JPH07127791A - Vacuum insulation pipe and manufacture thereof - Google Patents

Vacuum insulation pipe and manufacture thereof

Info

Publication number
JPH07127791A
JPH07127791A JP5276914A JP27691493A JPH07127791A JP H07127791 A JPH07127791 A JP H07127791A JP 5276914 A JP5276914 A JP 5276914A JP 27691493 A JP27691493 A JP 27691493A JP H07127791 A JPH07127791 A JP H07127791A
Authority
JP
Japan
Prior art keywords
inner cylinder
outer cylinder
cylinder
expanded
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP5276914A
Other languages
Japanese (ja)
Inventor
Yoshiaki Shimada
嘉晃 島田
Hanji Ishikawa
半二 石川
Shigeru Morikawa
茂 森川
Takafumi Nakamura
尚文 中村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Nisshin Co Ltd
Original Assignee
Nisshin Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshin Steel Co Ltd filed Critical Nisshin Steel Co Ltd
Priority to JP5276914A priority Critical patent/JPH07127791A/en
Publication of JPH07127791A publication Critical patent/JPH07127791A/en
Withdrawn legal-status Critical Current

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Abstract

PURPOSE:To obtain a vacuum insulation pipe excellent in heat insulation characteristic simply and at a low cost by engaging an inner cylinder with an outer cylinder through a vacuum layer to form a double pipe, expanding the inner cylinder at designated spaces, and directly airtightly joining the inner cylinder to the outer cylinder by the expanded pipe parts to reduce the number of parts. CONSTITUTION:An inner cylinder 10 is fitted in the interior of an outer cylinder 20. The inner cylinder 10 is expanded at parts corresponding to both end parts of the outer cylinder 20. That is, expanded pipe parts 11 having an outside diameter larger than a value obtained by subtracting the wall thickness of the outer cylinder 20 from the inside diameter of the outer cylinder 20 are formed on both end parts of the inner cylinder 10 by a rubber bulging method or the like. After the inner cylinder 10 and the outer cylinder 20 are directly joined to each other and airtightly connected to each other by the expanded pipe parts, the space part 30 between the cylinders is evacuated to a designated degree of vacuum. Thus, the need of the conventional sealing cover or the like can be eliminated, and a welding part and welding manhour can be reduced. Accordingly, the cost of a vacuum insulation pipe and the frequency of occurrence of defect can be decreased, and a product excellent in quality stability can be manufactured at high yield rate.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、地域冷暖房用蒸気配
管,給湯設備用配管,低温流体移送用配管等のように高
温又は低温の流体を輸送するときに使用される真空断熱
管及びその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a vacuum heat insulation pipe used for transporting a high or low temperature fluid, such as a steam pipe for district heating and cooling, a pipe for hot water supply equipment, a pipe for transferring a low temperature fluid and the like, and its manufacture. Regarding the method.

【0002】[0002]

【従来の技術】高温又は低温の流体を輸送する際、配管
内部を流れる流体と雰囲気温度との間に熱勾配が生じ
る。この熱勾配に応じ、高温流体の保有熱が配管から雰
囲気に放散され、或いは低温流体が雰囲気から熱を吸収
し昇温する。その結果、高温流体又は低温流体は、使用
箇所に到達した段階で必要温度から外れることになる。
使用箇所に送られた高温流体又は低温流体を所定温度に
するため、輸送中の熱損失を考慮した温度条件まで高温
流体を加熱、或いは低温流体を冷却する方法が採用され
ている。しかし、不可避の熱損失を補償する過熱又は過
冷却は熱経済的にみて可能な限り小さく設定すべきであ
り、輸送中の熱損失をできるだけ抑制することが好まし
い。
2. Description of the Related Art When a high or low temperature fluid is transported, a thermal gradient occurs between the fluid flowing inside the pipe and the ambient temperature. According to this thermal gradient, the heat of the high temperature fluid is dissipated from the pipe into the atmosphere, or the low temperature fluid absorbs the heat from the atmosphere and rises in temperature. As a result, the high temperature fluid or the low temperature fluid will deviate from the required temperature when it reaches the point of use.
In order to bring the high-temperature fluid or the low-temperature fluid sent to the place of use to a predetermined temperature, a method of heating the high-temperature fluid or cooling the low-temperature fluid to a temperature condition in consideration of heat loss during transportation is adopted. However, overheating or undercooling for compensating for unavoidable heat loss should be set as small as possible in terms of thermo-economics, and it is preferable to suppress heat loss during transportation as much as possible.

【0003】熱損失は、内筒と外筒の間に真空断熱層を
設けた二重管構造の断熱管を使用することにより抑制さ
れる。これらの内筒及び外筒は、種々の方法によって相
互に固定される。たとえば、特開昭61−99795号
公報,特開平3−20190号公報等では、金属製の封
止蓋を使用した溶接又はろう付けによって外筒の端部開
口を気密封止することが開示されている。また、特開平
1−240619号公報では、フレア加工によって内筒
の端部をラッパ状に拡管し、外筒の内面に溶着してい
る。
Heat loss is suppressed by using a heat insulating pipe having a double pipe structure in which a vacuum heat insulating layer is provided between an inner cylinder and an outer cylinder. The inner cylinder and the outer cylinder are fixed to each other by various methods. For example, JP-A-61-99795 and JP-A-3-20190 disclose that the end opening of the outer cylinder is hermetically sealed by welding or brazing using a metal sealing lid. ing. Further, in Japanese Patent Laid-Open No. 1-240619, the end portion of the inner cylinder is expanded into a trumpet shape by flare processing and is welded to the inner surface of the outer cylinder.

【0004】[0004]

【発明が解決しようとする課題】封止蓋を使用して気密
封止するとき、内筒及び外筒の両端開口部、合計4か所
に封止蓋が溶接されるため、溶接工程にかかる工数が多
くなる。また、内筒,外筒及び封止蓋それぞれの部材に
関し繁雑な品質管理が必要になることから、得られた断
熱管は、必然的にコストの高いものとなり、コスト面か
ら使用形態が制約される。内筒端部をラッパ状にフレア
加工する方式も、断熱管の構造が複雑化し易い欠点をも
っている。そのため、工数がかかる製造工程となり、依
然として低コスト化することができない。本発明は、こ
のような問題を解消すべく案出されたものであり、バル
ジ加工等によって形成した拡管部を介して内筒を外筒に
直接溶接することにより、熱収縮時の気密保持性を低下
させることなく、内筒と外筒とが簡単な構造で気密に接
続された真空断熱管を提供することを目的とする。
When airtight sealing is performed using the sealing lid, the sealing lid is welded to the opening portions at both ends of the inner cylinder and the outer cylinder, that is, at a total of four places. Man-hours increase. Further, since complicated quality control is required for each member of the inner cylinder, the outer cylinder and the sealing lid, the heat insulating pipe obtained is inevitably high in cost, and the usage form is restricted in terms of cost. It The method of flaring the end portion of the inner cylinder into a trumpet shape also has a drawback that the structure of the heat insulating pipe tends to be complicated. Therefore, the manufacturing process requires a lot of man-hours, and the cost cannot be reduced yet. The present invention has been devised in order to solve such a problem, and by directly welding the inner cylinder to the outer cylinder via an expanded portion formed by bulging or the like, airtightness at heat shrinkage is maintained. It is an object of the present invention to provide a vacuum heat insulating tube in which an inner cylinder and an outer cylinder are airtightly connected to each other with a simple structure without decreasing the temperature.

【0005】[0005]

【課題を解決するための手段】本発明の真空断熱管は、
その目的を達成するため、内筒及び外筒を真空層を介し
て嵌め合せた二重管構造をもち、所定間隔で前記内筒を
拡管することにより形成した拡管部で前記内筒が前記外
筒に気密に直接接合されていることを特徴とする。本発
明の真空断熱管は、外筒内径から外筒肉厚を引いた寸法
より大きな外径をもつ拡管部が形成されるように内筒を
所定間隔で拡管し、前記拡管部で前記外筒に前記内筒を
気密に固着し、前記内筒と前記外筒との間の空間部を真
空引きすることにより製造される。すなわち、内筒を部
分的に外筒の内径近くまで拡管し、拡管部で外筒に直接
接合することにより、封止蓋等の部品を必要とすること
なく、真空雰囲気に維持される空間部が形成される。
The vacuum heat insulating tube of the present invention comprises:
In order to achieve the object, it has a double pipe structure in which an inner cylinder and an outer cylinder are fitted with each other through a vacuum layer, and the inner cylinder is expanded by a pipe expanding portion formed by expanding the inner cylinder at predetermined intervals. It is characterized in that it is directly airtightly joined to the cylinder. The vacuum heat insulating pipe of the present invention expands the inner cylinder at a predetermined interval so that an expanded pipe portion having an outer diameter larger than a size obtained by subtracting the thickness of the outer cylinder from the outer cylinder inner diameter is formed, and the outer cylinder is expanded by the expanded pipe portion. It is manufactured by air-tightly fixing the inner cylinder to and vacuuming the space between the inner cylinder and the outer cylinder. That is, by partially expanding the inner cylinder to near the inner diameter of the outer cylinder and directly joining the outer cylinder to the outer expansion part, a space part that is maintained in a vacuum atmosphere without requiring parts such as a sealing lid. Is formed.

【0006】本発明に従った真空断熱管は、たとえば図
1に示すように、内筒10を外筒20に嵌め合せてい
る。内筒10は、外筒20の端部に相当する部分で拡管
される。この部分に、外筒内径Dinから外筒肉厚Tを引
いた値Din−Tより大きな外径dout をもつ拡管部11
をゴムバルジ法等により形成する。外筒20には、熱膨
張収縮等を吸収するコルゲート部21を設けることが好
ましい。内筒10と外筒20とを気密接続した後、空間
部30が所定の真空度まで真空引きされる。内筒外径d
out をdout ≧Din−Tの関係に維持するとき、接合部
に欠陥を生じさせることなく溶接により内筒10を外筒
20に気密接合できる。内筒外径dout が値Din−Tよ
り小さいと、溶接が困難になり、良好な気密接続部が得
られない。ただし、外筒20に内筒10を挿入して溶接
することから、拡管部の内筒外径dout は、外筒内径D
inよりも小さいことが必要とされる。
In the vacuum heat insulating tube according to the present invention, the inner cylinder 10 is fitted to the outer cylinder 20 as shown in FIG. 1, for example. The inner cylinder 10 is expanded at a portion corresponding to the end of the outer cylinder 20. In this portion, the pipe expanding portion 11 having an outer diameter d out larger than a value D in -T obtained by subtracting the outer cylinder wall thickness T from the outer cylinder inner diameter D in.
Are formed by a rubber bulge method or the like. The outer cylinder 20 is preferably provided with a corrugated portion 21 that absorbs thermal expansion and contraction. After air-tightly connecting the inner cylinder 10 and the outer cylinder 20, the space 30 is evacuated to a predetermined degree of vacuum. Inner cylinder outer diameter d
When out is maintained in the relationship of d out ≧ D in −T, the inner cylinder 10 can be hermetically joined to the outer cylinder 20 by welding without causing defects in the joint. When the inner cylinder outer diameter d out is smaller than the value D in −T, welding becomes difficult and a good airtight connection cannot be obtained. However, since the inner cylinder 10 is inserted into the outer cylinder 20 and welded, the inner cylinder outer diameter d out of the expanded portion is equal to the outer cylinder inner diameter D.
Required to be less than in .

【0007】拡管部11は、たとえば次の工程で内筒1
0に付けられる。先ず、内筒10として使用される鋼管
素材12を、図2(a)に示すように拡管装置40にセ
ットする。鋼管素材12の拡管しようとする部分を、金
型41,42内に位置させる。鋼管素材12の内部に油
圧Fで駆動されるスライド芯金43を挿入し、スライド
芯金43に固定ナット44を固着する。スライド芯金4
4には、ウレタンゴム等の環状弾性体45が装着されて
いる。環状弾性体45は、一側がスペーサ46を介して
固定ナット44に対向し、他側がストッパー47に対向
している。スライド芯金43を油圧Fによって矢印方向
に牽引するとき、スライド芯金43と一体化されている
固定ナット44も同じ方向に移動し、スペーサ46を介
して環状弾性体45を加圧する。環状弾性体45は、他
側がストッパー47で規制されているため、圧縮され
る。更に油圧Fによってスライド芯金43をスライドさ
せると、環状弾性体45は、鋼管素材12を金型41,
42に押し付けるように変形する。その結果、鋼管素材
12は、図2(b)に示すように金型41,42の凹部
形状に倣った形状に加工され、拡管部11が形成され
る。
The expanded portion 11 is formed by, for example, the inner cylinder 1 in the next step.
Attached to 0. First, the steel pipe material 12 used as the inner cylinder 10 is set in the pipe expanding device 40 as shown in FIG. The portion of the steel pipe material 12 to be expanded is located in the molds 41, 42. A slide mandrel 43 driven by hydraulic pressure F is inserted into the steel pipe material 12, and a fixing nut 44 is fixed to the slide mandrel 43. Slide core metal 4
An annular elastic body 45 made of urethane rubber or the like is attached to 4. One side of the annular elastic body 45 faces the fixed nut 44 via the spacer 46, and the other side faces the stopper 47. When the slide core 43 is pulled in the direction of the arrow by the hydraulic pressure F, the fixed nut 44 integrated with the slide core 43 also moves in the same direction, and presses the annular elastic body 45 via the spacer 46. The annular elastic body 45 is compressed because the other side is regulated by the stopper 47. When the slide core 43 is further slid by the hydraulic pressure F, the annular elastic body 45 causes the steel pipe material 12 to move to the mold 41,
It deforms so as to be pressed against 42. As a result, the steel pipe material 12 is processed into a shape that follows the recessed shapes of the molds 41 and 42 as shown in FIG. 2B, and the expanded pipe portion 11 is formed.

【0008】鋼管素材12の変形量は、スライド芯金4
3をスライドさせるときの油圧Fに関係する。したがっ
て、油圧Fを調整することにより、目標とする拡管径を
もつ拡管部11が成形される。拡管部11が設けられた
内筒10は、外筒20に挿入された後、レーザ溶接等に
よって拡管部11の外周面で外筒20の内面に直接接合
される。接合後に、外筒20の一部に小孔を穿設し、小
孔を介して空間部30をたとえば10-3トール以下まで
真空排気する。次いで、レーザ溶接等によって小孔を閉
塞することにより、真空断熱管が得られる。
The amount of deformation of the steel pipe material 12 depends on the slide core metal 4
3 is related to the hydraulic pressure F when sliding 3. Therefore, by adjusting the hydraulic pressure F, the pipe expanding portion 11 having a target pipe expanding diameter is formed. The inner cylinder 10 provided with the pipe expanding portion 11 is inserted into the outer cylinder 20 and then directly joined to the inner surface of the outer cylinder 20 at the outer peripheral surface of the pipe expanding portion 11 by laser welding or the like. After joining, a small hole is formed in a part of the outer cylinder 20, and the space portion 30 is evacuated to, for example, 10 −3 Torr or less through the small hole. Then, the vacuum insulation tube is obtained by closing the small holes by laser welding or the like.

【0009】[0009]

【実施例】内筒10として、肉厚1.2mm,外径34
mm及び長さ3mのSUS304ステンレス鋼管を使用
した。図2に示した拡管装置40を使用し、スライド圧
力200〜600kgf/cm2 の範囲で拡管し、9種
類の内筒10を作製した。外筒20として、肉厚0.4
mm,外径44.8mm,内径44.0mm及び長さ
2.7mのSUS304ステンレス鋼管を使用し、外径
62mm及びピッチ14mmで4山のコルゲート部21
を付けた。内筒10を外筒20に挿入し、レーザ溶接に
よる溶接性を調査した。調査結果を示す図3から明らか
なように、外筒20の内径Dinと拡管部11の外径d
outとの差が外筒20の肉厚0.4mmより小さいと
き、レーザ溶接時に生じる外筒20の溶け込みによって
十分な溶接封止が得られることが判った。他方、外筒2
0の内径Dinと拡管部11の外径dout との差が外筒2
0の肉厚0.4mmより大きいものでは、レーザ溶接時
に内筒10と外筒20との間に隙間が生じ、気密性のあ
る溶接接合部が得られなかった。
[Example] The inner cylinder 10 has a wall thickness of 1.2 mm and an outer diameter of 34
A SUS304 stainless steel tube of mm and length of 3 m was used. The tube expanding device 40 shown in FIG. 2 was used to expand the tube at a slide pressure of 200 to 600 kgf / cm 2 , and nine kinds of inner cylinders 10 were produced. The outer cylinder 20 has a wall thickness of 0.4
mm, outer diameter 44.8 mm, inner diameter 44.0 mm, and length 2.7 m of SUS304 stainless steel pipe, and outer diameter 62 mm and pitch 14 mm, four corrugated parts 21
Attached. The inner cylinder 10 was inserted into the outer cylinder 20, and the weldability by laser welding was investigated. As is clear from FIG. 3 showing the investigation result, the inner diameter D in of the outer cylinder 20 and the outer diameter d of the expanded portion 11 are shown.
When the difference between the out is smaller than the thickness 0.4mm of the outer cylinder 20, it was found that sufficient weld sealed by penetration of the outer tube 20 generated during the laser welding can be obtained. On the other hand, the outer cylinder 2
The difference between the inner diameter D in of 0 and the outer diameter d out of the expanded portion 11 is the outer cylinder 2
When the wall thickness of No. 0 was greater than 0.4 mm, a gap was formed between the inner cylinder 10 and the outer cylinder 20 during laser welding, and an airtight welded joint could not be obtained.

【0010】溶接封止できた7種類の真空断熱管につい
て、次の条件下で耐久性を調査した。外筒20と内筒1
0との温度差を80℃とした場合の軸方向の伸縮量を計
算伸縮量の3.7mmより大きい4mmに設定し、1日
1回の熱伸縮で且つ真空断熱管の耐用年数が30年と仮
定して膨張・収縮を繰り返した。その結果、何れの真空
断熱管も、目標伸縮回数1万回を超えても十分に使用に
耐える断熱特性及び強度を呈した。また、空間部30
も、何ら真空度の低下がみられなかった。
Durability of seven types of vacuum heat insulation tubes that could be welded and sealed was examined under the following conditions. Outer cylinder 20 and inner cylinder 1
The amount of expansion and contraction in the axial direction when the temperature difference from 0 is set to 80 ° C is set to 4 mm, which is larger than the expansion and contraction amount of 3.7 mm, and the thermal expansion and contraction is performed once a day and the service life of the vacuum insulation pipe is 30 years. Assuming that, expansion and contraction were repeated. As a result, all of the vacuum heat insulating tubes exhibited sufficient heat insulating properties and strength to withstand use even if the target expansion and contraction times exceeded 10,000 times. In addition, the space portion 30
However, no decrease in vacuum was observed.

【0011】[0011]

【発明の効果】以上に説明したように、本発明の真空断
熱管は、内筒の一部に拡管部を形成し、この拡管部の外
周面で内筒を外筒に直接接合している。そのため、封止
蓋を使用する方法,フレア加工によりラッパ状に成形し
た拡管部を外筒に接合する方法に比較して、封止蓋等の
部品を必要とすることなく、溶接個所が少なくなり、溶
接工程にかかる工数が削減される。その結果、得られた
真空断熱管のコストが低減することは勿論、溶接個所の
減少に伴って欠陥発生頻度が少なくなり、品質安定性に
優れた真空断熱管が高い歩留りで製造される。
As described above, in the vacuum heat insulating tube of the present invention, the expanded tube portion is formed in a part of the inner tube, and the inner tube is directly joined to the outer tube on the outer peripheral surface of the expanded tube portion. . Therefore, compared to the method of using the sealing lid and the method of joining the flared tube-shaped expanded portion by flare processing to the outer cylinder, the welding points are reduced without the need for parts such as the sealing lid. The man-hour required for the welding process is reduced. As a result, not only the cost of the obtained vacuum heat insulating tube is reduced, but also the frequency of defects is reduced as the number of welding points is reduced, and the vacuum heat insulating tube having excellent quality stability is manufactured with a high yield.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明に従った真空断熱管FIG. 1 Vacuum insulation tube according to the present invention

【図2】 拡管する前の内筒(a)及び拡管後の内筒
(b)
FIG. 2 is an inner cylinder (a) before expansion and an inner cylinder (b) after expansion.

【図3】 拡管部の外径が溶接性に与える影響を示した
グラフ
FIG. 3 is a graph showing the influence of the outer diameter of the expanded portion on the weldability.

【符号の説明】[Explanation of symbols]

10:内筒 11:拡管部 20:外筒 21:
コルゲート部 30:真空雰囲気に維持される空間部
40:拡管装置 41,42:金型 43:ス
ライド芯金 44:固定ナット 45:環状弾性体
46:スペーサ 47:ストッパー F:油圧
10: inner cylinder 11: expanded part 20: outer cylinder 21:
Corrugated part 30: Space part maintained in vacuum atmosphere 40: Tube expanding device 41, 42: Mold 43: Slide core metal 44: Fixed nut 45: Annular elastic body 46: Spacer 47: Stopper F: Hydraulic pressure

───────────────────────────────────────────────────── フロントページの続き (72)発明者 中村 尚文 兵庫県尼崎市鶴町1番地 日新製鋼株式会 社加工技術研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Naofumi Nakamura 1 Tsurumachi, Amagasaki City, Hyogo Prefecture Nisshin Steel Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 内筒及び外筒を真空層を介して嵌め合せ
た二重管構造をもち、所定間隔で前記内筒を拡管するこ
とにより形成した拡管部で前記内筒が前記外筒に気密に
直接接合されている真空断熱管。
1. A double tube structure in which an inner cylinder and an outer cylinder are fitted together via a vacuum layer, and the inner cylinder is expanded to the outer cylinder by a pipe expanding portion formed by expanding the inner cylinder at predetermined intervals. A vacuum insulation tube that is directly joined in an airtight manner.
【請求項2】 外筒内径から外筒肉厚を引いた寸法より
大きな外径をもつ拡管部が形成されるように内筒を所定
間隔で拡管し、前記拡管部で前記外筒に前記内筒を気密
に固着し、前記内筒と前記外筒との間の空間部を真空引
きすることを特徴とする真空断熱管の製造方法。
2. An inner cylinder is expanded at a predetermined interval so that an expanded tube portion having an outer diameter larger than a size obtained by subtracting the outer tube wall thickness from the outer tube inner diameter is formed, and the inner tube is expanded into the outer tube by the expanded tube portion. A method for manufacturing a vacuum heat insulating tube, comprising airtightly fixing a cylinder, and evacuating a space between the inner cylinder and the outer cylinder.
JP5276914A 1993-11-05 1993-11-05 Vacuum insulation pipe and manufacture thereof Withdrawn JPH07127791A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5276914A JPH07127791A (en) 1993-11-05 1993-11-05 Vacuum insulation pipe and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5276914A JPH07127791A (en) 1993-11-05 1993-11-05 Vacuum insulation pipe and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH07127791A true JPH07127791A (en) 1995-05-16

Family

ID=17576152

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5276914A Withdrawn JPH07127791A (en) 1993-11-05 1993-11-05 Vacuum insulation pipe and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH07127791A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106769191A (en) * 2017-01-08 2017-05-31 河北工程大学 A kind of geologic prospect soil sampler

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106769191A (en) * 2017-01-08 2017-05-31 河北工程大学 A kind of geologic prospect soil sampler
CN106769191B (en) * 2017-01-08 2024-04-05 辽宁工程技术大学 Geological survey geotome

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