JPH07100816A - Artificial stone with non-slip finish/and manufacture of artificial stone - Google Patents

Artificial stone with non-slip finish/and manufacture of artificial stone

Info

Publication number
JPH07100816A
JPH07100816A JP26820493A JP26820493A JPH07100816A JP H07100816 A JPH07100816 A JP H07100816A JP 26820493 A JP26820493 A JP 26820493A JP 26820493 A JP26820493 A JP 26820493A JP H07100816 A JPH07100816 A JP H07100816A
Authority
JP
Japan
Prior art keywords
resin
stone
stone material
artificial stone
granular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26820493A
Other languages
Japanese (ja)
Inventor
Katsuyuki Nagai
克之 永井
Eiichi Tajima
栄一 田島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tajima Inc
Original Assignee
Tajima Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tajima Inc filed Critical Tajima Inc
Priority to JP26820493A priority Critical patent/JPH07100816A/en
Publication of JPH07100816A publication Critical patent/JPH07100816A/en
Pending legal-status Critical Current

Links

Landscapes

  • Finishing Walls (AREA)
  • Floor Finish (AREA)
  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)

Abstract

PURPOSE:To obtain an artificial stone with a non-slip function having the original luster of a natural stone by constituting at least, a surface part with a resin part and a granular stone material part and removing the resin portion of the surface part by cutting with a water jet. CONSTITUTION:A resin material 2 for mold injection is injected into a mold which a granular crushed stone or an inorganic granule 1 are laid and allowed to be cured, or a resin 2 is mixed with this granule 1, then the mixture is pressed and left to be cured. Next, this cured product is removed from the mold and the resin portion 2 on a surface layer is removed by a water jet finishing method. Thus, the resin portion 2 is made more recessed relatively compared to a stone material part 1. After polishing the surface following the removal of the cured product from the mold, it is finished by the water jet finishing method so that it appears as if it were polished and this artificial stone obtained has a non-slip effect.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ノンスリップ加工をし
た人造石材、および該人造石材の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-slip artificial stone material and a method for producing the artificial stone material.

【0002】[0002]

【従来の技術】ミカゲ石のノンスリップ化の方法として
バーナー仕上げ、たたき仕上げ等の加工方法が知られて
いる。これらの方法は、いずれも表面に物理的に凹凸を
付けるもので、みがかれた鏡面に近い光沢は得られな
い。
2. Description of the Related Art Processing methods such as burner finishing and tapping finishing are known as non-slip methods for mikage stone. In all of these methods, the surface is made physically uneven, and a gloss close to a mirror-finished surface cannot be obtained.

【0003】[0003]

【目的】本発明の目的は、天然石の本来の色艶を保持
し、かつ、本磨き仕上げが施されているように見えなが
ら、ノンスリップの機能を有する人造石材の提供にあ
る。
[Purpose] An object of the present invention is to provide an artificial stone material that retains the original color and luster of natural stone and has a non-slip function while appearing to have been subjected to final polishing.

【0004】[0004]

【構成】本発明は、樹脂部および粒体状の石材部で構成
され、かつ樹脂部および粒体状の石材部の現出している
表面部、特に研磨された表面部の樹脂部をウォータージ
ェット加工により切削除去し、特に研磨仕上げされた石
材のごとく見える人造石材をノンスリップ加工する方
法、および該ノンスリップ加工法で得られた表面部の樹
脂部を石材部に比べて相対的に凹部としたノンスリップ
人造石材に関する。本発明のノンスリップ人造石材は、
例えば液状の注型用の樹脂材料を、粒体状の砕石又は無
機質系粒体を敷き詰めた型中に注入し、硬化して製造す
ることができる。また、該人造石材は、ウォータージェ
ット加工される前に、必要に応じて磨き仕上げ処理を行
う。人造石材は、通常のバーナー加工と同様に、研磨加
工する前にウォータージェット加工をすることにより、
ノンスリップ加工ができる。さらに、本発明は、研磨後
にウォータージェットをかけることで、研磨仕上げにみ
えて、かつ、ノンスリップの効果が得られる。本発明の
ノンスリップ人造石材の石材部としては、例えばミカゲ
石、大理石等の天然石の砕石が挙げられるが、鏡面にみ
がかれた表面にウォータージェット加工を行う際、石材
表面のみ鏡面(光沢)を維持するに充分な硬度を必要と
する等の理由から、ミカゲ石が好ましい。ただし、本発
明で使用する粒体状の石材成分は、前記のような天然石
の砕石に限定されるものではなく、例えばスラグのよう
なものを粉砕したもの、又は、セラミックス、ガラスな
どの無機質系粒体であってもよい。また、粒体状の石材
部の大きさは、好ましくは2〜10m/m程度のもの、
さらに好ましくは3〜5m/m程度の大きさのものであ
る。さらに、これら石材部の表面現出率は好ましくは8
0%以上、さらに好ましくは90〜95%である。
According to the present invention, a water jet is used which comprises a resin portion and a granular stone material portion, and the exposed surface portion of the resin portion and the granular stone material portion, especially the resin portion of the polished surface portion. A method of non-slip processing of artificial stone material that looks like a stone material that has been cut and removed by processing, and a non-slip process in which the resin portion of the surface portion obtained by the non-slip processing method is a concave portion relative to the stone portion Regarding artificial stone materials. The non-slip artificial stone material of the present invention is
For example, it can be manufactured by injecting a liquid resin material for casting into a mold in which granular crushed stones or inorganic particles are spread and curing. In addition, the artificial stone material is subjected to polishing and finishing treatment, if necessary, before being subjected to water jet processing. Artificial stone material, like normal burner processing, by water jet processing before polishing,
Non-slip processing is possible. Further, according to the present invention, by applying a water jet after polishing, an effect of non-slip can be obtained, which looks like polishing finish. Examples of the stone portion of the non-slip artificial stone material of the present invention include crushed stones of natural stones such as mikage stone and marble, but when performing water jet processing on the mirror-polished surface, only the stone surface has a mirror surface (gloss). Since it requires sufficient hardness to maintain, etc., mikage stone is preferable. However, the granular stone component used in the present invention is not limited to the crushed stone of the natural stone as described above, for example, a crushed substance such as slag, or an inorganic material such as ceramics or glass. It may be a granule. Further, the size of the granular stone material portion is preferably about 2 to 10 m / m,
More preferably, it has a size of about 3 to 5 m / m. Further, the surface appearance rate of these stone parts is preferably 8
It is 0% or more, more preferably 90 to 95%.

【0005】本発明のノンスリップ人造石材の樹脂部を
構成する樹脂材料としては、例えば注型用の液状の樹脂
材料が挙げられ、該樹脂材料は、本質的に液状である単
量体のメタアクリル酸メチルあるいは低重合度、低縮合
度のフェノール樹脂、エポキシ樹脂、メタクリル樹脂、
またはその低重合・低縮合度のフェノール樹脂、エポキ
シ樹脂、メタクリル樹脂、またはそのような低重合・低
縮合樹脂をその単量体に溶解した不飽和ポリエステル樹
脂、ジアリルフタレート樹脂、メタクリル樹脂に、それ
ぞれ適応する硬化剤と撹拌し、さらに必要に応じて着色
剤や充填剤等が配合されたものである。この場合に配合
材料に、気泡の混入を防止するように調製するのが好ま
しい。着色剤としては、使用する石材部の色調を考慮し
てその適当な色彩を選択することにより、得られる人造
石材に種々の態様の模様あるいは色調を付与することが
できる。充填材としては、例えば、炭酸カルシウム、ケ
イ酸カルシウム等の粉粒体やガラス繊維や石綿等の無機
繊維、炭素繊維等の繊維状の固形補強材が挙げられ、該
繊維状の補強剤は、長繊維あるいは短繊維であってもよ
いが、通常3〜10m/mの大きさの小裁断片を使用す
るのが好ましい。
Examples of the resin material constituting the resin portion of the non-slip artificial stone material of the present invention include a liquid resin material for casting, and the resin material is an essentially liquid monomer methacrylic. Methyl acid or low degree of polymerization, low degree of condensation phenol resin, epoxy resin, methacrylic resin,
Or its low polymerization / low condensation degree phenolic resin, epoxy resin, methacrylic resin, or unsaturated polyester resin, diallyl phthalate resin, methacrylic resin in which such low polymerization / low condensation resin is dissolved in its monomer, respectively, It is prepared by stirring with an appropriate curing agent and further adding a colorant, a filler and the like as required. In this case, it is preferable that the compounding material is prepared so as to prevent bubbles from being mixed therein. As the colorant, an appropriate color can be selected in consideration of the color tone of the stone portion to be used, and thus various patterns or color tones can be imparted to the obtained artificial stone material. Examples of the filler include calcium carbonate, calcium silicate and the like powdered particles, inorganic fibers such as glass fiber and asbestos, and fibrous solid reinforcing material such as carbon fiber, and the fibrous reinforcing agent, Long fibers or short fibers may be used, but it is generally preferable to use cut pieces having a size of 3 to 10 m / m.

【0006】前記樹脂材料を前記石材を敷き詰めた型
(金属製、ガラス製またはプラスチック製など)に注ぎ
込み、又はベルトコンベア上で常温または加熱し硬化さ
せる。あるいは、前記樹脂を表面にまぶした粒体状の砕
石又は無機質系粒体をプレスにより押し固め、硬化させ
る方法によっても製造することができる。前記材料の配
合比は、重量比で樹脂7〜20%、砕石45〜60%お
よび充填材10〜30%の範囲のものが好ましい。前記
の型の内面には、シリコーンを焼付けたり、あるいはシ
リコーングリース、PVA、ワックス、フッ素樹脂等で
離型膜を形成しておくのが好ましい。前記樹脂材料を硬
化後、前記の型より人造石材を離型し、表面研磨を行っ
た後、ウォータージェット加工により、硬化物の表面層
より樹脂部を除去して本発明のノンスリップ人造石材が
製造される。なお、本発明のノンスリップ人造石材は、
前記したように注型法により製造するのが好ましいが、
前記樹脂部を形成する樹脂材料と石材成分を混合し所望
の形状の人造石材に成型し、必要に応じ、表面研磨を行
った後、該石材をウォータージェット加工により製造し
たものであってもよい。
[0006] The resin material is poured into a mold (made of metal, glass, plastic, or the like) in which the stone material is spread, or is cured at room temperature or heated on a belt conveyor. Alternatively, it can also be produced by a method in which a granular crushed stone or an inorganic granule having the surface coated with the resin is pressed and hardened and then cured. The compounding ratio of the above materials is preferably such that the weight ratio of the resin is 7 to 20%, the crushed stone is 45 to 60%, and the filler is 10 to 30%. It is preferable that silicone is baked on the inner surface of the mold, or a release film is formed with silicone grease, PVA, wax, fluororesin or the like. After curing the resin material, the artificial stone material is released from the mold, and after surface polishing, the resin portion is removed from the surface layer of the cured product by water jet processing to produce the non-slip artificial stone material of the present invention. To be done. Incidentally, the non-slip artificial stone material of the present invention,
As described above, it is preferable to manufacture by the casting method,
A resin material forming the resin portion and a stone component may be mixed and molded into an artificial stone material having a desired shape, and if necessary, the stone material may be manufactured by water jet processing after surface polishing. .

【0007】[0007]

【実施例】次に、本発明の人造石材の製造法を実施例に
基づいて説明する。但し、本発明は、以下の実施例に記
載のものに限定されるものではない。 実施例1 無水マレイン酸とグリコールの反応によって得られた不
飽和アルキドをスチレンに溶解し樹脂液を調製し、該樹
脂液中に3mmの長さのガラス繊維、0.05m/m程
度の粒度の硅石粉末および必要に応じて着色剤を配合し
た。前記配合物とミカゲ石の砕石を混合し、該混合物を
型中に入れプレスで押し固め硬化した。硬化後、脱型
し、片面側の表面部分に図1に示すような状態で前記ミ
カゲ石の砕石が配置された厚さ5〜7mmの厚さの硬化
物を得た。前記硬化物を砥石による研磨の手段でミガキ
仕上げした。
EXAMPLES Next, a method for manufacturing an artificial stone material of the present invention will be described based on examples. However, the present invention is not limited to the examples described below. Example 1 An unsaturated alkyd obtained by the reaction of maleic anhydride and glycol was dissolved in styrene to prepare a resin solution, and a glass fiber having a length of 3 mm and a particle size of about 0.05 m / m was prepared in the resin solution. Silica powder and optionally a colorant were blended. The above compound and crushed stones of mikage stone were mixed, and the mixture was put into a mold and pressed and hardened by a press to be hardened. After the curing, the mold was removed, and a cured product having a thickness of 5 to 7 mm was obtained in which the crushed stones of the above-mentioned mikage stone were arranged on the surface portion on one side as shown in FIG. The cured product was polished by a means of polishing with a grindstone.

【0008】前記ミガキ仕上げした硬化物を慣用のウォ
ータージェット加工法により処理し、約0.1〜1mm
程度の深さで、樹脂部を除去した。ウォータージェット
加工による使用する水圧としては、1200kg〜15
00kg/cm2程度のものが採用される。また、前記
ノズルは、加工むら防止のため、単一でなく複数のノズ
ルを使用した。本実施例で使用したテスト機のノズル
は、0.12φ×12をエアーにより回転させ使用し
た。また、ノズルと前記ミガキ仕上げした硬化物の間隔
は15m/mであった。
The hardened product which has been finished by polishing is treated by a conventional water jet processing method to obtain about 0.1 to 1 mm.
The resin portion was removed at a depth of about the same. The water pressure used by water jet processing is 1200 kg to 15
A material of about 00 kg / cm 2 is adopted. Further, a plurality of nozzles were used instead of a single nozzle in order to prevent uneven processing. The nozzle of the tester used in this example was used by rotating 0.12φ × 12 with air. The distance between the nozzle and the hardened material after the polishing was 15 m / m.

【0009】[0009]

【効果】本発明で得た人造石材は、 1.ミガキの板の外観を呈するが、実際は、ノンスリッ
プ状態が確保されているおり、かつ 2.通常のバーナー仕上げ等のノンスリップ加工では色
調のよいものが得られないが、石の本来の色艶を保持す
る、という利点を有する。従って、本発明の人造石材
は、建物の一階、特に、玄関などのような個所の施工に
使用することができる。
[Effect] The artificial stone material obtained by the present invention is 1. It has the appearance of a shaving plate, but in reality it is in a non-slip state, and Although non-slip processing such as ordinary burner finishing does not give a good color tone, it has the advantage of retaining the original color and luster of stone. Therefore, the artificial stone material of the present invention can be used for the construction of the first floor of a building, particularly a location such as a front door.

【図面の簡単な説明】[Brief description of drawings]

【図1】(a)実施例1の人造石材のウォータージェッ
ト加工前の断面図である。 (b)実施例1の人造石材のウォータージェット加工後
の断面図である。
FIG. 1A is a cross-sectional view of an artificial stone material of Example 1 before water jet processing. (B) It is sectional drawing after the water jet processing of the artificial stone material of Example 1.

【符号の説明】[Explanation of symbols]

1 石材部分 2 樹脂部 1 Stone part 2 Resin part

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 少なくとも表層部が樹脂部および粒体状
の石材部で構成され、かつ樹脂部および粒体状の石材部
の現出している表面部の樹脂部をウォータージェット加
工により切削除去し、樹脂部を石材部に比べて相対的に
凹部としたことを特徴とするノンスリップ性人造石材。
1. At least the surface layer portion is composed of a resin portion and a granular stone portion, and the resin portion of the exposed surface portion of the resin portion and the granular stone portion is cut and removed by water jet machining. A non-slip artificial stone material, characterized in that the resin portion is a concave portion relative to the stone portion.
【請求項2】 少なくとも表層部が樹脂部および粒体状
の石材部で構成され、かつ樹脂部および粒体状の石材部
の現出している研磨加工された表面部の樹脂部をウォー
タージェット加工により切削除去し、樹脂部を石材部に
比べて相対的に凹部としたことを特徴とするノンスリッ
プ性人造石材。
2. At least the surface layer portion is composed of a resin portion and a granular stone material portion, and the resin portion of the exposed surface portion of the resin portion and the granular stone material portion that has been exposed is subjected to water jet processing. The non-slip artificial stone material is characterized in that the resin portion is relatively recessed as compared with the stone portion by cutting and removing.
【請求項3】 石材部が、粒体状の天然石、セラミック
ス、ガラスである請求項1または2記載の人造石材。
3. The artificial stone material according to claim 1, wherein the stone material portion is a granular natural stone, ceramics, or glass.
【請求項4】 樹脂材料および粒子状の石材からなる混
合物を硬化し、樹脂部および粒体状の石材部を少なくと
も片面の表面部に現出している人造石材を製造し、前記
表面部の樹脂部をウォータージェット加工により切削除
去し、樹脂部を石材部に比べて相対的に凹部とすること
を特徴とするノンスリップ性人造石材の製造法。
4. An artificial stone material in which a mixture of a resin material and a particulate stone material is hardened to expose a resin portion and a granular stone portion on at least one surface portion, and the resin of the surface portion is manufactured. A method for producing a non-slip artificial stone material, characterized in that the resin portion is cut away by water jet processing, and the resin portion is made relatively concave as compared with the stone portion.
【請求項5】 樹脂材料および粒子状の石材からなる混
合物を硬化し、樹脂部および粒体状の石材部を少なくと
も片面の表面部に現出している人造石材を製造し、その
表面を研磨した後、前記表面部の樹脂部をウォータージ
ェット加工により切削除去し、樹脂部を石材部に比べて
相対的に凹部とすることを特徴とするノンスリップ性人
造石材の製造法。
5. An artificial stone material in which a mixture of a resin material and a granular stone material is hardened to expose a resin portion and a granular stone portion on at least one surface portion, and the surface is polished. After that, the resin portion of the surface portion is cut and removed by water jet processing, and the resin portion is made to be a recess relatively to the stone portion, and a method for producing a non-slip artificial stone material.
JP26820493A 1993-09-30 1993-09-30 Artificial stone with non-slip finish/and manufacture of artificial stone Pending JPH07100816A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26820493A JPH07100816A (en) 1993-09-30 1993-09-30 Artificial stone with non-slip finish/and manufacture of artificial stone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26820493A JPH07100816A (en) 1993-09-30 1993-09-30 Artificial stone with non-slip finish/and manufacture of artificial stone

Publications (1)

Publication Number Publication Date
JPH07100816A true JPH07100816A (en) 1995-04-18

Family

ID=17455371

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26820493A Pending JPH07100816A (en) 1993-09-30 1993-09-30 Artificial stone with non-slip finish/and manufacture of artificial stone

Country Status (1)

Country Link
JP (1) JPH07100816A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999036371A1 (en) * 1998-01-16 1999-07-22 Doppel Co., Ltd. Non-slip artificial stone
WO2000047427A1 (en) * 1999-02-09 2000-08-17 Silena Gaggini Surfaces of transparent resin in which marble or other stones are embedded
WO2002010087A1 (en) * 2000-08-01 2002-02-07 Doppel Co., Ltd. Artificial stone having non-slip property
KR20020083534A (en) * 2001-04-24 2002-11-04 연창익 Nomslip tile

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51132213A (en) * 1975-05-14 1976-11-17 Shizuharu Date Production of artificial stone
JPH03254908A (en) * 1990-01-26 1991-11-13 Matsushita Electric Works Ltd Method of treating surface of stone material
JPH05104507A (en) * 1991-10-18 1993-04-27 Inax Corp Natural stone-like building material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51132213A (en) * 1975-05-14 1976-11-17 Shizuharu Date Production of artificial stone
JPH03254908A (en) * 1990-01-26 1991-11-13 Matsushita Electric Works Ltd Method of treating surface of stone material
JPH05104507A (en) * 1991-10-18 1993-04-27 Inax Corp Natural stone-like building material

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100518047B1 (en) * 1998-01-16 2005-09-28 가부시키가이샤 도펠 Non-slip artificial stone
EP1048631A1 (en) * 1998-01-16 2000-11-02 Doppel Co. Ltd. Non-slip artificial stone
WO1999036371A1 (en) * 1998-01-16 1999-07-22 Doppel Co., Ltd. Non-slip artificial stone
CN1102547C (en) * 1998-01-16 2003-03-05 株式会社多佩尔 Non-slip artificial stone
EP1048631A4 (en) * 1998-01-16 2005-02-02 Doppel Co Ltd Non-slip artificial stone
WO2000047427A1 (en) * 1999-02-09 2000-08-17 Silena Gaggini Surfaces of transparent resin in which marble or other stones are embedded
US6951679B2 (en) 1999-02-09 2005-10-04 Silena Gaggini Surfaces of transparent resin in which marble or other stones are embedded
AU757515B2 (en) * 1999-02-09 2003-02-20 Silena Gaggini Surfaces of transparent resin in which marble or other stones are embedded
US6699415B1 (en) 1999-02-09 2004-03-02 Silena Gaggini Surfaces of transparent resin in which marble or other stones are embedded
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