JPH0574540B2 - - Google Patents
Info
- Publication number
- JPH0574540B2 JPH0574540B2 JP28732989A JP28732989A JPH0574540B2 JP H0574540 B2 JPH0574540 B2 JP H0574540B2 JP 28732989 A JP28732989 A JP 28732989A JP 28732989 A JP28732989 A JP 28732989A JP H0574540 B2 JPH0574540 B2 JP H0574540B2
- Authority
- JP
- Japan
- Prior art keywords
- particles
- amount
- composite material
- particle
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002245 particle Substances 0.000 claims description 71
- 239000002131 composite material Substances 0.000 claims description 34
- 239000002270 dispersing agent Substances 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 21
- 239000004567 concrete Substances 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 9
- 239000008030 superplasticizer Substances 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 239000011398 Portland cement Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000009827 uniform distribution Methods 0.000 claims description 2
- 229910003480 inorganic solid Inorganic materials 0.000 claims 2
- 239000004576 sand Substances 0.000 description 9
- 238000010276 construction Methods 0.000 description 8
- 239000004575 stone Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- 239000011435 rock Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011372 high-strength concrete Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Description
（産業上の利用分野）
本発明は主に一軸ミキサあるいは二軸ミキサで
混練し、レミコンカーで施工現場まで運搬し、バ
ケツトまたはポンプ圧送によつて打設、施工でき
る高耐久性コンクリート、高耐磨性コンクリー
ト、超高強度コンクリート用として主として用い
られる水硬性複合材料に係るものである。
（従来の技術）
粒径50Å〜0.5μmの粒子Ａと、粒径0.5〜
100μm、かつ粒子Ａより少なくとも１オーダー大
きい個体粒子Ｂと、表面活性分散剤を含む水硬性
複合材料において、粒子Ａの量は、粒子Ｂが前記
複合材料中に実質的に変形されずに相互に実質的
に接触し、かつ橋かけ現象が実質的に存在しない
状態で密に充填されたときに、粒子Ｂの間の空隙
に理論的に充填されうる量以下の量であり、水の
量は、前記複合材料中に粒子Ｂが前記規定の如く
密に充填され、かつその密充填された粒子Ｂの間
の空隙に粒子Ａが均一に分布したときに、粒子Ｂ
および粒子Ａの間に形成される空隙を丁度満たす
ように、〔粒子Ａ＋粒子Ｂ〕に対する重量比が0.3
％以下であり、かつ、表面活性分散剤の量は、前
記複合材料を混合して前記規定の如き粒子Ｂの密
な充填と上記規定の如き粒子Ａの均一な分布を達
成するのに充分なように、乾燥状態における量が
〔粒子Ａ＋粒子Ｂ〕の合計重量を基準に計算して
1.0〜4.0重量％の範囲にあり、更に粒子Ｂより大
きい寸法を少なくとも１つ有している追加の素材
Ｃを含んでいる水硬性複合材料が、特公昭60−
59182号公報において提案されている。
（発明が解決しようとする課題）
前記従来の水硬性複合材料においては、追加の
素材Ｃとして川砂、川砂利、天然の岩石や玉砂利
等を破砕した砕石、破砂等が使用されている。
これら砕石、破砂等は天然のものであり、強度
にばらつきがある。
前記川砂、川砂利、天然の岩石や玉砂利等を破
砕した砕石、破砂等の天然の材料を追加の素材Ｃ
として用いた水硬性複合材料の強度を利用できる
範囲は、追加の素材Ｃの中で最も強度の低い値に
なる場合が多く、結果的には水硬性複合材料の利
用できる強度が低くなる。
また前記従来の水硬性複合材料においては、表
面活性剤の乾燥状態における量が、〔粒子Ａ＋粒
子Ｂ〕の合計重量を基準に計算して1.0〜4.0重量
％の範囲にあり、これは通常のコンクリートに用
いる表面活性分散剤の乾燥状態における量が0.2
〜0.8重量％の範囲にあるものが殆んどであるこ
とを考えると、高価な表面活性分散剤の使用量が
多きに過ぎ、不経済である。
またこのように表面活性分散剤の使用量が多い
と、水硬性複合材料の粘性が大となり、打設、施
工したのち沈降がみられる。
本発明は前記従来技術の有する問題点を解決す
るために提案されたもので、その目的とする処
は、利用できる強度の範囲が高く、表面活性分散
剤の使用量が少なく、打設、施工後の沈降が少な
い水硬性複合材料を提供する点にある。
〔課題を解決するための手段）
前記の目的を達成するため、本発明に係る水硬
性複合材料は、前記追加の素材Ｃを、少なくとも
１つ以上が組成の中にAl2O3が40〜60％，ZrO2が
30〜50％の範囲で含まれている素材より構成する
とともに、表面活性分散剤の乾燥状態における
〔粒子Ａ＋粒子Ｂ〕の合計重量を基準に計算して
0.6〜1.0重量％の範囲とし、粒子Ｂの少なくとも
20重量％がポルトランドセメントで、表面活性分
散剤はコンクリートスーパープラスチサイザーガ
リグニンスルホン酸高縮合物Na塩、メラミンス
ルホン酸縮合物からなり、活性分散剤の量が0.6
〜１重量％である
（作用）
本発明に係る水硬性複合材料においては、前記
追加の素材Ｃとして、組成の中にAl2O3が40〜60
％，ZrO2が30〜50％の範囲で含まれている人工
のものを使用したので強度のばらつきが少なく、
前記川砂、川砂利、天然の岩石や玉砂利等を破砕
した天然の砕石、砕砂の平均的硬度より遥かに硬
いため、結果的に水硬性複合材料の利用できる強
度を高くすることができる。
また前記追加の素材Ｃは耐熱性が大で、同素材
Ｃを用いた水硬性複合材料の耐熱性も向上でき
る。
更に前記追加の素材Ｃは人工のものであるの
で、物性のばらつきが少なく、物性の調整も可能
で、同素材Ｃを用いた水硬性複合材料の物性にば
らつきを生じる惧れも少ない。
更にまた本発明によれば、表面活性分散剤の乾
燥状態における量を、〔粒子Ａ＋粒子Ｂ〕の合計
重量を基準として0.6〜1.0重量％の範囲としたこ
とによつて、表面活性分散剤の使用量を節減し、
しかも強度、混練時間とも、前記従来の水硬性複
合材料に比して遜色のない、経済性の優れた水硬
性複合材料が得られるものであり、打設後、施工
後の沈降も少ない。
また本発明によれば前記したように、表面活性
分散剤の使用量が少ないため、水硬性複合材料の
流動性は水の量によつて大きく左右され、僅かな
使用水量の差で施工不能になる惧れがあるが、前
記追加の素材Ｃの少なくとも１つは人工のもので
あるので、吸水率や比重を正確に把握することが
でき、従つて水硬性複合材料の表面水や含水率の
正確な調整が可能となり、施工できなくなる惧れ
がなくなる。
更にまた本発明によれば表面活性分散剤がコン
クリートスーパープラスチサイザーガリグニンス
ルホン酸高縮合物Na塩、メラミンスルホン酸縮
合物から構成されているので施工性が改善され、
より強度が向上される。
（実施例）
以下本発明をコンクリートに適用した実施例に
ついて説明する。
同コンクリートにおける粒子Ａとして、50000
〜2000000cm2／ｇの比表面積を有する市販のシリ
カダスト粒子を、粒子Ｂとして少なくとも20％重
量のポルトランドセメントを、表面活性分散剤と
してコンリートスーパープラスチサイザーを用
い、調合水の〔粒子Ａ＋粒子Ｂ〕に対する重量比
が、0.1〜0.3の範囲にあり、前記表面活性分散剤
の乾燥状態の重量が、〔粒子Ａ＋粒子Ｂ〕の合計
重量を基準に計算して0.6〜1.0重量％の範囲にあ
るように構成されている。
更に前記追加の素材Ｃとして、組成の中でAl2
O3が40〜60％、ZrO2が30〜５％の範囲で含まれ
ているジルコナイトの細骨材を使用した。
表−１は同ジルコナイトの組成を示す。
(Industrial Application Field) The present invention is mainly concerned with highly durable concrete, which can be mixed with a single-shaft mixer or a twin-shaft mixer, transported to the construction site in a remixer truck, and cast and constructed by bucket or pump pumping. This relates to hydraulic composite materials that are mainly used for high-strength concrete and ultra-high strength concrete. (Prior art) Particle A with a particle size of 50 Å to 0.5 μm and particle size 0.5 to 0.5 μm.
In a hydraulic composite material comprising solid particles B of 100 μm and at least one order of magnitude larger than particles A, and a surface-active dispersant, the amount of particles A is such that the particles B are substantially undeformed and interoperable in said composite material. The amount of water is less than the amount that can be theoretically filled into the voids between particles B when they are in close contact with each other and are packed densely in a state where there is substantially no cross-linking phenomenon, and the amount of water is , when the particles B are densely packed in the composite material as specified above, and the particles A are uniformly distributed in the gaps between the tightly packed particles B, the particles B
And the weight ratio to [particle A + particle B] is 0.3 so as to exactly fill the voids formed between particles A.
% and the amount of surface-active dispersant is sufficient to mix said composite material to achieve close packing of particles B as defined above and uniform distribution of particles A as defined above. As shown, the amount in the dry state is calculated based on the total weight of [particle A + particle B].
A hydraulic composite material containing an additional material C in the range of 1.0 to 4.0% by weight and further having at least one dimension larger than the particle B is disclosed in Japanese Patent Publication No. 1986-
This is proposed in Publication No. 59182. (Problems to be Solved by the Invention) In the conventional hydraulic composite material, river sand, river gravel, crushed stone obtained by crushing natural rock, gravel, etc., crushed sand, etc. are used as the additional material C. These crushed stones, crushed sand, etc. are natural materials and vary in strength. Additional materials C include natural materials such as river sand, river gravel, crushed stone made by crushing natural rocks and gravel, crushed sand, etc.
The range in which the strength of the hydraulic composite material used as the material can be utilized is often the lowest value among the additional materials C, and as a result, the usable strength of the hydraulic composite material becomes low. In addition, in the conventional hydraulic composite material, the amount of the surfactant in the dry state is in the range of 1.0 to 4.0% by weight calculated based on the total weight of [particles A + particles B], which is higher than the normal amount. The amount of surface active dispersant used in concrete in the dry state is 0.2
Considering that most of the dispersants are in the range of ~0.8% by weight, the amount of expensive surface-active dispersants used is too large, which is uneconomical. Furthermore, if the amount of surface-active dispersant used is large, the viscosity of the hydraulic composite material increases, and sedimentation is observed after pouring and construction. The present invention was proposed in order to solve the problems of the prior art, and its objectives are to provide a wide range of usable strength, use a small amount of surface-active dispersant, and improve the ease of pouring and construction. The object of the present invention is to provide a hydraulic composite material with little subsequent settling. [Means for Solving the Problems] In order to achieve the above object, the hydraulic composite material according to the present invention includes at least one of the additional materials C in a composition containing 40 to 40% Al 2 O 3 . 60%， ZrO2
It is composed of materials containing 30 to 50% of the surface active dispersant, and is calculated based on the total weight of [particles A + particles B] in the dry state of the surface active dispersant.
The range is from 0.6 to 1.0% by weight, and at least
20% by weight is Portland cement, the surface active dispersant consists of Concrete Super Plasticizer galignine sulfonic acid high condensate Na salt, melamine sulfonic acid condensate, and the amount of active dispersant is 0.6
-1% by weight (effect) In the hydraulic composite material according to the present invention, the additional material C contains 40 to 60% Al 2 O 3 in the composition.
%, ZrO2 was used in the range of 30 to 50%, so there was little variation in strength.
Since it is much harder than the average hardness of the river sand, river gravel, natural crushed stones and crushed sand obtained by crushing natural rocks and gravel, it is possible to increase the strength that can be used as a hydraulic composite material. Further, the additional material C has high heat resistance, and the heat resistance of a hydraulic composite material using the same material C can also be improved. Furthermore, since the additional material C is artificial, there is little variation in physical properties, the physical properties can be adjusted, and there is little risk of variations in the physical properties of the hydraulic composite material using the same material C. Furthermore, according to the present invention, the amount of the surface-active dispersant in a dry state is in the range of 0.6 to 1.0% by weight based on the total weight of [particles A + particles B]. Reduce usage,
In addition, it is possible to obtain a hydraulic composite material which is comparable in strength and kneading time to the conventional hydraulic composite materials and is superior in economic efficiency, and also has less settling after casting and construction. In addition, according to the present invention, as mentioned above, since the amount of surface active dispersant used is small, the fluidity of the hydraulic composite material is greatly influenced by the amount of water, and even a small difference in the amount of water used can make construction impossible. However, since at least one of the additional materials C is artificial, the water absorption rate and specific gravity can be accurately determined, and therefore the surface water and water content of the hydraulic composite material can be accurately determined. Accurate adjustment becomes possible, and there is no fear that construction will not be possible. Furthermore, according to the present invention, since the surface active dispersant is composed of Concrete Super Plasticizer galignine sulfonic acid high condensate Na salt and melamine sulfonic acid condensate, workability is improved.
Strength is further improved. (Example) An example in which the present invention is applied to concrete will be described below. As particle A in the same concrete, 50,000
Commercially available silica dust particles with a specific surface area of ~2000000 cm 2 /g were mixed with [Particle A + Particle B] in the blended water using at least 20% by weight of Portland cement as Particle B and Conrete Super Plasticizer as the surface active dispersant. The weight ratio of the surface active dispersant to the surface active dispersant is in the range of 0.1 to 0.3, and the dry weight of the surface active dispersant is in the range of 0.6 to 1.0% by weight, calculated based on the total weight of [particles A + particles B]. It is composed of Furthermore, as the additional material C, Al 2
Zirconite fine aggregate containing 40-60% O 3 and 30-5% ZrO 2 was used. Table 1 shows the composition of the zirconite.
【表】【table】
【表】
また前記コンクリートスーパープラスチサイザ
ーとしては、リグニンスルホン酸ソーダ、グリコ
ン酸ソーダ、β−ナフタリンスルホン酸高縮合物
Na塩、メラミンスルホン酸縮合物が使用される。
次に前記追加の素材Ｃとしてジルコナイトを使
用した本発明のコンクリートと、同素材Ｃとして
前記天然の砕石、砕砂を使用した従来のコンクリ
ート（甲）、（乙）との強度試験結果を、表−２に
示す。
なお前記各コンクリートの水セメント比は21％
で、同一のコンクリートスーパープラスチサイザ
ーを使用した。
表−２より明らかなように、追加の素材Ｃとし
てジルコナイトの細骨材を使用した本発明のコン
クリートの28日圧縮強度は、砕砂を使用した従来
のコンクリートより遥かに高い。[Table] The concrete super plasticizers include sodium ligninsulfonate, sodium glyconate, and β-naphthalenesulfonic acid high condensate.
Na salt, melamine sulfonic acid condensate are used. Next, the strength test results of the concrete of the present invention using zirconite as the additional material C and the conventional concrete (A) and (B) using the natural crushed stone and crushed sand as the same material C are shown in Table-- Shown in 2. The water-cement ratio of each concrete mentioned above is 21%.
The same concrete super plasticizer was used. As is clear from Table 2, the 28-day compressive strength of the concrete of the present invention using zirconite fine aggregate as additional material C is much higher than the conventional concrete using crushed sand.
【表】
また前記本発明のコンクリートの一軸ミキサ、
あるいは二軸ミキサでの混練に要する時間は従来
のコンクリートと大差なく、またスランプ値は低
いが、粘度も少なく、従つて打設、施工後の沈降
が少ない。
（発明の効果）
本発明によれば、前述したように、水と〔粒子
Ａ＋粒子Ｂ〕の重量比が0.1〜0.3の水硬性複合材
料において、前記粒子Ｂより大きい寸法を少なく
とも１つ有している追加の素材Ｃを含んでおり、
少なくとも１つ以上が組成の中にAl2O3が40〜60
％，ZrO2が30〜50％の範囲で含まれているよう
に構成したことによつて、前記複合性材料の利用
できる強度を高くし、また物性のばらつきを少な
くし、更に耐熱性を向上するものである。
更に本発明によれば、表面活性分散剤の乾燥状
態における量を、〔粒子Ａ＋粒子Ｂ〕の合計重量
％を基準にして、0.6〜1.0重量％の範囲内とした
ことによつて、高価な表面活性分散剤の使用量を
節減し、更に、表面活性分散剤をコンクリートス
ーパープラスチサイザーガリグニンスルホン酸高
縮合物Na塩、メラミンスルホン酸縮合物より構
成したことと相俟つて。強度、混練時間の点にお
いて、前記従来の水硬性複合材料と遜色のない経
済性の優れた水硬性複合材料が構成され、更に打
設、施工後の沈降が少ない水硬性複合材料が得ら
れる。[Table] Also, the concrete uniaxial mixer of the present invention,
Alternatively, the time required for mixing with a twin-screw mixer is not much different from that of conventional concrete, and although the slump value is low, the viscosity is also low, so there is little settling after pouring and construction. (Effects of the Invention) According to the present invention, as described above, in a hydraulic composite material in which the weight ratio of water and [particles A + particles B] is 0.1 to 0.3, at least one particle has a size larger than the particle B. Contains additional material C,
At least one Al 2 O 3 in the composition is 40-60
%, ZrO 2 is contained in the range of 30 to 50%, thereby increasing the usable strength of the composite material, reducing variations in physical properties, and further improving heat resistance. It is something to do. Furthermore, according to the present invention, the amount of the surface-active dispersant in the dry state is within the range of 0.6 to 1.0% by weight based on the total weight% of [particles A + particles B], thereby reducing the cost of expensive The amount of surface-active dispersant used is reduced, and the surface-active dispersant is composed of concrete super plasticizer galignine sulfonic acid high condensate Na salt and melamine sulfonic acid condensate. In terms of strength and kneading time, a hydraulic composite material with excellent economic efficiency comparable to the conventional hydraulic composite materials is constructed, and furthermore, a hydraulic composite material with less settling after casting and construction can be obtained.
Claims (1)
Ａ（以下「粒子Ａ」と称する。）と、粒径の大きさ
が0.5〜100μmかつ粒子Ａよりすくなくとも１オ
ーダー大きい固体粒子Ｂ（以下「粒子Ｂ」と称す
る。）と、表面活性分散剤を含む水硬性複合材料
であつて、 粒子Ａの量は、粒子Ｂが前記複合材料中に実質
的に変形されずに相互に実質的に接触し、かつ橋
かけ現象が実質的に存在しない状態で密に充填さ
れうる量以下の量として、 粒子Ａの量が粒子Ａの量＋粒子Ｂの量の合計容
積の0.1〜50容積％の量で存在し、 水の量は、前記複合材料中に粒子Ｂが前記規定
の如く密に充填され、かつその密充填された粒子
Ｂの間の空隙に粒子Ａが均一に分布したときに、
粒子Ｂおよび粒子Ａの間に形成される空隙を満た
す程度の量として、 水と〔粒子Ａ＋粒子Ｂ〕の重量比が0.1〜0.3の
範囲内であり、かつ 表面活性分散剤の量は、前記複合材料を混合し
て前記規定の如き粒子Ｂの密な充填と前記規定の
如き粒子Ａの均一な分布を達成するのに充分な量
以上の量であり、 表面活性分散剤の乾燥状態における量が〔粒子
Ａ＋粒子Ｂ〕の合計重量を基準に計算して0.6〜
1.0重量％の範囲内にあり、更に前記複合材料が
粒子Ｂより大きい寸法を少なくとも１つ有してい
る追加の素材Ｃを含んでおり、少なくとも１つ以
上が組成の中にAl2O3が40〜60％，ZrO2が30〜50
％の範囲で含まれ、 粒子Ｂの少なくとも20重量％がポルトランドセ
メント粒子で、 表面活性分散剤はコンクリートスーパープラス
チサイザーガリグニンスルホン酸高縮合物Na塩、
メラミンスルホン酸縮合物からなる、 ことを特徴とする水硬性複合材料。 ２ 粒子Ａが50000〜2000000cm2／ｇの比表面積を
有するシリカダスト粒子である請求項１に記載の
水硬性複合材料。 ３ 粒子Ａが50000〜2000000cm2／ｇの比表面積を
有するシリカダスト粒子であり、粒子Ｂがポルト
ランドセメントを少なくとも20重量％を含み、表
面活性分散剤がコンクリートスーパープラスチサ
イザーである請求項１に記載の水硬性複合材料。[Scope of Claims] 1. Inorganic solid particles A (hereinafter referred to as "particles A") having a particle size of 50 Å to 0.5 μm, and inorganic solid particles A having a particle size of 0.5 to 100 μm and at least one order of magnitude larger than particles A. A hydraulic composite material comprising large solid particles B (hereinafter referred to as "particles B") and a surface-active dispersant, the amount of particles A being such that the particles B are not substantially deformed in the composite material. The amount of particles A is equal to the total volume of the amount of particles A + the amount of particles B. It is present in an amount of 0.1 to 50% by volume, and the amount of water is such that the particles B are densely packed in the composite material as specified above, and the particles A are uniformly distributed in the voids between the tightly packed particles B. When distributed in
The weight ratio of water and [particles A + particles B] is within the range of 0.1 to 0.3, and the amount of the surface active dispersant is as described above, as an amount sufficient to fill the voids formed between particles B and particles A. an amount sufficient to mix the composite material to achieve a close packing of particles B as defined above and a uniform distribution of particles A as defined above; an amount in the dry state of the surface-active dispersant; is calculated based on the total weight of [Particle A + Particle B] and is 0.6~
1.0% by weight, and the composite material further includes an additional material C having at least one dimension larger than the particles B, at least one of which has Al 2 O 3 in the composition. 40~60%, ZrO2 30~50
%, at least 20% by weight of particles B are Portland cement particles, and the surface active dispersant is Concrete Super Plasticizer Garignin Sulfonic Acid High Condensate Na Salt,
A hydraulic composite material comprising a melamine sulfonic acid condensate. 2. The hydraulic composite material according to claim 1, wherein the particles A are silica dust particles having a specific surface area of 50000 to 2000000 cm 2 /g. 3. Particle A is a silica dust particle having a specific surface area of 50,000 to 2,000,000 cm 2 /g, particle B contains at least 20% by weight of Portland cement, and the surface-active dispersant is concrete superplasticizer. hydraulic composite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1287329A JPH03150247A (en) | 1989-11-06 | 1989-11-06 | Hydraulic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1287329A JPH03150247A (en) | 1989-11-06 | 1989-11-06 | Hydraulic composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03150247A JPH03150247A (en) | 1991-06-26 |
| JPH0574540B2 true JPH0574540B2 (en) | 1993-10-18 |
Family
ID=17715957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1287329A Granted JPH03150247A (en) | 1989-11-06 | 1989-11-06 | Hydraulic composite material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03150247A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6059182A (en) * | 1983-09-09 | 1985-04-05 | Sunstar Giken Kk | Manufacture of leathery sheet material |
| JPH01160854A (en) * | 1987-11-05 | 1989-06-23 | Corhart Refractories Co | Fire-proof castables of high strength and abrasion resistance |
-
1989
- 1989-11-06 JP JP1287329A patent/JPH03150247A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6059182A (en) * | 1983-09-09 | 1985-04-05 | Sunstar Giken Kk | Manufacture of leathery sheet material |
| JPH01160854A (en) * | 1987-11-05 | 1989-06-23 | Corhart Refractories Co | Fire-proof castables of high strength and abrasion resistance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03150247A (en) | 1991-06-26 |
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| LAPS | Cancellation because of no payment of annual fees |