JPH07122111B2 - Superplastic magnesium alloy - Google Patents
Superplastic magnesium alloyInfo
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- JPH07122111B2 JPH07122111B2 JP9045493A JP9045493A JPH07122111B2 JP H07122111 B2 JPH07122111 B2 JP H07122111B2 JP 9045493 A JP9045493 A JP 9045493A JP 9045493 A JP9045493 A JP 9045493A JP H07122111 B2 JPH07122111 B2 JP H07122111B2
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- superplastic
- strength
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Description
【０００１】[0001]
【産業上の利用分野】本発明は軽量高強度で超塑性を有
するマグネシウム合金に関し、より詳しくは超塑性特性
における伸び、塑性変形速度を改善し、且つ室温での強
度を向上させた加工用マグネシウム合金に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a magnesium alloy which is lightweight and has high strength and superplasticity, and more specifically, magnesium for working which has improved elongation and plastic deformation rate in superplastic properties and improved strength at room temperature. Regarding alloys.
【０００２】[0002]
【従来の技術】最近の自動車、家電ＯＡ産業における軽
量化の流れの中でＭｇ合金が注目されている。しかし、
一般のＭｇ合金の欠点として塑性加工が困難であること
が挙げられる。そのような合金の中ではＭｇ−Ｌｉ共晶
合金は超塑性特性を有することで知られている。この超
塑性特性を利用して複合材料の製造やブロー成形が可能
になればＭｇ合金の新しい加工技術として有用である。2. Description of the Related Art In the recent trend of weight reduction in the automobile and home appliance OA industries, Mg alloys are drawing attention. But,
A drawback of general Mg alloys is that plastic working is difficult. Among such alloys, Mg-Li eutectic alloy is known to have superplastic properties. It would be useful as a new processing technology for Mg alloys if composite materials can be manufactured or blow-molded by utilizing this superplasticity.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、Ｍｇ−
Ｌｉ合金の超塑性は一般に歪み速度の遅い領域で発現す
るので実用面で問題がある。また、Ｍｇ−Ｌｉ合金は室
温での強度の安定性がないことも実用化を阻害してい
る。However, Mg-
Since the superplasticity of Li alloy generally develops in the region where the strain rate is low, there is a problem in practical use. In addition, the fact that the Mg-Li alloy does not have strength stability at room temperature also impedes its practical application.
【０００４】本発明者等は先に、Ｍｇ−Ｌｉ合金にイッ
トリウムを添加して超塑性特性における伸び、塑性変形
速度を改善し、且つ室温での強度を向上させた超塑性マ
グネシウム合金を特許出願したが（特願平４−９７３２
５号）、イットリウムは大変高価であり、そのため合金
がその分高価になるという欠点を有する。The present inventors have previously applied for a patent for a superplastic magnesium alloy in which yttrium is added to a Mg-Li alloy to improve the elongation and plastic deformation rate in superplastic characteristics and to improve the strength at room temperature. But (Japanese Patent Application No. 4-9732
No. 5), yttrium is very expensive, which has the disadvantage that the alloy is correspondingly expensive.
【０００５】本発明は、このような従来技術及び先に提
案した技術の有する課題に鑑みてなされたものであり、
本発明の目的は、Ｍｇ−Ｌｉ合金の特徴である低密度と
いう特性が維持されたままであり、その超塑性特性が実
用化されるために歪み速度の速い領域でも超塑性が発現
され、室温での強度の向上及び強度安定性の改善が図ら
れており且つ比較的安価であるＭｇ−Ｌｉ合金を提供す
ることにある。The present invention has been made in view of the problems of the conventional technique and the technique proposed above.
The object of the present invention is that the characteristic of low density, which is a feature of the Mg-Li alloy, is maintained, and since its superplasticity characteristics are put to practical use, superplasticity is expressed even in the region of high strain rate, and at room temperature. It is an object of the present invention to provide a Mg-Li alloy which has improved strength and strength stability and is relatively inexpensive.
【０００６】[0006]
【課題を解決するための手段】本発明者等は上記の課題
を解決するために種々検討を重ねた結果、リチウム添加
量を合金に超塑性特性をもたらす６重量％超１０．５重
量％未満とし、且つ適量のカルシウムを添加することに
より歪み速度を１０〜２０倍にした領域でも超塑性が発
現し、伸び（％）が大きくなり、室温での強度が向上
し、且つ時間経過による強度の劣化が抑制される即ち強
度の安定性が改善されることを見出し、本発明に到達し
た。Means for Solving the Problems As a result of various investigations by the present inventors in order to solve the above problems, as a result, the amount of lithium added exceeds 6% by weight and less than 10.5% by weight which brings superplastic characteristics to the alloy. And, by adding an appropriate amount of calcium, even in a region where the strain rate is increased by 10 to 20 times, superplasticity is developed, the elongation (%) is increased, the strength at room temperature is improved, and the strength with time elapses. The present inventors have found that deterioration is suppressed, that is, stability of strength is improved, and the present invention has been achieved.
【０００７】即ち、本発明の超塑性マグネシウム合金は
リチウム６重量％超１０．５重量％未満及びカルシウム
０．３〜３重量％を含有し、残部がマグネシウムと不可
避の不純物からなることを特徴とする。That is, the superplastic magnesium alloy of the present invention is characterized by containing more than 6% by weight of lithium and less than 10.5% by weight of lithium and 0.3 to 3% by weight of calcium, and the balance being magnesium and inevitable impurities. To do.
【０００８】本発明の超塑性マグネシウム合金は、所望
により、更に４重量％以下のアルミニウム、４重量％以
下の亜鉛、それぞれ２重量％以下の銀、マンガン、ケイ
素、ストロンチウム、イットリウム、スカンジウム及び
ランタノイドからなる群から選ばれた少なくとも１種の
合金元素を含有することができる。The superplastic magnesium alloy of the present invention optionally further comprises 4% by weight or less of aluminum, 4% by weight or less of zinc, and 2% by weight or less of each of silver, manganese, silicon, strontium, yttrium, scandium and lanthanoid. It may contain at least one alloying element selected from the group consisting of:
【０００９】リチウムは比重が０．５３であり、リチウ
ム添加量を増加させることにより本発明の超塑性マグネ
シウム合金を更に低比重とすることができる。そしてＭ
ｇ−Ｌｉ合金においてリチウム添加量が６重量％超１
０．５重量％未満の範囲内では超塑性特性を有すること
が知られている。この範囲から外れるとＨＣＰ単相及び
ＢＣＣ単相となる。従って、本発明の超塑性マグネシウ
ム合金においてはリチウム添加量を６重量％超１０．５
重量％未満、好ましくは７．５〜９．０重量％とする。Lithium has a specific gravity of 0.53, and the superplastic magnesium alloy of the present invention can have a lower specific gravity by increasing the amount of lithium added. And M
In the g-Li alloy, the amount of lithium added exceeds 6 wt% 1
It is known to have superplastic properties within the range of less than 0.5% by weight. Outside this range, the HCP single phase and the BCC single phase are obtained. Therefore, in the superplastic magnesium alloy of the present invention, the amount of lithium added is more than 6% by weight and 10.5%.
It is less than wt%, preferably 7.5 to 9.0 wt%.
【００１０】本発明の超塑性マグネシウム合金において
は、カルシウムは凝固段階で微細なＭｇ−Ｃａ系化合物
として晶出し、凝固組織を微細化する効果を有する。こ
の組織の微細化は言うまでもなく超塑性特性を改善す
る。また、このような晶出に費やされた以外のカルシウ
ムは主にＢＣＣ相に固溶し、合金を固溶硬化すると共に
合金の加工組織の回復など経時変化を抑制するので、室
温強度の向上と強度の安定化に寄与する。カルシウムの
添加量が３重量％を越えるとＭｇ−Ｃａ系化合物が結晶
粒界にネットワーク状に晶出するようになるので超塑性
特性を阻害するようになる。また、カルシウム添加量が
０．３重量％未満の場合にはＭｇ−Ｃａ系化合物が晶出
しないので組織の微細化効果が得られず、超塑性特性は
改善されない。従って、本発明の超塑性マグネシウム合
金においてはカルシウム添加量を０．３〜３重量％、好
ましくは０．５〜２重量％とする。なお、Ｍｇ−Ｌｉ合
金は酸素含有雰囲気中で溶解させるとＭｇが燃焼する
が、このＭｇ−Ｌｉ合金にカルシウムを添加すると酸素
含有雰囲気中での溶解時のＭｇの燃焼が抑制される。従
って、本発明の超塑性マグネシウム合金の溶解は完全な
不活性雰囲気中でなくても、あるいは空気中でも実施で
きる。In the superplastic magnesium alloy of the present invention, calcium is crystallized as a fine Mg-Ca compound in the solidification stage and has the effect of refining the solidification structure. Needless to say, this refinement of the structure improves superplastic properties. In addition, calcium other than that which has been spent for crystallization mainly forms a solid solution in the BCC phase, solid-solution hardens the alloy, and suppresses changes over time such as recovery of the work structure of the alloy, thus improving room temperature strength. And contribute to the stabilization of strength. If the amount of calcium added exceeds 3% by weight, the Mg-Ca-based compound will crystallize in the grain boundaries in a network form, thereby impairing superplastic properties. Further, when the amount of calcium added is less than 0.3% by weight, the Mg-Ca-based compound does not crystallize, so that the effect of refining the structure cannot be obtained and the superplasticity characteristics cannot be improved. Therefore, in the superplastic magnesium alloy of the present invention, the amount of calcium added is 0.3 to 3% by weight, preferably 0.5 to 2% by weight. It should be noted that Mg-Li alloy burns when dissolved in an oxygen-containing atmosphere, but when calcium is added to this Mg-Li alloy, combustion of Mg during melting in an oxygen-containing atmosphere is suppressed. Therefore, the melting of the superplastic magnesium alloy of the present invention can be carried out in a completely inert atmosphere or in air.
【００１１】Ｍｇ−Ｌｉ合金においては、アルミニウ
ム、亜鉛、銀、マンガン、ケイ素、ストロンチウム、イ
ットリウム、スカンジウム及びランタノイド（例えば、
Ｌａ、Ｃｅ、ミッシュメタル等）はいずれも合金の強度
向上に寄与することが知られており、この効果はカルシ
ウムとの共存によっても相殺されるものではない。これ
らの合金元素の添加量の増加と共に合金の強度が増大す
るが、アルミニウム及び亜鉛については４重量％で、ま
た銀、マンガン、ケイ素、ストロンチウム、イットリウ
ム、スカンジウム及びランタノイドについては２重量％
で合金強度の増大に対する効果が飽和し、それ以上添加
してもそれ以上の合金強度の増大は認められない。一
方、アルミニウム及び亜鉛については４重量％を越え
て、また銀、マンガン、ケイ素、ストロンチウム、イッ
トリウム、スカンジウム及びランタノイドについては２
重量％を越えて添加すると、合金は脆くなることもあ
り、合金の比重が大きくなり、また加工性も低下するこ
とになる。従って、本発明の超塑性マグネシウム合金に
おいては、アルミニウム及び亜鉛の添加量については４
重量％以下、好ましくは１．０〜３．０重量％、また
銀、マンガン、ケイ素、ストロンチウム、イットリウ
ム、スカンジウム及びランタノイドの添加量については
２重量％以下、好ましくは０．５〜１．５重量％とす
る。In Mg-Li alloys, aluminum, zinc, silver, manganese, silicon, strontium, yttrium, scandium and lanthanoids (eg,
La, Ce, misch metal, etc.) are all known to contribute to the improvement of the strength of the alloy, and this effect is not offset by coexistence with calcium. The strength of the alloy increases as the amount of these alloying elements increases, but it is 4% by weight for aluminum and zinc and 2% by weight for silver, manganese, silicon, strontium, yttrium, scandium and lanthanoids.
The effect on the increase in alloy strength saturates, and no further increase in alloy strength is observed even if more is added. On the other hand, it exceeds 4% by weight for aluminum and zinc, and 2 for silver, manganese, silicon, strontium, yttrium, scandium and lanthanoids.
If added in excess of weight%, the alloy may become brittle, the specific gravity of the alloy may increase, and the workability may decrease. Therefore, in the superplastic magnesium alloy of the present invention, the addition amount of aluminum and zinc is 4
% By weight or less, preferably 1.0 to 3.0% by weight, and 2% by weight or less, preferably 0.5 to 1.5% by weight with respect to the amount of silver, manganese, silicon, strontium, yttrium, scandium and lanthanoid added. %.
【００１２】[0012]
【実施例】実施例１〜１４及び比較例１〜５ アルゴン雰囲気の真空溶解炉に、表１に示す組成の合金
となるように原材料をを装入し、溶解させた。坩堝とし
てＳＵＳ３０４材を使用し、フラックス等は使用しなか
った。その溶湯を５０mm×５０mm×３００mmの金型中に
鋳込んで試験用鋳物を作成した。このようにして得た試
験用鋳物を２５０℃で１時間熱処理した後、２５０℃で
５mmから０．８mmに圧延して引張試験片を作成し、以下
の試験を実施した。試験はいずれも圧延方向である： 引張試験：インストロン引張試験機による、 試験片：厚さ０．８mm、長さ２０mm、幅２０mm、標点間
距離１０mm、標点間幅５mm、 鋳造後２５℃で測定（引張強度）及び６０℃で１週間保
持した後に２５℃で測定（６０℃に保持後の引張強
度）、 歪み速度＝４×１０-4／ｓ、測定単位＝ＭＰａ； 比重：アルキメデス法； 超塑性特性試験：温度３５０℃、標点間距離１０mm、 歪み速度＝４×１０-5〜４×１０-1／ｓ； 測定結果は表１及び図１に示す通りであった。図１にお
いてピークの位置が超塑性特性を示す。EXAMPLES Examples 1 to 14 and Comparative Examples 1 to 5 Raw materials were charged and melted in a vacuum melting furnace in an argon atmosphere so as to form an alloy having the composition shown in Table 1. SUS304 material was used as the crucible, and no flux or the like was used. The molten metal was cast into a mold of 50 mm × 50 mm × 300 mm to prepare a test casting. The test castings thus obtained were heat-treated at 250 ° C. for 1 hour and then rolled at 250 ° C. from 5 mm to 0.8 mm to prepare tensile test pieces, and the following tests were carried out. All tests are in the rolling direction: Tensile test: by Instron tensile tester, test piece: thickness 0.8 mm, length 20 mm, width 20 mm, gauge length 10 mm, gauge width 5 mm, 25 after casting Measured at 25 ° C. (tensile strength) and held at 60 ° C. for 1 week and then measured at 25 ° C. (tensile strength after held at 60 ° C.), strain rate = 4 × 10 −4 / s, measurement unit = MPa; Specific gravity: Archimedes Method: Superplastic property test: temperature 350 ° C., gauge length 10 mm, strain rate = 4 × 10 -5 to 4 × 10 -1 / s; The measurement results are shown in Table 1 and FIG. In FIG. 1, the position of the peak shows superplasticity characteristics.
【００１３】[0013]
【表１】 ６０℃に ３５０℃で 合 金 組 成 引張 保持後の の超塑性伸例番号 Ｌｉ Ｃａ その他 Ｍｇ 強度 引張強度 比重 び率、％ 実施例１ 8.5 1.0 − 残 200 190 1.51 800％ 実施例２ 8.5 3.0 − 残 220 220 1.51 700％ 実施例３ 8.5 0.3 − 残 190 180 1.51 650％ 実施例４ 6.0 1.0 − 残 220 210 1.55 300％ 実施例５ 10.5 1.0 − 残 180 170 1.47 300％ 比較例１ 8.5 − − 残 180 140 1.52 600％ 比較例２ 5.5 1.0 − 残 230 220 1.57 ※ 比較例３ 11.0 1.0 − 残 170 165 1.47 ※ 比較例４ 8.5 4.0 − 残 220 220 1.51 ※ 実施例６ 8.5 1.0 Al:2.0 残 260 255 1.55 400％ 実施例７ 8.5 1.0 Zn:2.0 残 250 245 1.57 380％ 実施例８ 8.5 1.0 Ag:1.0 残 240 240 1.56 450％ 実施例９ 8.5 1.0 Mn:0.6 残 210 210 1.53 820％ 実施例10 8.5 1.0 Si:1.0 残 220 220 1.52 750％ 実施例11 8.5 1.0 Ｙ:1.0 残 230 230 1.53 900％ 実施例12 8.5 1.0 Sr:1.0 残 230 225 1.52 750％ 実施例13 8.5 1.0 Sc:1.0 残 230 225 1.52 830％ 実施例14 8.5 1.0 La:1.0 残 230 230 1.53 880％ 比較例５ 8.5 1.0 Al:6.0 残 270 265 1.60 ※ 対照例１ 8.5 − Ｙ:1.0 残 210 205 1.55 400％ ※伸びは１２０％前後であるが超塑性は示さない。TABLE 1 superplastic Shin Example No. Li Ca Other Mg strength tensile strength gravity beauty rate of after 60 ° C. alloy sets formed at 350 ° C. in tensile retention,% Example 1 8.5 1.0 - remaining 200 190 1.51 800% Example 2 8.5 3.0-remaining 220 220 1.51 700% Example 3 8.5 0.3-remaining 190 180 1.51 650% Example 4 6.0 1.0-remaining 220 210 1.55 300% Example 5 10.5 1.0-remaining 180 170 1.47 300% Comparative Example 1 8.5 − − Remaining 180 140 1.52 600% Comparative example 2 5.5 1.0 − Remaining 230 220 1.57 * Comparative example 3 11.0 1.0 − Remaining 170 165 1.47 * Comparative example 4 8.5 4.0 − Remaining 220 220 1.51 * Example 6 8.5 1.0 Al: 2.0 Remaining 260 255 1.55 400% Example 7 8.5 1.0 Zn: 2.0 Remaining 250 245 1.57 380% Example 8 8.5 1.0 Ag: 1.0 Remaining 240 240 1.56 450% Example 9 8.5 1.0 Mn: 0.6 Remaining 210 210 1.53 820% Example 10 8.5 1.0 Si: 1.0 Remaining 220 220 1.52 750% Example 11 8.5 1.0 Y: 1.0 Remaining 230 230 1.53 900% Example 12 8.5 1.0 Sr: 1.0 Remaining 230 225 1.52 750% Example 13 8.5 1.0 Sc: 1.0 Remaining 230 225 1 .52 830% Example 14 8.5 1.0 La: 1.0 Remaining 230 230 1.53 880% Comparative Example 5 8.5 1.0 Al: 6.0 Remaining 270 265 1.60 * Control Example 1 8.5-Y: 1.0 Remaining 210 205 1.55 400% * Elongation is 120% Before and after, it does not show superplasticity.
【００１４】上記の実施例及び比較例のデータから次の
ことが明らかである：実施例１と比較例１との比較から
明らかなようにカルシウムは室温での強度向上及び強度
の安定性に有効である；図１から明らかなように超塑性
の伸び率はカルシウムの添加によって向上し、超塑性特
性を利用する加工技術の実用化において一層有意義な超
塑性を発現する歪み速度は１０〜２０倍になる；比較例
２〜４から明らかなようにリチウム添加量が共晶組成か
ら外れる場合及びカルシウム添加量が過大な場合には超
塑性特性を示さない；アルミニウム、亜鉛、銀、マンガ
ン、ケイ素、ストロンチウム、イットリウム、スカンジ
ウム及びランタノイドの添加はＭｇ−Ｌｉ合金の強度の
向上に寄与し、且つ超塑性特性を損なうこともない。From the data of the above Examples and Comparative Examples, it is clear that the following is true: As is clear from the comparison between Example 1 and Comparative Example 1, calcium is effective in improving strength and stability of strength at room temperature. As is clear from FIG. 1, the elongation rate of superplasticity is improved by the addition of calcium, and the strain rate at which more significant superplasticity is manifested in the practical application of processing technology utilizing superplasticity is 10 to 20 times. As is clear from Comparative Examples 2 to 4, when the amount of lithium added deviates from the eutectic composition and when the amount of calcium added is too large, superplastic properties are not exhibited; aluminum, zinc, silver, manganese, silicon, The addition of strontium, yttrium, scandium and lanthanoid contributes to the improvement of the strength of the Mg-Li alloy and does not impair the superplastic property.
【００１５】[0015]
【発明の効果】本発明の超塑性マグネシウム合金は、超
塑性を有するとされながら実用化されなかった従来のＭ
ｇ−Ｌｉ合金の超塑性特性を改善しており、また室温強
度の向上及び強度の安定性に優れている。EFFECT OF THE INVENTION The superplastic magnesium alloy of the present invention has a conventional M value which is said to have superplasticity but has not been put to practical use.
It improves the superplasticity of the g-Li alloy and is excellent in room temperature strength and strength stability.
【００１６】本発明の超塑性マグネシウム合金は、超塑
性特性を利用した加工、例えばブロー成形が可能とな
り、航空・宇宙関連はもとより、自動車・車両、家電・
ＯＡ関係に活用することができる。The superplastic magnesium alloy of the present invention can be processed by utilizing superplastic properties, for example, blow molding.
It can be used for OA relations.
【図１】本発明の超塑性マグネシウム合金の超塑性特性
（歪み速度と伸びとの関係）を示すグラフである。FIG. 1 is a graph showing superplasticity characteristics (relationship between strain rate and elongation) of a superplastic magnesium alloy of the present invention.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 二宮 隆二 埼玉県上尾市原市1333−２ 三井金属鉱業 株式会社総合研究所内 (72)発明者 佐藤 勉 埼玉県上尾市原市1333−２ 三井金属鉱業 株式会社総合研究所内 (72)発明者 ギュンター ナイテ ドイツ連邦共和国 Ｄ−6350 バッド ナ ウハイム マイヌスストラッセ ９ (72)発明者 エバハード イー シュミット ドイツ連邦共和国 Ｄ−8755 アルゼナウ アイウンターフランクフルト イグラウ ワー ストラッセ ２Ｅ ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Ryuji Ninomiya 1333-2, Ageo-shi, Saitama Prefecture Mitsui Mining & Smelting Co., Ltd. (72) Inventor Tsutomu Sato 1333-2, Ageo-shi, Saitama Mitsui Mining & Smelting Co., Ltd. (72) Inventor Günter Naite Germany Federal Republic of Germany D-6350 Bad Nauheim Mainus Strasse 9 (72) Inventor Eberhard Eschmidt Federal Republic of Germany D-8755 Arsenau Eiinter Frankfurt Igra Wer Strasse 2E
Claims (2)
及びカルシウム０．３〜３重量％を含有し、残部がマグ
ネシウムと不可避の不純物からなることを特徴とする超
塑性マグネシウム合金。1. A superplastic magnesium alloy containing more than 6% by weight of lithium and less than 10.5% by weight of lithium and 0.3 to 3% by weight of calcium, and the balance being magnesium and inevitable impurities.
及びカルシウム０．３〜３重量％を含有し、更に４重量
％以下のアルミニウム、４重量％以下の亜鉛、それぞれ
２重量％以下の銀、マンガン、ケイ素、ストロンチウ
ム、イットリウム、スカンジウム及びランタノイドから
なる群から選ばれた少なくとも１種の元素を含有し、残
部がマグネシウムと不可避の不純物からなることを特徴
とする超塑性マグネシウム合金。2. A lithium containing more than 6% by weight and less than 10.5% by weight of lithium and 0.3 to 3% by weight of calcium, and further 4% by weight or less of aluminum, 4% by weight or less of zinc, and 2% by weight or less of each. A superplastic magnesium alloy containing at least one element selected from the group consisting of silver, manganese, silicon, strontium, yttrium, scandium and lanthanoids, with the balance being magnesium and inevitable impurities.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9045493A JPH07122111B2 (en) | 1993-03-26 | 1993-03-26 | Superplastic magnesium alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9045493A JPH07122111B2 (en) | 1993-03-26 | 1993-03-26 | Superplastic magnesium alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06279905A JPH06279905A (en) | 1994-10-04 |
| JPH07122111B2 true JPH07122111B2 (en) | 1995-12-25 |
Family
ID=13999072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9045493A Expired - Fee Related JPH07122111B2 (en) | 1993-03-26 | 1993-03-26 | Superplastic magnesium alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07122111B2 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9502238D0 (en) * | 1995-02-06 | 1995-03-29 | Alcan Int Ltd | Magnesium alloys |
| US6342180B1 (en) * | 2000-06-05 | 2002-01-29 | Noranda, Inc. | Magnesium-based casting alloys having improved elevated temperature properties |
| JP3852769B2 (en) * | 2002-11-06 | 2006-12-06 | 三菱製鋼株式会社 | Room temperature formable magnesium alloy with excellent corrosion resistance |
| JP2013006293A (en) * | 2011-06-22 | 2013-01-10 | Fuji Heavy Ind Ltd | Laminate |
| CN102676893B (en) * | 2012-01-15 | 2014-05-07 | 河南科技大学 | High heat conductivity magnesium base alloy material, copper clad plate and preparation method thereof |
| CN104233024A (en) * | 2014-09-28 | 2014-12-24 | 中南大学 | High-strength two-phase ultralight magnesium lithium alloy and preparation method thereof |
| JP6794264B2 (en) * | 2015-01-27 | 2020-12-02 | 株式会社三徳 | Magnesium-lithium alloy, rolled materials and molded products |
| CN106834844B (en) * | 2017-02-20 | 2018-05-15 | 鼎镁（昆山）新材料科技有限公司 | A kind of high-strength ultralight single-phase magnesium lithium alloy plates of β and preparation method thereof |
| JP7362267B2 (en) * | 2018-04-23 | 2023-10-17 | キヤノン株式会社 | Magnesium-lithium alloys, optical equipment, imaging devices, electronic equipment, and mobile objects |
| CN115287514B (en) * | 2018-04-23 | 2023-11-03 | 佳能株式会社 | Magnesium-lithium alloy |
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-
1993
- 1993-03-26 JP JP9045493A patent/JPH07122111B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304508A (en) * | 2020-04-23 | 2020-06-19 | 上海交通大学 | AlN-reinforced magnesium-lithium-based composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06279905A (en) | 1994-10-04 |
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