JPH0684098B2 - Transfer foil for golf balls - Google Patents
Transfer foil for golf ballsInfo
- Publication number
- JPH0684098B2 JPH0684098B2 JP23574886A JP23574886A JPH0684098B2 JP H0684098 B2 JPH0684098 B2 JP H0684098B2 JP 23574886 A JP23574886 A JP 23574886A JP 23574886 A JP23574886 A JP 23574886A JP H0684098 B2 JPH0684098 B2 JP H0684098B2
- Authority
- JP
- Japan
- Prior art keywords
- ink
- golf ball
- transfer
- transfer foil
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、ゴルフボールに転写絵付するための転写箔に
関する。DETAILED DESCRIPTION OF THE INVENTION <Field of Industrial Application> The present invention relates to a transfer foil for transfer painting on a golf ball.
〈従来の技術〉 従来この種の転写箔としては特開昭57-145507号や特開
昭58-183285号が知られている。<Prior Art> JP-A-57-145507 and JP-A-58-183285 are conventionally known as transfer foils of this type.
これらの転写箔は、いずれもポリプロピレンフィルムを
離型フィルムとし、ニトロセルロースを主樹脂とするイ
ンキにより印刷したもので、その他の層、例えば接着層
を持たない。インキ中の顔料としてはアゾ顔料が用いら
れていた。Each of these transfer foils is a polypropylene film used as a release film and printed with an ink containing nitrocellulose as a main resin, and has no other layer such as an adhesive layer. An azo pigment was used as the pigment in the ink.
これらの転写箔は以下の如く使用される。すなわち、ゴ
ルフボールの外皮に直接、又はウレタン系の下地塗料を
塗布した後、これに転写箔を重ねホットスタンプして絵
柄を転写印刷する。この後、ウレタン系の塗料を塗布し
て、ゴルフボールとして市場に供される。These transfer foils are used as follows. That is, the outer coating of the golf ball is applied directly or after applying a urethane-based undercoating material, a transfer foil is laid over this and hot stamped to print a pattern. After that, a urethane-based paint is applied and the golf ball is put on the market.
この転写箔は、ディンプル部を含む被転写体への転写性
能に優れていて、一度のホットスタンプで転写できると
共に、過酷な使用条件における耐光性、耐候性、耐摩擦
性、耐クラック性等の物性に優れた絵付が可能であっ
た。This transfer foil has excellent transfer performance to the transfer target including the dimple portion, and can be transferred by one hot stamp, and also has light resistance, weather resistance, abrasion resistance, crack resistance, etc. under severe operating conditions. Painting with excellent physical properties was possible.
〈発明が解決しようとする問題点〉 ところで、転写絵付に失敗して、例えば絵柄が歪んだ
り、白抜けが生じた場合には、このゴルフボールはウレ
タン系塗料を塗布することなく、アルカリのアルコール
溶液により絵柄を洗い落として再使用される。しかる
に、顔料はゴルフボールの外皮や下地塗料に浸透してし
まい、良好に洗い落とすことができなかった。<Problems to be Solved by the Invention> By the way, when the transfer painting fails and, for example, the pattern is distorted or white spots are generated, this golf ball is treated with an alkaline alcohol without applying a urethane-based paint. The pattern is washed off with the solution and reused. However, the pigment penetrated the outer skin of the golf ball and the base paint and could not be washed off well.
従って、本発明は、その転写性能と物性とを維持したま
ま、アルカリのアルコール溶液で容易かつ完全に洗い落
とすことのできる絵柄を転写し得る転写箔を提供するこ
とを目的とする。Therefore, it is an object of the present invention to provide a transfer foil capable of transferring a pattern which can be easily and completely washed off with an alkaline alcohol solution while maintaining its transfer performance and physical properties.
〈問題点を解決するための手段〉 この目的を達成するため、本発明は、ポリプロピレンフ
ィルム等の離型フィルム上に、ニトロセルロースを主樹
脂とし、キナクリドン系顔料を含むインキを印刷して成
る転写箔を提供する。<Means for Solving the Problems> In order to achieve this object, the present invention is a transfer film formed by printing an ink containing a quinacridone-based pigment with nitrocellulose as a main resin on a release film such as a polypropylene film. Provide foil.
〈作用〉 本発明の転写箔はベースフィルムがポリプロピレン等の
離型フィルムであること、インキの主樹脂がニトロセル
ロースであること、他の層（例えば接着層）が存在しな
いことなどから、上記従来の転写箔と同じ転写性能と物
性を維持しており、インキ中の顔料がキナクリドン系顔
料であることから、ゴルフボールの外皮や下地塗料に浸
透せず、アルカリのアルコール溶液に溶解するので、転
写に失敗した際にも容易かつ完全に洗い落とすことがで
きる。また、この顔料の耐光性も優れているから、強い
曝光と衝撃を受けるゴルフボールの転写箔として極めて
好適なものである。<Operation> The transfer foil of the present invention has the above-mentioned conventional structure because the base film is a release film such as polypropylene, the main resin of the ink is nitrocellulose, and other layers (for example, an adhesive layer) are not present. It retains the same transfer performance and physical properties as the transfer foil, and because the pigment in the ink is a quinacridone-based pigment, it does not penetrate into the golf ball's outer coat or base paint, and dissolves in an alkaline alcohol solution. In case of failure, it can be washed off easily and completely. In addition, since the pigment has excellent light resistance, it is extremely suitable as a transfer foil for a golf ball which is subjected to strong light exposure and impact.
〈実施例の説明〉 本発明に係る離型フィルムとしては、ポリエチレンフィ
ルム、ポリプロピレンフィルム、ポリエステルフィル
ム、セロファン等が使用できるが、ポリプロピレンフィ
ルムが最も優れている。<Explanation of Examples> As the release film according to the present invention, polyethylene film, polypropylene film, polyester film, cellophane and the like can be used, but polypropylene film is the most excellent.
インキはバイダー及び転写の際の接着として働く樹脂、
顔料、溶剤、その他の添加剤とから成っている。Ink is a resin that works as a binder and adhesive during transfer,
It consists of pigments, solvents and other additives.
樹脂はニトロセルロースを主たる成分とし、これにアル
キッド樹脂、ハードレジン、アクリル樹脂、ポリエステ
ル樹脂、ウレタン樹脂等を従たる成分として用いる。ニ
トロセルロース10重量部に上記従たる成分を２〜７重量
部混合したものが好適である。Nitrocellulose is the main component of the resin, and alkyd resin, hard resin, acrylic resin, polyester resin, urethane resin and the like are used as subordinate components. It is preferable to mix 10 to 7 parts by weight of nitrocellulose with 2 to 7 parts by weight of the above subordinate components.
顔料はキナクリドン系顔料で、下記構造式（Ｉ）、（I
I）、（III）、（IV）のものがある。The pigment is a quinacridone pigment and has the following structural formulas (I) and (I
I), (III), and (IV).
キナクリドン系顔料（Ｉ） （R1、R2、R3はＨ、Cl、OH又は炭素数１〜５のアルキル
基） キナクリドン系顔料（II） （R1、R2、R3はＨ、Cl、OH又は炭素数１〜５のアルキル
基） キナクリドン系顔料（III） （R1、R2、R3はＨ、Cl、OH又は炭素数１〜５のアルキル
基） キナクリドン系顔料（IV） （R1、R2、R3はＨ、Cl、OH又は炭素数１〜５のアルキル
基） 溶剤としては、例えば酢酸エチル、メチルアルコール、
トルエン等の有機溶剤が使用でき、混合溶剤でも良い。Quinacridone pigment (I) (R 1 , R 2 and R 3 are H, Cl, OH or an alkyl group having 1 to 5 carbon atoms) Quinacridone pigment (II) (R 1 , R 2 and R 3 are H, Cl, OH or an alkyl group having 1 to 5 carbon atoms) Quinacridone pigment (III) (R 1 , R 2 and R 3 are H, Cl, OH or an alkyl group having 1 to 5 carbon atoms) Quinacridone pigment (IV) (R 1 , R 2 and R 3 are H, Cl, OH or an alkyl group having 1 to 5 carbon atoms) Examples of the solvent include ethyl acetate, methyl alcohol,
An organic solvent such as toluene can be used, and a mixed solvent may be used.
添加剤としてはポリエチレン粉末、界面活性剤、可塑
剤、体質顔料等を用いる。As the additive, polyethylene powder, a surfactant, a plasticizer, an extender pigment or the like is used.
ポリエチレン粉末はインキ層のブロッキング防止と耐摩
擦性を向上させる目的で添加され、可塑剤は主たる樹脂
が比較的硬い樹脂であり、打球時の強い衝撃によりイン
キ層がクラックを生じ易いため、クラックの防止を目的
として添加される。また、界面活性剤は顔料、ポリエチ
レン粉末等の非溶解性物質を有機溶剤中に均一に分散さ
せるための分散剤として添加される。Polyethylene powder is added for the purpose of preventing blocking of the ink layer and improving abrasion resistance, and the plasticizer is a resin whose main resin is relatively hard, and the ink layer is prone to crack due to a strong impact at the time of hitting a ball. It is added for the purpose of prevention. Further, the surfactant is added as a dispersant for uniformly dispersing the non-soluble substance such as pigment and polyethylene powder in the organic solvent.
本発明の転写箔は、例えば180〜190℃程度の温度で１秒
程度ゴルフボールに圧着することで転写できる。The transfer foil of the present invention can be transferred by pressing it onto a golf ball for about 1 second at a temperature of about 180 to 190 ° C.
〈試験例〉 本発明のインキとして以下のインキＡ、インキＢ、イン
キＣ、従来のインキとしてインキＤを用いて転写箔を作
成した。<Test Example> A transfer foil was prepared using the following ink A, ink B, and ink C as the ink of the present invention, and ink D as the conventional ink.
転写箔のベースフィルムはポリプロピレンフィルムであ
る。The base film of the transfer foil is a polypropylene film.
インキＡ ニトロセルロース20重量部、アルキッド樹脂５重量部、
下記キナクリドン系顔料（紅色）10重量部、ポリエチレ
ン粉末１重量部以下の微量、可塑剤（フタル酸系）１重
量部以下の微量、界面活性剤（アニオン系）１重量部以
下の微量、混合溶剤（酢酸エチル／メチルアルコール／
トルエン＝6/3/1）65重量部。Ink A Nitrocellulose 20 parts by weight, alkyd resin 5 parts by weight,
10 parts by weight of the following quinacridone pigment (red), trace amount of polyethylene powder 1 part by weight or less, plasticizer (phthalic acid type) 1 part by weight or less, surfactant (anion type) 1 part by weight or less, mixed solvent (Ethyl acetate / methyl alcohol /
Toluene = 6/3/1) 65 parts by weight.
インキＢ インキＡの顔料の代りに下記顔料を用いた外はインキＡ
と同一。 Ink B Ink A except that the following pigments are used instead of the ink A pigments
Same as
インキＣ 顔料として下記顔料を用いた外はインキＡと同一。 Ink C Same as Ink A except that the following pigments are used as the pigment.
インキＤ 顔料としてアゾ顔料を用いた外はインキＡと同一。 Ink D Same as Ink A except that azo pigment was used as the pigment.
得られた転写箔を用いて、パラタを主材料とする外皮を
有するゴルフボールにウレタン系白色塗料を塗布し、こ
の上に180℃に加熱したシリコンゴムにより１秒間圧着
して絵柄を転写した。Using the obtained transfer foil, a urethane type white paint was applied to a golf ball having an outer skin mainly composed of Parata, and a silicone rubber heated to 180 ° C. was pressed onto the golf ball for 1 second to transfer a pattern.
こうして絵付されたゴルフボールに対し、それぞれ、以
下の試験を行なった。なお、インキＡで絵付されたゴル
フボールをゴルフボールＡ、インキＢで絵付されたゴル
フボールをゴルフボールＢインキＣで絵付されたゴルフ
ボールをゴルフボールＣ、インキＤで絵付されたゴルフ
ボールをゴルフボールＤとする。The following tests were carried out on the golf balls thus painted. In addition, a golf ball painted with ink A is golf ball A, a golf ball painted with ink B is golf ball B, a golf ball painted with ink C is golf ball C, and a golf ball painted with ink D is golf ball. Let's call it ball D.
転写性試験 肉眼観察によりインキ層が完全に転写されたかどうかを
観察した。ゴルフボールＡ、Ｂ、Ｃ及びゴルフボールＤ
共に良好であった。Transferability test Whether or not the ink layer was completely transferred was observed by visual observation. Golf balls A, B, C and golf ball D
Both were good.
衝撃試験 ゴルフボールに透明ウレタン塗料を塗布硬化させた後、
これを45m/秒の速度で鉄板に衝突させることを50回繰り
返し、絵柄の剥離等の損傷度合を肉眼で観察した。ゴル
フボールＡ、Ｂ、Ｃ及びゴルフボールＤのいずれも良好
であった。Impact test After applying a transparent urethane paint to the golf ball and curing it,
This was repeated 50 times by colliding with an iron plate at a speed of 45 m / sec, and the degree of damage such as peeling of the pattern was visually observed. Golf balls A, B, C and golf ball D were all good.
摩耗試験 上記衝撃試験を行なった後のゴルフボール表面に、水と
砂とを強く吹きつける処理を５分間行い、絵柄の剥離、
磨滅等の損傷度合を肉眼で観察した。Abrasion test After the impact test, the surface of the golf ball is strongly sprayed with water and sand for 5 minutes to remove the pattern.
The degree of damage such as abrasion was visually observed.
ゴルフボールＡ、Ｂ、Ｃ及びＤいずれも特に良好であっ
た。Golf balls A, B, C and D were all particularly good.
洗浄試験 転写絵付されたゴルフボールを、そのまま（塗料を塗布
することなく）、苛性ソーダのエチルアルコール溶液で
洗浄した。ゴルフボールＡ、Ｂ、Ｃの絵柄は完全に除去
されたが、ゴルフボールＤの絵柄は、下地の白色塗料も
しくは外皮中に浸透しており、完全に除去することはで
きなかった。Cleaning Test The golf ball with the transferred image was washed as it is (without applying a paint) with an ethyl alcohol solution of caustic soda. The patterns of golf balls A, B, and C were completely removed, but the pattern of golf ball D was not completely removed because it penetrated into the white paint or the outer coat of the base.
〈効果〉 以上のように、本発明の転写箔によれば、従来と同様の
転写性と物性を維持しながら、しかも転写に失敗した際
の絵柄の除去が完全に行なえるという効果を有し、ゴル
フボールのための転写箔として誠に好適なものである。<Effect> As described above, according to the transfer foil of the present invention, there is an effect that the pattern can be completely removed when the transfer is failed while maintaining the transfer property and the physical property similar to the conventional one. It is a very suitable transfer foil for golf balls.
Claims (1)
樹脂とし、キナクリドン系顔料を含むインキを印刷して
成るゴルフボール用転写箔。1. A transfer foil for a golf ball, comprising a release film, and an ink containing a quinacridone pigment as a main resin and containing nitrocellulose as a main resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23574886A JPH0684098B2 (en) | 1986-10-03 | 1986-10-03 | Transfer foil for golf balls |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23574886A JPH0684098B2 (en) | 1986-10-03 | 1986-10-03 | Transfer foil for golf balls |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6389377A JPS6389377A (en) | 1988-04-20 |
| JPH0684098B2 true JPH0684098B2 (en) | 1994-10-26 |
Family
ID=16990641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23574886A Expired - Fee Related JPH0684098B2 (en) | 1986-10-03 | 1986-10-03 | Transfer foil for golf balls |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0684098B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6191185B1 (en) | 1995-09-18 | 2001-02-20 | Spalding Sports Worldwide, Inc. | UV curable ink containing aluminum trihydroxide for use in pad printing, and method of printing |
| US7048651B2 (en) | 1998-10-06 | 2006-05-23 | Callaway Golf Company | Golf Ball |
-
1986
- 1986-10-03 JP JP23574886A patent/JPH0684098B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6389377A (en) | 1988-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |