JPH0585767A - Chemically durable glass fiber - Google Patents
Chemically durable glass fiberInfo
- Publication number
- JPH0585767A JPH0585767A JP3238692A JP3238692A JPH0585767A JP H0585767 A JPH0585767 A JP H0585767A JP 3238692 A JP3238692 A JP 3238692A JP 3238692 A JP3238692 A JP 3238692A JP H0585767 A JPH0585767 A JP H0585767A
- Authority
- JP
- Japan
- Prior art keywords
- mol
- glass
- glass fiber
- bao
- cao
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Reinforced Plastic Materials (AREA)
- Glass Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、耐水性、耐酸性および
耐アルカリ性に優れたガラス繊維に関し、特にＦＲＰ
（ファイバー強化プラスチック）用、ＧＲＣ（ガラス繊
維強化コンクリート）用、アスベスト代替用、及びバッ
テリーセパレータ用等の複合材料の補強材或いは耐蝕性
材料に適した化学的耐久性ガラス繊維に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glass fiber having excellent water resistance, acid resistance and alkali resistance, and particularly FRP.
The present invention relates to a chemically durable glass fiber suitable as a reinforcing material or a corrosion resistant material for composite materials such as (fiber reinforced plastic), GRC (glass fiber reinforced concrete), asbestos substitute, and battery separator.
【０００２】[0002]
【従来の技術】従来、上記用途に使用されているガラス
繊維として、ＦＲＰ用には米国特許２，３３４，９６１
号に記載のようなＳｉＯ2 −Ｂ2Ｏ3 −Ａｌ2 Ｏ3 −Ｃ
ａＯ系のＥガラスが用いられており、ＧＲＣ用には特公
昭４９−４０１２６号に記載のようなＳｉＯ2 −ＺｒＯ
2 −Ｎａ2 Ｏ系のジルコニア含有ガラスが用いられてい
る。2. Description of the Related Art Conventionally, as glass fibers used for the above-mentioned applications, US Pat. No. 2,334,961 has been used for FRP.
No. 2 as SiO 2 --B 2 O 3 --Al 2 O 3 --C
aO and E glass is used for system, SiO 2 -ZrO like is for GRC described in JP-B-49-40126
A 2- Na 2 O-based zirconia-containing glass is used.
【０００３】Ｅガラスは、耐水性に優れておりアルカリ
溶出の小さいガラスであるが、酸やアルカリに対して著
しく侵食されるために、セメント中でアルカリによる侵
食をうけるＧＲＣ用には使用できない。一方、ジルコニ
ア含有ガラスは耐アルカリ性、耐酸性に優れているが、
耐水性が不十分で、且つ、アルカリ溶出量が大きいため
に、プラスチックの補強材としての作用をなさずＦＲＰ
用には使用できない。E-glass is a glass having excellent water resistance and small alkali elution, but since it is significantly corroded by acid and alkali, it cannot be used for GRC which is corroded by alkali in cement. On the other hand, zirconia-containing glass is excellent in alkali resistance and acid resistance,
Due to insufficient water resistance and large amount of alkali elution, it does not act as a reinforcing material for plastic FRP
Can not be used for.
【０００４】[0004]
【発明が解決しようとする課題】このために、ＦＥＰ用
にはＥガラスが、ＧＲＣ用にはジルコニア含有ガラスが
専用的に用いられているが、両方の用途に共用されてお
らず不経済である。また近年、耐蝕性に優れたＦＲＰが
求められており、それにはより化学的耐久性に優れたガ
ラス繊維が必要とされ、一方ＧＲＣ用にも複合材料の強
度の向上がより図れる補強材としてのガラス繊維が要求
されているが、従来のガラスはこれ等の要求を満足する
ものではない。For this reason, E glass is exclusively used for FEP and zirconia-containing glass is exclusively used for GRC, but it is uneconomical because it is not used for both purposes. is there. Further, in recent years, there has been a demand for FRP having excellent corrosion resistance, which requires glass fibers having more excellent chemical durability. On the other hand, as a reinforcing material for GRC, which can further improve the strength of the composite material. Although glass fibers are required, conventional glass does not meet these requirements.
【０００５】また通常、ガラス繊維を得るためには、所
定割合に配合されたガラス原料を溶融して均質なガラス
とした後、多数のノズルを底部に形成したブッシングに
溶融ガラスを供給し、ブッシングのノズルからガラスを
引き出すことによって繊維化する方法が採られるが、Ｅ
ガラスやビルコニア含有ガラスは、繊維化する際の温
度、すなわち粘度１０2.5 ポイズに相当する温度（以
下、ＴF という）が、１２５０℃以上と高いため、ブッ
シングが劣化しやすく、短期間で取り替える必要があ
る。Further, in order to obtain glass fiber, usually, a glass raw material mixed in a predetermined ratio is melted to form a homogeneous glass, and then the molten glass is supplied to a bushing having a large number of nozzles formed at the bottom thereof, and the bushing is made. The method of fiberizing by taking out the glass from the nozzle of
Glass and viruconia-containing glass have a high temperature at the time of fiberizing, that is, a temperature corresponding to a viscosity of 10 2.5 poise (hereinafter referred to as T F ) as high as 1250 ° C. or higher, so that the bushing easily deteriorates, and it is necessary to replace it in a short time. There is.
【０００６】本発明は上記の事情に鑑みてなされたもの
であり、耐酸性、耐アルカリ性および耐水性の全てにお
いて優れた特性を有し、ＦＲＰやＧＲＣ等の複合材料の
補強材として、或いは耐蝕性が必要とされる用途の材料
として有用であり、しかもＴF が１２００°以下である
ため、ブッシングの劣化が非常に少ない化学的耐久性ガ
ラス繊維を提供することを目的とする。The present invention has been made in view of the above circumstances, has excellent properties in all of acid resistance, alkali resistance and water resistance, and is used as a reinforcing material for a composite material such as FRP or GRC or as a corrosion resistant material. It is an object of the present invention to provide a chemically durable glass fiber which is useful as a material for applications requiring properties, and has a T F of 1200 ° or less, so that deterioration of the bushing is extremely small.
【０００７】[0007]
【課題を解決するための手段】本発明者等は、前記目的
に合致するガラス繊維を種々検討し研究を重ねた結果、
儀の発明に到達した。Means for Solving the Problems As a result of various studies and researches on glass fibers which meet the above-mentioned objects, the present inventors have found that
The invention of the rite was reached.
【０００８】すなわち、本発明の化学的耐久性ガラス繊
維は、モル％で、ＳｉＯ2 ４６〜７０、ＴｉＯ2 ５
〜１８、ＺｒＯ2 １〜１２、ＴｉＯ2 ＋ＺｒＯ2 １
２〜２５、ＭｇＯ０〜１０、ＣａＯ ０〜１８、ＳｒＯ
０〜１２、ＢａＯ ４〜１５、ＺｎＯ ０〜１０、Ｍ
ｇＯ＋ＣａＯ＋ＳｒＯ＋ＢａＯ＋ＺｎＯ １２〜３５、
Ｌｉ2 Ｏ ０〜１０、Ｎａ2 Ｏ １〜１０、Ｋ2 Ｏ ０
〜１０、Ｌｉ2 Ｏ＋Ｎａ2 Ｏ＋Ｋ2 Ｏ ２〜１２からな
り、且つ、これらの合量が９０％以上の組成からなるこ
とを特徴とする。That is, the chemically durable glass fiber of the present invention contains, in mol%, SiO 2 46 to 70, TiO 2 5
-18, ZrO 2 1-12, TiO 2 + ZrO 2 1
2-25, MgO 0-10, CaO 0-18, SrO
0-12, BaO 4-15, ZnO 0-10, M
gO + CaO + SrO + BaO + ZnO 12-35,
Li 2 O 0-10, Na 2 O 1-10, K 2 O 0
10, it consists of Li 2 O + Na 2 O + K 2 O 2~12, and these total content characterized by comprising the composition of 90%.
【０００９】また本発明の化学的耐久性ガラス繊維は、
好ましくは、モル％で、ＳｉＯ2 ５０〜６５％、ＴｉＯ
2 ６〜１８、ＺｒＯ2 ２〜１０、ＴｉＯ2 ＋ＺｒＯ
2 １２〜２３、ＭｇＯ ０〜５、ＣａＯ ２〜１３、Ｓ
ｒＯ ２〜１０、ＢａＯ４〜１２、ＺｎＯ０〜５、Ｍｇ
Ｏ＋ＣａＯ＋ＳｒＯ＋ＢａＯ＋ＺｎＯ １３〜３０、Ｌ
ｉ2 Ｏ ０〜５、Ｎａ2 Ｏ ３〜９．５、Ｋ2 Ｏ ０〜
５、Ｌｉ2 Ｏ＋Ｎａ2 Ｏ＋Ｋ2 Ｏ ３〜１１からなり、
且つ、これらの合量が９０％以上の組成からなることを
特徴とする。Further, the chemically durable glass fiber of the present invention comprises
Preferably, in mol%, SiO 2 50-65%, TiO 2.
2 6-18, ZrO 2 2-10, TiO 2 + ZrO
2 12-23, MgO 0-5, CaO 2-13, S
rO 2-10, BaO 4-12, ZnO 0-5, Mg
O + CaO + SrO + BaO + ZnO 13-30, L
i 2 O 0 to 5, Na 2 O 3 to 9.5, K 2 O 0
5, consisting of Li 2 O + Na 2 O + K 2 O 3-11,
Further, it is characterized in that the total amount of them is 90% or more.
【００１０】[0010]
【作用】本発明の化学的耐久性ガラス繊維は、酸に強い
ＳｉＯ2 成分とアルカリに強いＺｒＯ2 成分およびＴｉ
Ｏ2 成分が必須成分として特定範囲で含有され、且つ、
ガラスの紡糸性に寄与するＢａＯ等の２価金属酸化物の
成分が含有されているので、Ｎａ2 Ｏ等のアルカリ金属
酸化物の存在にもかかわらず、全体として優れた化学的
耐久性を有し、しかも繊維化できるものである。The chemically durable glass fiber of the present invention comprises a SiO 2 component resistant to acid, a ZrO 2 component resistant to alkali and Ti.
O 2 component is contained as an essential component in a specific range, and
Since it contains a component of a divalent metal oxide such as BaO that contributes to the spinnability of glass, it has excellent chemical durability as a whole despite the presence of an alkali metal oxide such as Na 2 O. In addition, it can be made into fibers.
【００１１】次に本発明の化学的耐久性ガラス繊維の各
成分について、上記のように限定した理由を説明する。Next, the reasons for limiting each component of the chemically durable glass fiber of the present invention as described above will be explained.
【００１２】ＳｉＯ2 の含有量は、４６〜７０モル％、
好ましくは、５０〜６５モル％である。４６モル％より
少ない場合には耐酸性が低下し、７０モル％より多い場
合には耐アルカリ性が低下する。The content of SiO 2 is 46 to 70 mol%,
It is preferably 50 to 65 mol%. When it is less than 46 mol%, the acid resistance is lowered, and when it is more than 70 mol%, the alkali resistance is lowered.
【００１３】ＴｉＯ2 の含有量は、５〜１８モル％、好
ましくは、６〜１８モル％である。５モル％より少ない
場合には、ガラスの耐アルカリ性が低下すると共に、Ｔ
F が高くなり、１８モル％より多い場合には、失透温度
（以下、ＴL という）が高くなり、ＴF とＴL の差（以
下、ΔＴという）が小さくなって紡糸性が悪くなる。The content of TiO 2 is 5 to 18 mol%, preferably 6 to 18 mol%. When it is less than 5 mol%, the alkali resistance of the glass is deteriorated and T
When F becomes high and exceeds 18 mol%, the devitrification temperature (hereinafter referred to as T L ) becomes high, the difference between T F and T L (hereinafter referred to as ΔT) becomes small, and the spinnability deteriorates. ..
【００１４】すなわちＴL がＴF を超えると、ガラス融
液中に失透物が生じ、ノズル付近で糸切れが起こり易く
なるため、ＴL は、ＴF より低い温度であることを繊維
化の条件であり、その差が大きいほど紡糸性が良好とな
る。That is, when T L exceeds T F , devitrified substances are generated in the glass melt, and thread breakage easily occurs near the nozzle. Therefore, T L is a temperature lower than T F. And the larger the difference, the better the spinnability.
【００１５】ＺｒＯ2 の含有量は、１〜１２モル％、好
ましくは、２〜１０モル％である。１モル％より少ない
場合には、ガラスの耐アルカリ性が低下し、１２モル％
より多い場合には、ΔＴが小さくなり、紡糸性が悪くな
る。The content of ZrO 2 is 1 to 12 mol%, preferably 2 to 10 mol%. If it is less than 1 mol%, the alkali resistance of the glass decreases, and
When it is more, ΔT becomes smaller and the spinnability becomes worse.
【００１６】ただしＴｉＯ2 とＺｒＯ2 の合量は、１２
〜２５モル％、好ましくは、１２〜２３モル％に規制す
る。すなわち両成分が合量で、１２モル％より少ない場
合にはガラスの耐アルカリ性が低下し、２５モル％より
多い場合にはΔＴが小さくなり、紡糸性が悪くなる。However, the total amount of TiO 2 and ZrO 2 is 12
To 25 mol%, preferably 12 to 23 mol%. That is, if the total amount of both components is less than 12 mol%, the alkali resistance of the glass is lowered, and if it is more than 25 mol%, ΔT is decreased and the spinnability is deteriorated.
【００１７】ＭｇＯの含有量は、０〜１０モル％、好ま
しくは、０〜５モル％である。１０モル％より多い場合
には、ΔＴが小さくなり、紡糸性が悪くなる。The content of MgO is 0 to 10 mol%, preferably 0 to 5 mol%. When it is more than 10 mol%, ΔT becomes small and the spinnability deteriorates.
【００１８】ＣａＯの含有量は、０〜１８モル％、好ま
しくは、２〜１３モル％である。１８モル％より多い場
合には、ΔＴが小さくなり、紡糸性が悪くなる。The content of CaO is 0 to 18 mol%, preferably 2 to 13 mol%. When it is more than 18 mol%, ΔT becomes small and spinnability deteriorates.
【００１９】ＳｒＯの含有量は、０〜１２モル％、好ま
しくは、２〜１０モル％である。１２モル％より多い場
合には、ΔＴが小さくなり、紡糸性が悪くなる。The content of SrO is 0 to 12 mol%, preferably 2 to 10 mol%. When it is more than 12 mol%, ΔT becomes small and the spinnability deteriorates.
【００２０】ＢａＯの含有量は、４〜１５モル％、好ま
しくは、４〜１２モル％である。４モル％より少ない場
合および１５モル％より多い場合には、ΔＴが小さくな
り、紡糸性が悪くなる。The content of BaO is 4 to 15 mol%, preferably 4 to 12 mol%. When it is less than 4 mol% or more than 15 mol%, ΔT becomes small and the spinnability deteriorates.
【００２１】ＺｎＯの含有量は、０〜１０モル％、好ま
しくは、０〜５モル％である。１０モル％より多い場合
には、ΔＴが小さくなり、紡糸性が悪くなる。The content of ZnO is 0 to 10 mol%, preferably 0 to 5 mol%. When it is more than 10 mol%, ΔT becomes small and the spinnability deteriorates.
【００２２】ただし、ＭｇＯ＋ＣａＯ＋ＢａＯ＋ＳｒＯ
＋ＺｎＯが１２モル％より少ない場合および３５モル％
より多い場合にも、ΔＴが小さくなり、紡糸性が悪くな
る。However, MgO + CaO + BaO + SrO
+ ZnO less than 12 mol% and 35 mol%
When it is more, ΔT becomes smaller and the spinnability deteriorates.
【００２３】Ｌｉ2 Ｏの含有量は、０〜１０モル％、好
ましくは、０〜５モル％である。１０モル％より多い場
合には、ガラスの耐水性が低下し、アルカリ溶出量が多
くなる。The content of Li 2 O is 0 to 10 mol%, preferably 0 to 5 mol%. When it is more than 10 mol%, the water resistance of the glass is lowered and the amount of alkali elution is increased.
【００２４】Ｎａ2 Ｏの含有量は、１〜１０モル％、好
ましくは、３〜９．５モル％である。１モル％より少な
い場合には、ΔＴが小さくなるため、紡糸性が悪くな
り、１０モル％より多い場合には、ガラスの耐水性が低
下し、アルカリ溶出量が増大する。The content of Na 2 O is 1 to 10 mol%, preferably 3 to 9.5 mol%. When it is less than 1 mol%, ΔT becomes small, so that the spinnability is deteriorated, and when it is more than 10 mol%, the water resistance of the glass decreases and the amount of alkali elution increases.
【００２５】Ｋ2 Ｏの含有量は、０〜１０モル％、好ま
しくは、０〜５モル％である。１０モル％より多い場合
には、ガラスの耐水性が低下し、アルカリ溶出量が増大
する。The content of K 2 O is 0 to 10 mol%, preferably 0 to 5 mol%. If it is more than 10 mol%, the water resistance of the glass is lowered and the amount of alkali elution is increased.
【００２６】ただしＬｉ2 Ｏ＋Ｎａ2 Ｏ＋Ｋ2 Ｏが２モ
ル％より少ない場合には、ΔＴが小さくなるため、紡糸
性が悪くなり、１２モル％より多い場合にはガラスの耐
水性が低下すると共にアルカリ溶出量が増大する。However, when the content of Li 2 O + Na 2 O + K 2 O is less than 2 mol%, ΔT becomes small, resulting in poor spinnability. The elution amount increases.
【００２７】本発明のガラスでは上記した成分が少なく
とも９０モル％以上を占めるが、他に１０モル％以下の
範囲内で、ＭｎＯ、ＳｎＯ、ＦｅＯ、Ｆｅ2Ｏ3 、Ａｌ
2 Ｏ3 、Ｐ2 Ｏ5 などの添加成分を含んでも差し支えな
い。しかしながら、これら添加成分の合計が１０モル％
を超えると紡糸性に問題を生じるため好ましくない。さ
らにＢ2 Ｏ3 やＦ2 は、製造工程において環境を害する
ため含有しない方が良い。In the glass of the present invention, the above-mentioned components occupy at least 90 mol% or more, but within the range of 10 mol% or less, MnO, SnO, FeO, Fe 2 O 3 , Al
Additives such as 2 O 3 and P 2 O 5 may be included. However, the total amount of these additional components is 10 mol%
If it exceeds the range, spinnability may be deteriorated, which is not preferable. Further, B 2 O 3 and F 2 should not be contained because they harm the environment in the manufacturing process.
【００２８】[0028]
【実施例】次に本発明の化学的耐久性ガラス繊維を実施
例に基づいて詳細に説明する。EXAMPLES Next, the chemically durable glass fiber of the present invention will be described in detail based on examples.
【００２９】表１、表２および表３は、本発明の実施例
および比較例の各試料のガラス組成と特性を示すもので
ある。比較例としては、従来ガラスであるＥガラス及び
ジルコニア含有ガラスを挙げた。Tables 1, 2 and 3 show the glass compositions and characteristics of the samples of the examples and comparative examples of the present invention. As comparative examples, conventional E glass and zirconia-containing glass were mentioned.
【００３０】[0030]
【表１】 [Table 1]
【００３１】[0031]
【表２】 [Table 2]
【００３２】[0032]
【表３】 [Table 3]
【００３３】表１、表２および表３に示した各試料は次
のようにして作成した。まず表に示す組成になるように
ガラス原料を調合し、白金坩堝を用いて１５００℃で４
時間溶融した。溶融後、融液を鉄板上に流し出し、厚さ
５mmの板状に成形して以下の測定に供するガラス試料を
得た。The samples shown in Table 1, Table 2 and Table 3 were prepared as follows. First, glass raw materials were mixed so as to have the composition shown in the table, and the mixture was mixed with a platinum crucible at 1500 ° C. for 4 hours.
Melted for hours. After melting, the melt was poured onto an iron plate and molded into a plate having a thickness of 5 mm to obtain a glass sample to be used in the following measurement.
【００３４】耐水性は、板状ガラス試料を粉砕し直径２
９７〜５００μm の粒度のガラスを比重グラム精秤し、
これを純水１００mlの入ったテフロン製容器中に密封し
てオートクレーブに入れ、１８０℃で１０時間保持した
後の重量減少率を測定した。この重量減少率が小さいほ
ど耐水性が良いことを示しており、以下の特性測定につ
いても同様である。Water resistance was measured by crushing a plate glass sample to a diameter of 2
Glass with a particle size of 97-500 μm is precisely weighed in specific gravity gram,
This was sealed in a Teflon container containing 100 ml of pure water, placed in an autoclave, and kept at 180 ° C. for 10 hours, and then the weight reduction rate was measured. The smaller the weight reduction rate, the better the water resistance, and the same applies to the following characteristic measurements.
【００３５】耐水性に関連する別の評価方法のアルカリ
溶出量については、ＪＩＳ Ｒ３５０２の方法に基づい
て測定した。The amount of alkali elution in another evaluation method relating to water resistance was measured based on the method of JIS R3502.
【００３６】耐酸性は上記耐水性測定の時と同様の粉砕
ガラス粒を比重グラム精秤し、これらを１０％のＨＣｌ
液１００ml中に浸漬し、８０℃、９６時間の条件で振と
うした後、その重量減少率を測定した。For acid resistance, ground glass particles were precisely weighed in the same manner as in the above-mentioned water resistance measurement, and the specific gravity gram was weighed to obtain 10% HCl.
After dipping in 100 ml of the liquid and shaking at 80 ° C. for 96 hours, the weight loss rate was measured.
【００３７】耐アルカリ性は上記耐水性及び耐酸性の測
定の時と同様の粉砕ガラス粒を比重グラム精秤後、１０
％のＮａＯＨ水溶液１００ml中に浸漬し、８０℃、１６
時間の条件で振とうした後、その重量減少率を測定し
た。Alkali resistance was determined by precisely weighing the crushed glass particles in the same manner as in the above-mentioned measurement of water resistance and acid resistance, and then measuring the specific gravity in grams.
% Aqueous NaOH solution 100ml, 80 ℃, 16
After shaking under the condition of time, the weight loss rate was measured.
【００３８】ＴF は、先記したように粘度１０2.5 ポイ
ズに相当する温度であり、白金球引き上げ法によって測
定し、ＴL は、ガラス試料の一部を２９７〜５００μm
の粉末にしてから、白金ボートに入れ、温度勾配を有す
る電気炉に１６時間保持した後、放冷し、顕微鏡で失透
出現位置を観察することによって測定した。T F is a temperature corresponding to a viscosity of 10 2.5 poise as described above, and is measured by a platinum ball pulling method, and T L is a part of a glass sample of 297 to 500 μm.
The powder was put in a platinum boat, held in an electric furnace having a temperature gradient for 16 hours, allowed to cool, and the devitrification appearance position was observed with a microscope.
【００３９】表１から、本発明のガラスは、比較例のＥ
ガラスに比べて耐酸性と耐アルカリ性に優れ、また比較
例のジルコニア含有ガラスに比べて耐水性に優れ、アル
カリ溶出量が少なく、従って本発明のガラスは、耐水
性、耐酸性および耐アルカリ性について総じて良好な特
性を兼ね備えたものであることが認められる。From Table 1, the glass of the present invention has a comparative example E
Excellent in acid resistance and alkali resistance as compared with glass, and also excellent in water resistance as compared with the zirconia-containing glass of Comparative Example, and has a small amount of alkali elution. Therefore, the glass of the present invention is generally water resistance, acid resistance and alkali resistance. It is recognized that they have good characteristics.
【００４０】また本発明のガラスは、比較例のガラスと
同様、ＴF がＴL より高く、またΔＴが４０℃以上であ
るため、繊維化が可能であり、しかも比較例のガラスに
比べてＴF が低いため、ブッシングの劣化が少ないこと
が理解できる。Further, the glass of the present invention, like the glass of the comparative example, has T F higher than T L and ΔT of 40 ° C. or more, and thus can be made into fibers, and moreover, compared with the glass of the comparative example. It can be understood that the bushing is less deteriorated because T F is low.
【００４１】尚、各ガラス試料を粉砕し、白金ブッシン
グに入れ、白金ブッシングに直接通電してガラスを溶融
し、ノズル温度を１０2.5 ポイズ温度に設定しておい
て、ブッシング底部のノズルから引き出すことによっ
て、繊維化が可能であるか否かを試験したところ、いず
れも繊維化が可能であった。Each glass sample was crushed, put into a platinum bushing, the platinum bushing was directly energized to melt the glass, and the nozzle temperature was set at 10 2.5 poise temperature, and the glass was pulled out from the nozzle at the bottom of the bushing. When it was tested whether or not fiberization was possible, it was found that fiberization was possible in all cases.
【００４２】[0042]
【発明の効果】以上のように本発明のガラス繊維は、耐
水性、耐酸性および耐アルカリ性に優れており、各種の
複合材料の補強材として広く用いることができ、また耐
蝕性が要求される用途にその使用範囲を拡大できる効果
がある。INDUSTRIAL APPLICABILITY As described above, the glass fiber of the present invention is excellent in water resistance, acid resistance and alkali resistance, can be widely used as a reinforcing material for various composite materials, and is required to have corrosion resistance. It has the effect of expanding the range of its usage.
【００４３】さらに本発明のガラス繊維は、Ｅガラスや
ジルコニア含有ガラスに比べてＴF が低いため、ブッシ
ングの劣化が少なく、取り替え期間を長くすることが可
能となる。Furthermore, since the glass fiber of the present invention has a lower T F than E glass and zirconia-containing glass, the bushing is less deteriorated and the replacement period can be extended.
Claims (2)
Ｏ2 ５〜１８、ＺｒＯ2 １〜１２、ＴｉＯ2 ＋Ｚｒ
Ｏ2 １２〜２５、ＭｇＯ ０〜１０、ＣａＯ ０〜１
８、ＳｒＯ ０〜１２、ＢａＯ ４〜１５、ＺｎＯ ０
〜１０、ＭｇＯ＋ＣａＯ＋ＳｒＯ＋ＢａＯ＋ＺｎＯ １
２〜３５、Ｌｉ2 Ｏ ０〜１０、Ｎａ2 Ｏ １〜１０、
Ｋ2 Ｏ ０〜１０、Ｌｉ2 Ｏ＋Ｎａ2 Ｏ＋Ｋ2 Ｏ ２〜
１２からなり、且つ、これらの合量が９０％以上の組成
からなることを特徴とする化学的耐久性ガラス繊維。1. SiO 2 46-70, Ti, in mol%.
O 2 5-18, ZrO 2 1-12, TiO 2 + Zr
O 2 12~25, MgO 0~10, CaO 0~1
8, SrO 0-12, BaO 4-15, ZnO 0
-10, MgO + CaO + SrO + BaO + ZnO 1
2-35, Li 2 O 0-10, Na 2 O 1-10,
K 2 O 0~10, Li 2 O + Na 2 O + K 2 O 2~
A chemically durable glass fiber, which is composed of 12 and has a total content of 90% or more.
Ｏ2 ６〜１８、ＺｒＯ2 ２〜１０、ＴｉＯ2 ＋Ｚｒ
Ｏ2 １２〜２３、ＭｇＯ ０〜５、ＣａＯ２〜１３、
ＳｒＯ ２〜１０、ＢａＯ ４〜１２、ＺｎＯ ０〜
５、ＭｇＯ＋ＣａＯ＋ＳｒＯ＋ＢａＯ＋ＺｎＯ １３〜
３０、Ｌｉ2 Ｏ ０〜５、Ｎａ2 Ｏ３〜９．５、Ｋ2 Ｏ
０〜５、Ｌｉ2 Ｏ＋Ｎａ2 Ｏ＋Ｋ2 Ｏ ３〜１１から
なり、且つ、これらの合量が９０％以上の組成からなる
ことを特徴とする請求項１の化学的耐久性ガラス繊維。2. SiO 2 50-65, Ti, in mol%.
O 2 6-18, ZrO 2 2-10, TiO 2 + Zr
O 2 12-23, MgO 0-5, CaO 2-13,
SrO 2-10, BaO 4-12, ZnO 0-
5, MgO + CaO + SrO + BaO + ZnO 13-
30, Li 2 O 0 to 5, Na 2 O 3 to 9.5, K 2 O
0-5, it consists of Li 2 O + Na 2 O + K 2 O 3~11, and chemical durability of glass fibers according to claim 1, these total content characterized by comprising the composition of 90%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3238692A JPH0585767A (en) | 1991-02-19 | 1992-02-19 | Chemically durable glass fiber |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4754791 | 1991-02-19 | ||
| JP3-47547 | 1991-02-19 | ||
| JP3238692A JPH0585767A (en) | 1991-02-19 | 1992-02-19 | Chemically durable glass fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0585767A true JPH0585767A (en) | 1993-04-06 |
Family
ID=26370950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3238692A Withdrawn JPH0585767A (en) | 1991-02-19 | 1992-02-19 | Chemically durable glass fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0585767A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1561732A1 (en) * | 2002-10-15 | 2005-08-10 | Nippon Electric Glass Co., Ltd | Glass composition and glass fiber |
| JP2009513470A (en) * | 2005-10-28 | 2009-04-02 | サン ゴバン ヴェトロテックス フランス ソシエテ アノニム | Alkali and acid resistant glass compositions for the production of glass strands |
| EP2402620A1 (en) | 2010-06-30 | 2012-01-04 | Pias Sales Co., Ltd. | Clinch bolt |
| US9212086B2 (en) | 2006-10-25 | 2015-12-15 | Owens Corning Intellectual Capital, Llc | Chemically resistant glass composition for the manufacture of glass reinforcing strands |
-
1992
- 1992-02-19 JP JP3238692A patent/JPH0585767A/en not_active Withdrawn
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1561732A1 (en) * | 2002-10-15 | 2005-08-10 | Nippon Electric Glass Co., Ltd | Glass composition and glass fiber |
| EP1561732A4 (en) * | 2002-10-15 | 2008-10-08 | Nippon Electric Glass Co | Glass composition and glass fiber |
| US7629279B2 (en) | 2002-10-15 | 2009-12-08 | Nippon Electric Glass Co., Ltd. | Glass fiber |
| JP2009513470A (en) * | 2005-10-28 | 2009-04-02 | サン ゴバン ヴェトロテックス フランス ソシエテ アノニム | Alkali and acid resistant glass compositions for the production of glass strands |
| US9790122B2 (en) | 2005-10-28 | 2017-10-17 | Ocv Intellectual Capital, Llc | Alkali-and acid-resistant glass composition for the manufacture of glass strands |
| US9212086B2 (en) | 2006-10-25 | 2015-12-15 | Owens Corning Intellectual Capital, Llc | Chemically resistant glass composition for the manufacture of glass reinforcing strands |
| US9932263B2 (en) | 2006-10-25 | 2018-04-03 | Ocv Intellectual Capital, Llc | Glass composition having improved hydraulic resistance for the manufacture of glass reinforcing strands |
| EP2402620A1 (en) | 2010-06-30 | 2012-01-04 | Pias Sales Co., Ltd. | Clinch bolt |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2019081707A (en) | Glass compositions and fibers made of glass compositions | |
| US5064785A (en) | Alkali-resistant glass for forming glass fibers | |
| JP6202318B2 (en) | Glass composition for glass fiber, glass fiber and method for producing glass fiber | |
| CA2811360A1 (en) | Low dielectric glass and fiber glass | |
| GB2025928A (en) | Alkali-resistant glass composition | |
| SK280485B6 (en) | Glass-fiber compositions | |
| CN109982982B (en) | Glass composition for glass fiber, and method for producing glass fiber | |
| EP0500325A1 (en) | Chemically resistant glass fiber composition | |
| MX2012009772A (en) | A composition for preparing ceramic fiber and a biosoluble ceramic fiber prepared therefrom for heat insulating material at high temperature. | |
| JP3132234B2 (en) | Glass long fiber | |
| US11577990B2 (en) | Glass fiber and method for producing same | |
| WO2016093212A1 (en) | Glass composition for glass fiber, glass fiber, and method for producing glass fiber | |
| WO2020230550A1 (en) | Glass composition for glass fibers | |
| JPH0585767A (en) | Chemically durable glass fiber | |
| JP3584586B2 (en) | Corrosion resistant glass fiber | |
| JP3801293B2 (en) | Corrosion resistant glass fiber | |
| JPH06157072A (en) | Corrosion resistant glass fiber | |
| JPH10231143A (en) | Corrosion-resistant glass fiber | |
| JP3771073B2 (en) | Glass fiber | |
| JPH11157876A (en) | Corrosion resistant glass fiber | |
| JP7235928B1 (en) | Glass fibers and compositions for glass fibers | |
| JPH10203845A (en) | Corrosion resistant glass fiber | |
| JPH11157875A (en) | Corrosion resistant glass fiber | |
| WO2024106292A1 (en) | Glass fiber and composition for glass fiber | |
| WO2023106048A1 (en) | Glass fibers, method for manufacturing glass fibers, and glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 19990518 |