JPH06193490A - Control device for internal combustion engine - Google Patents

Control device for internal combustion engine

Info

Publication number
JPH06193490A
JPH06193490A JP34596692A JP34596692A JPH06193490A JP H06193490 A JPH06193490 A JP H06193490A JP 34596692 A JP34596692 A JP 34596692A JP 34596692 A JP34596692 A JP 34596692A JP H06193490 A JPH06193490 A JP H06193490A
Authority
JP
Japan
Prior art keywords
exhaust gas
catalyst
temperature
air
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP34596692A
Other languages
Japanese (ja)
Inventor
Osamu Kuroda
黒田  修
Hisao Yamashita
寿生 山下
Akio Honchi
章夫 本地
Noriko Watanabe
紀子 渡辺
Toshio Ogawa
敏雄 小川
Hiroshi Miyadera
博 宮寺
Takeshi Atago
武士 阿田子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP34596692A priority Critical patent/JPH06193490A/en
Publication of JPH06193490A publication Critical patent/JPH06193490A/en
Pending legal-status Critical Current

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  • Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)

Abstract

PURPOSE:To enhance the exhaust gas purifying function at the time of starting an internal combustion engine by detecting a temperature of catalyst for purifying exhaust gas, and by controlling fuel and air in an intake air system so as to make fuel excessive in comparison with that of a stoichiometric air-fuel ratio when the detected value is lower than a set value. CONSTITUTION:An internal combustion engine 1 comprises an air volume adjusting valve 8 and a fuel injection valve 9 which are incorporated in an intake air system 4. Meanwhile, a precatalyst 2 and a main catalyst 3 are arranged in an exhaust system 4. Further, a secondary air supply pipe 6 incorporating a fuel supply pump 5 is laid upstream of the main catalyst 3. Moreover, a temperature sensor 7 for detecting a temperature of exhaust gas is located downstream of the main catalyst 3. Further, a temperature detected by the sensor 7 is lower than a set value, the air volume adjusting valve 8 and the fuel injection valve 9 is controlled so as to make fuel excessive in comparison with that of a stoichiometric air-fuel ratio by means of a control device 10. Accordingly, the temperature of the main catalyst is raised rapidly up to its activation temperature during a start of the internal combustion engine 1, thereby it is possible to enhance the exhaust purifying function.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、内燃機関の制御装置に
係り、特にエンジンの始動当初に排出される排気ガス中
の有害成分を内燃機関排気系に設置された浄化触媒によ
り効果的に浄化できるようにした内燃機関制御装置に関
する。本発明は特に内燃機関の燃料供給量制御装置に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a control device for an internal combustion engine, and more particularly, it effectively purifies harmful components in exhaust gas discharged at the start of the engine by means of a purification catalyst installed in the exhaust system of the internal combustion engine. The present invention relates to a control device for an internal combustion engine. The present invention particularly relates to a fuel supply amount control device for an internal combustion engine.

【0002】[0002]

【従来の技術】内燃機関から排出される排気ガスには、
一酸化炭素(CO),炭化水素(HC)及び窒素酸化物
(NOx)などの有害成分が含まれている。これらの有
害成分は大気汚染物質として人体に悪影響を及ぼす他に
植物の発育を妨げる原因となる。そこで、内燃機関の排
気ガスに含まれるこれらの有害成分の量を低減するため
に、内燃機関の排気系に三元系触媒の如き排気ガス浄化
触媒を設けて、内燃機関の排気ガスを浄化する研究がさ
かんに行われている。
2. Description of the Related Art Exhaust gas discharged from an internal combustion engine is
It contains harmful components such as carbon monoxide (CO), hydrocarbons (HC) and nitrogen oxides (NOx). These harmful components not only adversely affect the human body as air pollutants but also hinder the growth of plants. Therefore, in order to reduce the amount of these harmful components contained in the exhaust gas of the internal combustion engine, an exhaust gas purifying catalyst such as a three-way catalyst is provided in the exhaust system of the internal combustion engine to purify the exhaust gas of the internal combustion engine. Research is being actively conducted.

【0003】内燃機関の排気系に排気ガス浄化触媒を設
置することにより、排気ガス中の有害成分の量を低減す
ることができるが、排気ガス浄化性能が発揮されるの
は、触媒が活性を示す温度に加熱昇温されてからであ
る。触媒が活性を示す温度に昇温するまでの間は排気ガ
スの浄化性能が極めて悪く、有害成分が殆んど浄化され
ないで大気中に放出されてしまう。
By installing an exhaust gas purifying catalyst in the exhaust system of an internal combustion engine, the amount of harmful components in the exhaust gas can be reduced, but the exhaust gas purifying performance is exhibited by the catalyst being active. This is after heating to the temperature shown. Until the temperature of the catalyst reaches the temperature at which it is active, the exhaust gas purification performance is extremely poor, and harmful components are almost not purified and are released into the atmosphere.

【0004】排気ガス浄化触媒が活性を示す温度は、触
媒の成分によって異なるが、特開昭54−16018 号公報に
も記載されているように通常250〜400℃である。
The temperature at which the exhaust gas purifying catalyst is active varies depending on the components of the catalyst, but is usually 250 to 400 ° C. as described in JP-A-54-16018.

【0005】一方、エンジンが始動してから排気ガスの
温度が前述の250〜400℃の温度に昇温するまでに
は、およそ2分或いはそれ以上かかる。一説には3〜5
分かかるという説もあり、特開昭54−79319 号公報に記
載されている。
On the other hand, it takes about 2 minutes or more until the temperature of the exhaust gas rises to the above-mentioned temperature of 250 to 400 ° C. after the engine is started. 3-5 in one theory
There is a theory that it takes time, and it is described in JP-A-54-79319.

【0006】従って、エンジン排気ガス中の有害成分を
エンジン排気系に浄化触媒を設けて浄化する内燃機関排
気浄化システムでは、エンジンが始動してから触媒が排
気ガスによって活性温度に高められるまでの数分の間に
排出される排気ガス中の有害成分を如何に効果的に浄化
するかが重要な課題になる。
Therefore, in an internal combustion engine exhaust gas purification system for purifying harmful components in engine exhaust gas by providing a purification catalyst in the engine exhaust system, the number of times from when the engine is started until the catalyst is heated to the activation temperature by the exhaust gas. An important issue is how to effectively remove harmful components in the exhaust gas discharged in a minute.

【0007】[0007]

【発明が解決しようとする課題】本発明の目的は、エン
ジン排気系に排気ガス浄化触媒を備えた内燃機関排気ガ
ス浄化システムにおいて、排気ガス浄化触媒の温度がエ
ンジン始動後直ちに触媒活性温度まで高められるように
した内燃機関制御装置を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide an internal combustion engine exhaust gas purification system having an exhaust gas purification catalyst in an engine exhaust system, in which the temperature of the exhaust gas purification catalyst is raised to a catalyst activation temperature immediately after the engine is started. It is an object of the present invention to provide an internal combustion engine control device configured to perform the above.

【0008】[0008]

【課題を解決するための手段】本発明は、吸気系に燃料
噴射弁と空気量調整弁が設置され排気系に排気ガス浄化
触媒が設置された内燃機関を対象とした制御装置であっ
て、前記排気系に設置された排気ガス浄化触媒の温度を
入力してその値が設定値よりも低いときに理論空燃比よ
りも燃料過剰となるように前記吸気系の燃料噴射弁と空
気量調整弁を制御する手段を備えたことを特徴とする。
The present invention is a control device for an internal combustion engine in which a fuel injection valve and an air amount adjusting valve are installed in an intake system and an exhaust gas purifying catalyst is installed in an exhaust system. The temperature of the exhaust gas purifying catalyst installed in the exhaust system is input, and when the value is lower than a set value, the fuel injection valve and the air amount adjusting valve of the intake system are set so that the fuel exceeds the stoichiometric air-fuel ratio. Is provided with a means for controlling.

【0009】ここで、排気ガス浄化触媒の温度の設定値
としては、該触媒が活性を示す温度を設定する。エンジ
ン排気系の排気ガス浄化触媒の温度が活性温度よりも低
いときに理論空燃比よりも燃料過剰となるように燃料供
給量を増加するか或いは空気量を低減することによっ
て、排気ガスの成分を変化させ触媒温度を速やかに上昇
させることができる。
As the set value of the temperature of the exhaust gas purifying catalyst, the temperature at which the catalyst is active is set. When the temperature of the exhaust gas purifying catalyst in the engine exhaust system is lower than the activation temperature, the amount of fuel is increased so that the fuel exceeds the stoichiometric air-fuel ratio, or the amount of air is reduced to reduce the components of the exhaust gas. The temperature of the catalyst can be rapidly increased by changing the temperature.

【0010】この点について詳述すると、エンジン排気
ガスの成分は空燃比によって変化し、エンジンを理論空
燃比よりも燃料過剰の状態で運転すると、一酸化炭素が
多く発生し、炭化水素も比較的多く発生するようにな
る。特に注目すべき点は、炭化水素の濃度をはるかに超
える数%から十数%の一酸化炭素が含まれるようになる
ことである。
Explaining this point in detail, the components of the engine exhaust gas change depending on the air-fuel ratio, and when the engine is operated with a fuel excess of the stoichiometric air-fuel ratio, a large amount of carbon monoxide is generated and hydrocarbons are also relatively generated. It will occur a lot. Of particular note is the fact that carbon monoxide is now included in the range of a few percent to a dozen percent, well above the concentration of hydrocarbons.

【0011】理論空燃比すなわちA/F(Aは空気重
量、Fは燃料重量)が14.7 でエンジンを運転したと
きには、窒素酸化物の量が最も多くなり、次いで炭化水
素の量が多く、一酸化炭素は1%にも満たない。
When the engine is operated at a stoichiometric air-fuel ratio, that is, A / F (A is air weight, F is fuel weight), the amount of nitrogen oxides is the highest, followed by the amount of hydrocarbons. Carbon monoxide is less than 1%.

【0012】一酸化炭素は炭化水素よりもかなり低い温
度で燃焼される。従って、エンジン吸気系に理論空燃比
よりも過剰の燃料を供給すれば、排気ガスの温度が低く
ても触媒燃焼させることができ、これによる発熱で触媒
の温度を高めることができる。
Carbon monoxide is burned at much lower temperatures than hydrocarbons. Therefore, if an excess amount of fuel is supplied to the engine intake system in excess of the stoichiometric air-fuel ratio, catalytic combustion can be carried out even if the temperature of the exhaust gas is low, and the temperature of the catalyst can be raised by the heat generated thereby.

【0013】また、理論空燃比よりも燃料過剰の状態で
エンジンを運転した場合には、炭化水素もかなり多量に
発生し、この炭化水素の単位重量当たりの発熱量は一酸
化炭素の発熱量の5倍程度と大きい。従って、エンジン
吸気系の空燃比を理論空燃比よりも燃料過剰となるよう
にした場合には、一酸化炭素の触媒燃焼に引き続いて炭
化水素の触媒燃焼が加わり、触媒の温度を急速に高める
ことができるようになる。
Further, when the engine is operated in a fuel excess of the stoichiometric air-fuel ratio, a considerably large amount of hydrocarbon is also generated, and the calorific value of this hydrocarbon per unit weight is the calorific value of carbon monoxide. It is as large as 5 times. Therefore, if the air-fuel ratio of the engine intake system is set to be in excess of the stoichiometric air-fuel ratio, the catalytic combustion of carbon monoxide is followed by the catalytic combustion of hydrocarbons to rapidly raise the temperature of the catalyst. Will be able to.

【0014】この結果、エンジン始動当初であっても触
媒温度を急速に高めて排気ガス中の有害成分を効果的に
除去することができる。
As a result, even if the engine is started, the catalyst temperature can be rapidly raised to effectively remove harmful components in the exhaust gas.

【0015】本発明の内燃機関制御装置は、排気系に設
置された排気ガス浄化触媒の温度を入力して設定値と比
較する手段と、前記排気ガス浄化触媒の温度が設定値よ
りも低いときに理論空燃比よりも燃料過剰となるように
信号を発生する手段及び該信号に基づいて前記吸気系の
燃料噴射弁と空気量調整弁を開閉駆動する制御手段とを
備えることができる。
The internal combustion engine control apparatus of the present invention comprises means for inputting the temperature of the exhaust gas purification catalyst installed in the exhaust system and comparing it with a set value, and when the temperature of the exhaust gas purification catalyst is lower than the set value. Further, there may be provided a means for generating a signal so that the fuel is in excess of the stoichiometric air-fuel ratio, and a control means for opening / closing the fuel injection valve and the air amount adjusting valve of the intake system based on the signal.

【0016】また、排気系に設置された排気ガス浄化触
媒の温度を入力する手段と、該排気ガス浄化触媒の温度
設定値を記憶する手段と、前記入力手段の触媒温度と前
記記憶手段の温度設定値とを比較する手段と、前記入力
手段の触媒温度が前記温度設定値よりも低いときに理論
空燃比よりも燃料過剰となるように信号を発生する手段
及び該信号に基づいて前記吸気系の燃料噴射弁と空気量
調整弁を開閉駆動する制御手段とを備えることができ
る。
Further, means for inputting the temperature of the exhaust gas purifying catalyst installed in the exhaust system, means for storing the temperature set value of the exhaust gas purifying catalyst, catalyst temperature of the input means and temperature of the storage means Means for comparing a set value, means for generating a signal so that the fuel temperature exceeds the stoichiometric air-fuel ratio when the catalyst temperature of the input means is lower than the temperature set value, and the intake system based on the signal The fuel injection valve and the control means for opening and closing the air amount adjusting valve can be provided.

【0017】ここで、排気ガス浄化触媒の温度が設定値
よりも低いときには空燃比A/F(Aは空気重量、Fは
燃料重量)が13以下,10以上となるように吸気系の
燃料噴射弁と空気量調整弁を開閉駆動することが望まし
い。
Here, when the temperature of the exhaust gas purifying catalyst is lower than the set value, the fuel injection of the intake system is made so that the air-fuel ratio A / F (A is air weight, F is fuel weight) becomes 13 or less and 10 or more. It is desirable to open and close the valve and the air amount adjusting valve.

【0018】また、排気系に設置された排気ガス浄化触
媒の温度が設定値よりも高いときには、理論空燃比或い
はその近傍となるように吸気系の燃料噴射弁と空気量調
整弁を開閉駆動することが望ましい。
Further, when the temperature of the exhaust gas purifying catalyst installed in the exhaust system is higher than the set value, the fuel injection valve and the air amount adjusting valve of the intake system are opened and closed so as to be at or near the stoichiometric air-fuel ratio. Is desirable.

【0019】これらの制御は、いずれもマイクロコンピ
ューターを用いて行うことができる。
Any of these controls can be performed using a microcomputer.

【0020】本発明は、吸気系に燃料噴射弁と空気量調
整弁を有し、排気系に燃焼触媒と三元系排気ガス浄化主
触媒とを有する内燃機関をも適用対象とする。この場
合、燃焼触媒は三元系主触媒よりも前段に設置しておく
ことが望ましく、理論空燃比よりも燃料過剰とすること
によって、燃焼触媒が有効に機能しその燃焼熱で排気ガ
ス浄化触媒を速やかに昇温することができる。
The present invention is also applicable to an internal combustion engine having a fuel injection valve and an air amount adjusting valve in an intake system and a combustion catalyst and a three-way exhaust gas purifying main catalyst in an exhaust system. In this case, it is desirable to install the combustion catalyst before the three-way main catalyst, and by making the fuel excess of the stoichiometric air-fuel ratio, the combustion catalyst effectively functions and its combustion heat causes the exhaust gas purification catalyst. Can be quickly heated.

【0021】本発明は、吸気系に燃料噴射弁と空気量調
整弁を有し、排気系に燃焼触媒と排気ガス浄化触媒を有
し該燃焼触媒の前段に空気供給手段を有する内燃機関を
対象とすることもできる。理論空燃比よりも燃料過剰で
エンジンを運転した場合には、排気ガス中の酸素濃度が
低いので、排気ガス中の一酸化炭素及び炭化水素を触媒
燃焼させるときに酸素不足になることがある。理論空燃
比よりも燃料過剰でエンジンを運転する際に、排気系に
空気を供給することによって酸素不足を解消することが
できる。このような空気量の制御も本発明の制御装置に
よって行うことができる。
The present invention is directed to an internal combustion engine having a fuel injection valve and an air amount adjusting valve in an intake system, a combustion catalyst and an exhaust gas purifying catalyst in an exhaust system, and an air supply means before the combustion catalyst. Can also be When the engine is operated with a fuel excess of the stoichiometric air-fuel ratio, the oxygen concentration in the exhaust gas is low, and thus oxygen deficiency may occur when catalytically burning carbon monoxide and hydrocarbons in the exhaust gas. Oxygen deficiency can be eliminated by supplying air to the exhaust system when operating the engine with an excess of fuel compared to the stoichiometric air-fuel ratio. Such control of the air amount can also be performed by the control device of the present invention.

【0022】[0022]

【作用】本発明の内燃機関排気ガス浄化システムは、エ
ンジンの吸気系に燃料噴射弁とスロットルバルブの如き
空気量調整弁を有し、排気系に燃焼触媒よりなる前触媒
と排気ガス浄化主触媒とを有し、前記排気ガス浄化主触
媒の温度を検出する手段と、前記エンジンを始動してか
ら該排気ガス浄化主触媒の検出温度が活性を示す温度に
なるまでの間理論空燃比よりも燃料過剰となるように前
記燃料噴射弁と空気量調整弁を開閉駆動する制御手段
(コントロールボックス)を備える。
The internal combustion engine exhaust gas purification system of the present invention has an air amount adjusting valve such as a fuel injection valve and a throttle valve in the intake system of the engine, and a pre-catalyst consisting of a combustion catalyst and an exhaust gas purification main catalyst in the exhaust system. And means for detecting the temperature of the exhaust gas purifying main catalyst, and from the stoichiometric air-fuel ratio during the period from when the engine is started until the detected temperature of the exhaust gas purifying main catalyst reaches a temperature at which it is active. A control means (control box) for driving the fuel injection valve and the air amount adjusting valve to open and close so as to cause excess fuel is provided.

【0023】エンジンを始動してから前記排気ガス浄化
主触媒の温度が活性を示す温度になるまでの間は理論空
燃比よりも燃料過剰とし、前記排気ガス浄化主触媒の温
度が活性を示す温度になったならば理論空燃比或いはそ
の近傍の空燃比となるように前記燃料噴射弁,空気量調
整弁を開閉駆動することが望ましい。
From the time when the engine is started until the temperature of the exhaust gas purifying main catalyst reaches a temperature at which it is active, the fuel is in excess of the stoichiometric air-fuel ratio, and the temperature of the exhaust gas purifying main catalyst is at a temperature at which it is active. If so, it is desirable to drive the fuel injection valve and the air amount adjusting valve to open and close so that the stoichiometric air-fuel ratio or an air-fuel ratio in the vicinity thereof is obtained.

【0024】燃料過剰状態での空燃比A/F(Aは空気
重量、Fは燃料重量)は既に述べたように13以下,1
0以上とすることが望ましく、特に、エンジン排ガスの
CO濃度が3%以上,14%以下となる条件で燃料を過
剰供給することが望ましい。本発明を実施するに当って
は、例えば自動車の床下に排気ガス浄化主触媒を設け、
エンジンになるべく近い位置に燃焼触媒よりなる前触媒
を設けることが望ましい。エンジン排気ガスの温度は排
気ガス流路を流れる過程で低下する。エンジンになるべ
く近い位置に前触媒を備えることにより排気ガス温度が
低下しないうちに触媒に導くことができる。また、前触
媒を燃焼触媒とすることにより、CO及びHCの酸化活
性を高めることができる。
As described above, the air-fuel ratio A / F (A is air weight, F is fuel weight) in the excessive fuel state is 13 or less, 1
It is desirable to set it to 0 or more, and it is particularly desirable to excessively supply the fuel under the condition that the CO concentration of the engine exhaust gas is 3% or more and 14% or less. In carrying out the present invention, for example, an exhaust gas purifying main catalyst is provided under the floor of an automobile,
It is desirable to provide a pre-catalyst consisting of a combustion catalyst as close to the engine as possible. The temperature of engine exhaust gas decreases as it flows through the exhaust gas flow path. By providing the precatalyst at a position as close as possible to the engine, it is possible to guide the exhaust gas to the catalyst before the temperature of the exhaust gas decreases. Further, by using the combustion catalyst as the pre-catalyst, the oxidizing activity of CO and HC can be increased.

【0025】前触媒の上流側排気ガス流路には酸化剤例
えば空気を添加する手段を設けることが望ましい。
It is desirable to provide a means for adding an oxidizer such as air in the exhaust gas flow passage on the upstream side of the front catalyst.

【0026】燃料過剰条件で燃焼し生成した排気ガス中
の酸素は一般に低濃度である。そこで、前触媒の前段に
空気等の酸素含有ガスを添加することにより前触媒にお
けるCO,HCの燃焼を効果的に行わせる。
Oxygen in the exhaust gas produced by burning under the excessive fuel condition is generally low in concentration. Therefore, by adding an oxygen-containing gas such as air to the front stage of the front catalyst, CO and HC in the front catalyst are effectively burned.

【0027】空気(酸素)の添加量としては排気ガスの
理論酸素消費量と当量か当量よりやや過剰とすることが
望ましい。この場合、前触媒における燃焼と主触媒にお
ける排ガス浄化をともに良行に行うことができる。
The amount of air (oxygen) added is preferably equivalent to or slightly more than the theoretical oxygen consumption of exhaust gas. In this case, combustion in the front catalyst and exhaust gas purification in the main catalyst can both be performed satisfactorily.

【0028】前触媒には、COの酸化とHCの酸化に共
に活性を有する燃焼触媒を用いることが望ましい。具体
的には、触媒活性成分として、周期律表の第VIII族,Ib
族,希土類金属,亜鉛及び錫から選ばれた金属あるいは
酸化物の少なくとも1種をもちいることが望ましい。
As the pre-catalyst, it is desirable to use a combustion catalyst that is active in both CO oxidation and HC oxidation. Specifically, as a catalytically active component, Group VIII, Ib of the periodic table is used.
It is desirable to use at least one metal or oxide selected from the group consisting of rare earth metals, zinc and tin.

【0029】排気ガス浄化主触媒としては、COとHC
酸化とNOxの還元に共に活性を示す三元触媒を用いる
ことが望ましい。
Exhaust gas purifying main catalysts are CO and HC
It is desirable to use a three-way catalyst that is active in both oxidation and NOx reduction.

【0030】前触媒の支持体としてコージェライト,ム
ライト,アルミニウムチタネイト等のいわゆるセラミッ
クスハニカムを用い、これに前述の触媒活性成分を担持
するか、或いは支持体としてのセラミックスハニカムに
シリカ,アルミナ,チタニア等の多孔質担体を添着し、
さらに前述の触媒活性成分を担持することが望ましい。
A so-called ceramic honeycomb of cordierite, mullite, aluminum titanate or the like is used as a support for the precatalyst, and the above-mentioned catalytically active component is supported on this, or silica, alumina, titania is added to the ceramic honeycomb as a support. A porous carrier such as
Further, it is desirable to carry the above-mentioned catalytically active component.

【0031】本発明の排気ガス浄化システムにおいて
は、前触媒の触媒燃焼により発生した熱を有効に利用し
て前触媒自身を急速に加熱し活性化することが肝要であ
る。これは触媒担体や支持体の熱伝達率を小さくして触
媒と担体あるいは支持体との間の温度勾配を大きくする
ことにより達成できる。上記したセラミックスの熱伝達
率は小さく触媒の温度を急速に上昇させるのに有効に機
能する。
In the exhaust gas purification system of the present invention, it is essential that the heat generated by the catalytic combustion of the precatalyst be effectively used to rapidly heat and activate the precatalyst itself. This can be achieved by reducing the heat transfer coefficient of the catalyst carrier or support and increasing the temperature gradient between the catalyst and the carrier or support. The ceramics described above have a small heat transfer coefficient and effectively function to rapidly raise the temperature of the catalyst.

【0032】前触媒の支持体としては、ステンレス等の
導電性の金属あるいは合金のハニカムを用いることがで
きる。
As a support for the precatalyst, a honeycomb of a conductive metal or alloy such as stainless steel can be used.

【0033】触媒を急速に加熱することは触媒担体ある
いは支持体の比熱を小さくすることによってもまた達成
できる。ステンレス等の金属からなるハニカムを触媒の
支持体として使用することにより材料そのものの比熱が
小さくなるのに加え材料の薄板化が可能となり、その結
果、熱容量を小さくでき、より急速な昇温が可能とな
る。
Rapid heating of the catalyst can also be achieved by reducing the specific heat of the catalyst support or support. By using a honeycomb made of metal such as stainless steel as a support for the catalyst, the specific heat of the material itself can be reduced and the material can be thinned, resulting in a smaller heat capacity and a faster temperature rise. Becomes

【0034】前触媒に通電し触媒を加熱することも望ま
しいことである。
It is also desirable to energize the precatalyst to heat it.

【0035】金属の触媒担体あるいは支持体に通電しジ
ュール熱により加熱することにより前触媒の昇温を早め
ることができる。また、前触媒の昇温開始時に通電して
COの着火を促進することにより昇温を早めることがで
きる。
The temperature of the precatalyst can be accelerated by heating the metal catalyst carrier or support with Joule heat. Further, the temperature can be increased by energizing the pre-catalyst at the start of temperature increase to accelerate the ignition of CO.

【0036】本発明によれば、理論空燃比の燃料と空気
を供給してエンジンを駆動し排気ガスを排気ガス浄化触
媒によって浄化するようにした内燃機関の運転方法にお
いて、前記エンジンの起動時から少なくとも前記排気ガ
ス浄化触媒が活性を示す温度に昇温するまでの間前記エ
ンジンを理論空燃比よりも燃料過剰の状態で駆動する運
転方法が実現する。
According to the present invention, in an operating method of an internal combustion engine, in which fuel and air having a stoichiometric air-fuel ratio are supplied to drive the engine and exhaust gas is purified by an exhaust gas purifying catalyst, from the time of starting the engine. An operating method is realized in which the engine is driven in a fuel excess of the stoichiometric air-fuel ratio at least until the temperature of the exhaust gas purifying catalyst rises to a temperature at which it activates.

【0037】また、理論空燃比よりも燃料過剰の状態で
エンジンを始動してその排気ガスを燃焼触媒よって接触
燃焼してから排気ガス浄化触媒に送り、該排気ガス浄化
触媒の温度が活性を示す温度まで昇温したならば燃料過
剰供給を停止しその排気ガスを燃焼触媒に通さずに直接
前記排気ガス浄化触媒に送るようにした内燃機関排気ガ
ス浄化システムが実現する。
Further, the engine is started in a state where the fuel is in excess of the stoichiometric air-fuel ratio, the exhaust gas is catalytically burned by the combustion catalyst and then sent to the exhaust gas purification catalyst, and the temperature of the exhaust gas purification catalyst shows activity. When the temperature rises to a temperature, an internal combustion engine exhaust gas purification system is realized in which excessive fuel supply is stopped and the exhaust gas is directly sent to the exhaust gas purification catalyst without passing through the combustion catalyst.

【0038】本発明に係る内燃自動車は、内燃機関エン
ジンの排気ガス流路に排気ガス浄化触媒を備え、前記エ
ンジンを始動してから排気ガスの温度が該排気ガス浄化
触媒の活性温度に昇温するまでの間前記エンジンに理論
空燃比よりも過剰の燃料を供給する手段を備え、該燃料
過剰状態でのエンジン駆動によって排出された排気ガス
を接触燃焼する燃焼触媒を前記排気ガス流路の前記排気
ガス浄化触媒の上流側に備える。
The internal combustion vehicle according to the present invention is provided with an exhaust gas purifying catalyst in the exhaust gas passage of the engine, and the temperature of the exhaust gas rises to the activation temperature of the exhaust gas purifying catalyst after the engine is started. A means for supplying fuel to the engine in excess of the stoichiometric air-fuel ratio, and a combustion catalyst for catalytically burning the exhaust gas discharged by driving the engine in the excessive fuel state is provided in the exhaust gas flow path. It is provided on the upstream side of the exhaust gas purification catalyst.

【0039】本発明は、ガソリン或いは軽油を燃料とし
て駆動される自動車に用いるのに好適である。本発明の
排気ガス浄化システムでは、エンジンから排気ガス浄化
主触媒に至る排気ガスの流路にバイパス流路を備え、該
バイパス流路に燃焼触媒よりなる前触媒を備えることが
できる。
The present invention is suitable for use in an automobile driven by gasoline or light oil. In the exhaust gas purifying system of the present invention, the exhaust gas flow passage from the engine to the exhaust gas purifying main catalyst can be provided with a bypass flow passage, and the bypass flow passage can be provided with a pre-catalyst made of a combustion catalyst.

【0040】前触媒は起動直後の短時間(大略2分程
度)機能すればあとは本質的には不要となる。不要とな
った後も、排ガスを流通することはいたずらに圧力損失
を増加させることになる。また、前触媒を長時間高温に
さらすことは触媒劣化の原因を持ち込むこととなる。エ
ンジンから主触媒に至る排ガスの流路にバイパスを設
け、バイパス内に前触媒を設け、エンジン起動直後で主
触媒が作動温度に達していない間のみ燃料過剰の燃焼を
行い、その排気ガスをバイパスの前触媒を経て主触媒に
導くことによりこれらの問題を排除することができる。
If the pre-catalyst functions for a short time (about 2 minutes) immediately after starting, it becomes essentially unnecessary thereafter. Even after it becomes unnecessary, circulating the exhaust gas unnecessarily increases the pressure loss. Further, exposing the pre-catalyst to a high temperature for a long time brings a cause of catalyst deterioration. A bypass is provided in the exhaust gas flow path from the engine to the main catalyst, and a pre-catalyst is provided in the bypass to burn excess fuel only while the main catalyst does not reach the operating temperature immediately after engine startup, and the exhaust gas is bypassed. These problems can be eliminated by introducing the precatalyst to the main catalyst.

【0041】また、エンジンと前触媒の間の排ガス流路
に除湿手段好ましくは冷却除湿器を備えることは望まし
いことである。前触媒の温度が排ガスの露点以下の場
合、該除湿手段で排ガスを除湿し、例えば前触媒温度と
同等かもしくはそれ以下に冷却除湿し、その後、前触媒
に供給することが望ましい。
It is also desirable to provide a dehumidifying means, preferably a cooling dehumidifier, in the exhaust gas passage between the engine and the front catalyst. When the temperature of the precatalyst is equal to or lower than the dew point of the exhaust gas, it is desirable to dehumidify the exhaust gas by the dehumidifying means, cool and dehumidify the temperature to, for example, equal to or lower than the precatalyst temperature, and then supply the precatalyst.

【0042】エンジン排気ガスには通常多量の水蒸気が
含まれる。水蒸気を含む排ガスが前触媒に供給され前触
媒温度が低い場合、正確には前触媒の温度が排ガスの露
点以下の場合には、排気ガス中の水分は触媒上もしくは
触媒細孔内に凝縮する。この現象は触媒の性能を低下さ
せるのみならず触媒劣化の原因となり、また圧力損失を
増加させることにもなる。更に、一度凝縮が起こるとこ
れを蒸発させるには蒸発潜熱が必要となるため100℃
以上に昇温するには多量の熱量が必要となり、したがっ
て時間を要することともなる。排気ガスを除湿し、例え
ば前触媒温度と同等かもしくはそれ以下に冷却除湿し、
その後に前触媒に供給することにより、前触媒部での水
蒸気の凝縮を防止でき、それに伴う障害を回避すること
ができる。エンジンから主触媒に至る排気ガスの流路に
バイパス流路を設けて燃焼触媒を設置した排気ガス浄化
システムにおいては、バイパス流路に排ガス除湿手段を
設け、前触媒の温度が燃焼排ガスの露点以下の場合にバ
イパスの除湿手段により排気ガスを除湿した後主触媒に
導き、前触媒の温度が排ガスの露点以上の場合に排気ガ
スを直接前触媒へ導くことが望ましい。
The engine exhaust gas usually contains a large amount of water vapor. When the exhaust gas containing water vapor is supplied to the pre-catalyst and the pre-catalyst temperature is low, to be precise, when the temperature of the pre-catalyst is below the dew point of the exhaust gas, the water in the exhaust gas condenses on the catalyst or in the catalyst pores. . This phenomenon not only deteriorates the performance of the catalyst, but also causes deterioration of the catalyst, and also increases pressure loss. Furthermore, once condensation occurs, latent heat of vaporization is required to evaporate it, so 100 ° C
A large amount of heat is required to raise the temperature above, and thus it may take time. Dehumidifying exhaust gas, for example by cooling to a temperature equal to or lower than the precatalyst temperature,
By supplying it to the pre-catalyst after that, it is possible to prevent the condensation of water vapor in the pre-catalyst part and to avoid the troubles associated therewith. In an exhaust gas purification system in which a bypass flow path is provided in the exhaust gas flow path from the engine to the main catalyst and a combustion catalyst is installed, an exhaust gas dehumidifying means is installed in the bypass flow path, and the temperature of the front catalyst is below the dew point of the combustion exhaust gas. In this case, it is preferable to dehumidify the exhaust gas by the dehumidifying means of the bypass and then guide the exhaust gas to the main catalyst, and directly guide the exhaust gas to the front catalyst when the temperature of the precatalyst is equal to or higher than the dew point of the exhaust gas.

【0043】前触媒温度が排気ガスの露点以上となれば
水凝縮の可能性は無くなる。この状態で排ガスを除湿す
ることは不要な操作である。そこで、エンジンから主触
媒に至る排気ガスの流路にバイパスを設け、バイパス内
に排ガス除湿手段を設け、前触媒の温度が排ガスの露点
以下のときバイパスの除湿手段により排気ガスを除湿し
た後主触媒に導き、前触媒の温度が排気ガスの露点以上
のとき排気ガスを直接前触媒へ導くことにより、不要な
除湿を行うこと無く前触媒における水の凝縮とそれに伴
う障害を取り除くことができる。
If the precatalyst temperature is equal to or higher than the dew point of exhaust gas, the possibility of water condensation disappears. Dehumidifying the exhaust gas in this state is an unnecessary operation. Therefore, a bypass is provided in the exhaust gas flow path from the engine to the main catalyst, an exhaust gas dehumidifying means is provided in the bypass, and the exhaust gas is dehumidified by the bypass dehumidifying means when the temperature of the front catalyst is below the dew point of the exhaust gas. By guiding the exhaust gas to the catalyst and directly to the front catalyst when the temperature of the precatalyst is equal to or higher than the dew point of the exhaust gas, it is possible to remove water condensation in the precatalyst and its accompanying obstacles without unnecessary dehumidification.

【0044】なお、エンジンに理論空燃比よりも過剰の
燃料を供給した例が、特開昭61−58912 号公報に示され
ている。しかし、エンジン始動当初の排気ガス対策につ
いては全く考慮していない。
An example in which an engine is supplied with fuel in excess of the stoichiometric air-fuel ratio is shown in JP-A-61-58912. However, no consideration is given to measures against exhaust gas when the engine is started.

【0045】[0045]

【実施例】以下、具体的実施例を挙げて本発明を詳細に
説明する。但し、本発明は以下の実施例に限定されるも
のではない。
EXAMPLES The present invention will be described in detail below with reference to specific examples. However, the present invention is not limited to the following examples.

【0046】図1は、本発明の一実施例による内燃機関
排気ガス浄化システムの概略図である。エンジン1の排
気ガス流路11に前触媒2と主触媒3が設けられてい
る。エンジン1の吸気管4に空気量調整弁(スロットル
バルブ)8と燃料噴射弁9が取り付けられている。空気
量調整弁8と燃料噴射弁9は制御装置(コントロールボ
ックス)10にて開閉度が制御されるようになってい
る。排気ガス流路11の前触媒2の前段には空気を供給
する二次空気供給管6が設けられ、該二次空気供給管6
には空気ポンプ5が設けられている。主触媒3の後段に
は温度センサー7が設けられ、排気ガスの温度を検出す
るようにしている。ここで検出された温度はコントロー
ルボックス10に入力され、コントロールボックス10
ではかかる温度を設定値と比較して燃料過剰操作を継続
するか停止するかを判断するようになっている。
FIG. 1 is a schematic diagram of an internal combustion engine exhaust gas purification system according to an embodiment of the present invention. A front catalyst 2 and a main catalyst 3 are provided in an exhaust gas passage 11 of the engine 1. An air amount adjusting valve (throttle valve) 8 and a fuel injection valve 9 are attached to an intake pipe 4 of the engine 1. The degree of opening / closing of the air amount adjusting valve 8 and the fuel injection valve 9 is controlled by a control device (control box) 10. A secondary air supply pipe 6 for supplying air is provided in the exhaust gas flow path 11 before the front catalyst 2, and the secondary air supply pipe 6 is provided.
An air pump 5 is provided in the. A temperature sensor 7 is provided after the main catalyst 3 to detect the temperature of the exhaust gas. The temperature detected here is input to the control box 10, and the control box 10
Then, such a temperature is compared with a set value to determine whether to continue or stop the excess fuel operation.

【0047】図1の実施例におけるコントロールボック
ス(制御装置)の具体的な構成を図5に示す。主触媒3
に設けられた温度検出センサー7からの信号は、入力回
路により次の触媒温度設定値との比較に適した形に交換
されたのち比較手段に送られ、予め記憶手段に記憶され
た触媒設定温度と比較される。主触媒3の温度が設定値
よりも低い場合には、信号発生手段で理論空燃比よりも
燃料リッチとなるように燃料噴射弁9及びスロットルバ
ルブ8を調節する信号およびエアポンプ5をonする信
号を発生する。この信号は出力回路においてそれぞれの
出力先に適した形に変換されて燃料噴射弁9,スロット
ルバルブ8及びエアポンプ5に伝えられる。
FIG. 5 shows a specific configuration of the control box (control device) in the embodiment shown in FIG. Main catalyst 3
The signal from the temperature detection sensor 7 provided in the unit is exchanged by the input circuit into a form suitable for comparison with the next catalyst temperature set value, and then sent to the comparison unit, and the catalyst set temperature stored in advance in the storage unit. Compared to. When the temperature of the main catalyst 3 is lower than the set value, a signal for adjusting the fuel injection valve 9 and the throttle valve 8 so that the signal generating means is richer in fuel than the theoretical air-fuel ratio, and a signal for turning on the air pump 5 are given. Occur. This signal is converted into a form suitable for each output destination in the output circuit and transmitted to the fuel injection valve 9, the throttle valve 8 and the air pump 5.

【0048】同様に主触媒の温度が設定値よりも高い場
合には、信号発生手段で理論空燃比或いはその近傍の空
燃比になるように燃料噴射弁9及びスロットルバルブ8
を調節する信号およびエアポンプをoffする信号を発
生し、この信号は出力回路においてそれぞれの出力先に
適した形に変換されて燃料噴射弁9,スロットルバルブ
8およびエアポンプに伝えられる。
Similarly, when the temperature of the main catalyst is higher than the set value, the fuel injection valve 9 and the throttle valve 8 are controlled by the signal generating means so that the stoichiometric air-fuel ratio or an air-fuel ratio near the stoichiometric air-fuel ratio is obtained.
Is generated and a signal for turning off the air pump is generated, and this signal is converted into a form suitable for each output destination in the output circuit and transmitted to the fuel injection valve 9, the throttle valve 8 and the air pump.

【0049】図2は、ガソリンエンジンにおける空燃比
と排気ガスの組成との関係を示している。
FIG. 2 shows the relationship between the air-fuel ratio and the composition of exhaust gas in a gasoline engine.

【0050】図3は本発明による内燃機関排気ガス浄化
システムの他の例を示す概略図である。エンジン排気ガ
ス流路11にバイパス流路20を設け、このバイパス流
路に前触媒2を設ける。また、排気ガスの流れの切り替
えを行うために弁12および弁21を設ける。温度セン
サー7で主触媒出口の排気ガス温度を検出して温度信号
をコントロールボックス10に入力し、その温度が主触
媒の作動温度以下の場合に弁21を閉,弁12を開とし
て排気ガスをバイパス流路20の前触媒2に導き、同時
に空気量調整弁8および燃料噴射弁9を制御して燃料過
剰の燃焼を行う。また、その温度が主触媒の作動温度以
上の場合に弁21を開,弁12を閉として排気ガスを直
接主触媒3に導き、同時に空気量調整弁8および燃料噴
射弁9を制御して理論空燃比或いはそれに近い条件で燃
焼を行わせる。弁12,弁21を開閉する信号もコント
ロールボックス10から出力される。
FIG. 3 is a schematic diagram showing another example of the internal combustion engine exhaust gas purification system according to the present invention. A bypass flow passage 20 is provided in the engine exhaust gas flow passage 11, and a front catalyst 2 is provided in this bypass flow passage. Further, a valve 12 and a valve 21 are provided to switch the flow of exhaust gas. The temperature sensor 7 detects the temperature of the exhaust gas at the outlet of the main catalyst and inputs a temperature signal to the control box 10. When the temperature is below the operating temperature of the main catalyst, the valve 21 is closed and the valve 12 is opened to remove the exhaust gas. It guides to the pre-catalyst 2 of the bypass passage 20, and at the same time, controls the air amount adjusting valve 8 and the fuel injection valve 9 to burn excess fuel. Further, when the temperature is equal to or higher than the operating temperature of the main catalyst, the valve 21 is opened and the valve 12 is closed to guide the exhaust gas directly to the main catalyst 3, and at the same time, the air amount adjusting valve 8 and the fuel injection valve 9 are controlled to theoretically operate. Combustion is performed under an air-fuel ratio or conditions close to it. A signal for opening and closing the valves 12 and 21 is also output from the control box 10.

【0051】図4は本発明の更に他の実施例による内燃
機関排気ガス浄化システムの概略図を示したものであ
る。エンジン排気ガス流路11にバイパス流路20を設
け、このバイパス流路20に除湿器15を設けている。
また、排気ガスの流れの切り替えを行うため弁13およ
び14を設けている。前触媒2内には温度センサー16
を設けた。前触媒の温度が燃焼排ガスの露点以下の場合
にバイパス流路20の除湿器15により排気ガスを除湿
した後主触媒に導き、前触媒の温度が燃焼排ガスの露点
以上の場合に排気ガスを直接前触媒へ導く。弁13,弁
14の開閉操作もコントロールボックス10で行うこと
ができる。たとえば、温度センサー16の温度検出値を
入力し、予め記憶させておいて燃焼排ガスの露点と比較
することにより、コントロールボックス10で弁13,
弁14の開閉信号を出力することができる。
FIG. 4 is a schematic view of an internal combustion engine exhaust gas purification system according to another embodiment of the present invention. A bypass passage 20 is provided in the engine exhaust gas passage 11, and a dehumidifier 15 is provided in the bypass passage 20.
Further, valves 13 and 14 are provided to switch the flow of exhaust gas. A temperature sensor 16 is provided in the front catalyst 2.
Was set up. When the temperature of the pre-catalyst is below the dew point of the combustion exhaust gas, the exhaust gas is dehumidified by the dehumidifier 15 of the bypass passage 20 and then led to the main catalyst. When the temperature of the pre-catalyst is above the dew point of the combustion exhaust gas, the exhaust gas is directly fed. Lead to pre-catalyst. The control box 10 can also be used to open and close the valves 13 and 14. For example, by inputting the temperature detection value of the temperature sensor 16 and storing it in advance and comparing it with the dew point of the combustion exhaust gas, the valve 13
An opening / closing signal of the valve 14 can be output.

【0052】実施例1 前触媒2には、容積1リットル、開口比76%のセラミ
ック(コージェライト)ハニカムにアルミナをコーティン
グし、これにパラジウム(Pd)を0.5 重量%(以下
wt%という。)を担持した触媒を用い、主触媒3には
容積2リットルの同一材料かつ同一構造のセラミックハ
ニカムにPt,PdおよびRhを担持した触媒を用い、
これらにシリーズにガソリンエンジン排ガスを流通させ
た。空燃比(A/F)を12とし理論空燃比よりも燃料
過剰にして燃焼させて得たCO7体積%(以下vol%と
いう。)、HC 0.35vol%の排気ガスを1000リ
ットル/分の流速で前触媒2に導いたところ、前触媒出
口温度は63秒後に300℃に達し、主触媒7の出口温
度は135秒後に300℃に達した。
Example 1 In the pre-catalyst 2, a ceramic (cordierite) honeycomb having a volume of 1 liter and an opening ratio of 76% was coated with alumina, and palladium (Pd) was added to 0.5 wt% (hereinafter referred to as wt%). .) Is used for the main catalyst 3, and a catalyst having Pt, Pd and Rh supported on a ceramic honeycomb of the same material and the same structure having a volume of 2 liters is used.
The gasoline engine exhaust gas was distributed to these series. The air-fuel ratio (A / F) was set to 12, and the exhaust gas of CO7 volume% (hereinafter referred to as vol%) and HC 0.35 vol% obtained by burning the fuel in excess of the stoichiometric air-fuel ratio and flow rate of 1000 liters / min. When led to the pre-catalyst 2 at, the pre-catalyst outlet temperature reached 300 ° C. after 63 seconds, and the outlet temperature of the main catalyst 7 reached 300 ° C. after 135 seconds.

【0053】比較例1 理論空燃比に近い空燃比14.5で燃焼させて得たCO
0.9vol%,HC 0.2vol% の排気ガスを1000リッ
トル/分の流速で前触媒2に導いたところ、前触媒出口
温度は87秒後に300℃に達し、主触媒3の出口温度
は170秒後に300℃に達した。
Comparative Example 1 CO obtained by burning at an air-fuel ratio of 14.5 close to the theoretical air-fuel ratio
When exhaust gas of 0.9 vol% and HC 0.2 vol% was led to the pre-catalyst 2 at a flow rate of 1000 liter / min, the pre-catalyst outlet temperature reached 300 ° C. after 87 seconds and the main catalyst 3 outlet temperature was 170 seconds. Later reached 300 ° C.

【0054】実施例2 実施例1と同じ前触媒および主触媒さらには同じ燃焼条
件(A/F=12)において生成した排気ガスに前触媒
の前で空気を380リットル/分添加したところ、前触
媒出口温度は40秒後に300℃に達し、主触媒出口温
度は87秒後に300℃に達した。
Example 2 When 380 liters / minute of air was added before the precatalyst to the exhaust gas produced under the same pre-catalyst and main catalyst as in Example 1 and the same combustion conditions (A / F = 12), The catalyst outlet temperature reached 300 ° C after 40 seconds and the main catalyst outlet temperature reached 300 ° C after 87 seconds.

【0055】実施例3 実施例2と同一条件で、前触媒に各種触媒を用いて前触
媒出口温度300℃に達するのに要する時間を測定し表
1の結果を得た。前触媒の支持体としてはセラミックハ
ニカムを用い、これにアルミナをコーティングして表1
に示す触媒活性成分を担持した。
Example 3 Under the same conditions as in Example 2, various catalysts were used as the precatalyst and the time required to reach the precatalyst outlet temperature of 300 ° C. was measured, and the results shown in Table 1 were obtained. A ceramic honeycomb was used as a support for the pre-catalyst, which was coated with alumina.
The catalytically active component shown in was loaded.

【0056】[0056]

【表1】 [Table 1]

【0057】実施例4 実施例2と同一条件で、前触媒としてPdおよびPtを
各種多孔質担体および支持体に担持したものについて、
前触媒出口温度300℃に達するのに要する時間を測定
し表2の結果を得た。
Example 4 Pd and Pt as precatalysts supported on various porous carriers and supports under the same conditions as in Example 2,
The time required to reach the precatalyst outlet temperature of 300 ° C. was measured and the results shown in Table 2 were obtained.

【0058】[0058]

【表2】 [Table 2]

【0059】実施例5 前触媒として、厚さ0.05mm のフェライト系ステンレ
ス板からなる開孔率90%のハニカムにPdを0.5w
t% 担持した触媒を用い、実施例2と同一条件で触媒
昇温速度を測定したところ、前触媒出口温度は36秒で
300℃に達し、主触媒出口温度は83秒で300℃に
達した。
Example 5 As a pre-catalyst, 0.5 W of Pd was added to a honeycomb having a porosity of 90% and made of a ferritic stainless steel plate having a thickness of 0.05 mm.
When the catalyst temperature rising rate was measured under the same conditions as in Example 2 using the catalyst loaded with t%, the outlet temperature of the front catalyst reached 300 ° C in 36 seconds, and the outlet temperature of the main catalyst reached 300 ° C in 83 seconds. .

【0060】実施例6 実施例5と同一触媒,同一条件下において、触媒に3k
Wの直流電力を通じたところ、前触媒出口温度は28秒
で300℃に達し、主触媒出口温度は62秒で300℃
に達した。
Example 6 3k was added to the catalyst under the same conditions and conditions as in Example 5.
When DC power of W was passed, the outlet temperature of the front catalyst reached 300 ° C in 28 seconds and the outlet temperature of the main catalyst reached 300 ° C in 62 seconds.
Reached

【0061】[0061]

【発明の効果】以上、本発明によれば、内燃機関のエン
ジン起動直後に排出される燃料未燃分及び部分燃焼成分
を浄化することができる。特に前触媒を設けて理論空燃
比よりも燃料過剰の状態でエンジンを始動し、前触媒の
前段で排気ガスを酸化することにより前触媒を速やかに
昇温し、前触媒の後流に設けた主触媒を急速に活性化温
度まで高めることができる。これにより内燃機関のエン
ジン起動当初の排気ガス浄化性能を高めることができ
る。
As described above, according to the present invention, it is possible to purify unburned fuel components and partial combustion components discharged immediately after the engine of the internal combustion engine is started. In particular, the pre-catalyst was installed to start the engine with a fuel excess of the stoichiometric air-fuel ratio, and the exhaust gas was oxidized before the pre-catalyst to rapidly raise the temperature of the pre-catalyst. The main catalyst can be rapidly raised to the activation temperature. As a result, the exhaust gas purification performance of the internal combustion engine at the beginning of engine startup can be improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の内燃機関の排気ガス浄化システムの一
実施例を示す概略図。
FIG. 1 is a schematic diagram showing an embodiment of an exhaust gas purification system for an internal combustion engine of the present invention.

【図2】ガソリンエンジンにおける空燃比と排気ガス組
成の関係を示すグラフ。
FIG. 2 is a graph showing a relationship between an air-fuel ratio and an exhaust gas composition in a gasoline engine.

【図3】本発明の内燃機関排気ガス浄化システムの他の
実施例を示す概略図。
FIG. 3 is a schematic view showing another embodiment of the internal combustion engine exhaust gas purification system of the present invention.

【図4】本発明の内燃機関排気ガス浄化システムの他の
実施態様を示す概略図。
FIG. 4 is a schematic diagram showing another embodiment of the internal combustion engine exhaust gas purification system of the present invention.

【図5】図1の実施例におけるコントロールボックスの
具体的構成図である。
5 is a specific configuration diagram of a control box in the embodiment of FIG.

【符号の説明】[Explanation of symbols]

1…エンジン、2…前触媒、3…主触媒、8…空気量調
整弁、9…燃料噴射弁、10…制御装置、11…排気ガ
ス流路、20…バイパス流路。
DESCRIPTION OF SYMBOLS 1 ... Engine, 2 ... Front catalyst, 3 ... Main catalyst, 8 ... Air amount adjustment valve, 9 ... Fuel injection valve, 10 ... Control device, 11 ... Exhaust gas passage, 20 ... Bypass passage.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 渡辺 紀子 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 小川 敏雄 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 宮寺 博 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 阿田子 武士 茨城県勝田市大字高場2520番地 株式会社 日立製作所自動車機器事業部内 ─────────────────────────────────────────────────── ─── Continued Front Page (72) Inventor Noriko Watanabe 7-1-1 Omika-cho, Hitachi-shi, Ibaraki Hitachi Ltd. Hitachi Research Laboratory (72) Inventor Toshio Ogawa 7-chome, Omika-cho, Hitachi-shi, Ibaraki No. 1 Hitachi Ltd. Hitachi Research Laboratory (72) Inventor Hiroshi Miyadera 1-1-1 Omika-cho, Hitachi City, Ibaraki Prefecture Hitachi Ltd. Hitachi Research Laboratory (72) Inventor Atago Samurai Katsuta City, Ibaraki Prefecture 2520, Takaba, Oji Inside Automotive Equipment Division, Hitachi, Ltd.

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】吸気系に燃料噴射弁と空気量調整弁が設置
され排気系に排気ガス浄化触媒が設置された内燃機関の
制御装置であって、前記排気系に設置された排気ガス浄
化触媒の温度を入力してその値が設定値よりも低いとき
に理論空燃比よりも燃料過剰となるように前記吸気系の
燃料噴射弁と空気量調整弁を制御する手段を備えたこと
を特徴とする内燃機関の制御装置。
1. A control device for an internal combustion engine having a fuel injection valve and an air amount adjusting valve installed in an intake system and an exhaust gas purification catalyst installed in an exhaust system, the exhaust gas purification catalyst being installed in the exhaust system. And a means for controlling the fuel injection valve and the air amount adjusting valve of the intake system such that the temperature of the intake air is input and the value is lower than the set value so that the fuel exceeds the stoichiometric air-fuel ratio. Control device for internal combustion engine.
【請求項2】吸気系に燃料噴射弁と空気量調整弁が設置
され排気系に排気ガス浄化触媒が設置された内燃機関の
制御装置であって、前記排気系に設置された排気ガス浄
化触媒の温度を入力して設定値と比較する手段と、前記
排気ガス浄化触媒の温度が設定値よりも低いときに理論
空燃比よりも燃料過剰となるように信号を発生する手段
及び該信号に基づいて前記吸気系の燃料噴射弁と空気量
調整弁を開閉駆動する制御手段とを備えたことを特徴と
する内燃機関の制御装置。
2. A control device for an internal combustion engine, wherein a fuel injection valve and an air amount adjusting valve are installed in an intake system and an exhaust gas purifying catalyst is installed in an exhaust system, and the exhaust gas purifying catalyst is installed in the exhaust system. Means for inputting the temperature of the exhaust gas and comparing it with a set value, and means for generating a signal to make the fuel excess of the stoichiometric air-fuel ratio when the temperature of the exhaust gas purification catalyst is lower than the set value, and based on the signal. A control device for an internal combustion engine, comprising: a fuel injection valve of the intake system; and control means for driving the air amount adjusting valve to open and close.
【請求項3】吸気系に燃料噴射弁と空気量調整弁を有し
排気系に排気ガス浄化触媒を有する内燃機関の制御装置
であって、前記排気系に設置された排気ガス浄化触媒の
温度を入力する手段と、該排気ガス浄化触媒の温度設定
値を記憶する手段と、前記入力手段の触媒温度と前記記
憶手段の温度設定値とを比較する手段と、前記入力手段
の触媒温度が前記温度設定値よりも低いときに理論空燃
比よりも燃料過剰となるように信号を発生する手段及び
該信号に基づいて前記吸気系の燃料噴射弁と空気量調整
弁を開閉駆動する制御手段とを備えたことを特徴とする
内燃機関の制御装置。
3. A control device for an internal combustion engine having a fuel injection valve and an air amount adjusting valve in an intake system and an exhaust gas purifying catalyst in an exhaust system, the temperature of an exhaust gas purifying catalyst installed in the exhaust system. Inputting means, means for storing the temperature set value of the exhaust gas purifying catalyst, means for comparing the catalyst temperature of the input means with the temperature set value of the storage means, and the catalyst temperature of the input means A means for generating a signal so that the fuel exceeds the stoichiometric air-fuel ratio when the temperature is lower than the set temperature value, and a control means for opening / closing the fuel injection valve and the air amount adjusting valve of the intake system based on the signal. A control device for an internal combustion engine, comprising:
【請求項4】請求項2において、前記排気ガス浄化触媒
の温度が設定値よりも低いときに空燃比A/F(Aは空
気重量、Fは燃料重量)が13以下、10以上となるよ
うに前記吸気系の燃料噴射弁と空気量調整弁を開閉駆動
する手段を備えたことを特徴とする内燃機関の制御装
置。
4. The air-fuel ratio A / F (A is air weight, F is fuel weight) is 13 or less and 10 or more when the temperature of the exhaust gas purifying catalyst is lower than a set value. A control device for an internal combustion engine, further comprising means for opening and closing the fuel injection valve and the air amount adjusting valve of the intake system.
【請求項5】請求項2において、前記排気系に設置され
た排気ガス浄化触媒の温度が設定値よりも高いときに理
論空燃比或いはその近傍の空燃比となるように前記吸気
系の燃料噴射弁と空気量調整弁を開閉駆動する手段を備
えたことを特徴とする内燃機関の制御装置。
5. The fuel injection system according to claim 2, wherein when the temperature of the exhaust gas purifying catalyst installed in the exhaust system is higher than a set value, the stoichiometric air-fuel ratio or an air-fuel ratio near the stoichiometric air-fuel ratio is obtained. A control device for an internal combustion engine, comprising: means for opening and closing a valve and an air amount adjusting valve.
【請求項6】吸気系に燃料噴射弁と空気量調整弁を有し
排気系に燃焼触媒と三元系排気ガス浄化主触媒とを有す
る内燃機関の制御装置であって、前記排気ガス浄化主触
媒の温度を設定値と比較してその値が設定値よりも低い
ときに理論空燃比よりも燃料過剰となるように前記吸気
系の燃料噴射弁と空気量調整弁を開閉駆動する手段を備
えたことを特徴とする内燃機関の制御装置。
6. A control device for an internal combustion engine having a fuel injection valve and an air amount adjusting valve in an intake system, and a combustion catalyst and a three-way exhaust gas purifying main catalyst in an exhaust system, wherein the exhaust gas purifying main A means is provided for comparing the temperature of the catalyst with a set value and opening and closing the fuel injection valve and the air amount adjusting valve of the intake system so that when the value is lower than the set value, the fuel exceeds the stoichiometric air-fuel ratio. A control device for an internal combustion engine, characterized in that
【請求項7】吸気系に燃料噴射弁と空気量調整弁を有
し、排気系の前段に燃焼触媒を有し後段に三元系排気ガ
ス浄化主触媒を有し該燃焼触媒の前段に空気供給手段を
有する内燃機関の制御装置であって、前記排気ガス浄化
主触媒の温度を入力してその値が設定値よりも低いとき
に理論空燃比よりも燃料過剰となりかつ前記空気供給手
段より空気が供給されるように信号を発生する手段及び
該信号に基づいて前記吸気系の燃料噴射弁と空気量調整
弁を開閉駆動し前記空気供給手段をon,offする手
段を備えたことを特徴とする内燃機関の制御装置。
7. An intake system having a fuel injection valve and an air amount adjusting valve, a combustion catalyst in the front stage of the exhaust system, and a three-way exhaust gas purifying main catalyst in the rear stage, and air in the front stage of the combustion catalyst. A control device for an internal combustion engine having a supply means, wherein when the temperature of the exhaust gas purifying main catalyst is input and the value is lower than a set value, the fuel exceeds the stoichiometric air-fuel ratio and air is supplied from the air supply means. And a means for turning on and off the air supply means by driving to open and close the fuel injection valve and the air amount adjusting valve of the intake system based on the signal. Control device for internal combustion engine.
【請求項8】吸気系に燃料噴射弁と空気量調整弁が設置
され排気系に排気ガス浄化触媒が設置された内燃機関の
制御方法であって、前記排気系に設置された排気ガス浄
化触媒の温度を入力してその値が設定値よりも低いとき
に理論空燃比よりも燃料過剰となるように前記吸気系の
燃料噴射弁と空気量調整弁を制御するようにしたことを
特徴とする内燃機関の制御方法。
8. A method of controlling an internal combustion engine in which a fuel injection valve and an air amount adjusting valve are installed in an intake system and an exhaust gas purification catalyst is installed in an exhaust system, the exhaust gas purification catalyst being installed in the exhaust system. Is input, and the fuel injection valve and the air amount adjusting valve of the intake system are controlled so that when the value is lower than a set value, the fuel exceeds the stoichiometric air-fuel ratio. Internal combustion engine control method.
JP34596692A 1992-12-25 1992-12-25 Control device for internal combustion engine Pending JPH06193490A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34596692A JPH06193490A (en) 1992-12-25 1992-12-25 Control device for internal combustion engine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34596692A JPH06193490A (en) 1992-12-25 1992-12-25 Control device for internal combustion engine

Publications (1)

Publication Number Publication Date
JPH06193490A true JPH06193490A (en) 1994-07-12

Family

ID=18380220

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34596692A Pending JPH06193490A (en) 1992-12-25 1992-12-25 Control device for internal combustion engine

Country Status (1)

Country Link
JP (1) JPH06193490A (en)

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