JPH0620885A - Chip-type solid-state electrolytic capacitor - Google Patents
Chip-type solid-state electrolytic capacitorInfo
- Publication number
- JPH0620885A JPH0620885A JP17240492A JP17240492A JPH0620885A JP H0620885 A JPH0620885 A JP H0620885A JP 17240492 A JP17240492 A JP 17240492A JP 17240492 A JP17240492 A JP 17240492A JP H0620885 A JPH0620885 A JP H0620885A
- Authority
- JP
- Japan
- Prior art keywords
- anode
- anode lead
- chip
- lead wire
- electrolytic capacitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明はチップ状固体電解コンデ
ンサに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a chip solid electrolytic capacitor.
【0002】[0002]
【従来の技術】従来のチップ状固体電解コンデンサは図
3および図4に示すような構成となっていた。すなわ
ち、陽極導出線1を具備し、かつ弁作用金属であるタン
タル金属からなる多孔質の陽極体の表面に陽極酸化によ
る誘電体性酸化被膜を形成し、この表面に二酸化マンガ
ンなどの電解質層を形成し、さらにカーボン層および陰
極層2を順次積層形成することによりコンデンサ素子3
を構成し、そしてこのコンデンサ素子3を、前記陽極導
出線1および陰極層2が両端に突出するように外装樹脂
4で被覆し、その後、外装樹脂4より突出した前記陽極
導出線1の表面と陰極層2の露出部2aおよび外装樹脂
層4の陽極導出面5に陽極金属層6および陰極金属層7
を形成し、その後、半田メッキあるいは溶融半田浴中等
に浸漬して陽極側半田金属層8および陰極側半田金属層
9を形成していた。2. Description of the Related Art A conventional chip-shaped solid electrolytic capacitor has a structure as shown in FIGS. That is, a dielectric oxide film formed by anodic oxidation is formed on the surface of a porous anode body that is equipped with the anode lead-out wire 1 and is made of tantalum metal that is a valve metal, and an electrolyte layer such as manganese dioxide is formed on this surface. And then the carbon layer and the cathode layer 2 are sequentially laminated to form the capacitor element 3
And the capacitor element 3 is covered with the exterior resin 4 so that the anode lead wire 1 and the cathode layer 2 protrude at both ends, and then the surface of the anode lead wire 1 protruding from the exterior resin 4 An anode metal layer 6 and a cathode metal layer 7 are formed on the exposed portion 2a of the cathode layer 2 and the anode lead-out surface 5 of the exterior resin layer 4.
After that, the anode side solder metal layer 8 and the cathode side solder metal layer 9 were formed by immersing in a solder plating or a molten solder bath.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、このよ
うに構成されたチップ状固体電解コンデンサでは、陽極
導出線1が外装樹脂4の端面より外方に突出しているた
め、キャリアテープに設けた凹状の収納部内に収納され
ているチップ状固体電解コンデンサを自動実装装置によ
って取り出した後、例えばプリント基板に取り付ける場
合、前記陽極導出線1が凹状の収納部の内側面に引っ掛
かってチップ状固体電解コンデンサを凹状の収納部から
スムーズに取り出せないという問題点があった。また、
陽極側半田金属層8と陰極側半田金属層9からなる外部
電極端子における左右の表面積が違うため、例えば、ク
リーム状半田を用いたリフロー法による実装時において
プリント基板上でチップ立ち不良が発生するという問題
点があった。However, in the chip-shaped solid electrolytic capacitor configured as described above, since the anode lead wire 1 projects outward from the end surface of the exterior resin 4, a concave shape provided on the carrier tape is used. When the chip-shaped solid electrolytic capacitor housed in the housing is taken out by an automatic mounting device and then mounted on, for example, a printed circuit board, the anode lead-out wire 1 is caught on the inner surface of the recessed housing to mount the chip-shaped solid electrolytic capacitor. There was a problem that it could not be taken out smoothly from the concave storage part. Also,
Since the left and right surface areas of the external electrode terminals composed of the anode-side solder metal layer 8 and the cathode-side solder metal layer 9 are different, for example, a chip standing defect occurs on the printed circuit board when mounting by a reflow method using cream solder. There was a problem.
【0004】本発明は上記した従来の問題点を解決する
もので、寸法精度の良い外部電極端子を形成することが
でき、かつ自動実装装置による実装と半田付けを確実に
行うことができるチップ状固体電解コンデンサを提供す
ることを目的とするものである。The present invention solves the above-mentioned problems of the prior art, and is capable of forming external electrode terminals with high dimensional accuracy, and can be surely mounted and soldered by an automatic mounting device. An object of the present invention is to provide a solid electrolytic capacitor.
【0005】[0005]
【課題を解決するための手段】上記目的を達成するため
に本発明のチップ状固体電解コンデンサは、陽極導出線
を具備した弁作用金属からなる陽極体の表面に誘電体性
酸化被膜、電解質層、陰極層を形成して構成したコンデ
ンサ素子と、このコンデンサ素子を前記陽極導出線が片
側に引き出されるように被覆する外装樹脂とを備え、前
記外装樹脂の陽極導出線側に陽極導出線を折り曲げて収
納する凹部を設け、かつこの凹部内の一部もしくは全部
に、前記陽極導出線と電気的に接続される導電ペイント
を埋め込んで、前記凹部と前記陽極導出線が機械的に保
持されるようにした陽極端子部を設け、この陽極端子部
とは反体側にコンデンサ素子の陰極層と電気的に接続さ
れる陰極端子部を設け、さらに前記陽極端子部と陰極端
子部をほぼ同一の表面積となるようにフラットに構成し
たものである。In order to achieve the above object, a chip solid electrolytic capacitor of the present invention comprises a dielectric oxide film and an electrolyte layer on the surface of an anode body made of a valve metal having an anode lead wire. A capacitor element formed by forming a cathode layer, and an exterior resin covering the capacitor element so that the anode lead wire is drawn out to one side, and the anode lead wire is bent on the anode lead wire side of the exterior resin. A concave portion for accommodating the anode lead-out wire is provided, and a conductive paint electrically connected to the anode lead-out wire is embedded in a part or the whole of the recessed portion so that the recess and the anode lead-out wire are mechanically held. And a cathode terminal portion electrically connected to the cathode layer of the capacitor element on the side opposite to the anode terminal portion, and the anode terminal portion and the cathode terminal portion are substantially the same. So that the area is obtained by constituting the flat.
【0006】[0006]
【作用】上記構成によれば、外装樹脂の陽極導出線側に
設けた凹部内に陽極導出線を折り曲げて収納するように
しているため、陽極導出線が外装樹脂の端面より外方に
突出することはなくなり、また凹部内の一部もしくは全
部に、陽極導出線と電気的に接続される導電ペイントを
埋め込んで、前記凹部と前記陽極導出線が機械的に保持
されるようにした陽極端子部を設けているため、機械的
な外部からのストレスにも強く、その結果、例えば自動
実装装置による機械的な外部ストレスに対しても本発明
のチップ状固体電解コンデンサは、その接続が断たれて
容量不足になるという問題は出ないものとなる。また、
陽極端子部と陰極端子部をほぼ同一の表面積となるよう
にフラットに構成しているため、外部電極端子における
左右のバラツキの影響を受けることはなくなり、その結
果、自動実装装置によるチップ状固体電解コンデンサの
実装も確実に行うことができるとともに、クリーム状半
田を用いたリフロー法による実装時においてプリント回
路基板上で発生していたチップ立ち不良も大幅に軽減さ
れるものである。According to the above construction, since the anode lead wire is bent and accommodated in the recess provided on the anode lead wire side of the exterior resin, the anode lead wire projects outward from the end face of the exterior resin. In addition, a conductive paint electrically connected to the anode lead wire is embedded in a part or all of the recess so that the recess and the anode lead wire are mechanically held. Since it is provided, the chip-shaped solid electrolytic capacitor of the present invention is resistant to mechanical external stress, and as a result, the chip-shaped solid electrolytic capacitor of the present invention is not disconnected even when mechanical external stress is applied by an automatic mounting apparatus. There will be no problem of running out of capacity. Also,
Since the anode and cathode terminals are made flat so that they have almost the same surface area, they are not affected by the left-right variations in the external electrode terminals, and as a result, the chip-type solid electrolytic by the automatic mounting device is eliminated. The capacitor can be mounted surely, and the chip standing defect that has occurred on the printed circuit board at the time of mounting by the reflow method using the creamy solder is significantly reduced.
【0007】[0007]
【実施例】以下、本発明の一実施例について図面を参照
しながら説明する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings.
【0008】図1は本発明の一実施例におけるチップ状
固体電解コンデンサの断面図を示し、また図2は図1の
チップ状固体電解コンデンサの斜視図を示したものであ
る。この図1,図2において、11はコンデンサ素子
で、このコンデンサ素子11は陽極導出線12を具備す
るタンタルよりなる多孔質の陽極体の表面に一般的な陽
極酸化法により誘電体性酸化被膜を形成し、さらに、こ
の上に電解質層、カーボン層と銀塗料層よりなる陰極層
13を順次形成することにより構成している。FIG. 1 is a sectional view of a chip solid electrolytic capacitor according to an embodiment of the present invention, and FIG. 2 is a perspective view of the chip solid electrolytic capacitor of FIG. In FIGS. 1 and 2, reference numeral 11 denotes a capacitor element. The capacitor element 11 has a porous anode body made of tantalum having an anode lead wire 12 and a dielectric oxide film formed on the surface thereof by a general anodic oxidation method. It is formed by further forming a cathode layer 13 composed of an electrolyte layer, a carbon layer and a silver coating layer on top of this.
【0009】そして、このコンデンサ素子11の周囲に
設けた陰極層13のうち、陽極導出線12の引き出し面
と対向する面には導電材料よりなる陰極導電体層14を
分厚く形成し、続いてコンデンサ素子11の陽極導出線
12が引き出される面には陽極導出線12を折り曲げ収
納する凹部15を設け、そして前記コンデンサ素子11
および陰極導電体層14と前記陽極導出線12が片側に
引き出されるように外装樹脂16で被覆し、その後、外
装樹脂16の陽極導出線12とは反体側をカットまたは
研削することにより前記陰極導電体層14の露出面14
aをフラットに構成する。Then, of the cathode layer 13 provided around the capacitor element 11, a cathode conductor layer 14 made of a conductive material is formed thickly on the surface facing the lead-out surface of the anode lead wire 12, and then the capacitor is formed. A concave portion 15 for folding and housing the anode lead wire 12 is provided on a surface of the element 11 from which the anode lead wire 12 is drawn out, and the capacitor element 11 is provided.
Also, the cathode conductor layer 14 and the anode lead wire 12 are covered with the exterior resin 16 so as to be drawn out to one side, and thereafter, the side opposite to the anode lead wire 12 of the exterior resin 16 is cut or ground to form the cathode conductive material. Exposed surface 14 of body layer 14
a is made flat.
【0010】次に、凹部15内に折り曲げ収納した陽極
導出線12と外装樹脂16の陽極導出面17を機械的お
よび電気的に接続するために外装樹脂16の陽極導出線
12側の凹部15内の一部もしくは全部に導電ペイント
19を埋め込み、かつ陽極導出線12を含む外装樹脂1
6の陽極導出面17上にも導電ペイント19を塗布し、
凹部15と陽極導出線12が機械的に保持されるように
塗布形成する。なお、このときに使用する導電ペイント
19としては、導電ペイント中に含まれる導電粉に無電
解メッキの金属が析出するものが好ましい。次に、無電
解メッキ法で金属層を形成する表面を、ウェットブラス
ト法等により機械的に粗面化し、その後、フッ酸、フッ
化珪素酸、ホウフッ酸、フッ化アンモニウム等のフッ化
物を含んでいる溶液により化学的エッチングを行う。次
いで、無電解メッキ法をするためのパラジウムを付与
し、その後、無電解メッキ法によって、1〜5μ程度の
ニッケル層で陽極下地層21と陰極下地層22を形成
し、次いで陽極下地層21と陰極下地層22の表面に電
解メッキ法により、2〜8μ程度の半田層で陽極端子部
23と陰極端子部24を電着形成して、チップ状固体電
解コンデンサを作製した。Next, in order to mechanically and electrically connect the anode lead-out wire 12 folded and housed in the recess 15 and the anode lead-out surface 17 of the exterior resin 16, the interior of the recess 15 of the exterior resin 16 on the side of the anode lead-out 12 is formed. The exterior resin 1 in which a conductive paint 19 is embedded in a part or all of the above and the anode lead wire 12 is included.
Apply the conductive paint 19 also on the anode lead-out surface 17 of 6,
The coating is formed so that the recess 15 and the anode lead wire 12 are mechanically held. The conductive paint 19 used at this time is preferably one in which electroless plating metal is deposited on the conductive powder contained in the conductive paint. Next, the surface on which the metal layer is formed by the electroless plating method is mechanically roughened by a wet blast method or the like, and then a fluoride such as hydrofluoric acid, silicofluoric acid, borofluoric acid, or ammonium fluoride is included. Chemical etching is performed with the resulting solution. Next, palladium for electroless plating is applied, and thereafter, the anode underlayer 21 and the cathode underlayer 22 are formed by a nickel layer of about 1 to 5 μm by the electroless plating, and then the anode underlayer 21 is formed. An anode terminal portion 23 and a cathode terminal portion 24 were electrodeposited on the surface of the cathode underlayer 22 with an electroplating method using a solder layer having a thickness of about 2 to 8 μm to produce a chip solid electrolytic capacitor.
【0011】上記した本発明の一実施例においては、外
装樹脂16に設けた凹部15内に陽極導出線12を折り
曲げて収納しているため、陽極導出線12が外装樹脂1
6の端面より外方に突出するということはなくなり、ま
た陰極導電体層14を露出させるために外装樹脂16の
陰極導出面18をカットまたは研削してフラットに構成
しているため、コンデンサ素子11の寸法バラツキの影
響を受けることなく、寸法精度の良い外形にすることが
できる。さらに、陽極導出線12と電気的に接続される
導電ペイント19を凹部15内の一部もしくは全部に埋
め込んでいるため、陽極導出線12側の端面も従来品に
比べフラットとなり、その結果、陽極端子部23と陰極
端子部24における左右の外部電極端子としての表面積
はほぼ同一となるものである。In the above-described embodiment of the present invention, the anode lead-out wire 12 is bent and accommodated in the recess 15 provided in the outer-wrapping resin 16.
6 does not project outward from the end face of the capacitor 6, and the cathode lead-out surface 18 of the exterior resin 16 is cut or ground to expose the cathode conductor layer 14 to form a flat structure. It is possible to obtain an outer shape with high dimensional accuracy without being affected by the dimensional variation of the. Further, since the conductive paint 19 electrically connected to the anode lead-out wire 12 is embedded in a part or the whole of the recess 15, the end face on the side of the anode lead-out wire 12 is flat as compared with the conventional product, and as a result, the anode The surface areas of the terminal portion 23 and the cathode terminal portion 24 as the left and right external electrode terminals are substantially the same.
【0012】これらのことから、キャリアテープに設け
た凹状の収納部内に収納されている本発明のチップ状固
体電解コンデンサを自動実装装置によって取り出し、プ
リント基板に取り付ける場合においても、従来のように
チップ状固体電解コンデンサがキャリアテープに設けた
凹状の収納部内の内側面に引っかかるということはなく
なる。また、クリーム状半田を用いたリフロー法による
実装時には、従来に比べ次のような特長を有するもので
ある。まず、クリーム状半田をスクリーン印刷等を用い
てプリント回路基板上に印刷し、この印刷されたクリー
ム状半田上にチップ状固体電解コンデンサを搭載する
と、クリーム状半田の粘着力でチップ状固体電解コンデ
ンサは保持され、そしてこのプリント回路基板をリフロ
ー炉に流すとクリーム状半田は溶融する。この場合、チ
ップ状固体電解コンデンサにおける左右の外部電極端
子、つまり陽極端子部23と陰極端子部24の表面積が
ほぼ同一となっているため、同時に半田が濡れるととも
に陽極側の半田と陰極側の半田により、互いの溶融半田
で同時に引っ張られる。From these things, even when the chip-shaped solid electrolytic capacitor of the present invention housed in the recessed housing portion provided in the carrier tape is taken out by the automatic mounting apparatus and mounted on the printed circuit board, the chip can be mounted as in the conventional case. The solid electrolytic capacitor does not get caught on the inner side surface inside the concave accommodating portion provided on the carrier tape. Further, when mounting by a reflow method using creamy solder, it has the following features as compared with the conventional one. First, the cream solder is printed on the printed circuit board using screen printing, etc., and the chip solid electrolytic capacitor is mounted on the printed cream solder, and the chip solid electrolytic capacitor is attached by the adhesive force of the cream solder. Are retained, and the cream solder melts when the printed circuit board is run through a reflow oven. In this case, since the surface areas of the left and right external electrode terminals in the chip-shaped solid electrolytic capacitor, that is, the anode terminal portion 23 and the cathode terminal portion 24 are substantially the same, the solder gets wet at the same time and the anode side solder and the cathode side solder Thus, they are simultaneously pulled by the molten solder.
【0013】このとき、左右の外部電極端子における表
面積がアンバランスであればチップ立ち不良が多発する
が本発明の一実施例におけるチップ状固体電解コンデン
サは、左右の外部電極端子、つまり陽極端子部23と陰
極端子部24の表面積がほぼ同一となっているため、半
田溶融時に左右均等に引っ張られても、プリント回路基
板上に保持されて確実な半田付けができるものである。
このことにより、クリーム状半田を用いたリフロー法に
よりプリント回路基板に実装してもチップ立ち不良は大
幅に軽減されることになり、その結果、半田付け時の実
装も確実に行うことができる。At this time, if the surface areas of the left and right external electrode terminals are unbalanced, chip standing defects frequently occur. However, the chip-shaped solid electrolytic capacitor in one embodiment of the present invention uses the left and right external electrode terminals, that is, the anode terminal portion. Since the surface areas of the cathode 23 and the cathode terminal portion 24 are substantially the same, even when the solder is melted and pulled right and left evenly, the solder is held on the printed circuit board for reliable soldering.
As a result, even if the chip soldering is mounted on the printed circuit board by the reflow method using the creamy solder, the chip standing defect is significantly reduced, and as a result, the mounting at the time of soldering can be surely performed.
【0014】[0014]
【発明の効果】以上のように本発明のチップ状固体電解
コンデンサは、外装樹脂の陽極導出線側に設けた凹部内
に陽極導出線を折り曲げて収納するようにしているた
め、陽極導出線が外装樹脂の端面より外方に突出するこ
とはなくなり、また凹部内の一部もしくは全部に、陽極
導出線と電気的に接続される導電ペイントを埋め込ん
で、前記凹部と前記陽極導出線が機械的に保持されるよ
うにした陽極端子部を設けているため、機械的な外部か
らのストレスにも強く、その結果、例えば自動実装装置
による機械的な外部ストレスに対しても本発明のチップ
状固体電解コンデンサは、その接続が断たれて容量不足
になるという問題は出ないものである。As described above, in the chip solid electrolytic capacitor of the present invention, since the anode lead-out wire is bent and accommodated in the concave portion provided on the side of the anode lead-out wire of the exterior resin, the anode lead-out wire is It does not project outward from the end face of the exterior resin, and a conductive paint electrically connected to the anode lead wire is embedded in a part or all of the recess to make the recess and the anode lead wire mechanical. Since it is provided with an anode terminal portion adapted to be retained in the chip-shaped solid state of the present invention against mechanical stress from the outside, as a result, for example, against mechanical external stress due to an automatic mounting apparatus. The electrolytic capacitor does not have the problem that its connection is broken and the capacity becomes insufficient.
【0015】また陽極端子部と陰極端子部をほぼ同一の
表面積となるようにフラットに構成しているため、外部
電極端子における左右のバラツキの影響を受けることは
なくなり、その結果、自動実装装置によるチップ状固体
電解コンデンサの実装も確実に行うことができるととも
に、クリーム状半田を用いたリフロー法による実装時に
おいてプリント回路基板上で発生していたチップ立ち不
良も大幅に軽減されるものである。Further, since the anode terminal portion and the cathode terminal portion are flat so as to have substantially the same surface area, they are not affected by the left and right variations in the external electrode terminals, and as a result, the automatic mounting apparatus The chip-shaped solid electrolytic capacitor can be mounted reliably, and the chip standing failure that has occurred on the printed circuit board during mounting by the reflow method using cream-like solder is greatly reduced.
【図面の簡単な説明】[Brief description of drawings]
【図1】本発明の一実施例におけるチップ状固体電解コ
ンデンサの断面図FIG. 1 is a sectional view of a chip solid electrolytic capacitor according to an embodiment of the present invention.
【図2】同チップ状固体電解コンデンサの斜視図FIG. 2 is a perspective view of the chip solid electrolytic capacitor.
【図3】従来のチップ状固体電解コンデンサの断面図FIG. 3 is a cross-sectional view of a conventional chip solid electrolytic capacitor.
【図4】同チップ状固体電解コンデンサの斜視図FIG. 4 is a perspective view of the chip solid electrolytic capacitor.
11 コンデンサ素子 12 陽極導出線 13 陰極層 15 凹部 16 外装樹脂 19 導電ペイント 23 陽極端子部 24 陰極端子部 DESCRIPTION OF SYMBOLS 11 Capacitor element 12 Anode lead wire 13 Cathode layer 15 Recessed portion 16 Exterior resin 19 Conductive paint 23 Anode terminal portion 24 Cathode terminal portion
───────────────────────────────────────────────────── フロントページの続き (72)発明者 上岡 浩二 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Koji Ueoka 1006 Kadoma, Kadoma City, Osaka Prefecture Matsushita Electric Industrial Co., Ltd.
Claims (1)
陽極体の表面に誘電体性酸化被膜、電解質層、陰極層を
形成して構成したコンデンサ素子と、このコンデンサ素
子を前記陽極導出線が片側に引き出されるように被覆す
る外装樹脂とを備え、前記外装樹脂の陽極導出線側に陽
極導出線を折り曲げて収納する凹部を設け、かつこの凹
部内の一部もしくは全部に前記陽極導出線と電気的に接
続される導電ペイントを埋め込んで前記凹部と前記陽極
導出線が機械的に保持されるようにした陽極端子部を設
け、この陽極端子部とは反体側にコンデンサ素子の陰極
層と電気的に接続される陰極端子部を設け、さらに前記
陽極端子部と陰極端子部をほぼ同一の表面積となるよう
にフラットに構成したチップ状固体電解コンデンサ。1. A capacitor element comprising a dielectric oxide film, an electrolyte layer, and a cathode layer formed on the surface of an anode body made of a valve metal having an anode lead wire, and the capacitor element having the anode lead wire. Is provided on one side with an exterior resin covering the anode resin, and a concave portion for accommodating the anode lead wire is provided on the anode lead wire side of the exterior resin, and the anode lead wire is partly or wholly inside the recess. An anode terminal portion is provided in which a conductive paint electrically connected to is embedded so that the recess and the anode lead wire are mechanically held, and the anode terminal portion is opposite to the cathode layer of the capacitor element. A chip-shaped solid electrolytic capacitor in which a cathode terminal portion to be electrically connected is provided, and the anode terminal portion and the cathode terminal portion are flat so as to have substantially the same surface area.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17240492A JPH0620885A (en) | 1992-06-30 | 1992-06-30 | Chip-type solid-state electrolytic capacitor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17240492A JPH0620885A (en) | 1992-06-30 | 1992-06-30 | Chip-type solid-state electrolytic capacitor |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0620885A true JPH0620885A (en) | 1994-01-28 |
Family
ID=15941326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17240492A Pending JPH0620885A (en) | 1992-06-30 | 1992-06-30 | Chip-type solid-state electrolytic capacitor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0620885A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0660746B2 (en) † | 1993-07-16 | 2005-04-27 | UOP Sinco S.r.l. | Process for the purification of inert gases |
JP2007173303A (en) * | 2005-12-19 | 2007-07-05 | Nichicon Corp | Chip type solid electrolytic capacitor |
JP2009272598A (en) * | 2008-05-06 | 2009-11-19 | Samsung Electro Mech Co Ltd | External electrode forming method of tantalum capacitor |
-
1992
- 1992-06-30 JP JP17240492A patent/JPH0620885A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0660746B2 (en) † | 1993-07-16 | 2005-04-27 | UOP Sinco S.r.l. | Process for the purification of inert gases |
JP2007173303A (en) * | 2005-12-19 | 2007-07-05 | Nichicon Corp | Chip type solid electrolytic capacitor |
JP2009272598A (en) * | 2008-05-06 | 2009-11-19 | Samsung Electro Mech Co Ltd | External electrode forming method of tantalum capacitor |
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