JPH0577059B2 - - Google Patents
Info
- Publication number
- JPH0577059B2 JPH0577059B2 JP14005785A JP14005785A JPH0577059B2 JP H0577059 B2 JPH0577059 B2 JP H0577059B2 JP 14005785 A JP14005785 A JP 14005785A JP 14005785 A JP14005785 A JP 14005785A JP H0577059 B2 JPH0577059 B2 JP H0577059B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- diazo
- layer forming
- water
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000011118 polyvinyl acetate Substances 0.000 description 5
- 229920002689 polyvinyl acetate Polymers 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000035553 feeding performance Effects 0.000 description 2
- 239000012669 liquid formulation Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 1
- SZCWECLZCCHJRZ-UHFFFAOYSA-N NCCCN1CCOCC1.C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 Chemical compound NCCCN1CCOCC1.C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 SZCWECLZCCHJRZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005553 polystyrene-acrylate Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/60—Compositions containing diazo compounds as photosensitive substances with macromolecular additives
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、自動給紙性能及び原稿との自動分離
性能を改善したジアゾ複写材料に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a diazo copying material with improved automatic paper feeding performance and automatic separation performance from original documents.
（従来の技術）
紙、プラスチツクフイルム等の支持体の表面に
プレコート層及びジアゾ感光層、裏面にバツクコ
ート層を設けたジアゾ複写材料が知られている。
このプレコート層は微粒子シリカなどの顔料と結
合剤とからなるもので、画像濃度を上げ画像の色
調をいつそう鮮明にするためと、筆記性をもたせ
るために設けられる。また、バツクコート層は結
合剤のみからなるもので、ジアゾ複写材料のカー
ル性を改良するために設けられるのである。(Prior Art) Diazo copying materials are known in which a precoat layer and a diazo photosensitive layer are provided on the surface of a support such as paper or plastic film, and a backcoat layer is provided on the back surface.
This precoat layer is made of a pigment such as particulate silica and a binder, and is provided to increase the image density, sharpen the color tone of the image, and provide writability. Further, the back coat layer consists only of a binder and is provided to improve the curling properties of the diazo copying material.
このようなジアゾ複写材料は摩擦係数が大きい
ので、自動給紙や自動分離機構を持つた複写機に
通すと、ジアゾ複写材料どうしの表面の摩擦によ
り給紙出来なかつたり、また、給紙出来ても一度
に重なつて給紙されたり、ジアゾ複写材料と原稿
との自動分離が非常に困難であつた。 Such diazo copying materials have a large coefficient of friction, so if they are passed through a copying machine with an automatic paper feed or automatic separation mechanism, the friction between the surfaces of the diazo copying materials may cause the paper to not be fed or may not be able to be fed. Also, the sheets were sometimes fed overlapping each other at once, and it was very difficult to automatically separate the diazo copying material from the original.
（本発明が解決しようとする問題点）
本発明はこれら従来の問題点を解決するもので
あり、自動給紙や自動分離機構を持つた複写機に
使用できるジアゾ複写材料を提供するものであ
る。(Problems to be Solved by the Present Invention) The present invention solves these conventional problems and provides a diazo copying material that can be used in a copying machine having an automatic paper feeding and automatic separation mechanism. .
（問題点を解決するための手段）
本発明のジアゾ複写材料は、支持体の表面にプ
レコート層及びジアゾ感光層を設け、さらに裏面
にバツクコート層を設けたジアゾ複写材料におい
て、プレコート層及び／又はバツクコート層中に
粒径0.05〜10μｍの水分散型四フツ化エチレン樹
脂微粒子をプリコート層には塗布量の0.5〜10重
量％、バツクコート層には塗布量の0.1〜30重量
％の量で含有させたものである。(Means for Solving the Problems) The diazo copying material of the present invention is a diazo copying material in which a precoat layer and a diazo photosensitive layer are provided on the surface of a support, and a back coat layer is further provided on the back surface. Water-dispersed polytetrafluoroethylene resin particles with a particle size of 0.05 to 10 μm are contained in the back coat layer in an amount of 0.5 to 10% by weight of the coating amount in the precoat layer and 0.1 to 30% by weight of the coating amount in the back coat layer. It is something that
本発明において使用される水分散型四フツ化エ
チレン樹脂微粒子としては、四フツ化エチレン樹
脂の微粒子に非イオン活性剤を添加散させたもの
や適度の親水性を付与させたものが用いられる。
また、以下の理由により限定される。粒径が
0.05μｍより小さい場合は層形成液中で該微粒子
が凝集して、得られた層中に微粒子が均一に分散
していないので、本発明の目的が達成できない。
また粒径が10μｍより大きい場合は得られる複写
物の感触が好ましくない。 As the water-dispersed type tetrafluoroethylene resin fine particles used in the present invention, those prepared by adding and dispersing a nonionic activator to the tetrafluoroethylene resin fine particles or imparting appropriate hydrophilicity are used.
Furthermore, it is limited due to the following reasons. particle size
If the particle diameter is smaller than 0.05 μm, the particles will aggregate in the layer forming solution and will not be uniformly dispersed in the resulting layer, making it impossible to achieve the object of the present invention.
Furthermore, if the particle size is larger than 10 μm, the feel of the resulting copy is unfavorable.
本発明のジアゾ複写材料を作成するには、紙、
プラスチツクフイルム、布等の支持体上に特定の
水分散型四フツ化エチレン樹脂微粒子をプレコー
ト層形成液及び／又はバツクコート層形成液に含
有させる他は、従来の方法と同様に各層の形成液
を順次塗布乾燥すればよい。この場合、水分散型
四フツ化エチレン樹脂微粒子は、プレコート層形
成液には全体量の0.5〜10重量％好ましくは１〜
５重量％、バツクコート層形成液には全体量の
0.1〜30重量％好ましくは0.5〜10重量％の範囲で
含有させればよい。この範囲の下限より少ない含
有量では効果がない。また上限より含有量が多い
と発色性に悪影響を与えるる。 To make the diazo copying material of the present invention, paper,
The forming liquid for each layer is prepared in the same manner as in the conventional method, except that specific water-dispersed polytetrafluoroethylene resin fine particles are contained in the precoat layer forming liquid and/or the back coat layer forming liquid on a support such as a plastic film or cloth. Just apply and dry in sequence. In this case, the water-dispersible tetrafluoroethylene resin fine particles are added to the precoat layer forming liquid in an amount of 0.5 to 10% by weight, preferably 1 to 10% by weight of the total amount.
5% by weight, and the back coat layer forming liquid contains
It may be contained in a range of 0.1 to 30% by weight, preferably 0.5 to 10% by weight. Contents below the lower limit of this range are ineffective. Moreover, if the content is higher than the upper limit, color development will be adversely affected.
プレコート層に用いられる顔料は、微粒子シリ
カ、タルク、ケイソウ土、酸化マグネシウム等
が、また、結合剤としては、カゼインソーダ、水
溶性セルロース等の水溶性物質、ポリ酢酸ビニ
ル、ポリスチレン、ポリアクリル酸塩、ポリメタ
クリル酸塩等の水分散性物質が上げられる。 Pigments used in the precoat layer include fine particle silica, talc, diatomaceous earth, magnesium oxide, etc., and binders include casein soda, water-soluble substances such as water-soluble cellulose, polyvinyl acetate, polystyrene, and polyacrylates. and water-dispersible substances such as polymethacrylates.
また、ジアゾ感光層には従来と同じジアゾ化合
物、カツプラー、酸安定剤等の添加剤が使用され
る。カツプラーは現像液中に含有させて一成分型
ジアゾ複写材料として用いてもよい。 Further, the same additives as conventional ones such as diazo compounds, couplers, acid stabilizers, etc. are used in the diazo photosensitive layer. The coupler may be incorporated into a developer and used as a one-component diazo copying material.
以下に実施例及び比較例を示す。 Examples and comparative examples are shown below.
（実施例）
実施例 １
シリカ（粒径２〜9μｍ） ４重量部
ポリ酢酸ビニルエマルジヨン
（固形分50％） 10重量部
四フツ化エチレン樹脂水性デイスパージヨン
（固形分60％、粒径0.05〜10μｍ、非イオン活性
剤３〜４％） ３重量部
水 83重量部
よりなるプレコート層形成液を調製する。即ち水
60重量部中にシリカをよく分散し、ポリ酢酸ビニ
ルエマルジヨンを加え、緩やかに攪拌した後、四
フツ化エチレン樹脂水性デイスパージヨンを加
え、再び緩やかに攪拌し、水で全量を100重量と
する。(Example) Example 1 Silica (particle size 2 to 9 μm) 4 parts by weight Polyvinyl acetate emulsion (solid content 50%) 10 parts by weight Tetrafluoroethylene resin aqueous dispersion (solid content 60%, particle size 0.05 ~10 μm, 3 to 4% nonionic active agent) A precoat layer forming solution consisting of 3 parts by weight of water and 83 parts by weight of water is prepared. i.e. water
Disperse silica well in 60 parts by weight, add polyvinyl acetate emulsion, stir gently, add tetrafluoroethylene resin aqueous dispersion, stir gently again, and bring the total amount to 100 parts by weight with water. do.
一方、下記処方の感光層形成液を用意する。 On the other hand, a photosensitive layer forming liquid having the following formulation is prepared.
グリセリン ３重量部
クエン酸 １重量部
２−ヒドロキシ、３−ナフトエ酸アミノプロピ
ルモルフオリン ２重量部
４−モルホリノ−２，５−ジブトキシベンゼン
ジアゾニウムクロライド塩化亜鉛複塩
１重量部
水 93重量部
また、バツクコート層形成液として下記処方の
ものを用意する。 Glycerin 3 parts by weight Citric acid 1 part by weight 2-hydroxy, 3-naphthoic acid aminopropylmorpholin 2 parts by weight 4-morpholino-2,5-dibutoxybenzenediazonium chloride zinc chloride double salt
1 part by weight Water 93 parts by weight Also, prepare the following formulation as a back coat layer forming liquid.
ポリ酢酸ビニルエマルジヨン
（固形分50％） ３重量部
水 97重量部
次に複写用原紙の表面に前記プリコート層形成
液を乾燥重量で約３〜５ｇ／m2となるように塗布
乾燥した後、感光層形成液を乾燥重量で約1.5
ｇ／m2程度に塗布乾燥し、さらに、裏面にバツク
コート層形成液を乾燥重量で約0.5〜１ｇ／m2と
なるように塗布乾燥してジアゾ複写材料を作成し
た。 Polyvinyl acetate emulsion (solid content 50%) 3 parts by weight Water 97 parts by weight Next, the pre-coat layer forming liquid was applied to the surface of the base paper for copying at a dry weight of about 3 to 5 g/m 2 and dried. , the dry weight of the photosensitive layer forming liquid is approximately 1.5
A diazo copying material was prepared by coating and drying the coating to a weight of about 0.5 to 1 g/m 2 on the back side, and then coating and drying a back coat layer forming liquid to a dry weight of about 0.5 to 1 g/m 2 .
比較例 １
実施例１においてプレコート層形成液処方から
四フツ化エチレン樹脂水性デイスパージヨンを除
いた他は同様にしてジアゾ複写材料を作成した。Comparative Example 1 A diazo copying material was prepared in the same manner as in Example 1 except that the tetrafluoroethylene resin aqueous dispersion was omitted from the precoat layer forming liquid formulation.
実施例 ２
下記処方のプレコート層形成液を実施例１の方
法に従つて用意した。Example 2 A precoat layer forming solution having the following formulation was prepared according to the method of Example 1.
シリカ（粒径１〜5μｍ） ４重量部
スチレン・アクリル共重合エマルジヨン（固形
分43％） 10重量部
水 86重量部
一方、感光層形成液は実施例１と同様のものを
用意した。 Silica (particle size 1 to 5 μm) 4 parts by weight Styrene-acrylic copolymer emulsion (solid content 43%) 10 parts by weight Water 86 parts by weight On the other hand, the same photosensitive layer forming liquid as in Example 1 was prepared.
また、バツクコート層形成液として下記処方を
用意した。 In addition, the following formulation was prepared as a back coat layer forming liquid.
ポリ酢酸ビニルエマルジヨン
（固形分50％） ３重量部
四フツ化エチレン樹脂水性デイスパージヨン
（実施例１と同じもの） １重量部
水 93重量部
次に、以上の各層形成液を実施例１と同様に塗
布乾燥してジアゾ複写材料を得た。 Polyvinyl acetate emulsion (solid content 50%) 3 parts by weight Tetrafluoroethylene resin aqueous dispersion (same as in Example 1) 1 part by weight Water 93 parts by weight Next, each of the above layer forming liquids was added to Example 1. A diazo copying material was obtained by coating and drying in the same manner as above.
比較例 ２
実施例２においてバツクコート層形成液処方か
ら四フツ化エチレン樹脂水性デイスパージヨンを
除いた他は同様にしてジアゾ複写材料を作成し
た。Comparative Example 2 A diazo copying material was prepared in the same manner as in Example 2 except that the tetrafluoroethylene resin aqueous dispersion was omitted from the back coat layer forming liquid formulation.
実施例 ３
実施例１において、バツクコート層形成液を実
施例２で用意したものに変えた他は同様にしてジ
アゾ複写材料を作成した。Example 3 A diazo copying material was prepared in the same manner as in Example 1 except that the back coat layer forming liquid was changed to that prepared in Example 2.
以上のようにして得られた各ジアゾ複写材料を
自動給紙と自動分離機構を持つた複写機（リコ
ー：SD580）でテストを行つたところ、本発明で
は自動分離性能並びに自動給紙性能は極めて良好
であつた。しかし、比較品では自動給紙しなかつ
たりジアゾ複写材料と原稿との自動分離が困難で
あつた。 When testing each of the diazo copying materials obtained as described above using a copying machine (Ricoh: SD580) equipped with automatic paper feeding and automatic separation mechanisms, it was found that the automatic separation performance and automatic paper feeding performance of the present invention were extremely high. It was good and warm. However, the comparative product did not automatically feed paper, and it was difficult to automatically separate the diazo copying material from the original.
Claims (1)
層を設け、さらに裏面にバツクコート層を設けた
ジアゾ複写材料において、プレコート層及び／又
はバツクコート層中に粒径0.05〜10μｍの水分散
型四フツ化エチレン樹脂微粒子をプリコート層に
は塗布量の0.5〜10重量％、バツクコート層には
塗布量の0.1〜30重量％の量で含有したジアゾ複
写材料。1. In a diazo copying material in which a precoat layer and a diazo photosensitive layer are provided on the surface of a support, and a backcoat layer is further provided on the back surface, water-dispersed ethylene tetrafluoride with a particle size of 0.05 to 10 μm is contained in the precoat layer and/or the backcoat layer. A diazo copying material containing fine resin particles in an amount of 0.5 to 10% by weight of the coating amount in the precoat layer and 0.1 to 30% by weight of the coating amount in the back coat layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14005785A JPS61296351A (en) | 1985-06-25 | 1985-06-25 | Diazo copying material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14005785A JPS61296351A (en) | 1985-06-25 | 1985-06-25 | Diazo copying material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61296351A JPS61296351A (en) | 1986-12-27 |
| JPH0577059B2 true JPH0577059B2 (en) | 1993-10-25 |
Family
ID=15259984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14005785A Granted JPS61296351A (en) | 1985-06-25 | 1985-06-25 | Diazo copying material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61296351A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080187691A1 (en) * | 2007-02-07 | 2008-08-07 | S.D. Warren Company | Rapid Ink Drying Papers |
-
1985
- 1985-06-25 JP JP14005785A patent/JPS61296351A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61296351A (en) | 1986-12-27 |
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