JPH06107456A - Production of light transmissive yttrium-aluminum-garnet sintered body - Google Patents
Production of light transmissive yttrium-aluminum-garnet sintered bodyInfo
- Publication number
- JPH06107456A JPH06107456A JP4257695A JP25769592A JPH06107456A JP H06107456 A JPH06107456 A JP H06107456A JP 4257695 A JP4257695 A JP 4257695A JP 25769592 A JP25769592 A JP 25769592A JP H06107456 A JPH06107456 A JP H06107456A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- sintered body
- calcined
- firing
- yag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、透光性に優れた透光性
イットリウム−アルミニウム−ガーネット（以下、ＹＡ
Ｇという）焼結体の製造方法に関するもので、特に、可
視光領域の直線透過率が７０％を達成することができる
透光性ＹＡＧ焼結体の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a translucent yttrium-aluminum-garnet (hereinafter referred to as YA) having excellent translucency.
The present invention relates to a method for producing a sintered body (referred to as G), and particularly to a method for producing a translucent YAG sintered body capable of achieving a linear transmittance of 70% in the visible light region.
【０００２】[0002]
【従来技術】従来、ＹＡＧ（Ｙ3 Ａｌ5 Ｏ12) は結晶型
が立方晶であるため、粒界散乱が起こりにくく透明体と
して良好であるため、各種の製法により透光性焼結体を
得る試みがなされている。2. Description of the Related Art Conventionally, since YAG (Y 3 Al 5 O 12 ) has a cubic crystal type, grain boundary scattering hardly occurs and it is good as a transparent body. Attempts to get are made.
【０００３】このようなＹＡＧは、単結晶により作成す
る方法、Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3粉末をＨＩＰ処理や
ホットプレス焼成する方法、イットリウムイオンとアル
ミニウムイオンの尿素沈澱法等により製造されている
（例えば、特公昭５４−８３６９号公報）。Such YAG is produced by a method of producing a single crystal, a method of HIPing Al 2 O 3 powder and Y 2 O 3 powder or hot press firing, a urea precipitation method of yttrium ion and aluminum ion, and the like. (For example, Japanese Patent Publication No. 54-8369).
【０００４】[0004]
【発明が解決しようとする問題点】しかしながら、単結
晶合成では高価であり、任意の形状に製作することが困
難であるという問題があった。また、ＨＩＰ処理による
場合には装置が大きくなり、生産性が良くないという問
題があった。さらに、ホットプレスにより製造する場合
には、成形型に用いるカーボンから焼結体に炭素が入
り、透明度が下がるという欠点があった。However, there has been a problem that the single crystal synthesis is expensive and it is difficult to manufacture it into an arbitrary shape. Further, in the case of HIP processing, there is a problem that the apparatus becomes large and the productivity is not good. Further, in the case of manufacturing by hot pressing, there is a drawback that carbon enters the sintered body from the carbon used for the molding die and the transparency decreases.
【０００５】また、尿素沈澱法では、アンモニア蒸気の
処理が必要であり、環境に悪影響を与える虞があった。In addition, the urea precipitation method requires treatment of ammonia vapor, which may adversely affect the environment.
【０００６】[0006]
【問題点を解決するための手段】本発明者等は、このよ
うな問題点に対して充分に検討を行った結果、Ａｌ2 Ｏ
3 粉末とＹ2 Ｏ3 粉末を混合した後、仮焼し、粉砕した
ものを原料粉末として使用することで、従来のようなＨ
ＩＰ処理、ホットプレス、尿素沈澱法を用いなくても良
好な透光性焼結体を得ることができることを見出し、本
発明に至った。[Means for Solving the Problems] The inventors of the present invention have sufficiently studied such problems, and as a result, Al 2 O
After mixing 3 powders and Y 2 O 3 powders, calcining and crushing them, and using them as raw material powder,
The present inventors have found that a good light-transmitting sintered body can be obtained without using IP treatment, hot pressing, or urea precipitation, and have reached the present invention.
【０００７】即ち、本発明の透光性ＹＡＧ焼結体の製造
方法は、純度がそれぞれ９９．９％以上のＡｌ2 Ｏ3 粉
末とＹ2 Ｏ3 粉末を混合した後、１０００〜１６００℃
で仮焼し、これを粉砕して原料粉末とし、この原料粉末
を所定形状に成形した後、還元性雰囲気中において、１
６００〜１９００℃の温度で焼成する方法である。That is, according to the method of manufacturing the translucent YAG sintered body of the present invention, the Al 2 O 3 powder and the Y 2 O 3 powder each having a purity of 99.9% or more are mixed, and then 1000 to 1600 ° C.
After calcination in a crushed state, it is pulverized into a raw material powder, and the raw material powder is molded into a predetermined shape.
This is a method of firing at a temperature of 600 to 1900 ° C.
【０００８】ここで、純度がそれぞれ９９．９％以上の
Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末を使用するのは、純度が
９９．９％よりも低いと焼結体中に不純物が存在し、そ
の透光性が低下するからである。Here, the use of Al 2 O 3 powder and Y 2 O 3 powder each having a purity of 99.9% or more is because impurities are present in the sintered body when the purity is lower than 99.9%. However, the translucency is reduced.
【０００９】また、Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末の混
合粉体を１０００〜１６００℃で仮焼するのは、この仮
焼によりある程度（１０〜５０％程度）のＹＡＧ化を生
じさせ、ＹＡＧの異常粒成長を抑制し、活性化を保持す
るためである。よって、仮焼温度が１０００℃よりも低
いとＹＡＧ化が生じ難く、１６００℃よりも高いと活性
化が低下し、緻密な焼結体を作成することができず、或
いは、粉砕に長時間を要するようになるからである。そ
して、仮焼により、Ａｌ2 Ｏ3 粉末とＹ2 Ｏ３粉末の混
合粉末からＹＡＭへ、ＹＡＭからＹＡＧへ結晶が変化す
るが、仮焼することにより、ＹＡＭからＹＡＧへ変化す
る際の体積膨張を生じさせ、成形後の焼成では体積膨張
を生じさせずに焼結させ、これにより、焼結体中のボイ
ドや欠陥の発生を抑制し、均一な焼結体を作成するため
である。Further, calcination of the mixed powder of Al 2 O 3 powder and Y 2 O 3 powder at 1000 to 1600 ° C. causes YAG formation to some extent (about 10 to 50%). , YAG to suppress abnormal grain growth and maintain activation. Therefore, if the calcination temperature is lower than 1000 ° C., YAG formation is unlikely to occur, and if it is higher than 1600 ° C., the activation is decreased, and a dense sintered body cannot be prepared, or crushing takes a long time. Because it will cost you. Then, the calcination changes the crystals from the mixed powder of Al 2 O 3 powder and Y 2 O 3 powder to YAM and from YAM to YAG, but the calcination changes the volume expansion when changing from YAM to YAG. This is because sintering is performed without causing volume expansion in firing after forming, thereby suppressing the generation of voids and defects in the sintered body and creating a uniform sintered body.
【００１０】また、１６００〜１９００℃の温度で焼成
するのは、１６００℃よりも低い温度で焼成すると、焼
結が不十分であり緻密化せず透光性が低下するからであ
り、１９００℃よりも高い温度で焼成すると、異常粒成
長が生じ、気孔を粒内に取り込んでしまい透光性が低下
するからである、また、ＹＡＧの蒸発が生じ均質な焼結
体を作成することができなくなるからである。The firing at a temperature of 1600 to 1900 ° C. is because firing at a temperature lower than 1600 ° C. causes insufficient sintering, does not densify, and lowers light transmission. This is because if the firing is performed at a higher temperature, abnormal grain growth occurs, the pores are taken into the grains, and the translucency is reduced. Further, evaporation of YAG occurs and a homogeneous sintered body can be produced. Because it will disappear.
【００１１】さらに、還元性雰囲気中で焼成するのは、
大気中に比べＨ２ やＮ2 は拡散が速いため、焼結体の
緻密化を容易に達成することができるからである。真空
焼成も同様な理由で良好である。Further, firing in a reducing atmosphere is
This is because the diffusion of H 2 and N 2 is faster than that in the atmosphere, so that the sintered body can be easily densified. Vacuum firing is also good for the same reason.
【００１２】本発明のＹＡＧ焼結体は、例えば、それぞ
れ純度が９９．９％以上、ＢＥＴ比表面積５ｍ2 ／ｇ以
上のＡｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末を、Ａｌ2 Ｏ3 ：Ｙ
2 Ｏ3 が０．４３：０．５７となるように調製し、混合
した後、１０００〜１６００℃で０．５時間以上、好ま
しくは２時間程度仮焼する。仮焼は、完全にＹＡＧ化す
る前の段階、即ち、ＹＡＭやＹＡＧが混在した状態まで
反応させる。Ａｌ2 Ｏ3 粉末，Ｙ2 Ｏ3 粉末の粒径は、
ＹＡＧの異常粒成長を防止するためそれぞれ２μｍ以下
であることが好ましい。The YAG sintered body of the present invention comprises, for example, Al 2 O 3 powder and Y 2 O 3 powder each having a purity of 99.9% or more and a BET specific surface area of 5 m 2 / g or more, Al 2 O 3 : Y
2 O 3 is prepared to be 0.43: 0.57, mixed, and then calcined at 1000 to 1600 ° C. for 0.5 hour or more, preferably about 2 hours. The calcination is performed until the stage before complete YAG conversion, that is, the state where YAM and YAG are mixed. The particle size of Al 2 O 3 powder and Y 2 O 3 powder is
In order to prevent abnormal grain growth of YAG, each is preferably 2 μm or less.
【００１３】そして、これを粉砕して原料粉末とし、こ
の原料粉末に所定の溶媒を添加し、これをポットミル，
回転ミル等で混合粉砕する。仮焼粉末の粒子は２μｍ以
下、好ましくは１μｍ以下であることが望ましい。この
後、これを乾燥した後、８０メッシュパスで整粒する。
これを所望の成形手段、例えば、金型プレス，冷間静水
圧プレス，押出し成形等により任意の形状に成形する。
例えば、金型プレスによる場合には、２．５ｔｏｎ／ｃ
ｍ3 以上で行い、生成形体の密度をできるだけ上げる。
成形体の生密度は、焼結体中のボイドを最小限に抑制す
るため２．１ｇ／ｃｍ3 以上となることが好ましい。Then, this is pulverized into a raw material powder, a predetermined solvent is added to the raw material powder, and this is subjected to a pot mill,
Mix and pulverize with a rotary mill. The particles of the calcined powder are desirably 2 μm or less, preferably 1 μm or less. After that, this is dried and then sized by an 80-mesh pass.
This is molded into a desired shape by a desired molding means such as a die press, a cold isostatic press, an extrusion molding and the like.
For example, when using a die press, 2.5 ton / c
m 3 or more to increase the density of the green body as much as possible.
The green density of the molded body is preferably 2.1 g / cm 3 or more in order to minimize voids in the sintered body.
【００１４】そして、焼成を真空度が１×１０-2torr以
上である真空雰囲気において、１６００〜１９００℃で
２〜１０時間行う。真空度は１×１０-3torr以上が好ま
しい。昇温速度は、ある一定温度、例えば１６５０℃ま
では１時間当たり５０〜３００℃が好ましく、特に１時
間当たり２００〜３００℃が好ましい。この後、粒径を
均一化するため２〜２０時間保持する。そして、最高温
度までは１時間当たり１００℃以下、好ましくは１時間
当たり２０℃で昇温し、最高温度で２〜２０時間保持す
る。このようにしてＹＡＧ焼結体を得る。Then, firing is performed at 1600 to 1900 ° C. for 2 to 10 hours in a vacuum atmosphere having a vacuum degree of 1 × 10 -2 torr or more. The degree of vacuum is preferably 1 × 10 −3 torr or more. The heating rate is preferably 50 to 300 ° C. per hour up to a certain constant temperature, for example, 1650 ° C., and particularly preferably 200 to 300 ° C. per hour. After that, in order to make the particle diameter uniform, it is held for 2 to 20 hours. Then, the temperature is raised to 100 ° C. or less per hour up to the maximum temperature, preferably 20 ° C. per hour, and kept at the maximum temperature for 2 to 20 hours. Thus, a YAG sintered body is obtained.
【００１５】尚、真空雰囲気で焼成する代わりに、水素
雰囲気或いは窒素雰囲気等の還元性雰囲気で焼成しても
良い。Instead of firing in a vacuum atmosphere, firing may be performed in a reducing atmosphere such as a hydrogen atmosphere or a nitrogen atmosphere.
【００１６】[0016]
【作用】Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末の混合粉末をそ
のまま１６００℃以上の温度で焼成すると、混合粉末か
らＹＡＭが生成し、ＹＡＭからＹＡＧへ結晶が変化し、
ＹＡＭからＹＡＧへ変化する際に体積膨張が生じ、これ
により焼結体中にボイドや欠陥を生じ、均一な焼結体を
作成することが困難となるが、本発明の透光性ＹＡＧ焼
結体の製造方法では、Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末の
混合粉末を１０００〜１６００℃で仮焼し、この後１６
００〜１９００℃で焼成したので、１０００〜１６００
℃の仮焼によりＹＡＭからＹＡＧへ変化する際の体積膨
張を生じさせることができるため、成形後の焼成では体
積膨張が生じることがなく、これにより、焼結体中のボ
イドや欠陥の発生を抑制し、均一な焼結体を作成するこ
とが可能となる。これにより、可視光領域の直線透過率
を７０％以上とすることができる。When the mixed powder of Al 2 O 3 powder and Y 2 O 3 powder is baked as it is at a temperature of 1600 ° C. or higher, YAM is produced from the mixed powder and the crystal changes from YAM to YAG,
Volume expansion occurs when changing from YAM to YAG, which causes voids and defects in the sintered body, making it difficult to create a uniform sintered body. However, the translucent YAG sintering of the present invention In the body manufacturing method, a mixed powder of Al 2 O 3 powder and Y 2 O 3 powder is calcined at 1000 to 1600 ° C., and then 16
Since it was fired at 00 to 1900 ° C, 1000 to 1600
Since calcination at ℃ can cause volume expansion when changing from YAM to YAG, there is no volume expansion in firing after molding, which causes generation of voids and defects in the sintered body. It is possible to suppress and produce a uniform sintered body. Thereby, the linear transmittance in the visible light region can be 70% or more.
【００１７】また、本発明によれば、従来のように、単
結晶合成，ＨＩＰ処理，ホットプレス，イットリウムイ
オンとアルミニウムイオンの尿素沈澱法等を用いず、一
般的な常圧焼成により製造するため、安価にかつ容易に
透光性ＹＡＧ焼結体を得ることができる。さらに、多結
晶ＹＡＧ焼結体を使用して透明体を製造するため、低価
格となり、強度が安定し、任意の形状を容易に製造で
き、研磨等の加工を容易に行うことができる。Further, according to the present invention, the production is carried out by general atmospheric pressure firing without using the conventional single crystal synthesis, HIP treatment, hot pressing, urea precipitation method of yttrium ion and aluminum ion, etc. Thus, the translucent YAG sintered body can be obtained at low cost and easily. Furthermore, since the transparent body is manufactured using the polycrystalline YAG sintered body, the cost is low, the strength is stable, an arbitrary shape can be easily manufactured, and processing such as polishing can be easily performed.
【００１８】[0018]
【実施例】先ず、出発原料として、それぞれ純度が９
９．９％、ＢＥＴ比表面積５ｍ2 ／ｇ、平均結晶粒径が
０．７μｍであるＡｌ2 Ｏ3 粉末１２９ｇとＹ2 Ｏ3 粉
末１７１ｇを容易し、これと、高純度アルミナボール６
００ｇとバインダーとしてのイソプロピルアルコール
（ＩＰＡ）３００ｇをポリポットに投入し、回転ミルで
２４時間混合粉砕した。混合したものを３２５メッシュ
に通し乾燥させた後、８０メッシュを通し、均一な粉末
を得た。EXAMPLE First, as a starting material, the purity of each is 9
9.9%, BET specific surface area of 5 m 2 / g, average crystal grain size of 0.7 μm 129 g of Al 2 O 3 powder and 171 g of Y 2 O 3 powder, and high purity alumina balls 6
00 g and 300 g of isopropyl alcohol (IPA) as a binder were put into a polypot, and mixed and pulverized by a rotary mill for 24 hours. The mixed product was passed through 325 mesh and dried, and then passed through 80 mesh to obtain a uniform powder.
【００１９】この粉末を表１に示す温度で電気炉により
表１に示す温度で仮焼した後、再度、高純度アルミナボ
ール６００ｇと溶媒としてのイソプロピルアルコール
（ＩＰＡ）３００ｇをポリポットに投入し、回転ミルで
２４時間混合粉砕した。粉砕した粉末を３２５メッシュ
に通し乾燥させた後、８０メッシュを通し、均一な粉末
を得た。この粉末を金型プレスおよび冷間静水圧プレス
を用い２．５ｇ／ｃｍ3以上の生密度の成形体を作成し
た。この成形体を表１に示す焼成温度、焼成時間、昇温
速度、焼成雰囲気で１６００〜１９００℃の温度で２〜
２０時間焼成した。得られた焼結体をＸ線回折装置によ
り測定したところ、ＹＡＧの生成を確認した。This powder was calcined in an electric furnace at the temperature shown in Table 1 at the temperature shown in Table 1, and then 600 g of high-purity alumina balls and 300 g of isopropyl alcohol (IPA) as a solvent were again charged into a polypot and rotated. The mixture was mixed and ground in a mill for 24 hours. The pulverized powder was passed through a 325 mesh and dried, and then passed through a 80 mesh to obtain a uniform powder. A molding having a green density of 2.5 g / cm 3 or more was prepared from this powder using a die press and a cold isostatic press. This molded product is shown in Table 1 at a firing temperature, a firing time, a heating rate, and a firing atmosphere at a temperature of 1600 to 1900 ° C.
It was baked for 20 hours. When the obtained sintered body was measured by an X-ray diffractometer, the production of YAG was confirmed.
【００２０】そして、得られた焼結体を厚さ１ｍｍに研
磨した後、１μｍのダイヤモンドペーストで鏡面仕上げ
を行った。この焼結体の波長６００ｎｍの可視光の直線
透過率を、赤外分光計により測定した。尚、可視光領域
とは、波長が３００〜８００ｎｍである。この実験結果
を表１に示す。Then, the obtained sintered body was polished to a thickness of 1 mm, and then mirror-finished with 1 μm diamond paste. The linear transmittance of visible light having a wavelength of 600 nm of this sintered body was measured by an infrared spectrometer. The visible light region has a wavelength of 300 to 800 nm. The results of this experiment are shown in Table 1.
【００２１】[0021]
【表１】 [Table 1]
【００２２】この実験結果より、本発明のＹＡＧ焼結体
は可視光領域の直線透過率が７０％以上と優れた透光性
を有することが判る。尚、試料Ｎo.１，１５は仮焼する
ことなく、Ａｌ2 Ｏ3 粉末とＹ2 Ｏ3 粉末を焼成した例
である。また、表１中の昇温速度は、試料Ｎo.４を除
き、１６５０℃までの昇温速度である。また、本発明者
等は仮焼を１６５０℃で行う実験を行ったが、この場合
には仮焼後回転ミルで粉砕できなかった。さらに、焼成
を１９５０℃で行う実験を行ったが、試料は溶解して冷
却中に割れを生じた。From this experimental result, it is understood that the YAG sintered body of the present invention has an excellent light-transmitting property with a linear transmittance of 70% or more in the visible light region. Samples Nos. 1 and 15 are examples of firing Al 2 O 3 powder and Y 2 O 3 powder without calcination. Moreover, the temperature rising rate in Table 1 is the temperature rising rate up to 1650 ° C. except for sample No. 4. Further, the inventors conducted an experiment in which calcination was performed at 1650 ° C., but in this case, it was impossible to pulverize with a rotary mill after calcination. Further, an experiment was conducted in which firing was performed at 1950 ° C., but the sample melted and cracked during cooling.
【００２３】[0023]
【発明の効果】以上詳述した通り、本発明の透光性ＹＡ
Ｇ焼結体の製造方法では、Ａｌ2 Ｏ3粉末とＹ2 Ｏ3 粉
末を混合した後１０００〜１６００℃で仮焼し、この後
還元性雰囲気中において１６００〜１９００℃の温度で
焼成したので、１０００〜１６００℃の仮焼によりＹＡ
ＭからＹＡＧへ変化する際の体積膨張を生じさせること
ができ、成形後の焼成では体積膨張が生じることがな
く、これにより、焼結体中のボイドや欠陥の発生を抑制
し、均一な焼結体を作成することができる。これによ
り、可視光領域の直線透過率を７０％以上とすることが
でき、時計用窓材，ランプ管，装飾品等に最適な材料を
提供することができる。As described above in detail, the translucent YA of the present invention
In the method for manufacturing the G sintered body, the Al 2 O 3 powder and the Y 2 O 3 powder are mixed, then calcined at 1000 to 1600 ° C., and then calcined at a temperature of 1600 to 1900 ° C. in a reducing atmosphere. , YA by calcination at 1000-1600 ℃
It is possible to cause the volume expansion when changing from M to YAG, and the volume expansion does not occur in the firing after molding, whereby the generation of voids and defects in the sintered body is suppressed, and uniform sintering is performed. You can create a union. As a result, the linear transmittance in the visible light region can be set to 70% or more, and the optimum material can be provided for the timepiece window material, the lamp tube, the decorative article, and the like.
Claims (1)
3 粉末とＹ2 Ｏ3 粉末を混合した後、１０００〜１６０
０℃で仮焼し、これを粉砕して原料粉末とし、この原料
粉末を所定形状に成形した後、還元性雰囲気中におい
て、１６００〜１９００℃の温度で焼成することを特徴
とする透光性イットリウム−アルミニウム−ガーネット
焼結体の製造方法。1. Al 2 O having a purity of 99.9% or more, respectively.
After mixing 3 powder and Y 2 O 3 powder, 1000-160
A light-transmitting material characterized by being calcined at 0 ° C., pulverized into a raw material powder, shaped into a predetermined shape, and then fired at a temperature of 1600 to 1900 ° C. in a reducing atmosphere. Method for producing yttrium-aluminum-garnet sintered body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25769592A JP3285620B2 (en) | 1992-09-28 | 1992-09-28 | Method for producing translucent yttrium-aluminum-garnet sintered body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25769592A JP3285620B2 (en) | 1992-09-28 | 1992-09-28 | Method for producing translucent yttrium-aluminum-garnet sintered body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06107456A true JPH06107456A (en) | 1994-04-19 |
| JP3285620B2 JP3285620B2 (en) | 2002-05-27 |
Family
ID=17309833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25769592A Expired - Fee Related JP3285620B2 (en) | 1992-09-28 | 1992-09-28 | Method for producing translucent yttrium-aluminum-garnet sintered body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3285620B2 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0717328A1 (en) * | 1994-12-16 | 1996-06-19 | Montres Rado S.A. | Wear resistant transparent closing member of a watch case and watch case provided with the same |
| JP2002220278A (en) * | 2001-01-19 | 2002-08-09 | Shinetsu Quartz Prod Co Ltd | Light-transmitting ceramic and method of manufacturing the same |
| JP2003048792A (en) * | 2001-08-02 | 2003-02-21 | Toshiba Ceramics Co Ltd | Plasma resistant member for semiconductor manufacturing apparatus and method of manufacturing the same |
| US6740262B2 (en) | 2000-05-09 | 2004-05-25 | Matsushita Electric Industrial Co., Ltd. | Light-transmitting sintered body, light-emitting tube and electric discharge lamp using same |
| EP1433764A2 (en) * | 2002-12-25 | 2004-06-30 | Ngk Insulators, Ltd. | Sintered bodies of yttrium-aluminium garnet, a method of producing the same and sintering aid therefor |
| WO2006061225A1 (en) * | 2004-12-09 | 2006-06-15 | Carl Zeiss Smt Ag | Transmitting optical element and objective for a microlithographic projection exposure apparatus |
| JP2006251805A (en) * | 2005-03-08 | 2006-09-21 | Schott Ag | Manufacturing method of optical element for microlithography, lens system obtained by the method and using method of the lens system |
| EP1777281A2 (en) * | 2005-10-24 | 2007-04-25 | Fujifilm Corporation | Inorganic compound, composition and molded body containing the same, light emitting device, and solid laser device |
| JP2008541167A (en) * | 2005-05-10 | 2008-11-20 | ダブリューティーピー オプティクス， インコーポレイテッド | Solid-state method and apparatus for making lenses and lens components |
| JP2009084060A (en) * | 2007-09-27 | 2009-04-23 | Covalent Materials Corp | Translucent oxidized yttrium aluminum garnet sintered compact and its producing method |
| US7691765B2 (en) | 2005-03-31 | 2010-04-06 | Fujifilm Corporation | Translucent material and manufacturing method of the same |
| US7691764B2 (en) | 2006-06-21 | 2010-04-06 | Murata Manufacturing Co., Ltd. | Translucent ceramic, optical component, and optical device |
| US8163667B2 (en) | 2006-12-21 | 2012-04-24 | Carl Zeiss Smt Gmbh | Transmitting optical element with low foreign-element contamination |
| CN114409394A (en) * | 2022-01-17 | 2022-04-29 | 江苏师范大学 | Preparation method of large-size YAG transparent ceramic sheet |
-
1992
- 1992-09-28 JP JP25769592A patent/JP3285620B2/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0717328A1 (en) * | 1994-12-16 | 1996-06-19 | Montres Rado S.A. | Wear resistant transparent closing member of a watch case and watch case provided with the same |
| CH688297GA3 (en) * | 1994-12-16 | 1997-07-31 | Rado Montres Sa | Transparent and scratch-resistant closure element of a watch case and watch case provided with such an element. |
| US6740262B2 (en) | 2000-05-09 | 2004-05-25 | Matsushita Electric Industrial Co., Ltd. | Light-transmitting sintered body, light-emitting tube and electric discharge lamp using same |
| JP2002220278A (en) * | 2001-01-19 | 2002-08-09 | Shinetsu Quartz Prod Co Ltd | Light-transmitting ceramic and method of manufacturing the same |
| JP2003048792A (en) * | 2001-08-02 | 2003-02-21 | Toshiba Ceramics Co Ltd | Plasma resistant member for semiconductor manufacturing apparatus and method of manufacturing the same |
| JP4683783B2 (en) * | 2001-08-02 | 2011-05-18 | コバレントマテリアル株式会社 | Method for manufacturing plasma-resistant member for semiconductor manufacturing apparatus |
| EP1433764A3 (en) * | 2002-12-25 | 2004-09-22 | Ngk Insulators, Ltd. | Sintered bodies of yttrium-aluminium garnet, a method of producing the same and sintering aid therefor |
| EP1433764A2 (en) * | 2002-12-25 | 2004-06-30 | Ngk Insulators, Ltd. | Sintered bodies of yttrium-aluminium garnet, a method of producing the same and sintering aid therefor |
| US7371704B2 (en) | 2002-12-25 | 2008-05-13 | Ngk Insulators, Ltd. | Sintered bodies of yttrium-aluminum garnet, a method of producing the same and sintering aid therefor |
| WO2006061225A1 (en) * | 2004-12-09 | 2006-06-15 | Carl Zeiss Smt Ag | Transmitting optical element and objective for a microlithographic projection exposure apparatus |
| US8570488B2 (en) | 2004-12-09 | 2013-10-29 | Carl Zeiss Smt Gmbh | Transmitting optical element and objective for a microlithographic projection exposure apparatus |
| JP2008523426A (en) * | 2004-12-09 | 2008-07-03 | カール・ツアイス・エスエムテイ・アーゲー | Transmission optical element and objective lens for microlithography projection exposure apparatus |
| JP2006251805A (en) * | 2005-03-08 | 2006-09-21 | Schott Ag | Manufacturing method of optical element for microlithography, lens system obtained by the method and using method of the lens system |
| US7691765B2 (en) | 2005-03-31 | 2010-04-06 | Fujifilm Corporation | Translucent material and manufacturing method of the same |
| JP2008541167A (en) * | 2005-05-10 | 2008-11-20 | ダブリューティーピー オプティクス， インコーポレイテッド | Solid-state method and apparatus for making lenses and lens components |
| EP1777281A3 (en) * | 2005-10-24 | 2007-10-03 | Fujifilm Corporation | Inorganic compound, composition and molded body containing the same, light emitting device, and solid laser device |
| EP1777281A2 (en) * | 2005-10-24 | 2007-04-25 | Fujifilm Corporation | Inorganic compound, composition and molded body containing the same, light emitting device, and solid laser device |
| US7691764B2 (en) | 2006-06-21 | 2010-04-06 | Murata Manufacturing Co., Ltd. | Translucent ceramic, optical component, and optical device |
| US8163667B2 (en) | 2006-12-21 | 2012-04-24 | Carl Zeiss Smt Gmbh | Transmitting optical element with low foreign-element contamination |
| JP2009084060A (en) * | 2007-09-27 | 2009-04-23 | Covalent Materials Corp | Translucent oxidized yttrium aluminum garnet sintered compact and its producing method |
| CN114409394A (en) * | 2022-01-17 | 2022-04-29 | 江苏师范大学 | Preparation method of large-size YAG transparent ceramic sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3285620B2 (en) | 2002-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ikesue et al. | Synthesis of Nd3+, Cr3+‐codoped YAG ceramics for high‐efficiency solid‐state lasers | |
| US4273587A (en) | Polycrystalline transparent spinel sintered body and a method for producing the same | |
| JP3285620B2 (en) | Method for producing translucent yttrium-aluminum-garnet sintered body | |
| Yu et al. | Fabrication of Nd: YAG transparent ceramics using powders synthesized by citrate sol-gel method | |
| US10023795B2 (en) | Ceramic composite systems and method | |
| CN110272282B (en) | Low-temperature preparation method of AlON transparent ceramic | |
| US20040109808A1 (en) | Yttrium aluminum garnet powders and processing | |
| JPH06211573A (en) | Production of transparent y2o3 sintered compact | |
| JP5000934B2 (en) | Translucent rare earth gallium garnet sintered body, manufacturing method thereof and optical device | |
| Zawrah et al. | Synthesis andcharacterisation of nanocrystalline MgAl2O4 ceramic powders by use of molten salts | |
| JPH10273364A (en) | Production of transparent yttrium oxide sintered body | |
| JPH03218963A (en) | Production of transparent yttrium-aluminumgarvent-ceramics | |
| JP4251649B2 (en) | Translucent lutetium oxide sintered body and method for producing the same | |
| JP3420377B2 (en) | Method for producing yttrium-aluminum-garnet sintered body | |
| JP3214927B2 (en) | Translucent yttrium-aluminum-garnet sintered body, method for producing the same, and window material for watch | |
| JPH11157933A (en) | Light transmission ceramic, its production, and arc tube and high-voltage discharge lamp by using light transmission ceramic | |
| JP3000685B2 (en) | Translucent yttria sintered body and method for producing the same | |
| JPH05345662A (en) | Production of forsterite ceramic | |
| EP3560905B1 (en) | Transparent aln sintered body and production method therefor | |
| JP3245234B2 (en) | Method for producing translucent yttrium-aluminum-garnet sintered body | |
| JPH0782025A (en) | Light-transmitting yttrium-aluminum-garnet sintered compact and its production | |
| JP2558849B2 (en) | Method for producing transparent aluminum oxynitride composite sintered body | |
| JP2620287B2 (en) | Method for producing translucent spinel sintered body | |
| JPS6360106A (en) | Spinel powder and its production | |
| JP2566737B2 (en) | Method for producing translucent aluminum magnesium oxynitride sintered body |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090308 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090308 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100308 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110308 Year of fee payment: 9 |
|
| LAPS | Cancellation because of no payment of annual fees |