JPH0699038A - Hollow fiber membrane module - Google Patents

Hollow fiber membrane module

Info

Publication number
JPH0699038A
JPH0699038A JP25486092A JP25486092A JPH0699038A JP H0699038 A JPH0699038 A JP H0699038A JP 25486092 A JP25486092 A JP 25486092A JP 25486092 A JP25486092 A JP 25486092A JP H0699038 A JPH0699038 A JP H0699038A
Authority
JP
Japan
Prior art keywords
hollow fiber
fiber membrane
potting
module
membrane module
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP25486092A
Other languages
Japanese (ja)
Other versions
JP3200190B2 (en
Inventor
Hisayoshi Yamamori
久嘉 山森
Masumi Kobayashi
真澄 小林
Kenji Watari
謙治 亘
Akira Hoshiide
明 星出
Yoshiro Nieda
義郎 贄田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP25486092A priority Critical patent/JP3200190B2/en
Publication of JPH0699038A publication Critical patent/JPH0699038A/en
Application granted granted Critical
Publication of JP3200190B2 publication Critical patent/JP3200190B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To provide a hollow fiber membrane module easy in cleaning of the hollow fiber membrane, free from the disorder or damage of the hollow fiber membrane at the time of cleaning and suitable for industrial applications. CONSTITUTION:This hollow fiber membrane module is formed from a rod like supporting body 3 which is set at the center part of the hollow fiber membrane module and is integrally fixed to potting cases 7, 7' of the potting parts on both sides of the module, a hollow fiber membrane 1 which is arranged around the supporting body 3 and is potted at both sides and a dividing and binding part 4 of the hollow fiber membrane 1 provided at an intermediate part between the potting parts 7 and 7' on both ends. In the potting parts on both sides, the bundled hollow fiber membrane 1 is potted around the supporting body 3 in divided state and in the dividing and binding part 4 provided at the middle, the bundled hollow fiber membrane 1 is divided into the number of bundles of integral multiple of the divided number of the potting parts and is bound around the supporting body.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、浄水器等に組み込んで
用いられる中空糸膜モジュールに関する。より詳しく
は、中空糸膜の洗浄に適した工業用中空糸膜モジュール
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hollow fiber membrane module used by incorporating it into a water purifier or the like. More specifically, the present invention relates to an industrial hollow fiber membrane module suitable for cleaning hollow fiber membranes.

【0002】[0002]

【従来の技術】一般に中空糸膜を利用した浄水器等の液
体濾過器は、中空糸膜の片端もしくは両端を集束し、集
束端を中空糸膜の開口部を維持した状態で樹脂固定して
容器内壁と気密状に一体化して形成されており、原水を
中空糸膜壁を透過させて濾過している。濾過方向として
は、中空糸膜の外側から内側に原水を通過させる外圧型
と、中空糸膜の内側から外側に原水を通過させる内圧型
とがあり、家庭用浄水器による水道水等上水の浄化を始
め、下水等の生活排水から産業排水の浄化等の広い範囲
で用いられている。
2. Description of the Related Art Generally, a liquid filter such as a water purifier using a hollow fiber membrane focuses one end or both ends of the hollow fiber membrane and fixes the focused end with a resin while maintaining the opening of the hollow fiber membrane. It is formed in an airtight manner integrally with the inner wall of the container, and the raw water is filtered through the hollow fiber membrane wall. As the filtration direction, there are an external pressure type that allows raw water to pass from the outside to the inside of the hollow fiber membrane, and an internal pressure type that allows the raw water to pass from the inside to the outside of the hollow fiber membrane, and tap water such as tap water from a household water purifier. It is used in a wide range of areas including purification of domestic wastewater such as sewage and industrial wastewater.

【0003】特に近年、環境保全や衛生上の観点から工
業用水の浄化に強い関心が払われており、下水、排水中
の有機物や重金属などの無機物の除去等工業用水の有効
な浄化手段としての多孔質中空糸膜を用いた浄水器の利
用が多くなりつつある。
In recent years, in particular, strong attention has been paid to the purification of industrial water from the viewpoint of environmental protection and hygiene, and it has been used as an effective purification means for industrial water such as removal of organic substances in sewage and wastewater, and inorganic substances such as heavy metals. The use of water purifiers using porous hollow fiber membranes is increasing.

【0004】このような工業用の浄水器は、水道水等上
水の浄化の場合と異なり、濾過処理時における中空糸膜
の目詰まりが大きいために、一定時間濾過処理後、空気
を送って中空糸膜を振動させて膜表面を洗浄したり、濾
過処理と逆方向に処理水を通水するなどの膜面洗浄を繰
り返し行っている。
Unlike the case of purifying tap water such as tap water, such a water purifier for industrial use has a large clogging of the hollow fiber membrane during the filtration process, and therefore air is sent after the filtration process for a certain period of time. The membrane surface is repeatedly washed by vibrating the hollow fiber membrane to wash the membrane surface, or by passing treated water in the direction opposite to the filtration treatment.

【0005】[0005]

【発明が解決しようとする課題】通常の工業用浄水器の
場合は、濾過モジュールをコンパクトにし、濾過効率を
上げようとして、単位面積あたりの中空糸本数を増や
し、中空糸を密に集束配置させて膜面積を大きくしてお
り、膜面洗浄の際に空気や通水が通過し難くなるため
に、洗浄が充分に行われず、次第に濾過効率が低下し、
モジュールの寿命を縮める原因となっている。
In the case of an ordinary industrial water purifier, the number of hollow fibers per unit area is increased and the hollow fibers are densely bundled in an attempt to make the filtration module compact and increase the filtration efficiency. Since the membrane area is increased, it becomes difficult for air and water to pass through when cleaning the membrane surface, so the washing is not performed sufficiently and the filtration efficiency gradually decreases.
This is the cause of shortening the module life.

【0006】この解決策として、モジュールケースを籠
状として膜面の洗浄を容易にする試みもなされている
が、洗浄の際、中空糸膜が密に集束されているために、
内部の膜面の洗浄が困難であり、排水処理の場合のよう
な汚れが大きな濾過処理の場合には効果が少ない。
As a solution to this problem, attempts have been made to facilitate cleaning of the membrane surface by making the module case into a basket shape. However, since the hollow fiber membranes are densely bundled during cleaning,
It is difficult to clean the inner membrane surface, and the effect is small in the case of filtration treatment with large dirt such as in the case of wastewater treatment.

【0007】また、中空糸膜をポッティング部のみで拘
束し、中間部を解放状とすることも考えられるが、工業
用モジュールは形態が大きいために取扱いが難しく、中
空糸膜の損傷が生じ易くなり、好ましくない。
It is also conceivable that the hollow fiber membrane is restrained only by the potting portion and the intermediate portion is opened, but the industrial module is large in shape and is difficult to handle, and the hollow fiber membrane is easily damaged. It is not preferable.

【0008】本発明は、このような問題を解決したもの
であり、中空糸膜面の洗浄が容易で、且つ取扱いに優れ
た工業用用途に適した中空糸膜モジュールを提供するこ
とを目的とするものである。
The present invention has solved the above problems, and an object of the present invention is to provide a hollow fiber membrane module suitable for industrial use, in which the hollow fiber membrane surface can be easily washed and which is excellent in handling. To do.

【0009】[0009]

【課題を解決するための手段】本発明の要旨は、中空糸
膜モジュールの中心部にあって両端のポッティング部の
ポッティングケースと一体的に固定されている棒状の支
持体と、該支持体の周囲に配され両端をポッティングさ
れた中空糸膜と、両端のポッティング部の中間に設けら
れた中空糸膜の分割拘束部とで形成され、両端のポッテ
ィング部においては、集束された中空糸膜が支持体の周
囲に分割状態でポッティングされており、中間に設けら
れた分割拘束部においては、集束された中空糸膜が支持
体の周囲にポッティング部の分割数の整数倍に分割され
て拘束されていることを特徴とする中空糸膜モジュール
である。
SUMMARY OF THE INVENTION The gist of the present invention is a rod-shaped support body that is integrally fixed to the potting cases of the potting portions at both ends of the hollow fiber membrane module, and the support body of the support body. Hollow fiber membranes arranged around the periphery and potted at both ends, and split restriction portions of the hollow fiber membranes provided in the middle of the potting portions at both ends are formed. It is potted in a divided state around the support, and in the split restraint portion provided in the middle, the converged hollow fiber membrane is restrained around the support by being divided into an integral multiple of the number of divisions of the potting portion. Is a hollow fiber membrane module.

【0010】本発明における濾過方式としては、全量濾
過、クロスフロー濾過、吸引濾過等の公知の濾過方式が
全て採用される。
As the filtration method in the present invention, all known filtration methods such as total volume filtration, cross-flow filtration, suction filtration and the like are adopted.

【0011】[0011]

【作用】ポッティング部の中空糸膜が分割状で集束され
ており、工業用のような大容量で集束本数の大きな場合
でも、ポッティング部の端部が緻密な集束部とならず、
膜洗浄の際にポッティング端部まで効率よく洗浄ができ
る。
[Function] The hollow fiber membrane of the potting portion is converged in a divided form, and even if the volume is large and the number of bundles is large as in industrial use, the end portion of the potting portion does not become a dense converging portion,
When cleaning the membrane, the potting edge can be efficiently cleaned.

【0012】また、モジュールの中間に多分割された拘
束部を有しており、大型のモジュールであっても、膜洗
浄等の際に、中間部の中空糸膜の乱れを生じさせずに洗
浄作用が内部にまで及ぶ。
Further, since the module has a multi-divided restraint in the middle of the module, even a large module can be washed without disturbing the hollow fiber membrane in the middle when washing the membrane. The action extends to the inside.

【0013】また、支持体及び分割拘束部が、モジュー
ル全体を構造的に保護しており、格納や持ち運び等にお
ける取扱いが極めて容易となる。
Further, the support and the split restraint structurally protect the entire module, which makes it extremely easy to handle during storage and carrying.

【0014】[0014]

【実施例】以下本発明を図面に従い詳細に説明する。The present invention will be described in detail below with reference to the drawings.

【0015】図は本発明の中空糸膜モジュールの一例を
示したものである。そして、図1はその縦断面図、図2
はポッティング部の横断面図、図3は分割拘束部の横断
面図であり、1は中空糸膜、2、2′はポッティング
部、3は支持体、4は分割拘束部、5は分割拘束板、6
は分割拘束板に設けられた拘束孔、7、7′はポッティ
ングケース、8は支持体の中空部、9はポッティングケ
ースに設けられた分割孔をそれぞれ示している。
The figure shows an example of the hollow fiber membrane module of the present invention. FIG. 1 is a longitudinal sectional view thereof, and FIG.
Is a cross-sectional view of the potting portion, FIG. 3 is a cross-sectional view of the split restraint portion, 1 is a hollow fiber membrane, 2 is a potting portion, 2 is a support, 4 is a split restraint portion, 5 is a split restraint portion. Board, 6
Is a restraint hole provided in the split restraint plate, 7, 7'is a potting case, 8 is a hollow portion of the support, and 9 is a split hole provided in the potting case.

【0016】図1において、棒状の支持体3は、中空糸
膜モジュールの中心部に位置しており、集束された中空
糸膜1の両端部に形成されているポッティング部2、
2′のポッティングケース7、7′と固定され一体的に
形成されている。この支持体3は、中空糸膜モジュール
の形態を維持し得る強度を有していれば材質を問わない
が、酸やアルカリ成分を含む液体の浄化が前提であり、
その観点からは、耐薬品性があり錆等の発生がないプラ
スチックで形成されているのが好ましく、断面形状とし
ては、円形、正方形、矩形など棒状であれば差し支えな
い。
In FIG. 1, a rod-shaped support 3 is located at the center of the hollow fiber membrane module, and potting portions 2 are formed at both ends of the bundled hollow fiber membrane 1.
It is fixed and integrally formed with the 2'potting case 7, 7 '. The support 3 may be made of any material as long as it has a strength capable of maintaining the shape of the hollow fiber membrane module, but it is premised on purification of a liquid containing an acid or alkali component,
From this point of view, it is preferably formed of a plastic that is chemically resistant and does not cause rust and the like, and the cross-sectional shape may be a rod shape such as a circle, a square, or a rectangle.

【0017】なお、この棒状の支持体3を円筒形などの
管状とし、中空部8を浄水の流路として利用することも
可能である。
It is also possible to make the rod-shaped support 3 into a tubular shape such as a cylindrical shape and use the hollow portion 8 as a flow path for purified water.

【0018】中空糸膜1は、支持体3の周囲に配されて
おり、両端部が集束され、その集束端が支持体3の周囲
に分割された状態でポッティングされている。この場合
の分割は、ポッティングケース7を図2に示したような
分割孔9を有したものとすることにより容易になし得
る。また分割数は、図2においては4分割状態を示して
いるが必要に応じ適宜設定すればよい。また、本発明の
中空糸膜モジュールにおいて用いられる中空糸膜1とし
ては、一般の浄水用等に用いられているポリエチレン
系、ポリプロピレン系、ポリスルフォン系など任意の膜
質のものが用いられる。
The hollow fiber membrane 1 is arranged around the support body 3, both ends thereof are converged, and the converging ends are potted in a state of being divided around the support body 3. The division in this case can be easily performed by providing the potting case 7 with the division hole 9 as shown in FIG. Although the number of divisions is shown in FIG. 2 in the state of four divisions, it may be set appropriately as necessary. Further, as the hollow fiber membrane 1 used in the hollow fiber membrane module of the present invention, those having any film quality such as polyethylene type, polypropylene type and polysulfone type used for general water purification are used.

【0019】ポッティングケース7の材質、ポッティン
グ材として用いられる樹脂、ポッティングの手法等につ
いては、一般に用いられている中空糸膜モジュールのポ
ッティングに準ずればよく特に制約を受けない。
The material of the potting case 7, the resin used as the potting material, the potting method, and the like are not particularly limited as long as they are in accordance with the potting of the generally used hollow fiber membrane module.

【0020】本発明の中空糸膜モジュールにおいては、
図1に示したように両端のポッティング部2、2′の中
間に分割拘束部4が設けられており、分割されてポッテ
ィングされている中空糸膜1が更に分割された状態で個
々に拘束されている。図3は、分割拘束部4の一例を示
したものであり、分割拘束板5には、ポッティング部4
の分割孔9の3倍にあたる12個の拘束孔6が支持体3
を取り巻くようにして設けられており、ポッティング部
4において4分割されている中空糸膜1がそれぞれ3等
分され、全体として12等分された状態で拘束孔6によ
って拘束されている。
In the hollow fiber membrane module of the present invention,
As shown in FIG. 1, a split restraint portion 4 is provided in the middle of the potting portions 2 and 2 ′ at both ends, and the hollow fiber membrane 1 that is split and potted is restrained individually in a further split state. ing. FIG. 3 shows an example of the split constraining portion 4, and the split constraining plate 5 has a potting portion 4
The 12 constraining holes 6 which are three times as large as the dividing holes 9 of
The hollow fiber membranes 1 that are provided so as to surround each of them are divided into four equal parts in the potting portion 4, and each of the hollow fiber membranes 1 is divided into 12 equal parts as a whole and is restricted by the restriction holes 6.

【0021】この拘束孔6の孔数は、分割孔9の整数倍
の範囲で必要に応じて設定すればよく、また、この分割
拘束板5の孔数は必ずしも中空糸膜1の分割数に合わせ
る必要はなく、分割拘束板5に予め多数の拘束孔6を設
けておき、必要数の分割拘束孔6を使用することも可能
である。
The number of the constraining holes 6 may be set as necessary within the range of an integral multiple of the number of the dividing holes 9, and the number of the dividing constraining plates 5 is not necessarily the number of dividing the hollow fiber membrane 1. It is not necessary to match them, and it is also possible to provide a large number of restraint holes 6 in the divided restraint plate 5 in advance and use the necessary number of divided restraint holes 6.

【0022】分割拘束板5の形状としては、図3に示さ
れているような四角形の他、円形、三角形、楕円形、多
角形など任意の形状のものが使用可能である。また材質
としては、前述した支持体3やポッティングケース7と
同様な理由からプラスチック製のものが好ましく、支持
体3と強固に接合一体化されているのが好ましい。
As the shape of the divided constraining plate 5, any shape such as a circle, a triangle, an ellipse, and a polygon can be used in addition to the quadrangle as shown in FIG. The material is preferably made of plastic for the same reason as the support 3 and the potting case 7 described above, and is preferably firmly joined and integrated with the support 3.

【0023】また、本発明においては、中空糸膜モジュ
ールを形成している中空糸膜1部分の外周全面をネット
状物で被覆しておくことにより、中空糸膜1の乱れをよ
り効果的に防ぐことができる。
Further, in the present invention, by covering the entire outer periphery of the hollow fiber membrane 1 portion forming the hollow fiber membrane module with a net-like material, the disturbance of the hollow fiber membrane 1 can be more effectively performed. Can be prevented.

【0024】[0024]

【発明の効果】本発明の中空糸膜モジュールは、端部で
集束された中空糸膜が分割状でポッティングされてお
り、更に中間部が多数分割されて拘束されているため
に、工業用等の繰り返し洗浄が必要なモジュールとして
用いた際、膜洗浄効率が大きく、しかも、大型モジュー
ルであっても中空糸膜の乱れが小さく、膜損傷の少ない
モジュールとなる。
INDUSTRIAL APPLICABILITY The hollow fiber membrane module of the present invention is industrially used because the hollow fiber membranes bundled at the ends are potted in a divided shape, and the middle portion is divided into a plurality of pieces and constrained. When it is used as a module requiring repeated washing, the membrane cleaning efficiency is high, and even a large module, the disorder of the hollow fiber membrane is small and the membrane is less damaged.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の中空糸膜モジュールの一例を示した縦
断面図である。
FIG. 1 is a vertical cross-sectional view showing an example of a hollow fiber membrane module of the present invention.

【図2】本発明の中空糸膜モジュールのポッティング部
の横断面図である。
FIG. 2 is a cross-sectional view of a potting portion of the hollow fiber membrane module of the present invention.

【図3】本発明の中空糸膜モジュールの分割拘束部の横
断面図である。
FIG. 3 is a cross-sectional view of a split restraint portion of the hollow fiber membrane module of the present invention.

【符号の説明】[Explanation of symbols]

1 中空糸膜 2、2′ ポッティング部 3 支持体 4 分割拘束部 5 分割拘束板 6 分割拘束板に設けられた拘束孔 7、7′ ポッティングケース 8 支持体の中空部 9 ポッティングケースに設けられた分割孔 1 hollow fiber membrane 2 2'potting part 3 support 4 split restraint part 5 split restraint plate 6 restraint hole provided in split restraint plate 7, 7'potting case 8 hollow part of support 9 provided in potting case Dividing hole

───────────────────────────────────────────────────── フロントページの続き (72)発明者 星出 明 東京都中央区京橋二丁目3番19号 三菱レ イヨン株式会社内 (72)発明者 贄田 義郎 東京都中央区京橋二丁目3番19号 三菱レ イヨン株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Akira Hoshide Akira Hoshide 2-3-19 Kyobashi, Chuo-ku, Tokyo Mitsubishi Rayon Co., Ltd. (72) Inventor Yoshiro Sakata 2-3-3 Kyobashi, Chuo-ku, Tokyo Within Mitsubishi Rayon Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 中空糸膜モジュールの中心部にあって両
端のポッティング部のポッティングケースと一体的に固
定されている棒状の支持体と、該支持体の周囲に配され
両端をポッティングされた中空糸膜と、両端のポッティ
ング部の中間に設けられた中空糸膜の分割拘束部とで形
成され、両端のポッティング部においては、集束された
中空糸膜が支持体の周囲に分割状態でポッティングされ
ており、中間に設けられた分割拘束部においては、集束
された中空糸膜が支持体の周囲にポッティング部の分割
数の整数倍に分割されて拘束されていることを特徴とす
る中空糸膜モジュール。
1. A rod-shaped support body which is integrally fixed to potting cases of potting portions at both ends of a hollow fiber membrane module, and a hollow which is arranged around the support body and potted at both ends. It is formed of a fiber membrane and a split restraint portion of the hollow fiber membrane provided in the middle of the potting portions at both ends. At the potting portions at both ends, the bundled hollow fiber membranes are potted in a divided state around the support. In the split restraint portion provided in the middle, the bundled hollow fiber membrane is restrained around the support by being divided into an integral multiple of the number of divisions of the potting portion. module.
【請求項2】 棒状の支持体が、ポッティング部の端部
に開口端を有した状態で管状に形成されている請求項1
記載の中空糸膜モジュール
2. The rod-shaped support body is formed in a tubular shape with an open end at the end of the potting portion.
Hollow fiber membrane module described
JP25486092A 1992-09-24 1992-09-24 Hollow fiber membrane module Expired - Fee Related JP3200190B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25486092A JP3200190B2 (en) 1992-09-24 1992-09-24 Hollow fiber membrane module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25486092A JP3200190B2 (en) 1992-09-24 1992-09-24 Hollow fiber membrane module

Publications (2)

Publication Number Publication Date
JPH0699038A true JPH0699038A (en) 1994-04-12
JP3200190B2 JP3200190B2 (en) 2001-08-20

Family

ID=17270850

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25486092A Expired - Fee Related JP3200190B2 (en) 1992-09-24 1992-09-24 Hollow fiber membrane module

Country Status (1)

Country Link
JP (1) JP3200190B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2005042133A1 (en) * 2003-10-30 2007-04-26 三菱レイヨン株式会社 Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
US7294267B2 (en) 2002-09-27 2007-11-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, membrane filtration device using the same and method of operating the same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7294267B2 (en) 2002-09-27 2007-11-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, membrane filtration device using the same and method of operating the same
US7491329B2 (en) 2002-09-27 2009-02-17 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, membrane filtration device using the same and method of operating the same
JPWO2005042133A1 (en) * 2003-10-30 2007-04-26 三菱レイヨン株式会社 Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
US7922902B2 (en) 2003-10-30 2011-04-12 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
US8075773B2 (en) 2003-10-30 2011-12-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
JP4907992B2 (en) * 2003-10-30 2012-04-04 三菱レイヨン株式会社 Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
US8241502B2 (en) 2003-10-30 2012-08-14 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method
US8636904B2 (en) 2003-10-30 2014-01-28 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module, hollow fiber membrane module unit, and water treatment method

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