JPH06256134A - Granular cosmetic - Google Patents
Granular cosmeticInfo
- Publication number
- JPH06256134A JPH06256134A JP5094838A JP9483893A JPH06256134A JP H06256134 A JPH06256134 A JP H06256134A JP 5094838 A JP5094838 A JP 5094838A JP 9483893 A JP9483893 A JP 9483893A JP H06256134 A JPH06256134 A JP H06256134A
- Authority
- JP
- Japan
- Prior art keywords
- ascorbic acid
- licorice
- granular
- cosmetic
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はＬ−アスコルビン酸及び
甘草の有機溶媒抽出物とを配合する美白化粧料に関す
る。The present invention relates to a whitening cosmetic composition containing L-ascorbic acid and an organic solvent extract of licorice.
【０００２】[0002]
【従来の技術】Ｌ−アスコルビン酸及びその誘導体は皮
膚の異常色素沈着を抑制する作用があり、多くの美白化
粧料に配合されている。2. Description of the Related Art L-Ascorbic acid and its derivatives have the effect of suppressing abnormal pigmentation of the skin and are incorporated in many whitening cosmetics.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら従来のＬ
−アスコルビン酸やその誘導体を配合した顆粒状化粧料
は製造時にＬ−アスコルビン酸やその誘導体が劣化した
り、保存時に着色したりする等の問題点があった。本発
明者らは上記欠点の改善について検討した結果、後記顆
粒状化粧料がこの欠点を解決することを見いだし、本発
明を完成した。However, the conventional L
-Granular cosmetics containing ascorbic acid or a derivative thereof have problems such as deterioration of L-ascorbic acid or a derivative thereof at the time of production, or coloring during storage. As a result of studying the improvement of the above-mentioned drawbacks, the present inventors have found that the granular cosmetics described later solve this drawback, and completed the present invention.
【０００４】[0004]
【課題を解決するための手段】すなわち本発明は、Ｌ−
アスコルビン酸及びその誘導体とからなる群から選ばれ
た１種または２種以上と、甘草の有機溶媒抽出物とを配
合することを特徴とする顆粒状化粧料である。That is, the present invention is based on L-
A granular cosmetic comprising one or more selected from the group consisting of ascorbic acid and its derivatives, and an organic solvent extract of licorice.
【０００５】以下、本発明の構成について詳述する。本
発明で用いられるＬ−アスコルビン酸とその誘導体は、
特異な優れた生理作用により、注射剤、内服剤として医
薬品に使用される他、化粧品、食品の強化栄養剤として
或いは油脂、食品等の酸化防止剤として用いられ極めて
広範な用途に利用されている。誘導体としては、アスコ
ルビン酸モノステアレート、アスコルビン酸モノパルミ
テート、アスコルビン酸モノオレエート、アスコルビン
酸ジステアレート、アスコルビン酸ジパルミテートなど
のエステル誘導体、アスコルビン酸リン酸マグネシウ
ム、アスコルビン酸リン酸ナトリウムなどのアスコルビ
ン酸リン酸の金属塩もしくは有機アミン塩、アスコルビ
ン酸硫酸ナトリウムなどのアスコルビン酸硫酸の金属塩
もしくは有機アミン塩等が挙げられる。Ｌ−アスコルビ
ン酸とその誘導体とからなる群から選ばれた一種または
二種以上の配合量は顆粒状化粧料全量中の０．０１〜６
０重量％である。The structure of the present invention will be described in detail below. L-ascorbic acid and its derivatives used in the present invention are
Due to its unique and excellent physiological action, it is used in pharmaceuticals as injections and internal medicines, as a nutritional supplement for cosmetics and foods, or as an antioxidant for oils and fats, foods, etc. . As the derivative, ascorbic acid monostearate, ascorbic acid monopalmitate, ascorbic acid monooleate, ascorbic acid distearate, ester derivative such as ascorbic acid dipalmitate, magnesium ascorbyl phosphate, ascorbyl phosphate such as sodium ascorbyl phosphate. Examples thereof include metal salts or organic amine salts, metal salts of ascorbic acid sulfuric acid such as sodium ascorbate sulfate, or organic amine salts. The amount of one or more selected from the group consisting of L-ascorbic acid and its derivative is 0.01 to 6 in the total amount of the granular cosmetic.
It is 0% by weight.
【０００６】本発明で用いられる甘草の有機溶媒抽出物
は、甘草またはその水抽出残部の有機溶媒抽出物であ
る。抽出溶媒の例としては、メチルエチルケトンなどの
脂肪族ケトン類、エチルエーテル等の脂肪族エーテル
類、石油エーテル、ヘキサン、シクロヘキサン、トルエ
ン、ベンゼン等の炭化水素類、塩化メチレン、クロロホ
ルム等のハロゲン化炭化水素類、酢酸エチル、酢酸イソ
プロピル等のエステル類、ジエチルエーテル、テトラヒ
ドロフラン、ジオキサン等のエーテル類、エタノール等
のアルコール類等が挙げられる。これら一種の単一系ま
たは二種以上の混合系溶媒を用いることができる。甘草
の有機溶媒抽出物の配合量は顆粒状化粧料全量中の０．
０００１〜１０重量％である。The organic solvent extract of licorice used in the present invention is an organic solvent extract of licorice or its water extraction residue. Examples of the extraction solvent include aliphatic ketones such as methyl ethyl ketone, aliphatic ethers such as ethyl ether, hydrocarbons such as petroleum ether, hexane, cyclohexane, toluene and benzene, and halogenated hydrocarbons such as methylene chloride and chloroform. Examples thereof include esters, esters such as ethyl acetate and isopropyl acetate, ethers such as diethyl ether, tetrahydrofuran and dioxane, alcohols such as ethanol. It is possible to use one kind of these single-system solvents or two or more kinds of mixed-system solvents. The content of the organic solvent extract of licorice was 0.
It is 0001 to 10% by weight.
【０００７】本発明の顆粒状化粧料には上記の必須成分
のほか、Ｄ−マンニトール、乳糖、でんぷん類、無機粉
体、顔料、色素、有機樹脂粉体、油脂、界面活性剤、有
機溶剤、水溶性高分子、水、酸化防止剤、紫外線吸収
剤、防腐剤、薬剤、ビタミン類、香料などを必要に応じ
て加えることができる。本発明の顆粒状化粧料は、非エ
マルション型の顆粒状化粧料であり、顆粒の製造は公知
の方法を用いればよく、例えば、非エマルション系の粉
末部を均一に混合し、これにエタノールに溶解した非エ
マルション系の界面活性剤を添加し、均一に湿潤後、押
し出し造粒を行い、乾燥し、顆粒を得る。In addition to the above essential components, the granular cosmetic of the present invention contains D-mannitol, lactose, starches, inorganic powders, pigments, dyes, organic resin powders, oils and fats, surfactants, organic solvents, Water-soluble polymers, water, antioxidants, ultraviolet absorbers, preservatives, drugs, vitamins, fragrances and the like can be added as necessary. The granular cosmetic of the present invention is a non-emulsion type granular cosmetic, and a known method may be used for producing the granules. For example, a non-emulsion type powder part is uniformly mixed and ethanol is added thereto. A dissolved non-emulsion type surfactant is added, and after uniformly moistening, extrusion granulation is performed and drying is performed to obtain granules.
【０００８】[0008]
【実施例】次に、実施例及び比較例によって本発明を詳
細に説明する。EXAMPLES Next, the present invention will be described in detail with reference to Examples and Comparative Examples.
【０００９】実施例１及び比較例１ 下記成分を均一に混合した後、全量に対し４０％の精製
水を添加し湿潤後、押し出し造粒を行い、乾燥して顆粒
状化粧料を得た。Example 1 and Comparative Example 1 The following components were uniformly mixed, 40% of purified water was added to the total amount, the mixture was moistened, extruded and granulated, and dried to obtain a granular cosmetic.
【００１０】[0010]
【表１】 [Table 1]
【００１１】尚、この甘草抽出末は甘草の根及び根茎を
試料としてエタノールと酢酸エチルの混合溶媒（１：
１）によって還流下で５時間抽出を行って得た。 実施
例１および比較例１の顆粒状化粧料を４０℃の条件下に
て４カ月間保存した後、着色度を調べた。結果を表２に
示す。The licorice-extracted powder is a mixed solvent of ethanol and ethyl acetate (1:
It was obtained by carrying out extraction under reflux for 5 hours according to 1). The granular cosmetics of Example 1 and Comparative Example 1 were stored at 40 ° C. for 4 months, and then the degree of coloring was examined. The results are shown in Table 2.
【００１２】[0012]
【表２】 [Table 2]
【００１３】表２から、本発明の実施例１は甘草抽出末
の０．０１％配合によって高温保存下での変色が防止さ
れ、品質に優れたものであることがわかる。From Table 2, it can be seen that Example 1 of the present invention is excellent in quality because the discoloration under high temperature storage is prevented by adding 0.01% of licorice extract powder.
【００１４】実施例２及び比較例２ 下記成分を均一に混合した後、全量の１５％のエタノー
ルを添加し湿潤後、押し出し造粒を行い、乾燥して顆粒
状化粧料を得た。Example 2 and Comparative Example 2 The following components were uniformly mixed, 15% of the total amount of ethanol was added, wetted, extruded and granulated, and dried to obtain a granular cosmetic.
【００１５】[0015]
【表３】 [Table 3]
【００１６】尚、この甘草抽出末は甘草の根及び根茎を
試料としてエタノールによって還流下で５時間抽出を行
って得た。The licorice extract powder was obtained by extracting licorice roots and rhizomes with ethanol for 5 hours under reflux.
【００１７】実施例２及び比較例２中の製造後のアスコ
ルビン酸ジパルミテートの含有量を分析し、その残存率
を下式により算出した。その結果を表４に示す。 残存率（％）＝１００×製造後の分析値（重量％）／処
方値（重量％）The content of ascorbic acid dipalmitate after production in Example 2 and Comparative Example 2 was analyzed, and the residual rate was calculated by the following formula. The results are shown in Table 4. Residual rate (%) = 100 x analytical value (wt%) after manufacturing / prescription value (wt%)
【００１８】[0018]
【表４】 [Table 4]
【００１９】表４から甘草抽出末を０．１％を配合した
実施例２はアスコルビン酸ジパルミテートの製造時の劣
化が防がれている事がわかる。It can be seen from Table 4 that Example 2 containing 0.1% of licorice extract powder prevented deterioration of ascorbic acid dipalmitate during production.
【００２０】実施例３ 下記成分のうちヒドロキシプロピルセルロースを除く全
成分を均一に混合し、この混合物にヒドロキシプロピル
セルロースの５％水溶液を噴霧しながら撹拌して造粒し
た後、乾燥して顆粒状化粧料を得た。Example 3 Of the following components, all components except hydroxypropyl cellulose were uniformly mixed, and a 5% aqueous solution of hydroxypropyl cellulose was sprayed and stirred to granulate the mixture. I got cosmetics.
【００２１】[0021]
【表５】 [Table 5]
【００２２】尚、この甘草抽出末は甘草の根及び根茎を
試料として酢酸エチルによって還流下で２０時間抽出を
行って得た。本顆粒状化粧料は製造時のアスコルビン酸
誘導体の劣化が少なく、また保存時に着色がないもので
あった。The licorice extract powder was obtained by extracting licorice roots and rhizomes as samples with ethyl acetate under reflux for 20 hours. The present granular cosmetic product showed little deterioration of the ascorbic acid derivative during production and no coloring during storage.
【００２３】[0023]
【発明の効果】以上記載のとおり、本発明は、製造時に
劣化したり、保存時に着色したりすることが顕著に抑制
されるＬ−アスコルビン酸あるいはその誘導体配合の顆
粒状化粧料を提供することは明らかである。As described above, the present invention provides a granular cosmetic composition containing L-ascorbic acid or a derivative thereof, which is significantly suppressed from being deteriorated during production or being colored during storage. Is clear.
Claims (1)
なる群から選ばれた１種または２種以上と、甘草の有機
溶媒抽出物とを配合することを特徴とする顆粒状化粧
料。1. A granular cosmetic composition comprising one or more selected from the group consisting of L-ascorbic acid and its derivatives, and an organic solvent extract of licorice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05094838A JP3126543B2 (en) | 1993-03-03 | 1993-03-03 | Granular cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05094838A JP3126543B2 (en) | 1993-03-03 | 1993-03-03 | Granular cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06256134A true JPH06256134A (en) | 1994-09-13 |
| JP3126543B2 JP3126543B2 (en) | 2001-01-22 |
Family
ID=14121191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05094838A Expired - Lifetime JP3126543B2 (en) | 1993-03-03 | 1993-03-03 | Granular cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3126543B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892056A (en) * | 1994-09-22 | 1996-04-09 | Kao Corp | Whitening cosmetic |
-
1993
- 1993-03-03 JP JP05094838A patent/JP3126543B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892056A (en) * | 1994-09-22 | 1996-04-09 | Kao Corp | Whitening cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3126543B2 (en) | 2001-01-22 |
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