JPH06314586A - Composite material for discharge electrode - Google Patents

Composite material for discharge electrode

Info

Publication number
JPH06314586A
JPH06314586A JP12794393A JP12794393A JPH06314586A JP H06314586 A JPH06314586 A JP H06314586A JP 12794393 A JP12794393 A JP 12794393A JP 12794393 A JP12794393 A JP 12794393A JP H06314586 A JPH06314586 A JP H06314586A
Authority
JP
Japan
Prior art keywords
alloy
discharge electrode
stable
range
covering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12794393A
Other languages
Japanese (ja)
Inventor
Mitsuyoshi Sayama
光義 佐山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tanaka Kikinzoku Kogyo KK
Original Assignee
Tanaka Kikinzoku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tanaka Kikinzoku Kogyo KK filed Critical Tanaka Kikinzoku Kogyo KK
Priority to JP12794393A priority Critical patent/JPH06314586A/en
Publication of JPH06314586A publication Critical patent/JPH06314586A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To prevent oxidation so as to provide a stable discharge electrode characteristic by covering Ni or an Ni alloy with Pt, a Pt alloy, or Au, an Au alloy. CONSTITUTION:A discharge electrode made from an Ni alloy is covered with Pt, a Pt alloy or Au, an Au alloy all of which are chemically stable, so as to prevent oxidation and to improve a discharge electrode characteristic through thermally and electrically stable characteristics. The thickness of the cover is 0.04 to 2.5% of the diameter of wire. Below that range, the effect of covering is small and it is difficult to achieve stable covering at uniform thickness; above that range, the cost increases and no corresponding effect can be expected. The strength at which a discharge electrode machine is joined to the cover is secured and the condition for an effective heat treatment to restrain diffusion is 500 to 1000 deg.C. Below that temperature range, removal of distortion and annealing become insufficient, while when that range is exceeded a core and an outer cover material are diffused from each other, resulting in the deterioration of their characteristics. Materials are combined by pipe insertion method or extrusion method, etc.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、放電を伴う電極用材料
に係り、特に化学的、熱的、電気的侵食に伴う条件、環
境、雰囲気で用いられる芯材と外被材とからなる複合材
料に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a material for an electrode accompanied by electric discharge, and more particularly to a composite consisting of a core material and an outer coating material used under conditions, environments and atmospheres associated with chemical, thermal and electrical erosion. It is about materials.

【0002】[0002]

【従来技術と課題】従来、放電を伴う電極用材料として
耐アーク消耗特性の優れていることからNi系合金材料
等が用いられている。しかし、これらの合金材料は酸化
による強固な被覆を生成し易く、従って酸化物が堆積し
てくると放電特性を損なうこととなり安定した特性が得
られないという課題があった。
2. Description of the Related Art Conventionally, Ni-based alloy materials and the like have been used as materials for electrodes accompanied by discharge because of their excellent arc wear resistance. However, these alloy materials tend to form a strong coating due to oxidation, and therefore, when oxides are deposited, there is a problem that discharge characteristics are impaired and stable characteristics cannot be obtained.

【0003】[0003]

【発明の目的】本発明は上記課題を解決すべくなされた
もので、酸化し難く従って酸化物の堆積し難い放電特性
の安定で良好な放電電極用複合材料を提供するものであ
る。
SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and provides a composite material for a discharge electrode, which is stable and has good discharge characteristics in which it is difficult to oxidize and therefore oxides do not easily deposit.

【0004】[0004]

【発明の構成】本発明の放電電極用複合材料はNiまた
はNi系合金材料の外周をPt、Pt合金、Auまたは
Au合金で被覆したことを特徴とするものである。
The discharge electrode composite material of the present invention is characterized in that the outer periphery of Ni or Ni-based alloy material is coated with Pt, Pt alloy, Au or Au alloy.

【0005】[0005]

【作用】上記のように構成された本発明の放電電極用複
合材料は化学的に安定なPt、Pt合金、AuまたはA
u合金でNiまたはNi系合金材料の外周を被覆してな
るので、酸化し難く従って酸化物の堆積し難く、また熱
的、電気的にも安定なPt、Pt合金、AuまたはAu
合金の特性とも相俟ってNiまたはNi系合金材料の放
電電極特性を更に改善するものである。なお、被覆の厚
みは線径の0.04〜 2.5%が好ましく、0.04%未満だと被
覆の効果が少なくまた均一な厚み、安定した被覆が困難
で、また、 2.5%を超えても厚みにみあうより以上の効
果は期待できず、更に高価なPt、Pt合金、Auまた
はAu合金により価格的制約を受けることとなる。また
NiまたはNi系合金材料とPt、Pt合金、Auまた
はAu合金との接合強度の確保または拡散防止の為、A
g、Cu、Ni、Mo等を介在させた複合材料とさせて
もいいものである。さらに、接合強度を確保しつつ拡散
を抑える為の効果的な熱処理条件は 500℃〜1000℃が好
ましく、 500℃未満だと熱処理による歪除去、焼鈍が不
十分で、1000℃を越えると芯材と外被材の相互拡散によ
り芯材と外被材の各々の特性が損なわれることとなるか
らである。また、複合の方法としてはパイプ挿入法、押
出し法、乾式めっき及び湿式めっき等適宜選択するもの
である。
The composite material for a discharge electrode of the present invention constructed as described above is chemically stable Pt, Pt alloy, Au or A.
Since the outer circumference of Ni or a Ni-based alloy material is coated with a u alloy, Pt, Pt alloy, Au, or Au which is hard to oxidize and therefore hard to deposit an oxide, and which is also thermally and electrically stable
Together with the characteristics of the alloy, the characteristics of the discharge electrode of Ni or a Ni-based alloy material are further improved. The coating thickness is preferably 0.04 to 2.5% of the wire diameter. If it is less than 0.04%, the coating effect is small, uniform thickness is difficult, and stable coating is difficult. No further effect can be expected, and more expensive Pt, Pt alloy, Au, or Au alloy imposes price restrictions. In order to secure the bonding strength between Ni or a Ni-based alloy material and Pt, Pt alloy, Au or Au alloy, or to prevent diffusion, A
A composite material having g, Cu, Ni, Mo, etc. interposed may be used. Furthermore, the effective heat treatment condition to secure the bonding strength and suppress the diffusion is preferably 500 ° C to 1000 ° C. If it is less than 500 ° C, strain removal and annealing due to heat treatment are insufficient, and if it exceeds 1000 ° C, the core material This is because the characteristics of the core material and the jacket material are impaired due to mutual diffusion of the jacket material and the jacket material. As the composite method, a pipe insertion method, an extrusion method, dry plating, wet plating, or the like is appropriately selected.

【0005】[0005]

【実施例】以下に実施例と従来例についてのべる。まず
実施例として下記表1のような外径 8.6mm、内径8mm,
材質Ptのパイプ材に外径 7.9mm、材質インコネル(Ni8
0%Cr14%Fe6%)の棒材を挿入し、伸線加工後、温度 800
℃、時間60分、雰囲気H2 +N2 中にて熱処理した後、
更に伸線加工を行った。その後熱処理、伸線加工を繰り
返し外径 1.0mmの実施例3の放電電極用複合材料とし
た。以下同様にして実施例1、2、4,比較例1、2、
3の放電電極用複合材料とした。一方、従来例として、
下記表1のような外径 8mm,材質インコネル(Ni80%Cr14
%Fe6%)及びNiの棒材から伸線加工、熱処理にて外径
1.0mmの従来例1、2の放電電極材料とした。然して、
各実施例、比較例、従来例の複合材料を各々長さ20mmに
切断し放電試験試料として、電圧3000V、電極間距離
1.0mm、60Hz/sec、連続放電時間 300Hの試験条件にて
放電試験を行った。その結果、下記表1の如くまとまっ
た。ここで伸線時の断線は、拡散による脆化、未接合に
よる外被材の亀裂等によるものであった。放電試験後の
摩耗(mm)は+極における酸化消耗によるものであった。
EXAMPLES Examples and conventional examples will be described below. First, as an example, as shown in Table 1 below, the outer diameter is 8.6 mm, the inner diameter is 8 mm,
Material Pt pipe material, outer diameter 7.9mm, material Inconel (Ni8
(0% Cr14% Fe6%) is inserted, and after drawing wire, the temperature is 800
After heat treatment in the atmosphere H 2 + N 2 for 60 minutes at ℃,
Further, wire drawing was performed. Thereafter, heat treatment and wire drawing were repeated to obtain a composite material for discharge electrode of Example 3 having an outer diameter of 1.0 mm. Similarly, Examples 1, 2, 4 and Comparative Examples 1, 2,
The discharge electrode composite material of No. 3 was used. On the other hand, as a conventional example,
The outer diameter is 8mm and the material is Inconel (Ni80% Cr14
% Fe6%) and Ni bar wire drawing and heat treatment
The discharge electrode material of Conventional Examples 1 and 2 having a thickness of 1.0 mm was used. However,
Each of the composite materials of Examples, Comparative Examples and Conventional Example was cut into a length of 20 mm and used as a discharge test sample with a voltage of 3000 V and an electrode distance
A discharge test was conducted under the test conditions of 1.0 mm, 60 Hz / sec, and continuous discharge time of 300 H. As a result, the results are summarized as shown in Table 1 below. Here, the wire breakage during wire drawing was due to embrittlement due to diffusion, cracking of the jacket material due to unbonding, and the like. The wear (mm) after the discharge test was due to oxidative consumption at the + electrode.

【0006】[0006]

【表1】 [Table 1]

【0007】[0007]

【発明の効果】以上の結果から明らかなように、本発明
の放電電極用複合材料によれば、化学的、熱的、電気的
に安定なPt、Pt合金、AuまたはAu合金でNiま
たはNi系合金材料の外周を被覆してなるので、酸化し
難く従って酸化物の堆積し難く良好で安定した放電電極
特性が得られるという優れた効果を有するものである。
As is clear from the above results, according to the discharge electrode composite material of the present invention, chemically or thermally stable Pt, Pt alloy, Au or Au alloy is Ni or Ni. Since the outer periphery of the base alloy material is coated, it is difficult to oxidize, and thus it is difficult to deposit an oxide, and it has an excellent effect that good and stable discharge electrode characteristics can be obtained.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 NiまたはNi系合金材料の外周をP
t、Pt合金、AuまたはAu合金で被覆したことを特
徴とする放電電極用複合材料。
1. The outer periphery of Ni or Ni-based alloy material is P
A composite material for a discharge electrode, which is coated with t, Pt alloy, Au, or Au alloy.
JP12794393A 1993-04-30 1993-04-30 Composite material for discharge electrode Pending JPH06314586A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12794393A JPH06314586A (en) 1993-04-30 1993-04-30 Composite material for discharge electrode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12794393A JPH06314586A (en) 1993-04-30 1993-04-30 Composite material for discharge electrode

Publications (1)

Publication Number Publication Date
JPH06314586A true JPH06314586A (en) 1994-11-08

Family

ID=14972476

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12794393A Pending JPH06314586A (en) 1993-04-30 1993-04-30 Composite material for discharge electrode

Country Status (1)

Country Link
JP (1) JPH06314586A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003080504A1 (en) * 2002-03-27 2003-10-02 Jisouken Co., Ltd. Device for forming hydrogen using hydrocarbon or oxygen-containing compound as material and discharge electrode for use therein

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003080504A1 (en) * 2002-03-27 2003-10-02 Jisouken Co., Ltd. Device for forming hydrogen using hydrocarbon or oxygen-containing compound as material and discharge electrode for use therein

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