JPH05981B2 - - Google Patents

Info

Publication number
JPH05981B2
JPH05981B2 JP59044537A JP4453784A JPH05981B2 JP H05981 B2 JPH05981 B2 JP H05981B2 JP 59044537 A JP59044537 A JP 59044537A JP 4453784 A JP4453784 A JP 4453784A JP H05981 B2 JPH05981 B2 JP H05981B2
Authority
JP
Japan
Prior art keywords
stevioside
cyclodextrin
weight
taste
organic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59044537A
Other languages
Japanese (ja)
Other versions
JPS60188035A (en
Inventor
Akyo Kasori
Mitsuyasu Kawasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Riken Vitamin Co Ltd
Original Assignee
Riken Vitamin Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Riken Vitamin Co Ltd filed Critical Riken Vitamin Co Ltd
Priority to JP59044537A priority Critical patent/JPS60188035A/en
Publication of JPS60188035A publication Critical patent/JPS60188035A/en
Publication of JPH05981B2 publication Critical patent/JPH05981B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Seasonings (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明はステビオサイド(レバウデイオサイド
を含む)を含む甘味料の呈味を改善する方法に関
するものである。 その目的とするところは、酒石酸ナトリウム、
クエン酸ナトリウム、リンゴ酸ナトリウム等の有
機酸塩とサイクロデキストリンとを併用添加する
ことにより、ステビオサイド及びそれらを含むス
テビア抽出物の呈味上の苦味、嫌味等の欠点を除
去し、経済的に良質の甘味を得ることである。 ステビオサイドは、砂糖の300倍の甘味度をも
つ天然甘味物質であり、最近の合成甘味料の安全
性の問題、または糖害が社会問題となりつつある
今日、これを解決し得る甘味源として急激に注目
されてきた。 しかしステビオサイド及びステビア抽出物は砂
糖に比較し甘味の発現性が遅く且つ苦味、嫌味等
の不快味の欠点を有しており、ステビオサイドの
実用上の大きな障害となつている。 従つて、ステビオサイド及びステビア抽出物の
呈味性の改良については、種々の提案がなされて
いるにもかかわらず、未だ解決されていない。 一方、特公昭57−18779号で、ステビオサイド
と例えばマルトース、マルトオリゴ糖等のα−グ
ルコシル糖化合物を共存させ、このα−グルコシ
ル基をステビオサイドに転移しうるα−グルコシ
ル転移酵素を作用させてα−グルコシルステビオ
サイドを作る方法が提案され甘味質の良好な甘味
料が市場へ提供させているが価格が高く実用上に
問題がある。 本発明者らは、上述した事情に鑑み、ステビオ
サイド及びステビア抽出物の苦味、嫌味を除去す
る方法について鋭意検討した結果、サイクロデキ
ストリンを有機酸塩類と併用添加することにより
不快味を呈する物質をマスキング出来る事実を発
見し、本発明を完成した。 こゝでいう有機酸塩とはクエン酸ナトリウム、
リンゴ酸ナトリウム、酒石酸ナトリウム等で、ス
テビオサイド1重量部に対して有機酸塩の一種又
は二種以上を0.2〜50重量部の範囲で添加すれば
良く、好ましくは0.5〜4重量部が良好である。 また、ここでいうサイクロデキストリンとは6
〜12個のグルコースがα−1,4グルコシド結合
で環状に連なつた非還元性のマルトオリゴ糖で、
Bacillus属のある種の微生物から得られるサイク
ロデキストリン生成酵素を澱粉に作用させて得ら
れる。サイクロデキストリンには3種類あり、グ
ルコースが6個のα−、7個のβ−、8個のγー
サイクロデキストリンがある。市場では主として
β−サイクロデキストリンの粉末かα,β,γの
混合物でサイクロデキストリン含量20%の水あめ
状のものが多く使用されている。 本発明では、β−サイクロデキストリンに効果
が認められたが、勿論β−サイクロデキストリン
を含むものであれば良い。ステビオサイドに対す
るサイクロデキストリンの添加量はステビオサイ
ドの1重量部に対して0.5〜100重量部であれば良
い。サイクロデキストリンの最適添加量はステビ
ア抽出物中の不純物の量によつて変動するために
特定は出来ないが、ステビオサイドの純度が80〜
98%の場合、ステビオサイドの100%純度換算1
重量部に対して3〜10重量添加すれば良い。ステ
ビオサイドの純度が40〜80%の場合は、ステビオ
サイドの100%純度換算1重量部あたり10〜30重
量部添加すれば良い。 次に実施例によつて本発明をさらに説明する。 実施例 1 ステビア抽出物(ステビオサイド含量86.3%)
の0.5%水溶液にクエン酸ナトリウム、酒石酸ナ
トリウム、α,β,γ−サイクロデキストリンを
組合わせて、ステビア抽出物の苦味、嫌味の改善
度合を官能検査によつて比較した。 その結果を第1表に示した。 評価基準 AA……苦味、嫌味、ほぼ完全にマスクされて
いる。 A……若干、苦味を感じるが、良好である。 B……やや効果あり。 C……効果なし。
The present invention relates to a method for improving the taste of sweeteners containing stevioside (including rebaudioside). The purpose is to use sodium tartrate,
By adding organic acid salts such as sodium citrate and sodium malate together with cyclodextrin, disadvantages such as bitterness and unpleasant taste of stevioside and stevia extract containing them can be removed, resulting in an economically high quality product. The goal is to obtain the sweetness of Stevioside is a natural sweetening substance that is 300 times sweeter than sugar, and is rapidly becoming a source of sweetness that can solve the recent safety problems of synthetic sweeteners and sugar damage, which is becoming a social problem. It has been attracting attention. However, compared to sugar, stevioside and stevia extracts have the drawbacks of slower sweetness development and unpleasant tastes such as bitterness and sarcastic taste, which are major obstacles to the practical use of stevioside. Therefore, although various proposals have been made to improve the taste of stevioside and stevia extracts, the problem remains unsolved. On the other hand, in Japanese Patent Publication No. 57-18779, stevioside and an α-glucosyl sugar compound such as maltose or malto-oligosaccharide were made to coexist, and an α-glucosyltransferase capable of transferring this α-glucosyl group to stevioside was activated to produce an α- A method for producing glucosyl stevioside has been proposed, and a sweetener with good sweetness has been provided to the market, but it is expensive and has problems in practical use. In view of the above-mentioned circumstances, the present inventors conducted extensive studies on a method for removing the bitterness and unpleasant taste of stevioside and stevia extracts, and found that by adding cyclodextrin in combination with organic acid salts, substances that exhibit unpleasant taste can be masked. He discovered the fact that it is possible and completed the present invention. The organic acid salts mentioned here are sodium citrate,
One or more organic acid salts such as sodium malate and sodium tartrate may be added to 1 part by weight of stevioside in a range of 0.2 to 50 parts by weight, preferably 0.5 to 4 parts by weight. . Also, the cyclodextrin mentioned here is 6
It is a non-reducing maltooligosaccharide in which ~12 glucose molecules are connected in a ring through α-1,4 glucosidic bonds.
It is obtained by allowing cyclodextrin-producing enzyme obtained from certain microorganisms of the genus Bacillus to act on starch. There are three types of cyclodextrins: α-cyclodextrin, which has 6 glucose units, β-cyclodextrin, which has 7 glucose units, and γ-cyclodextrin, which has 8 glucose units. In the market, mainly β-cyclodextrin powder or a mixture of α, β, and γ in the form of starch syrup with a cyclodextrin content of 20% are often used. In the present invention, β-cyclodextrin was found to be effective, but of course any substance containing β-cyclodextrin may be used. The amount of cyclodextrin added to stevioside may be 0.5 to 100 parts by weight per 1 part by weight of stevioside. The optimal amount of cyclodextrin added cannot be determined because it varies depending on the amount of impurities in the stevia extract, but it is important to note that the optimal amount of cyclodextrin added varies depending on the amount of impurities in the stevia extract, but
If 98%, stevioside 100% purity conversion 1
It may be added in an amount of 3 to 10 parts by weight. When the purity of stevioside is 40 to 80%, it is sufficient to add 10 to 30 parts by weight per 1 part by weight of stevioside in terms of 100% purity. Next, the present invention will be further explained with reference to Examples. Example 1 Stevia extract (stevioside content 86.3%)
A 0.5% aqueous solution of Stevia extract was combined with sodium citrate, sodium tartrate, and α,β,γ-cyclodextrin, and the degree of improvement in the bitterness and unpleasant taste of the Stevia extract was compared through a sensory test. The results are shown in Table 1. Evaluation criteria: AA...Bitterness, sarcasm, almost completely masked. A: Slightly bitter taste, but good. B: Somewhat effective. C...No effect.

【表】 尚α,β,γ−サイクロデキストリンは日本食
品化工(株)のものを使用した。(純度98.5%以上) 有機酸塩とβ−サイクロデキストリンを併用し
たものに顕著な効果が認められる。 実施例 2 ステビア抽出物(ステビオサイド含量80.7%)
0.5%水溶液の系にて有機酸塩とβ−サイクロデ
キストリンの組合わせについて検討した。 その結果を第2表に示した。 評価基準は実施例−1と同様である。
[Table] The α, β, γ-cyclodextrin used was from Nihon Shokuhin Kako Co., Ltd. (Purity 98.5% or higher) A remarkable effect is observed when an organic acid salt and β-cyclodextrin are used in combination. Example 2 Stevia extract (stevioside content 80.7%)
We investigated the combination of organic acid salts and β-cyclodextrin in a 0.5% aqueous solution system. The results are shown in Table 2. The evaluation criteria are the same as in Example-1.

【表】【table】

【表】 使用しても改善効果は認められないが、両者を
併用すると顕著な改善効果が認められる。
実施例 3 ステビア抽出物(ステビオサイド含量51.8%)
の0.5%水溶液の系にて検討した。 その結果を第3表に示した。 評価基準は実施例−1と同様である。
[Table] Although no improvement effect is observed when both are used together, a significant improvement effect is observed when both are used together.
Example 3 Stevia extract (stevioside content 51.8%)
The study was conducted using a 0.5% aqueous solution. The results are shown in Table 3. The evaluation criteria are the same as in Example-1.

【表】 不純物の多い中純度のステビア抽出物でも有機
酸塩とサイクロデキストリンを併用することによ
り顕著な呈味改善効果が認められる。 但し、不純物が多いためにステビオサイドあた
りのサイクロデキストリンの添加量は多く必要で
ある。 実施例 4 通常市販されているステビオサイド製剤と本発
明品とを比較した。 その結果を第4表に示した。
[Table] Even with medium-purity Stevia extract containing many impurities, a remarkable taste improvement effect is observed by using an organic acid salt and cyclodextrin together. However, since there are many impurities, it is necessary to add a large amount of cyclodextrin per stevioside. Example 4 A commonly available stevioside preparation and the product of the present invention were compared. The results are shown in Table 4.

【表】【table】

【表】 以上7種類のサンプルを5,7.5,10%溶液に
て官能検査を行なつたところ、有機酸塩とサイク
ロデキストリンを併用した本発明品(テストNo.
3,4,5,6,7)の方が苦味、嫌味が除去さ
れ顕著な呈味改善効果が認められた。
[Table] Sensory tests were conducted on the above seven types of samples using 5, 7.5, and 10% solutions.
3, 4, 5, 6, and 7), the bitterness and sarcastic taste were removed, and a remarkable taste improvement effect was observed.

Claims (1)

【特許請求の範囲】[Claims] 1 ステビオサイド(レバウデイオサイドを含
む)を呈味成分とする甘味料において、ステビオ
サイド1重量部に対して、酒石酸塩、クエン酸
塩、リンゴ酸塩又はその他の有機酸塩の一種又は
二種以上を0.2〜50重量部、サイクロデキストリ
ン0.5〜100重量部の割合で併用添加することを特
徴とするステビオサイドの呈味改善法。
1. In sweeteners containing stevioside (including rebaudioside) as a flavor component, one or more of tartrate, citrate, malate, or other organic acid salts per 1 part by weight of stevioside. A method for improving the taste of stevioside, which comprises adding 0.2 to 50 parts by weight of stevioside and 0.5 to 100 parts by weight of cyclodextrin.
JP59044537A 1984-03-08 1984-03-08 Taste improvement in stevioside Granted JPS60188035A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59044537A JPS60188035A (en) 1984-03-08 1984-03-08 Taste improvement in stevioside

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59044537A JPS60188035A (en) 1984-03-08 1984-03-08 Taste improvement in stevioside

Publications (2)

Publication Number Publication Date
JPS60188035A JPS60188035A (en) 1985-09-25
JPH05981B2 true JPH05981B2 (en) 1993-01-07

Family

ID=12694255

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59044537A Granted JPS60188035A (en) 1984-03-08 1984-03-08 Taste improvement in stevioside

Country Status (1)

Country Link
JP (1) JPS60188035A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009517041A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー Cereal composition using high-potency sweetener
JP2009517023A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー High-intensity sweetener composition containing calcium and sweetened composition thereby
JP2009517039A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー Baked foods containing high-potency sweeteners

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9107436B2 (en) 2011-02-17 2015-08-18 Purecircle Sdn Bhd Glucosylated steviol glycoside as a flavor modifier
US8956677B2 (en) * 2005-11-23 2015-02-17 The Coca-Cola Company High-potency sweetener composition with glucosamine and compositions sweetened therewith
US8524303B2 (en) 2005-11-23 2013-09-03 The Coca-Cola Company High-potency sweetener composition with phytosterol and compositions sweetened therewith
US20070134391A1 (en) * 2005-11-23 2007-06-14 The Coca-Cola Company High-Potency Sweetener Composition for Treatment and/or Prevention of Autoimmune Disorders and Compositions Sweetened Therewith
US9144251B2 (en) 2005-11-23 2015-09-29 The Coca-Cola Company High-potency sweetener composition with mineral and compositions sweetened therewith
US8993027B2 (en) 2005-11-23 2015-03-31 The Coca-Cola Company Natural high-potency tabletop sweetener compositions with improved temporal and/or flavor profile, methods for their formulation, and uses
US8512789B2 (en) 2005-11-23 2013-08-20 The Coca-Cola Company High-potency sweetener composition with dietary fiber and compositions sweetened therewith
US8945652B2 (en) * 2005-11-23 2015-02-03 The Coca-Cola Company High-potency sweetener for weight management and compositions sweetened therewith
US8962058B2 (en) 2005-11-23 2015-02-24 The Coca-Cola Company High-potency sweetener composition with antioxidant and compositions sweetened therewith
US8524304B2 (en) 2005-11-23 2013-09-03 The Coca-Cola Company High-potency sweetener composition with probiotics/prebiotics and compositions sweetened therewith
US9101160B2 (en) 2005-11-23 2015-08-11 The Coca-Cola Company Condiments with high-potency sweetener
US20070116822A1 (en) * 2005-11-23 2007-05-24 The Coca-Cola Company High-potency sweetener composition with saponin and compositions sweetened therewith
US8367138B2 (en) 2005-11-23 2013-02-05 The Coca-Cola Company Dairy composition with high-potency sweetener
ES2611887T3 (en) 2005-11-23 2017-05-11 The Coca-Cola Company Natural high potency sweetener compositions with improved temporal profile and / or aroma profile
CN101312660B (en) * 2005-11-23 2013-07-17 可口可乐公司 High-potency sweetener for weight management and compositions sweetened therewith
US8435587B2 (en) 2005-11-23 2013-05-07 The Coca-Cola Company High-potency sweetener composition with long-chain primary aliphatic saturated alcohol and compositions sweetened therewith
US8956678B2 (en) 2005-11-23 2015-02-17 The Coca-Cola Company High-potency sweetener composition with preservative and compositions sweetened therewith
US8435588B2 (en) 2005-11-23 2013-05-07 The Coca-Cola Company High-potency sweetener composition with an anti-inflammatory agent and compositions sweetened therewith
US8367137B2 (en) 2005-11-23 2013-02-05 The Coca-Cola Company High-potency sweetener composition with fatty acid and compositions sweetened therewith
US8377491B2 (en) 2005-11-23 2013-02-19 The Coca-Cola Company High-potency sweetener composition with vitamin and compositions sweetened therewith
JP6145021B2 (en) * 2006-09-22 2017-06-07 三栄源エフ・エフ・アイ株式会社 Method for improving taste of high intensity sweetener
JP5447754B2 (en) * 2006-09-22 2014-03-19 三栄源エフ・エフ・アイ株式会社 Method for improving taste of high intensity sweetener
US9101161B2 (en) 2006-11-02 2015-08-11 The Coca-Cola Company High-potency sweetener composition with phytoestrogen and compositions sweetened therewith
US8017168B2 (en) * 2006-11-02 2011-09-13 The Coca-Cola Company High-potency sweetener composition with rubisco protein, rubiscolin, rubiscolin derivatives, ace inhibitory peptides, and combinations thereof, and compositions sweetened therewith
US8029846B2 (en) * 2007-03-14 2011-10-04 The Concentrate Manufacturing Company Of Ireland Beverage products
US20080226800A1 (en) * 2007-03-14 2008-09-18 Concentrate Manufacturing Company Of Ireland Diet cola beverages
US9877500B2 (en) 2007-03-14 2018-01-30 Concentrate Manufacturing Company Of Ireland Natural beverage products
US8277862B2 (en) 2007-03-14 2012-10-02 Concentrate Manufacturing Company Of Ireland Beverage products having steviol glycosides and at least one acid
JP5525210B2 (en) 2009-08-27 2014-06-18 小川香料株式会社 Taste improver for high-intensity sweeteners
CN103079411A (en) * 2010-02-08 2013-05-01 可口可乐公司 Solubility enhanced terpene glycoside(s)
US10696706B2 (en) 2010-03-12 2020-06-30 Purecircle Usa Inc. Methods of preparing steviol glycosides and uses of the same
US11690391B2 (en) 2011-02-17 2023-07-04 Purecircle Sdn Bhd Glucosylated steviol glycoside as a flavor modifier
US9771434B2 (en) 2011-06-23 2017-09-26 Purecircle Sdn Bhd Products from stevia rebaudiana
CN105682467A (en) 2013-06-07 2016-06-15 谱赛科美国股份有限公司 Stevia extract containing selected steviol glycosides as flavor, salty and sweetness profile modifier
US10952458B2 (en) 2013-06-07 2021-03-23 Purecircle Usa Inc Stevia extract containing selected steviol glycosides as flavor, salty and sweetness profile modifier
US10485256B2 (en) * 2014-06-20 2019-11-26 Sweet Green Fields International Co., Limited Stevia sweetener with improved solubility with a cyclodextrin
CN107072237B (en) 2014-09-02 2021-12-14 谱赛科有限责任公司 Stevia extract

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009517041A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー Cereal composition using high-potency sweetener
JP2009517023A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー High-intensity sweetener composition containing calcium and sweetened composition thereby
JP2009517039A (en) * 2005-11-23 2009-04-30 ザ・コカ−コーラ・カンパニー Baked foods containing high-potency sweeteners
JP2011087597A (en) * 2005-11-23 2011-05-06 Coca Cola Co:The Cereal composition comprising high-potency sweetener
US8940350B2 (en) 2005-11-23 2015-01-27 The Coca-Cola Company Cereal compositions comprising high-potency sweeteners

Also Published As

Publication number Publication date
JPS60188035A (en) 1985-09-25

Similar Documents

Publication Publication Date Title
JPH05981B2 (en)
EP1295533A1 (en) Sweetener and process for producing the same
JP2898688B2 (en) Highly sweetened sugar-added stevia sweetener and process for producing the same
JP3896577B2 (en) Quercetin glycoside composition and preparation method thereof
BR112013020891B1 (en) process for the production of a highly purified stevia glycosyl composition
KR20130014227A (en) NOVEL α-GLUCOSYL STEVIOSIDES AND PROCESS FOR PRODUCING THE SAME
JP2022529107A (en) Steviol Glycoside Solubility Improver
JP2798433B2 (en) Highly sweetened sugar-added stevia sweetener and process for producing the same
JP2011206030A (en) Taste quality improving and fruit juice feeling imparting agent
JP5952442B2 (en) Method for improving taste of high intensity sweetener
JPS6387959A (en) Method for improving flavoring of stevia sweetener
JP3925356B2 (en) Sweetener and method for producing the same
JP5447754B2 (en) Method for improving taste of high intensity sweetener
JPH05982B2 (en)
JPH04364130A (en) Soya saponin-containing food and soya saponin pharmaceutical preparation
JPS5939268A (en) Preparation of sweetener
BR112021001097A2 (en) steviol glycoside aggregates with specific particle size distribution
JPS6037950A (en) Method for improving taste of stevia sweetener
JP2001509007A (en) Sweet stable soft drinks, concentrates and syrups containing dipeptide sweeteners and fructans
JPH012552A (en) Method for reducing bitterness of Gymnema sylvestre extract
JP2820945B2 (en) Method for removing bitterness of glycyrrhizin-containing liquid
JPS6098957A (en) Novel stevioside sweetener and its production
JPS61224963A (en) Sweetener composition
JP3288406B2 (en) Novel beverage composition containing dipeptide sweetener, saccharin salt and hydrated colloidal polysaccharide
JPS5848157B2 (en) Complex sweetener containing palatinose