JPH06293621A - Perming solution - Google Patents

Perming solution

Info

Publication number
JPH06293621A
JPH06293621A JP8340793A JP8340793A JPH06293621A JP H06293621 A JPH06293621 A JP H06293621A JP 8340793 A JP8340793 A JP 8340793A JP 8340793 A JP8340793 A JP 8340793A JP H06293621 A JPH06293621 A JP H06293621A
Authority
JP
Japan
Prior art keywords
betaine
hair
perming solution
formula
active ingredient
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8340793A
Other languages
Japanese (ja)
Other versions
JP3238789B2 (en
Inventor
Kentaro Kanda
健太郎 神田
Kenji Hama
健二 浜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP08340793A priority Critical patent/JP3238789B2/en
Publication of JPH06293621A publication Critical patent/JPH06293621A/en
Application granted granted Critical
Publication of JP3238789B2 publication Critical patent/JP3238789B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain a perming solution hardly damaging hair only by the addition of a small amount of a specific betaine and having extremely good touch after using by including the specific betaine as an active ingredient. CONSTITUTION:This perming solution contains a betaine expressed by the formula (another name: trimethylglycine, glycine betaine or alkyldimethyl betaine) as an active ingredient. The betaine has excellent hair protecting action and can improve handle after using. The betaine is contained in an amount of 0.05-20 pts.wt., preferably 2-6 pts.wt. The perming solution may contain, e.g. thioglycol acid or its salt, an alkali such as ammonia, a surfactant such as stearyl chloride trimethylammonium salt, a stabilizer such as ethylene diamine tetraacetate.2Na, sodium bromate, a perfume, a humectant such as pro;ylene glycol, amino aids and oils and fats such as silicone oil in addition to the betaine of the formula.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ベタイン(別名:トリ
メチルグリシン、グリシンベタイン、アルキルジメチル
ベタイン)を有効成分とするパーマ液に関する。なお、
本発明にかかるパーマ液とは、毛髪のウェーブ形成もし
くは縮毛矯正を目的として用いる物であり、1処理あた
り複数の薬剤を使用する場合には、用いる全ての薬剤を
指す。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a perm solution containing betaine (also known as trimethylglycine, glycine betaine, alkyldimethyl betaine) as an active ingredient. In addition,
The perm solution according to the present invention is used for the purpose of wave formation or straightening of hair, and when a plurality of agents are used per treatment, it means all the agents used.

【0002】[0002]

【従来の技術および解決しようとする課題】従来、パー
マ液の毛髪損傷防止剤としては、各種油成分、プロピレ
ングリコール、アミノ酸等が用いられてきたが、従来の
物はいずれもその効果が充分でなく、使用者の満足を得
る物ではなかった。
2. Description of the Related Art Conventionally, various oil components, propylene glycol, amino acids, etc. have been used as a hair damage preventing agent for perm solution, but the conventional products are not sufficiently effective. No, it did not satisfy the user.

【0003】[0003]

【課題を解決するための手段】本発明者らは、パーマ液
に用いる物として、優れた毛髪保護機能を有する化合物
を得るべく鋭意検討の結果、上記ベタインに優れた毛髪
保護作用及び、使用後の風合いの改良作用がある事を見
いだし、本発明を完成した。すなわち、本発明は式
(1)で表されるベタインを有効成分とするパーマ液で
ある。ベタインの毛髪保護機能は、その優れた保湿力
と、毛髪組織に対する浸透性の良さに起因すると推定さ
れる。
Means for Solving the Problems As a result of intensive investigations by the present inventors to obtain a compound having an excellent hair-protecting function as a substance to be used in a perm solution, the above-mentioned betaine has an excellent hair-protecting action and after use. The present invention has been completed by discovering that it has the effect of improving the texture. That is, the present invention is a perm solution containing betaine represented by the formula (1) as an active ingredient. The hair-protecting function of betaine is presumed to be due to its excellent moisturizing power and good permeability to hair tissues.

【0004】例えば、ベタインは水100重量部に対
し、160重量部可溶であり、その保湿性を調べたとこ
ろ、表1のような値を得た。
For example, betaine was soluble in 160 parts by weight with respect to 100 parts by weight of water, and its moisturizing property was examined. The values shown in Table 1 were obtained.

【0005】[0005]

【表1】 [Table 1]

【0006】 式(1)のベタインの配合量は、最終製品の0.05〜
10重量部、好ましくは、2〜6重量部である。
[0006] The compounding amount of betaine of the formula (1) is 0.05 to 0.5% of the final product.
10 parts by weight, preferably 2 to 6 parts by weight.

【0007】本発明のパーマ液は、前記必須成分の他、
通常パーマ液に用いられる物質、例えばチオグリコール
酸またはその塩類(アンモニウム、モノエタノールアミ
ン、ナトリウムなど)、システイン、アルカリ(アンモ
ニア、モノエタノールアミンなど)、界面活性剤(ポリ
オキシエチレン(20)ラウリルエーテル、塩化ステア
リルトリメチルアンモニウムなど)、安定剤(エチレン
ジアミン四酢酸・2Naなど)、臭素酸ナトリウム、香
料、湿潤剤(プロピレングリコールなど)、アミノ酸
類、各種油脂(シリコーンオイルなど)などを配合する
事ができる。
The perm solution of the present invention comprises, in addition to the above essential components,
Substances usually used in perm solution, such as thioglycolic acid or its salts (ammonium, monoethanolamine, sodium, etc.), cysteine, alkalis (ammonia, monoethanolamine, etc.), surfactants (polyoxyethylene (20) lauryl ether) , Stearyltrimethylammonium chloride, etc.), stabilizers (ethylenediaminetetraacetic acid / 2Na, etc.), sodium bromate, fragrances, wetting agents (propylene glycol, etc.), amino acids, various oils and fats (silicone oil, etc.), etc. can be added. .

【0008】本発明のパーマ液は、通常用いられる方法
に従って、製造、充填、流通する事ができる。
The perm solution of the present invention can be manufactured, filled and distributed according to a method usually used.

【0009】[0009]

【実施例】以下、実施例を挙げて本発明を具体的に説明
するが、本発明はこれによって限定を受けるものではな
い。
EXAMPLES The present invention will now be specifically described with reference to examples, but the present invention is not limited thereto.

【0010】[0010]

【実施例1】 チオグリコール酸型1液 成分 配合量(重量部) ベタイン 5.0 チオグリコール酸アンモニウム(50%水溶液) 10.0 アンモニア水(28%) 3.0 塩化ステアリルトリメチルアンモニウム 0.1 エチレンジアミン四酢酸・2ナトリウム 適量 香料 適量 精製水にて全量を100重量部とする チオグリコール酸アンモニウム、アンモニア水以外の成
分を均一に撹拌混合し、後に両者を添加し混合する
Example 1 Thioglycolic Acid Type 1 Liquid Component Amount (part by weight) Betaine 5.0 Ammonium thioglycolate (50% aqueous solution) 10.0 Ammonia water (28%) 3.0 Stearyltrimethylammonium chloride 0.1 Ethylenediaminetetraacetic acid ・ 2 sodium, proper amount Perfume, proper amount Total amount to 100 parts by weight with purified water Stir and mix components other than ammonium thioglycolate and ammonia water uniformly, and then add both and mix.

【0011】[0011]

【比較例1】 チオグリコール酸型1液 チオグリコール酸アンモニウム(50%水溶液) 10.0 アンモニア水(28%) 3.0 塩化ステアリルトリメチルアンモニウム 0.1 プロピレングリコール 5.0 エチレンジアミン四酢酸・2ナトリウム 適量 香料 適量 精製水にて全量を100重量部とする チオグリコール酸アンモニウム、アンモニア水以外の成
分を均一に撹拌混合し、後に両者を添加し混合する
Comparative Example 1 Thioglycolic acid type 1 liquid Ammonium thioglycolate (50% aqueous solution) 10.0 Ammonia water (28%) 3.0 Stearyltrimethylammonium chloride 0.1 Propylene glycol 5.0 Ethylenediaminetetraacetic acid / 2 sodium Proper amount Perfume Proper amount Make up to 100 parts by weight with purified water Uniformly stir and mix components other than ammonium thioglycolate and ammonia water, and then add and mix both

【0012】[0012]

【実施例2】 システイン型1液 ベタイン 5.0 システイン 5.0 チオグリコール酸アンモニウム 0.3 モノエタノールアミン 2.0 エチレンジアミン四酢酸・2ナトリウム 適量 香料 適量 精製水にて全量を100重量部とする 各成分を均一に撹拌混合するExample 2 Cysteine Type 1 Liquid Betaine 5.0 Cysteine 5.0 Ammonium Thioglycolate 0.3 Monoethanolamine 2.0 Ethylenediaminetetraacetic acid / 2 sodium Proper amount Perfume Proper amount 100 parts by weight with purified water. Stir and mix each component uniformly

【0013】[0013]

【比較例2】 システイン型1液 システイン 5.0 チオグリコール酸アンモニウム 0.3 モノエタノールアミン 2.0 エチレンジアミン四酢酸・2ナトリウム 適量 香料 適量 精製水にて全量を100重量部とする 各成分を均一に撹拌混合するComparative Example 2 Cysteine type 1 liquid Cysteine 5.0 Ammonium thioglycolate 0.3 Monoethanolamine 2.0 Ethylenediaminetetraacetic acid / disodium Suitable amount Perfume Suitable amount Purified water makes the total amount 100 parts by weight Each component is uniform Stir to mix

【0014】[0014]

【実施例3】 第2液 ベタイン 3.0 臭素酸ナトリウム 5.0 シリコーンエマルション 1.0 香料 適量 精製水にて全量を100重量部とするExample 3 Second Liquid Betaine 3.0 Sodium Bromate 5.0 Silicone Emulsion 1.0 Perfume Appropriate amount Purified water is added to 100 parts by weight.

【0015】[0015]

【比較例3】 第2液 臭素酸ナトリウム 5.0 シリコーンエマルション 4.0 香料 適量 精製水にて全量を100重量部とする 実施例1〜3及び比較例1〜3に示したパーマ液をそれ
ぞれパネラー(20才〜36才の女性:直毛)10名に
よって評価した。美容経験10年以上を有する専門家
が、実施前と比較して「髪の毛が傷んだ」と評価した人
数を示す。
Comparative Example 3 Second Liquid Sodium Bromate 5.0 Silicone Emulsion 4.0 Perfume Appropriate amount Purified water makes the total amount 100 parts by weight The perm liquids shown in Examples 1 to 3 and Comparative Examples 1 to 3 respectively. It was evaluated by 10 panelists (female aged 20 to 36: straight hair). The number of people evaluated by experts having more than 10 years of beauty experience as "damaged hair" compared to before the implementation is shown.

【0016】[0016]

【表2】 [Table 2]

【0017】また、「未処理」、「比較例2×比較例
3」、「実施例2×実施例3」それぞれの毛髪の電子顕
微鏡写真を図1〜3に示す。「未処理」の毛髪ではキュ
ーティクルが整然と並んでいるのに対し、「比較例2×
比較例3」の毛髪ではキューティクルが浮き上がってい
るのが見える。一方、「実施例2×実施例3」の毛髪で
は、「未処理」の毛髪と同様に、キューティクルが浮か
び上がることもなく、正常な状態である事が判る。
Electron micrographs of the hairs of "untreated", "Comparative example 2 x Comparative example 3" and "Example 2 x Example 3" are shown in FIGS. The cuticles are lined up neatly in the “untreated” hair, whereas in “Comparative Example 2 ×
The cuticles are visible on the hair of Comparative Example 3 ”. On the other hand, in the case of the hair of “Example 2 × Example 3”, the cuticle does not emerge and the hair is in a normal state as in the case of the “untreated” hair.

【0018】[0018]

【発明の効果】本発明により、少量の添加で毛髪の損傷
が少なく、使用後の感触が極めて良いパーマ液を提供す
る事が可能となった。
EFFECTS OF THE INVENTION According to the present invention, it is possible to provide a perm solution which is less damaged by addition of a small amount and has a very good feel after use.

【図面の簡単な説明】[Brief description of drawings]

【図1】未処理毛髪の電子顕微鏡像1] Electron microscope image of untreated hair

【図2】「比較例2×比較例3」で処理した毛髪の電子
顕微鏡像
FIG. 2 is an electron microscopic image of hair treated in “Comparative Example 2 × Comparative Example 3”.

【図3】「実施例2×実施例3」で処理した毛髪の電子
顕微鏡像
FIG. 3 is an electron microscopic image of hair treated in “Example 2 × Example 3”.

─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成6年3月3日[Submission date] March 3, 1994

【手続補正1】[Procedure Amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】図面の簡単な説明[Name of item to be corrected] Brief description of the drawing

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【図面の簡単な説明】[Brief description of drawings]

【図1】未処理毛髪の電子顕微鏡像(繊維の形状)の写
真。
FIG. 1 is a photograph of an electron microscope image (fiber shape) of untreated hair.

【図2】「比較例2×比較例3」で処理した毛髪の電子
顕微鏡像(繊維の形状)の写真。
FIG. 2 is a photograph of an electron microscope image (fiber shape) of hair treated in “Comparative Example 2 × Comparative Example 3”.

【図3】「実施例2×実施例3」で処理した毛髪の電子
顕微鏡像(繊維の形状)の写真。
FIG. 3 is a photograph of an electron microscope image (fiber shape) of hair treated in “Example 2 × Example 3”.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 式(1) で表されるベタインを有効成分とする事を特徴とするパ
ーマ液。
1. Formula (1) A perm solution characterized by containing betaine as an active ingredient.
【請求項2】 式(1)で表される成分を0.05〜2
0重量部含む事を特徴とする請求項1記載のパーマ液。
2. The component represented by the formula (1) is 0.05 to 2
The perm solution according to claim 1, which contains 0 part by weight.
JP08340793A 1993-04-09 1993-04-09 Alkaline perm solution Expired - Lifetime JP3238789B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP08340793A JP3238789B2 (en) 1993-04-09 1993-04-09 Alkaline perm solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08340793A JP3238789B2 (en) 1993-04-09 1993-04-09 Alkaline perm solution

Publications (2)

Publication Number Publication Date
JPH06293621A true JPH06293621A (en) 1994-10-21
JP3238789B2 JP3238789B2 (en) 2001-12-17

Family

ID=13801583

Family Applications (1)

Application Number Title Priority Date Filing Date
JP08340793A Expired - Lifetime JP3238789B2 (en) 1993-04-09 1993-04-09 Alkaline perm solution

Country Status (1)

Country Link
JP (1) JP3238789B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001010936A (en) * 1999-06-29 2001-01-16 Hoyu Co Ltd Pretreatment composition for permanent wave hair and its use
JP2001302461A (en) * 2000-04-24 2001-10-31 Nonogawa Shoji Kk Hair cosmetic
WO2002087526A1 (en) * 2001-05-02 2002-11-07 Finnfeeds Finland Oy Use of betaine in hair care
WO2005117815A1 (en) * 2004-06-03 2005-12-15 Kao Corporation Hair style control agent
JP2008088138A (en) * 2006-10-05 2008-04-17 Takara Belmont Co Ltd Permanent wave treatment agent and permanent wave treatment method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001010936A (en) * 1999-06-29 2001-01-16 Hoyu Co Ltd Pretreatment composition for permanent wave hair and its use
JP2001302461A (en) * 2000-04-24 2001-10-31 Nonogawa Shoji Kk Hair cosmetic
WO2002087526A1 (en) * 2001-05-02 2002-11-07 Finnfeeds Finland Oy Use of betaine in hair care
WO2005117815A1 (en) * 2004-06-03 2005-12-15 Kao Corporation Hair style control agent
JP2008088138A (en) * 2006-10-05 2008-04-17 Takara Belmont Co Ltd Permanent wave treatment agent and permanent wave treatment method

Also Published As

Publication number Publication date
JP3238789B2 (en) 2001-12-17

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