JPH06134910A - Water disintegrable nonwoven fabric and laminate thereof - Google Patents
Water disintegrable nonwoven fabric and laminate thereofInfo
- Publication number
- JPH06134910A JPH06134910A JP4312979A JP31297992A JPH06134910A JP H06134910 A JPH06134910 A JP H06134910A JP 4312979 A JP4312979 A JP 4312979A JP 31297992 A JP31297992 A JP 31297992A JP H06134910 A JPH06134910 A JP H06134910A
- Authority
- JP
- Japan
- Prior art keywords
- water
- sheet
- nonwoven fabric
- polyvinyl alcohol
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、水崩壊性不織布および
その積層物に関し、更に詳しくは、生理用品、紙おむつ
等の衛生用品の、使用時における限定された量の水また
は水溶液との接触においては、溶解による前記素材の破
壊および裏面への浸透現象がなく、吸収能力以上の量の
水中においては、崩壊して放流可能な状態となる水崩壊
性不織布およびその積層物に関する。更に、使用済み後
の廃棄物処理方法としては、前記した下水中への放流処
理の外に、地中での埋没による微生物の分解法、また
は、天然の繊維と殆ど同じ4000〜5000kcal
の低い燃焼カロリーであることから、既存の焼却炉によ
る焼却法が可能である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-disintegratable non-woven fabric and a laminate thereof, and more particularly, to contacting sanitary products such as sanitary products and disposable diapers with a limited amount of water or aqueous solution during use. The present invention relates to a water-disintegratable nonwoven fabric and a laminate thereof, which is free from the destruction of the above-mentioned material due to dissolution and the phenomenon of permeation to the back surface and is disintegrated into a state capable of being discharged in water in an amount exceeding the absorption capacity. Further, as a method for treating waste after it is used, in addition to the above-mentioned discharge treatment into sewage, a method for degrading microorganisms by burial in the ground, or 4000 to 5000 kcal which is almost the same as natural fiber.
Since it has a low calorific value, it can be incinerated by existing incinerators.
【0002】[0002]
【従来の技術】従来、使用時の限定された量の水との接
触では、素材の溶解による製品の構造破壊を生ずること
なく、商品としての機能を有し、吸収能力以上の量の水
中においては崩壊して放流可能となり、更に量的に多い
成分の微生物による生分解も可能となるポリマー・シス
テムは存在しなかった。従って、生理用品、紙おむつ等
の衛生用品の基本となる共通の構造は、 (1)表面の保護と皮膚接触面の乾燥状態維持のための
ポリエチレン製ネット。 (2)水分または血液等の吸収のための吸収層。 (3)衣服への浸透を防止するためのポリエチレン製フ
ィルム。 の3層からなり、特にポリエチレン製ネット、フィルム
は崩壊しないので、前記衛生用品全体が排泄物を吸収し
た非常に不潔な状態で、一般の家庭ゴミと共に運搬、処
理されている状態で、特に運搬時、包装袋の破裂による
排泄物の飛散は、作業員に対する衛生上の問題ともな
り、社会的関心をひき始めた。2. Description of the Related Art Conventionally, when contacted with a limited amount of water at the time of use, it has a function as a product without causing structural destruction of the product due to dissolution of raw materials, There was no polymer system that could disintegrate and be released, and that could also be biodegraded by microorganisms in large amounts. Therefore, the basic common structure of sanitary items such as sanitary items and disposable diapers is (1) a polyethylene net for protecting the surface and keeping the skin contact surface dry. (2) An absorption layer for absorbing water or blood. (3) A polyethylene film for preventing penetration into clothes. Since the polyethylene net and film do not disintegrate, the whole sanitary article is very filthy and absorbs excrement, and is transported and treated together with general household waste, especially when transported. At that time, the scattering of excrement due to the rupture of the packaging bag became a hygiene problem for workers and began to attract social attention.
【0003】[0003]
【発明が解決しようとする課題】前記したように、従
来、市販されている生理用品、紙おむつ等の衛生用品
は、それらの使用状況から要求される機能を満足させる
ために、既存の構造をとっているものであるが、この要
因は、前記したような条件を満足させるポリマー・シス
テムが見出されていなかったからである。従って本発明
は、前記した生理用品、紙おむつ等の衛生用品としての
機能を満足し、同時に廃棄処理の問題を解決し、最終的
には大部分の成分が微生物で生分解され、下水処理場
で、処理可能な水崩壊性不織布積層物を提供することを
目的とする。As described above, sanitary products such as sanitary products and disposable diapers that are commercially available in the past have an existing structure in order to satisfy the functions required by their usage. However, the reason for this is that no polymer system satisfying the above-mentioned conditions has been found. Therefore, the present invention satisfies the above-mentioned functions as sanitary products such as sanitary products and disposable diapers, and at the same time solves the problem of waste treatment, and finally, most of the components are biodegraded by microorganisms, and at the sewage treatment plant. An object of the present invention is to provide a water-disintegratable nonwoven fabric laminate that can be treated.
【0004】[0004]
【課題を解決するための手段】本発明に従えば、ポリエ
ステルまたはポリオレフィン繊維シートに、実質的に全
面に小孔を有するポリビニルアルコール・フィルムを接
着させてなる水崩壊性不織布および、この不織布と、実
質的に小孔を有しない連続した平面を有するポリビニル
アルコール・フィルムを、ポリエステルまたはポリオレ
フィン繊維シートに接着させてなる水崩壊性不織布との
間に、高吸水性ポリマーを内蔵するパルプ繊維シートと
の積層物が提供される。According to the present invention, a water-disintegratable non-woven fabric comprising a polyester or polyolefin fiber sheet adhered to a polyvinyl alcohol film having pores on substantially the entire surface thereof, and this non-woven fabric, Between a polyvinyl alcohol film having a continuous flat surface having substantially no pores and a water-disintegratable non-woven fabric obtained by adhering it to a polyester or polyolefin fiber sheet, and a pulp fiber sheet containing a super absorbent polymer. A laminate is provided.
【0005】本発明の第一の態様に従えば、鹸化度80
〜88%、平均重合度500〜1000のポリビニルア
ルコールをT−ダイ方式で厚さ50〜100ミクロンに
調製し、更に全面に直径1〜3mmの小孔を加工したフ
ィルムをポリエステルまたはポリオレフィン繊維シート
に加熱、接着させることにより、水および水溶液を容易
に透過する水崩壊性のポリエステルまたはポリオレフィ
ン繊維不織布を得ることができる。本発明で得られる不
織布は、水および水溶液を容易に透過し、しかもポリエ
ステルまたはポリオレフィン繊維の有する撥水性のため
に、水および水溶液との接触においても乾燥した状態が
得られるので、非常に興味ある用途が提供される。即
ち、既存の紙おむつ使用の時は、大便を紙おむつ自体で
包み、それを一般の家庭ゴミと一緒に運搬、処理すると
いう、極めて非衛生的な廃棄処理方法がとられている
が、本発明によって得られる水崩壊性不織布を既存の紙
おむつの内側に大便用ライナーとして挿入使用する時
は、小便は容易に透過して紙おむつに吸収されるが、大
便はライナーとして使用した本発明の薄い水崩壊性不織
布上に残るので、包んでトイレットの水中に投入すれ
ば、全体がスラリー状となり、放流可能となる。更に使
用した紙おむつは、汚れる迄、本発明の第一態様の水崩
壊性不織布を挿入して反復使用することができる。紙お
むつは使用不能となれば、一般の家庭ゴミと一緒に廃棄
処理することが可能であり、衛生上の問題を解決するこ
とができる。According to the first aspect of the invention, the degree of saponification is 80
-88%, polyvinyl alcohol having an average degree of polymerization of 500-1000 was prepared to a thickness of 50-100 microns by T-die method, and a film having small holes with a diameter of 1-3 mm was processed on the entire surface of a polyester or polyolefin fiber sheet. By heating and adhering, a water-disintegratable polyester or polyolefin fiber nonwoven fabric that easily permeates water and an aqueous solution can be obtained. The nonwoven fabric obtained in the present invention is very interesting because it easily permeates water and aqueous solution, and due to the water repellency of the polyester or polyolefin fiber, a dry state can be obtained even in contact with water and aqueous solution. Applications are provided. That is, when using an existing disposable diaper, a very unhygienic disposal method is used, in which stool is wrapped in the disposable diaper itself and is transported and treated together with general household waste. When the resulting water-disintegratable nonwoven fabric is inserted into an existing paper diaper and used as a stool liner, urine is easily permeated and absorbed by the paper diaper, but stool is used as a liner for thin water-disintegration of the present invention. Since it remains on the non-woven fabric, if it is wrapped and put in the water of the toilet, the whole becomes a slurry and can be discharged. Further, the used paper diaper can be repeatedly used by inserting the water-disintegrating nonwoven fabric of the first aspect of the present invention until it becomes soiled. If the disposable diaper becomes unusable, it can be disposed of together with general household waste, which can solve the problem of hygiene.
【0006】本発明の第二の態様によれば、本発明の第
一の態様で得られるポリエステルまたはポリオレフィン
繊維水崩壊不織布と、実質的に小孔を有しないポリビニ
ルアルコール・フィルムを、ポリエステルまたはポリオ
レフィン繊維シートに加熱、接着してなる水崩壊性不織
布とを、ポリビニルアルコール・フィルムの面を内側に
して重ね合わせ、その中間に、高吸水性ポリマーを含有
するパルプ繊維シートを挿入して、周辺を加熱、接着さ
せることにより、既存の生理帯、紙おむつの機能を有
し、しかも、使用後、トイレットの水中に投入してスラ
リー状に崩壊し、放流可能となる水崩壊性不織布積層物
を得ることができる。本発明の積層物は、小孔を有する
ポリビニルアルコール・フィルムの不織布の面が水分の
吸収、透過の効果を有し、小孔を有しないポリビニルア
ルコール・フィルムの不織布の面が、防漏性の効果を示
し、しかも、ポリビニルアルコール・フィルム自体が積
層物の接着剤となり得るものである。According to the second aspect of the present invention, the polyester or polyolefin fiber water-disintegrating nonwoven fabric obtained in the first aspect of the present invention and a polyvinyl alcohol film having substantially no pores are mixed with polyester or polyolefin. A water-disintegratable non-woven fabric formed by heating and adhering to a fibrous sheet is overlaid with the surface of the polyvinyl alcohol film inside, and a pulp fibrous sheet containing a super absorbent polymer is inserted in the middle, and the periphery is To obtain a water-disintegratable non-woven fabric laminate which has the functions of an existing menstrual band and a disposable diaper by heating and adhering, and is put into the water of a toilet after use to be disintegrated into a slurry state and can be discharged. You can In the laminate of the present invention, the non-woven fabric surface of the polyvinyl alcohol film having small pores has an effect of absorbing and transmitting water, and the non-woven fabric surface of the non-woven fabric of polyvinyl alcohol film has a leakproof property. It is effective, and the polyvinyl alcohol film itself can be an adhesive for the laminate.
【0007】[0007]
【実施例】次に実施例で本発明を具体的に説明するが、
本発明をこれらの実施例に限定するものでないことはい
うまでもない。The present invention will be described in detail with reference to the following examples.
It goes without saying that the present invention is not limited to these examples.
【0008】実施例1 鹸化度88%、平均重合度500のポリビニルアルコー
ル100重量部、平均分子量400のポリエチレングリ
コール15重量部の混合物を加熱、溶融してT−ダイ方
式により厚さ50ミクロンのフィルムを得た。このフィ
ルムの全面に、直径約2mmの小孔を5mmの間隔であ
けて目付50g/m2 のポリエステル繊維シートに、加
熱、接着させて水分透過性のすぐれた水崩壊性不織布を
得た。実施例1の不織布の構造を図1に示す。この不織
布のポリビニルアルコール・フィルムの面を既存の紙お
むつ内面の身体に接触する部分に挿入して実用試験を行
った。小便のみの場合は、小便は、小孔を通して急速に
紙おむつの吸収層に吸収されて表面は乾燥状態となり、
従来と同じように原型を保って使用可能であった。大便
の場合は、前記不織布で包み、トイレットの水中に投入
すると、スラリー状に崩壊して放流することができ、使
用した紙おむつは再度使用可能な程度に汚れを防ぐこと
が可能であった。勿論、一度、使用済みの紙おむつは、
加圧下においても水分を放出することがないので、一般
の家庭ゴミと同時に、運搬、処理することが可能であ
る。本実施例において、ポリエステル繊維シートの代り
にポリエチレン繊維シートを使用したが、紙おむつの大
便用ライナーとして前記と同等の効果が得られた。Example 1 A mixture of 100 parts by weight of polyvinyl alcohol having a saponification degree of 88% and an average degree of polymerization of 500 and 15 parts by weight of polyethylene glycol having an average molecular weight of 400 is heated and melted to form a film having a thickness of 50 μm by a T-die method. Got Small holes having a diameter of about 2 mm were opened at intervals of 5 mm on the entire surface of this film, and heated and bonded to a polyester fiber sheet having a basis weight of 50 g / m 2 to obtain a water-disintegratable non-woven fabric excellent in water permeability. The structure of the nonwoven fabric of Example 1 is shown in FIG. A practical test was conducted by inserting the surface of the polyvinyl alcohol film of the non-woven fabric into the portion of the existing inner surface of the disposable diaper that comes into contact with the body. In the case of only urine, the urine is rapidly absorbed by the absorbent layer of the disposable diaper through the small holes and the surface becomes dry,
It was possible to use it while maintaining the original shape as in the past. In the case of stool, when wrapped with the non-woven fabric and put in the water of a toilet, it could be collapsed into a slurry and discharged, and the used diaper could be prevented from being soiled to the extent that it could be reused again. Of course, once used diapers are
Since it does not release water even under pressure, it can be transported and treated at the same time as general household waste. In this example, a polyethylene fiber sheet was used instead of the polyester fiber sheet, but the same effect as the above was obtained as a stool liner for a disposable diaper.
【0009】実施例2 実施例1に示した、実質的に全面に小孔を有するポリビ
ニルアルコール・フィルムを加熱、接着させた水崩壊性
不織布、高吸水性ポリマーを含有するパルプ繊維シート
および小孔を有しない連続した平面を有するポリビニル
アルコール・フィルムを加熱、接着させた水崩壊性不織
布を図2のように重ねて、周辺を加熱、接着させて切断
する。このような操作により、生理帯、紙おむつを調製
した。このような積層構造を有する生理帯、紙おむつ
は、既存の商品と同じような機能を有し、トイレットの
水中に投入する時は、繊維のスラリー状に崩壊して放流
可能の状態を示した。血液、小便等の液体は図2に示し
た(2)のポリビニルアルコール・フィルムの小孔を通
して、急速に(3)のパルプ繊維シートに吸収され、
(4)のポリビニルアルコール・フィルムの溶解を防
ぎ、完全な防漏性を示した。液体の吸収速度が大で、表
面が疎水性の繊維であるため、使用中、表面を乾燥状態
に保つことが可能である。Example 2 A water-disintegratable non-woven fabric obtained by heating and adhering a polyvinyl alcohol film having pores on substantially the entire surface thereof as shown in Example 1, a pulp fiber sheet containing a super absorbent polymer, and pores. A water-disintegratable nonwoven fabric obtained by heating and adhering a polyvinyl alcohol film having a continuous flat surface without heat treatment is stacked as shown in FIG. By such an operation, a menstrual band and a disposable diaper were prepared. The sanitary belt and the disposable diaper having such a laminated structure have the same functions as existing products, and when they are put into the water of a toilet, they are collapsed into a slurry of fibers and can be discharged. Liquids such as blood and urine are rapidly absorbed by the pulp fiber sheet of (3) through the small holes of the polyvinyl alcohol film of (2) shown in FIG.
The polyvinyl alcohol film of (4) was prevented from being dissolved and showed complete leakproofness. Since the liquid has a high absorption rate and the surface is a hydrophobic fiber, it is possible to keep the surface dry during use.
【図1】本発明の水崩壊性不織布の断面図である。FIG. 1 is a cross-sectional view of a water-disintegratable nonwoven fabric of the present invention.
【図2】水崩壊性不織布を用いた積層物の断面図であ
る。FIG. 2 is a cross-sectional view of a laminate using a water-disintegratable nonwoven fabric.
1,5 ポリエステル繊維またはポリオレフィン繊維
シート 2 小孔を全面に有するポリビニルアルコール・フィ
ルム 3 高吸水性ポリマーを含有するパルプ繊維シート 4 ポリビニルアルコール・フィルム1,5 Polyester fiber or polyolefin fiber sheet 2 Polyvinyl alcohol film having small holes all over the surface 3 Pulp fiber sheet containing superabsorbent polymer 4 Polyvinyl alcohol film
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 D04H 1/42 T 7199−3B K 7199−3B 1/58 B 7199−3B D06M 15/333 2119−3B A41B 13/02 E 7603−4C A61F 13/18 307 G D06M 15/333 (72)発明者 小島 四郎 東京都中央区京橋二丁目3番13号東洋イン キ製造株式会社内 (72)発明者 遠藤 満 神奈川県川崎市中原区下小田中六丁目5番 19号Front page continuation (51) Int.Cl. 5 Identification code Office reference number FI Technical display location D04H 1/42 T 7199-3B K 7199-3B 1/58 B 7199-3B D06M 15/333 2119-3B A41B 13 / 02 E 7603-4C A61F 13/18 307 G D06M 15/333 (72) Inventor Shiro Kojima 2-3-13 Kyobashi, Chuo-ku, Tokyo Toyo Inki Manufacturing Co., Ltd. (72) Inventor Mitsuru Endo Kanagawa Prefecture 6-5-19 Shimootachu, Nakahara-ku, Kawasaki-shi
Claims (3)
シートに、実質的に全面に小孔を有するポリビニルアル
コール・フィルムを接着させてなることを特徴とする水
崩壊性不織布。1. A water-disintegratable non-woven fabric comprising a polyester or polyolefin fiber sheet adhered with a polyvinyl alcohol film having pores on substantially the entire surface thereof.
シートに実質的に全面に小孔を有するポリビニルアルコ
ール・フィルムを接着させてなるシートと、ポリエステ
ルまたはポリオレフィン繊維シートに実質的に小孔を有
しないポリビニルアルコール・フィルムを接着させてな
るシートとの間に、高吸水性ポリマーを含有するパルプ
繊維シートを積層し、周辺を接着してなることを特徴と
する水崩壊性不織布積層物。2. A sheet obtained by adhering a polyvinyl alcohol film having pores substantially all over the polyester or polyolefin fiber sheet, and a polyvinyl alcohol film having substantially no pores in the polyester or polyolefin fiber sheet. A water-disintegratable non-woven fabric laminate, characterized in that a pulp fiber sheet containing a superabsorbent polymer is laminated between the sheet and the sheet obtained by adhering the sheet, and the periphery is adhered.
アルコール・フィルムを張り合わせた不織布の面を、水
溶液の吸収面とする請求項1または2に記載の水崩壊性
不織布およびその積層物。3. The water-disintegratable nonwoven fabric according to claim 1 or 2, wherein the surface of the nonwoven fabric obtained by laminating a polyvinyl alcohol film having pores on substantially the entire surface is an aqueous solution absorbing surface.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31297992A JP3209591B2 (en) | 1992-10-28 | 1992-10-28 | Water disintegrable nonwoven laminate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31297992A JP3209591B2 (en) | 1992-10-28 | 1992-10-28 | Water disintegrable nonwoven laminate |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06134910A true JPH06134910A (en) | 1994-05-17 |
JP3209591B2 JP3209591B2 (en) | 2001-09-17 |
Family
ID=18035782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP31297992A Expired - Lifetime JP3209591B2 (en) | 1992-10-28 | 1992-10-28 | Water disintegrable nonwoven laminate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3209591B2 (en) |
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WO2018152272A1 (en) | 2017-02-16 | 2018-08-23 | The Procter & Gamble Company | Absorbent articles with substrates having repeating patterns of apertures comprising a plurality of repeat units |
KR102415020B1 (en) * | 2017-12-22 | 2022-07-01 | 주식회사 이지트로닉스 | Power semiconductor mounting structure |
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JPS59125973A (en) * | 1982-09-21 | 1984-07-20 | 株式会社クラレ | Nonwoven fabric good in water absorbability and water holdability and production thereof |
JPH01160550A (en) * | 1987-12-17 | 1989-06-23 | Nippon Synthetic Chem Ind Co Ltd:The | Filth receiving container |
JPH03162956A (en) * | 1989-08-29 | 1991-07-12 | Dainippon Printing Co Ltd | Base material with resin-coated layer |
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JPS59125973A (en) * | 1982-09-21 | 1984-07-20 | 株式会社クラレ | Nonwoven fabric good in water absorbability and water holdability and production thereof |
JPH01160550A (en) * | 1987-12-17 | 1989-06-23 | Nippon Synthetic Chem Ind Co Ltd:The | Filth receiving container |
JPH03162956A (en) * | 1989-08-29 | 1991-07-12 | Dainippon Printing Co Ltd | Base material with resin-coated layer |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999026672A1 (en) * | 1997-11-25 | 1999-06-03 | Kimberly-Clark Worldwide, Inc. | Flushable release liners and methods of making the same |
WO1999026671A1 (en) * | 1997-11-25 | 1999-06-03 | Kimberly-Clark Worldwide, Inc. | A flushable release liner comprising a release coating on a water-sensitive film |
GB2347868A (en) * | 1997-11-25 | 2000-09-20 | Kimberly Clark Co | A flushable release liner comprising a release coating on a water-sensitive film |
GB2347867A (en) * | 1997-11-25 | 2000-09-20 | Kimberly Clark Co | Flushable release liners and methods of making the same |
GB2347867B (en) * | 1997-11-25 | 2002-08-21 | Kimberly Clark Co | Flushable release liners and methods of making the same |
GB2347868B (en) * | 1997-11-25 | 2002-11-27 | Kimberly Clark Co | A flushable release liner comprising a release coating on a water-sensitive film |
JPH11290376A (en) * | 1998-04-08 | 1999-10-26 | Oji Paper Co Ltd | Disposable diaper |
JP2001170099A (en) * | 1999-10-04 | 2001-06-26 | Ferikku Kk | Air-permeable sheet and heating element structure using the same |
EP1118314A2 (en) * | 2000-01-06 | 2001-07-25 | Uni-Charm Corporation | Water-decomposable absorbent article |
US7271113B2 (en) | 2002-02-13 | 2007-09-18 | Fiberweb Corovin Gmbh | Composite with an absorbent layer |
JP2005291658A (en) * | 2004-04-02 | 2005-10-20 | Gas & Power Investment:Kk | Method of preventing scattering of liquid droplet, forcible draft cooling tower, and method and device of measuring scattering quantity of liquid droplet |
US7928180B2 (en) | 2005-06-30 | 2011-04-19 | Mitsui Chemicals, Inc. | Biodegradable polymer, production method thereof, molded product thereof, and use thereof |
Also Published As
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