set to 1: 1, the ratio of the rubber spheres may be further increased or decreased.
【００１１】[0011]
【発明の効果】以上の説明から明らかなように、本発明
によれば、空気と水とフロンを充填封入したゴム球体を
潜熱蓄熱体として水槽に入れると共に、水槽内に攪拌手
段を設けたので、クラスレートの潜熱蓄熱の利用が可能
になり、高温度の蓄熱が可能になる。しかも、クラスレ
ートは、ゴム球体の中に密封するので、メンテナンスや
回収も容易になり、また、水の量をゴム球体と半々にす
ることにより、水のメンテナンスや取替えの手間も軽減
することができる。As is apparent from the above description, according to the present invention, a rubber sphere filled with air, water and chlorofluorocarbon is put in a water tank as a latent heat storage body and a stirring means is provided in the water tank. , Clathrate latent heat storage can be used, and high temperature heat storage becomes possible. Moreover, since the clathrate is sealed in the rubber sphere, maintenance and recovery are easy, and the amount of water is half that of the rubber sphere, which reduces the maintenance and replacement of water. it can.
【図１】 本発明に係るハイブリッド蓄熱槽の１実施例
を示す図である。FIG. 1 is a diagram showing one embodiment of a hybrid heat storage tank according to the present invention.
１…水槽、２…給水パイプ、３…送水パイプ、４…送水
ポンプ、５…ゴム球体、６…攪拌機、１１…球状ゴム、
１２…空気、１３…水、１４…フロンDESCRIPTION OF SYMBOLS 1 ... Water tank, 2 ... Water supply pipe, 3 ... Water supply pipe, 4 ... Water supply pump, 5 ... Rubber sphere, 6 ... Stirrer, 11 ... Spherical rubber,
12 ... Air, 13 ... Water, 14 ... Freon
Claims (3)
蓄熱槽であって、空気と水と高温高密度の蓄熱媒体を充
填封入したゴム球体を潜熱蓄熱体として水槽に入れると
共に、水槽内に攪拌手段を設けたことを特徴とするハイ
ブリッド蓄熱槽。1. A hybrid heat storage tank for storing heat via a heat transfer fluid, wherein a rubber sphere filled with air, water and a high temperature and high density heat storage medium is charged as a latent heat storage body into the water tank and agitated in the water tank. A hybrid heat storage tank characterized by having means.
徴とする請求項１記載のハイブリッド蓄熱槽。2. The hybrid heat storage tank according to claim 1, wherein chlorofluorocarbon is used as the heat storage medium.
対１にしたことを特徴とする請求項１記載のハイブリッ
ド蓄熱槽。3. The volume ratio of the heat transfer fluid water to the rubber sphere is 1
The hybrid heat storage tank according to claim 1, wherein the hybrid heat storage tank is a pair 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5316403A JPH07167575A (en) | 1993-12-16 | 1993-12-16 | Hybrid thermal storage tank |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5316403A JPH07167575A (en) | 1993-12-16 | 1993-12-16 | Hybrid thermal storage tank |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07167575A true JPH07167575A (en) | 1995-07-04 |
Family
ID=18076691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5316403A Pending JPH07167575A (en) | 1993-12-16 | 1993-12-16 | Hybrid thermal storage tank |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07167575A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2239159A1 (en) * | 2009-04-09 | 2010-10-13 | Kabushiki Kaisha Toyota Jidoshokki | Thermal storage unit and vehicle air conditioner |
| CN108088297A (en) * | 2017-11-06 | 2018-05-29 | 上海交通大学 | A kind of assembly type subregion modularization phase-change heat storage device and its preparation |
-
1993
- 1993-12-16 JP JP5316403A patent/JPH07167575A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2239159A1 (en) * | 2009-04-09 | 2010-10-13 | Kabushiki Kaisha Toyota Jidoshokki | Thermal storage unit and vehicle air conditioner |
| CN108088297A (en) * | 2017-11-06 | 2018-05-29 | 上海交通大学 | A kind of assembly type subregion modularization phase-change heat storage device and its preparation |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1235046B1 (en) | Thermal storage material using hydrate and thermal storage device therefor, and production method of the thermal storage material | |
| JP2006219557A (en) | Heat storage material composition, heat storage body using the same and heat storage apparatus | |
| US5140824A (en) | Gas hydrate thermal energy storage system | |
| Isobe et al. | Formation of gas hydrate or ice by direct-contact evaporation of CFC alternatives | |
| CN102307965A (en) | Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids | |
| JPH11264681A (en) | Cold storage method and system employing inclusion hydrate and cold storage agent | |
| JPH09291272A (en) | Heat accumulating material | |
| US4986079A (en) | Apparatus and method of generating coldness | |
| Li et al. | Cold thermal energy storage materials and applications toward sustainability | |
| US5778685A (en) | Clathrate forming medium and its use in thermal energy storage systems and processes for thermal energy storage and transfer | |
| JPH07167575A (en) | Hybrid thermal storage tank | |
| JP4830572B2 (en) | Latent heat storage material | |
| JP2000205775A (en) | Manufacture of clathrate hydrate slurry | |
| JP2007285627A (en) | Solidification/fusion promotion method of thermal storage material and thermal storage device | |
| JPH10122607A (en) | On-ground air conditioning system for airplane | |
| JPH037834A (en) | Cold heat accumulator system | |
| WO1993004139A1 (en) | Improved thermal energy storage system and process for thermal energy storage and transfer | |
| JPH09324960A (en) | Heat generating or heat absorbing method and apparatus using hydrogen storing alloy | |
| JP2623006B2 (en) | Refrigeration equipment using hydrogen storage alloy | |
| JPS63202687A (en) | Thermal energy storage agent and method for storing thermal energy | |
| JPH11325769A (en) | Heat storage type heat exchanger | |
| JP2000111285A (en) | Method and device for producing inclusion hydrate slurry | |
| JPS60196580A (en) | Cryogenic warehouse | |
| JPH0525471A (en) | Heat storage medium | |
| JP2832563B2 (en) | How to use engine vibration |