JPH07145032A - Cosmetic - Google Patents

Cosmetic

Info

Publication number
JPH07145032A
JPH07145032A JP4327432A JP32743292A JPH07145032A JP H07145032 A JPH07145032 A JP H07145032A JP 4327432 A JP4327432 A JP 4327432A JP 32743292 A JP32743292 A JP 32743292A JP H07145032 A JPH07145032 A JP H07145032A
Authority
JP
Japan
Prior art keywords
skin
cosmetic
effect
improving
components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4327432A
Other languages
Japanese (ja)
Other versions
JP3170699B2 (en
Inventor
Akiyoshi Ryu
明美 笠
Masami Igarashi
正美 五十嵐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kose Corp
Original Assignee
Kose Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kose Corp filed Critical Kose Corp
Priority to JP32743292A priority Critical patent/JP3170699B2/en
Publication of JPH07145032A publication Critical patent/JPH07145032A/en
Application granted granted Critical
Publication of JP3170699B2 publication Critical patent/JP3170699B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To prepare a cosmetic having excellently improving effect on chapped skin, effective for preventing and improving occurrence of darkening of skin, having extremely excellent beautifying effect on skin. CONSTITUTION:This cosmetic contains a perilla oil and one or more compounds selected from OUGON (root of Scutellaria baicalensis), OUBAKU (bark of Phellodendron amurense), lily, TOUKI (root of Angelica acutiloba) and Chinese milk vetch.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、化粧料に関し、更に詳
細には、優れた肌荒れ改善作用を有する化粧料に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic composition, and more particularly to a cosmetic composition having an excellent effect of improving rough skin.

【0002】[0002]

【従来の技術】従来、肌荒れ改善のために用いられてき
た薬効成分としては、アラントイン、アロエ抽出物、人
参抽出物、胎盤抽出物、牛血液除蛋白物、発酵代謝物等
が知られている。しかしながら、これらの薬剤成分を含
む化粧料では、十分な効果を得ることができず、より優
れた作用を有する化粧料の開発が望まれていた。
2. Description of the Related Art Allantoin, aloe extract, ginseng extract, placenta extract, bovine blood deproteinization product, fermented metabolites, etc. are known as medicinal components conventionally used for improving rough skin. . However, cosmetics containing these drug components cannot obtain sufficient effects, and development of cosmetics having more excellent action has been desired.

【0003】一方、エゴマ油は、ω−3系高度不飽和脂
肪酸の一種であるα−リノレン酸を高度に含有してお
り、肌に塗布した場合、潤いを与え、肌のかさつきを防
ぐ効果が知られている。また、このα−リノレン酸は、
体内においてエイコサペンタエン酸やドコサヘキサエン
酸に代謝される。これらのω−3系高度不飽和脂肪酸
は、現在、制ガン効果やアレルギー反応をおこすロイコ
トリエンの産生を減少させる効果があることがわかり、
注目を集めている。
On the other hand, perilla oil contains a large amount of α-linolenic acid which is a kind of ω-3 polyunsaturated fatty acid, and when applied to the skin, moisturizes and prevents the skin from becoming bulky. Are known. Also, this α-linolenic acid is
It is metabolized in the body to eicosapentaenoic acid and docosahexaenoic acid. These ω-3 polyunsaturated fatty acids are currently found to have an anti-cancer effect and an effect of reducing the production of leukotrienes that cause allergic reactions,
It is getting attention.

【0004】[0004]

【発明が解決しようとする課題】本発明者らは、エゴマ
油の有する上記作用に着目し、これを化粧料、特に肌荒
れ改善作用を有する化粧料に配合することを試みた。し
かし、エゴマ油を単独に配合した場合の肌荒れ改善作用
は十分なものとはいえず、また他の基剤等の影響によ
り、これの本来有する効果が十分に発揮され得ないのが
実情であった。
DISCLOSURE OF THE INVENTION The present inventors have focused on the above-mentioned action of sesame oil and attempted to add it to a cosmetic, particularly a cosmetic having a rough skin improving action. However, when the sesame oil is blended alone, the rough skin improving effect cannot be said to be sufficient, and due to the influence of other bases etc., the actual effect of this cannot be sufficiently exerted. It was

【0005】更に、より高い効果を得る目的で、エゴマ
油を高濃度で配合した場合の作用効果にも限界があり、
逆に、これら化合物自体の有する特有の色や臭いの発生
により、配合量や剤型等製品面における制限も生じてく
るといった問題もあった。
Further, there is a limit to the action and effect when the perilla oil is blended at a high concentration for the purpose of obtaining a higher effect.
On the contrary, there is also a problem that due to the generation of the unique color and odor of these compounds themselves, there are restrictions on the amount of formulation, formulation, etc. in terms of products.

【0006】[0006]

【課題を解決するための手段】前記実情に鑑み、本発明
者等は、エゴマ油の有する作用を十分に引き出すべく鋭
意研究を行った。そしてその結果、これらと特定の化合
物とを組合せることにより、優れた肌荒れ改善効果が安
定且つ相乗的に発揮されることを見出し本発明を完成し
た。
In view of the above circumstances, the inventors of the present invention have conducted earnest studies to sufficiently bring out the action of perilla oil. As a result, they have found that by combining these with a specific compound, an excellent effect of improving rough skin can be stably and synergistically achieved, and the present invention has been completed.

【0007】すなわち、本発明は、エゴマ油と、オウゴ
ン、オウバク、ユリ、トウキ及びレンゲソウから選ばれ
る一種または二種以上の植物の抽出物とを含有する化粧
料を提供するものである。
[0007] That is, the present invention provides a cosmetic containing sesame oil and an extract of one or more kinds of plants selected from sorghum, psyllium, lily, toki and astragalus.

【0008】エゴマ油は、シソ科に属するエゴマの果実
より通常用いられる方法により分離、精製されたもので
あり、方法は特に限定されない。また、主成分であるα
−リノレン酸を更に濃縮して含量を高めたものや、ある
いはこれらの他の成分を調合した油脂組成物も含まれ
る。
The perilla oil is isolated and purified from the fruits of perilla belonging to the Lamiaceae family by a commonly used method, and the method is not particularly limited. Also, the main component α
-Included are those in which linolenic acid is further concentrated to increase its content, or oil and fat compositions prepared by mixing these other components.

【0009】エゴマ油は、そのまま本発明の化粧料に配
合しても、また、更に水蒸気蒸留、活性炭処理、酸性白
土処理等によって精製したものを利用しても良い。
The perilla oil may be blended with the cosmetic of the present invention as it is, or may be refined by steam distillation, activated carbon treatment, acid clay treatment, or the like.

【0010】本発明の化粧料におけるエゴマ油の含有量
は、0.0001〜10重量%(以下単に「%」で示
す)であり、より好ましくは、0.01〜5%である。
含有量が0.0001%未満であると十分な効果が得ら
れないことがあり、また、10%を超えて配合してもそ
れ以上の効果の増大は見られず、かえって着色、臭いの
発生や、剤型によっては沈殿が生じる等、製品面での問
題が生じる場合がある。
The content of perilla oil in the cosmetic of the present invention is 0.0001 to 10% by weight (hereinafter simply referred to as "%"), and more preferably 0.01 to 5%.
If the content is less than 0.0001%, a sufficient effect may not be obtained, and even if the content exceeds 10%, no further increase in the effect is observed, and instead, coloring and odor are generated. Also, depending on the dosage form, problems such as precipitation may occur on the product side.

【0011】一方、本発明において他の必須成分である
オウゴン、オウバク、ユリ、トウキ及びレンゲソウなど
の植物の抽出物(以下、「植物抽出物」という)は、い
ずれも天然由来であり、従来から化粧料に配合されてい
る成分である。
On the other hand, in the present invention, the other essential components such as extracts of plants such as sorghum, saccharum, lily, Japanese tallow and astragalus (hereinafter referred to as "plant extract") are all of natural origin and have been conventionally used. It is an ingredient blended in cosmetics.

【0012】これらの植物抽出物を得るための抽出方法
は、精製処理方法について特に制約はなく、常法に従い
得ることができる。例えば、抽出溶媒として水;メチル
アルコール、エチルアルコール等の1級アルコール;プ
ロピレングリコール、1,3−ブチレングリコール等の
液状多価アルコール;酢酸エチルエステル等の低級アル
キルエステル;ベンゼン、ヘキサン等の炭化水素;エチ
ルエーテル、アセトン等の公知の溶媒を用いる方法が採
用され、これら溶媒は1種または2種以上を組合わせて
使用することができる。就中、好ましい抽出溶媒として
は、水と混和する有機溶媒の水溶液、特にエチルアルコ
ール、メチルアルコール、アセトン等が挙げられる。
The extraction method for obtaining these plant extracts is not particularly limited in the purification treatment method, and can be obtained according to a conventional method. For example, water as an extraction solvent; primary alcohols such as methyl alcohol and ethyl alcohol; liquid polyhydric alcohols such as propylene glycol and 1,3-butylene glycol; lower alkyl esters such as acetic acid ethyl ester; hydrocarbons such as benzene and hexane. A method using a known solvent such as ethyl ether or acetone is adopted, and these solvents can be used alone or in combination of two or more kinds. Among them, preferred extraction solvents include aqueous solutions of water-miscible organic solvents, particularly ethyl alcohol, methyl alcohol, acetone and the like.

【0013】これら植物抽出物の本発明化粧料中の含有
量は、一般には0.0001〜5%、好ましくは0.0
01〜3%である。植物抽出物の含有量が0.0001
%より少ない場合は、十分な効果が得られるないことが
あり、また、5%を超えて配合しても効果がほぼ一定と
なり、その増大は見られない。
The content of these plant extracts in the cosmetic of the present invention is generally 0.0001 to 5%, preferably 0.0
It is 01 to 3%. The content of plant extract is 0.0001
If it is less than 5%, a sufficient effect may not be obtained, and even if it exceeds 5%, the effect is almost constant and its increase is not observed.

【0014】更に、本発明の化粧料には、本発明の効果
を損なわない範囲で、前記必須成分の他に、通常の化粧
料に用いられる水性成分、粉体、界面活性剤、油剤、保
湿剤、アルコール類、pH調整剤、防腐剤、色素、酸化
防止剤、紫外線吸収剤、増粘剤、香料、美容成分等を必
要に応じて適宜配合することができる。
Further, in the cosmetic of the present invention, in addition to the above-mentioned essential components, an aqueous component, a powder, a surfactant, an oil, a moisturizing agent which are used in ordinary cosmetics, in the range not impairing the effects of the present invention. Agents, alcohols, pH adjusters, antiseptics, pigments, antioxidants, ultraviolet absorbers, thickeners, fragrances, cosmetic ingredients and the like can be appropriately added as necessary.

【0015】本発明の化粧料は、必須成分である前述の
エゴマ油と、植物抽出物とを配合し、常法に従って製造
することができ、乳液、クリーム、化粧水、美容液、ク
レンジング、パック、洗浄料、ファンデーション等とし
て適用することができる。
The cosmetic composition of the present invention can be produced in a conventional manner by mixing the above-mentioned sesame oil, which is an essential component, and a plant extract, and can be produced according to a conventional method, such as emulsion, cream, lotion, beauty essence, cleansing, pack. It can be applied as a cleaning agent, foundation, etc.

【0016】[0016]

【実施例】次に実施例を挙げて本発明を更に詳細に説明
するが、本発明はこれらに限定されるものではない。
The present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

【0017】実施例1〜2 乳液 表1に示す組成及び下記方法で乳液を調製し、下記試験
方法でその肌荒れ改善作用を評価した。
Examples 1 and 2 Emulsions The compositions shown in Table 1 and the following methods were used to prepare emulsions, and their rough skin improving effects were evaluated by the following test methods.

【0018】[0018]

【表1】 [Table 1]

【0019】(製法) A.成分(6)、(8)〜(10)及び(14)を加熱
混合し、70℃に保つ。 B.成分(1)〜(5)、(7)及び(11)〜(1
2)を加熱混合し、70℃に保つ。 C.上記Bを先のAに加えて混合し、(13)を加えて
均一に乳化し、30℃まで冷却して乳液を得る。
(Production Method) A. The components (6), (8) to (10) and (14) are mixed by heating and kept at 70 ° C. B. Components (1) to (5), (7) and (11) to (1
2) is mixed by heating and kept at 70 ° C. C. The above B is added to the above A and mixed, (13) is added to uniformly emulsify, and the emulsion is obtained by cooling to 30 ° C.

【0020】(試験方法)23〜30才の女性30名を
パネルとし、スキーに行く前日の肌状態をミクロスコー
プカメラで観察し、下記基準によりそのスコアを認め
た。スキーから帰って1日たった後にも同様に肌状態の
スコアを求めた。更にその後は、7日間にわたって毎
日、朝と夜の2回洗顔後に被験乳液を塗布した。そし
て、スキーの3、5及び7日後に前記と同様肌状態のス
コアを求めた。その結果を表2に示す。
(Test Method) Thirty women aged 23 to 30 were used as a panel, and the skin condition of the day before skiing was observed with a microscope camera, and the score was recognized according to the following criteria. The skin condition score was also obtained one day after returning from skiing. After that, the test milky lotion was applied after washing the face twice in the morning and at night every day for 7 days. Then, after 3, 5 and 7 days of skiing, the skin condition score was obtained in the same manner as above. The results are shown in Table 2.

【0021】 (肌状態スコア) スコア 肌状態 1 肌の皮溝が不鮮明であり、角質のはがれが認められる。 2 肌の皮溝がやや不鮮明であるかまたは一方向性が強い。 3 肌の皮溝は認められるが、浅いかまたは一方向性が強い。 4 肌の皮溝が認められるかまたはやや網目状である。 5 肌の皮溝がはっきり認められるかまたはきれいな網目状である。(Skin Condition Score) Score Skin Condition 1 The skin groove of the skin is unclear and peeling of the keratin is observed. 2 The skin groove on the skin is slightly blurred or unidirectional. 3 Skin groove is recognized, but shallow or unidirectional. 4 Skin crevices are observed or are slightly mesh-like. 5 Skin groove is clearly visible or has a clean mesh.

【0022】[0022]

【表2】 [Table 2]

【0023】表2の結果から明らかな如く、エゴマ油と
オウゴン抽出物を組合せた実施例1及びエゴマ油とユリ
抽出物を組合せた実施例2は、それぞれを単独で配合し
た比較例1〜3及びこれらを含まない比較例4に比べ、
顕著な肌荒れ改善効果を示すものであった。
As is clear from the results shown in Table 2, Example 1 in which the sesame oil and the Scutellariae extract were combined and Example 2 in which the sesame oil and the lily extract were combined were Comparative Examples 1 to 3 in which they were individually blended. And compared to Comparative Example 4 not containing these,
It showed a remarkable skin roughening improving effect.

【0024】実施例3〜4 クリーム 表3に示す組成及び下記製法でクリームを調製し、下記
試験方法でその美肌効果を評価した。
Examples 3 to 4 Cream Creams were prepared according to the composition shown in Table 3 and the following production method, and the skin beautifying effect was evaluated by the following test methods.

【0025】[0025]

【表3】 [Table 3]

【0026】(製法) A.成分(1)〜(8)、(11)及び(12)を混合
し、加熱して70℃に保つ。 B.成分(9)〜(10)及び(13)を混合し、加熱
して70℃に保つ。 C.上記AにBを加え、混合した後、冷却してクリーム
を得る。
(Production Method) A. Components (1)-(8), (11) and (12) are mixed and heated to maintain 70 ° C. B. Ingredients (9)-(10) and (13) are mixed and heated to maintain 70 ° C. C. B is added to A above, mixed and cooled to obtain a cream.

【0027】(試験方法)26〜52才の女性15名を
パネルとし、毎日朝と夜の2回、12週間にわたって洗
顔後に被験クリームの適量を顔面に塗布した。塗布によ
る美肌効果を下の基準によって評価した。その結果を表
4に示す。
(Test method) Fifteen women aged 26 to 52 were used as a panel, and an appropriate amount of the test cream was applied to the face after washing the face twice a day every morning and night for 12 weeks. The skin beautifying effect by application was evaluated according to the following criteria. The results are shown in Table 4.

【0028】 (美肌効果) 評価 内容 有効 肌のくすみが見立たなくなった。 やや有効 肌のくすみがあまり目立たなくなった。 無効 使用前と変化なし(Beautiful Skin Effect) Evaluation Content Effective The dullness of the skin became inconspicuous. Somewhat effective The dullness of the skin became less noticeable. Disabled Before use and unchanged

【0029】[0029]

【表4】 [Table 4]

【0030】表4の結果より明らかな如く、実施例3及
び4のクリームは肌の「くすみ」等の発生の防止、改善
に有効であり、美肌効果が認められた。
As is clear from the results of Table 4, the creams of Examples 3 and 4 were effective in preventing and improving the occurrence of "dullness" on the skin, and the skin-beautifying effect was recognized.

【0031】 実施例5 化粧水 (処方) (重量%) (1)グリセリン 5.0 (2)1,3−ブチレングリコール 6.5 (3)ポリオキシエチレンソルビタン 1.2 モノラウリン酸エステル(20E.O.) (4)エチルアルコール 8.0 (5)エゴマ油 0.01 (6)ユリ抽出物 3.0 (7)防腐剤 適量 (8)香料 適量 (9)精製水 残量Example 5 Lotion (Formulation) (% by weight) (1) Glycerin 5.0 (2) 1,3-butylene glycol 6.5 (3) Polyoxyethylene sorbitan 1.2 Monolauric acid ester (20E. O.) (4) Ethyl alcohol 8.0 (5) Perilla oil 0.01 (6) Lily extract 3.0 (7) Preservative proper amount (8) Perfume proper amount (9) Purified water residual amount

【0032】(製法) A.成分(3)〜(5)、(7)及び(8)を混合溶解
する。 B.成分(1)〜(2)、(6)及び(9)を混合溶解
する。 C.上記AとBを混合して均一とし、化粧水を得る。
(Production Method) A. Components (3) to (5), (7) and (8) are mixed and dissolved. B. Components (1) to (2), (6) and (9) are mixed and dissolved. C. The above A and B are mixed to make uniform and a lotion is obtained.

【0033】 実施例6 パック (処方) (重量%) (1)ポリビニルアルコール 20.0 (2)グリセリン 5.0 (3)カオリン 6.0 (4)トウキ抽出物 0.01 (5)エチルアルコール 20.0 (6)エゴマ油 0.05 (7)防腐剤 適量 (8)香料 適量 (9)精製水 残量Example 6 Pack (formulation) (% by weight) (1) Polyvinyl alcohol 20.0 (2) Glycerin 5.0 (3) Kaolin 6.0 (4) Touki extract 0.01 (5) Ethyl alcohol 20.0 (6) Perilla oil 0.05 (7) Preservative Suitable amount (8) Perfume Suitable amount (9) Purified water Remaining amount

【0034】(製法) A.成分(1)〜(4)及び(9)を混合し、70℃に
加熱して攪拌する。 B.成分(5)〜(8)を混合する。 C.上記Bを先のAに加え混合した後、冷却してパック
を得る。
(Production Method) A. The components (1) to (4) and (9) are mixed, heated to 70 ° C. and stirred. B. Mix components (5)-(8). C. The above B is added to the above A, mixed and cooled to obtain a pack.

【0035】 実施例7 洗浄料 (処方) (重量%) (1)ステアリン酸 10.0 (2)パルミチン酸 8.0 (3)ミリスチン酸 12.0 (4)ラウリン酸 4.0 (5)オレイルアルコール 1.5 (6)精製ラノリン 1.0 (7)香料 適量 (8)防腐剤 適量 (9)グリセリン 18.0 (10)水酸化カリウム 6.0 (11)エゴマ油 0.5 (12)レンゲソウ抽出物(注6) 0.05 (13)精製水 残量 (注6)50%1,3−ブチレングリコール、2%エチ
ルアルコール混液による抽出液(乾燥固型分として約3
%含有するもの)
Example 7 Cleaning Agent (Formulation) (% by Weight) (1) Stearic Acid 10.0 (2) Palmitic Acid 8.0 (3) Myristic Acid 12.0 (4) Lauric Acid 4.0 (5) Oleyl alcohol 1.5 (6) Purified lanolin 1.0 (7) Perfume proper amount (8) Preservative proper amount (9) Glycerin 18.0 (10) Potassium hydroxide 6.0 (11) Perilla oil 0.5 (12) ) Astragalus extract (Note 6) 0.05 (13) Purified water Remaining amount (Note 6) Extraction solution with 50% 1,3-butylene glycol, 2% ethyl alcohol mixture (about 3% as dry solids)
% Contained)

【0036】(製法) A.成分(9)〜(10)及び(13)を混合し、70
℃に加熱する。 B.成分(1)〜(6)、(8)及び(11)を混合
し、70℃に加熱する。 C.上記Bを先のAに加え、暫く70℃に保ち、けん化
反応が終了後、50℃まで冷却し、(7)及び(12)
を加え、冷却して洗浄料を得る。
(Production Method) A. Mixing components (9)-(10) and (13), 70
Heat to ℃. B. Components (1)-(6), (8) and (11) are mixed and heated to 70 ° C. C. The above B was added to the above A, and the temperature was kept at 70 ° C. for a while, and after the saponification reaction was completed, it was cooled to 50 ° C., and (7) and (12)
Is added and cooled to obtain a cleaning agent.

【0037】[0037]

【発明の効果】以上詳述した如く、本発明の化粧料は優
れた肌荒れ改善効果を有すると共に、肌の「くすみ」等
の発生の防止、改善に有効であり、美肌効果が極めて優
れたものである。
As described in detail above, the cosmetic composition of the present invention has an excellent effect of improving rough skin, is effective in preventing and improving the occurrence of "dullness" of the skin, and has an extremely excellent skin-cleaning effect. Is.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 エゴマ油と、オウゴン、オウバク、ユ
リ、トウキ及びレンゲソウから選ばれる一種または二種
以上の植物の抽出物とを含有する化粧料。
1. A cosmetic containing sesame oil and an extract of one or more kinds of plants selected from sorghum, rye, lily, toki and astragalus.
JP32743292A 1992-11-12 1992-11-12 Cosmetics Expired - Lifetime JP3170699B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32743292A JP3170699B2 (en) 1992-11-12 1992-11-12 Cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32743292A JP3170699B2 (en) 1992-11-12 1992-11-12 Cosmetics

Publications (2)

Publication Number Publication Date
JPH07145032A true JPH07145032A (en) 1995-06-06
JP3170699B2 JP3170699B2 (en) 2001-05-28

Family

ID=18199107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32743292A Expired - Lifetime JP3170699B2 (en) 1992-11-12 1992-11-12 Cosmetics

Country Status (1)

Country Link
JP (1) JP3170699B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020061196A (en) * 2001-01-15 2002-07-24 주식회사 코리아나화장품 Cosmetic compositions containing scutellaria extracts
EP1265583A1 (en) * 2000-03-07 2002-12-18 Avon Products, Inc. Method of treating skin conditions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1265583A1 (en) * 2000-03-07 2002-12-18 Avon Products, Inc. Method of treating skin conditions
EP1265583A4 (en) * 2000-03-07 2003-06-11 Avon Prod Inc Method of treating skin conditions
US7736661B1 (en) 2000-03-07 2010-06-15 Avon Products, Inc Method of treating skin conditions
KR20020061196A (en) * 2001-01-15 2002-07-24 주식회사 코리아나화장품 Cosmetic compositions containing scutellaria extracts

Also Published As

Publication number Publication date
JP3170699B2 (en) 2001-05-28

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