JPH0672666B2 - Combination sliding member - Google Patents

Description

Description: TECHNICAL FIELD The present invention relates to a combined sliding member, and more particularly to a combined sliding member in which both base materials are aluminum alloys (hereinafter abbreviated as “aluminum alloys”). Is.

(Prior Art) A sliding member used in an automobile or the like is required to use an aluminum alloy as a base material in order to reduce its weight. By the way, the aluminum alloy itself has a drawback that it is inferior in wear resistance when used as a sliding member. As a method of compensating for this drawback, it is known to form an alumite layer on the surface by anodizing treatment ("Mechanical Design", Vol. 29, No. 15, pages 77 to 86, 1985). The material having this alumite layer formed (hereinafter referred to as "alumite material") has considerably improved wear resistance despite the base material being an aluminum alloy.

However, if an alumite layer is formed on both of a pair of combination sliding members, the same type of material will slide, resulting in increased wear. Rather, the combined sliding member of anodized material and aluminum alloy base material will wear. Less is.

Therefore, as a conventional lightweight sliding member, a combination sliding member that uses an aluminum alloy with an anodized aluminum layer as the body side member and steel with excellent wear resistance or heat treated steel as the valve side member is used. A member is used.

(Problems to be Solved by the Invention) However, when the combination sliding member is used in the piston type, there are the following problems caused by the temperature change of the lubricating oil.

That is, since the body side (aluminum alloy + alumite layer) and the valve side (iron-based material) have different thermal expansion coefficients,
When the temperature is low, the clearance of the sliding portion becomes small and stick (valve sliding failure) occurs, and when the temperature is high, the clearance becomes large and oil leakage occurs. Further, there is a problem that foreign matter in the lubricating oil circuit remains between the valve and the body and sticks when left to cool after being used at a high temperature.

As a countermeasure, it is of course possible to use a member having the same thermal expansion coefficient on the body side and the valve side as much as possible. Therefore, it is possible to use an alumite material on the valve side as well, and it has been partially commercialized. There is. With this combination, the above-mentioned problems due to the clearance change and the like do not occur, but there is a problem that the sliding resistance between the alumite layers is poor as described above.

By the way, as a method of improving the wear resistance of the aluminum-based member, the following method is known in addition to the above-described anodizing treatment (alumite conversion).

A method of applying Fe (iron) plating to harden the surface (see Nikkan Kogyo Shimbun's "Plating Technology Handbook", Sho 46.725, First Edition, p. 270), electrolytically polish one aluminum alloy, and Fe-on the other aluminum alloy. A method of forming a P (iron-phosphorus alloy) plating film (see Japanese Patent Application Laid-Open No. 58-146763). One aluminum alloy is subjected to etching treatment by electrolytic polishing or chemical polishing (hereinafter referred to as "ECM treatment"), and the other Method for forming a Fe-P plating film in which SiC (silicon carbide) particles and the like are dispersed on the aluminum alloy of JP-A-60-165389
No.).

However, although these methods have some improvement effects, they are not completely satisfactory. By the way, when using a high-silicon aluminum alloy (standard: A390), which has good wear resistance among aluminum alloys, friction occurs between primary crystal silicon (Hv900 ~ 1100) in the aluminum alloy structure and the mating material (Fe plated material). As a result, the wear of the mating material increases, and the surface roughness becomes large, so that the wear of the mating material and the mating material increases. Further, when used in a high load region, the same phenomenon as when foreign matter enters due to cracking and falling of primary crystal silicon appears, and the baking load decreases.

The present invention has been made to solve the above problems,
An object of the invention is to provide a combined sliding member which does not cause a clearance change due to temperature and whose base material is an aluminum alloy, and which is excellent in wear resistance and seizure resistance. That is.

(Means for Solving the Problems) A combination sliding member of the present invention which can achieve the above object is a pair of sliding members each having an aluminum alloy as a base material,
An alumite layer is formed on the sliding surface of one member, and the surface roughness of the sliding surface of the other member is 2 μRz or less and hardness Hv600 to 1
It is characterized in that 000 molybdenum (Mo) sprayed layers are formed.

In the present specification, “surface roughness” means ten-point average roughness represented by Rz, and “hardness” means “Vickers hardness” represented by Hz.

The present invention has been surprisingly found to be a sliding member which is remarkably improved in wear resistance and seizure resistance as compared with conventional ones, and it will be described in more detail below. .

The alumite material which is one of the members is a conventional method, and an aluminum alloy capable of forming an alumite layer is electrolyzed, for example, a sulfuric acid bath,
It can be obtained by treatment on the anode side using an oxalic acid bath or a mixed acid bath of these. The hardness of this alumite layer is Hv15
It may be 0 or more. Below that, the wear of the alumite layer increases rapidly.

The surface roughness of the Mo sprayed layer formed on the other member is 2
It is less than μRz. This is because when the surface roughness exceeds 2 μRz, the opponent's aggressiveness is increased and the opponent material is easily worn. Further, the sprayed layer preferably has a thickness of 5 to 150 μm and a hardness of Hv 600 to 1000 in consideration of wear resistance and seizure resistance of itself and the counterpart material. Such a Mo sprayed layer can be formed according to a conventional method by appropriately selecting plasma spraying conditions such as Ar, H ₂ gas flow rate, supply current, average particle diameter of sprayed powder, and spraying time.

The difference in coefficient of thermal expansion between the two aluminum alloys that are the base materials of the combination sliding member of the present invention is preferably 3 × 10 ⁻⁶ / ° C. or less. When the temperature is higher than this, if used at a high temperature (150 ° C) and left to cool, foreign matter in the lubricating oil circuit tends to remain between the body and valve, causing sticking. At 3 × 10 ^-6 / ° C or less, foreign matter remains. This is because a slight scratch mark is generated between the body and the valve, but no stick is generated.

Therefore, this combination sliding member is suitable as a piston type sliding member, particularly as a combination sliding member for a body and a valve of an oil passage switching device of an automatic transmission.

(Examples) Examples of the present invention will be described below together with comparative examples, but the present invention is not limited thereto.

Example 1 An aluminum alloy (JIS standard ADC12) is used and the size is 35 m in outer diameter.
By making a cylindrical piece of m, inner diameter 30 mm, width 10 mm, and then subjecting its outer peripheral surface to anodizing treatment using a sulfuric acid bath,
A cylindrical test piece having an oxide film (alumite layer) with a thickness of 10 μm and a hardness of Hv300 was prepared.

On the other hand, 16 x 6 x 10 mm aluminum alloy casting (JIS standard AC1A)
On one side, Ar gas flow rate 2300 l / h, H ₂ gas flow rate 450 l / h, supply current 450 to 500 A, average particle diameter of sprayed powder 20 μm, plasma spraying condition, thickness 20 μm, surface roughness 2 μRz or less, hardness
An Hv800 Mo sprayed layer was formed, and a dice test piece having a 16 mm × 6 mm surface as a test surface was prepared.

The dice test piece and the cylindrical test piece were combined and subjected to the following wear test.

Comparative Examples 1 to 3 Various combination test pieces (Comparative Examples 1 to 3) in which one cylindrical test piece and the other dice test piece are members shown in Table 1
Was prepared and subjected to the following abrasion test as in the example.

Abrasion test The combined test pieces of Example 1 and Comparative Examples 1 to 3 were sequentially set in a friction wear tester, and the outer peripheral surface of the cylindrical test piece was brought into contact with the 16 mm x 6 mm surface of the dice test piece, and the test pieces were brought into contact with each other. Lubricating oil with a temperature of 25 ° C on the part
Was supplied, a wear test was performed by rotating the cylindrical test piece for 30 minutes at a load of 60 kg and a rotation speed of 160 rpm. The surface roughness of the cylindrical test piece and that of the dice test piece are 0.8 μRz and 1.2 μRz, respectively.

The results of this abrasion test are shown in FIG. In the figure, the upper half represents the wear amount (wear loss mg) of the cylindrical test piece, and the lower half represents the wear amount (wear depth μ) of the dice test piece.

From FIG. 1, in the combination (A) of the alumite material and the aluminum wrought material of Comparative Example 1, the abrasion of the dice test piece not subjected to the surface treatment was large, and in the combination of the alumite materials of Comparative Example 2 (B). Shows that the wear of the cylindrical test piece increases. The combination (D) of the alumite material and the Mo sprayed material of Example 1 is a combination (C) of the alumite material and the hardened steel of Comparative Example 3 even though both base materials are aluminum alloys.
It can be seen that the wear resistance is superior to that of the above-mentioned materials by comparing the wear amounts of those cylindrical test pieces and dice test pieces.

Example 2 and Comparative Examples 4 to 6 As Example 2, Comparative Examples 4, 5 and 6, each was made of the same combination members as D, A, B and C in Table 1, each having an outer diameter of 25.4c.
m, inner diameter 20 mm, length 10 mm
It was subjected to the following baking test.

Baking test The cylindrical end surfaces of the combined cylindrical test pieces of Example 2, Comparative Examples 4, 5 and 6 were brought into contact with each other, lubricating oil (trade name "Castle motor oil" 5w-30) was supplied, and the rotation speed was set to 1000 rpm. The pressing load was gradually increased from 10 kg to 700 kg, and a seizure test was carried out to measure the seizure limit load.
The results are shown in Table 2.

As can be seen from Table 2, it was confirmed that the combined test piece of Example 2 was superior in seizure resistance to that of each comparative example.

Example 3 and Comparative Examples 7 and 8 FIG. 2 shows a hydraulic pressure switching device 3 incorporated in an automatic transmission. The valve body 1 was manufactured by anodizing using an aluminum alloy (JIS standard ADC10). In addition, the shift valve 2
It was made of the same material as the three types of dice test pieces B, C and D shown in the table. These valves 2 and the body 1
The hydraulic switching device 3 obtained by combining the above was actually mounted on the transmission of the vehicle and subjected to a durability test for comparing the damage status of the valve after 90,000 cycles of operation (100 hours of operation). The outer diameter of the valve was 10 mm, and the clearance between the valve and the body was 40 μm.

The results are summarized in Table 3. 40,0 was produced by the combination (C) of the alumite material and the hardened steel of Comparative Example 8.
The valve stopped working after sticking for 00 cycles. In the case of the comparative example 7 manufactured by the combination (B) of the alumite materials, the stick did not occur, but the body and the valve were greatly worn. On the other hand, a combination of the alumite material and the Mo sprayed material of Example 3 (D)
The products produced in Table 3 showed good results as can be seen from Table 3.

(Effects of the Invention) The combination sliding member of the present invention has extremely excellent performance such as seizure resistance is 2 times and abrasion resistance is 2 to 30 times as compared with the conventional sliding member in which aluminum alloys are combined. Indicates.

Therefore, it can be used as a piston type sliding member which is placed under severe sliding conditions. When used in the piston type, since the base material of both of the combination sliding members of the present invention is an aluminum alloy, the change in clearance due to thermal expansion is small and sticking does not occur.

In addition, since it has better wear resistance and seizure resistance than the combined sliding member of aluminum alloy and steel, this combined sliding member can be used instead of it, contributing to weight reduction of sliding parts. .

[Brief description of drawings]

FIG. 1 is a view showing the results of wear test of the combination sliding member of the embodiment of the present invention in comparison with that of the comparative example, and FIG. 2 is a structure of a piston type sliding portion of an oil passage switching device used for an automatic transmission. FIG. In the figure, 1 ... Valve body, 2 ... Shift valve

Claims (4)

[Claims] 1. A pair of sliding members both having an aluminum alloy as a base material, wherein an alumite layer is formed on the sliding surface of one member, and the sliding surface of the other member has a surface roughness of 2 μRz or less and a hardness of A combination sliding member having a Hv 600-1000 molybdenum sprayed layer formed thereon. 2. The difference in thermal expansion coefficient between the aluminum alloy of one member and the aluminum alloy of the other member is 3 × 10 ⁻⁶ /
The combination sliding member according to claim 1, characterized in that the temperature is not higher than ° C. 3. A combination sliding member according to claim 1 or 2, wherein one member is a body and the other member is a piston type sliding member of a valve. 4. The combination sliding member according to claim 3, wherein the piston type sliding member is a body and a valve of an oil passage switching device of an automatic transmission.