JPH0686637A - Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production - Google Patents

Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production

Info

Publication number
JPH0686637A
JPH0686637A JP5173028A JP17302893A JPH0686637A JP H0686637 A JPH0686637 A JP H0686637A JP 5173028 A JP5173028 A JP 5173028A JP 17302893 A JP17302893 A JP 17302893A JP H0686637 A JPH0686637 A JP H0686637A
Authority
JP
Japan
Prior art keywords
cocoa
chocolate
alkali
cacao
flavor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5173028A
Other languages
Japanese (ja)
Inventor
Toshio Takemori
俊雄 竹森
Toshinobu Tsurumi
利信 鶴見
Masanori Ito
雅範 伊藤
Tatsuya Kamiwaki
達也 上脇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lotte Co Ltd
Original Assignee
Lotte Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lotte Co Ltd filed Critical Lotte Co Ltd
Priority to JP5173028A priority Critical patent/JPH0686637A/en
Priority to KR1019940000727A priority patent/KR950002601A/en
Publication of JPH0686637A publication Critical patent/JPH0686637A/en
Priority to US08/220,224 priority patent/US5635183A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a chocolate having lowered sweetness and improved taste and flavor to enable the improvement in the concentration power making use of the aromatic cacao fragrance by improving and promoting the taste and flavor of cacao useful as a main raw material for chocolate. CONSTITUTION:Shells and germs are removed from raw cacao beans or half- roasted cacao beans and the obtained cacao nib is mixed and reacted with an alkali under agitation to effect the alkali-treatment of the cacao nib. The treated nib is dried and roasted to prepare cacao nib having improved taste and flavor, a sweetness-lowering effect and a concentration improving effect. A chocolate prepared by using the cacao nib having the sweetness-lowering effect and the concentration improving effect can be prepared by conventional process from a cacao mass produced by crushing and grinding the alkali-treated cacao nib.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、チョコレートの主原料
であるカカオの香味を改良すると共に、香味を増強した
カカオを用いて、芳香なカカオ感を生かし、しかも集中
度の向上にも役立ち得る、甘味の低減されたチョコレー
トおよびその製造方法に関する。
INDUSTRIAL APPLICABILITY The present invention improves the flavor of cocoa, which is the main raw material of chocolate, and makes use of the cocoa with enhanced flavor to bring out the aromatic cocoa sensation and also helps to improve the concentration. , A chocolate with reduced sweetness and a method for producing the same.

【0002】[0002]

【従来の技術】チョコレートの製造を目的として、従来
カカオのアルカリ処理が行われた例はない。別の目的の
ために、カカオの処理方法として、アルカリ処理が行わ
れたことはあるが、これは概して、ココアパウダーの香
味や色調、水に対する分散性等を改良する目的で行われ
るものである。
2. Description of the Related Art For the purpose of producing chocolate, there has been no conventional case where cacao is subjected to alkali treatment. For another purpose, as a method for treating cocoa, alkali treatment has been performed, but this is generally performed for the purpose of improving the flavor and color tone of cocoa powder, dispersibility in water and the like. .

【0003】また、前記カカオのアルカリ処理が、ココ
ア以外の用途で用いられている例としては、カカオの殺
菌の目的で、弱アルカリ性塩水溶液を用いて処理する試
み(特公平2−291233号公報)、低級カカオ豆の
香味改良の目的でアンモニアを用いて有機酸を中和する
試み(特公昭61−56975号公報)、および食品原
料用チョコレート(プリンやゼリーに用いられる)の水
分散性を高めるためにアルカリ処理を行う試み(特公昭
61−10094号公報)等を挙げることができる。
Further, as an example in which the cacao alkali treatment is used for purposes other than cocoa, an attempt is made to treat the cacao with a weak alkaline salt aqueous solution (Japanese Patent Publication No. 2-291233). ), An attempt to neutralize organic acids with ammonia for the purpose of improving the flavor of lower cocoa beans (Japanese Patent Publication No. 61-56975), and the water dispersibility of chocolate for food ingredients (used for pudding and jelly). For example, an attempt to carry out alkali treatment to increase the temperature (Japanese Patent Publication No. 61-10094) can be mentioned.

【0004】一方、特定pHのカカオニブまたはカカオ
マスに、所定のアルカリ、還元糖、アミノ酸、タンニン
を添加して焙炒する方法(特公昭53−31493号公
報)が提案されている。しかし、この方法では、予め原
料のカカオ豆の組成分を測定して、必要な前記添加物質
の所定量に対して添加するため、作業が複雑化する。ま
た、この場合においても、香味を十分に改良することは
できない。
On the other hand, a method has been proposed in which a predetermined alkali, reducing sugar, amino acid and tannin are added to cacao nibs or cacao masses having a specific pH and roasted (Japanese Patent Publication No. 53-31493). However, in this method, the composition of the raw material cocoa beans is measured in advance and added to a predetermined amount of the required additional substance, which complicates the work. Also in this case, the flavor cannot be sufficiently improved.

【0005】これらの従来技術は、高級なカカオ豆の豊
かな香気を更に引き出すと共に、芳香なカカオ感を生か
し、しかも集中度の向上にも役立ち得る、甘味の低減さ
れたチョコレートを得る本発明の試みとは目的が異な
り、さらに操作の簡便さや香気の発現等においても十分
なものではないと考えられる。
[0005] These conventional techniques further bring out the rich aroma of high-quality cocoa beans, utilize the aromatic cocoa sensation, and can also serve to improve the degree of concentration to obtain chocolate with reduced sweetness. The purpose is different from the trial, and it is considered that it is not sufficient in terms of easiness of operation and expression of aroma.

【0006】なお、従来技術において、集中度を向上さ
せ得るチョコレートについては、未だ提案され、あるい
は実施されていない。
[0006] In the prior art, chocolate that can improve the degree of concentration has not yet been proposed or implemented.

【0007】[0007]

【発明が解決しようとする課題】そこで本発明は、チョ
コレートの主原料であるカカオの香味を改良し、更に香
味の増強されたカカオを用い、芳香なカカオ感を生か
し、しかも甘味の低減されたチョコレートを提供すると
共に、特に集中度を向上させ得る香味を増強させたカカ
オを使用することにより、集中度を向上させ得るチョコ
レートを提供することを目的とする。
SUMMARY OF THE INVENTION Therefore, the present invention improves the flavor of cocoa, which is the main raw material of chocolate, and further uses cocoa with an enhanced flavor to bring out the aromatic cocoa sensation and reduce the sweetness. It is an object of the present invention to provide a chocolate which can improve the degree of concentration, by using cocoa having enhanced flavor which can enhance the degree of concentration, in addition to providing chocolate.

【0008】[0008]

【課題を解決するための手段】前記の目的を達成するた
め、本発明によれば、生カカオ豆または半焙炒したカカ
オ豆のカカオニブをアルカリ処理してなる、チョコレー
トに用いる集中度を向上させ得るカカオニブの香味の改
良並びに増強方法が提供される。
In order to achieve the above object, according to the present invention, the concentration of the raw cocoa beans or semi-roasted cocoa nibs treated with alkali is improved, and the concentration of chocolate is improved. Methods of improving and enhancing the flavor of the resulting cocoa nibs are provided.

【0009】また、本発明によれば、生カカオ豆または
半焙炒したカカオ豆からシェルおよびジャームを除去し
てカカオニブとし、これにアルカリを添加し、撹拌、反
応させてアルカリ処理し、更に乾燥、焙炒したカカオニ
ブを調製し、このアルカリ処理したカカオニブを粉砕、
摩砕してカカオマスとし、これを原料として常法により
チョコレートを製造することを特徴とする、集中度を向
上させ得る香味を改良並びに増強させたカカオニブを用
いるチョコレートの製造方法が提供される。
Further, according to the present invention, shells and germs are removed from raw cocoa beans or semi-roasted cocoa beans to obtain cocoa nibs, and an alkali is added to the cocoa nibs, and the mixture is stirred, reacted and alkali-treated, and then dried. , Prepare roasted cocoa nibs, crush the alkali-treated cocoa nibs,
A method for producing chocolate using cocoa nibs having an improved and enhanced flavor capable of improving the concentration, characterized by grinding chocolate to produce cocoa mass and using the raw material to produce chocolate.

【0010】更に、本発明によれば、生カカオ豆または
半焙炒したカカオ豆からシェルおよびジャームを除去し
て得られるカカオニブにアルカリを添加し、撹拌、反応
させてアルカリ処理し、更に乾燥、焙炒した集中度を向
上させ得る香味を改良並びに増強させたカカオニブを粉
砕、摩砕したカカオマスと、カカオマス以外の通常のチ
ョコレート原料とからなることを特徴とする、集中度を
向上させ得る香味を改良並びに増強させたカカオニブを
用いたチョコレートが提供される。
Further, according to the present invention, an alkali is added to cacao nibs obtained by removing shells and germs from raw cacao beans or semi-roasted cacao beans, and the mixture is stirred, reacted and alkali-treated, and further dried, A cocoa nib that has been crushed and ground to enhance and enhance the flavor that can improve the concentration of roasted cocoa, and a cocoa mass that is ground and ground, and a normal chocolate ingredient other than cocoa mass, which can improve the concentration. Chocolates with improved and enhanced cocoa nibs are provided.

【0011】本発明においては、前記のカカオニブのア
ルカリ処理に用いられるアルカリは、炭酸カリウム、炭
酸ナトリウム、重炭酸カリウム、重炭酸ナトリウム、水
酸化アンモニウム、炭酸アンモニウム、酸化マグネシウ
ム、炭酸マグネシウム等の種々のアルカリを使用するこ
とができるが、従来のカカオのアルカリ処理に使用され
たことのない水酸化カルシウムが特に好適である。
In the present invention, the alkali used for the alkali treatment of cocoa nibs may be various ones such as potassium carbonate, sodium carbonate, potassium bicarbonate, sodium bicarbonate, ammonium hydroxide, ammonium carbonate, magnesium oxide and magnesium carbonate. Alkali can be used, but calcium hydroxide, which has never been used for conventional alkali treatment of cocoa, is particularly preferred.

【0012】本発明において使用するカカオ豆の種類、
豆の大きさ、状態(醗酵の程度、水分含量、有機酸濃度
等)は、通常のチョコレートの原料として使用し得るも
のであれば、特に限定されない。しかしながら、本発明
は低級のカカオ豆や醗酵不十分の不良豆を改善すること
を意図するものではなく、高級カカオ豆の香気を積極的
に引き出すものであるので、良質のカカオ豆を用いた方
がより好ましい結果が得られる。
The types of cocoa beans used in the present invention,
The size and state of the beans (degree of fermentation, water content, organic acid concentration, etc.) are not particularly limited as long as they can be used as a raw material for ordinary chocolate. However, the present invention is not intended to improve low-grade cocoa beans or poor beans that are insufficiently fermented, and is intended to positively bring out the aroma of high-grade cocoa beans. More favorable results are obtained.

【0013】カカオニブのアルカリ処理に際し、アルカ
リ、特に水酸化カルシウムの添加量は、カカオニブに対
して0.2〜3.0重量%、好ましくは1.0〜2.0
重量%とする。0.2%以下の場合においては、好まし
い香気の発現や不快臭の低減効果が十分に期待できず、
3.0%以上においては、アルカリ臭が強く発生するた
めに、香気のバランスが崩れてしまう。
When the cocoa nibs are treated with alkali, the amount of alkali, particularly calcium hydroxide, added is 0.2 to 3.0% by weight, preferably 1.0 to 2.0, based on the cocoa nibs.
Weight% In the case of 0.2% or less, it is not possible to sufficiently expect a preferable aroma expression and an unpleasant odor reducing effect,
At 3.0% or more, a strong alkaline odor is generated, and the balance of aroma is lost.

【0014】また、アルカリ、特に水酸化カルシウム
と、カカオニブとの反応は、好ましくは水の存在する状
態で行う。反応条件としては、温度は40〜210℃、
圧力は大気圧〜5気圧が好ましい。反応する場合は、乾
燥したニブと粉体のアルカリとを単に混ぜるのではな
く、水の存在下で温度と圧力をかけて反応性を高めた方
が好ましい。
The reaction of the cacao nibs with alkali, especially calcium hydroxide, is preferably carried out in the presence of water. The reaction conditions include a temperature of 40 to 210 ° C,
The pressure is preferably atmospheric pressure to 5 atm. When reacting, it is preferable to increase the reactivity by applying temperature and pressure in the presence of water, rather than simply mixing the dried nib and the powdered alkali.

【0015】アルカリ処理反応終了後のカカオニブは、
乾燥、焙炒、粉砕、摩砕からなる一般のカカオマスの製
造方法に従ってカカオマスとする。その後も、一般的な
チョコレートの製法に準じてチョコレートを製造する。
The cocoa nibs after completion of the alkaline treatment reaction are
A cocoa mass is prepared according to a general method for producing cocoa mass, which comprises drying, roasting, crushing and grinding. After that, chocolate is manufactured according to a general chocolate manufacturing method.

【0016】なお、本発明においては、アルカリ処理を
ローストの前に行うか、後に行うかも重要な特徴であ
る。アルカリ処理をローストの前に行うと、アルカリと
香気成分の前駆体とが反応し、香気成分の前駆物質を化
学反応させた後のロースト工程中に香気の発現が認めら
れ、香気の発現機構であるメイラード反応がより進み易
いpHに保たれる。これに対して、アルカリ処理をロー
ストの後に行うと、アルカリと香気成分自体とが反応す
ることとなり、ローストによって発現した香気成分が、
アルカリ処理によってかなり違った香気成分に変化して
しまい、芳香なカカオ感や集中力を向上させ得る香味は
得られない。
In the present invention, it is an important feature whether the alkali treatment is performed before or after roasting. When the alkali treatment is performed before roasting, the alkali and the precursor of the aroma component react with each other, and the aroma expression is observed during the roasting step after the chemical reaction of the aroma component precursor is observed. A certain Maillard reaction is maintained at a pH at which it can proceed more easily. On the other hand, when the alkali treatment is performed after roasting, the alkali and the aroma component itself react with each other, and the aroma component expressed by the roast,
Alkali treatment changes the fragrance component to a considerably different level, and it is not possible to obtain a flavor that can improve the aromatic cocoa sensation and concentration.

【0017】[0017]

【作用】本発明によれば、チョコレートの主原料である
カカオの香味が改良され、香味を増強することによっ
て、集中度を向上し得ると共に芳香なカカオ感を生かし
たチョコレートが提供されるが、これはアルカリ、特に
水酸化カルシウムにより、カカオ豆の構造を構成する成
分であるヘミセルロースの水解、蛋白質や澱粉の加水分
解が起こり、これに伴ってアミノ酸、糖のような香気の
前駆物質が遊離の状態となって増加し、香気の発現量が
増加するためと推定される。
According to the present invention, the flavor of cocoa, which is the main raw material of chocolate, is improved, and by enhancing the flavor, the concentration of the chocolate can be improved and the chocolate having an aromatic cocoa feeling is provided. This is because alkali, especially calcium hydroxide, causes the hydrolysis of hemicellulose, which is a component that constitutes the structure of cocoa beans, and the hydrolysis of proteins and starch, which accompanies the release of fragrance precursors such as amino acids and sugars. It is presumed that this is due to an increase in the state and an increase in the expression level of aroma.

【0018】このようなアルカリ処理したカカオ豆をチ
ョコレートに用いると、カカオ本来の香気成分が増加す
ると共に不快臭成分が減少し、更に甘味を低減した総合
的に優れた嗜好性を有するチョコレートを得ることがで
きる。
When such an alkali-treated cocoa bean is used in chocolate, the original aroma component of cocoa is increased and the unpleasant odor component is reduced, and further the sweetness is reduced to obtain a chocolate having an excellent overall taste. be able to.

【0019】また、この様にして改良並びに増強された
香味は、集中度の向上に貢献し得ることが実験の結果か
ら明らであり、従って本発明により香味を改良並びに増
強したカカオニブを使用してチョコレートを製造するこ
とにより、集中度を向上し得るチョコレートを得ること
ができる。
Further, it is clear from the results of experiments that the flavor thus improved and enhanced can contribute to the improvement of the concentration, and therefore cocoa nibs having the flavor improved and enhanced according to the present invention are used. By producing chocolate by using the above method, it is possible to obtain chocolate that can improve the degree of concentration.

【0020】[0020]

【発明の効果】本発明によれば、チョコレートの主原料
であるカカオの香味を改良並びに増強することができ、
更に香味の増強したカカオを用い、芳香なカカオ感を生
かし、しかも甘味の低減されたチョコレートを得ること
ができると共に、集中度を向上させ得る香味を増強させ
たカカオを使用することにより、集中度を向上させ得る
チョコレートを得ることができる。
According to the present invention, it is possible to improve and enhance the flavor of cacao which is the main raw material of chocolate.
Furthermore, by using a cacao with an enhanced flavor, it is possible to obtain chocolate with a reduced sweetness while making the most of the aromatic cacao feel, and by using cacao with an enhanced flavor that can improve the degree of concentration, It is possible to obtain chocolate that can improve the.

【0021】[0021]

【実施例】以下の実施例により、本発明を更に具体的に
説明するが、本発明は以下の実施例にのみ限定されるも
のではない。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to the following examples.

【0022】実施例1(水酸化カルシウム処理カカオニ
ブの製造) カカオニブに130℃で1気圧の圧力下で20分間、
1.5%水酸化カルシウムを加えて撹拌を行った。反応
終了後、乾燥、焙炒を行い、水酸化カルシウム処理カカ
オニブを製造した。
Example 1 (Calcium hydroxide treated cacao ni
Production of bu) cocoa nibs at 130 ° C. under a pressure of 1 atm for 20 minutes,
1.5% calcium hydroxide was added and the mixture was stirred. After completion of the reaction, drying and roasting were performed to produce calcium hydroxide-treated cocoa nibs.

【0023】試験例1 本発明のチョコレートは、従来のチョコレートと比較す
ると、好ましい香気が増強されている一方で、悪い香り
が抑えられているのが特徴である。実際に、実施例1の
アルカリ処理したカカオマスと、無処理のカカオマスと
を試料として、ガスクロ分析を行った結果を図1に示
す。カカオ本来の香気成分であるピラジン類が、2倍以
上に増えた一方で、不快臭として知られている揮発性の
有機酸類が、約4分の1迄抑えられていることが分っ
た。
Test Example 1 The chocolate of the present invention is characterized in that a favorable aroma is enhanced and a bad aroma is suppressed as compared with conventional chocolate. FIG. 1 shows the results of gas chromatographic analysis using the alkali-treated cocoa mass and the untreated cocoa mass of Example 1 as samples. It was found that the amount of pyrazines, which is the original fragrance component of cocoa, increased more than double, while the amount of volatile organic acids known as unpleasant odor was suppressed to about 1/4.

【0024】実施例2(水酸化カルシウム処理カカオニ
ブを用いたチョコレートの製造) 実施例1の水酸化カルシウム処理カカオニブを摩砕した
カカオマス、および砂糖、全脂粉乳、ココアバターの一
部を十分ミキシングし、その後ロールミルで粉砕し、更
にココアバターと乳化剤、香料を添加し、コンチングを
行ってチョコレート生地を製造した。更に、その生地を
成型し、チョコレート製品とした。
Example 2 (Calcium hydroxide treated cacao ni
Production of chocolate using bubu ) cocoa mass obtained by grinding the cacao nib treated with calcium hydroxide of Example 1, sugar, whole milk powder, and a part of cocoa butter were thoroughly mixed, and then pulverized by a roll mill, and further cocoa butter An emulsifier and a fragrance were added and conching was performed to produce a chocolate dough. Further, the dough was molded into a chocolate product.

【0025】比較例1 通常のカカオマスを用いた以外は、本発明により製造し
た実施例2のチョコレートと同じ配合として、同様の方
法によりチョコレートを製造し、チョコレート製品を得
た。
COMPARATIVE EXAMPLE 1 A chocolate product was obtained by the same method as that for the chocolate of Example 2 produced according to the present invention except that ordinary cocoa mass was used, and chocolate was produced by the same method.

【0026】試験例2 本発明による実施例1のチョコレートと、通常のカカオ
マスを用いた比較例1のチョコレートとを試料とし、チ
ョコレートの嗜好調査をパネラー(女子高校生200
名)に対して行った。結果を図2に示す。
Test Example 2 The chocolate of Example 1 according to the present invention and the chocolate of Comparative Example 1 using ordinary cacao mass were used as samples, and a chocolate preference survey was conducted by a panelist (200 high school girls).
First name). The results are shown in Figure 2.

【0027】図2から分るように、本発明によるチョコ
レートは、おいしさ、香りのいずれにおいても高く支持
された。更に、甘さも控え目であることが分った。
As can be seen from FIG. 2, the chocolate according to the present invention was highly supported in both the taste and the aroma. Furthermore, the sweetness was found to be modest.

【0028】試験例3 本発明による実施例1のチョコレートと、通常のカカオ
マスを用いた比較例1のチョコレートとを試料とし、チ
ョコレートの香りによる集中度の向上試験をパネラー
(大学生20人)に対して行った。
Test Example 3 Using the chocolate of Example 1 according to the present invention and the chocolate of Comparative Example 1 using ordinary cacao mass as a sample, a test for improving the degree of concentration due to the scent of chocolate was given to panelists (20 university students). I went.

【0029】集中度は、勉強する時や各作業をする時
に、その能率を向上させるための重要な精神作用の一つ
である。集中の度合、いわゆる集中度は、その時の脳波
(α波)を測定することにより解析できる。脳波は、図
3に示すように、頭部に取り付けた電極によって、脳活
動時に発生する微弱な電気を測定することにより計測す
る。そして、集中度の測定に際しては、前頭葉部分(図
3中に示す1の部分)と後頭葉部分(図3中に示す9の
部分)から測定される脳波(α波)の波形の相互相関関
数を計算し、最初のピークまでの時間をτmとして求め
る(図4参照)。なお、図4において、集中度が向上す
ると、このτmは小さくなる。
The degree of concentration is one of the important psychological actions for improving the efficiency of studying or performing each work. The degree of concentration, that is, the degree of concentration can be analyzed by measuring the electroencephalogram (α wave) at that time. As shown in FIG. 3, the electroencephalogram is measured by measuring the weak electricity generated during brain activity by means of electrodes attached to the head. Then, in measuring the degree of concentration, the cross-correlation function of the waveform of the electroencephalogram (α wave) measured from the frontal lobe portion (portion 1 shown in FIG. 3) and the occipital lobe portion (portion 9 shown in FIG. 3) Is calculated and the time to the first peak is determined as τm (see FIG. 4). In FIG. 4, when the degree of concentration is improved, this τm becomes smaller.

【0030】実施例1と比較例1のチョコレートの香り
をそれぞれ嗅いだ後、パネラーの脳波を測定し、その結
果を図5に示す。図5からも明らかなように、本発明に
よる実施例1のチョコレートの香りを嗅いだ時の40.
0τmに対して、比較例1のチョコレートの香りを嗅い
だ時は、44.3τmと値が大きく、実施例1のチョコ
レートの香りを嗅いだ時の方が集中度が向上しているこ
とが分かる。なお、図5中の右に示す2つのグラフは、
いずれのチョコレートの香りをも嗅いでいないパネラー
の脳波を測定したもので、非集中時の指標として安静閉
眼時の脳波を、集中している時の指標として暗算時の脳
波をそれぞれ測定してτmの値を求めたものである。か
かる数値との比較によれば、実施例1のチョコレートの
香気による集中度の向上は、暗算時の39.5τmと極
めて近い数値であることが分かる。
After sniffing the chocolate scents of Example 1 and Comparative Example 1, the brain waves of the panelists were measured, and the results are shown in FIG. As is clear from FIG. 5, when the scent of chocolate of Example 1 according to the present invention was sniffed, 40.
Compared to 0τm, when the smell of the chocolate of Comparative Example 1 was sniffed, the value was as large as 44.3τm, and it was found that the concentration was improved when the smell of the chocolate of Example 1 was sniffed. . Note that the two graphs shown on the right in FIG.
We measured the EEG of a panelist who did not smell any chocolate scent, and measured the EEG at rest with eyes closed as an index for non-concentration, and the EEG at mental arithmetic as an index for concentrated τm. Is the value of. Comparing with such a numerical value, it can be seen that the improvement of the concentration degree due to the aroma of the chocolate of Example 1 is a numerical value very close to 39.5 τm at the time of mental calculation.

【0031】試験例4 本発明による実施例1のチョコレートと、比較例1のチ
ョコレートを試料とし、パネラー(女子大学生155
名)に対して英単語の校正テストを行った。表1にテス
トの例題の一部を示す。表1に示すように、校正試験は
左に正解の英単語を、右にこれと一字違いの英単語をそ
れぞれ表示し、右に表示された単語の間違いを校正させ
ることにより行った。
Test Example 4 Using the chocolate of Example 1 according to the present invention and the chocolate of Comparative Example 1 as samples, panelists (female college students 155
Proofreading test of English words was performed for (name). Table 1 shows some of the test examples. As shown in Table 1, the proofreading test was performed by displaying the correct English words on the left and the English words with a letter difference from the right, and calibrating the mistakes of the words displayed on the right.

【0032】実施例1のチョコレートと、比較例1のチ
ョコレートとをそれぞれ試食し、試食後から校正を開始
して1分毎に回答数を記録した。結果を図6に示す。図
6中の縦軸は、チョコレートを試食した後に行った校正
テストの回答数から、チョコレートを試食せずに行った
校正テストの回答数を、差し引いた数を表す。また、横
軸は回答時間である。比較例1のチョコレートを試食し
た場合に比べて、本発明による実施例1のチョコレート
を試食した場合は、回答数が試食1分後から徐々に増加
し初め、7分後の回答数の増加は、比較例1のチョコレ
ートを試食した場合の約6倍にも達するという、驚異的
な作業能率の向上が確認された。
The chocolate of Example 1 and the chocolate of Comparative Example 1 were sampled, and calibration was started after the sample was sampled, and the number of responses was recorded every minute. Results are shown in FIG. The vertical axis in FIG. 6 represents the number obtained by subtracting the number of responses of the calibration test performed without tasting chocolate from the number of responses of the calibration test performed after tasting chocolate. The horizontal axis is the response time. When the chocolate of Example 1 according to the present invention was tasted, the number of answers gradually increased from 1 minute after the tasting, compared with the case where the chocolate of Comparative Example 1 was tasted. It was confirmed that the work efficiency was astonishingly high, reaching about 6 times that when the chocolate of Comparative Example 1 was tasted.

【0033】実施例3(水酸化カルシウム処理カカオニ
ブの製造) カカオニブに、130℃で1気圧の圧力下で20分間、
1.0%水酸化カルシウムを加えて撹拌を行った。反応
終了後、乾燥、焙炒を行い、水酸化カルシウム処理カカ
オニブを製造した。
Example 3 (Calcium hydroxide treated cacao ni
Production of bubu ), to cocoa nibs, at 130 ° C. under a pressure of 1 atmosphere for 20 minutes,
1.0% calcium hydroxide was added and the mixture was stirred. After completion of the reaction, drying and roasting were performed to produce calcium hydroxide-treated cocoa nibs.

【0034】実施例4(水酸化カルシウム処理カカオニ
ブを用いたチョコレートの製造) 実施例3の水酸化カルシウム処理カカオニブを摩砕した
カカオマス、および砂糖、全脂粉乳、ココアバターの一
部を十分ミキシングし、その後ロールミルで粉砕し、更
にココアバターと乳化剤、香料を添加し、コンチングを
行ってチョコレート生地を製造した。更に、その生地を
成型し、チョコレート製品とした。
Example 4 (Calcium hydroxide treated cacao ni)
(Production of chocolate using broth) Cocoa mass obtained by grinding the cacao nibs treated with calcium hydroxide of Example 3, sugar, whole milk powder, and a part of cocoa butter were thoroughly mixed, and then pulverized by a roll mill, and further cocoa butter was added. An emulsifier and a fragrance were added and conching was performed to produce a chocolate dough. Further, the dough was molded into a chocolate product.

【0035】実施例5(炭酸カリウム処理カカオニブの
製造) カカオニブに、130℃で1気圧の圧力下で20分間、
1.0%炭酸カリウムを加えて撹拌を行った。反応終了
後、乾燥、焙炒を行い、炭酸カリウム処理カカオニブを
製造した。
Example 5 (of potassium carbonate treated cocoa nibs
Production) on cocoa nibs at 130 ° C. under 1 atm pressure for 20 minutes,
1.0% Potassium carbonate was added and stirred. After the completion of the reaction, drying and roasting were performed to produce potassium carbonate-treated cocoa nibs.

【0036】実施例6(炭酸カリウム処理カカオニブを
用いたチョコレートの製造) 実施例5の炭酸カリウム処理カカオニブを摩砕したカカ
オマス、および砂糖、全脂粉乳、ココアバターの一部を
十分ミキシングし、その後ロールミルで粉砕し、更にコ
コアバターと乳化剤、香料を添加し、コンチングを行っ
てチョコレート生地を製造した。更に、その生地を成型
し、チョコレート製品とした。
Example 6 (potassium carbonate treated cocoa nibs
Production of chocolate used) Cocoa mass obtained by grinding the potassium carbonate-treated cocoa nibs of Example 5, sugar, whole milk powder, and a part of cocoa butter were thoroughly mixed, and then pulverized by a roll mill, and further cocoa butter, an emulsifier, and a fragrance. Was added and conching was performed to produce a chocolate dough. Further, the dough was molded into a chocolate product.

【0037】試験例5 水酸化カルシウム処理により製造した実施例4のチョコ
レートと、炭酸カリウム処理により製造した実施例6の
チョコレートとを試料とし、パネラー(女子高校生10
0名)を対象にチョコレートの嗜好調査を行った。結果
を図7に示す。
Test Example 5 The chocolate of Example 4 produced by treatment with calcium hydroxide and the chocolate of Example 6 produced by treatment with potassium carbonate were used as samples, and panelists (high school girls 10
A chocolate preference survey was conducted for 0 people. The results are shown in Fig. 7.

【0038】図7から分かるように、本発明によるアル
カリ処理に用いるアルカリとしては、炭酸カリウムより
水酸化カルシウムの方が優れていた。
As can be seen from FIG. 7, calcium hydroxide was superior to potassium carbonate as the alkali used in the alkali treatment according to the present invention.

【0039】試験例6 水酸化カルシウム処理により製造した実施例4のチョコ
レートと、炭酸カリウム処理により製造した実施例6の
チョコレートとを試料とし、チョコレートの香りによる
集中度向上の測定を、パネラー(大学生20人)を対象
に試験例4と同様の方法で行った。
Test Example 6 The chocolate of Example 4 produced by calcium hydroxide treatment and the chocolate of Example 6 produced by potassium carbonate treatment were used as samples to measure the improvement in concentration due to the scent of chocolate. The same method as in Test Example 4 was performed on 20 people).

【0040】実施例4と実施例6のチョコレートの香り
をそれぞれ嗅いだ後、パネラーの脳波を測定した。その
結果を図8に示す。図8からも明らかなように、本発明
による実施例4のチョコレートの香りを嗅いだ時の方
が、39.5τmと実施例6のチョコレートの香りを嗅
いだ時の43.9τmよりも、はるかに値が小さく、集
中度が向上していることが分かる。なお、図8中の右に
示す2つのグラフは、いずれのチョコレートの香りをも
嗅いでいないパネラーの脳波を測定し、τmの値を求め
たもので、非集中時の指標として安静閉眼時の脳波を、
集中している時の指標として暗算時の脳波をそれぞれ測
定したものである。かかる数値との比較によれば、実施
例4のチョコレートの香気による集中度の向上は、暗算
時の数値である39.5τmと同数値であることが分か
る。
After sniffing the aromas of the chocolates of Examples 4 and 6, the brain waves of the panelists were measured. The result is shown in FIG. As is clear from FIG. 8, when the scent of chocolate of Example 4 according to the present invention was sniffed, it was far more than 39.5 τm and 43.9 τm when the smell of chocolate of Example 6 was sniffed. It can be seen that the value is small and the degree of concentration is improved. In addition, the two graphs shown on the right in FIG. 8 are obtained by measuring the brain waves of a panelist who does not smell any chocolate scent and calculating the value of τm. EEG,
These are the brain waves measured during mental arithmetic as an index when the user is concentrated. Comparison with such a numerical value shows that the improvement in the degree of concentration due to the aroma of the chocolate of Example 4 is the same as the numerical value at the time of mental calculation, 39.5τm.

【0041】試験例7 水酸化カルシウム処理により製造した実施例4のチョコ
レートと、炭酸カリウム処理により製造した実施例6の
チョコレートとを試料とし、パネラー(女子大生150
名)に対して英単語の校正テストを試験例4と同様の方
法で行った。結果を図9に示す。
Test Example 7 The chocolate of Example 4 produced by treatment with calcium hydroxide and the chocolate of Example 6 produced by treatment with potassium carbonate were used as samples, and panelists (150 female college students)
Name) was subjected to a proofreading test of English words in the same manner as in Test Example 4. The results are shown in Fig. 9.

【0042】図9から分るように、実施例6のチョコレ
ートに比べて、本発明による実施例4のチョコレートの
香りを嗅いだ場合の方が、回答数が有意に増加し、7分
後には実施例6のチョコレートを試食した場合の回答数
の5倍強という、画期的な作業能率の向上が確認され
た。
As can be seen from FIG. 9, compared with the chocolate of Example 6, the number of responses significantly increased when the smell of chocolate of Example 4 according to the present invention was sniffed, and after 7 minutes. A breakthrough improvement in work efficiency was confirmed, which was more than five times the number of responses when the chocolate of Example 6 was tasted.

【0043】実施例7(炭酸ナトリウム処理カカオニブ
の製造) カカオニブに、115℃で1気圧の圧力下で20分間、
1.0%炭酸ナトリウムを加えて、撹拌を行った。反応
終了後、乾燥、焙炒を行い、炭酸ナトリウム処理カカオ
ニブを製造した。
Example 7 (Sodium carbonate treated cocoa nibs
Production of cocoa nibs at 115 ° C. under a pressure of 1 atm for 20 minutes,
1.0% Sodium carbonate was added and the mixture was stirred. After completion of the reaction, drying and roasting were performed to produce sodium carbonate-treated cocoa nibs.

【0044】実施例8(炭酸ナトリウム処理カカオニブ
を用いたチョコレートの製造) 実施例7の炭酸ナトリウム処理カカオニブを摩砕したカ
カオマス、および砂糖、全脂粉乳、ココアバターの一部
を十分ミキシングし、その後ロールミルで粉砕し、更に
ココアバターと乳化剤、香料を添加し、コンチングを行
ってチョコレート生地を製造した。更に、その生地を成
型し、チョコレート製品とした。
Example 8 (Sodium carbonate treated cocoa nibs
Production of chocolate using the above) Cocoa mass obtained by grinding the sodium carbonate-treated cocoa nibs of Example 7, sugar, whole milk powder, and a part of cocoa butter were thoroughly mixed, and then pulverized by a roll mill, and further cocoa butter and an emulsifier, A chocolate material was manufactured by adding a flavor and conching. Further, the dough was molded into a chocolate product.

【0045】試験例8 水酸化カルシウム処理により製造した実施例4のチョコ
レートと、炭酸ナトリウム処理により製造した実施例8
のチョコレートとを試料とし、パネラー(女子高校生1
00名)を対象にチョコレートの嗜好調査を行った。結
果を図10に示す。
Test Example 8 Chocolate of Example 4 produced by treatment with calcium hydroxide and Example 8 produced by treatment with sodium carbonate.
Panelists (high school girls 1
A chocolate preference survey was conducted on (00 people). The results are shown in Fig. 10.

【0046】図10から分るように、本発明によるアル
カリ処理に用いるアルカリとしては、炭酸ナトリウムよ
り水酸化カルシウムの方が優れていた。
As can be seen from FIG. 10, calcium hydroxide was superior to sodium carbonate as the alkali used in the alkali treatment according to the present invention.

【0047】試験例9 水酸化カルシウム処理により製造した実施例4のチョコ
レートと、炭酸ナトリウム処理により製造した実施例8
のチョコレートとを試料とし、チョコレートの香りによ
る集中度測定を試験例4と同様の方法でパネラー(大学
生20人)に対して行った。
Test Example 9 Chocolate of Example 4 produced by treatment with calcium hydroxide and Example 8 produced by treatment with sodium carbonate
The chocolate was used as a sample, and the concentration of the chocolate was measured for the panelists (20 university students) in the same manner as in Test Example 4.

【0048】実施例4と実施例8のチョコレートの香り
をそれぞれ嗅いだ後、パネラーの脳波を測定した。その
結果を図11に示す。図11からも明らかなように、本
発明による実施例4のチョコレートの香りを嗅いだ時の
方が、実施例8のチョコレートの香りを嗅いだ時より
も、τmの値が小さく、集中度が向上していることが分
かる。なお、図11中の右に示す2つのグラフは、いず
れのチョコレートの香りをも嗅いでいないパネラーの脳
波を測定し、τmの値を求めたもので、非集中時の指標
として安静閉眼時の脳波を、集中している時の指標とし
て暗算時の脳波をそれぞれ測定したものである。かかる
数値との比較によれば、実施例4のチョコレートの香気
による集中度の向上は、39.5τmであり、暗算時と
同数値あることが分かる。
After sniffing the chocolate scents of Example 4 and Example 8, the brain waves of the panelists were measured. The result is shown in FIG. As is clear from FIG. 11, when the smell of chocolate of Example 4 according to the present invention was sniffed, the value of τm was smaller and the concentration was higher than when the smell of chocolate of Example 8 was sniffed. You can see that it is improving. In addition, the two graphs shown on the right in FIG. 11 are obtained by measuring the brain waves of a panelist who does not smell any chocolate scent and determining the value of τm. The electroencephalogram was measured by mental calculation as an index when the brain was concentrated. Comparing with such a numerical value, it can be seen that the improvement in the degree of concentration due to the aroma of the chocolate of Example 4 is 39.5 τm, which is the same value as in the mental calculation.

【0049】試験例10 本発明による実施例4のチョコレートと、実施例8のチ
ョコレートを試料とし、パネラー(女子大生150名)
に対して英単語の校正テストを試験例4と同様の方法で
行った。結果を図12に示す。実施例8に比べて、本発
明による実施例4の回答数が有意に増加し、作業能率の
向上が確認された。
Test Example 10 Using the chocolate of Example 4 according to the present invention and the chocolate of Example 8 as samples, panelists (150 female college students)
On the other hand, a proofreading test for English words was performed in the same manner as in Test Example 4. Results are shown in FIG. Compared to Example 8, the number of responses in Example 4 according to the present invention was significantly increased, and it was confirmed that the work efficiency was improved.

【0050】[0050]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】カカオマスのガスクロ分析結果を示すグラフで
ある。
FIG. 1 is a graph showing the results of gas chromatography analysis of cocoa mass.

【図2】チョコレートの嗜好調査結果を示す説明図であ
る。
FIG. 2 is an explanatory diagram showing results of a chocolate preference survey.

【図3】脳波の測定に際し頭部につける電極の配置を示
す説明図である。
FIG. 3 is an explanatory diagram showing an arrangement of electrodes attached to the head when measuring an electroencephalogram.

【図4】脳波の波形相互相関関数を示す特性線図であ
る。
FIG. 4 is a characteristic diagram showing a waveform cross-correlation function of an electroencephalogram.

【図5】脳波測定による集中度の向上を示すグラフであ
る。
FIG. 5 is a graph showing an improvement in concentration by measuring an electroencephalogram.

【図6】英単語校正テストの結果を示す特性線図であ
る。
FIG. 6 is a characteristic diagram showing a result of an English word proofreading test.

【図7】チョコレートの嗜好調査結果を示す説明図であ
る。
FIG. 7 is an explanatory diagram showing the results of a chocolate preference survey.

【図8】脳波測定による集中度の向上を示すグラフであ
る。
FIG. 8 is a graph showing an improvement in concentration by measuring an electroencephalogram.

【図9】英単語校正テストの結果を示す特性線図であ
る。
FIG. 9 is a characteristic diagram showing a result of an English word proofreading test.

【図10】チョコレートの嗜好調査結果を示す説明図で
ある。
FIG. 10 is an explanatory diagram showing results of a chocolate preference survey.

【図11】脳波測定による集中度の向上を示すグラフで
ある。
FIG. 11 is a graph showing an improvement in concentration by measuring an electroencephalogram.

【図12】英単語校正テストの結果を示す特性線図であ
る。
FIG. 12 is a characteristic diagram showing a result of an English word proofreading test.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 生カカオ豆または半焙炒したカカオ豆の
カカオニブをアルカリ処理してなるチョコレートに用い
る集中度を向上させ得るカカオニブの香味の改良並びに
増強方法。
1. A method for improving and enhancing the flavor of cocoa nibs, which can improve the concentration of cocoa nibs of raw cocoa beans or semi-roasted cocoa beans to be treated with an alkali.
【請求項2】 カカオニブをアルカリ処理するに際して
使用されるアルカリを、水酸化カルシウムとする請求項
1記載の方法。
2. The method according to claim 1, wherein the alkali used in the alkali treatment of cocoa nibs is calcium hydroxide.
【請求項3】 生カカオ豆または半焙炒したカカオ豆か
らシェルおよびジャームを除去してカカオニブとし、こ
れにアルカリを添加し、撹拌、反応させてアルカリ処理
し、更に乾燥、焙炒したカカオニブを調製し、このアル
カリ処理したカカオニブを粉砕、摩砕してカカオマスと
し、これを原料として常法によりチョコレートを製造す
ることを特徴とする集中度を向上させ得る香味を改良並
びに増強させたカカオニブを用いるチョコレートの製造
方法。
3. Cocoa nibs obtained by removing shells and germs from raw cocoa beans or semi-roasted cocoa beans to obtain cocoa nibs, and adding alkali to the cocoa nibs, stirring and reacting them to carry out alkali treatment, and further drying and roasting cocoa nibs. Prepared and crushed and milled the alkali-treated cocoa nibs to produce cocoa mass, which is used as a raw material to produce chocolate by a conventional method. A cocoa nib having improved and enhanced flavor which can improve concentration is used. Manufacturing method of chocolate.
【請求項4】 カカオニブに添加されるアルカリを、水
酸化カルシウムとする請求項3記載のチョコレートの製
造方法。
4. The method for producing chocolate according to claim 3, wherein the alkali added to the cocoa nibs is calcium hydroxide.
【請求項5】 生カカオ豆または半焙炒したカカオ豆か
らシェルおよびジャームを除去して得られるカカオニブ
にアルカリを添加し、撹拌、反応させてアルカリ処理
し、更に乾燥、焙炒した集中度を向上させ得る香味を改
良並びに増強させたカカオニブを粉砕、摩砕したカカオ
マスと、カカオマス以外の通常のチョコレート原料とか
らなることを特徴とする集中度を向上させ得る香味を改
良並びに増強させたカカオニブを用いたチョコレート。
5. An alkali is added to cocoa nibs obtained by removing shells and germs from raw cocoa beans or semi-roasted cocoa beans, and the mixture is stirred, reacted and alkali-treated, and then dried and roasted to achieve a concentration degree. A cocoa nib with improved and enhanced flavor, which is characterized by comprising a cocoa mass obtained by crushing and grinding a cocoa nib with improved and enhanced flavor which can be improved, and a normal chocolate raw material other than cocoa mass. The chocolate used.
【請求項6】 カカオニブに添加されるアルカリを、水
酸化カルシウムとする請求項5記載のチョコレート。
6. The chocolate according to claim 5, wherein the alkali added to the cocoa nibs is calcium hydroxide.
JP5173028A 1992-07-21 1993-07-13 Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production Pending JPH0686637A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP5173028A JPH0686637A (en) 1992-07-21 1993-07-13 Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production
KR1019940000727A KR950002601A (en) 1993-07-13 1994-01-17 Method for improving and enhancing the flavor of the cacao nib can improve the concentration, Chocolate using the cocoa nib improved and enhanced flavor to improve the concentration and its manufacturing method.
US08/220,224 US5635183A (en) 1993-07-13 1994-03-30 Chocolate with improved and enriched aroma, and a process of its production

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP19362092 1992-07-21
JP4-193620 1992-07-21
JP5173028A JPH0686637A (en) 1992-07-21 1993-07-13 Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production

Publications (1)

Publication Number Publication Date
JPH0686637A true JPH0686637A (en) 1994-03-29

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP5173028A Pending JPH0686637A (en) 1992-07-21 1993-07-13 Method for improving and promoting flavor of cacao nib capable of improving concentration, chocolate produced from cacao nib having improved and promoted flavor and capable of improving concentration and its production

Country Status (1)

Country Link
JP (1) JPH0686637A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005008606A (en) * 2003-06-23 2005-01-13 Morinaga & Co Ltd Cerebral age retarder
JP2009278938A (en) * 2008-05-23 2009-12-03 Meiji Seika Kaisha Ltd Method for improving aroma of cocoa powder
JP2012510274A (en) * 2008-11-28 2012-05-10 アーチャー ダニエルズ ミッドランド カンパニー How to improve the quality of cocoa products obtained from beans by washing them
WO2013154286A1 (en) * 2012-04-10 2013-10-17 An Young-Il Method for processing cacao composition using alkaline electrolytic water
US8715766B2 (en) 2009-04-17 2014-05-06 Kraft Foods R&D, Inc. Process for producing high flavour cocoa
WO2017208741A1 (en) * 2016-06-02 2017-12-07 不二製油グループ本社株式会社 Chocolate-like food containing highly unsaturated fatty acid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6156975A (en) * 1984-08-28 1986-03-22 Nissin Electric Co Ltd Harmonic analyzer
JPS61195647A (en) * 1985-02-27 1986-08-29 Kanebo Shokuhin Kk Production of bitter chocolate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6156975A (en) * 1984-08-28 1986-03-22 Nissin Electric Co Ltd Harmonic analyzer
JPS61195647A (en) * 1985-02-27 1986-08-29 Kanebo Shokuhin Kk Production of bitter chocolate

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005008606A (en) * 2003-06-23 2005-01-13 Morinaga & Co Ltd Cerebral age retarder
JP2009278938A (en) * 2008-05-23 2009-12-03 Meiji Seika Kaisha Ltd Method for improving aroma of cocoa powder
JP2012510274A (en) * 2008-11-28 2012-05-10 アーチャー ダニエルズ ミッドランド カンパニー How to improve the quality of cocoa products obtained from beans by washing them
US8715766B2 (en) 2009-04-17 2014-05-06 Kraft Foods R&D, Inc. Process for producing high flavour cocoa
WO2013154286A1 (en) * 2012-04-10 2013-10-17 An Young-Il Method for processing cacao composition using alkaline electrolytic water
CN104185423A (en) * 2012-04-10 2014-12-03 安英一 Method for processing cacao composition using alkaline electrolytic water
GB2515212A (en) * 2012-04-10 2014-12-17 Young-Il An Method for processing cacao composition using alkaline electrolytic water
WO2017208741A1 (en) * 2016-06-02 2017-12-07 不二製油グループ本社株式会社 Chocolate-like food containing highly unsaturated fatty acid
KR20190013746A (en) * 2016-06-02 2019-02-11 후지세유 그룹 혼샤 가부시키가이샤 Chocolate-like foods containing polyunsaturated fatty acids
JPWO2017208741A1 (en) * 2016-06-02 2019-03-28 不二製油株式会社 Chocolate-like food containing highly unsaturated fatty acids
US11051530B2 (en) 2016-06-02 2021-07-06 Fuji Oil Holdings Inc. Chocolate-like food containing highly unsaturated fatty acid

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