JPH07137207A - Water-barrier sheet for civil engineering work - Google Patents

Water-barrier sheet for civil engineering work

Info

Publication number
JPH07137207A
JPH07137207A JP28311293A JP28311293A JPH07137207A JP H07137207 A JPH07137207 A JP H07137207A JP 28311293 A JP28311293 A JP 28311293A JP 28311293 A JP28311293 A JP 28311293A JP H07137207 A JPH07137207 A JP H07137207A
Authority
JP
Japan
Prior art keywords
sheet
water
civil engineering
waterproof layer
engineering work
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28311293A
Other languages
Japanese (ja)
Inventor
Masaru Hayashi
勝 林
Akio Nakao
昭夫 中尾
Shuichi Matsumoto
修一 松本
Mamoru Kamitoku
守 神徳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEOTECS KK
Izumi Cosmo Co Ltd
Toray Industries Inc
Original Assignee
GEOTECS KK
Izumi Cosmo Co Ltd
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GEOTECS KK, Izumi Cosmo Co Ltd, Toray Industries Inc filed Critical GEOTECS KK
Priority to JP28311293A priority Critical patent/JPH07137207A/en
Publication of JPH07137207A publication Critical patent/JPH07137207A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/30Landfill technologies aiming to mitigate methane emissions

Landscapes

  • Laminated Bodies (AREA)
  • Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
  • Revetment (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE:To provide a water barrier sheet for civil engineering work, which makes a highly water-absorbent resin swell with water leaked from the hole when a waterproof layer of a toxic wastes final disposing site or water reser voir, etc., is damaged, and thus prevents a water leakage from generating, and does not require maintenance. CONSTITUTION:The water barrier sheet is a sheet formed object which is laid under a waterproof layer for civil engineering work, and a highly water- absorbent macro-molecular substance is diffused on a sheet formed base material by a ratio of 10-3000g/m<2>, and the highly water-absorbent macro-molecular substance is covered by a cover sheet, or is carried on the sheet formed base material by bonding.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、土木用遮水シートに関
し、更に詳細には有害廃棄物最終処分場や貯水池などの
防水層からの漏れ出た水が地盤内にしみ出すことを防止
する土木用遮水シートに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a waterproof sheet for civil engineering, and more particularly, to prevent water leaking from a waterproof layer such as a hazardous waste final disposal site or a reservoir from leaking into the ground. It relates to a waterproof sheet for civil engineering.

【0002】[0002]

【従来の技術】人体や環境に有害な物質を含む廃棄物を
最終処分するための貯留する手段として、地面に穴を堀
り、ここに廃棄物を収容することが行われていることは
知られている。これらの廃棄物貯留用穴から、廃棄物に
含まれる液体や、前記穴に降った雨水が漏水すると、土
壌汚染、地下水汚染などの環境破壊を起こす原因となる
という問題がある。また灌漑用などの貯水池などから漏
水があると貯水効率が低下するという問題がある。した
がって、これらの穴や池からの漏水を防止する方法とし
て次の各種の方法が従来から行われている。 (1)ゴムや樹脂製の防水シートを池の底部やのり面に
敷設する方法。 (2)前記防水シートの下地材として所定の厚さ、例え
ば1〜5cmの厚さに不織布をクッション材として敷設
し、固い突起物で前記シートが損傷しないよにする方
法。などである。これらの方法は、いずれも漏水したこ
とを早期に検知することが不可能に近いため信頼性に乏
しいという問題がある。そこで、 (3)前記防水シートとクッション材とを積層する方
法。があるが、この(3)の方法はコストが高く、また
メンテナンスに手間が掛かるという問題がある。そこ
で、前記漏水を早期に検知する各手段として次のような
提案がなされている。即ち、 (4)防水シートで形成した袋内に加圧流体と圧力セン
サとを封入し、袋が破れて漏水が始まり袋内の圧力低下
をセンサが検出することにより漏水を早期に発見する特
開平1−25024号公報に記載の方法。 (6)漏水を熱に変換し、この熱を温度センサで検出し
漏水を早期に発見する特開平1−63834号公報に記
載の方法。 (6)防水シートの両側にそれぞれ電極を取り付け常時
電圧を印加しておき、電極間を流れる電流を検知して漏
水を発見する特開平4−134237号公報に記載の方
法。 (7)2枚の防水シートの間にラーメン状繊維を配置
し、シートそれぞれに電極を設け、流れる電流によりシ
ートの漏水箇所を検知し、その部分に外部から樹脂を注
入して止水する方法。 これら(4)〜(7)に示した漏水検知方法は、設備費
が高く、メンテナンスに手間が掛かるなどコスト的に問
題があり、なお改善の必要が認められる。
2. Description of the Related Art It is known that a hole is dug in the ground and the waste is stored in the ground as a storage means for the final disposal of the waste containing a substance harmful to the human body and the environment. Has been. If the liquid contained in the waste or rainwater that has fallen into the hole leaks from these waste storage holes, there is a problem that it may cause environmental damage such as soil pollution or groundwater pollution. In addition, there is a problem that water storage efficiency will decrease if water leaks from reservoirs for irrigation. Therefore, the following various methods have been conventionally performed as methods for preventing water leakage from these holes and ponds. (1) A method of laying a waterproof sheet made of rubber or resin on the bottom or slope of a pond. (2) A method in which a non-woven fabric is laid as a cushioning material with a predetermined thickness, for example, a thickness of 1 to 5 cm as a base material of the waterproof sheet so that the sheet is not damaged by a hard protrusion. And so on. All of these methods have a problem of poor reliability because it is almost impossible to detect water leakage at an early stage. Therefore, (3) a method of laminating the waterproof sheet and the cushion material. However, the method (3) has a problem that the cost is high and maintenance is troublesome. Therefore, the following proposals have been made as means for early detection of the water leakage. That is, (4) a pressurized fluid and a pressure sensor are enclosed in a bag formed of a waterproof sheet, and the sensor detects a pressure drop in the bag when the bag is broken and water leakage starts, so that water leakage can be detected early. The method described in Kaihei 1-225024. (6) The method described in Japanese Patent Application Laid-Open No. 1-63834, which converts leaked water into heat and detects the heat with a temperature sensor to detect the leaked water at an early stage. (6) The method described in JP-A-4-134237, in which electrodes are attached to both sides of the waterproof sheet and a voltage is constantly applied, and a current flowing between the electrodes is detected to detect water leakage. (7) A method of arranging ramen-shaped fibers between two waterproof sheets, providing electrodes on each sheet, detecting a water leakage point of the sheet by flowing current, and injecting resin from the outside into the portion to stop water . The water leak detection methods shown in (4) to (7) have cost problems such as high equipment cost and troublesome maintenance, and further improvement is recognized.

【0003】[0003]

【発明が解決しようとする課題】本発明は、前記問題に
着目してなされたものであり、有害廃棄物最終処分場や
貯水池の防水層が損傷した場合に、その損傷部分から漏
れ出した水で高吸水性樹脂を膨潤させ、漏れ出した水が
地盤内にしみ込むことを防止し、メンテナンス不要の土
木用遮水シートを提供することを目的としている。
SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and when the hazardous waste final disposal site or the waterproof layer of a reservoir is damaged, water leaking from the damaged part is lost. The purpose of the present invention is to provide a water impervious sheet for civil engineering that swells the super absorbent resin and prevents leaked water from seeping into the ground, and does not require maintenance.

【0004】[0004]

【課題を解決するための手段】以上の目的を達成するた
めの本発明の土木用遮水シートの構成は、土木用防水層
の下に敷設するシート状物であって、高吸水性高分子物
質を、10〜3000g/m2 の割合でシート状基材上
に分散配置し、カバーシートで覆うか又は接着により前
記シート状基材に担持させたものである。
[Means for Solving the Problems] A construction of a water-impermeable sheet for civil engineering according to the present invention for achieving the above object is a sheet-like article laid under a waterproof layer for civil engineering, which is a super absorbent polymer. The substance is dispersed and arranged on the sheet-shaped substrate at a rate of 10 to 3000 g / m 2 , and is carried on the sheet-shaped substrate by covering with a cover sheet or adhering.

【0005】前記防水層には特に限定はないが、一般に
は従来から使用される天然又は合成ゴムシート、可撓性
の合成樹脂、例えば塩化ビニール系、不飽和ポリエステ
ル系などの防水シートを使用することができる。前記高
吸水性高分子物質は、高吸水性であり、環境に悪影響を
与えないものであれば特に限定はないが、例えば、セル
ロース・アクリルニトリル重合体、デンプン・アクリル
ニトリル重合体などの天然系のもの、アクリル酸・ビニ
ルアルコール共重合体、アクリル酸ソーダ重合体、アク
リル酸ソーダ・アクリルアミド共重合体、ポリエチレン
オキサイド変成物、イソブチレン・無水マレイン酸共重
合体などの合成系のものがあるが、土中、特に湿潤した
土中で分解しにくい点で合成系のものが好ましい。
The waterproof layer is not particularly limited, but generally a conventionally used natural or synthetic rubber sheet or a flexible synthetic resin, for example, a vinyl chloride-based or unsaturated polyester-based waterproof sheet is used. be able to. The super absorbent polymer is not particularly limited as long as it is super absorbent and does not adversely affect the environment, for example, a natural system such as cellulose / acrylonitrile polymer, starch / acrylonitrile polymer, etc. , Acrylic acid / vinyl alcohol copolymer, sodium acrylate polymer, sodium acrylate / acrylamide copolymer, polyethylene oxide modified product, isobutylene / maleic anhydride copolymer, etc. A synthetic type is preferable because it is difficult to decompose in soil, particularly in moist soil.

【0006】前記シート状基材は、可撓性シートであ
り、輸送、敷設などに要求される強度を有し、土中で変
質しにくいものであれば特に限定はない。好ましいシー
ト状基材としては、繊維を織編した布帛状のもの、不織
布、シート状のスポンジ状物など連通性の多孔質材料で
あり、高吸水性高分子物質が孔内に入り込み安定して担
持できるので好ましい。また、前記不織布は長繊維材料
により形成したものが強度などの点で好ましい。使用し
うる繊維としては、特に限定はないが、好ましい繊維と
してはポリエチレンテレフタレート繊維、ポリプロピレ
ン繊維、木綿、ヤシ繊維などである。
The sheet-shaped base material is a flexible sheet, and is not particularly limited as long as it has strength required for transportation, laying, etc. and is resistant to alteration in soil. Preferred sheet-like base materials are cloth-like materials obtained by woven and knitting fibers, non-woven fabrics, sheet-like sponge-like materials, and the like, and porous materials having a high water-absorbing property can be stably introduced into pores. It is preferable because it can be carried. Further, the non-woven fabric is preferably made of a long fiber material in terms of strength and the like. The fibers that can be used are not particularly limited, but preferred fibers include polyethylene terephthalate fibers, polypropylene fibers, cotton, and palm fibers.

【0007】前記カバーシートは、前記シート状基材と
同じ素材を使用してもよく、その他の合成樹脂フィルム
又はシートを使用することもできる。前記シート状基材
に高吸水性高分子物質を担持させる手段としては、次の
手段によることができる。即ち、 i.シート状基材上に粉状の高吸水性高分子物質を所定
量散布した上にカバーシートを積層し、熱圧着、繊維と
不織布を製造するときに使用するニードルパンチによる
縫合、、キルティング手段などによる縫合、差し込んで
から先端を曲げる金属針による接合手段などの手段によ
り一体とする方法。なお前記熱圧着は、使用する高吸水
性高分子物質が熱融着性物質でない場合には、熱融着物
質を添加したり、熱融着性を有するシート状物を間に積
層するなどの手段により熱圧着させることができる。
The cover sheet may be made of the same material as the sheet-shaped substrate, or may be made of other synthetic resin film or sheet. As a means for supporting the superabsorbent polymer substance on the sheet-shaped substrate, the following means can be used. That is, i. A sheet of base material is sprayed with a certain amount of powdery super absorbent polymer, and a cover sheet is laminated on the base material, followed by thermocompression bonding, stitching with a needle punch used when manufacturing fibers and nonwovens, quilting means, etc. A method in which the elements are integrated by means such as suturing by means of, and a joining means such as a metal needle that bends the tip after inserting. In the thermocompression bonding, when the super absorbent polymer used is not a heat-fusible substance, a heat-fusible substance is added, or a sheet-like material having a heat-fusible property is laminated between them. It can be thermocompression bonded by means.

【0008】ii.複数のシート状基材を積層し、その間
に粉状の高吸水性高分子物質を所定量吹き込み、前記と
同様に一体とすることができる。 iii.高吸水性高分子物質をバインダー樹脂と混合し、
シート状基材の片面又はと両面に塗布する方法。 iv.前記と同様に高吸水性高分子物質をシート状基材に
塗布し、その上にカバーシートを積層する方法。 などの各手段を用いることができる。高吸水性高分子物
質を固体として扱う場合には粉状とするが、この場合の
粉状とは、細かな粒子とした状態を意味し、特に粒子径
に限定はなく、水に触れて容易に膨潤できる程度であれ
ばよく、また粒子径が揃っていなくともよい。
Ii. It is possible to stack a plurality of sheet-shaped base materials and blow a predetermined amount of powdery highly water-absorbent polymer substance into them to integrate them as described above. iii. Super absorbent polymer is mixed with binder resin,
A method of coating on one side or both sides of a sheet-shaped substrate. iv. A method in which a highly water-absorbing polymer substance is applied to a sheet-shaped substrate in the same manner as described above, and a cover sheet is laminated thereon. Each means such as can be used. When the super absorbent polymer is treated as a solid, it is in powder form.In this case, the powder form means a state in which it is made into fine particles, and there is no particular limitation on the particle size, and it is easy to touch water. As long as it can swell, the particle size does not have to be uniform.

【0009】高吸水性高分子物質の使用量は、使用する
高吸水性高分子物質の吸水倍率、吸水膨潤速度、シート
状基材に担持させる方法などで異なるが、10〜300
0g/m2 の割合でシート状基材に担持させる必要があ
り、200〜1500g/m 2 がより好ましい。高吸水
性高分子物質の使用量が10g/m2 以下では本発明の
目的としている遮水効果が発揮されず、また3000g
/m2 を越えると、必要以上にシートの耐水圧性が高く
なり不経済となる。
The amount of super absorbent polymer used depends on
Water absorption capacity, water absorption swelling rate, sheet of super absorbent polymer
It depends on the method of supporting it on the base material.
0 g / m2It is necessary to support the sheet-shaped substrate at a ratio of
200 to 1500 g / m 2Is more preferable. High water absorption
The amount of use of high molecular weight polymer is 10g / m2In the following, the invention
The desired water-blocking effect is not exhibited, and 3000g
/ M2If it exceeds the limit, the water pressure resistance of the sheet will be higher than necessary.
It becomes uneconomical.

【0010】前記土木用遮水シートの敷設法は、従来の
防水シートの敷設方法と同様に行うことができる。なお
遮水シートを敷き詰める場合には、高吸水性物質層に隙
間ができないように遮水シートを重ね合わせることがこ
のましいが、特に互いを必ずしも接着させる必要はな
い。本土木用遮水シートを敷設した上に防水層を設ける
手段には特に限定はなく、従来と同様に行うことができ
る。但し防水層を敷設する際に本土木用遮水シートが損
傷するおそれがある場合には、その間に保護層を設ける
ことがてきる。
The method of laying the water-impermeable sheet for civil engineering can be performed in the same manner as the conventional method of laying a waterproof sheet. When laying the water-impermeable sheets, it is preferable to stack the water-impermeable sheets so that no gap is formed in the superabsorbent layer, but it is not always necessary to bond them together. The means for providing the waterproof layer on the water-proof sheet for civil engineering is not particularly limited and can be performed in the same manner as in the past. However, if there is a risk of damaging the waterproof sheet for main civil engineering when laying the waterproof layer, a protective layer may be provided between them.

【0011】[0011]

【作用】防水層の下に本発明の土木用遮水シートを敷設
すると、何らかの原因で防水層に穴が開いたり亀裂が生
じたりして漏水が始まると、その下に敷設された高吸水
性高分子物質が膨潤し、ゲル化して不透水層を形成する
ことで、強固な遮水作用を発揮し、メンテナンスを不要
にする。
When the water barrier sheet for civil engineering of the present invention is laid under the waterproof layer, if water leakage starts due to holes or cracks in the waterproof layer for some reason, high water absorption laid under it. The polymer substance swells and gels to form a water impermeable layer, thereby exerting a strong water-blocking effect and eliminating the need for maintenance.

【0012】また、前記シート状基材に高吸水性高分子
物質を担持させる前記手段は、高吸水性高分子物質によ
る均一な遮水層を形成するように作用する。また、シー
ト状基材に不織布など多孔質素材を使用した場合には、
クッション性が得られ、防水シートなどの防水層を保護
する作用が得られる。本発明の土木用遮水シートの耐水
圧性は、1.0Kg/cm2 以上が得られ、10m以上
の深さの廃棄物最終処理場や貯水池などの底部の防水層
が損傷しても遮水する性能を発揮することができる。
Further, the means for supporting the highly water-absorbent polymer substance on the sheet-shaped substrate acts so as to form a uniform impermeable layer of the highly water-absorbent polymer substance. Also, when a porous material such as nonwoven fabric is used for the sheet-shaped substrate,
Cushioning property is obtained, and an action of protecting a waterproof layer such as a waterproof sheet is obtained. The water-proof sheet for civil engineering of the present invention has a water pressure resistance of 1.0 kg / cm 2 or more, and even if the waterproof layer at the bottom of a waste final treatment plant or a reservoir at a depth of 10 m or more is damaged, The ability to perform can be demonstrated.

【0013】[0013]

【発明の効果】以上説明した本発明の土木用遮水シート
は、シート状基材に高吸水性高分子物質を担持させ、防
水層の下に敷設するようにしたので、防水層が損傷し、
漏水が生じた場合でも、前記高吸水性高分子物質が漏水
した水などで膨潤してゲル化し、不透水層を形成して強
固な遮水性を発揮し、漏水を防止することができる。し
かも遮水シートのメンテナンスが不要であるので、メン
テナンスが困難な有害廃棄物最終処分場や貯水池などの
防水層からの漏水防止手段として有効に効果的に使用す
ることができる。また、シート状基材に不織布などクッ
ション性のある素材を使用した場合には、その上の防水
層、特に防水シートを損傷から保護する効果が得られ
る。
EFFECTS OF THE INVENTION In the above-described waterproofing sheet for civil engineering of the present invention, the sheet-like base material is made to carry the superabsorbent polymer substance and is laid under the waterproof layer, so that the waterproof layer is damaged. ,
Even when water leakage occurs, the highly water-absorbent polymer substance swells with water or the like and gels to form a water impermeable layer, exhibiting strong water impermeability, and preventing water leakage. Moreover, since the maintenance of the water blocking sheet is unnecessary, it can be effectively and effectively used as a means for preventing water leakage from a waterproof layer such as a hazardous waste final disposal site or a reservoir, which is difficult to maintain. Further, when a cushioning material such as a non-woven fabric is used for the sheet-shaped base material, an effect of protecting the waterproof layer thereon, particularly the waterproof sheet, from damage can be obtained.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 中尾 昭夫 東京都中央区日本橋室町2丁目2番1号 東レ株式会社東京事業場内 (72)発明者 松本 修一 神奈川県鎌倉市大船1993番地の18 (72)発明者 神徳 守 神奈川県横浜市保土ケ谷区星川3丁目2番 7号 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Akio Nakao 2-2-1 Nihombashi Muromachi, Chuo-ku, Tokyo Toray Industries, Inc. Tokyo Plant (72) Inventor Shuichi Matsumoto 18 of 1993, Ofuna, Kamakura, Kanagawa Prefecture (72 ) Inventor Mamoru Shintoku 3-2-7 Hoshikawa, Hodogaya-ku, Yokohama-shi, Kanagawa

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 土木用防水層の下に敷設するシート状物
であって、高吸水性高分子物質を、10〜3000g/
2 の割合でシート状基材上に分散配置し、カバーシー
トで覆うか又は接着により前記シート状基材に担持させ
た土木用遮水シート。
1. A sheet-like material laid under a waterproofing layer for civil engineering, comprising 10 to 3000 g / highly water-absorbing polymeric substance.
A water impervious sheet for civil engineering, which is dispersedly arranged on a sheet-shaped substrate at a ratio of m 2 , and is carried on the sheet-shaped substrate by being covered with a cover sheet or adhered thereto.
【請求項2】 前記シート状基材を繊維材料で構成した
請求項1の土木用遮水シート。
2. The water impervious sheet for civil engineering according to claim 1, wherein the sheet-shaped substrate is made of a fiber material.
【請求項3】 前記シート状基材が不織布からなる請求
項1の土木用遮水シート。
3. The water impervious sheet for civil engineering according to claim 1, wherein the sheet-shaped substrate is made of a non-woven fabric.
【請求項4】 前記不織布が長繊維不織布である請求項
3の土木用遮水シート。
4. The water impervious sheet for civil engineering according to claim 3, wherein the non-woven fabric is a long fiber non-woven fabric.
JP28311293A 1993-11-12 1993-11-12 Water-barrier sheet for civil engineering work Pending JPH07137207A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28311293A JPH07137207A (en) 1993-11-12 1993-11-12 Water-barrier sheet for civil engineering work

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28311293A JPH07137207A (en) 1993-11-12 1993-11-12 Water-barrier sheet for civil engineering work

Publications (1)

Publication Number Publication Date
JPH07137207A true JPH07137207A (en) 1995-05-30

Family

ID=17661385

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28311293A Pending JPH07137207A (en) 1993-11-12 1993-11-12 Water-barrier sheet for civil engineering work

Country Status (1)

Country Link
JP (1) JPH07137207A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002325799A (en) * 2001-05-02 2002-11-12 Nippon Kyushutai Gijutsu Kenkyusho:Kk Water absorptive water resistant sheet, method of fabrication for the same and absorptive product using the same
JP2007160185A (en) * 2005-12-12 2007-06-28 Kureha Ltd Auxiliary sheet for covering with soil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002325799A (en) * 2001-05-02 2002-11-12 Nippon Kyushutai Gijutsu Kenkyusho:Kk Water absorptive water resistant sheet, method of fabrication for the same and absorptive product using the same
JP4556017B2 (en) * 2001-05-02 2010-10-06 株式会社日本吸収体技術研究所 Water-absorbing water-resistant sheet, method for producing the same, and absorbent product using the same
JP2007160185A (en) * 2005-12-12 2007-06-28 Kureha Ltd Auxiliary sheet for covering with soil
JP4630186B2 (en) * 2005-12-12 2011-02-09 呉羽テック株式会社 Auxiliary sheet for soil covering

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