JPH0661679A - Thin radio wave absorbent - Google Patents

Thin radio wave absorbent

Info

Publication number
JPH0661679A
JPH0661679A JP4226546A JP22654692A JPH0661679A JP H0661679 A JPH0661679 A JP H0661679A JP 4226546 A JP4226546 A JP 4226546A JP 22654692 A JP22654692 A JP 22654692A JP H0661679 A JPH0661679 A JP H0661679A
Authority
JP
Japan
Prior art keywords
radio wave
electromagnetic wave
wave absorber
thin
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4226546A
Other languages
Japanese (ja)
Other versions
JP3097343B2 (en
Inventor
Yasuo Hashimoto
康雄 橋本
Kenichi Ichihara
謙一 市原
Takashi Tanaka
隆 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TDK Corp
Original Assignee
TDK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TDK Corp filed Critical TDK Corp
Priority to JP04226546A priority Critical patent/JP3097343B2/en
Publication of JPH0661679A publication Critical patent/JPH0661679A/en
Application granted granted Critical
Publication of JP3097343B2 publication Critical patent/JP3097343B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To provide flexibility by providing a flexible radio wave absorbing sheet layer produced by mixing an electromagnetic wave energy loss material and a holding material, and a radio wave reflection layer produced by subjecting an organic fiber cloth to electroless plating of highly conductive metal material and laminated on the rear of the radio wave absorbing sheet layer, thereby integrating a radio wave reflector. CONSTITUTION:A flexible radio wave absorbing sheet layer 10 is provided by admixing powder of magnetic loss material, i.e., ferrite, with a holding material, i.e., rubber. A radio wave reflective layer 11 is laminated integrally on the rear of the radio wave absorbing layer 10. The radio wave reflective layer 11 is provided by subjecting a polyester fiber cloth to electroless plating of nickel and copper. Accuracy is not required in the bonding thickness of the radio wave absorbent and a body to be applied because of the integrated radio wave reflector and workability is enhanced, especially at the time of mounting onto a curved face, because of the flexibility. The radio wave absorbing layer 10 may employ an ohmic loss material such as carbon or other loss material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、レーダゴースト防止
(偽像防止)、構造物からの電磁波の散乱等の反射防止
に用いられる薄型電波吸収体に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thin electromagnetic wave absorber used for preventing radar ghosts (preventing false images) and for preventing reflection of electromagnetic waves scattered from structures.

【0002】[0002]

【従来の技術】近年、電波の利用が進むにつれて、電波
障害、電波による誤動作等の問題がしばしば発生してい
る。このような問題を解決する対策として、薄型電波吸
収体を電波の反射、散乱等が大きい構造物に装着するこ
とが行われており、これによってその構造物からの電波
散乱を抑える等して大きな効果を奏している。
2. Description of the Related Art In recent years, as the use of radio waves has advanced, problems such as radio wave interference and malfunction due to radio waves have often occurred. As a measure to solve such a problem, a thin electromagnetic wave absorber is mounted on a structure having a large reflection and scattering of electromagnetic waves, which suppresses the scattering of the electromagnetic waves from the structure. It has an effect.

【0003】薄型電波吸収体は、一般に、例えばフェラ
イト等の磁性損失材又はカーボン等のオーム損失材をゴ
ム、樹脂等の保持材に混合させてなる電波吸収材とその
裏面に配置される金属等の電波反射体とから構成され
る。このような薄型電波吸収体を構造物に装着する場
合、構造物の形状が多様であることからその形状に適合
するように柔軟性のある電波吸収体を用いることが要求
される。
The thin electromagnetic wave absorber is generally a electromagnetic wave absorbing material formed by mixing a magnetic loss material such as ferrite or an ohmic loss material such as carbon with a holding material such as rubber and resin, and a metal disposed on the back surface thereof. And a radio wave reflector of. When such a thin electromagnetic wave absorber is attached to a structure, since the structure has various shapes, it is required to use a flexible electromagnetic wave absorber so as to conform to the shape.

【0004】薄型電波吸収体を構造物(一般には金属
体)に装着させる方法として、電波反射体のない柔軟な
電波吸収材を接着剤等によりその構造物(金属体)に直
接的に装着し、その構造物を電波反射体として利用する
方法、及び柔軟な電波吸収材に金属箔等の電波反射体を
あらかじめ裏打ちしたものを構造物に装着する方法があ
る。
As a method of mounting the thin wave absorber on a structure (generally a metal body), a flexible wave absorber without a wave reflector is directly attached to the structure (metal body) with an adhesive or the like. There is a method of using the structure as a radio wave reflector, and a method of mounting a flexible radio wave absorber on which a radio wave reflector such as a metal foil is lined in advance.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、電波吸
収材を構造物に直接的に接着する方法においては、電波
吸収材と構造物との間の接着層の厚さが電波吸収性能に
影響するため、接着層の厚さを制御して装着する必要が
あり、電波吸収材の装着作業は容易ではない。
However, in the method of directly bonding the electromagnetic wave absorber to the structure, the thickness of the adhesive layer between the electromagnetic wave absorber and the structure affects the electromagnetic wave absorption performance. Since it is necessary to control the thickness of the adhesive layer to mount it, the work of mounting the electromagnetic wave absorber is not easy.

【0006】また、電波吸収材と電波反射体とをあらか
じめ一体化しておく従来技術には、電波反射体として、
金属箔、金属蒸着フィルム、金属繊維布、炭素繊維布、
又は金属めっきガラス繊維布等を用いる方法がある。
Further, in the prior art in which the radio wave absorber and the radio wave reflector are integrated in advance, as a radio wave reflector,
Metal foil, metal deposition film, metal fiber cloth, carbon fiber cloth,
Alternatively, there is a method using a metal-plated glass fiber cloth or the like.

【0007】しかしながら、金属箔を用いた場合、これ
がほとんど伸縮しないものであるため、電波吸収材と一
体化して折り曲げ等を行うと金属箔にしわや亀裂を生じ
これが損傷してしまう。
However, when a metal foil is used, since it hardly expands or contracts, wrinkles or cracks are formed in the metal foil when it is integrated with the electromagnetic wave absorber and bent, and this is damaged.

【0008】金属蒸着フィルムを用いた場合、蒸着膜が
折り曲げ等により損傷しやすく、しかも電波吸収材と一
体化したときにフィルムに伸縮性がないので柔軟性が劣
化してしまう。
When a metal vapor deposition film is used, the vapor deposition film is easily damaged by bending or the like, and when it is integrated with a radio wave absorber, the film does not have stretchability, resulting in deterioration of flexibility.

【0009】金属繊維布を用いた場合、繊維が金属であ
ることから折り曲げを行うと復元しにくく、加工性に問
題がある。また、折り曲げ等を行うと金属箔と同様にし
わが入ってしまう。
When a metal fiber cloth is used, since the fiber is metal, it is difficult to restore it when it is bent, and there is a problem in workability. Moreover, when it is bent, wrinkles are formed as in the case of the metal foil.

【0010】炭素繊維布、金属めっきガラス繊維布を用
いた場合、電波吸収材と繊維布とを加熱して一体成形す
ると、繊維布の熱膨張率が電波吸収体のそれに対して小
さいことから電波吸収体が変形するという問題がある。
When a carbon fiber cloth or a metal-plated glass fiber cloth is used, if the electromagnetic wave absorber and the fiber cloth are heated and integrally molded, the coefficient of thermal expansion of the fiber cloth is smaller than that of the electromagnetic wave absorber, so that the electromagnetic wave There is a problem that the absorber is deformed.

【0011】従って本発明は、従来技術の上述の問題点
を解決するためになされたものであり、電波反射体を一
体化してなり柔軟性を有する薄型電波吸収体を提供する
ものである。
Therefore, the present invention has been made to solve the above-mentioned problems of the prior art, and provides a thin wave absorber having flexibility by integrating a wave reflector.

【0012】[0012]

【課題を解決するための手段】本発明によれば、電磁波
エネルギ損失材と保持材とを混合してなる可撓性のシー
ト状電波吸収層と、このシート状電波吸収層の裏面に積
層されており、有機繊維布に高導電性金属材料を無電解
めっきしてなる電波反射層とを備えた薄型電波吸収体が
提供される。
According to the present invention, a flexible sheet-shaped electromagnetic wave absorbing layer formed by mixing an electromagnetic wave energy loss material and a holding material is laminated on the back surface of the sheet-shaped electromagnetic wave absorbing layer. Accordingly, a thin wave absorber provided with a radio wave reflection layer formed by electrolessly plating a highly conductive metal material on an organic fiber cloth is provided.

【0013】シート状電波吸収層の前面に被着された有
機高分子フィルム又は有機塗膜等の有機保護膜をさらに
備えることが好ましい。
It is preferable to further include an organic protective film such as an organic polymer film or an organic coating film deposited on the front surface of the sheet-shaped electromagnetic wave absorbing layer.

【0014】電波反射層の表面抵抗が0.5Ω/□以下
であることが好ましい。
The surface resistance of the radio wave reflection layer is preferably 0.5Ω / □ or less.

【0015】高導電性金属材料は、ニッケル、銅、又は
銀を含むことが好ましい。
The highly conductive metal material preferably contains nickel, copper, or silver.

【0016】[0016]

【作用】電波反射層として、導電性有機繊維布にニッケ
ル、銅、又は銀等の高導電性金属材料を無電解めっきし
て表面抵抗が0.5Ω/□以下という高導電性を実現し
ているため、充分な電波反射特性を有しておりかつ有機
繊維布という基材を用いているので伸縮性に富み折り曲
げ等に強くしかも電波吸収材との一体化も容易に行え
る。従ってこのような電波反射層を用いて電波吸収体を
形成することにより、柔軟性を有し曲面部への装着が容
易な薄型電波吸収体が得られる。
[Function] As a radio wave reflection layer, a conductive organic fiber cloth is electrolessly plated with a highly conductive metal material such as nickel, copper or silver to realize a high conductivity of 0.5Ω / □ or less. Therefore, since it has a sufficient radio wave reflection property and uses a base material such as an organic fiber cloth, it is highly stretchable, resistant to bending and easily integrated with a radio wave absorber. Therefore, by forming a radio wave absorber using such a radio wave reflection layer, it is possible to obtain a thin radio wave absorber which is flexible and easy to mount on a curved surface portion.

【0017】[0017]

【実施例】以下図面を用いて本発明の実施例を詳細に説
明する。
Embodiments of the present invention will be described in detail below with reference to the drawings.

【0018】図1は、本発明の一実施例である薄型電波
吸収体の斜視図である。
FIG. 1 is a perspective view of a thin electromagnetic wave absorber which is an embodiment of the present invention.

【0019】同図において、10は磁性損失材であるフ
ェライトの粉末を保持材であるゴムに混合させてなる可
撓性を有するシート状の電波吸収層である。この電波吸
収層10は、厚さ2.5mmに形成されており、その裏
面には電波反射層11が一体的に積層形成されている。
この電波反射層11は、ポリエステル繊維布にニッケル
及び銅を無電解めっきを施してなり、その表面抵抗は本
実施例では0.1Ω/□以下に設定されている。
In the figure, 10 is a flexible sheet-shaped electromagnetic wave absorbing layer formed by mixing ferrite powder, which is a magnetic loss material, with rubber, which is a holding material. The radio wave absorption layer 10 is formed to have a thickness of 2.5 mm, and a radio wave reflection layer 11 is integrally laminated on the back surface thereof.
The radio wave reflection layer 11 is formed by electrolessly plating a polyester fiber cloth with nickel and copper, and its surface resistance is set to 0.1 Ω / □ or less in this embodiment.

【0020】図2は、図1の実施例の薄型電波吸収体に
おける周波数対反射係数の特性を示している。同図から
も明らかのように、本実施例の薄型電波吸収体は、特に
ほぼ10GHz付近で大きな減衰量を備えている優れた
電波吸収特性を有している。
FIG. 2 shows the frequency-reflection coefficient characteristic of the thin electromagnetic wave absorber of the embodiment shown in FIG. As is clear from the figure, the thin electromagnetic wave absorber of this embodiment has excellent electromagnetic wave absorption characteristics with a large amount of attenuation, especially at around 10 GHz.

【0021】この薄型電波吸収体を、図3に示すよう
に、直径30mm(30φ)の円筒棒12に巻付けて曲
げた後、特性及び外観の評価を再度行ったが、巻付け前
と全く変わらなかった。
As shown in FIG. 3, the thin electromagnetic wave absorber was wound around a cylindrical rod 12 having a diameter of 30 mm (30φ) and bent, and the characteristics and appearance were evaluated again. It didn't change.

【0022】一方、図1の実施例における電波吸収層1
0と同様の電波吸収層に厚さ25μmのアルミ箔を一体
化して積層形成した電波吸収体を、この円筒棒12に巻
付けて曲げた後、特性及び外観の評価を行うと、電波反
射層であるアルミ箔に亀裂が生じた。
On the other hand, the radio wave absorption layer 1 in the embodiment of FIG.
A radio wave absorber formed by integrally laminating a 25 μm thick aluminum foil on a radio wave absorption layer similar to that of No. 0 was wound around this cylindrical rod 12 and bent, and then the characteristics and appearance were evaluated. A crack was formed in the aluminum foil.

【0023】図4は、本発明の他の実施例である薄型電
波吸収体の斜視図である。
FIG. 4 is a perspective view of a thin electromagnetic wave absorber according to another embodiment of the present invention.

【0024】この実施例では、図1の実施例と同様の電
波吸収層10の裏面に電波反射層11を一体的に積層形
成し、さらに電波吸収層10の表面に有機保護膜13を
積層したものである。有機保護膜13は、本実施例では
厚さ50μmのフッ素系樹脂から形成されており、電波
吸収層10の表面を保護するものである。
In this embodiment, a radio wave reflection layer 11 is integrally laminated on the back surface of the radio wave absorption layer 10 as in the embodiment of FIG. 1, and an organic protective film 13 is further laminated on the front surface of the radio wave absorption layer 10. It is a thing. In this embodiment, the organic protective film 13 is made of a fluorine-based resin having a thickness of 50 μm and protects the surface of the radio wave absorption layer 10.

【0025】図5は、図4の実施例の薄型電波吸収体に
おける周波数対反射係数の特性を示している。同図から
も明らかのように、本実施例の薄型電波吸収体は、特に
ほぼ10GHz付近で大きな減衰量を備えている優れた
電波吸収特性を有している。
FIG. 5 shows the frequency-reflection coefficient characteristic of the thin electromagnetic wave absorber of the embodiment shown in FIG. As is clear from the figure, the thin electromagnetic wave absorber of this embodiment has excellent electromagnetic wave absorption characteristics with a large amount of attenuation, especially at around 10 GHz.

【0026】本実施例の作用効果は、図1の実施例とほ
ぼ同様である。
The operation and effect of this embodiment are almost the same as those of the embodiment of FIG.

【0027】上述した実施例では、電波吸収層10とし
て、磁性損失材であるフェライトを用いているが、これ
は例えばカーボン等のオーム損失材又は他の損失材を用
いてもよいことは明らかである。保持材も電波吸収層が
可撓性となるようなものであればどのようなものであっ
てもよい。
In the above-mentioned embodiments, the electromagnetic wave absorbing layer 10 is made of ferrite which is a magnetic loss material. However, it is obvious that ohmic loss material such as carbon or other loss material may be used. is there. The holding material may be any material as long as the radio wave absorption layer is flexible.

【0028】また、電波反射層11として、ポリエステ
ル繊維布とは異なる有機繊維布を用いてもよいし、ニッ
ケル及び銅の他に銀を無電解めっきしてもよい。
As the radio wave reflection layer 11, an organic fiber cloth different from polyester fiber cloth may be used, or silver may be electroless plated in addition to nickel and copper.

【0029】さらに、有機保護膜13として、フッ素系
樹脂とは異なる有機高分子フィルム、有機塗膜を用いて
もよい。
Further, as the organic protective film 13, an organic polymer film or an organic coating film different from fluorine resin may be used.

【0030】[0030]

【発明の効果】以上詳細に説明したように本発明では、
電磁波エネルギ損失材と保持材とを混合してなる可撓性
のシート状電波吸収層と、このシート状電波吸収層の裏
面に積層されており、有機繊維布に高導電性金属材料を
無電解めっきしてなる電波反射層とを備えている。この
ように、電波反射体が一体化しているので電波吸収体と
被着体間の接着厚さの精度が要求されず、しかも柔軟性
を有しているので施工が行い易く曲面部への装着が非常
に容易となる。
As described in detail above, according to the present invention,
A flexible sheet-shaped electromagnetic wave absorption layer formed by mixing an electromagnetic energy loss material and a holding material, and laminated on the back side of this sheet-shaped electromagnetic wave absorption layer. And a radio wave reflection layer formed by plating. In this way, since the radio wave reflector is integrated, the accuracy of the adhesive thickness between the radio wave absorber and the adherend is not required, and since it has flexibility, it can be easily installed and mounted on a curved surface. Becomes very easy.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例である薄型電波吸収体の斜視
図である。
FIG. 1 is a perspective view of a thin electromagnetic wave absorber that is an embodiment of the present invention.

【図2】図1の実施例における周波数対反射係数の特性
図である。
2 is a characteristic diagram of frequency vs. reflection coefficient in the embodiment of FIG.

【図3】図1の実施例の薄型電波吸収体を円筒棒に巻付
けて曲げた状態を表す斜視図である。
FIG. 3 is a perspective view showing a state where the thin electromagnetic wave absorber of the embodiment of FIG. 1 is wound around a cylindrical rod and bent.

【図4】本発明の他の実施例である薄型電波吸収体の斜
視図である。
FIG. 4 is a perspective view of a thin electromagnetic wave absorber that is another embodiment of the present invention.

【図5】図4の実施例における周波数対反射係数の特性
図である。
5 is a characteristic diagram of frequency vs. reflection coefficient in the embodiment of FIG.

【符号の説明】[Explanation of symbols]

10 電波吸収層 11 電波反射層 12 円筒棒 13 有機保護膜 10 Radio wave absorption layer 11 Radio wave reflection layer 12 Cylindrical rod 13 Organic protective film

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 電磁波エネルギ損失材と保持材とを混合
してなる可撓性のシート状電波吸収層と、該シート状電
波吸収層の裏面に積層されており、有機繊維布に高導電
性金属材料を無電解めっきしてなる電波反射層とを備え
たことを特徴とする薄型電波吸収体。
1. A flexible sheet-shaped electromagnetic wave absorption layer formed by mixing an electromagnetic wave energy loss material and a holding material, and laminated on the back surface of the sheet-shaped electromagnetic wave absorption layer, and made of an organic fiber cloth with high conductivity. A thin radio wave absorber comprising a radio wave reflection layer formed by electrolessly plating a metal material.
【請求項2】 前記シート状電波吸収層の前面に被着さ
れた有機保護膜をさらに備えたことを特徴とする請求項
1に記載の薄型電波吸収体。
2. The thin electromagnetic wave absorber according to claim 1, further comprising an organic protective film deposited on the front surface of the sheet-shaped electromagnetic wave absorbing layer.
【請求項3】 前記有機保護膜が有機高分子フィルムで
あることを特徴とする請求項2に記載の薄型電波吸収
体。
3. The thin electromagnetic wave absorber according to claim 2, wherein the organic protective film is an organic polymer film.
【請求項4】 前記有機保護膜が有機塗膜であることを
特徴とする請求項2に記載の薄型電波吸収体。
4. The thin electromagnetic wave absorber according to claim 2, wherein the organic protective film is an organic coating film.
【請求項5】 前記電波反射層の表面抵抗が0.5Ω/
□以下であることを特徴とする請求項1から4のいずれ
か1項に記載の薄型電波吸収体。
5. The surface resistance of the radio wave reflection layer is 0.5 Ω /
□ The following is a thin electromagnetic wave absorber according to any one of claims 1 to 4.
【請求項6】 前記高導電性金属材料がニッケルを含む
ことを特徴とする請求項1から5のいずれか1項に記載
の薄型電波吸収体。
6. The thin electromagnetic wave absorber according to claim 1, wherein the highly conductive metal material contains nickel.
【請求項7】 前記高導電性金属材料が銅を含むことを
特徴とする請求項1から5のいずれか1項に記載の薄型
電波吸収体。
7. The thin electromagnetic wave absorber according to claim 1, wherein the highly conductive metal material contains copper.
【請求項8】 前記高導電性金属材料が銀を含むことを
特徴とする請求項1から5のいずれか1項に記載の薄型
電波吸収体。
8. The thin electromagnetic wave absorber according to claim 1, wherein the highly conductive metal material contains silver.
JP04226546A 1992-08-04 1992-08-04 Thin radio wave absorber Expired - Fee Related JP3097343B2 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6426457B1 (en) * 1998-04-27 2002-07-30 Sony Corporation Apparatus and method for shielding electromagnetic wave
JP2006332260A (en) * 2005-05-25 2006-12-07 Hajime Murazaki Material and structure for shielding electromagnetic wave
JP2011143096A (en) * 2009-12-14 2011-07-28 Yokohama Rubber Co Ltd:The Ball for ball game

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002329995A (en) 2001-05-07 2002-11-15 Shin Etsu Chem Co Ltd Electromagnetic wave absorbing body

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JPS5947707A (en) * 1982-09-13 1984-03-17 Tdk Corp Composite ferrite and preparation thereof
JPS59171397U (en) * 1983-04-28 1984-11-16 株式会社 高瀬染工場 Electromagnetic shielding material
JPS6057700A (en) * 1983-09-08 1985-04-03 ティーディーケイ株式会社 Electromagnetic shielding material
JPS61253373A (en) * 1985-04-30 1986-11-11 Chihiro Kogyo:Kk Electromagnetic-wave shielding material and its manufacture
JPH01107598A (en) * 1987-10-20 1989-04-25 Nec Corp Radiowave absorbing body
JPH03167893A (en) * 1989-11-28 1991-07-19 Yokohama Rubber Co Ltd:The Electric wave-absorbing material
JPH04153034A (en) * 1990-10-17 1992-05-26 Kanai Hiroyuki Electromagnetic wave shielding interior material
JPH04340299A (en) * 1991-01-16 1992-11-26 Tech Res & Dev Inst Of Japan Def Agency Millimeter radio wave absorber

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
JPS5947707A (en) * 1982-09-13 1984-03-17 Tdk Corp Composite ferrite and preparation thereof
JPS59171397U (en) * 1983-04-28 1984-11-16 株式会社 高瀬染工場 Electromagnetic shielding material
JPS6057700A (en) * 1983-09-08 1985-04-03 ティーディーケイ株式会社 Electromagnetic shielding material
JPS61253373A (en) * 1985-04-30 1986-11-11 Chihiro Kogyo:Kk Electromagnetic-wave shielding material and its manufacture
JPH01107598A (en) * 1987-10-20 1989-04-25 Nec Corp Radiowave absorbing body
JPH03167893A (en) * 1989-11-28 1991-07-19 Yokohama Rubber Co Ltd:The Electric wave-absorbing material
JPH04153034A (en) * 1990-10-17 1992-05-26 Kanai Hiroyuki Electromagnetic wave shielding interior material
JPH04340299A (en) * 1991-01-16 1992-11-26 Tech Res & Dev Inst Of Japan Def Agency Millimeter radio wave absorber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6426457B1 (en) * 1998-04-27 2002-07-30 Sony Corporation Apparatus and method for shielding electromagnetic wave
JP2006332260A (en) * 2005-05-25 2006-12-07 Hajime Murazaki Material and structure for shielding electromagnetic wave
JP2011143096A (en) * 2009-12-14 2011-07-28 Yokohama Rubber Co Ltd:The Ball for ball game

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