JPH06145450A - Vinyl chloride-based resin composition - Google Patents
Vinyl chloride-based resin compositionInfo
- Publication number
- JPH06145450A JPH06145450A JP4299784A JP29978492A JPH06145450A JP H06145450 A JPH06145450 A JP H06145450A JP 4299784 A JP4299784 A JP 4299784A JP 29978492 A JP29978492 A JP 29978492A JP H06145450 A JPH06145450 A JP H06145450A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- based resin
- resistance
- chloride resin
- impact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、塩化ビニル系樹脂組成
物に関する。TECHNICAL FIELD The present invention relates to a vinyl chloride resin composition.
【０００２】[0002]
【従来の技術】塩化ビニル樹脂は、安価で、耐候性、難
燃性、耐薬品性、耐水性、機械的強度等が良好で、雨
樋、デッキ材、波板、窓枠などの建材、その他各種の用
途に広く使用されているが、耐熱性が低いため、オフィ
スオートメーション機器のハウジングや自動車の内部部
品のように高温になる部品に使用するのは不適当であっ
た。2. Description of the Related Art Vinyl chloride resin is inexpensive, has good weather resistance, flame resistance, chemical resistance, water resistance, mechanical strength, etc., and is a building material for rain gutters, deck materials, corrugated boards, window frames, etc. It is widely used for various other purposes, but its low heat resistance makes it unsuitable for use in high temperature parts such as housings of office automation equipment and internal parts of automobiles.
【０００３】塩化ビニル樹脂の上記の物性を低下させる
ことなく、耐熱性を付与するために、最近、高塩素化さ
れた塩化ビニル系樹脂が使用されている。しかしながら
高塩素化された塩化ビニル系樹脂は成形性が悪く、得ら
れた成形体は耐衝撃性が小さいという欠点を有してい
た。Recently, a highly chlorinated vinyl chloride resin has been used in order to impart heat resistance without deteriorating the above physical properties of the vinyl chloride resin. However, the highly chlorinated vinyl chloride resin has poor moldability, and the molded product obtained has the drawback of low impact resistance.
【０００４】上記の欠点を解消するために種々の提案が
なされている。たとえば、特開平４−７６０４４号公報
には、塩素化塩化ビニル樹脂に、ＡＢＳ樹脂、ＭＢＳ樹
脂、塩素化ポリエチレン及びアクリルゴムから選ばれる
衝撃改良剤と、スチレン系化合物とシアン化ビニル化合
物との共重合体とフェノール系酸化防止剤を添加した塩
化ビニル系樹脂組成物が記載されている。Various proposals have been made to solve the above drawbacks. For example, in Japanese Patent Laid-Open No. 4-76044, an impact modifier selected from ABS resin, MBS resin, chlorinated polyethylene and acrylic rubber is added to a chlorinated vinyl chloride resin, and a styrene compound and a vinyl cyanide compound are used together. A vinyl chloride resin composition containing a polymer and a phenolic antioxidant is described.
【０００５】上記組成物は、成形性が改善され、得られ
た成形体の耐衝撃性もすぐれたものとなっているが、耐
候性が悪く、特に光によって黄変や褪色などの光劣化を
容易に生ずるという欠点があった。The above composition has improved moldability and the resulting molded article has excellent impact resistance, but the weatherability is poor, and in particular, light deterioration such as yellowing and fading is caused by light. It had the drawback of being easily produced.
【０００６】[0006]
【発明が解決しようとする課題】本発明の目的は上記欠
点に鑑み、成形性が優れ、耐衝撃性、耐熱性、難燃性、
耐薬品性及び耐水性のみならず耐候性（特に耐光性）に
優れた成形体を得ることができる塩化ビニル系樹脂組成
物を提供することにある。In view of the above-mentioned drawbacks, the object of the present invention is to provide excellent moldability, impact resistance, heat resistance, flame retardancy,
It is an object of the present invention to provide a vinyl chloride resin composition capable of obtaining a molded article excellent not only in chemical resistance and water resistance but also in weather resistance (particularly light resistance).
【０００７】[0007]
【課題を解決するための手段】本発明で使用される塩化
ビニル系樹脂(a) とは、塩化ビニル樹脂、塩化ビニル
と、共重合可能なエチレン、プロピレン等のエチレン性
不飽和結合を有するモノマーとの共重合体及びこれ等の
樹脂の後塩素化物をいう。The vinyl chloride resin (a) used in the present invention is a vinyl chloride resin, vinyl chloride, and a monomer having an ethylenically unsaturated bond such as ethylene and propylene which are copolymerizable. And post-chlorinated products of these resins.
【０００８】塩化ビニル系樹脂(a) の平均重合度は、小
さくなると得られた成形体の耐衝撃性が低下し、大きく
なると熱流動性が低下するので、２５０〜１４００が好
ましい。又、後塩素化物も平均重合度が２５０〜１４０
０の塩化ビニル系樹脂が後塩素化されたものが好まし
い。そして、平均重合度が２５０〜１４００の塩化ビニ
ル系樹脂と平均重合度が２５０〜１４００の塩化ビニル
系樹脂が後塩素化された塩素化塩化ビニル系樹脂が併用
されるのが好ましい。又、射出成形する際には、平均重
合度は３００〜８００のものが好ましい。When the average degree of polymerization of the vinyl chloride resin (a) is small, the impact resistance of the obtained molded article is low, and when it is large, the heat fluidity is low. The post-chlorinated product also has an average degree of polymerization of 250 to 140.
It is preferable that the vinyl chloride resin of 0 is post-chlorinated. Then, it is preferable to use a vinyl chloride resin having an average degree of polymerization of 250 to 1400 and a chlorinated vinyl chloride resin obtained by post-chlorinating a vinyl chloride resin having an average degree of polymerization of 250 to 1400. Further, when injection molding, the average degree of polymerization is preferably 300 to 800.
【０００９】塩化ビニル系樹脂(a) の平均塩素含有量
は、少なくなると耐熱性が低下し、逆に多くなると熱流
動性が低下し、成形しにくくなるので、６０〜７０Wt％
に限定される。従って、塩化ビニル系樹脂(a) は、塩素
含有量がこの範囲にはいるように単独もしくは二種以上
の樹脂が併用して使用される。When the average chlorine content of the vinyl chloride resin (a) is low, the heat resistance is low, and conversely, when it is high, the heat fluidity is low and the molding becomes difficult.
Limited to Therefore, the vinyl chloride resin (a) is used alone or in combination of two or more so that the chlorine content falls within this range.
【００１０】本発明で使用される衝撃改良剤(b) は、ア
クリルゴム、ＡＥＳ樹脂及び塩素化化ポリエチレンより
なる群から選ばれ、一種もしくは二種以上が併用され
る。The impact modifier (b) used in the present invention is selected from the group consisting of acrylic rubber, AES resin and chlorinated polyethylene, and one kind or a combination of two or more kinds is used.
【００１１】上記アクリルゴムとは、メチルアクリレー
ト、エチルアクリレート、ブチルアクリレート、オクチ
ルアクリレート等のアクリレートを主体とし、このアク
リレートと2-クロロエチルビニルエーテル、メチルビニ
ルケトン、アクリル酸、アクリロニトリル、ブタジエン
等のモノマーとの共重合体であり、例えば、鐘淵化学社
製、カネエースＦＭ、呉羽化学社製、クレハＫＭ−３３
４等があげられる。The acrylic rubber is mainly composed of acrylates such as methyl acrylate, ethyl acrylate, butyl acrylate and octyl acrylate, and this acrylate and monomers such as 2-chloroethyl vinyl ether, methyl vinyl ketone, acrylic acid, acrylonitrile and butadiene. Kaneha Chemical Co., Ltd., Kaneace FM, Kureha Chemical Co., Kureha KM-33.
4 etc.
【００１２】上記ＡＥＳ樹脂とは、エチレン−プロピレ
ン共重合ゴム又はエチレン−プロピレン−非共役ジエン
共重合ゴムに、スチレンとアクリロニトリルをグラフト
重合して得られる樹脂である。The above AES resin is a resin obtained by graft-polymerizing styrene and acrylonitrile onto an ethylene-propylene copolymer rubber or an ethylene-propylene-non-conjugated diene copolymer rubber.
【００１３】又、上記非共役ジエンとしては、たとえ
ば、ジシクロペンタジエン、メチルテトラヒドロインデ
ン、エチリデンノルボルネン、1,4-ヘキサジエン等があ
げられる。Examples of the non-conjugated dienes include dicyclopentadiene, methyltetrahydroindene, ethylidene norbornene and 1,4-hexadiene.
【００１４】ＡＥＳ樹脂の重量平均分子量は、低すぎる
と得られる成形体の耐衝撃性を向上させる効果が低下
し、高すぎると組成物の熱流動性が低下するので、３万
〜１５万の範囲が好ましい。When the weight average molecular weight of the AES resin is too low, the effect of improving the impact resistance of the obtained molded article is lowered, and when it is too high, the heat fluidity of the composition is lowered, so that it is 30,000 to 150,000. Ranges are preferred.
【００１５】上記塩素化ポリエチレンは、塩素化度が大
き過ぎても小さ過ぎても衝撃改良効果が低下するので３
０〜４０Wt％のものが好ましい。又、重量平均分子量は
１０万〜１５万のものが好ましい。The above-mentioned chlorinated polyethylene has a low impact improving effect if the degree of chlorination is too high or too low.
It is preferably from 0 to 40 Wt%. The weight average molecular weight is preferably 100,000 to 150,000.
【００１６】本発明で使用されるスチレン系共重合体
(c) はスチレン系化合物とシアン化ビニル化合物との共
重合体である。上記スチレン系化合物としては、例え
ば、スチレン、α−メチルスチレン等があげられ、スチ
レンが熱流動性が優れているので好ましい。又、シアン
化ビニル化合物としては、例えば、アクリロニトリル、
メタリロニトリル等が挙げられ、アクリロニトリルが塩
化ビニル系樹脂との相溶性が優れているので好ましい。Styrenic copolymer used in the present invention
(c) is a copolymer of a styrene compound and a vinyl cyanide compound. Examples of the styrene compound include styrene and α-methylstyrene, and styrene is preferable because it has excellent heat fluidity. Further, as the vinyl cyanide compound, for example, acrylonitrile,
Examples thereof include methacrylonitrile, and acrylonitrile is preferable because it has excellent compatibility with a vinyl chloride resin.
【００１７】スチレン系共重合体は、耐衝撃性及び熱流
動性の特性から、スチレン系化合物とシアン化ビニル化
合物が６０：４０〜８０：２０（重量比）の割合で共重
合されているのが好ましく、その重量平均分子量は、小
さくなると成形体の耐衝撃性が低下し、大きくなると熱
流動性が低下するので、３万〜１０万が好ましく、アク
リロニトリル−スチレン共重合体（ＡＳ樹脂）が好適に
使用される。The styrene copolymer is a copolymer of a styrene compound and a vinyl cyanide compound at a ratio of 60:40 to 80:20 (weight ratio) because of its impact resistance and thermal fluidity. The weight average molecular weight is preferably 30,000 to 100,000 because the impact resistance of the molded article decreases when the weight average molecular weight decreases and the heat fluidity decreases when the weight average molecular weight increases, and acrylonitrile-styrene copolymer (AS resin) is preferable. It is preferably used.
【００１８】本発明で使用されるヒンダードアミン系光
安定剤(d) は一般式(1) で表されるる。The hindered amine light stabilizer (d) used in the present invention is represented by the general formula (1).
【化２】 [Chemical 2]
【００１９】式中、ＸはWhere X is
【化３】 であり、ＲはＨ又はＣＨ3 である。又、ｎは大きくなる
と塩化ビニル系樹脂組成物の熱流動性が低下するので、
１〜５の整数である。尚、ヒンダードアミン系光安定剤
(d) はｎ数の異なる安定剤の混合物であってもよく、平
均分子量は１５７０〜３０００の混合物が好適に使用さ
れる。[Chemical 3] And R is H or CH 3 . Further, when n becomes large, the heat fluidity of the vinyl chloride resin composition decreases, so
It is an integer of 1 to 5. In addition, hindered amine light stabilizer
(d) may be a mixture of stabilizers having different n numbers, and a mixture having an average molecular weight of 1570 to 3000 is preferably used.
【００２０】本発明の組成物は、上記塩化ビニル系樹脂
(a) と衝撃改良剤(b) とスチレン系共重合体(c) とヒン
ダードアミン系光安定剤(d) よりなるが、塩化ビニル系
樹脂(a) の添加量が少なくなると難燃性が低下し、衝撃
改良剤(b) の添加量が少なくなると耐衝撃性が低下し、
多くなると熱流動性、耐熱性等が低下し、スチレン系共
重合体(c) の添加量が多くなると耐衝撃性が低下するの
で、塩化ビニル系樹脂(a) は４０〜７０Wt％添加され、
衝撃改良剤(b) は１０〜４０Wt％添加され、スチレン系
共重合体(c) は１５〜４０Wt％添加される。The composition of the present invention comprises the above vinyl chloride resin.
Composed of (a), impact modifier (b), styrene-based copolymer (c) and hindered amine-based light stabilizer (d), but flame retardancy decreases when vinyl chloride resin (a) is added in a small amount However, if the amount of impact modifier (b) added is reduced, the impact resistance decreases,
If the amount of styrene-based copolymer (c) is increased, the impact resistance will be reduced. If the amount of styrene-based copolymer (c) is increased, the vinyl chloride-based resin (a) is added in an amount of 40 to 70 wt%.
The impact modifier (b) is added in an amount of 10 to 40 wt% and the styrene copolymer (c) is added in an amount of 15 to 40 wt%.
【００２１】又、光安定剤(d) の添加量は少なくなると
耐候性が低下し、多くなると成形時に熱分解をおこし、
成形体の物性が低下するので、０．０１〜５Wt％添加さ
れるのであり、好ましくは０．１〜２Wt％である。Further, when the amount of the light stabilizer (d) added decreases, the weather resistance decreases, and when it increases, thermal decomposition occurs during molding,
Since the physical properties of the molded product deteriorate, 0.01 to 5 wt% is added, and preferably 0.1 to 2 wt%.
【００２２】本発明の塩化ビニル系樹脂組成物の構成
は、上述の通りであり、更に、成形性、熱安定性等を向
上させるために、一般に使用されるポリエチレンワック
ス、高級アルコール、エステル系滑剤、ポリメチルメタ
クリレート系加工助剤、ジブチル錫マレート、ジブチル
錫メルカプト、金属石鹸、鉛化合物等の熱安定剤、紫外
線吸収剤、炭酸カルシウム、ガラスファイバー等の充填
剤、酸化チタン等の顔料、染料などが併用されてもよ
い。The composition of the vinyl chloride resin composition of the present invention is as described above, and further, in order to improve moldability, heat stability and the like, generally used polyethylene wax, higher alcohol, ester lubricant. , Polymethylmethacrylate processing aids, heat stabilizers such as dibutyltin malate, dibutyltin mercapto, metal soap, lead compounds, UV absorbers, calcium carbonate, fillers such as glass fibers, pigments such as titanium oxide, dyes, etc. May be used in combination.
【００２３】本発明の塩化ビニル系樹脂組成物は、押出
成形法、カレンダー成形、ロール・プレス成形、射出成
形等従来公知の任意の加熱成形法で成形することが可能
であるが、射出成形に適している。The vinyl chloride resin composition of the present invention can be molded by any conventionally known heat molding method such as extrusion molding method, calender molding, roll press molding and injection molding. Are suitable.
【００２４】上記塩化ビニル系樹脂組成物を射出成形す
るには、例えば、組成物をスーパーミキサーで均一に分
散した混合物又はこの混合物を押出機に供給しペレタイ
ザーで切断して得られたペレットを射出成形機に供給し
て成形すればよく、射出条件は一般に、バレル温度１７
０〜１９０℃、射出圧力１２０〜１５０ kｇ／cm2 であ
る。For injection molding of the vinyl chloride resin composition, for example, a mixture in which the composition is uniformly dispersed by a super mixer or a pellet obtained by feeding the mixture to an extruder and cutting with a pelletizer is injected. It may be supplied to a molding machine for molding, and the injection condition is generally a barrel temperature of 17
The injection pressure is 0 to 190 ° C. and the injection pressure is 120 to 150 kg / cm 2 .
【００２５】[0025]
【実施例】次に本発明の実施例を説明する。実施例１〜５、比較例１〜８ 表１に示した所定の塩化ビニル樹脂（重合度４５０、塩
素含有率５７Wt％）、塩素化塩化ビニル樹脂（重合度５
００、塩素含有率６６Wt％）、衝撃改良剤、ＡＳ樹脂
（住友ダウ社製「Ｓ−１０００」）及び光安定剤並びに
ジブチル錫マレート３重量部、ジブチル錫メルカプト
０．５重量部、ステアリン酸カルシウム１重量部、エス
テル系滑剤１重量部、酸化チタン３重量部を、スーパー
ミキサーに供給し、１８０℃のロールミルで３分間混練
して厚さ約１mmのシートを得た。得られたシートを１９
０℃、１５０ kｇ／cm2 の条件で１０分間プレスして物
性測定用の試料を得た。EXAMPLES Examples of the present invention will be described below. Examples 1 to 5 and Comparative Examples 1 to 8 Prescribed vinyl chloride resin (polymerization degree 450, chlorine content 57 Wt%) and chlorinated vinyl chloride resin (polymerization degree 5 shown in Table 1)
00, chlorine content 66 Wt%), impact modifier, AS resin (“S-1000” manufactured by Sumitomo Dow Co., Ltd.) and light stabilizer, 3 parts by weight of dibutyltin malate, 0.5 parts by weight of dibutyltin mercapto, 1 part of calcium stearate. Parts by weight, 1 part by weight of ester-based lubricant, and 3 parts by weight of titanium oxide were supplied to a super mixer and kneaded for 3 minutes by a roll mill at 180 ° C. to obtain a sheet having a thickness of about 1 mm. 19 sheets obtained
A sample for measuring physical properties was obtained by pressing for 10 minutes at 0 ° C. and 150 kg / cm 2 .
【００２６】得られた試料を用いて、熱変形温度及び衝
撃強度を測定し、難燃性試験及び耐候性試験を行い、結
果を表１に示した。測定方法及び試験方法は下記の通り
である。The heat distortion temperature and impact strength of the obtained sample were measured, and the flame retardancy test and weather resistance test were conducted. The results are shown in Table 1. The measurement method and test method are as follows.
【００２７】熱変形温度 ＡＳＴＭ Ｄ−６４８に準拠し、厚さ０．２５インチの
試験片について、荷重１８．６ kｇ／cm2 で測定した。衝撃強度 ＡＳＴＭ Ｄ−２５６に準拠し、厚さ０．１２５インチ
の試験片について、ノッチ付き、２３℃の条件で測定し
た。 Heat distortion temperature According to ASTM D-648, a test piece having a thickness of 0.25 inch was measured under a load of 18.6 kg / cm 2 . Impact strength According to ASTM D-256, a test piece having a thickness of 0.125 inches was measured under a condition of 23 ° C. with a notch.
【００２８】難燃性試験 ＵＬ−９４法に準拠し、厚さ１／１６インチの試験片に
ついて、難燃性を評価した。耐候性試験 サンシャイン・ウエザー・オ・メーターにより、ブラッ
クパネル温度６３℃の条件で、１０００時間照射後の試
験片（厚さ０．１２５インチ）について、測色計による
色差（ΔＥ）を測定した。 Flame Retardancy Test According to the UL-94 method, a 1/16 inch thick test piece was evaluated for flame retardancy. Weather resistance test The color difference (ΔE) of a test piece (thickness 0.125 inch) after irradiation for 1000 hours under a condition of a black panel temperature of 63 ° C. was measured by a colorimeter using a sunshine weather o-meter.
【００２９】[0029]
【表１】 [Table 1]
【００３０】注１ 呉羽化学社製「クレハＫＭ−３３
４」 注２ 住友ダウ社製「ＰＳＮ−６２７」 注３ 大阪曹達社製「ダイソラックＨ−１３５」 注４ 住友ダウ社製「Ｓ−３７０２」* 1 Kureha KM-33 manufactured by Kureha Chemical Co., Ltd.
4 "Note 2 Sumitomo Dow" PSN-627 "Note 3 Osaka Soda" Daisolac H-135 "Note 4 Sumitomo Dow" S-3702 "
【００３１】注５ 旭電化社製「ＬＡ−６８」（一般式
(1) 中、ＲはＨ、平均分子量１９００） 注６ 旭電化社製「ＬＡ−６３」（一般式(1) 中、Ｒは
ＣＨ3 平均分子量２０００） 注７ 吉富製薬製「トミソーブ７７」Note 5 "LA-68" manufactured by Asahi Denka Co., Ltd. (general formula
(1), R is H, average molecular weight 1900) Note 6 Asahi Denka Co., Ltd. "LA-63" in (Formula (1), R represents CH 3 average molecular weight 2000) Note 7, manufactured by Yoshitomi Pharmaceutical Co. "Tomisobu 77"
【化４】 注８ 2-(2'-ヒドロキシ-3'-t-ブチル-5'-メチルフェニ
ル)-5-クロロベンゾトリアゾール、吉富製薬製「トミソ
ーブ６００」[Chemical 4] Note 8 2- (2'-hydroxy-3'-t-butyl-5'-methylphenyl) -5-chlorobenzotriazole, Yoshitomi Pharmaceutical "Tomisorb 600"
【００３２】[0032]
【発明の効果】本発明の塩化ビニル系樹脂組成物の構成
は上述の通りであるから、熱流動性がよく、成形性が優
れており、得られた成形体は耐衝撃性、耐熱性、難燃
性、耐薬品性、耐水性に優れかつ耐熱性特に耐光性が優
れている。The constitution of the vinyl chloride resin composition of the present invention is as described above, so that it has good heat fluidity and excellent moldability, and the obtained molded product has impact resistance, heat resistance, Excellent flame resistance, chemical resistance, water resistance, and heat resistance, especially light resistance.
【００３３】従って、雨樋、デッキ材、波板、窓枠等の
建材等屋外で長期間にわたって使用される成形品のみな
らず、オフィスオートメーション機器のハウジングや自
動車の内部部品等に好適に使用できる。Therefore, it can be suitably used not only for molded articles such as rain gutters, deck materials, corrugated boards, building materials such as window frames that are used outdoors for a long time, but also for housings of office automation equipment and internal parts of automobiles. .
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０８Ｋ 5/3432 ＫＨＬ 7242−4Ｊ //(Ｃ０８Ｌ 27/06 33:00 7921−4Ｊ 51:06 7142−4Ｊ 23:28 7107−4Ｊ 25:12） 9166−4Ｊ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical display location C08K 5/3432 KHL 7242-4J // (C08L 27/06 33:00 7921-4J 51:06 7142 -4J 23:28 7107-4J 25:12) 9166-4J
Claims (1)
塩化ビニル系樹脂４０〜７０Wt％、(b) アクリルゴム、
ＡＥＳ樹脂及び塩素化ポリエチレンよりなる群から選ば
れた一種以上の衝撃改良剤１０〜４０Wt％、(c) スチレ
ン系化合物とシアン化ビニル化合物が共重合されてなる
スチレン系共重合体１５〜４０Wt％及び(d) 一般式(1)
で表されるヒンダードアミン系光安定剤０．０１〜５Wt
％からなる塩化ビニル系樹脂組成物。 【化１】 1. A vinyl chloride resin having an average chlorine content of 60 to 70 wt%, 40 to 70 wt%, and (b) an acrylic rubber,
10-40 wt% of one or more impact modifiers selected from the group consisting of AES resin and chlorinated polyethylene, and (c) 15-40 wt% styrene copolymer obtained by copolymerizing a styrene compound and a vinyl cyanide compound. And (d) general formula (1)
Hindered amine light stabilizer represented by 0.01 to 5 Wt
% Vinyl chloride resin composition. [Chemical 1]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4299784A JPH06145450A (en) | 1992-11-10 | 1992-11-10 | Vinyl chloride-based resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4299784A JPH06145450A (en) | 1992-11-10 | 1992-11-10 | Vinyl chloride-based resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06145450A true JPH06145450A (en) | 1994-05-24 |
Family
ID=17876907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4299784A Pending JPH06145450A (en) | 1992-11-10 | 1992-11-10 | Vinyl chloride-based resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06145450A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016037542A (en) * | 2014-08-07 | 2016-03-22 | アキレス株式会社 | Substrate for printed matter protective film |
| JP2019214634A (en) * | 2018-06-11 | 2019-12-19 | 日本カーバイド工業株式会社 | Resin composition and molding film |
-
1992
- 1992-11-10 JP JP4299784A patent/JPH06145450A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016037542A (en) * | 2014-08-07 | 2016-03-22 | アキレス株式会社 | Substrate for printed matter protective film |
| JP2019214634A (en) * | 2018-06-11 | 2019-12-19 | 日本カーバイド工業株式会社 | Resin composition and molding film |
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