JPH06241589A - Counter measure for chlorofludrocarbon in apparatus - Google Patents

Abstract

PURPOSE:To increase a quantity of chlorefluorocarbon and to prevent environment pollution of chlorofluorocarbon gas by adding, to chlorofluorocarbon refrigerant, a mixed refrigerant of butane chlorofluoro carbon and silicone, the quantity of the mixed refrigerant being almost the same as or less then that of the chlorofluoro carbon refrigerant. CONSTITUTION:Mixed refrigerant of butane chlorofluorocarbon and silicone are added to chlorofluorocarbon refrigerant contained in apparatuses using present chlorofluorocarbon. The quantity of the mixed refrigerant is almost the same as or less than that of the chlorofluorocarbon refrigerant. This newly produced refrigerant has no ozone environment pollution. If light chlorofluorocarbon refrigerant is bonded to heavy butane refrigerant to be increased in weight, it is rotatably accelerated by the solar light in the low- height air to be decomposed to solve the ozone problem. The chlorofluorocarbon to be mixed with the butane is not limited to low-cost R-22, but may include R-14CF4, R-23CHF3, or C2H4F2 of part of component of R-500.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to countermeasures against CFCs that destroy the ozone layer.

[0002]

2. Description of the Related Art It is not possible to find a countermeasure for all fluorocarbon media in equipment currently in use, which conventionally causes the problem of ozone depletion. Conventionally, there are a heavy medium in which silicone is added to an organic compound, and a medium in which a heavy butane C ₄ H ₁₀ is added with CFC H, Cl, and F refrigerants to make it heavy and flame-retardant. This medium was developed by the present inventor. is doing. Japanese Patent Application 4-1
94490 and Japanese Patent Application No. 4-2906609, both of which are excellent heavy media. Then C ₂ F ₄ H ₃ and C ₂
I hear that Cl ₂ F ₂ was developed as a low-pollution refrigerant. However, it is said that the high pressure makes it unsuitable for conventional automobiles and general use, and that it can only be used for new product equipment that meets the high pressure of the new Freon, but details are not clear. C ₂ F ₄ H ₃ is a conventional chlorine-free Freon C
F ₄ (R-14) boiling point-128.0, CHF ₂ (R-2
3) The boiling point is -82.2, which is convincing. On the other hand C ₂ C
l ₂ F ₂ has more carbon atoms, is heavier, and has lower pressure,
Generally, it can be used, but it is hard to say that it has a large amount of chlorine and little ozone pollution. Further, there is a limit to the combination of atoms as a single molecule, and it is extremely difficult to polymerize a single molecule bond without pollution. Therefore, in order to obtain a CFC refrigerant that does not cause ozone pollution due to polymerization, the problem of high price arises.

[003]

[Problems to be Solved by the Invention] CFCs which cause CFC pollution are used as a medium free from CFC pollution.

[004]

[Means for Solving the Problems] Prior art, Japanese Patent Application No. 4-
According to 194490 and Japanese Patent Application No. 4-290669, an appropriate amount of butane, freon, and butane mixed refrigerant composed of silicone is added to a freon medium incorporated in a device that uses the present freon to change to a medium that does not cause ozone pollution. Room coolers for automobiles, refrigeration equipment for aging household appliances, large refrigerators for commercial use, and large room coolers for buildings will become obsolete and will cause serious CFC pollution. It is no exaggeration to say that we are not taking any measures against the CFC media that cause the ozone problem that we are currently using.
It is necessary to deal with it as soon as possible. Next, chlorine also exists as rock salt, and fluorine in the composition of CFC coexisted with silicon in the form of rock, so if these elements coexist, it becomes a heavy substance. Moreover, the problem of the ozone layer does not occur even if vinyl chloride is incinerated to release a large amount of chlorine. This is because elemental chlorine combines with water in the air to form hydrochloric acid, which dissolves in seawater and the ground. The CFC medium, which has a small number of carbon atoms, is light and easily reaches the ozone layer, and even carries heavy chlorine to cause ozone depletion. Therefore, if the number of carbon atoms in the medium is increased, it becomes a heavy gas and the problem is solved. Further, since fluorine and silicon originally coexisted in the form of rock, they are made into a butane mixed medium which is easy to be familiar with and is flame retardant and heavy. Also, the fact that the pressure of the medium changes when butane and freon are mixed indicates a molecular bond. Evidence that a molecular bond has occurred is to show a pressure that does not belong to R-22 or butane. Next, as the number of carbon atoms in the hydrocarbon increases, it becomes heavier and closer to a viscous lubricating oil. Therefore, for example, if kerosene is mixed with diesel oil, it will enter the strong attraction range of diesel oil and lose the volatility of kerosene. It enters the strong attraction range of and becomes a heavy refrigerant as slow as decomposition of butane. Further, if different liquids are mixed to form a layer, they are separated, and if they are completely transparent, they are not separated. In any case, the CFC component causing the problem is diluted with butane, so that the absolute amount of CFC is reduced and the problem is reduced. The problem is how to deal with the old refrigerant contained in the automobile cooler and the general-purpose cooler. In the case of an automobile cooler, the mechanical seal that a compressor rotates at high speed is basically not a perfect seal. Therefore, even if there is a difference in gas leakage or a difference in the timing of replenishing the refrigerant, it is necessary to replenish the refrigerant eventually. It can be implemented. Also, even in the case of household coolers, it is necessary to consider the deterioration of the old CFC built in the cooler regardless of how much it is, so if you extract a part of the old refrigerant and add an appropriate amount of butane mixed refrigerant, the CFC problem will not occur. It will be resolved. Next, the behavior of the chlorine atom will be described. It is known that the oxygen molecule O ₂ which gives combustion and the chlorine atom Cl have a strong atomic rotation, and generate an extremely large amount of heat or explode when they combine with other atoms. So, for example, R-12 CCl ₂ F
See ₂ of molecular bonds the two Cl atoms through the junction of the molecular bonds assuming spherical motor (associative gear)
It becomes lighter because it accelerates two F atoms.
Atoms shift to high-speed rotation and become lighter because the mass (physical properties or mass properties) of atoms changes to speed. It is the carbon atom that exacerbates this minor problem. Next, the reason why ozone O ₃ is lighter than O ₂ is that the degree of electron bonding of O ₃ is shallow and in contact with each other. Therefore, the electron rotation of each atom is fast and light because the electron interference of the bond is small and the resistance is small. Although it is easy for two molecules to be bonded by the degree of electron contact, the gravity of the central atom arranged in three is reduced by half in three, so the bond attraction as a molecule is weak. One of the reasons why the attractive force coupling is weak is an indivisible odd number. Therefore, the ozone layer composed of O _3, which has a weak bond, is molecularly bonded to the light CFC refrigerant, and the ozone layer is destroyed. Therefore, if a light chlorofluorocarbon refrigerant is combined with a heavy butane refrigerant to make it heavier, it will be rotationally accelerated and decomposed by sunlight in the low sky, and the ozone problem will be solved. As a butane refrigerant, a mixed refrigerant of butane and propane is being implemented in Germany, but the problem of combustion remains. There is no narrative or atomic physics that can explain light and heavy. It is open to the public that what makes the elucidation of the phenomenon unknown is the calculus that does not belong to physics or mathematics that follows the paper. Then R
-12 CCl ₂ F ₂ has a low water solubility, and R-22
It is only 1/10 of that. Therefore, it becomes a light refrigerant that is hard to combine with the water in the air and causes a problem of ozone destruction. On the other hand, the refrigerant R-22 CHClF ₂ has a high water solubility, and when it is used in a refrigerator without being dried, hydrochloric acid is generated to cause rusting. There is heavy hydrochloric acid that reacts with the moisture in the atmosphere, so R-22 does not cause ozone depletion even if it causes a very slight chlorine pollution on the ground just like incinerating vinyl chloride. Of. In addition, butane C ₄ which has oily rust resistance of R-22
H ₁₀ improves with the lubricating oil. R-2
Since the cooling capacity of No. 2 is 50 to 60% higher than that of R-12, the cooling capacity of the mixed refrigerant with butane, R-22 and R-12 can be known. Upon decomposition, the mixed refrigerant containing these three components was converted to hydrogen of butane C ₄ H ₁₀ by R-12CCl.
₂ in combination with Cl ₂ in F ₂ may become heavy hydrochloride does not lead to the ozone pollution HCl of R-22 is further strongly likely to be hydrochloric acid. Next, it is the work of extracting the refrigerant from the refrigeration equipment currently in use. In refrigeration equipment where the packing system is perfect and does not leak gas, some of the old refrigerant must be extracted. However, since most of the extracted refrigerant is in a gas state, a huge container is required if the gas remains as it is, so a pollution control vehicle with a liquefaction device that can liquefy the gas at the same time is required. The R-12 collected in this way has to be purchased by a manufacturer from a store and processed by a refrigerant manufacturer. Currently, however, the removal of CFCs is not done by paying the price for the removal work. It should not happen, and as soon as there is no physical disability, pay the price and pay R-12
It seems that no one is willing to pick up or replace the, but if it becomes mandatory, the problem will be different. Moreover, even though there is information that production of R-12 was discontinued, there is no information about technology and disposal method for converting R-12 into a pollution-free refrigerant. R-12, which is currently held in huge automobiles and refrigeration equipment, has been left undissolved and has been destroyed. Now, the production of new vehicles that use new refrigerants, new refrigeration equipment, and new refrigerants It is necessary to carefully consider whether the R-12 process is to be performed first. Incidentally, _R-14 CF 4 Freon is not limited to the inexpensive R-22 to be mixed with butane, R-23CH
F ₃ , C ₂ H ₄ F which is a part of other components of R-500
_{Although 2} is acceptable, there is a price problem. Next, since the compressor and the condenser, which are likely to cause gas leakage of the domestic cooler, are located outdoors, there is little problem even if a flammable refrigerant is used.
Also, if there is a leak, it is usually very small,
Unless there is a large leak unless it is an earthquake, gasoline is ignited in the case of a car accident that leads to a fire. Since it is unlikely that a human accident such as the purpose of causing ignition and combustion, such as a refrigerant extinguishing test, is considered, it is better to add as little fluorine-containing refrigerant to butane as a non-combustion countermeasure. If you stick to the assumption of a fire accident too much, you will lose the major pollution countermeasures on the earth side. Incidentally, it is the fluorine atom that makes the hydrocarbon such as butane flame-retardant, and no other than the fluorine atom can be found.

[0005]

As described above, by carrying out the method of the present invention, a refrigerant which is already in use and which causes ozone pollution can be easily and rapidly changed to a heavy refrigerant, so that a substance that destroys the ozone layer disappears. Therefore, it is necessary to implement it as soon as possible.

Claims (1)

[Claims] 1. A freon gas is measured by adding a mixed refrigerant composed of butane, freon and silicone in an amount equal to or greater than that of the freon medium to a freon medium being used in a device containing freon. How to prevent pollution by.