JPH06294946A - Member of spectacles - Google Patents

Member of spectacles

Info

Publication number
JPH06294946A
JPH06294946A JP8184893A JP8184893A JPH06294946A JP H06294946 A JPH06294946 A JP H06294946A JP 8184893 A JP8184893 A JP 8184893A JP 8184893 A JP8184893 A JP 8184893A JP H06294946 A JPH06294946 A JP H06294946A
Authority
JP
Japan
Prior art keywords
shape memory
memory alloy
rim
alloy tube
lenses
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8184893A
Other languages
Japanese (ja)
Inventor
Kiyoshi Yamauchi
清 山内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokin Corp
Original Assignee
Tokin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokin Corp filed Critical Tokin Corp
Priority to JP8184893A priority Critical patent/JPH06294946A/en
Publication of JPH06294946A publication Critical patent/JPH06294946A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a member of spectacles showing basic characteristics as a shape memory alloy and having excellent durability and applicability. CONSTITUTION:A shape memory alloy tube produced from a Ti-Ni alloy material which shows superelasticity in the use environment at normal temp. is used as rims 10A, 10B of frames of spectacles. The shape memory alloy tube shows small deformation load against bending, so that lenses can be stably attached and detached. Further, the tube has high recovery strength so that enough constraint for lenses is maintained and lenses are stably fixed. Since the shape memory alloy tube has no residual strain against bending, it has good durability against attaching and detaching of lenses.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、常温使用環境下で適用
可能な形状記憶合金製部材を使用したメガネ部材に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a spectacle member using a shape memory alloy member applicable under normal temperature use environment.

【0002】[0002]

【従来の技術】一般に、形状記憶合金(例えばTi−N
i系合金やCu−Zn−Al系合金が挙げられる)は、
マルテンサイト変態の逆変態に付随して顕著な形状記憶
効果を示すことが知られている。又、形状記憶合金は、
逆変態の母相状態では良好な超弾性を示すことも知られ
ている。
2. Description of the Related Art Generally, shape memory alloys such as Ti--N are used.
i-based alloys and Cu-Zn-Al-based alloys)
It is known that a remarkable shape memory effect is exhibited in association with the reverse transformation of the martensitic transformation. Also, the shape memory alloy is
It is also known to exhibit good superelasticity in the reverse transformation matrix state.

【0003】例えば、形状記憶合金製の超弾性バネは、
伸び歪みが7%程度でも可逆な為、ステンレス線やピア
ノ線等とは異なり、コイル状にしなくても直線状バネと
して使用できる利点を持っている。このような直線状バ
ネ材は、変形防止や保型性の改善を図り得る長所を有す
るので、カテーテルガイドワイヤ,ブラジャーの芯金,
コルセットの芯金等に実用化されている。
For example, a superelastic spring made of shape memory alloy is
Since it is reversible even when the elongation strain is about 7%, it has the advantage that it can be used as a linear spring without forming a coil unlike stainless steel wire or piano wire. Since such a linear spring material has an advantage of being able to prevent deformation and improve shape retention, a catheter guide wire, a brass core bar,
It has been put to practical use as a core metal for corsets.

【0004】一方、近年では主としてメガネフレームを
構成するメガネ部材にも形状記憶合金が用いられてい
る。通常メガネ部材用の形状記憶合金製部材には、メガ
ネの装着時の変形をお湯等に入れて元に戻し得る形状記
憶性や、基本的に変形が生じ難い超弾性を有するものが
使用されている。
On the other hand, in recent years, shape memory alloys have been mainly used for eyeglass members which mainly constitute eyeglass frames. Usually, the shape memory alloy member for eyeglass members is one that has a shape memory property that allows deformation when wearing glasses to be returned to the original state by putting it in hot water, etc. There is.

【0005】具体的に云えば、メガネ部材の形状記憶合
金製部材には、主としてテンプル,ブリッジ,渡り等に
Ti−Ni合金材料が用いられている。
Specifically, a Ti-Ni alloy material is mainly used for the shape memory alloy member of the spectacle member, mainly for temples, bridges, transitions and the like.

【0006】[0006]

【発明が解決しようとする課題】ところで、従来のメガ
ネ部材の場合、リムにはバネ材が使用されている。この
リムに用いられるバネ材は、レンズを固定するフレーム
のバネ材となるもので、そのバネ材には口径φが0.5
mm程度の細線の使用が提案されている。
By the way, in the case of the conventional eyeglass member, a spring material is used for the rim. The spring material used for this rim is the spring material of the frame that fixes the lens, and the diameter φ of the spring material is 0.5.
The use of thin wires on the order of mm has been proposed.

【0007】しかしながら、形状記憶合金の回復可能な
伸歪みが7%程度の限界を示すのに対し、リムの長さが
50mm程度あることを考慮すれば、リムの最大可動範
囲は3.5mmであり、0.5mm程度の細線を使用す
るとレンズの装脱や固定には殆ど対応できず、実際には
実用化されていない。
However, while the recoverable elongation of the shape memory alloy shows a limit of about 7%, considering that the rim length is about 50 mm, the maximum movable range of the rim is 3.5 mm. However, if a thin wire of about 0.5 mm is used, it is hardly possible to mount or dismount the lens and it is not practically used.

【0008】この為、一般的なリムのバネ材にはステン
レス製のコイルバネが汎用的に使用されている。ところ
が、このステンレス製コイルバネの場合、リムとしてレ
ンズの固定を十分に行い得るように,即ち、バネの復元
力を強くするために可動範囲を抑える(弾性率を小さく
する)必要があり、繰り返しの装脱を行い難いという問
題がある。
Therefore, a coil spring made of stainless steel is generally used as a spring material for a general rim. However, in the case of this stainless steel coil spring, it is necessary to suppress the movable range (decrease the elastic modulus) in order to sufficiently fix the lens as the rim, that is, in order to strengthen the restoring force of the spring, and thus the repetition There is a problem that it is difficult to put on and take off.

【0009】本発明は、かかる問題点を解決すべくなさ
れたもので、その技術的課題は、形状記憶合金の基本特
性を活かし、耐久性及び適用性に優れたメガネ部材を提
供することにある。
The present invention has been made to solve the above problems, and a technical object thereof is to provide a spectacle member excellent in durability and applicability by utilizing the basic characteristics of the shape memory alloy. .

【0010】[0010]

【課題を解決するための手段】本発明によれば、形状記
憶合金製チューブと該形状記憶合金製チューブに結合さ
れた付加部材とから成るメガネフレーム用リム部材が得
られる。
According to the present invention, there is obtained a rim member for an eyeglass frame including a shape memory alloy tube and an additional member connected to the shape memory alloy tube.

【0011】一方、本発明によれば、形状記憶合金製チ
ューブから成るメガネフレーム用リム部材が得られる。
On the other hand, according to the present invention, a rim member for a spectacle frame made of a shape memory alloy tube can be obtained.

【0012】又、本発明によれば、上記何れかのメガネ
フレーム用リム部材において、形状記憶合金製チューブ
は、常温使用環境下で超弾性を示すTi−Ni系合金材
料から成るメガネフレーム用リム部材が得られる。
Further, according to the present invention, in any one of the above-mentioned rim members for spectacle frames, the shape memory alloy tube is a rim for spectacle frames, which is made of a Ti--Ni alloy material that exhibits superelasticity under normal temperature use environment. The member is obtained.

【0013】更に、本発明によれば、上記何れか一つに
記載のメガネフレーム用リム部材の2つと、これらのリ
ム部材間を結合した結合部材とを含むメガネフレームが
得られる。
Further, according to the present invention, there can be obtained an eyeglass frame including two of the eyeglass frame rim members described in any one of the above and a connecting member connecting the rim members.

【0014】加えて、本発明によれば、上記メガネフレ
ームと該メガネフレームに保持されたレンズとを含むメ
ガネが得られる。
In addition, according to the present invention, spectacles including the spectacle frame and the lenses held by the spectacle frame can be obtained.

【0015】[0015]

【実施例】以下に実施例を挙げ、本発明のメガネ部材に
ついて、図面を参照して詳細に説明する。最初に本発明
のメガネ部材の基本構成について簡単に説明する。
Embodiments Hereinafter, the eyeglass member of the present invention will be described in detail with reference to the drawings by referring to embodiments. First, the basic structure of the eyeglass member of the present invention will be briefly described.

【0016】このメガネ部材は、常温使用環境下で超弾
性を示すTi−Ni系合金材料を用いて製造した形状記
憶合金製チューブをメガネフレームのリムの一部か、或
いは全部に使用したものである。
This spectacle member is formed by using a shape memory alloy tube manufactured from a Ti-Ni alloy material that exhibits superelasticity at room temperature for use in part or all of the rim of the spectacle frame. is there.

【0017】そこで、以下はこのリムに用いられる形状
記憶合金製チューブの製造方法及びその特性について具
体的に説明する。
Therefore, the method of manufacturing the shape memory alloy tube used for this rim and its characteristics will be specifically described below.

【0018】先ず、高周波真空溶解法によりそれぞれT
i−50at%Ni合金材料,Ti−50.5at%N
i合金材料,Ti−51at%Ni合金材料を得た後、
これらの各合金材料を中実ビレットに加工し、引き続い
て機械加工により外径φ(o ut)が15mm,内径φ
(in)が11mmの3種別な筒体とした。
First, each of the T
i-50 at% Ni alloy material, Ti-50.5 at% N
After obtaining the i alloy material and the Ti-51 at% Ni alloy material,
Each of these alloy materials is machined into a solid billet, and subsequently machined to have an outer diameter φ ( out ) of 15 mm and an inner diameter φ.
Three types of cylindrical bodies having (in) of 11 mm were used.

【0019】引き続き、各種の筒体に熱間加工,及び冷
間加工を行うことにより、口径φが0.5mm,厚みが
0.05mmの3種別なチューブを得た。更に、これら
の各チューブを400〜500[℃]の温度条件下で熱
処理することによって3種類の形状記憶合金製チューブ
を得た。
Subsequently, various tubular bodies were subjected to hot working and cold working to obtain three types of tubes having a diameter φ of 0.5 mm and a thickness of 0.05 mm. Furthermore, each of these tubes was heat-treated under a temperature condition of 400 to 500 [° C.] to obtain three types of shape memory alloy tubes.

【0020】次に、長さ寸法が100mmとなるように
各形状記憶合金製チューブの両端を固定し、且つその中
央部分を10mm押し込む三点曲げ試験を10℃及び2
5℃の温度条件下でそれぞれ3種類の形状記憶合金製チ
ューブに対して行った。
Next, a three-point bending test in which both ends of each shape memory alloy tube were fixed so that the length dimension was 100 mm and the central portion was pushed in by 10 mm at 10 ° C. and 2
The test was performed on each of the three types of shape memory alloy tubes under the temperature condition of 5 ° C.

【0021】表1は、これら3種類の形状記憶合金製チ
ューブに対する三点曲げ試験の結果を、Ti−50.5
at%Ni合金材料を用いて同様な過程を経て製造した
線径φ´が0.5mmのワイヤ,及び線径φ´が0.1
mmのワイヤを用いて外径を0.5mmにしたコイルバ
ネと、純ステンレス製の線径φ´が0.1mmのワイヤ
を用いて外径を0.5mmにしたコイルバネとに対する
三点曲げ試験の結果と合わせて示したものである。
Table 1 shows the results of the three-point bending test for these three types of shape memory alloy tubes, which are Ti-50.5.
A wire having a wire diameter φ ′ of 0.5 mm manufactured through a similar process using an at% Ni alloy material, and a wire diameter φ ′ of 0.1
of a three-point bending test for a coil spring having an outer diameter of 0.5 mm using a wire of mm and a coil spring having an outer diameter of 0.5 mm using a wire of pure stainless steel having a wire diameter φ ′ of 0.1 mm. It is shown together with the results.

【0022】[0022]

【表1】 [Table 1]

【0023】表1からは、試料番号1〜3の形状記憶合
金製チューブは、何れも10mm押し曲げに対して殆ど
残留歪みが零であり、10℃で唯一残留歪み4を示した
試料番号2の形状記憶合金製チューブも25℃では零と
なることが判る。因みに、この試料番号2の形状記憶合
金製チューブにおける10℃での残留歪みは、形状記憶
効果による見かけ上の歪みである。
It can be seen from Table 1 that the shape memory alloy tubes of Sample Nos. 1 to 3 have almost no residual strain when pressed and bent by 10 mm, and have a residual strain of 4 only at 10 ° C. It can be seen that the shape memory alloy tube of No. 0 also becomes zero at 25 ° C. Incidentally, the residual strain at 10 ° C. in the shape memory alloy tube of Sample No. 2 is an apparent strain due to the shape memory effect.

【0024】ところで、押し曲げに際しての曲げ荷重
(変形荷重)は、その材料をメガネフレームのリムとし
て使用する場合、レンズをリムに装脱するときに必要な
力となる為、小さい方が好ましい。試料番号1〜3の形
状記憶合金製チューブの変形荷重は、何れも試料番号6
のステンレス製コイルバネとほぼ同等となっているが、
試料番号4の形状記憶合金製ワイヤでは極めて大きくな
っている。
By the way, the bending load (deformation load) at the time of pushing and bending, when using the material as the rim of the spectacle frame, becomes a force necessary for mounting and dismounting the lens on and from the rim, so that it is preferable that the bending load is small. The deformation loads of the shape memory alloy tubes of sample numbers 1 to 3 are all sample number 6
It is almost the same as the stainless steel coil spring of
The shape memory alloy wire of Sample No. 4 is extremely large.

【0025】一方、回復荷重はレンズに対する拘束力と
なるため、大きい方が好ましい。試料番号1〜3の形状
記憶合金製チューブの回復荷重は、何れも試料番号6の
ステンレス製コイルバネとほぼ同等となっているが、試
料番号5の形状記憶合金製コイルバネでは極めて小さく
なっている。
On the other hand, since the recovery load acts as a restraining force on the lens, it is preferable that the recovery load is large. The recovery loads of the shape memory alloy tubes of sample numbers 1 to 3 are almost the same as those of the stainless steel coil spring of sample number 6, but are extremely small in the shape memory alloy coil spring of sample number 5.

【0026】図1は、試料番号1の形状記憶合金製チュ
ーブと試料番号6のステンレス製コイルバネとに関する
温度25℃における荷重F(kgf)−撓みτ(mm)
特性を示したものである。ここで、試料番号1の形状記
憶合金製チューブに関する荷重−撓み特性は実線で示さ
れており、試料番号6のステンレス製コイルバネに関す
る荷重−撓み特性は点線で示されている。
FIG. 1 shows the load F (kgf) -deflection τ (mm) at a temperature of 25 ° C. for the shape memory alloy tube of sample No. 1 and the stainless steel coil spring of sample No. 6.
It shows the characteristics. Here, the load-deflection characteristic of the shape memory alloy tube of sample number 1 is shown by a solid line, and the load-deflection characteristic of the stainless steel coil spring of sample number 6 is shown by a dotted line.

【0027】何れの荷重−撓み特性における曲線C,C
´も、荷重大側の上昇部分CA ,CA ´は変形荷重を示
し、その上昇部分から変極点K,K´を経て荷重小側に
連続する部分CB ,CB ´は回復荷重を示す。又、回復
荷重部分CB ´より撓み軸に至る交点CX ´における撓
みの値は残留歪みを示す。
Curves C, C in any load-deflection characteristic
Also in ′, the ascending portions C A and C A ′ on the large load side show the deformation load, and the portions C B and C B ′ that continue from the ascending portion to the small load side through the inflection points K and K ′ represent the recovery load. Show. Further, the value of the flexure at the intersection point C X ′ from the recovery load portion C B ′ to the flexure axis indicates the residual strain.

【0028】即ち、試料番号1に関する荷重−撓み特性
における曲線Cは閉曲線となり、残留歪みが存在せず、
又試料番号6に関する荷重−撓み特性における曲線C´
は開曲線となり、表1にも示した如く残留歪みが約8程
度存在することが判る。
That is, the curve C in the load-deflection characteristic for sample No. 1 is a closed curve, and there is no residual strain.
Also, the curve C'in the load-deflection characteristic for sample No. 6
Is an open curve, and as shown in Table 1, it can be seen that there is about 8 residual strains.

【0029】以上の結果により、表1における試料番号
1〜3の形状記憶合金製チューブは、何れもメガネフレ
ームのリム材料として極めて優れたものとなることが判
る。因みに、変形荷重や回復荷重は、製造するチューブ
の外径,肉厚,熱処理条件等を変えることにより調整可
能であるので、目的に応じて選定できる。
From the above results, it is understood that the shape memory alloy tubes of sample Nos. 1 to 3 in Table 1 are all extremely excellent as rim materials for eyeglass frames. Incidentally, the deformation load and the recovery load can be adjusted by changing the outer diameter, the wall thickness, the heat treatment conditions, etc. of the tube to be manufactured, and can be selected according to the purpose.

【0030】図2は、本発明のメガネ部材を含むメガネ
フレームの外観を斜視図により示したものである。ここ
でメガネフレームは、一対のレンズを拘束するリム10
A,10Bと、これらのリム10A,10Bが成す両端
から延在するテンプル11と、リム10A,10Bの間
に架設されたブリッジ12及び渡り部13とを含んで構
成される。即ち、ブリッジ12及び渡り部13はリム1
0A,10Bに対する結合部材となる。
FIG. 2 is a perspective view showing the outer appearance of an eyeglass frame including the eyeglass member of the present invention. Here, the spectacle frame is a rim 10 that restrains a pair of lenses.
A, 10B, a temple 11 extending from both ends formed by these rims 10A, 10B, a bridge 12 and a bridging portion 13 installed between the rims 10A, 10B. That is, the bridge 12 and the transition portion 13 are the rim 1
It becomes a coupling member for 0A and 10B.

【0031】このメガネフレームの場合、リム10A,
10Bの材料に上述した形状記憶合金製チューブを使用
しているので、レンズの固定を十分に行い得ると共に、
レンズの装脱を安定性良く行い得る。即ち、このリム1
0A,10Bはレンズの装脱に際して耐久性の優れたも
のになる。因みに、リムの材料の一部に形状記憶合金製
チューブを用いて残部に付加部材を使用した場合も、リ
ムの材料の全部に形状記憶合金製チューブを用いた場合
に準じた効果が得られる。
In the case of this spectacle frame, the rim 10A,
Since the shape memory alloy tube described above is used as the material of 10B, the lens can be sufficiently fixed, and
The lens can be attached and detached with good stability. That is, this rim 1
0A and 10B have excellent durability when the lens is attached and detached. Incidentally, even when the shape memory alloy tube is used for a part of the material of the rim and the additional member is used for the rest, the same effect as when the shape memory alloy tube is used for the entire material of the rim is obtained.

【0032】尚、実施例ではリムの材料とする形状記憶
合金製チューブの材料に3種のTi−Ni系合金材料を
用いた場合を説明したが、実際にはTi−(48〜5
2)at%Ni合金材料であれば適用可能である。更
に、Fe,Cr,V等の第3元素を添加したTi−Ni
−X合金(但し、XはFe,Cr,V等)や、銅基合
金,鉄基合金等の全ての形状記憶合金材料を対象とし得
るし、これに付加部材を加えた場合にも適用されるの
で、本発明は実施例に限定されない。
In the embodiment, the case where three kinds of Ti-Ni alloy materials are used as the material of the shape memory alloy tube used as the material of the rim has been described, but in reality, Ti- (48-5
2) Any at% Ni alloy material can be applied. Furthermore, Ti-Ni added with a third element such as Fe, Cr, V
-It can be applied to all shape memory alloy materials such as X alloys (where X is Fe, Cr, V, etc.), copper-based alloys, iron-based alloys, etc., and is also applied when additional members are added. Therefore, the present invention is not limited to the embodiments.

【0033】[0033]

【発明の効果】以上に述べた通り、本発明によれば、常
温使用環境下で超弾性を示すTi−Ni系合金材料を用
いて製造した形状記憶合金製チューブをメガネフレーム
のリムに使用しているので、押し曲げに際しての変形荷
重が小さく,回復荷重が大きく,且つ残留歪みが零とな
り、レンズの装脱に際しての安定性と耐久性が保証され
ると共に、レンズに対する拘束力が十分に確保されてレ
ンズの固定が安定化されるようになる。結果として、形
状記憶合金の基本特性を維持し、耐久性及び適用性に優
れたメガネ部材が得られることになる。
As described above, according to the present invention, a shape memory alloy tube manufactured using a Ti-Ni alloy material that exhibits superelasticity at room temperature is used for the rim of an eyeglass frame. Since the deformation load during push-bending is small, the recovery load is large, and the residual strain is zero, stability and durability are guaranteed when the lens is attached and detached, and a sufficient restraining force for the lens is secured. As a result, the fixing of the lens is stabilized. As a result, it is possible to obtain an eyeglass member that maintains the basic properties of the shape memory alloy and is excellent in durability and applicability.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明のメガネ部材の一例である形状記憶合金
製チューブと従来のメガネ部材の一例であるステンレス
製コイルバネとに関する温度25℃における荷重F(k
gf)−撓みτ(mm)特性を示したものである。
FIG. 1 is a load F (k at a temperature of 25 ° C. regarding a shape memory alloy tube which is an example of the eyeglass member of the present invention and a stainless steel coil spring which is an example of a conventional eyeglass member.
gf) -deflection τ (mm) characteristics are shown.

【図2】本発明のメガネ部材を含むメガネフレームの外
観を示した斜視図である。
FIG. 2 is a perspective view showing an outer appearance of an eyeglass frame including an eyeglass member of the present invention.

【符号の説明】[Explanation of symbols]

10A,10B リム 11 テンプル 12 ブリッジ 13 渡り部 10A, 10B Rim 11 Temple 12 Bridge 13 Crossover

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 形状記憶合金製チューブと該形状記憶合
金製チューブに結合された付加部材とから成ることを特
徴とするメガネフレーム用リム部材。
1. A rim member for a spectacle frame, comprising a shape memory alloy tube and an additional member connected to the shape memory alloy tube.
【請求項2】 形状記憶合金製チューブから成ることを
特徴とするメガネフレーム用リム部材。
2. A rim member for a spectacle frame, which is made of a shape memory alloy tube.
【請求項3】 請求項1又は2記載のメガネフレーム用
リム部材において、前記形状記憶合金製チューブは、常
温使用環境下で超弾性を示すTi−Ni系合金材料から
成ることを特徴とするメガネフレーム用リム部材。
3. The spectacle frame rim member according to claim 1 or 2, wherein the shape memory alloy tube is made of a Ti—Ni-based alloy material that exhibits superelasticity under a normal temperature use environment. Frame rim member.
【請求項4】 請求項1〜3の何れか一つに記載のメガ
ネフレーム用リム部材の2つと、これらのリム部材間を
結合した結合部材とを含むことを特徴とするメガネフレ
ーム。
4. A spectacle frame comprising two rim members for a spectacle frame according to any one of claims 1 to 3 and a coupling member coupling between these rim members.
【請求項5】 請求項4のメガネフレームと該メガネフ
レームに保持されたレンズとを含むことを特徴とするメ
ガネ。
5. An eyeglass comprising the eyeglass frame according to claim 4 and a lens held by the eyeglass frame.
JP8184893A 1993-04-08 1993-04-08 Member of spectacles Pending JPH06294946A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8184893A JPH06294946A (en) 1993-04-08 1993-04-08 Member of spectacles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8184893A JPH06294946A (en) 1993-04-08 1993-04-08 Member of spectacles

Publications (1)

Publication Number Publication Date
JPH06294946A true JPH06294946A (en) 1994-10-21

Family

ID=13757903

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8184893A Pending JPH06294946A (en) 1993-04-08 1993-04-08 Member of spectacles

Country Status (1)

Country Link
JP (1) JPH06294946A (en)

Similar Documents

Publication Publication Date Title
EP0310628B1 (en) Eyeglass frame including shape-memory elements
KR100413832B1 (en) Metal frames
US4896955A (en) Eyeglass frame including shape-memory elements
US5951793A (en) Ni-Ti-Pd superelastic alloy material, its manufacturing method, and orthodontic archwire made of this alloy material
US4983029A (en) Eyeglass frame having Ti-Ni-V alloy element with improved wear comfortability
US4472035A (en) Eyeglass-frame
US6557993B2 (en) Eyeglasses and parts thereof made with specially processed NiTi shape memory alloy
US4895438A (en) Eyeglass frame including shape-memory elements
JPH06294946A (en) Member of spectacles
US6419358B1 (en) Pseudoelastic β titanium eyeglass components
US4494832A (en) Eyeglass-frame
JPH09137241A (en) Spectacle frame and its production as well as method for adjusting shape
JPS63127225A (en) Spectacles parts
JP3915543B2 (en) Partly superelastic parts and method of manufacturing the same
JP3190443B2 (en) Glasses material
JPH07207390A (en) Super elastic spring
JPH06118348A (en) Member made of shape memory alloy and spectacle member using its member
JPH0792432A (en) Spectacle frame and its production and shape adjusting method
JP2737830B2 (en) Eyeglass frame manufacturing method
JPH0762506A (en) Production of superelastic spring
EP1360540A1 (en) Frames for glasses and/or parts thereof
JP2002182162A (en) Method of manufacturing spectacles frame using ultraelastic material
JP3014020U (en) Eyeglass parts using beryllium copper alloy and eyeglasses incorporating the same
JPH0551682A (en) Superelastic material and its production
JPS62280819A (en) Spectacles frame

Legal Events

Date Code Title Description
A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20020710