JPH059488A - Grease for sealing bearing - Google Patents

Grease for sealing bearing

Info

Publication number
JPH059488A
JPH059488A JP15837591A JP15837591A JPH059488A JP H059488 A JPH059488 A JP H059488A JP 15837591 A JP15837591 A JP 15837591A JP 15837591 A JP15837591 A JP 15837591A JP H059488 A JPH059488 A JP H059488A
Authority
JP
Japan
Prior art keywords
grease
bearing
oil
fatty acid
sodium salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15837591A
Other languages
Japanese (ja)
Inventor
Kazunori Kubota
和則 久保田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NTN Corp
Original Assignee
NTN Corp
NTN Toyo Bearing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NTN Corp, NTN Toyo Bearing Co Ltd filed Critical NTN Corp
Priority to JP15837591A priority Critical patent/JPH059488A/en
Publication of JPH059488A publication Critical patent/JPH059488A/en
Pending legal-status Critical Current

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  • Lubricants (AREA)

Abstract

PURPOSE:To provide the title grease which allows a bearing having a noncontact sealing device to run very quietly without polluting a clean atmosphere. CONSTITUTION:The title grease comprises a base oil consisting of a polyol ester oil or diester oil having a kinematic viscosity at 40 deg.C of 50-200cSt and 15-40wt.% thickener consisting of a sodium salt of 12-hydroxystearic or another fatty acid. A bearing sealed with the grease runs very quietly with very little dust being generated, i.e., without polluting a clean atmosphere.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、軸受内に封入して用
いられる軸受封入用のグリースに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a bearing enclosing grease which is used by enclosing it in a bearing.

【0002】[0002]

【従来の技術】一般に、軸受外に粉塵や潤滑油が飛散す
るのを防止するための密封装置として、非接触式密封装
置と接触式密封装置があり、前者は軸と軸受間に狭小な
すき間を有し、このすき間にグリースを詰めたもので、
回転時の静粛性や構造の簡単さにおいて、後者より優れ
る。
2. Description of the Related Art Generally, there are a non-contact type sealing device and a contact type sealing device as sealing devices for preventing dust and lubricating oil from scattering outside the bearing. The former is a narrow gap between a shaft and a bearing. With a gap filled with grease,
It is superior to the latter in quietness during rotation and simple structure.

【0003】しかし、昨今の電子機器関連の回転部分に
は、より一層の静粛性と清浄性が求められており、たと
えば、ハードディスクドライブ装置(以下HDDと略記
する)や、レーザービームプリンタ(以下LBPと略記
する)といった装置では、使用される雰囲気中に微細な
油粒子や粉塵等の汚染粒子(以下ダストという)が混入
すると、前記HDDではヘッドクラッシュが起こると
か、前記LBPでは光学反射面の反射率が低下するとい
われている。
However, further quietness and cleanliness are required for rotating parts related to electronic devices these days, and for example, hard disk drive devices (hereinafter abbreviated as HDD) and laser beam printers (hereinafter LBP) are required. In such a device, when fine oil particles or contaminant particles such as dust (hereinafter referred to as dust) are mixed in the atmosphere used, head crash occurs in the HDD, or reflection of an optical reflection surface occurs in the LBP. It is said that the rate will decrease.

【0004】このような事態を機構上回避するには、軸
受の非接触式密封装置に代えて、またはこの装置と共
に、磁性流体シール装置を取り付ける手法が知られてい
る。この磁性流体シールは、軸受転動体の挾持部材の対
向する端面にマグネット部材を固定し、その端面間に磁
性流体を集合させて密封性を高めたものである。
In order to mechanically avoid such a situation, a method is known in which a magnetic fluid sealing device is attached instead of or together with the non-contact type sealing device of the bearing. In this magnetic fluid seal, a magnet member is fixed to opposite end surfaces of a holding member of a bearing rolling element, and magnetic fluid is collected between the end surfaces to enhance the hermeticity.

【0005】一方、このような密封装置や軸受内に封入
されるグリースとしては、特に防塵用に改良されたもの
はなく、比較的低粘度の鉱油、合成油を基油として、リ
チウム、カルシウム、ナトリウムを塩とする金属石けん
を増稠剤とした一般的組成分からなるものが用いられて
いた。
On the other hand, there is no grease that is sealed in such a sealing device or a bearing, which has not been particularly improved to prevent dust. Mineral oil or synthetic oil having a relatively low viscosity is used as a base oil, and lithium, calcium, Those having a general composition having a thickening agent of metallic soap containing sodium as a salt have been used.

【0006】[0006]

【発明が解決しようとする課題】しかし、前記した電子
機器関連の装置に対する要望は増々高度となり、より一
層の小型化と生産コストの低減を図るための特定用途の
潤滑剤として、磁性流体シールのない軸受に対しても上
記静粛性と清浄性を満足するグリースの開発が求められ
てきている。
However, the demand for the above-mentioned electronic equipment-related devices is becoming higher and higher, and as a lubricant for a specific purpose, a magnetic fluid seal is used as a lubricant for further miniaturization and reduction in production cost. It has been required to develop a grease that satisfies the above quietness and cleanliness even for bearings that do not have it.

【0007】この発明は、上記したように従来のグリー
スが構造上複雑な磁性流体シールを付設しなければ、静
粛性のある清浄雰囲気下で軸受を潤滑できないという問
題点を解決し、非接触式密封装置を備えた軸受に封入す
るだけで、静粛性に優れ、清浄雰囲気下で使用し得る軸
受封入用グリースとすることを課題としている。
As described above, the present invention solves the problem that the conventional grease cannot lubricate the bearing in a quiet and clean atmosphere unless a magnetic fluid seal having a complicated structure is attached. An object of the present invention is to provide a bearing-encapsulating grease that is excellent in quietness and can be used in a clean atmosphere simply by enclosing it in a bearing equipped with a sealing device.

【0008】[0008]

【課題を解決するための手段】上記の課題を解決するた
め、この発明においては40℃における動粘度が50〜
200cStのエステル油を基油とし、増稠剤として高
級脂肪酸ナトリウム塩を15〜40重量%配合した構成
を採用したのである。
In order to solve the above problems, in the present invention, the kinematic viscosity at 40 ° C. is 50 to 50 ° C.
A composition was used in which a 200 cSt ester oil was used as a base oil and 15 to 40% by weight of a higher fatty acid sodium salt was blended as a thickener.

【0009】以下、その詳細を述べる。The details will be described below.

【0010】まず、この発明におけるエステル油として
は、有機酸とアルコールとの反応生成物として得られる
ジエステル系潤滑油およびヒンダードエステルとしての
ポリオールエステルが例示できる。上記ジエステル油と
しては、直鎖二塩基酸であるセバシン酸、アゼライン
酸、アジピン酸などと側鎖をもつ高級アルコールとから
得られるジエステル類、すなわち、ジ−2−エチルヘキ
シルセバケート、ジ−2−エチルヘキシルアジペートな
どが挙げられる。また、ポリオールエステル油として
は、ペンタエリスリトール、ジペンタエリスリトール、
トリメチロールプロパンおよびこれらの混合物の脂肪酸
エステルであるペンタエリスリトールテトラヘキサエー
トなどが挙げられる。
First, as the ester oil in the present invention, a diester type lubricating oil obtained as a reaction product of an organic acid and an alcohol and a polyol ester as a hindered ester can be exemplified. Examples of the diester oil include diesters obtained from linear dibasic acids such as sebacic acid, azelaic acid, and adipic acid, and a higher alcohol having a side chain, that is, di-2-ethylhexyl sebacate, di-2- Examples thereof include ethylhexyl adipate. Further, as the polyol ester oil, pentaerythritol, dipentaerythritol,
Examples include fatty acid esters of trimethylolpropane and mixtures thereof, such as pentaerythritol tetrahexaate.

【0011】上記したエステル油の40℃における動粘
度は、50〜200cStである。なぜなら50cSt
未満の低粘度ではダスト発生低減効果が小さく、200
cStを越える高粘度では製造段階で増稠剤の分散が不
均一となり易く、軸受の静粛性、トルクに対しても好ま
しくないからである。
The kinematic viscosity of the above ester oil at 40 ° C. is 50 to 200 cSt. Because 50 cSt
If the viscosity is less than less than 200, the dust generation reducing effect is small,
This is because if the viscosity is higher than cSt, the thickener is likely to be unevenly dispersed in the manufacturing stage, which is not preferable for quietness and torque of the bearing.

【0012】つぎに、この発明における高級脂肪酸ナト
リウム塩としては、炭素数12〜24の脂肪酸ナトリウ
ム塩が好ましく、特に炭素数18の12ヒドロキシステ
アリン酸ナトリウムが好ましい。このような高級脂肪酸
のナトリウム塩の配合割合は15〜40重量%である。
なぜなら、15重量%未満の少量ではダスト発生の低減
効果が小さく、40重量%を越える多量では、グリース
が硬くなり過ぎて、軸受へ封入し難く、静粛性も劣るか
らである。
Next, as the higher fatty acid sodium salt in the present invention, a fatty acid sodium salt having 12 to 24 carbon atoms is preferable, and sodium 12 hydroxystearate having 18 carbon atoms is particularly preferable. The compounding ratio of such sodium salt of higher fatty acid is 15 to 40% by weight.
This is because if the amount is less than 15% by weight, the dust generation reducing effect is small, and if the amount is more than 40% by weight, the grease becomes too hard to be easily filled in the bearing, and the quietness is poor.

【0013】[0013]

【実施例】【Example】

実施例1〜3:40℃における動粘度が80cStまた
は150cStのポリオールエステルと12ヒドロキシ
ステアリン酸ナトリウムの合計重量が100%となるよ
うに表1に示す割合で混合し、この混合物に0.5%のフ
ェノチアジンを酸化防止剤として添加し、全量が液体に
なるまで攪拌しながら加熱した。冷却後、三段ローラで
均一化しグリース組成物を得た。
Examples 1 to 3: Polyol ester having a kinematic viscosity of 80 cSt or 150 cSt at 40 ° C. and sodium 12-hydroxystearate were mixed at a ratio shown in Table 1 so that the total weight was 100%, and 0.5% was added to this mixture. Was added as an antioxidant and heated with stirring until the total amount became liquid. After cooling, it was homogenized with a three-stage roller to obtain a grease composition.

【0014】上記グリース組成物に対して以下に示すダ
スト発生試験を行ない、この結果を表1中に示した。
The following dust generation test was conducted on the above grease composition, and the results are shown in Table 1.

【0015】ダスト発生試験:非接触式密封装置(ニト
リルゴムLBシール)を両側部に備えた密封ころがり軸
受695にグリース組成物17mgを封入し、この軸受2
個を一組として駆動軸に装着し、スラスト荷重1kgf 、
3600rpm の条件下で運転した。このとき、前記一組
の軸受から発生する0.3μm以上のダストを測定した。
Dust generation test: 17 mg of a grease composition was sealed in a sealed rolling bearing 695 equipped with a non-contact type sealing device (nitrile rubber LB seal) on both sides, and this bearing 2
Installed on the drive shaft as a set, thrust load 1kgf,
It was operated under the conditions of 3600 rpm. At this time, dust of 0.3 μm or more generated from the set of bearings was measured.

【0016】[0016]

【表1】 [Table 1]

【0017】比較例1および2:基油と増稠剤の原材料
名が知られている市販のグリースについて、実施例1〜
3と全く同様の試験を行ない、この結果を表1中に併記
した。
Comparative Examples 1 and 2: Commercially available greases with known raw material names of base oil and thickener were used in Examples 1 to 1.
The same test as in Example 3 was performed, and the results are also shown in Table 1.

【0018】比較例3〜5:40℃における動粘度が1
50cStポリオールエステルと12ヒドロキシステア
リン酸リチウム(11.5重量%、7重量%)または、同
80cStポリオールエステルと12ヒドロキシステア
リン酸ナトリウム(7.5重量%)を表1に示す配合割合
として、実施例1〜3と全く同様にしてグリース組成物
を得た。このグリース組成物に対して上記ダスト発生試
験を行ない、この結果を表1中に併記した。
Comparative Examples 3 to 5: Kinematic viscosity at 40 ° C. is 1
Examples of 50 cSt polyol ester and lithium 12-hydroxystearate (11.5% by weight, 7% by weight) or 80 cSt polyol ester and sodium 12-hydroxystearate (7.5% by weight) were used as mixing ratios shown in Table 1. A grease composition was obtained in exactly the same manner as 1-3. The above dust generation test was conducted on this grease composition, and the results are also shown in Table 1.

【0019】表1の試験結果から明らかなように、増稠
剤が脂肪酸リチウム塩またはリチウム石けんである比較
例1〜4および増稠剤が脂肪酸ナトリウム塩であるが1
5重量%以下の配合割合である比較例5は、ダストの発
生量が1256〜6274と極めて高い値を示した。こ
れに対し、基油に80〜150cStのポリオールエス
テル油を用い、脂肪酸ナトリウム塩の増稠剤を15重量
%以上配合したグリースは、ダストの発生量が240〜
591と極めて低い値を示した。
As is clear from the test results in Table 1, Comparative Examples 1 to 4 in which the thickener is a fatty acid lithium salt or lithium soap and the thickener is a fatty acid sodium salt
In Comparative Example 5 having a blending ratio of 5% by weight or less, the amount of dust generated was 1256 to 6274, which was an extremely high value. On the other hand, the grease produced by using polyol ester oil of 80 to 150 cSt as the base oil and blending 15% by weight or more of a thickener of fatty acid sodium salt has a dust generation amount of 240 to
It showed an extremely low value of 591.

【0020】[0020]

【効果】この発明は、以上説明したように、所定動粘度
のエステル油を基油とし、かつ高級脂肪酸の金属塩であ
る増稠剤のうち、ナトリウム塩を限定使用したものであ
るから、これを封入した軸受から発生するダスト量が極
めて少なく、磁性流体シールがなくても清浄雰囲気を汚
染することなく、静粛性を保って軸受を使用することが
できる。したがって、このような軸受を用いて回転部分
を含む装置の部品点数を削減することが可能となり、装
置を小型化し得ると共に、製造コストの低減を図ること
ができるという利点もある。
As described above, the present invention uses, as a base oil, an ester oil having a predetermined kinematic viscosity, and limits use of a sodium salt among thickeners which are metal salts of higher fatty acids. The amount of dust generated from the bearing in which is sealed is extremely small, and even if there is no magnetic fluid seal, the clean atmosphere is not contaminated and the bearing can be used while maintaining quietness. Therefore, it is possible to reduce the number of parts of the device including the rotating portion by using such a bearing, and it is possible to reduce the size of the device and to reduce the manufacturing cost.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C10N 30:04 40:02 50:10 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C10N 30:04 40:02 50:10

Claims (1)

【特許請求の範囲】 【請求項1】 40℃における動粘度が50〜200c
Stのエステル油を基油とし、増稠剤として高級脂肪酸
ナトリウム塩を15〜40重量%配合してなる軸受封入
用グリース。
1. A kinematic viscosity at 40 ° C. of 50 to 200 c.
A grease for bearing encapsulation, which comprises an ester oil of St as a base oil and 15 to 40% by weight of a higher fatty acid sodium salt as a thickener.
JP15837591A 1991-06-28 1991-06-28 Grease for sealing bearing Pending JPH059488A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15837591A JPH059488A (en) 1991-06-28 1991-06-28 Grease for sealing bearing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15837591A JPH059488A (en) 1991-06-28 1991-06-28 Grease for sealing bearing

Publications (1)

Publication Number Publication Date
JPH059488A true JPH059488A (en) 1993-01-19

Family

ID=15670332

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15837591A Pending JPH059488A (en) 1991-06-28 1991-06-28 Grease for sealing bearing

Country Status (1)

Country Link
JP (1) JPH059488A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5500058A (en) * 1994-08-16 1996-03-19 Topy Kogyo Kabushiki Kaisha Method for producing a vehicular endless track link
JPH0921424A (en) * 1995-07-07 1997-01-21 Nippon Seiko Kk Bearing for electric motor
US5759309A (en) * 1996-08-28 1998-06-02 Caterpillar Inc. Thermal process for selectively hardening track chain links
US7040080B2 (en) 2002-06-14 2006-05-09 Komatsu Ltd. Track link production method and track link produced by the same
KR100791739B1 (en) * 2003-08-29 2008-01-04 오므론 가부시키가이샤 Wireless ic tag joining method, wireless ic tag-carrying article, and vehicle
US8188016B2 (en) 2003-07-08 2012-05-29 Ntn Corporation Lubricant composition and bearing using same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5500058A (en) * 1994-08-16 1996-03-19 Topy Kogyo Kabushiki Kaisha Method for producing a vehicular endless track link
JPH0921424A (en) * 1995-07-07 1997-01-21 Nippon Seiko Kk Bearing for electric motor
US5759309A (en) * 1996-08-28 1998-06-02 Caterpillar Inc. Thermal process for selectively hardening track chain links
US7040080B2 (en) 2002-06-14 2006-05-09 Komatsu Ltd. Track link production method and track link produced by the same
US8188016B2 (en) 2003-07-08 2012-05-29 Ntn Corporation Lubricant composition and bearing using same
KR100791739B1 (en) * 2003-08-29 2008-01-04 오므론 가부시키가이샤 Wireless ic tag joining method, wireless ic tag-carrying article, and vehicle

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