JPH06228808A - Permanent electrode-carrying fiber mixed with tourmaline fine power and its production - Google Patents
Permanent electrode-carrying fiber mixed with tourmaline fine power and its productionInfo
- Publication number
- JPH06228808A JPH06228808A JP3623493A JP3623493A JPH06228808A JP H06228808 A JPH06228808 A JP H06228808A JP 3623493 A JP3623493 A JP 3623493A JP 3623493 A JP3623493 A JP 3623493A JP H06228808 A JPH06228808 A JP H06228808A
- Authority
- JP
- Japan
- Prior art keywords
- tourmaline
- fine powder
- fiber
- electrode
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、広くは電気石利用の永
久電極担持物に関するものであり、特にこれを繊維に応
用した技術に関するものである。就中、電気石微粉末を
特定の繊維に混入して永久電極担持物とした繊維とその
製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates generally to a permanent electrode carrier using tourmaline, and more particularly to a technique in which it is applied to a fiber. In particular, the present invention relates to fibers which are made by mixing tourmaline fine powder into specific fibers to form a permanent electrode carrier and a method for producing the fibers.
【０００２】[0002]
【従来の技術】従来、繊維は衣服をはじめ、保温やから
だをカバーし、さらには身体を飾ること等、その他多く
の目的のために利用されいる。そして、これらの繊維に
何らかの機能、例えば防臭や赤外放射とか各種医療健康
効果等をもつと思われるセラミックその他の物質を混入
したり接着したりするものがつくられ数多くの商品が市
場に出ている。電気石の微粉末を繊維に混入したり接着
する考えもこれらの部類に入いる。前記のような各種の
機能を持った固形物（粒子）等を混入または接着するだ
けのことは、機能の発揮と無関係で極めて容易なことで
あり、特に新しい技術ではない。2. Description of the Related Art Conventionally, fibers have been used for many other purposes such as clothing, heat insulation, body covering, and even body decoration. Then, some of these fibers are mixed with or bonded with ceramics or other substances that are considered to have some function, such as deodorization, infrared radiation, and various medical and health effects, and many products are on the market. There is. The idea of mixing fine particles of tourmaline with fibers or adhering them to fibers also falls into these categories. It is extremely easy to mix or adhere solid substances (particles) or the like having various functions as described above, regardless of the function, and is not a new technology.
【０００３】[0003]
【発明が解決しようとする課題】ここで重要なことは、
例えば防臭力のある物質を繊維に混入又は接着した場合
には、その物質が化学繊維をつくる原材料に埋もれてし
まう。したがって、外部の悪臭と防臭剤が接することが
出来ず、期待する効果が得られないことが多い。ある繊
維に防臭機能をもたせるためには、何らかの方法によっ
てその繊維の外部の悪臭物質を、その繊維または接着物
質内の防臭物質と接触させる通気機能をその繊維にもた
せることが必要である。このことは、他の機能性を持つ
繊維をつくる場合にも言える。つまり、ある機能を持っ
た物質（粉末）を単に繊維等に混合または接着するだけ
でなくその繊維に混合または接着しても充分にその機能
を発揮出来る性質をもつ素材繊維でなければならない。What is important here is that
For example, when a substance having a deodorizing effect is mixed or adhered to the fiber, the substance is buried in the raw material for forming the chemical fiber. Therefore, the external odor and the deodorant cannot come into contact with each other, and the expected effect is often not obtained. In order for a fiber to have a deodorant function, it is necessary to give the fiber a ventilation function by which a malodorous substance outside the fiber is brought into contact with the deodorant substance in the fiber or the adhesive substance by some method. This is also true when making fibers with other functionalities. In other words, it is necessary to use a raw material fiber having the property of exerting its function sufficiently even if a substance (powder) having a certain function is not simply mixed or adhered to a fiber or the like but also mixed or adhered to the fiber.
【０００４】電気石は、天然に産出する特異な結晶であ
る。花崗岩等の火成岩層をマグマ（溶岩）が割って溶出
する時の変成作用によって電気石は作られる。電気石結
晶の格子点イオンが本来有るべき位置から、歪んでいる
ことによって電気石の永久電極がつくられる。常温でこ
の歪みを元に戻す事は不可能である。しかし、約 1,000
℃位の高温にすれば歪みも取れ、電極もなくなる。これ
は、磁性体における永久磁石のキュリー温度と似てい
る。弱いけれど安定な永久電極を持つものとして、現在
までに知られているものは、電気石（Tourmaline）だけ
である。Tourmaline is a unique crystal that occurs naturally. Tourmaline is produced by the metamorphism when magma (lava) breaks and elutes igneous rock layers such as granite. From the position where the lattice point ion of tourmaline should originally exist, a permanent electrode of tourmaline is created by being distorted. It is impossible to undo this distortion at room temperature. But about 1,000
If the temperature is raised to about ℃, the strain is removed and the electrode is lost. This is similar to the Curie temperature of a permanent magnet in a magnetic material. Tourmaline is the only one known to date as having a weak but stable permanent electrode.
【０００５】電気石が微弱ではあるが永久電極を有する
と言うことを利用して、電気石結晶を数ミクロンの微細
結晶に粉砕し、適当な誘電体に混合担持させて、その担
持物の電気抵抗が、電気石結晶の電気抵抗が有する約１
０10Ω・cmより充分低い１０4Ω・cm〜１０8Ω・cm程度
のものである場合か、あるいは担持物が２種類以上の物
質からなりその粒界が電子を輸送する性質を持っている
とき、微細ではあるが無数の電気石結晶の電極と水また
は水分を含む皮膚表層等の反応系において電極反応を示
す。たとえば、微少電流が皮膚表層を流れ、皮膚表面の
ある感覚受容器とこれにつながる神経において、いわゆ
る「電気刺激」を生じ、大脳を経て血行促進や痛みをブ
ロックすることによる抑制等いろいろな生理反応が生ま
れる。また、つぼや圧痛点に電気刺激を与えて、東洋医
学で言う経絡による治療に役立つ。これは、はり、灸等
と同様なものといえる。Taking advantage of the fact that tourmaline has a weak electrode but a permanent electrode, the tourmaline crystal is crushed into fine crystals of several microns and mixed and carried by a suitable dielectric material, and the electric power of the carried material is reduced. The resistance is about 1 that of tourmaline crystal
If it is about 10 4 Ω · cm to 10 8 Ω · cm, which is sufficiently lower than 0 10 Ω · cm, or if the supported material is composed of two or more kinds of substances and the grain boundaries have the property of transporting electrons. When it is present, it shows an electrode reaction in an infinitesimal number of tourmaline crystal electrodes and a reaction system such as skin surface layer containing water or water. For example, a minute electric current flows through the surface layer of the skin, causes so-called "electrical stimulation" in sensory receptors on the skin surface and nerves connected to this, and various physiological reactions such as suppression by promoting blood circulation and blocking pain via the cerebrum. Is born. In addition, it gives electrical stimulation to the acupuncture points and tender points, and is useful for the treatment by the meridian in Oriental medicine. It can be said that this is similar to acupuncture and moxibustion.
【０００６】電気石微粉末を繊維の原料に練り込むだけ
で、電気石の持つ電極機能を発現出来るものではないこ
とは他の機能を持つ各種粉末の場合と同様である。この
ためには、上述したように次の事が必要な条件である。 Ａ、 水、皮膚表層と言う反応系において電気石の電極
（カソード）から電子が流れ、反応系で目的とする反応
を果たし、一方の電極（アノード）に反応の結果生まれ
た電子が入ってくることによって電子の補充がなされ、
電気石電極の電極エネルギー（電位差）が維持されるこ
と。 Ｂ、 電気石微粉末が混入された担持物が皮膚面に接触
したとき、電子は電気石電極のカソードから電気石を被
覆している担持物を通して反応系例えば水又は水分を充
分含む皮膚表層等を通り、そして電気石を被覆している
物質を通じて電気石電極のアノードに入り、つぎに結晶
内を輸送されて電気石電極のカソードへ達する。 Ｃ、 電気石を混入する割合は、適切なものでなければ
ならない。その量が大きいと、繊維等の強度を弱め、高
価なノズルの損耗を大きくし、そのコストを高める。さ
らに、電気石特有の色により着色が濃くなり、製品の着
色加工を制限する等の不都合が生じる。逆に、あまり混
合物が少ないと、電気石の電極反応による効果が弱くな
る。[0006] The fact that the electrode function of tourmaline cannot be exhibited only by kneading tourmaline fine powder into the fiber raw material is the same as in the case of various powders having other functions. For this purpose, as described above, the following conditions are necessary. A, Electrons flow from the tourmaline electrode (cathode) in the reaction system such as water and skin surface layer, perform the desired reaction in the reaction system, and the electron generated as a result of the reaction enters one electrode (anode) By doing so, replenishment of electrons is made,
The electrode energy (potential difference) of tourmaline electrode must be maintained. B, When a carrier containing a mixture of tourmaline fine particles comes into contact with the skin surface, the electron passes from the cathode of the tourmaline electrode through the carrier covering the tourmaline to the reaction system, for example, the skin surface layer containing sufficient water or water. Through the material covering the tourmaline and into the anode of the tourmaline electrode and then transported through the crystal to the cathode of the tourmaline electrode. C, the rate of mixing tourmaline must be appropriate. When the amount is large, the strength of the fiber or the like is weakened, the wear of the expensive nozzle is increased, and the cost is increased. Further, the color unique to tourmaline causes deep coloring, which causes inconveniences such as limiting the coloring process of the product. On the contrary, if the mixture is too small, the effect of the electrode reaction of tourmaline becomes weak.
【０００７】ほとんどの合成繊維は水分率は非常に少な
くて、電気抵抗値も高く１０10Ω・cm〜１０14Ω・cmで
ある。これに対し、再生セルローズ繊維であるレーヨン
は、公定水分率が１０％程度を示し、天然セルローズを
主原料とした絹と同じ位である。この使用状態において
は、皮膚面と衣服の間の相対湿度が高くなり水分率は２
０％をこえる。レーヨンは、このような吸湿した状態で
は１０8Ω・cm 以下の電気抵抗値を示す。このことは、
電気石を練り込んだレーヨンを用いた各種繊維や布地は
肌と接触したときに充分な電気刺激を与えるものであ
る。しかし、実用上から見て、レーヨン自体は機械的強
度に弱く、また耐水性に劣る。さらに、コストの点から
考えても、電気石微粉末の混入量は少ない程よい。しか
し、混入量を減らすことは機能を低下し、商品性の上で
問題がある。また、粉体を 0.3ミクロン以下に小さくす
ることは、技術とコストの上で難しい。Most synthetic fibers have a very low water content and a high electric resistance value of 10 10 Ω · cm to 10 14 Ω · cm. On the other hand, rayon, which is a regenerated cellulose fiber, has an official moisture content of about 10%, which is about the same as that of silk whose main raw material is natural cellulose. In this state of use, the relative humidity between the skin surface and clothes is high and the moisture content is 2
Over 0%. Rayon exhibits an electric resistance value of 10 8 Ω · cm or less in such a moisture-absorbed state. This is
Various fibers and cloths using rayon in which tourmaline is kneaded give sufficient electric stimulation when contacting the skin. However, from a practical point of view, rayon itself has low mechanical strength and poor water resistance. Further, from the viewpoint of cost, the smaller the amount of tourmaline fine powder mixed, the better. However, reducing the amount of mixture lowers the function and poses a problem in terms of commerciality. Moreover, it is difficult in terms of technology and cost to reduce the powder size to less than 0.3 micron.
【０００８】[0008]
【課題を解決するための手段】本発明にかかる電気石微
粉末混入永久電極担持繊維と製造方法は、以上の問題点
に鑑みて、その使用状態における電気抵抗が104〜108Ω
・cm 程度の繊維に、1.0ミクロン〜0.3 ミクロンの電気
石結晶の微粉末を最大１０％（紡糸原液に対する重量
比）特に１〜３％混合したものとした。In view of the above problems, the electric resistance fine powder-mixed permanent electrode supporting fiber according to the present invention and the manufacturing method thereof have an electric resistance of 10 4 to 10 8 Ω in a use state.
The fine powder of tourmaline crystals of 1.0 micron to 0.3 micron was mixed at a maximum of 10% (weight ratio with respect to the spinning dope), especially 1 to 3%, to a fiber of about cm.
【０００９】以下に、本発明にかかる電気石微粉末混入
永久電極担持繊維と製造方法の具体的な構成を詳細に記
載する。最初に、本発明の請求項１に記載の発明の電気
石微粉末混入永久電極担持繊維の構成を説明する。これ
は、まず、1.0 ミクロン〜0.3 ミクロンの電気石結晶の
微粉末がある。つぎに、下記の繊維がある。この繊維
は、上記の微粉末を最大１０％（紡糸原液に対する重量
比）特に１〜３％混合したものであって、且つ天然また
は合成した高分子化合物を溶媒や加熱等によって溶解し
た溶液を冷却固化したものである。上記の繊維は、その
使用状態における直流電気抵抗値が電気石微粉末を含ん
だ状態で１０4Ω・cm 〜１０8Ω・cm 程度、特に１０5
〜１０7Ω・cm 程度のものから成る。The concrete constitution of the tourmaline fine powder-mixed permanent electrode supporting fiber and the manufacturing method according to the present invention will be described in detail below. First, the constitution of the tourmaline fine powder-mixed permanent electrode-supporting fiber of the invention according to claim 1 of the present invention will be described. First, there is a fine powder of tourmaline crystals of 1.0 micron to 0.3 micron. Next, there are the following fibers. This fiber is a mixture of the above-mentioned fine powders at a maximum of 10% (weight ratio to the spinning dope), especially 1 to 3%, and cools a solution in which a natural or synthetic polymer compound is dissolved by a solvent or heating. It is solidified. The above-mentioned fibers have a DC electric resistance value of about 10 4 Ω · cm to 10 8 Ω · cm, especially 10 5 Ω in a state of containing tourmaline fine powder.
It consists of about 10 7 Ω · cm.
【００１０】つぎに、本発明の請求項２に記載の発明の
電気石微粉末混入永久電極担持繊維の構成を説明する。
これは、以下の点以外は、上記の請求項１の発明の構成
と同一である。それゆえに、上記の請求項１の発明の構
成の説明の全文の内から下記の点を除きここに引用し
て、以下の構成の説明をこれに追加する。その差異は、
その電気石にある。この電気石は、電極の強さが従来知
られている鉄電気石のそれと比べて３〜１２倍特に１０
〜１２倍と極めて強い強力電極電気石である。Next, the structure of the tourmaline fine powder-mixed permanent electrode-supporting fiber of the invention according to claim 2 of the present invention will be described.
This is the same as the configuration of the invention of claim 1 except for the following points. Therefore, from the whole sentence of the description of the configuration of the invention of claim 1 above, the following description is added to the reference except for the following points. The difference is
It is on the tourmaline. The strength of this tourmaline is 3 to 12 times that of the conventionally known iron tourmaline, especially 10
It is a strong electric tourmaline with a strength of up to 12 times.
【００１１】しかして、最近我々は中華人民共和国から
産出する鉄電気石の中で、電極の強さが従来知られてい
る鉄電気石のそれと比べて、１０〜１２倍と極めて強い
鉄電気石を発見した。今後の調査によっては、他の地域
からも産出されるであろう。この鉄電気石（強力電極電
気石）は、その外見の結晶形自体は従来の鉄電気石と違
わないが、200 メッシュ程度の粉末にすると色が大きく
変化して、緑黄色やカーキ色とか無色（従来の鉄電気石
の200 メッシュ程度の粉末の色は濃紺と黒の中間色）で
ある。これは、結晶の光学的性質が異なるためであろ
う。200 〜300 メッシュの間にふるい分けた微粉を10ｇ
用いて、一定量（１リットル）のpH３の塩酸水溶液を電
気分解するときの電気電導度の変化（低下）の速さを指
標とした電極反応の強さは測定によれば従来知られてい
る鉄電気石に比べ１０〜１２倍と大きい。However, recently, among the iron tourmaline produced from the People's Republic of China, the strength of the electrode is 10 to 12 times as strong as that of the conventionally known iron tourmaline, which is extremely strong. I have found Depending on future research, it may be produced in other areas. This iron tourmaline (strong electrode tourmaline) does not differ from the conventional iron tourmaline in its crystalline form, but when it is made into powder of about 200 mesh, the color changes greatly, and it becomes greenish yellow or khaki or colorless ( The color of the powder of about 200 mesh of the conventional tourmaline is an intermediate color between dark blue and black). This may be due to the different optical properties of the crystals. 10g of fine powder sieved between 200-300 mesh
The strength of the electrode reaction, which is based on the rate of change (decrease) in the electric conductivity when a certain amount (1 liter) of a hydrochloric acid aqueous solution of pH 3 is electrolyzed, is known by measurement. It is 10 to 12 times larger than iron tourmaline.
【００１２】これを要約すれば、 Ａ． 電気石微粉末を練り込むときの物質は、他の機能
性物質応用の場合と同様にその機能を発揮できるような
物性を持ったものでなければならない。 Ｂ． 電気石を練り込んだ繊維に用いた素材の電気的性
質が電極からの電子の流れを阻止するものでないこと、
すなわち、電気石結晶内の電気抵抗値（１０10Ω・cm）
より高くなく、むしろ１０8〜１０4Ω・cmの範囲のもの
であることが必要である。言い換えれば、電流（電子の
流れと逆方向である）を絶縁するものであっては目的と
する機能を発現することはできないと言うことである。To summarize this, A. The substance used when kneading tourmaline fine powder must have physical properties capable of exerting its function as in the case of applying other functional substances. B. The electrical properties of the material used for the fibers mixed with tourmaline do not prevent the flow of electrons from the electrodes,
That is, the electric resistance value in the tourmaline crystal (10 10 Ω · cm)
It should not be higher, but rather in the range of 10 8 to 10 4 Ω · cm. In other words, it is not possible to exhibit the intended function if it insulates an electric current (which is in the opposite direction to the flow of electrons).
【００１３】なお、電気石の電極の強さは、電気石結晶
の種類とその一定量（重量）当りの粒度の大きさによっ
て大きく異なる。前述のように、同じ鉄電気石でも、一
般的な電気石原石の１２倍も強い電極の強さを示すもの
がある。また、鉄原子がリチウムやバリウムあるいはア
ルミニウム等に置換したものも数倍〜十数倍の電極の強
さを持つ。資源的および価格の点からは、他に用途のな
い鉄電気石やマグネシウム電気石が本発明の素材として
は適しているが、この中でも最近見つかった１０倍以上
の電極の強さのものは素材として重要である。価格等に
大差がなければ電極の強い物を用いる方が、混入量も少
なくノズルの損耗によるコストアップも防ぎ、色も薄
く、染色も容易になる。以上の理由により、繊維への混
入量は最大１０％としたが、実用上は用いる電気石の電
極の強さによって混入量は最適量を決める。これはその
繊維の用途やコスト等で決まるが、一般的には３％〜１
％の量が適当である。The strength of the tourmaline electrode greatly differs depending on the type of tourmaline crystal and the size of the particle size per a fixed amount (weight) thereof. As described above, even the same iron tourmaline exhibits a 12 times stronger electrode strength than general tourmaline ore. In addition, a material in which iron atoms are replaced with lithium, barium, aluminum, or the like also has an electrode strength which is several times to several tens times. From the viewpoint of resource and price, iron tourmaline and magnesium tourmaline, which have no other uses, are suitable as the material of the present invention, but among them, the ones which have recently been found to have an electrode strength of 10 times or more are materials. As important as. If there is no big difference in price etc., it is better to use a material with a strong electrode because the amount of mixture is small and the cost increase due to wear of the nozzle is prevented, the color is light and the dyeing is easy. For the above reasons, the maximum amount of fibers mixed is 10%, but in practice, the optimum amount is determined by the strength of the tourmaline electrode used. This depends on the use and cost of the fiber, but generally 3% to 1
% Amounts are suitable.
【００１４】そして、本発明の請求項３に記載の発明の
電気石微粉末混入永久電極担持繊維の製造方法の構成を
説明する。これはまず、電気石結晶を 1.0ミクロン〜0.
3 ミクロンと微細化する。つぎに、この微粉末を天然ま
たは合成した高分子化合物を溶媒や加熱等によって溶解
した溶液の中に混入する。その混入量は、最大１０％
（紡糸原液に対する重量比）特に１〜３％である。そし
て、これを孔の細い紡糸口金（白金やセラミックが多
い）から押し出し、冷却固化して繊維とする。上記の繊
維は、その使用状態における直流電気抵抗値が、電気石
微粉末を含んだ状態で、１０4Ω・cm 〜１０8Ω・cm 程
度、特に１０5〜１０7Ω・cm 程度のものから成るも の
である。Then, the construction of the method for producing a permanent electrode-supporting fiber mixed with tourmaline fine powder according to the third aspect of the present invention will be described. First of all, tourmaline crystal is 1.0 micron to 0.
Miniaturized to 3 microns. Next, the fine powder is mixed into a solution in which a natural or synthetic polymer compound is dissolved by a solvent or heating. The maximum content is 10%
(Weight ratio to spinning dope) It is especially 1 to 3%. Then, this is extruded from a spinneret having thin holes (mostly platinum and ceramics), and cooled and solidified to form fibers. The above fibers have a DC electric resistance value of about 10 4 Ω · cm to 10 8 Ω · cm, especially about 10 5 to 10 7 Ω · cm in a state of containing tourmaline fine powder in the usage state. It consists of
【００１５】最後に、本発明の請求項４に記載の発明の
電気石微粉末混入永久電極担持繊維の製造方法の構成を
説明する。これは、以下の点以外は、上記の請求項３の
発明の構成と同一である。それゆえに、上記の請求項３
の発明の構成の説明の全文の内から下記の点を除きここ
に引用して、以下の構成の説明をこれに追加する。その
差異は、その電気石にある。この電気石は、電極の強さ
が従来知られている鉄電気石のそれと比べて３〜１２倍
特に１０〜１２倍と極めて強い強力電極電気石である。Finally, the construction of the method for producing a fiber carrying a tourmaline fine powder according to the fourth aspect of the present invention will be described. This is the same as the configuration of the invention of claim 3 except for the following points. Therefore, claim 3 above
Except for the following points, the entire text of the description of the configuration of the invention is cited here, and the following description of the configuration is added thereto. The difference lies in the tourmaline. This tourmaline is a strong electrode tourmaline whose strength is 3 to 12 times, especially 10 to 12 times that of the conventionally known iron tourmaline.
【００１６】[0016]
【作用】本発明にかかる電気石微粉末混入永久電極担持
繊維と製造方法は、以上のごとくに構成したゆえに以下
のごとき作用が生じた。最初に、本発明の請求項１に記
載の発明の電気石微粉末混入永久電極担持繊維の作用を
説明する。これは、1.0ミクロン〜0.3 ミクロンの電気
石結晶の微粉末を最大１０％（紡糸原液に対する重量
比）特に１〜３％混合したものであって、且つ天然また
は合成した高分子化合物を溶媒や加熱等によって溶解し
た溶液を冷却固化した繊維が、永久電極を含有する。そ
して、この繊維は、その使用状態における直流電気抵抗
値が電気石微粉末を含んだ状態で、１０4Ω・cm〜１０8
Ω・cm 程度、特に１０5 〜１０7Ω・cm 程度のものか
ら成るゆえに、この繊維は反応系において電極反応を示
す。The permanent magnet electrode-supporting fiber mixed with tourmaline fine powder and the method for producing the same according to the present invention have the following effects because of the above-described construction. First, the operation of the tourmaline fine powder-mixed permanent electrode-supporting fiber of the invention according to claim 1 of the present invention will be described. This is a mixture of 1.0 micron to 0.3 micron tourmaline crystal fine powder at a maximum of 10% (weight ratio to the stock solution for spinning), especially 1 to 3%, and a natural or synthetic polymer compound as a solvent or heating. The fiber obtained by cooling and solidifying the solution dissolved by the etc. contains the permanent electrode. This fiber has a DC electric resistance value of 10 4 Ω · cm to 10 8 in a state of containing tourmaline fine powder.
Since the fibers are of the order of Ω · cm, in particular of the order of 10 5 to 10 7 Ω · cm, this fiber exhibits an electrode reaction in the reaction system.
【００１７】つぎに、本発明の請求項２に記載の発明の
電気石微粉末混入永久電極担持繊維の作用を説明する。
これは、以下の点以外は、上記の請求項１の発明の作用
と同一である。それゆえに、上記の請求項１の発明の作
用の説明の全文の内から下記の点を除きここに引用し
て、以下の作用の説明をこれに追加する。その差異は、
その電気石にある。この電気石は、電極の強さが従来知
られている鉄電気石のそれと比べて３〜１２倍特に１０
〜１２倍と極めて強い強力電極電気石であるゆえに、電
気石が少量でも反応系において充分な電極反応を示す。Next, the operation of the tourmaline fine powder-mixed permanent electrode-supporting fiber of the present invention according to claim 2 of the present invention will be described.
This is the same as the operation of the invention of claim 1 except for the following points. Therefore, the entire description of the operation of the invention according to claim 1 is cited herein except for the following points, and the following description of the operation is added thereto. The difference is
It is on the tourmaline. The strength of this tourmaline is 3 to 12 times that of the conventionally known iron tourmaline, especially 10
Since it is a strong electrode tourmaline with an extremely strong strength of ~ 12 times, even a small amount of tourmaline shows a sufficient electrode reaction in the reaction system.
【００１８】そして、本発明の請求項３に記載の発明の
電気石微粉末混入永久電極担持繊維の製造方法の作用を
説明する。まず、電気石結晶を 1.0ミクロン〜0.3 ミク
ロンと微細化する。つぎに、この微粉末を天然または合
成した高分子化合物を溶媒や加熱等によって溶解した溶
液の中に混入して、これを孔の細い紡糸口金（白金やセ
ラミックが多い）から押し出し、冷却固化して繊維とす
るゆえに、永久電極を含有した繊維となる。そして、上
記の繊維は、その使用状態における直流電気抵抗値が電
気石微粉末を含んだ状態で１０4Ω・cm〜１０8Ω・cm
程度特に１０5〜１０7Ω・cm 程度のものから成るもの
であるゆえに、この繊維は反応系において電極反応を示
す。Then, the operation of the method for producing a fiber carrying a tourmaline fine powder according to the third aspect of the present invention will be described. First, the tourmaline crystal is refined to 1.0 micron to 0.3 micron. Next, the fine powder is mixed with a solution of a natural or synthetic polymer compound dissolved in a solvent or heating, and the mixture is extruded from a spinneret with small pores (mostly platinum or ceramic) and solidified by cooling. As a result, it becomes a fiber containing a permanent electrode. Further, the above-mentioned fibers have a DC electric resistance value of 10 4 Ω · cm to 10 8 Ω · cm in a state of containing tourmaline fine powder in the use state
Since these fibers have a degree of about 10 5 to 10 7 Ω · cm, they show an electrode reaction in the reaction system.
【００１９】最後に、本発明の請求項４に記載の発明の
電気石微粉末混入永久電極担持繊維の製造方法の作用を
説明する。これは、以下の点以外は、上記の請求項３の
発明の作用と同一である。それゆえに、上記の請求項３
の発明の作用の説明の全文の内から下記の点を除きここ
に引用して、以下の作用の説明をこれに追加する。その
差異は、その電気石にある。この電気石は、電極の強さ
が従来知られている鉄電気石のそれと比べて３〜１２倍
特に１０〜１２倍と極めて強い強力電極電気石であるゆ
えに、電気石が少量でも反応系において充分な電極反応
を示す。Finally, the operation of the method for producing a permanent electrode-supporting fiber mixed with tourmaline fine powder according to the fourth aspect of the present invention will be described. This is the same as the operation of the invention of claim 3 except for the following points. Therefore, claim 3 above
From the entire text of the description of the operation of the present invention, the following description is added to the above except for the following points. The difference lies in the tourmaline. This tourmaline is a very strong electrode tourmaline with an electrode strength of 3 to 12 times, especially 10 to 12 times that of the conventionally known iron tourmaline, so even if a small amount of tourmaline is used in the reaction system. Shows sufficient electrode reaction.
【００２０】[0020]
【実施例】以下に、本発明にかかる電気石微粉末混入永
久電極担持繊維と製造方法をその一実施例を用いて添付
の図面と共に詳細に述べる。図１は、本発明にかかる電
気石微粉末混入永久電極担持繊維の一実施例の側面図の
一部を示したものである。図２は、図１のものの一部の
拡大断面図を示したものであって、説明用の概略図であ
る。EXAMPLE A tourmaline fine powder-mixed permanent electrode supporting fiber according to the present invention and a method for producing the same will be described below in detail with reference to the accompanying drawings by using an example thereof. FIG. 1 shows a part of a side view of an embodiment of a permanent electrode supporting fiber mixed with tourmaline fine powder according to the present invention. FIG. 2 shows an enlarged cross-sectional view of a portion of FIG. 1 and is a schematic diagram for explanation.
【００２１】しかして、本発明にかかる電気石微粉末混
入永久電極担持繊維の一実施例を以下に説明する。ま
ず、1.0 ミクロン〜0.3 ミクロンの電気石結晶の微粉末
１がある。なお、本明細書において示すこの微粉末１の
サイズは当然ながら平均値である。つぎに、下記の繊維
２がある。この繊維２は、上記の微粉末１を最大１０％
（紡糸原液に対する重量比）特に１〜３％混合したもの
であり、且つ天然または合成した高分子化合物を溶媒や
加熱等によって溶解した溶液を冷却固化したものであ
る。上記の繊維２は、その使用状態における直流電気抵
抗値が、その繊維２に電気石微粉末を含んだ状態で、１
０4Ω・cm〜１０8Ω・cm 程度、特に１０5〜１０7Ω・c
m 程度のものから成る。An embodiment of the tourmaline fine powder-mixed permanent electrode supporting fiber according to the present invention will be described below. First, there is a fine powder 1 of tourmaline crystal having a size of 1.0 micron to 0.3 micron. The size of the fine powder 1 shown in this specification is, of course, an average value. Next, there is the following fiber 2. This fiber 2 contains up to 10% of the above fine powder 1
(Weight ratio to spinning stock solution) Particularly, it is a mixture of 1 to 3%, and a solution obtained by dissolving a natural or synthetic polymer compound by a solvent or heating is cooled and solidified. The fiber 2 has a DC electric resistance value of 1 when the fiber 2 contains tourmaline fine powder.
0 4 Ω · cm to 10 8 Ω · cm, especially 10 5 to 10 7 Ω · c
It consists of about m.
【００２２】つぎに、本発明にかかる電気石微粉末混入
永久電極担持繊維の製造方法の一実施例を以下に説明す
る。まず、電気石結晶を湿式トロンミル等を用いて 1.0
ミクロン〜0.3 ミクロンと微細化する。この微粉末を天
然または合成した高分子化合物を溶媒等で溶解するか、
加熱によって溶解した液の中に混合し、孔の細い紡糸口
金（白金やセラミック製が多い）から押し出して、冷却
固化し、繊維を形成させる。Next, an embodiment of the method for producing the permanent electrode supporting fiber mixed with tourmaline fine powder according to the present invention will be described below. First, the tourmaline crystal is applied to 1.0
Micron to 0.3 micron. Dissolve a polymer compound that is a natural or synthetic form of this fine powder in a solvent, or
It is mixed in a liquid that is melted by heating, extruded from a spinneret with small pores (often made of platinum or ceramic), cooled and solidified to form fibers.
【００２３】電気石粉末の混入量は、最大１０％（紡糸
原液に対する重量比）、近くまでは可能であるが、余り
多いと繊維の機械的強度が弱くなる。また、高価な紡糸
口金の磨耗によるコストの問題も生じる。そこで、この
新しく中華人民共和国で発見された強力電気石の場合
は、１〜３％を繊維の原料に練り込むだけで反応系にお
いて充分な電極反応が得れるゆえに、この困難な問題は
殆ど解決した。The amount of tourmaline powder mixed can be up to 10% (weight ratio with respect to the spinning dope), but if it is too large, the mechanical strength of the fiber becomes weak. Further, there is a problem of cost due to wear of the expensive spinneret. Therefore, in the case of this powerful tourmaline newly discovered in the People's Republic of China, a sufficient electrode reaction can be obtained in the reaction system simply by kneading 1 to 3% into the raw material of the fiber, and thus this difficult problem is almost solved. did.
【００２４】この強力電気石をレーヨンの原料に１％混
入したものと、従来の鉄電気石を３％混入したのもので
紡糸をつくり電極反応の強さを比較したが、強力電気石
の場合は後者のものの４倍を示した。また、通常の電気
石を使用の場合は、電気石混合の繊維の原料を繊維状に
する高価な紡糸口金が、混入量の多い電気石のために損
耗が激しいが、この強力電気石をレーヨンへ１％混入し
た場合は、高価な紡糸口金の損耗は殆ど生じない。The strength of the electrode reaction was compared by spinning with a mixture of 1% of this strong tourmaline in the raw material of rayon and a mixture of conventional iron tourmaline of 3%. Showed four times the latter. Also, when using a regular tourmaline, the expensive spinneret, which makes the raw material of the tourmaline mixed fiber into a fibrous state, is heavily worn due to the tourmaline containing a large amount of this tourmaline. When 1% is mixed in, the wear of the expensive spinneret hardly occurs.
【００２５】かようにして、図２に示すごとく、電気石
の微粉末１の永久電極からでる電流は繊維２と皮膚３等
を点線で示したごとくに流れる。Thus, as shown in FIG. 2, the electric current from the permanent electrode of the tourmaline fine powder 1 flows through the fibers 2 and the skin 3 as shown by the dotted lines.
【００２６】[0026]
【発明の効果】本発明にかかる電気石微粉末混入永久電
極担持繊維と製造方法は、以上のごとくになしたゆえに
以下のごとき多大な効果が生じた。すなわち、電気石の
結晶をを 1.0〜0.3 ミクロン程度の微粉末にしたことに
より、電気石の電極の数が非常に増えた。As described above, the tourmaline fine powder-mixed permanent electrode supporting fiber and the manufacturing method according to the present invention have the following great effects. That is, the number of tourmaline electrodes was greatly increased by converting tourmaline crystals into fine powder of about 1.0 to 0.3 microns.
【００２７】その電気石を、電極の強さが従来知られて
いる鉄電気石のそれと比べて、３〜１２倍特に１０〜１
２倍と極めて強い強力電極電気石を使用した場合は、電
気石の混入量が微量でも充分な電極反応を示すゆえ、繊
維原液を繊維状にする高価な紡糸口金の損耗は殆ど生じ
ない。そして、その繊維の色も白色に近い。したがっ
て、繊維の着色の色の限定も減少し、それだけ着色が自
由になる。The tourmaline is 3 to 12 times as strong as that of the iron tourmaline in which the strength of the electrode is conventionally known, particularly 10 to 1.
In the case of using a strong electrode tourmaline having an extremely strong strength of 2 times, even if a small amount of tourmaline is mixed, a sufficient electrode reaction is exhibited, so that wear of an expensive spinneret for making a fiber stock solution into a fiber hardly occurs. And the color of the fiber is also close to white. Therefore, the limitation of the color of the coloring of the fiber is reduced, and the coloring becomes free.
【００２８】そして、この繊維は、その使用状態におけ
る直流電気抵抗値が、その繊維に電気石微粉末を含んだ
状態で、１０4Ω・cm〜１０8Ω・cm 程度、特に１０5〜
１０7Ω・cm 程度のものから成るゆえに、その繊維の中
に含まれる永久電極による適度な電極反応を示すものと
なった。This fiber has a direct current electrical resistance value of about 10 4 Ω · cm to 10 8 Ω · cm, particularly 10 5 to about 10 5 Ω · cm in a state in which the fiber contains tourmaline fine powder.
Since it consisted of about 10 7 Ω · cm, it exhibited an appropriate electrode reaction due to the permanent electrode contained in the fiber.
【００２９】この電気石を含む繊維によって、皮膚表層
を微少電流が流れて、皮膚表面のある感覚受容器とこれ
につながる神経において、電気刺激を生じ、大脳を経て
いろいろな生理反応が生まれるゆえに、その応用価値は
大きいものである。A minute electric current flows through the surface layer of the skin by the fibers containing tourmaline, and electrical stimulation is generated in the sensory receptors on the skin surface and the nerves connected thereto, and various physiological reactions are generated through the cerebrum. Its application value is great.
【００３０】その他、身体用の応用例以外にも、空気清
浄機やエアーコンディショナー等の集塵機等の電極反応
による多種の効果が生じる。In addition to the application examples for the body, various effects are produced by the electrode reaction of dust collectors such as air cleaners and air conditioners.
【図１】本発明にかかる電気石微粉末混入永久電極担持
繊維の一実施例の側面図の一部を示したものである。FIG. 1 shows a part of a side view of an embodiment of a permanent electrode-supporting fiber mixed with tourmaline fine powder according to the present invention.
【図２】図１のものの一部の拡大断面図を示したもので
あって、説明用の概略図である。FIG. 2 is an enlarged cross-sectional view of a part of FIG. 1 and is a schematic diagram for explanation.
１ 電気石 ２ 繊維 1 Tourmaline 2 Fiber
Claims (4)
の微粉末、該微粉末を最大１０％（紡糸原液に対する重
量比）特に１〜３％混合したものであって天然または合
成した高分子化合物を溶媒や加熱等によって溶解した溶
液を冷却固化した下記の繊維、より構成されることを特
徴とした電気石微粉末混入永久電極担持繊維。上記の繊
維は、その使用状態における直流電気抵抗値が電気石微
粉末を含んだ状態で、１０4Ω・cm〜１０8Ω・cm 程度
特に１０5〜１０7Ω・cm 程度のものから成るものであ
る。1. A fine powder of tourmaline crystals of 1.0 micron to 0.3 micron, which is a natural or synthetic polymer compound in which the fine powder is mixed at a maximum of 10% (weight ratio with respect to the spinning dope), especially 1 to 3%. A permanent electrode-supporting fiber mixed with tourmaline fine powder, characterized by comprising the following fiber obtained by cooling and solidifying a solution obtained by dissolving the above in a solvent or heating. The above fiber is made of a material having a direct current electric resistance value of about 10 4 Ω · cm to 10 8 Ω · cm, especially about 10 5 to 10 7 Ω · cm in a state of containing tourmaline fine powder in its used state. It is a thing.
石結晶の微粉末、該微粉末を最大１０％（紡糸原液に対
する重量比）特に、１〜３％混合したものであって天然
または合成した高分子化合物を溶媒や加熱等によって溶
解した溶液を冷却固化した下記の繊維、より構成される
ことを特徴とした電気石微粉末混入永久電極担持繊維。
上記の電気石は、電極の強さが従来知られている鉄電気
石のそれと比べて３〜１２倍特に１０〜１２倍と極めて
強い電気石（以下、本明細書においては「強力電極電気
石」と言う）である。上記の繊維は、その使用状態にお
ける直流電気抵抗値が電気石微粉末を含んだ状態で、１
０4Ω・cm〜１０8Ω・cm 程度特に１０5〜１０7Ω・cm
程度のものから成るものである。2. A fine powder of tourmaline crystal having a particle size of 1.0 micron to 0.3 micron, which is a mixture of the fine powder at a maximum of 10% (weight ratio with respect to the spinning dope), especially 1 to 3%, which is natural or synthetic. A tourmaline fine powder-mixed permanent electrode-supporting fiber comprising the following fiber obtained by cooling and solidifying a solution obtained by dissolving a polymer compound in a solvent or heating.
The tourmaline described above has a very strong tourmaline having an electrode strength of 3 to 12 times, particularly 10 to 12 times, as compared with that of a conventionally known iron tourmaline (hereinafter, referred to as “strong electrode tourmaline” in the present specification). "). The above-mentioned fibers have a DC electric resistance value in the use state of containing tourmaline fine powder of 1
0 4 Ω · cm to 10 8 Ω · cm, especially 10 5 to 10 7 Ω · cm
It consists of a few things.
と微細化し、この微粉末を天然または合成した高分子化
合物を溶媒や加熱等によって溶解した溶液の中にその混
入量を最大１０％（紡糸原液に対する重量比）特に１〜
３％混合し、これを孔の細い紡糸口金（白金やセラミッ
クが多い）から押し出し、冷却固化して繊維とする、こ
とより構成されることを特徴とした電気石微粉末混入永
久電極担持繊維の製造方法。上記の繊維は、その使用状
態における直流電気抵抗値が電気石微粉末を含んだ状態
で、１０4Ω・cm〜１０8Ω・cm 程度特に１０5〜１０7
Ω・cm 程度のものから成るものである。3. A tourmaline crystal is refined to 1.0 micron to 0.3 micron, and the fine powder is dissolved in a solution of a natural or synthetic polymer compound in a solvent or by heating. Weight ratio to undiluted solution) Especially 1 ~
3% mixed, extruded from a spinneret with small pores (mostly platinum and ceramics), cooled and solidified to form fibers, Production method. The above fibers have a DC electric resistance value of 10 4 Ω · cm to 10 8 Ω · cm, particularly 10 5 to 10 7 when the DC electric resistance value in the use state includes tourmaline fine powder.
It is composed of about Ω · cm.
3 ミクロンと微細化し、この微粉末を天然または合成し
た高分子化合物を溶媒や加熱等によって溶解した溶液の
中にその混入量を最大１０％（紡糸原液に対する重量
比）特に１〜３％混合し、これを孔の細い紡糸口金（白
金やセラミックが多い）から押し出し、冷却固化して繊
維とする、ことより構成されることを特徴とした電気石
微粉末混入永久電極担持繊維の製造方法。上記の繊維
は、その使用状態における直流電気抵抗値が電気石微粉
末を含んだ状態で、１０4Ω・cm〜１０8Ω・cm 程度特
に１０5〜１０7Ω・cm 程度のものから成るものであ
る。4. A strong electrode tourmaline crystal of 1.0 micron to 0.
Finely powdered to 3 microns, and mixing this fine powder with a solution of a natural or synthetic polymer compound dissolved in a solvent, heating, etc. up to 10% (weight ratio to the spinning dope), especially 1 to 3%. A method for producing a permanent electrode-supporting fiber mixed with tourmaline fine powder, which comprises extruding this from a spinneret having fine pores (mostly platinum and ceramics) and cooling and solidifying to form a fiber. The above fiber is made of a material having a direct current electric resistance value of about 10 4 Ω · cm to 10 8 Ω · cm, especially about 10 5 to 10 7 Ω · cm in a state of containing tourmaline fine powder in its used state. It is a thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3623493A JPH06228808A (en) | 1993-02-02 | 1993-02-02 | Permanent electrode-carrying fiber mixed with tourmaline fine power and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3623493A JPH06228808A (en) | 1993-02-02 | 1993-02-02 | Permanent electrode-carrying fiber mixed with tourmaline fine power and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06228808A true JPH06228808A (en) | 1994-08-16 |
Family
ID=12464089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3623493A Pending JPH06228808A (en) | 1993-02-02 | 1993-02-02 | Permanent electrode-carrying fiber mixed with tourmaline fine power and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06228808A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0735164A2 (en) * | 1995-03-27 | 1996-10-02 | Kuraray Co., Ltd. | Fiber product containing pyroelectric substance |
| KR970064706A (en) * | 1996-03-14 | 1997-10-13 | 데쯔 지로 구보 | Air generating device and method for generating hydroxyl minus ion with humidification function |
| WO2007055432A1 (en) * | 2005-11-14 | 2007-05-18 | Se Da Coperation Co., Ltd. | Yarn and manufacture method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63152413A (en) * | 1986-12-15 | 1988-06-24 | Nobuhide Maeda | Composite fiber radiating far infrared radiation |
| JPH02169764A (en) * | 1988-12-21 | 1990-06-29 | Biimu Kogyo Kk | Electret fiber |
| JPH04327207A (en) * | 1991-04-26 | 1992-11-16 | Beam Kogyo Kk | Production of electrifiable rayon fiber |
-
1993
- 1993-02-02 JP JP3623493A patent/JPH06228808A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63152413A (en) * | 1986-12-15 | 1988-06-24 | Nobuhide Maeda | Composite fiber radiating far infrared radiation |
| JPH02169764A (en) * | 1988-12-21 | 1990-06-29 | Biimu Kogyo Kk | Electret fiber |
| JPH04327207A (en) * | 1991-04-26 | 1992-11-16 | Beam Kogyo Kk | Production of electrifiable rayon fiber |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0735164A2 (en) * | 1995-03-27 | 1996-10-02 | Kuraray Co., Ltd. | Fiber product containing pyroelectric substance |
| EP0735164A3 (en) * | 1995-03-27 | 1997-05-07 | Kuraray Co | Fiber product containing pyroelectric substance |
| US5981063A (en) * | 1995-03-27 | 1999-11-09 | Kuraray Co., Ltd. | Fiber product containing pyroelectric substance |
| KR100452250B1 (en) * | 1995-03-27 | 2005-06-27 | 니혼에뽁끄 가부시끼가이샤 | Textile Products Containing Superconducting Materials |
| KR970064706A (en) * | 1996-03-14 | 1997-10-13 | 데쯔 지로 구보 | Air generating device and method for generating hydroxyl minus ion with humidification function |
| WO2007055432A1 (en) * | 2005-11-14 | 2007-05-18 | Se Da Coperation Co., Ltd. | Yarn and manufacture method thereof |
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