JPH0657190A - Ink composition for ink jet printing - Google Patents

Abstract

PURPOSE:To obtain the ink compsn. which contains a dye in a high concn., caures neither thickening nor precipitation of crystals even if stored in a long time, and has been improved in fastness, facing resistance, and reproducibility of dyeing by incorporating a specific reactive dye into the compsn. CONSTITUTION:The ink compsn. is prepd. by dissolving, in water, 1-50wt.% hydrophilic org. solvent, 1-30wt.% reactive dye of the formula (wherein Me is Cr or Co; and M is Na and/or K) contg. 1wt.% or lower inorg. salt, and, if necessary, 1-30wt.% urea and/or epsilon-caprolactam as a dissolution aid.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a reactive dye ink composition for ink jet printing. In particular, woven or non-woven fabrics made of fibers dyeable with a reactive dye such as cotton, hemp, viscose, wool, silk, nylon, etc., or mixed woven fabrics or non-woven fabrics made of these fibers and other fibers The present invention relates to an ink composition for inkjet printing, which is suitable for printing.

[0002]

2. Description of the Related Art Conventionally, a so-called ink jet printing method has been known in which ink droplets are ejected from a minute ejection orifice to perform printing. Various types of printing methods have been proposed. For example, a device that gives a signal to a printer head having a piezo-vibrator, generates ink droplets according to the signal, and prints,
A device that electrostatically attracts ink and controls the generated droplets by an electric field according to a signal to perform printing, generates droplets whose charge amount is controlled by a continuous vibration generation method, and generates a uniform electric field by the droplets. Many methods are known, such as one in which printing is performed by flying between deflection electrodes to which is applied.

In such an ink jet printing method, ink droplets are ejected, and the ink droplets are attached to a material to be dyed for printing. Such an ink has a colorant and a liquid medium (for which water or various organic solvents or a mixture thereof is used) that dissolves the colorant as a basic component, and various additives are added as necessary.

The preferable conditions for this type of ink are:
Does not clog the discharge orifice, has liquid properties suitable for discharge (viscosity, surface tension, electrical conductivity, etc.), does not cause changes in physical properties or solid content during storage,
Providing a high concentration of dyeing material, fast fixing to the dyeing material, little ink bleeding, excellent water resistance and light resistance, less odor and toxicity, and safe for flammability It is excellent.

Since the ink applied to the print for the purpose is basically composed of the dye and the solvent thereof as described above, the characteristics of the above-mentioned ink have the components used as the dye and the liquid medium. It is greatly influenced by its inherent properties. Therefore, it is a very important technique in the technical field to select the dye and the liquid medium so that the ink has the above characteristics.

Further, it is a recent social demand from the environmental aspect that the BOD and COD loads of the waste water after dyeing are reduced. Although the ink jet printing method has made it possible to greatly reduce the printing paste, it is desirable that the ink side itself has a small drainage load. That is, it is desired that the amount of various additives added is small and the dye has a high concentration and good storage stability over a long period of time. From this viewpoint as well, it is more important to select a dye, a dissolution aid and a liquid medium. Technology.

Further, in ink jet printing, normally,
The three primary colors (yellow, red, blue) and black are used, but in order to mix and output a wide range of hues, it is particularly required that the three primary colors (yellow, red, blue) be vivid hues. Further, it is required that the dye used for printing on the fiber is excellent in dyeing properties, for example, dyeing reproducibility, various fastnesses, and white field stain resistance.

[0008]

The addition amount of various additives is small, the dye concentration is sufficiently high, and the viscosity is stable and does not cause crystal precipitation even when left for a long period of time. Development of an excellent ink composition for inkjet printing is desired.

[0009]

The present inventors have accomplished the present invention as a result of intensive studies to solve the above-mentioned problems. That is, the present invention relates to the above formula (1)

[0010]

[Chemical 2]

(Wherein Me represents a chromium atom and / or a cobalt atom, M represents a sodium atom or a potassium atom, and M may be a mixture of a sodium atom and a potassium atom). At least (the ink composition for ink jet printing for fibers containing one kind (hereinafter simply referred to as ink composition). The present invention will be described in detail below. The liquid medium of the ink composition of the present invention is at least water or preferably Is a liquid medium containing ion-exchanged water and a hydrophilic organic solvent, in which the hydrophilic organic solvent has an effect as a non-drying agent and has a role of preventing solid matter from being generated by drying. It is necessary to select one that has the function of adjusting the viscosity of the ink composition and does not hinder the solubility of the reactive dye represented by the general formula (1). Shall.

Examples of the hydrophilic organic solvent include polyalkylene glycols such as polyethylene glycol and polypropylene glycol; alkylene glycols such as ethylene glycol, propylene glycol and butylene glycol. Glycerin; N-methyl-2-pyrrolidone,
One or more nitrogen-containing heterocyclic ketones such as 1,3-dimethyl-2-imidazolidinone can be used as a liquid medium component.

The content of the above-mentioned hydrophilic organic solvent in the ink composition is generally 1% by weight based on the total weight of the ink liquid.
50%, preferably 3-40%, more preferably 5-2
The range is 5%.

In the ink composition of the present invention, a solubilizing agent can be added to prevent the dye from precipitating in the composition. In that case, urea and / or ε-caprolactam is contained in the composition as a dissolution aid in an amount of 1 to 30% by weight.
It is preferable to contain, preferably 1 to 20%.

The dye (colorant) used in the present invention has the structure of the above formula (1), but is generally sodium chloride,
Inorganic salts such as Glauber's salt are mixed in during dye synthesis. Further, calcium ions, magnesium ions, etc. contained in general water are mixed in in a trace amount. These inorganic components not only significantly deteriorate the solubility and storage stability of the dye, but also cause corrosion and abrasion of the printer head.

In order to remove these inorganic salts, methods such as ultrafiltration, reverse osmosis and ion exchange are used, and it is desirable to remove the inorganic salts as much as possible, but in practice a standard is set. Must be managed. At least 1
It is necessary to set the content to not more than 0.5% by weight, preferably not more than 0.5% by weight, more preferably not more than 0.1% by weight.

Although the desired dye concentration is obtained by diluting or concentrating after removing the inorganic salts, the ink composition of the present invention can contain 1 to 30% by weight of the dye component, and practically 5 to 25. Weight percent is preferred. After being prepared from such components, liquid filtration is performed using a cellulosic filter aid to remove dust, foreign matter, and other insoluble materials, and then a membrane filter (pore size 1 micron) is used for precision filtration. It is filtered and further microfiltered with a membrane filter having a pore size of 0.45 micron.

The ink composition for ink-jet printing of the present invention thus prepared is characterized in that it is particularly excellent in stability and long-term storability among various characteristics and does not clog the discharge orifice. In addition, stabilizers for coloring agents (polyacrylic acid soda, for example, Kayakylator-C-1000 manufactured by Nippon Kayaku Co., Ltd.) and antibacterial / antifungal agents (for example, Deltop manufactured by Takeda Pharmaceutical Co., Ltd.) Etc.) is added at a stage before microfiltration.

[0019]

EXAMPLES The present invention will be specifically described with reference to examples.
The invention is not limited to only these examples.
In the text, parts and% are based on weight.

Example 1 The following formula (2) obtained by synthesis by a general method such as diazotization and coupling

[0021]

[Chemical 3]

After adjusting the pH of the reaction solution containing 20 parts of the reactive dye of 6 to 6 to 8, the solution is filtered to remove insoluble matter. Next, the salt is desalted by the reverse osmosis method to make the inorganic salts 0.5% or less, and the following substances are added to this liquid.

Ε-caprolactam 10 parts Propylene glycol 5 parts Sodium polyacrylate 1 part After liquid filtration of this liquid again, a membrane filter with a pore size of 1 micron was used to further refine with a membrane filter of 0.45 micron. The mixture was filtered and adjusted to a total amount of 100 parts with ion-exchanged water to obtain an ink composition for inkjet printing of the present invention.

The ink composition for ink jet printing obtained in this example showed good stability for one month or more even at room temperature or low temperature (0 degree Celsius).

Example 2 Dye synthesis and desalting were carried out according to Example 1, and the following substances were added. ε-caprolactam 10 parts Propylene glycol 15 parts Sodium polyacrylate 1 part

This liquid was microfiltered in the same manner as in Example 1 and adjusted to a total amount of 100 parts with ion-exchanged water to obtain an ink composition for inkjet printing of the present invention. The ink composition for inkjet printing obtained in this example showed good stability for one month or more even at room temperature or low temperature (0 degree Celsius).

Using the inks obtained according to the above examples,
An on-demand inkjet printer was used to print on a 100% cotton blown fabric (mercerized product) that had been pretreated, air dried, steamed at 100 ° C for 10 minutes, washed with water, and soaped. A dyed product of The obtained dyed product was excellent in dyeing reproducibility and white field stain resistance.

[0028]

EFFECTS OF THE INVENTION According to the present invention, an ink composition for ink jet printing for fibers is obtained which has a high dye concentration and does not cause precipitation of crystals with increased viscosity even when stored for a long period of time.

Claims (4)

[Claims] 1. An ink composition for ink-jet printing for fibers, which comprises at least one reactive dye represented by the general formula (1). [Chemical 1] (In the formula, Me represents a chromium atom or a cobalt atom,
M represents a sodium atom or a potassium atom. Also, M
May be a mixture of sodium atom and potassium atom. ) 2. A water-soluble organic solvent containing water and a hydrophilic organic solvent.
Ink composition for ink jet printing according to 3. The ink composition for inkjet printing according to claim 1, which contains 1 to 30% of urea and / or ε-caprolactam as a dissolution aid. 4. An inorganic salt concentration of 1% by weight or less.
Or the ink composition for inkjet printing according to item 3.