JPH0682624A - Phase-difference compensating film - Google Patents

Abstract

PURPOSE:To provide a polycarbonate phase-difference compensating film with the retardation value controllable in an appropriate range and with the variance of retardation values remarkably reduced. CONSTITUTION:This phase-difference compensating film consists of the drawn film or sheet of a polycarbonate having a repeating unit shown by formula I or the repeating units shown by formulas I and II and having 0.5-2.5dl/g reduced viscosity (etasp/c). In the formulas, X is a unit expressed by formula III, R<1> to R<3> and R<5> to R<12> are each a halogen atom, alkyl, cycloalkyl or aryl R<4> is hydrogen atom, an alkyl or cycloalkyl, (a) to (f) and (i) to (k) are each an integer of 0 to 4, (g) and (h) are an integer of 0 to 2, Z is a single bond, -O-, -CO-, -S-, -SO-, -SO2- or -CH2-, and Y is a single bond, -O-, -CO-, -S-, -SO-, -SO2-, etc.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a retardation compensation film, and more particularly to a high performance optical retardation compensation film useful as a retardation compensation film for liquid crystal panels.

[0002]

2. Description of the Related Art Polycarbonate is generally used as a material in various fields because it is excellent in mechanical strength, heat resistance and the like, and is also excellent in optical properties such as transparency and dimensional stability. ing. Nevertheless, with the expansion of applications in recent years, it has been required to develop products with even better performance.

The most typical polycarbonates are those obtained by the reaction of bisphenol A and phosgene, and a wide variety of others are known. However, in the present situation, even the basic point of which structure of polycarbonate is preferably used has not been clarified depending on the application. Therefore, in terms of application development, it is necessary to select a type of polycarbonate that is better suited for each application, and further to make it possible to exhibit the performance suitable for the application.

By the way, recently, as one of the uses of polycarbonate, there are various optical retardation compensation films (sheet-shaped and plate-shaped ones, for example, various names such as retardation sheet and retardation plate). Unless otherwise specified, their use as an optical retardation compensating film including these is attracting attention. The optical phase difference compensating film has a birefringence property, causes a phase difference in a direction perpendicular to incident light of linearly polarized light, and has a function of converting transmitted light into circularly polarized light or elliptically polarized light. It is used in various optical devices and devices for liquid crystal panels.

When the optical retardation compensating film is used for such an application, the retardation value (hereinafter referred to as R value), which is one of its characteristics, is usually referred to as the R value. And its birefringence Δn, that is, R = t × Δn is expressed as a numerical value in nm.) Is around 135 nm, a so-called quarter wavelength or more, for example, an optical path around 600 nm. A retardation film that causes a difference is suitable. In addition, in order to obtain a high-performance retardation film, it is also important to manufacture the stretched film or the stretched sheet so that the R value does not vary in all regions.

Such an optical retardation compensation film includes
Conventionally, cellulose acetate-based films and sheets have been used. Recently, it has been proposed to use a polycarbonate film or sheet as an optical retardation compensation film from the viewpoint of dimensional stability and thinning (see, for example, JP-A-63-189804, Kaihei 1
(See Japanese Patent Publication No. 2011608). However, in stretched films and sheets made of these conventional materials,
Generally, depending on the stretched film or sheet portion, for example, the difference in optical properties between the central portion and both end portions is large,
Therefore, there is a problem that the retardation compensation film as a product can be taken out only from the central portion of the stretched film or sheet.

When a polycarbonate film or sheet is used as an optical retardation compensating film, a polycarbonate material, a method of stretching the same, a stretching condition, and the like have been studied with the aim of obtaining a uniform R value. (See, for example, JP-A-4-84107). However, the conventional techniques have not been able to achieve a sufficiently satisfactory uniform R value, and in particular, there is no variation in the R value under optically orthogonal Nicols, that is, there is no uneven color. At present, the development of high-performance retardation compensation film is required.

[0008]

The present invention has been made based on the above circumstances. The object of the present invention is to solve the above-mentioned problems and to easily control the R value within an appropriate range.
It is an object of the present invention to provide a high-performance polycarbonate-based optical retardation compensation film, which has the advantage of being able to significantly reduce variations in R value and can be suitably used as a retardation compensation film for liquid crystal panels.

[0009]

Means for Solving the Problems The inventors of the present invention have conducted extensive studies to achieve the above object, and as a result, a film formed by stretching a material made of polycarbonate having a repeating unit represented by a specific general formula. It was also found that a high-performance optical retardation compensation film satisfying the above purpose can be realized by using a sheet. The present inventors have completed the present invention based on the above findings.

That is, the present invention provides the following general formula [I]

[0011]

[Chemical 4] [Wherein, R ¹ and R ² each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms, and a and b each independently. Indicates an integer of 0 to 4, and X is

[0012]

[Chemical 5] (However, in the formula, R ³ , R ⁵ , R ⁶ , R ⁷ , R ⁸ , R ⁹ and R
Each ¹⁰ independently represents a halogen atom, an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 1 to 12 carbon atoms, and R ⁴ is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms or a cycloalkyl group. Groups, c, d, e, f and i
Each independently represent an integer of 0 to 4, g and h each independently represent an integer of 0 to 2, Z is a single bond, -O-, -CO.
-, - S -, - SO -, - SO 2 - or -CH ₂ - shows a. ). ] The repeating unit [I] or the repeating unit [I] and the following general formula [II]

[0013]

[Chemical 6] [Wherein, R ¹¹ and R ¹² are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. A group, j and k each independently represent an integer of 0 to 4, Y is a single bond, -O-, -CO-, -S-,-.
_{SO -, - SO 2 -,} - CR 13 R 14 - ( wherein, R ¹³ and R ¹⁴ are each independently a hydrogen atom, a trifluoromethyl group, 1 to 6 carbon atoms alkyl group or having 6 to 12 carbon atoms A substituted or unsubstituted aryl group), a cycloalkylidene group having 5 to 8 carbon atoms, or an α, ω-alkylene group having 2 to 12 carbon atoms. And a concentration of 0.5 g / dl in which methylene chloride is used as a solvent.
Solution has a reduced viscosity [η _sp / c] of 0.5-
It is intended to provide a retardation compensation film comprising a stretched film or sheet of polycarbonate in the range of 2.5 dl / g.

A stretched film or sheet made of the above polycarbonate is used in the retardation compensation film of the present invention. The polycarbonate is composed of the repeating unit [I] represented by the general formula [I]. It is important to use at least one of the following polycarbonate and a polycarbonate comprising the repeating unit [I] and the repeating unit [II] represented by the general formula [II]. Examples of the polycarbonate include various polycarbonate homopolymers or copolymers consisting of one or more of the repeating units [I], one or more of repeating units [I], and a repeating unit [ I
Various polycarbonate copolymers composed of one or more of [I] can be used. Further, other repeating units may be contained within a range not hindering achievement of the object of the present invention. Particularly, in the case of a copolymer having the repeating unit [I] and the repeating unit [II], the content ratio of the repeating unit [I] to the total content of the repeating unit [I] and the repeating unit [II] is usually 1 mol. Those in the range of% or more are preferable.

These polycarbonates may be used alone or in combination of two or more as a mixture or the like, if necessary. Further, when these polycarbonates are stretched, other polymer components and desired components such as additives may be added as necessary and used as a composition.

In the general formula [I], R ¹ , R ² , R ³ ,
R ⁵ , R ⁶ , R ⁷ , R ⁸ , R ⁹ and R ¹⁰ are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms or 1 to 12 carbon atoms.
Represents a substituted or unsubstituted aryl group of.

Substituents R ¹ , R ² , R ³ , R ⁵ , R ⁶ , R ⁷ , R
^The following can be illustrated as specific examples of ⁸ , R ⁹ and R ¹⁰ .

Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom, and examples of the alkyl group include a methyl group, an ethyl group and n-.
Propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, isobutyl group, n-pentyl group, isopentyl group, sec-pentyl group, ter
Examples of the substituted or unsubstituted aryl group include t-pentyl group, neopentyl group, n-hexyl group, isohexyl group, sec-hexyl group, tert-hexyl group, neohexyl group and cyclopentylmethyl group. , Phenyl group, methylphenyl group, ethylphenyl group, propylphenyl group, butylphenyl group,
Examples thereof include dimethylphenyl group, trimethylphenyl group, cyclohexylphenyl group, p-biphenylyl group, m-biphenylyl group, 1-naphthyl group, 2-naphthyl group, methylnaphthyl group, dimethylnaphthyl group and ethylnaphthyl group.

In the general formula [I], R ⁴ is a hydrogen atom,
An alkyl group or a cycloalkyl group having 1 to 12 carbon atoms is shown. Specific examples of the alkyl group include an octyl group, a nonyl group, a decyl group, and an undecyl group, in addition to those exemplified above.
Examples thereof include dodecyl group, and the cycloalkyl group preferably has 4 to 8 carbon atoms, and particularly preferably cyclohexyl group.

In the general formula [II], R ¹¹ and R ¹² are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms or 6 to 1 carbon atoms.
2 represents a substituted or unsubstituted aryl group, and specific examples of the halogen atom, the alkyl group having 1 to 6 carbon atoms, and the aryl group having 6 to 12 carbon atoms are those exemplified in the description of the above general formula [I]. Can be mentioned. Carbon number 5
As the cycloalkyl of 7, a cyclohexyl group is preferable.

In the general formula [II], Y is a single bond,
O -, - CO -, - S -, - SO -, - SO 2 -, - C
R < ¹³ > R < ¹⁴ >-, a C5-C8 cycloalkylidene group or a C2-C12 [alpha], [omega] -alkylene group is shown.

Here, R ¹³ and R ^{14 in} —CR ¹³ R ¹⁴ —.
Are each independently a hydrogen atom, a trifluoromethyl group, an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. Examples of the alkyl group and the aryl group include Examples can be given.

Examples of the cycloalkylidene group as Y include a 1,1-cyclopentylidene group, a 1,1-cyclohexylidene group, and a 1,1-cycloheptylidene group.
Of these, a 1,1-cyclohexylidene group is preferable.

Examples of the α, ω-alkylene group having 2 to 12 carbon atoms as Y include various polymethylene groups ranging from a dimethylene group to a decamethylene group.

Each of these various repeating units [I] and [II] can be formed from a monomer having a corresponding structure. For example, bisphenols (dihydric phenols) having a corresponding structure and It can be formed by reacting phosgene. Therefore, instead of directly showing the specific examples of these various repeating units [I] and [II], specific examples of the corresponding bisphenols will be given below.

The bisphenols forming the repeating unit [I] are represented by the following general formula [III]

[0027]

[Chemical 7] (In the formula, R ¹ , R ² , a, b and X have the same meanings as described above.), And specific examples thereof include the following.

[0028]

[Chemical 8] The bisphenols forming the repeating unit [II] are
The following general formula [IV]

[0029]

[Chemical 9] (Wherein R ¹¹ , R ¹² , j, k and Y have the same meanings as described above), and specific examples thereof include, for example,
Bis (4-hydroxyphenyl) methane, 1,1-bis (4-hydroxyphenyl) ethane, 1,2-bis (4
-Hydroxyphenyl) ethane, 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (3-methyl-4-hydroxyphenyl) butane, 2,2-bis (4-hydroxyphenyl) butane, 2 , 2-bis (4
-Hydroxyphenyl) octane, 4,4-bis (4-
Hydroxyphenyl) heptane, 4,4'-dihydroxytetraphenylmethane, 1,1-bis (4-hydroxyphenyl) -1-phenylethane, 1,1-bis (4
-Hydroxyphenyl) -1-phenylmethane, bis (4-hydroxyphenyl) ether, bis (4-hydroxyphenyl) sulfide, bis (4-hydroxyphenyl) sulfone, 1,1-bis (4-hydroxyphenyl) cyclopentane , 1,1-bis (4-hydroxyphenyl) cyclohexane, 2,2-bis (3-methyl-4-hydroxyphenyl) propane, 2- (3-methyl-4-hydroxyphenyl) -2- (4-hydroxy) Phenyl) -1-phenylethane, bis (3-methyl-
4-hydroxyphenyl) sulfide, bis (3-methyl-4-hydroxyphenyl) sulfone, bis (3-methyl-4-hydroxyphenyl) methane, 1,1-bis (3-methyl-4-hydroxyphenyl) cyclohexane, 2,2-bis (2-methyl-4-hydroxyphenyl) propane, 1,1-bis (2-butyl-4-hydroxy-5-methylphenyl) butane, 1,1-bis (2
-Tert-butyl-4-hydroxy-3-methylphenyl) ethane, 1,1-bis (2-tert-butyl-
4-hydroxy-5-methylphenyl) propane, 1,
1-bis (2-tert-butyl-4-hydroxy-5)
-Methylphenyl) butane, 1,1-bis (2-ter
t-butyl-4-hydroxy-5-methylphenyl) isobutane, 1,1-bis (2-tert-butyl-4-
Hydroxy-5-methylphenyl) heptane, 1,1-
Bis (2-tert-butyl-4-hydroxy-5-methylphenyl) -1-phenylmethane, 1,1-bis (2-tert-amyl-4-hydroxy-5-methylphenyl) butane, bis (3- Chloro-4-hydroxyphenyl) methane, bis (3,5-dibromo-4-hydroxyphenyl) methane, 2,2-bis (3-chloro-)
4-hydroxyphenyl) propane, 2,2-bis (3
-Fluoro-4-hydroxyphenyl) propane, 2,
2-bis (3-bromo-4-hydroxyphenyl) propane, 2,2-bis (3,5-difluoro-4-hydroxyphenyl) propane, 2,2-bis (3,5-dichloro-4-hydroxyphenyl) ) Propane, 2,2-bis (3,5-dibromo-4-hydroxyphenyl) propane, 2,2-bis (3-bromo-4-hydroxy-5)
-Chlorophenyl) propane, 2,2-bis (3,5-
Dichloro-4-hydroxyphenyl) butane, 2,2-
Bis (3,5-dibromo-4-hydroxyphenyl) butane, 1-phenyl-1,1-bis (3-fluoro-4)
-Hydroxyphenyl) ethane, bis (3-fluoro-)
4-hydroxyphenyl) ether, 3,3'-difluoro-4,4'-dihydroxybiphenyl, 1,1-bis (3-cyclohexyl-4-hydroxyphenyl) cyclohexane, 2,2-bis (4-hydroxyphenyl) Hexafluoropropane, 1,1-bis (4-hydroxyphenyl) -1-phenyl-2,2,2-trifluoroethane, 2,2-bis (3-phenyl-4-hydroxyphenyl) propane, 1,1 -Bis (3-phenyl-4-hydroxyphenyl) cyclohexane, bis (3-phenyl-4-hydroxyphenyl) sulfone,
4,4'-dihydroxybenzophenone, bis (4-
Hydroxyphenyl) sulfoxide, 4,4'-dihydroxybiphenyl, 4,4'-dihydroxy-3,3 '
-Dimethylbiphenyl, 4,4'-dihydroxy-2,
2'-dimethylbiphenyl, 4,4'-dihydroxy-
3,3'-dicyclohexylbiphenyl and the like can be mentioned.

Among these bisphenols represented by the general formula [IV], 2,2-bis (4-hydroxyphenyl) propane, 4,4-dihydroxytetraphenylmethane, 1-phenyl-1,1-bis ( 4-hydroxyphenyl) ethane, bis (4-hydroxyphenyl) sulfone, 1,1-bis (4-hydroxyphenyl) cyclohexane, 2,2-bis (3-methyl-4-hydroxyphenyl) propane, 4,4- Dihydroxybiphenyl, 2,2-bis (3-phenyl-4-hydroxyphenyl) propane and the like are preferable.

The polycarbonate used in the present invention may have a linear structure, a branched structure, a branched structure, a cyclic structure or a cyclic structure, and a special structure at the end of the polycarbonate. Those having various molecular structures such as those introduced are applicable.

The polycarbonate used in the present invention is
The reduced viscosity [η _sp / c] of a solution having a concentration of 0.5 g / dl in methylene chloride at 20 ° C. is 0.5 to 2.5 d.
It is in the range of 1 / g. If the reduced viscosity is less than 0.5 dl / g, the strength of the film or sheet will be reduced to 2.5 dl.
If it exceeds / g, molding may be difficult.

The method for producing these polycarbonates is not particularly limited. For example, various bisphenols exemplified above are used as monomers in the presence of an acid acceptor such as an alkali metal compound or pyridine (if necessary. Prepared by various methods such as known polymerization method such as phosgene method of reacting with phosgene gas (in a suitable solvent) (interfacial polycondensation method, pyridine method, etc.), chloroformate method, transesterification method, etc. Applicable. In the case of this phosgene method, the raw material bisphenols and phosgene may be reacted at once to obtain a desired polycarbonate, or a part of the reaction raw material bisphenols and phosgene may be reacted in advance to give a chloro group at the molecular end. A two-step method may be used in which an oligomer having a formate group is produced, and then the remaining reaction raw materials are added to complete polycondensation to obtain a desired polycarbonate.

The retardation compensating film of the present invention is a film obtained by molding and stretching a material comprising at least one of the repeating unit [I] or the repeating unit [I] and the repeating unit [II]. It is composed by using the or sheet. At that time, the polycarbonate can be used alone or as a mixture in an arbitrary ratio, and further, if necessary, it can be used as a mixture with other components such as a mixture with other polymer. it can.

The polycarbonate film or sheet can be molded by various known film forming methods, for example, solvent casting method, extrusion method, calendering method and the like. At the same time as or continuously with this molding, stretching may be performed to obtain a desired stretched film or sheet. Further, the film or sheet thus formed may be stretched and used. In any case, this stretching can be performed by various methods such as a method using a stretching roll, a known stretching method, or a known forming and stretching method.

A suitable temperature for stretching is a temperature slightly higher than the glass transition temperature of polycarbonate.

The stretching of this film or sheet is usually carried out.
Stretching in the uniaxial direction may be performed, and the stretching ratio in the uniaxial direction (percentage of the stretched length with respect to the original length) is usually in the range of 1 to 10%, preferably 3 to 5%. Is preferred. This stretching may be performed in a single stage or in multiple stages.

The thickness of the stretched film or sheet thus obtained cannot be uniformly set because the optimum value varies depending on the properties of the polycarbonate used (especially optical properties such as birefringence) and the degree of stretching. , 50 to 300 μm is preferable. That is, considering the birefringence Δn of the stretched film or sheet,
A retardation compensation film having a desired R value can be easily manufactured by appropriately selecting the thickness t.

The retardation compensation film of the present invention obtained as described above has a particularly small variation in R value (for example, this variation is easily within a remarkably small range of 3% or less, further 2% or less). It is a high-performance optical retardation compensation film, and can be advantageously used in various applications including liquid crystal panels.

[0040]

EXAMPLES The present invention will now be described in detail based on examples, but the present invention is not limited thereto.

Example 1 The following structure was used as a raw material monomer

[0042]

[Chemical 10] Bisphenol compound of 15.4 g (0.051 mol)
And 2,2-bis (4-hydroxyphenyl) propane 42.6 g (0.205 mol), sodium hydroxide aqueous solution having a concentration of 8% 550 ml, methylene chloride 400 ml, and p-tert- as a terminal stopper (molecular weight modifier). 0.15 g of butylphenol and 3 ml of 10% triethylamine aqueous solution as a catalyst were introduced into a reactor equipped with a baffle, and the reaction solution was vigorously stirred while maintaining the temperature at around 10 ° C., and phosgene gas was added at a rate of 100 ml / min for 15 minutes. The polycondensation reaction was performed by blowing.

After completion of the reaction, 1 liter of methylene chloride was added to the organic layer to dilute it, and the organic layer was washed with water, diluted hydrochloric acid and water in this order, and then poured into methanol to obtain a polycarbonate.

The polycarbonate thus obtained has a reduced viscosity [η _sp / c] of 0.78 dl at 20 ° C. in a solution of methylene chloride in a concentration of 0.5 g / dl.
/ G. ¹ H-NMR spectrum analysis confirmed that the obtained polycarbonate was a polycarbonate having the following repeating units [Ia] and [IIa] in the following molar ratios.

[0045]

[Chemical 11] The above polycarbonate is extruded to a thickness of 120
A transparent film having a thickness of 500 μm and a width of 500 mm was uniaxially stretched by 5% at 160 ° C. to obtain a uniform retardation compensation film having a thickness of 100 μm. The obtained retardation compensation film is cut into a width of 400 mm and a length of 1 m, and the length and width are each 50 m.
Birefringence was measured at 8 × 20 = 160 points at m intervals using a Senarmont compensator attached to a polarization microscope,
The R value was calculated. A halogen lamp was used as the light source. The measurement results are shown in Table 1. The film also showed a uniform color tone under crossed Nicols.

Example 2 The following structure as a monomer

[0047]

[Chemical 12] 20.0 g (0.051 mol) of bisphenol compound
A polycarbonate was obtained in the same manner as in Example 1 except that 54.9 g (0.205 mol) of 1,1-bis (4-hydroxyphenyl) cyclohexane was used.

The polycarbonate thus obtained has a reduced viscosity [η _sp / c] of 0.81 dl at 20 ° C. in a solution of methylene chloride in a concentration of 0.5 g / dl.
/ G. ^{According to 1} H-NMR spectrum analysis, the obtained polycarbonate had the following repeating unit [Ib].
And [IIb] were confirmed to be polycarbonates having the following molar ratios.

[0049]

[Chemical 13] Using this polycarbonate, a retardation compensation film was prepared in the same manner as in Example 1, and the R value was measured. The measurement results are shown in Table 1. The film also showed a uniform color tone under crossed Nicols.

Example 3 The following structure was used as a monomer

[0051]

[Chemical 14] 20.0 g (0.051 mol) of bisphenol compound
And 4,4'-dihydroxytetraphenylmethane 7
A polycarbonate was obtained in the same manner as in Example 1 except that 2.2 g (0.205 mol) was used.

The polycarbonate thus obtained has a reduced viscosity [η _sp / c] of 0.82 dl at 20 ° C. in a solution of methylene chloride at a concentration of 0.5 g / dl.
/ G. ^{According to 1} H-NMR spectrum analysis, the obtained polycarbonate has the following repeating unit [Ic].
And [IIc] were confirmed to be polycarbonates having the following molar ratios.

[0053]

[Chemical 15] Using this polycarbonate, a retardation compensation film was prepared in the same manner as in Example 1, and the R value was measured. The measurement results are shown in Table 1. The film also showed a uniform color tone under crossed Nicols.

Comparative Example 1 Reaction of commercially available polymer 2,2-bis (4-hydroxyphenyl) propane with phosgene (the terminator is p
Example 1 was prepared using a polycarbonate ([η _sp /c]=0.76 dl / g) composed of the following repeating unit [IIa] produced by -tert-butylphenol).
An attempt was made to prepare a retardation compensation film, and the R value of the obtained film was measured in the same manner as in Example 1. The measurement results are shown in Table 1. This film showed remarkable unevenness in color tone under crossed Nicols.

[0055]

[Chemical 16]

[0056]

[Table 1]

[0057]

EFFECTS OF THE INVENTION According to the present invention, since a stretched film or sheet made of polycarbonate having a specific structure is used, it is easy to control the R value within an appropriate range, and the variation of the R value is within 3%, for example. Furthermore, it can be easily reduced to a remarkably low range of 2% or less, and therefore, a high-performance retardation compensation film that can be suitably and advantageously used as a retardation compensation film for liquid crystal panels can be provided. .

Further, according to the present invention, it is possible to remarkably reduce quality irregularities such as variations in R value not only within the same film but also among various products, so that the yield and productivity of the products can be remarkably improved. it can.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁵ Identification number Reference number within the agency FI Technical indication location B29L 7:00 4F (72) Inventor Tomohiro Nagao 1280, Kamizumi, Sodegaura, Chiba Idemitsu Kosan Ceremony In the company

Claims (1)

[Claims] 1. The following general formula [I]: [Wherein, R ¹ and R ² each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms, and a and b each independently. Represents an integer of 0 to 4, and X is (However, in the formula, R ³ , R ⁵ , R ⁶ , R ⁷ , R ⁸ , R ⁹ and R
Each ¹⁰ independently represents a halogen atom, an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 1 to 12 carbon atoms, and R ⁴ is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms or a cycloalkyl group. Groups, c, d, e, f and i
Each independently represent an integer of 0 to 4, g and h each independently represent an integer of 0 to 2, Z is a single bond, -O-, -CO.
-, - S -, - SO -, - SO 2 - or -CH ₂ - shows a. ). ] The repeating unit [I] or the repeating unit [I] and the following general formula [II] [Wherein, R ¹¹ and R ¹² are each independently a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. A group, j and k each independently represent an integer of 0 to 4, Y is a single bond, -O-, -CO-, -S-,-.
_{SO -, - SO 2 -,} - CR 13 R 14 - ( wherein, R ¹³ and R ¹⁴ are each independently a hydrogen atom, a trifluoromethyl group, 1 to 6 carbon atoms alkyl group or having 6 to 12 carbon atoms A substituted or unsubstituted aryl group), a cycloalkylidene group having 5 to 8 carbon atoms, or an α, ω-alkylene group having 2 to 12 carbon atoms. And a concentration of 0.5 g / dl in which methylene chloride is used as a solvent.
Solution has a reduced viscosity [η _sp / c] of 0.5-
A retardation compensation film comprising a stretched film or sheet of polycarbonate in the range of 2.5 dl / g.