JPH06227921A - Herbicidal formula composition for paddy field - Google Patents

Abstract

PURPOSE:To provide the subject composition expandable in herbicidal range and the period range for its suitable application without impairing its safety to paddy rice, and giving adequate effect thereof through mutual mixing of the components at respective doses greatly lower than those in the case of using the respective components singly. CONSTITUTION:The objective herbicide composed of (A) 3-(2-fluoro-4-chloro-5- cyclopentyloxyphenyl)-5-isopropylidene-1,3-oxazoline-2,4-dione etc., and (B) 1-(alpha,alpha- dimethylbenzyl)-3-p-tolylurea.

Description

Detailed Description of the Invention

[0001]

[Object of the Invention]

[0002]

FIELD OF THE INVENTION The present invention relates to a novel herbicidal composition for paddy fields having excellent herbicidal activity.

[0003]

2. Description of the Related Art At present, many herbicides have been put into practical use as paddy herbicides and widely used as single and mixed agents.

The 3- (2-fluoro-4-chloro-5-cyclopentyloxyphenyl) -5-isopropylidene-1,3-oxazoline-2,4-dione (hereinafter referred to as compound A) of the present invention is It is a known compound described in JP-A No. 62-167713.

The 3-chloro-2- (4-chloro-) of the present invention
2-Fluoro-5-propargyloxyphenyl)-
4,5,6,7-Tetrahydro-2H-indazole (hereinafter referred to as compound B) is disclosed in JP-A-59-84872.
It is a known compound described in Japanese Patent Publication No.

2- [4-chloro-2-fluoro-5- (1-methyl-2-propynyloxy) phenyl] -4,5,6,7-tetrahydroisoindole of the present invention
1,3-dione (hereinafter, referred to as compound C) is disclosed in
It is a known compound described in JP-A 8-38256.

2- (7-Fluoro-4-propargyl-2H-1,4-benzoxazine-3 (4H) of the present invention
-On-6-yl) -4,5,6,7-tetrahydroisoindole-1,3-dione (hereinafter referred to as compound D) is a known compound described in JP-B-4-1748. is there.

2- (4-chloro-2-fluoro-5-carboxymethoxyphenyl) -4,5,6,7 of the present invention
-Tetrahydroisoindole-1,3-dione (hereinafter referred to as compound E) is a known compound described in European Patent Publication 83,055.

These compounds A, B, C, D and E belong to a group of compounds generally called phthalimide herbicides,
Although it has an effect on annual grass weeds, especially broad-leaved weeds, perennial weeds, for example, firefly, Cyperaceae family, Cyperus japonicus, kurogwai etc. May cause drug damage. Especially under bad environmental conditions such as high temperature, sandy soil, leaky rice field,
In addition, shallow planting and seedlings immediately after transplantation will cause even stronger chemical damage.

On the other hand, 1- (α, α-dimethylbenzyl) -3-p-tolylurea (hereinafter referred to as compound F) of the present invention is a known herbicide with a general name of Daimlon,
It has been widely used as a herbicide for these weeds because it has an excellent herbicidal effect on cyperaceae, firefly, etc. of Cyperaceae weeds in paddy fields.

So far, the compounds A, B, C, D and E
There is no known admixture comprising one or more compounds selected from and compound F.

[0012]

DISCLOSURE OF THE INVENTION The present invention is intended to provide a practically useful herbicide for paddy fields, which shows less phytotoxicity to transplanted paddy rice and shows high efficacy against annual and perennial weeds.

[0013]

[Constitution of the invention]

[0014]

The present invention provides 3- (2-fluoro-4-chloro-5-cyclopentyloxyphenyl) -5-isopropylidene-1,3-oxazoline-
2,4-dione, 3-chloro-2- (4-chloro-2-
Fluoro-5-propargyloxyphenyl) -4,
5,6,7-Tetrahydro-2H-indazole, 2-
[4-chloro-2-fluoro-5- (1-methyl-2-
Propinyloxy) phenyl] -4,5,6,7-tetrahydroisoindole-1,3-dione, 2- (7-
Fluoro-4-propargyl-2H-1,4-benzoxazin-3 (4H) -on-6-yl) -4,5,
From 6,7-tetrahydroisoindole-1,3-dione and 2- (4-chloro-2-fluoro-5-carboxymethoxyphenyl) -4,5,6,7-tetrahydroisoindole-1,3-dione One or more compounds selected and 1- (α, α-dimethylbenzyl) -3-p
-A herbicidal compounding composition for paddy fields, which is characterized by being mixed with tolyl urea.

The synergistic effect according to the present invention is observed in a wide range of mixing ratios, and 0.1 to 10 parts by weight of compound F is added to 1 part by weight of compound A, B, C, D or E. Can be mixed to make useful herbicides. The herbicide of the present invention thus completed can be highly effective in soil treatment before and after germination of weeds.

The mixture of the present invention may be sprayed on the drug substance itself, or may be mixed with a carrier and, if necessary, other auxiliary agents to prepare a formulation form usually used as a herbicide, for example, powder, coarse powder, It is prepared and used as a fine granule, a granule, a wettable powder, an emulsion, an aqueous suspension, a wettable granule, an oil suspension and the like.

Suitable solid carriers used for preparing the herbicide of the present invention include clays represented by kaolinite group, montmorillonite group or attapulgite group, talc, mica, pyrophyllite, pumice, vermiculite, Gypsum, calcium carbonate, dolomite, diatomaceous earth, magnesium lime, apatite, zeolite, anhydrous silicic acid, inorganic substances such as synthetic calcium silicate, soybean powder, tobacco flour, walnut flour, wheat flour, wood flour, starch, crystals Vegetable organic substances such as cellulose, coumarone resin, petroleum resin,
Examples thereof include synthetic or natural polymer compounds such as alkyd resins, polyvinyl chloride, polyalkylene glycols, ketone resins, ester gums, cobal gums, dammal gums, waxes such as carnauba wax and beeswax, and urea.

Suitable liquid carriers include paraffinic or naphthenic hydrocarbons such as kerosene, mineral oil, spindle oil and white oil, aromatic hydrocarbons such as benzene, toluene, xylene, ethylbenzene, cumene and methylnaphthalene, and tetrachloride. Carbon, chlorinated hydrocarbons such as chloroform, trichloroethylene, monochlorobenzene, O-chlorotoluene, dioxane, ethers such as tetrahydrofuran, acetone, methyl ethyl ketone,
Ketones such as diisobutyl ketone, cyclohexanone, acetophenone, and isophorone, ethyl acetate, amyl acetate, ethylene glycol acetate, diethylene glycol acetate, dibutyl maleate, esters such as diethyl succinate, methanol, n-hexanol, ethylene glycol, dietine glycol , Cyclohexanol, alcohols such as benzyl alcohol, ethylene glycol ethyl ether, ethylene glycol phenyl ether, diethylene glycol ethyl ether,
Examples thereof include ether alcohols such as diethylene glycol butyl ether, polar solvents such as dimethylformamide and dimethylsulfoxide, and water.

Surfactants used for the purposes of emulsification, dispersion, wetting, spreading, binding, control of disintegration, stabilization of active ingredient, improvement of fluidity, rust prevention, etc. are nonionic, anionic and cationic. Either ionic or zwitterionic may be used, but usually nonionic and / or anionic ones are used. Examples of suitable nonionic surfactants include those obtained by polymerizing addition of ethylene oxide to higher alcohols such as lauryl alcohol, stearyl alcohol and oleyl alcohol, those obtained by polymerizing addition of ethylene oxide to alkylphenols such as isooctylphenol and nonylphenol, Butyl naphthol, octyl naphthol and other alkyl naphthols with ethylene oxide polymerized, palmitic acid, stearic acid, oleic acid and other higher fatty acids with ethylene oxide polymerized and added, these nonionic surfactants and phosphoric acid A mixture of monoesters, diesters and triesters or sulfuric acid ester and salts thereof, dodecylamine, stearic acid amide and other amines polymerized with ethylene oxide, sorbiters That the higher fatty acid ester and ethylene oxide to that of the polyhydric alcohol and the like were polymerized addition, such as those obtained by polymerizing addition of ethylene oxide and propylene oxide. Suitable anionic surfactants include, for example, sodium lauryl sulfate, alkyl sulfate ester salts such as oleyl alcohol sulfate amine salt, sodium dioctyl sulfosuccinate, sodium isopropylnaphthalenesulfonate, sodium methylenebisnaphthalenesulfonate, Examples thereof include aryl sulfonates such as sodium lignin sulfonate and sodium dodecylbenzene sulfonate.

Further, the herbicide of the present invention contains casein, gelatin, and gelatin for the purpose of improving the properties of the preparation and enhancing the biological effect.
High molecular compounds such as albumin, glue, sodium alginate, carboxymethyl cellulose, methyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol and the like and other auxiliary agents can be used together.

The above-mentioned carrier and various auxiliary agents are appropriately used alone or in combination depending on the purpose, taking into consideration the dosage form of the preparation, the application scene and the like.

Dusts usually contain, for example, 1 compound of the active ingredient.
To 25 parts by weight, the balance being a solid carrier.

The wettable powder usually contains, for example, 25 to 90 parts by weight of the active ingredient compound, and the rest is a solid carrier and a dispersion wetting agent, and if necessary, a protective colloid agent, a thixotropic agent, an antifoaming agent and the like. Added.

Granules, for example, usually contain 1 active ingredient compound.
To 35 parts by weight, the balance mostly solid carrier. The active ingredient compound is either uniformly mixed with the solid carrier, or is uniformly fixed or adsorbed on the surface of the solid carrier, and the particle diameter is about 0.2 to 1.5 mm.
Emulsions, for example, usually contain 5 to 3 active ingredient compounds.
It contains 0 part by weight, contains about 5 to 20 parts by weight of an emulsifier, the rest is a liquid carrier, and a rust preventive agent is added if necessary.

[0025]

INDUSTRIAL APPLICABILITY The herbicidal combination composition of the present invention has a broader herbicidal range beyond the range of application obtained with each single agent, and the herbicidal range is perennial such as Nobie, general weeds and firefly. Spans weeds. Furthermore, the safety of paddy rice is enhanced, and it has a phytotoxicity-reducing effect.

[0026]

[Examples] Formulation examples of the present herbicide composition are shown below as Examples.

[0027]

Example 1 (Granule) 1.5 parts of compound A, 2.0 parts of compound F, 72.3 parts of calcium carbonate powder (manufactured by Adachi Lime Co., Ltd.), bentonite powder (manufactured by Hoshun Mining Co., Ltd. Hotaka seal) 20 copies, Amicole N
o. 1 (Nippon Kagaku Kogyo Co., Ltd. dextrin) 1.5
Parts, mixed with Eck Sample Mill (Fuji Paudal Co., Ltd.)
It was crushed twice under the conditions of a screen diameter of 1 mm and a supply rate of 6 kg / hr. Crushed product 95.
Toxanone GR3 was prepared by charging 8 parts into a Nauta mixer (conical mixer manufactured by Hosokawa Micron Co., Ltd.) and mixing.
1A (manufactured by Sanyo Kasei Co., Ltd., dispersant, active ingredient 40%
Solution), Neocol SWCE (wetting agent manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) 0.20 part, and water 12.5 parts were mixed and kneaded. Kneaded mixture with Ek Peretta-EX-
Type 1 (extrusion granulator manufactured by Fuji Paudal Co., Ltd.)
It was extruded and granulated through a screen having an opening diameter of 0.8 mm.
After drying at 60 ° C. using a blower shelf dryer, sieving was performed using a sieve with opening diameters of 1.000 mm and 0.500 mm,
A granule containing 1.5% of compound A and 2.0% of compound F was obtained.

[0028]

[Test example]

[0029]

[Test Example 1] Water was poured into a 1 / 5000a Wagner pot filled with 3 kg of paddy soil each to form a paddy field, and seeds of broad-leaved weeds such as Taenia japonicus, firefly, konjac, azena, and yellow cypress were sown in this pot. I planted tubers. Furthermore, rice seedlings at the 2.5 leaf stage were transplanted, the pots were placed in a greenhouse at 20 to 25 ° C. to grow the plants, and on the 9th day after sowing, the millet was wetted with a prescribed amount of the drug at the 1.5 leaf stage. Was prepared in the following manner, diluted with water and treated with 10 cc per pot. After that, it was grown in a greenhouse and the herbicidal effect was investigated 25 days after the chemical treatment. The planting depth of paddy rice is 0 cm. In addition, the herbicidal effect was represented by the numbers 0 to 10 as follows depending on the weed control rate. The results are shown in Table 1.

Suppression rate 0: 0 to 9% 1: 10 to 19% 2: 20 to 29% 3: 30 to 39% 4: 40 to 49% 5: 50 to 59% 6: 60 to 69% 7: 70-79% 8: 80-89% 9: 90-99% 10: 100% (complete death) In Table 1, EO is Taenia muscaria, BL is broad-leaved weeds, SJ is firefly, and CS is cyperus japonicus. Show.

[0031]

[Table 1]

[Procedure amendment]

[Submission date] April 11, 1994

[Procedure Amendment 1]

[Document name to be amended] Statement

[Name of item to be amended] Claims

[Correction method] Change

[Correction content]

[Claims]

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Toyokuni Honma 1041 Yasu, Yasu-cho, Yasu-gun, Shiga Sankyo Stock Company In-house

Claims (1)

[Claims] 1. 3- (2-Fluoro-4-chloro-5-cyclopentyloxyphenyl) -5-isopropylidene-1,3-oxazoline-2,4-dione, 3-chloro-2- (4-chloro) -2-Fluoro-5-propargyloxyphenyl) -4,5,6,7-tetrahydro-2
H-indazole, 2- [4-chloro-2-fluoro-
5- (1-methyl-2-propynyloxy) phenyl]
-4,5,6,7-tetrahydroisoindole-1,
3-dione, 2- (7-fluoro-4-propargyl-
2H-1,4-benzoxazin-3 (4H) -one-
6-yl) -4,5,6,7-tetrahydroisoindole-1,3-dione and 2- (4-chloro-2-fluoro-5-carboxymethoxyphenyl) -4,5,
One or more compounds selected from 6,7-tetrahydroisoindole-1,3-dione and 1- (α, α-dimethylbenzyl) -3-p-tolylurea. A herbicidal composition for paddy fields.