JPH06192021A - Method for cleaning sand in sandbox - Google Patents

Method for cleaning sand in sandbox

Info

Publication number
JPH06192021A
JPH06192021A JP34445492A JP34445492A JPH06192021A JP H06192021 A JPH06192021 A JP H06192021A JP 34445492 A JP34445492 A JP 34445492A JP 34445492 A JP34445492 A JP 34445492A JP H06192021 A JPH06192021 A JP H06192021A
Authority
JP
Japan
Prior art keywords
sand
sandbox
particles
antibacterial
soluble glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34445492A
Other languages
Japanese (ja)
Other versions
JP2975492B2 (en
Inventor
Takashi Shiraki
隆司 白木
Hisashi Nonoyama
尚志 野々山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ishizuka Glass Co Ltd
Original Assignee
Ishizuka Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Application filed by Ishizuka Glass Co Ltd filed Critical Ishizuka Glass Co Ltd
Priority to JP4344454A priority Critical patent/JP2975492B2/en
Publication of JPH06192021A publication Critical patent/JPH06192021A/en
Application granted granted Critical
Publication of JP2975492B2 publication Critical patent/JP2975492B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To provide a method for cleaning sand in a sandbox, capable of reducing various saprophytes as Escherichia coli and eggs of ascaris in sand by a method safe to human body, maintaining the effect in the open air for a long period of time. CONSTITUTION:Particles of inorganic antimicrobial agent capable of eluting silver ion or copper ion is dispersed into sand particles in a sandbox. At least one selected from the group consisting of antimicrobial zeolite, antimicrobial amorphous aluminosilicate, antimicrobial interlayer compound and soluble glass is used as the inorganic antimicrobial agent. In the case of silver-containing soluble glass, the blending ratio is about 0.01-20wt.% by weight.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、公園等の砂場用砂の浄
化方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for purifying sand for sandboxes such as parks.

【0002】[0002]

【従来の技術】公園に設置されている砂場には、犬、猫
等のペットが侵入して排泄物を残すため、大腸菌を初め
大量の雑菌や回虫の卵が含まれていることが調査の結果
判明した。このために雑菌が砂場で遊ぶ幼児の手指に付
着して健康を害するおそれがある。またペットに寄生す
る回虫の卵は人体に入っても成虫にはならないものの、
腹痛を引き起こすおそれがある。そこで砂場の周囲に金
網を張ってペットの侵入を防止することも検討されてい
るが、砂場が利用しにくくなるという問題があるうえ、
猫等の侵入を完全に防止することは困難であった。
2. Description of the Related Art It has been investigated that pets such as dogs and cats infiltrate the sandboxes installed in parks and leave excrement, so that a large amount of bacteria and roundworm eggs including E. coli are contained in the sandboxes. The result turned out. For this reason, various bacteria may attach to the hands and fingers of infants playing in the sandbox, which may impair their health. Also, although roundworm eggs that parasitize pets do not become adults even if they enter the human body,
May cause abdominal pain. Therefore, it is considered to prevent the pet from entering by putting a wire mesh around the sandbox, but there is a problem that it becomes difficult to use the sandbox.
It was difficult to completely prevent the invasion of cats and the like.

【0003】また、砂場に殺虫剤や殺菌剤を散布するこ
とも考えられるが、殺虫剤や殺菌剤が人体に影響を及ぼ
す危険性があるために実際に使用された例はなく、また
屋外では揮発したり太陽光線等により分解されるため、
殺虫剤や殺菌剤の効力が短期間で失われてしまうという
問題もあった。
It is also conceivable to spray insecticides and bactericides in the sandbox, but since insecticides and bactericides have a risk of affecting the human body, they have not been used actually, and outdoors. As it volatilizes and is decomposed by sunlight, etc.,
There is also a problem that the effects of insecticides and fungicides are lost in a short period of time.

【0004】[0004]

【発明が解決しようとする課題】本発明は上記した従来
の問題点を解決して、人体に安全な方法で砂中の大腸菌
等の雑菌や回虫卵を減少させることができ、しかもその
効果を屋外において長期間維持することができる砂場用
砂の浄化方法を提供するために完成されたものである。
DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned conventional problems and is able to reduce bacteria such as Escherichia coli in the sand and roundworm eggs by a safe method for the human body, and its effect. The present invention has been completed in order to provide a method for purifying sand for sandboxes that can be maintained outdoors for a long time.

【0005】[0005]

【課題を解決しようとする手段】上記の課題を解決する
ために完成された本発明は、抗菌性ゼオライト、抗菌性
無定型アルミノ珪酸塩、抗菌性層間化合物、及び溶解性
ガラスからなる群より選ばれた少なくとも1種の無機抗
菌剤の粒子を、砂粒子中に分散させることを特徴とする
ものである。
The present invention completed to solve the above-mentioned problems is selected from the group consisting of antibacterial zeolite, antibacterial amorphous aluminosilicate, antibacterial intercalation compound, and soluble glass. The particles of at least one inorganic antibacterial agent are dispersed in the sand particles.

【0006】このような無機抗菌剤のうち、抗菌性ゼオ
ライトはゼオライト中のイオン交換可能なイオンを、抗
菌性のある銀イオン及び/又は銅イオンを溶出し得るイ
オンに置換したものである。抗菌性無定型アルミノ珪酸
塩はアルミノ珪酸塩中のイオン交換可能なイオンを、抗
菌性のある銀イオン及び/又は銅イオンを溶出し得るイ
オンに置換したものである。抗菌性層間化合物は無機層
状化合物の層間に銀錯塩を担持させたものである。抗菌
性の溶解性ガラスは、水分との接触により所定の速度で
溶解するガラス中に銀及び/又は銅を含有させたもので
ある。これらのうち、安定性、安全性、抗菌効果の観点
から銀含有溶解性ガラスを使用することが最も好まし
い。
Among such inorganic antibacterial agents, the antibacterial zeolite is one in which ion-exchangeable ions in zeolite are replaced with ions capable of eluting antibacterial silver ions and / or copper ions. The antibacterial amorphous aluminosilicate is an aluminosilicate in which ion-exchangeable ions are replaced with ions capable of eluting antibacterial silver ions and / or copper ions. The antibacterial intercalation compound is one in which a silver complex salt is supported between layers of an inorganic layered compound. The antibacterial soluble glass is one in which silver and / or copper is contained in glass that melts at a predetermined rate when contacted with water. Among these, it is most preferable to use the silver-containing soluble glass from the viewpoint of stability, safety and antibacterial effect.

【0007】この抗菌性の溶解性ガラスは、長期間にわ
たり徐々に銀又は銅イオンを溶出させ、銀や銅イオンの
持つ抗菌効果により細菌の繁殖を防止したり、回虫卵を
死滅させることができるものである。銀含有溶解性ガラ
スの場合には、砂100 重量部に対して0.01〜20重量部の
範囲で混合することが好ましい。これ以下では効果が少
なく、これ以上では不経済であるためである。
This antibacterial soluble glass gradually elutes silver or copper ions over a long period of time, and can prevent bacterial growth or kill roundworm eggs by the antibacterial effect of silver or copper ions. It is possible. In the case of the silver-containing soluble glass, it is preferable to mix it in the range of 0.01 to 20 parts by weight with respect to 100 parts by weight of sand. This is because if it is less than this, the effect is small and if it is more than that, it is uneconomical.

【0008】なお、既存のある公園の砂の粒度分布を測
定したところ、106 μm 以下が2.1%、106 〜250 μm
が7.7 %、250 〜500 μm が28.3%、500 〜840 μm が
24.3%、840 〜2000μm が25.4%、2000〜4000μm が1
1.8%、4000μm 以上が0.4 %であった。そして無機抗
菌剤の粒子は、公園の砂と粒度を合わせておくことが均
一分散を図るうえで好ましいため、この場合には840 μ
m 以下の粒径とすることが望ましい。
The particle size distribution of sand in an existing park was measured and found to be 2.1% for 106 μm or less, 106-250 μm.
Is 7.7%, 250-500 μm is 28.3%, 500-840 μm is
24.3%, 840-2000 μm is 25.4%, 2000-4000 μm is 1
1.8% and 0.4% at 4000 μm or more. The particle size of the inorganic antibacterial agent should be the same as that of the sand in the park to ensure uniform dispersion.
It is desirable that the particle size be m or less.

【0009】[0009]

【作用】上記のように、銀イオン及び/又は銅イオンを
溶出し得る無機抗菌剤の粒子を砂粒子中に分散させてお
けば、雨水や地中の水分との接触により無機抗菌剤から
抗菌性のある銀イオンや銅イオンが溶出し、砂中の大腸
菌等の雑菌の繁殖を防止したり、回虫卵を死滅させたり
することができる。このために砂場で遊ぶ幼児が砂を口
に入れても、健康が損なわれるおそれがない。また銀イ
オンや銅イオンは人体に対して安全であるうえ、銀含有
溶解性ガラスを使用すれば2年程度の長期間にわたりそ
の効力を安定に維持することができる。
When the particles of the inorganic antibacterial agent capable of eluting silver ions and / or copper ions are dispersed in the sand particles as described above, the antibacterial effect of the inorganic antibacterial agent can be obtained by contact with rainwater or underground water. Efficient silver ions and copper ions are eluted to prevent the propagation of various bacteria such as Escherichia coli in the sand and to kill roundworm eggs. Therefore, even if an infant playing in the sandbox puts sand in his mouth, he does not have to worry about his health. In addition, silver ions and copper ions are safe for the human body, and if silver-containing soluble glass is used, its efficacy can be stably maintained for a long period of about 2 years.

【0010】[0010]

【実施例】B2O3 55モル%、Na2O 10モル%、CaO 5モ
ル%、SiO2 30モル%の組成の溶解性ガラス100 重量部
中に、Ag2Oを0.5 重量%添加したものを溶融し、ロール
クラッシャーで粉砕したうえ840 μm 以下の粒径となる
ように分級し、銀含有溶解性ガラスの粒子を得た。一
方、公園の砂場の5箇所から砂を採取し、その生菌数を
測定したところ表1の通りの結果が得られた。
Example: Ag 2 O was added in an amount of 0.5% by weight to 100 parts by weight of a soluble glass having a composition of 55% by mole of B 2 O 3 , 10% by mole of Na 2 O, 5% by mole of CaO and 30% by mole of SiO 2 . The material was melted, crushed by a roll crusher, and then classified so as to have a particle diameter of 840 μm or less to obtain particles of silver-containing soluble glass. On the other hand, when sand was sampled from five places in the sandbox of the park and the number of viable bacteria was measured, the results shown in Table 1 were obtained.

【表1】 [Table 1]

【0011】上記の砂場の砂100 重量部に対して、銀含
有溶解性ガラスの粒子を実施例1では0.5 重量部加え、
実施例2では2.0 重量部を加えた。その後、6時間経過
後と24時間経過後の砂1g当りの生菌数を測定したとこ
ろ、表2、表3の通りの結果が得られた。実施例では砂
場中の生菌数が著しく低下していることが分かる。
In Example 1, 0.5 part by weight of silver-containing soluble glass particles was added to 100 parts by weight of sand in the above sandbox.
In Example 2, 2.0 parts by weight was added. Then, the viable cell count per 1 g of sand was measured after 6 hours and 24 hours, and the results shown in Tables 2 and 3 were obtained. In the examples, it can be seen that the number of viable bacteria in the sandbox is significantly reduced.

【0012】[0012]

【表2】 [Table 2]

【表3】 [Table 3]

【0013】[0013]

【発明の効果】以上に説明したように、本発明の砂場用
砂の浄化方法は無機抗菌剤の粒子を砂粒子中に分散させ
ることにより、人体に安全な方法で砂場中の大腸菌等の
雑菌や回虫卵を減少させることができる。またこれらの
無機抗菌剤はその効果を屋外において長期間維持するこ
とができるので、メンテナンスの手数も少なくて済む利
点がある。このため本発明によれば砂場を金網等で囲む
必要もなく、幼児等を安心して遊ばせることができる。
Industrial Applicability As described above, the method for purifying sand for sandboxes of the present invention disperses the particles of the inorganic antibacterial agent in the sand particles, so that various bacteria such as Escherichia coli in the sandbox are safe for the human body. It can reduce roundworm eggs. Moreover, since these inorganic antibacterial agents can maintain their effects outdoors for a long period of time, there is an advantage that the number of maintenance steps can be reduced. Therefore, according to the present invention, it is not necessary to surround the sandbox with a wire net or the like, and an infant or the like can be played without anxiety.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 抗菌性ゼオライト、抗菌性無定型アルミ
ノ珪酸塩、抗菌性層間化合物、及び溶解性ガラスからな
る群より選ばれた少なくとも1種の無機抗菌剤の粒子
を、砂粒子中に分散させることを特徴とする砂場用砂の
浄化方法。
1. Particles of at least one inorganic antibacterial agent selected from the group consisting of antibacterial zeolite, antibacterial amorphous aluminosilicate, antibacterial intercalation compound, and soluble glass are dispersed in sand particles. A method for purifying sand for a sandbox, which is characterized in that
【請求項2】 無機抗菌剤が銀及び/又は銅を含有する
溶解性硝子であることを特徴とする請求項1記載の砂場
用砂の浄化方法。
2. The method for purifying sand for sandbox according to claim 1, wherein the inorganic antibacterial agent is a soluble glass containing silver and / or copper.
JP4344454A 1992-12-24 1992-12-24 Sand purification sand purification method Expired - Fee Related JP2975492B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4344454A JP2975492B2 (en) 1992-12-24 1992-12-24 Sand purification sand purification method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4344454A JP2975492B2 (en) 1992-12-24 1992-12-24 Sand purification sand purification method

Publications (2)

Publication Number Publication Date
JPH06192021A true JPH06192021A (en) 1994-07-12
JP2975492B2 JP2975492B2 (en) 1999-11-10

Family

ID=18369396

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4344454A Expired - Fee Related JP2975492B2 (en) 1992-12-24 1992-12-24 Sand purification sand purification method

Country Status (1)

Country Link
JP (1) JP2975492B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07304617A (en) * 1994-05-09 1995-11-21 Japan Carlit Co Ltd:The Method for cleaning sandbox

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07304617A (en) * 1994-05-09 1995-11-21 Japan Carlit Co Ltd:The Method for cleaning sandbox

Also Published As

Publication number Publication date
JP2975492B2 (en) 1999-11-10

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