JPH06249820A - Estimation of corrosion-proof electric potential - Google Patents

Estimation of corrosion-proof electric potential

Info

Publication number
JPH06249820A
JPH06249820A JP5037611A JP3761193A JPH06249820A JP H06249820 A JPH06249820 A JP H06249820A JP 5037611 A JP5037611 A JP 5037611A JP 3761193 A JP3761193 A JP 3761193A JP H06249820 A JPH06249820 A JP H06249820A
Authority
JP
Japan
Prior art keywords
anticorrosion
potential
corrosion
current
proof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5037611A
Other languages
Japanese (ja)
Other versions
JP3177049B2 (en
Inventor
Hidemasa Nonaka
英正 野中
Yuichiro Yamaguchi
祐一郎 山口
Yoshimi Sakaguchi
義美 坂口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osaka Gas Co Ltd
Original Assignee
Osaka Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osaka Gas Co Ltd filed Critical Osaka Gas Co Ltd
Priority to JP03761193A priority Critical patent/JP3177049B2/en
Publication of JPH06249820A publication Critical patent/JPH06249820A/en
Application granted granted Critical
Publication of JP3177049B2 publication Critical patent/JP3177049B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

PURPOSE:To obtain a corrosion-proof electric potential estimation method for measuring or estimating the correct true corrosion-proof electric potential. CONSTITUTION:As for the corrosion-proof electric potential estimation method for a corrosion-proof objective article 1 in which an outside electric power source 4 whose negative side is connected with the corrosion-proof objective article 1 such as a buried pipe buried under the ground 5 and whose positive side is connected with an opposed electrode 3 buried in the ground 5 is installed, and electric corrosion-proof operation is carried out by suppllying electric corrosion-proof current from the ground 5 side to the corrosionproof objective article 1 side, the electric current which is formed by rectifying the full waves of the sine wave alternating current is used as the corrosion-proof electric current, and the electric potential between the corrosion-proof objective article 1 and the ground surface 50 is measured. Then, the dc component and the ac component of the electric potential are detected, and the sum of the dc ocmponent and constant times of the ac component is estimated as the corrosion-proof electric potential of the corrosion-proof objective article 1.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、電気防食を施された埋
設管等の防食電位の推定方法に関し、さらに詳細には、
負極側が土壌内に埋設された防食対象物に接続されると
ともに、正極側が土壌内に備えられる対極に接続される
外部電源を設け、土壌側より防食対象物側へ防食電流を
供給して電気防食される防食対象物の防食電位推定方法
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for estimating the anticorrosion potential of a buried pipe or the like which has been subjected to anticorrosion, and more specifically,
The negative electrode side is connected to the anticorrosion target embedded in the soil, and the positive electrode side is provided with an external power source connected to the counter electrode provided in the soil, and the anticorrosion current is supplied from the soil side to the anticorrosion target side. The present invention relates to a method for estimating the anticorrosion potential of an anticorrosion target.

【0002】[0002]

【従来の技術】現在、埋設管の防食対策としては、塗覆
装の形成と共に電気防食が施されており導管の保全に大
きな威力を発揮している。電気防食においては、防食効
果を判断する重要な指標として、埋設管周部の土壌と埋
設管との間の電位である防食電位が所定の値(E≦−8
50mVvs.Cu/CuSO4)の範囲内にあるかどうか
が判断基準とされる。このような防食電位を測定あるい
は推定するにあたっては、土壌表面50に照合電極6を
設けるとともに、前記埋設管1に他端を接続されたケー
ブルを設けて、両者間の直流電位差(みかけの防食電
位)を測定することにより、測定値を上記の値と比較し
てその判定をおこなっている。このような方法をとる場
合は、このみかけの防食電位の測定にあたって、土壌抵
抗と防食電流とによるIR損が存在することとなる。従
って、みかけの防食電位(測定される電位)は真の防食
電位(埋設管近傍の土壌と埋設管との間の電位)より低
く計測され、あたかも十分な防食効果があるかのような
不安全サイドの評価をすることが起こる。そこで、この
防食電流成分を除去する目的で、直流電源である外部電
源を一時的にOFF(防食電流をゼロ、即ちIR損をゼ
ロ)にして、グラフ上に電位変化を取りOFF操作直後
の瞬時に示す電位により真の防食電位を推定することが
行われている。
2. Description of the Related Art Currently, as a corrosion protection measure for buried pipes, galvanic protection is applied together with the formation of coating, which is very effective for the maintenance of conduits. In cathodic protection, as an important index for judging the anticorrosion effect, the anticorrosion potential, which is the potential between the soil around the buried pipe and the buried pipe, has a predetermined value (E ≦ −8).
Whether or not it is within the range of 50 mV vs. Cu / CuSO 4 ) is the criterion. In measuring or estimating such an anticorrosion potential, a collation electrode 6 is provided on the soil surface 50, and a cable having the other end connected to the buried pipe 1 is provided so that a DC potential difference (apparent anticorrosion potential) between the two is provided. ), The measured value is compared with the above value to make the determination. When such a method is adopted, IR loss due to soil resistance and anticorrosion current is present when measuring the apparent anticorrosion potential. Therefore, the apparent anticorrosion potential (measured potential) is measured lower than the true anticorrosion potential (potential between the soil in the vicinity of the buried pipe and the buried pipe), which is unsafe as if it had a sufficient anticorrosion effect. A side evaluation takes place. Therefore, for the purpose of removing this anticorrosion current component, the external power supply, which is a direct current power source, is temporarily turned off (corrosion protection current is zero, that is, IR loss is zero), and the potential change is taken on the graph to obtain the instant immediately after the OFF operation. The true anti-corrosion potential is estimated from the potential shown in.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、この方
法では、外部電源を一時的にOFFする操作あるいは装
置が必要であり、また一つの防食路線に多数の外部電源
が設置されている場合には、全数同時に(msオーダ
で)OFFする必要があり、実施する上で困難を伴う。
従って、本発明の目的は、外部電源を稼動状態にさせた
ままでより正確な真の防食電位を測定もしくは推定する
ことが可能な防食電位推定方法を得ることにある。
However, this method requires an operation or device for temporarily turning off the external power source, and when a large number of external power sources are installed on one corrosion protection line, It is necessary to turn off all of them simultaneously (on the ms order), which is difficult to implement.
Therefore, an object of the present invention is to obtain a method for estimating the anticorrosion potential that can measure or estimate the true anticorrosion potential more accurately while the external power supply is kept in the operating state.

【0004】[0004]

【課題を解決するための手段】この目的を達成するため
の本発明による防食電位推定方法の特徴的な手段は、防
食電流として周期的に0値を採る電流を使用し、防食対
象物と土壌表面間の電位で、防食電流が周期的に0値を
採る瞬間に於ける電位を、防食対象物の防食電位と推定
することにある。その作用・効果は次の通りである。
The characteristic means of the method for estimating the anticorrosion potential according to the present invention for achieving this object is to use a current having a value of 0 periodically as the anticorrosion current, and The potential between the surfaces at the moment when the anticorrosion current takes a zero value periodically is estimated as the anticorrosion potential of the anticorrosion target. The action and effect are as follows.

【0005】[0005]

【作用】つまり、本願の防食構成においては、防食電流
として周期的に0値を採る電流が採用される。そして、
防食電位の測定においては、従来通り地表面と埋設管と
の間の電位で測定される。ただし、その測定時としては
防食電流が0値となる時点でのものが測定される。従っ
て、この時点においては、防食電流自体が無いため、従
来問題となっていた地表面と埋設管近傍部間のIR損が
存在せず、結果、計測される電位が真の防食電位を代表
するものとなっている。
That is, in the anticorrosion structure of the present application, a current that takes a zero value periodically is adopted as the anticorrosion current. And
In the measurement of the anticorrosion potential, the potential between the ground surface and the buried pipe is measured as usual. However, the measurement is made at the time when the anticorrosion current becomes zero. Therefore, at this point, since there is no anticorrosion current itself, there is no IR loss between the ground surface and the vicinity of the buried pipe, which has been a problem in the past, and as a result, the measured potential represents the true anticorrosion potential. It has become a thing.

【0006】[0006]

【発明の効果】従って、防食電流供給用の外部電源とし
て各別のものを採用して、本願の方法により防食電位を
測定する場合は、外部電源の電流供給状態を保持したま
まで、任意の地点での”真の電位”を測定することがで
きるようになった。
Therefore, when each of the external power supplies for supplying the anticorrosion current is adopted and the anticorrosion potential is measured by the method of the present invention, an arbitrary power supply is maintained while the current supply state of the external power supply is maintained. It has become possible to measure the "true potential" at a point.

【0007】さらにここで、防食電流として正弦波交流
を全波整流した電流を使用し、電位の直流成分及び交流
成分を夫々直流電圧計、交流電圧計で検出し、直流成分
と交流成分より、前述の防食電流が0となる時点での防
食電位を求めることとすると、みかけの防食電位計測側
の出力は、図3に示すように直流成分に、防食電流の周
期に見合った交流成分が乗ったものとすることができ、
防食電流が0となる周期と電位が最大値(最貴値)を示
す時期の周期が一致し、直流成分計測値に交流成分計測
値の定数倍(実際の交流電圧振幅巾を交流電圧計の出力
値から換算する換算係数)したものを加えて割り出せ
ば、これが真の防食電位となる。
Further, a current obtained by full-wave rectifying a sine wave alternating current is used as the anticorrosion current, and a direct current component and an alternating current component of the potential are detected by a direct current voltmeter and an alternating current voltmeter, respectively. Assuming that the anticorrosion potential at the time when the anticorrosion current becomes 0 is obtained, the apparent output of the anticorrosion potential measurement side has a direct current component and an alternating current component corresponding to the period of the anticorrosion current as shown in FIG. Can be
The cycle in which the anticorrosion current becomes 0 and the cycle in which the potential shows the maximum value (noble value) match, and the DC component measured value is a constant multiple of the AC component measured value (actual AC voltage amplitude range This is the true anti-corrosion potential if you add it by adding the value obtained by converting the output value).

【0008】[0008]

【実施例】本願の実施例を図面に基づいて説明する。図
1には本願の方法が適用される防食対象物としての埋設
管1の状況が示されている。
Embodiments of the present application will be described with reference to the drawings. FIG. 1 shows a situation of a buried pipe 1 as an anticorrosion object to which the method of the present application is applied.

【0009】先ず電気防食の構成から説明する。防食対
象としての埋設管1に対して、この埋設管1が埋設され
ている土壌5中に対極3が設置されるとともに、埋設管
1、対極3に渡って負極側が埋設管1に接続され、正極
側が対極3に接続される外部電源4が設けられる。外部
電源4から供給される防食電流は、図2に示すように正
弦波交流を全波整流したものとされる。ここで、電源と
しては通常の商用電源が利用されるため、防食電流の周
波数は120Hzとなる。防食電流は周期的に0値をと
りながら、対極3から土壌5内の塗覆装欠陥部2を介し
て、埋設管1へ流れることとなる。
First, the structure of cathodic protection will be described. With respect to the buried pipe 1 as an anticorrosion target, the counter electrode 3 is installed in the soil 5 in which the buried pipe 1 is buried, and the negative electrode side is connected to the buried pipe 1 across the buried pipe 1 and the counter electrode 3, An external power supply 4 whose positive electrode side is connected to the counter electrode 3 is provided. The anticorrosion current supplied from the external power supply 4 is a full-wave rectified sine wave alternating current as shown in FIG. Here, since a normal commercial power source is used as the power source, the frequency of the anticorrosion current is 120 Hz. The anticorrosion current takes a value of 0 periodically and flows from the counter electrode 3 to the buried pipe 1 through the coating defect portion 2 in the soil 5.

【0010】さて、防食電位の測定にあたっては、土壌
表面50に設けられている照合電極6と埋設管1との間
に、直流及び交流電圧計7が配設されて、この間の電位
差が計測される。さらに、本願の埋設管1の防食電位測
定方法においては、即ちこれらの電圧計7により計測さ
れる計測電位から、直流成分電位EDCと交流成分電位E
ACが測定され、これらの値より以下の式より得られる値
を真の防食電位ETと推定する。 ET=EDC+定数×EAC ここで、定数は計測される交流の実際の電圧振幅(EDC
より上側の振幅)÷交流電圧計の出力値 以下、計測手順を順を追って説明する。外部電源4より
商用電流(正弦波交流60Hz)を全波整流したもの
が、防食電流として流される。この防食電流には、その
電流値が瞬間的にゼロになる点がある(1秒間に120
回)。従って、埋設管1の電位も120Hzで変化する
交流成分を含んでいる(図2,3参照)。この状態で、
埋設管1の”特定点”で電圧計7を用いて電位測定を行
うと、図3に示すような測定結果が得られる。同図にお
いて、直流成分がEDCで、さらに、交流成分はEACであ
る。これらの測定値(直流成分EDCと交流成分EAC)を
用いてET(真の電位)が求められ、防食電位が推定さ
れる。
When measuring the anticorrosion potential, a DC and AC voltmeter 7 is provided between the verification electrode 6 provided on the soil surface 50 and the buried pipe 1, and the potential difference between them is measured. It Further, in the method for measuring the anticorrosion potential of the buried pipe 1 of the present application, that is, from the measurement potentials measured by these voltmeters 7, the DC component potential E DC and the AC component potential E
AC is measured, and the value obtained from the following equation based on these values is estimated as the true anticorrosion potential E T. E T = E DC + constant × E AC Here, the constant is the actual voltage amplitude of the measured alternating current (E DC
Amplitude above) / Output value of AC voltmeter Hereinafter, the measurement procedure will be described step by step. A full-wave rectified commercial current (sine wave AC 60 Hz) is supplied as an anticorrosion current from the external power source 4. This anticorrosion current has a point at which the current value instantaneously becomes zero (120 per second).
Times). Therefore, the potential of the buried pipe 1 also includes an AC component that changes at 120 Hz (see FIGS. 2 and 3). In this state,
When the potential is measured using the voltmeter 7 at the "specific point" of the buried pipe 1, the measurement result as shown in FIG. 3 is obtained. In the figure, the DC component is E DC , and the AC component is E AC . Using these measured values (DC component E DC and AC component E AC ), E T (true potential) is obtained, and the anticorrosion potential is estimated.

【0011】〔別実施例〕上記の実施例においては、全
波整流された電流を使用する防食電流を採用し、この電
流が0値を採る時点における測定防食電位を真の防食電
位として推定したが、これは必ずしも正弦波形のものに
限られるものではない。即ち、防食電流として周期的に
0値を採る電流を使用し(ただし、防食電流は土壌側か
ら埋設管側に流れる必要がある)、埋設管1と土壌表面
50間の電位で、防食電流が周期的に0値を採る瞬間に
於ける電位を、埋設管1の防食電位と推定すればよい。
従って、波形に任意の設定が可能で、測定時点で急激に
0値となるもの、あるいはその逆に漸近的に0値となる
もの等が採用可能である。さらに、防食対象物として
は、埋設管1の他、地中埋設構造体等、様々なものが考
えられる。さらに、直流電圧計、交流電圧計7を備える
変わりに、図4に示すように埋設管1と照合電極6との
間の電位を出力するトランジェントメモリー装置(7
0)を備えておき、その出力曲線より真の防食電位を求
めるものとしてもよい。さらに、防食電位の検出にあた
って、図5に示すように分離手段としてのFRA、FF
T等の波形解析装置(7a)を備え、この装置により防
食電流が0値となる特定瞬間の電位を推定手段(7b)
によって推定してもよい。
[Other Embodiments] In the above-mentioned embodiment, an anticorrosion current using a full-wave rectified current is adopted, and the measured anticorrosion potential at the time when this current takes 0 value is estimated as the true anticorrosion potential. However, this is not necessarily limited to the sinusoidal waveform. That is, a current that takes a 0 value periodically is used as the anticorrosion current (however, the anticorrosion current needs to flow from the soil side to the buried pipe side), and the anticorrosion current is the potential between the buried pipe 1 and the soil surface 50. The potential at the instant when the zero value is taken periodically may be estimated as the anticorrosion potential of the buried pipe 1.
Therefore, the waveform can be arbitrarily set, and it is possible to employ a waveform that suddenly becomes a zero value at the time of measurement, or vice versa. Further, as the anticorrosion target, various objects such as the underground pipe 1 and the underground buried structure can be considered. Further, instead of including a DC voltmeter and an AC voltmeter 7, as shown in FIG. 4, a transient memory device (7 for outputting a potential between the buried tube 1 and the reference electrode 6).
0) may be provided and the true anticorrosion potential may be obtained from the output curve. Further, in detecting the anticorrosion potential, as shown in FIG.
A waveform analyzing device (7a) such as T is provided, and by this device, the potential at a specific moment when the anticorrosion current becomes 0 value is estimated (7b).
May be estimated by

【0012】尚、特許請求の範囲の項に図面との対照を
便利にするために符号を記すが、該記入により本発明は
添付図面の構成に限定されるものではない。
It should be noted that although reference numerals are given in the claims for convenience of comparison with the drawings, the present invention is not limited to the configurations of the accompanying drawings by the entry.

【図面の簡単な説明】[Brief description of drawings]

【図1】電気防食構成と防食電位の測定状態を示す図FIG. 1 is a view showing a configuration of an anticorrosion structure and a measurement state of an anticorrosion potential.

【図2】防食電流を示す図FIG. 2 is a diagram showing an anticorrosion current.

【図3】検出される防食電位を示す図FIG. 3 is a diagram showing detected anticorrosion potentials.

【図4】トランジェントメモリー装置による測定例を示
す図
FIG. 4 is a diagram showing an example of measurement by a transient memory device.

【図5】FRA、FFT等の波形解析装置による測定例
を示す図
FIG. 5 is a diagram showing a measurement example by a waveform analyzer such as FRA or FFT.

【符号の説明】[Explanation of symbols]

1 防食対象物 3 対極 4 外部電源 5 土壌 50 土壌表面 1 Anticorrosion target 3 Counter electrode 4 External power supply 5 Soil 50 Soil surface

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 負極側が土壌(5)内に埋設された防食
対象物(1)に接続されるとともに、正極側が前記土壌
(5)内に備えられる対極(3)に接続される外部電源
(4)を設け、前記土壌(5)側より前記防食対象物
(1)側へ防食電流を供給して電気防食される防食対象
物(1)の防食電位推定方法であって、 前記防食電流として周期的に0値を採る電流を使用し、
前記防食対象物(1)と土壌表面(50)間の電位で、
前記防食電流が周期的に0値を採る瞬間に於ける電位
を、前記防食対象物(1)の防食電位と推定する防食電
位推定方法。
1. An external power source (negative electrode side is connected to an anticorrosion target (1) buried in soil (5) and positive electrode side is connected to a counter electrode (3) provided in said soil (5). 4) is provided, which is a method for estimating the anticorrosion potential of an anticorrosion target (1) which is galvanically protected by supplying an anticorrosion current from the soil (5) side to the anticorrosion target (1) side. Using a current that takes a zero value periodically,
At the potential between the anticorrosion target (1) and the soil surface (50),
A method for estimating an anticorrosion potential, which estimates the electric potential at the instant when the anticorrosion current takes a value of 0 periodically as the anticorrosion potential of the anticorrosion target (1).
【請求項2】 前記防食電流として正弦波交流を全波整
流した電流を使用し、前記防食対象物(1)と土壌表面
(50)間の電位の内、直流成分を直流電圧計で、交流
成分を交流電圧計で検出し、前記直流成分測定値と前記
交流成分測定値より前記防食電流が周期的に0値を採る
瞬間に於ける電位を求める請求項1記載の防食電位推定
方法。
2. A current obtained by full-wave rectifying a sinusoidal alternating current is used as the anticorrosion current, and a direct current component of the potential between the anticorrosion target (1) and the soil surface (50) is measured by a direct current voltmeter. Is detected by an AC voltmeter, and the potential at the instant when the anticorrosion current periodically takes a value of 0 is determined from the measured value of the DC component and the measured value of the AC component.
JP03761193A 1993-02-26 1993-02-26 Corrosion protection potential estimation method Expired - Fee Related JP3177049B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03761193A JP3177049B2 (en) 1993-02-26 1993-02-26 Corrosion protection potential estimation method

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1082865A (en) * 1996-07-17 1998-03-31 Osaka Gas Co Ltd Position searching method for underground buried pipe
JP2006257532A (en) * 2005-03-18 2006-09-28 Nakabohtec Corrosion Protecting Co Ltd Method for measuring potential of corrosion-prevented body by cathodic protection, device for measuring potential, cathodic protection method and device
KR100806961B1 (en) * 2006-05-23 2008-03-06 주식회사 예스코 Integrated measurement device capable of measuring corrosion against protection direct voltage, alternating voltage and ground resistance
CN104947118A (en) * 2015-06-17 2015-09-30 中国石油天然气股份有限公司 Flexible anode breakpoint detection method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1082865A (en) * 1996-07-17 1998-03-31 Osaka Gas Co Ltd Position searching method for underground buried pipe
JP2006257532A (en) * 2005-03-18 2006-09-28 Nakabohtec Corrosion Protecting Co Ltd Method for measuring potential of corrosion-prevented body by cathodic protection, device for measuring potential, cathodic protection method and device
KR100806961B1 (en) * 2006-05-23 2008-03-06 주식회사 예스코 Integrated measurement device capable of measuring corrosion against protection direct voltage, alternating voltage and ground resistance
CN104947118A (en) * 2015-06-17 2015-09-30 中国石油天然气股份有限公司 Flexible anode breakpoint detection method

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