JPH057337B2 - - Google Patents
Info
- Publication number
- JPH057337B2 JPH057337B2 JP61149333A JP14933386A JPH057337B2 JP H057337 B2 JPH057337 B2 JP H057337B2 JP 61149333 A JP61149333 A JP 61149333A JP 14933386 A JP14933386 A JP 14933386A JP H057337 B2 JPH057337 B2 JP H057337B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polymer
- glass fiber
- aqueous
- treatment composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003365 glass fiber Substances 0.000 claims description 181
- 239000000203 mixture Substances 0.000 claims description 137
- 229920000642 polymer Polymers 0.000 claims description 135
- 238000011282 treatment Methods 0.000 claims description 99
- 239000000126 substance Substances 0.000 claims description 82
- 239000011159 matrix material Substances 0.000 claims description 41
- 239000002216 antistatic agent Substances 0.000 claims description 40
- 239000004593 Epoxy Substances 0.000 claims description 36
- 125000001931 aliphatic group Chemical group 0.000 claims description 30
- -1 acryloxy Chemical group 0.000 claims description 29
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 29
- 125000002091 cationic group Chemical group 0.000 claims description 29
- 239000000314 lubricant Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 23
- 239000011521 glass Substances 0.000 claims description 23
- 229920000728 polyester Polymers 0.000 claims description 22
- 238000009736 wetting Methods 0.000 claims description 21
- 125000003545 alkoxy group Chemical group 0.000 claims description 20
- 239000007822 coupling agent Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 17
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000009833 condensation Methods 0.000 claims description 9
- 230000005494 condensation Effects 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000004848 polyfunctional curative Substances 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 230000001939 inductive effect Effects 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000005643 Pelargonic acid Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 229920001225 polyester resin Polymers 0.000 claims description 5
- 239000004645 polyester resin Substances 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 238000012993 chemical processing Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000007046 ethoxylation reaction Methods 0.000 claims description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 238000005461 lubrication Methods 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229920001281 polyalkylene Polymers 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 229910052810 boron oxide Inorganic materials 0.000 claims 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 2
- 239000000292 calcium oxide Substances 0.000 claims 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims 2
- 239000000395 magnesium oxide Substances 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 38
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 24
- 238000000034 method Methods 0.000 description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 17
- 229920000647 polyepoxide Polymers 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003822 epoxy resin Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 10
- 229930185605 Bisphenol Natural products 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 229910000077 silane Inorganic materials 0.000 description 8
- 238000005481 NMR spectroscopy Methods 0.000 description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000011152 fibreglass Substances 0.000 description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 125000003700 epoxy group Chemical group 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 230000002238 attenuated effect Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000011151 fibre-reinforced plastic Substances 0.000 description 3
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002990 reinforced plastic Substances 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ORTVZLZNOYNASJ-UPHRSURJSA-N (z)-but-2-ene-1,4-diol Chemical compound OC\C=C/CO ORTVZLZNOYNASJ-UPHRSURJSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- UTLQFNPZWCRAIP-UHFFFAOYSA-N 3-(diethylamino)propyl 2-phenylheptanoate;hydrochloride Chemical compound [Cl-].CC[NH+](CC)CCCOC(=O)C(CCCCC)C1=CC=CC=C1 UTLQFNPZWCRAIP-UHFFFAOYSA-N 0.000 description 1
- MCSXGCZMEPXKIW-UHFFFAOYSA-N 3-hydroxy-4-[(4-methyl-2-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound Cc1ccc(N=Nc2c(O)c(cc3ccccc23)C(=O)Nc2cccc(c2)[N+]([O-])=O)c(c1)[N+]([O-])=O MCSXGCZMEPXKIW-UHFFFAOYSA-N 0.000 description 1
- GRAGBWDYQWZYKP-UHFFFAOYSA-N 4-[3,3-bis(4-hydroxyphenyl)propyl]phenol Chemical compound C1=CC(O)=CC=C1CCC(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 GRAGBWDYQWZYKP-UHFFFAOYSA-N 0.000 description 1
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920003265 Resimene® Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000009614 chemical analysis method Methods 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- 239000000109 continuous material Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- HOXINJBQVZWYGZ-UHFFFAOYSA-N fenbutatin oxide Chemical compound C=1C=CC=CC=1C(C)(C)C[Sn](O[Sn](CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C1=CC=CC=C1 HOXINJBQVZWYGZ-UHFFFAOYSA-N 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000010513 hydrogenated corn oil Substances 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
æ¬çºæã¯æ°Žæ§ååŠçåŠççšçµæç©ã§åŠçããã
ã¬ã©ã¹ç¹ç¶ã§ãããã«ïŒPanelïŒãç¹ã«åéæã®
ããã«ã補é ããçºã®éåäœãããªãã¯ã¹ãè£åŒ·
ããã®ã«çšããã®ã«çæ³çãªã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã«é¢ããã è£åŒ·ãã©ã¹ããã¯å·¥æ¥ã§ã¯æ¥µããŠå€ãã®è£œåã
補é ããããã®éåäœãããªãã¯ã¹ãè£åŒ·ããçº
ã«çš®ã ã®åœ¢ã®ã¬ã©ã¹ç¹ç¶ãçšããŠãããäŸãã°ã
ã¬ã©ã¹ç¹ç¶ã¯é£ç¶çåã³çŽ°æããåç¹ç¶åã³ã¹ã
ã©ã³ãããããããŒãã³ã°ïŒrovingïŒãç¹ç©åã³
äžç¹åžã®åœ¢ã§éåäœãè£åŒ·ããçºã«çšããããŠã
ããç±å¯å¡æ§åã³ç±ç¡¬åæ§éåäœãããªãã¯ã¹ã¯
äž¡æ¹ãšããèæ¿æåææãèåç©æåææãå°åº
æåçæç©ãåŽé§æåçæç©ãåã³åæ§ãªæåç
æç©ã®åŠã補åã補é ããã®ã«çš®ã ã®åœ¢ã®ã¬ã©ã¹
ç¹ç¶ã§è£åŒ·ãããŠæ¥ãã éåäœè£åŒ·ç©åžå Žã®çºã®ã¬ã©ã¹ç¹ç¶ã補é ãã
éã«ãã¬ã©ã¹ç¹ç¶ã¯æº¶èãããç¹ç¶åå¯èœãªã¬ã©
ã¹ææã®å ¥ã€ãçã«çµåãããå¥ç®¡ãªã©ã®è£ 眮ã
ãåºãç¹ç¶åå¯èœãªã¬ã©ã¹ææã®æº¶èæµãã现ã
ãããã§ãããã¬ã©ã¹ç¹ç¶ã¯ãéãŸã€ãåç¹ç¶ã
åéããŠããã±ãŒãžïŒPackageïŒã«ããå·»ãåã
åšãæã¯ç¹ç¶ãéããããŠçŽ°æãããåã«ããã
ç¹ç¶ãåŒåŒµãããŒã©ãŒã«ãã€ãŠçŽ°ãããããã¬ã©
ã¹ç¹ç¶ã補é ããæ¹æ³ã§ã¯ãååŠçåŠççšçµæç©
ããç¹ç¶ãã¬ã©ã¹æº¶èæµãšããŠçŽ°ããããããåŸ
ã§ãããã«é©çšããããååŠçåŠççšçµæç©ã¯é
åžžãã€ã«ã 圢ææ§ææã«ãããªã³ã°å€åã³æœ€æ»å€
ãæ £ç¿çã«å«ãã§ããæ°Žæ§çµæç©ã§ãããååŠç
åŠççšçµæç©ã¯ãããããã¬ã©ã¹ç¹ç¶åã¯ã¹ãã©
ã³ãã®æã«éããããæã¬ã©ã¹ç¹ç¶ã®åç¹ç¶çžäº
ã®æ©èãé ãããè£åŒ·ããããšããéåäœãããª
ãã¯ã¹ã«å¯Ÿããããã¬ã©ã¹ç¹ç¶ãçžå®¹æ§ã«ããçº
ã«å¿ èŠã§ãããå žåçã«ã¯ãååŠçã«åŠçããã
ã¬ã©ã¹ç¹ç¶ã¯ããã±ãŒãžã®åœ¢æã¯ç¹ç¶ãéåäœã
ããªãã¯ã¹ãè£åŒ·ããããã«çšããããåã®çŽ°æ
ãããã¹ãã©ã³ãã®åœ¢ã§ä¹Ÿç¥ããããéææã¯å
éæã®è£åŒ·ããããã©ã¹ããã¯æ¿ã®ãããªã¬ã©ã¹
ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã¯ã倪éœéå åšã倩
çªãç §æåšå ·ã®èŠãããã©ã¹ã®èŠããäž»èŠéè·¯ã®
æšèåã³èšå·ã枩宀ã®ã¬ã©ã¹çã®çšéãæããã
ã¬ã©ã¹ç¹ç¶è£åŒ·ç©ãæããåéæããã«ã®å Žåã
ã¬ã©ã¹ç¹ç¶ã¯ä»ã®è£åŒ·ãããéåäœçæç©ã®å Žå
ã«èŠæ±ãããéåžžã®ã¬ã©ã¹ç¹ç¶ç¹æ§ãè¶ ããç¹å¥
ãªç¹æ§ãæã€ãŠããªããã°ãªããªããäŸãã°ãã¬
ã©ã¹ç¹ç¶ã¯ããã«ã®æž æŸæ§æã¯èåæ§ãæžããã
ã®ã§ãã€ãŠã¯ãªãããã¬ã©ã¹ç¹ç¶ã¯ããã«è£œé ã®
éã®é©åãªå å·¥æ§ãæããªããã°ãªããªããé©å
ãªå å·¥æ§ã«ã¯è¯å¥œãªã¹ãã©ã³ã现ææ§ãããã«ã
補é ããéã®ã¹ãã©ã³ãå士ãæ¥çããåŸåãå°
ããããæ§è³ªãå²ãåœãŠãããåŠçæéã§éåäœ
ãããªãã¯ã¹äžã«ã¹ãã©ã³ãã容æã«åæ£ããæ§
質ãå«ãŸããããã®æè¡åéã§çŽé¢ããéåžžã«å°
ã€ãåé¡ã¯ãç¹å®ã®çš®é¡ã®ã¬ã©ã¹ç¹ç¶åã³æ°Žæ§å
åŠçåŠççšçµæç©ã®ç¹å®ã®æåãçšããŠå¿ èŠãªç¹
æ§ãåŸãããšãåºæ¥ã«ããããšã§ãããããå Žå
ã«ã¯ããã®å°é£æ§ã¯å®éã«äºãã«æä»çãªããã€
ãã®ç¹æ§ã«ãªãã æ¬çºæã®ç®çã¯ãã¬ã©ã¹ç¹ç¶è£åŒ·ãã©ã¹ãã
ã¯ãç¹ã«éææã¯åéæã¬ã©ã¹ç¹ç¶è£åŒ·ãã©ã¹ã
ãã¯æ¿ãžå å·¥ããããšãåºæ¥ãååŠçã«åŠçãã
ãã¬ã©ã¹ç¹ç¶ãäžããããšã§ããã ãæ¬çºæã®èŠçŽã ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã®å®è³ªçéšåã«ååšããæ°Žæ§
ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæããæ¬çºæã®
ã¬ã©ã¹ç¹ç¶ã¯ãéåäœãããªãã¯ã¹ãè£åŒ·ããã®
ã«è¯å¥œãªå å·¥æ§ãæããè¯å¥œãªèåæ§ãæãã硬
åãããªãã¯ã¹ãäžããã æ°Žæ§ååŠçåŠççšçµæç©ã¯åçš®é¡ã®ååçãªé
æ°Žæ§æåãæãããäžã€ã®éæ°Žæ§æåã¯äžçš®é¡ä»¥
äžã®æ°Žæº¶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã¹ããšããŒã«
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœã§ãããå
ç¬æã¯ããããªãã¯ã¹éåäœãšçžæº¶æ§ããããã
ãã«å¯æº¶æ§ã®ãšããã·å«æãã€ã«ã 圢ææ§éåäœ
ãšã®æ··åç©ã®åœ¢ã«ãªã€ãŠãããä»ã®é氎溶æ§æå
ã¯äžçš®é¡ä»¥äžã®ã¢ã¯ãªããã·åã¯ã¡ã¿ã¯ãªããã·
å«æææ©ã«ãããªã³ã°å€ã§ãããããã«å¥ã®éæ°Ž
æ§æåã¯äžçš®é¡ä»¥äžã®éœã€ãªã³æ§åç¹ç¶æœ€æ»å€ã
äŸãã°ãå°ãªããšãäžçš®é¡ããã©ã«ãŽã³é žã§ãã
èèªé žã§éšåçã«ã¢ããåïŒamidateïŒãããã
ãªã¢ã«ãã¬ã³ã€ãã³ã§ãããä»ã®éæ°Žæ§æåã¯ã
äžçš®é¡ä»¥äžã®ã¢ã«ã³ãã·éšåãæããéœã€ãªã³æ§
ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ããéé»é²æ¢å€ã§é
é»é²æ¢ã«æå¹ãªéã§ååšãããåèšçµæç©ã¯æ¬è³ª
çã«ç¡æ©éé»é²æ¢å€åã³æ°ŽçŽ åæ€ç©æ²¹ãå«ãŸãª
ããçµæç©äžã®æ°Žã®éã¯ã¬ã©ã¹ç¹ç¶ãæ°Žæ§åŠççš
çµæç©ã§åŠçåºæ¥ãããã«ãããããªéã§ããã
æŽã«ãæ°Žæ§çµæç©ã¯ã¹ãã©ã³ã硬åå€ãå«ãããš
ãåºæ¥ããéæ°Žæ§æåã®å€§éšåã®éã¯ãã€ã«ã 圢
ææ§éåäœãããªããææ©ã«ãããªã³ã°å€åã³æœ€
æ»å€ã¯ããããã«ãããªã³ã°åã³æœ€æ»ãè¡ãªãã
ãã®ã«æå¹ãªéã§ååšãããéé»é²æ¢å€ã®éé»é²
æ¢ã«æå¹ãªéã¯æ°Žæ§åŠççšçµæç©ã®çŽ0.05ã0.4
ééïŒ ã®ç¯å²ã«ããã æ¬çºæã®åºãæ æ§ãšããŠãæ°Žæ§åŠççšçµæç©ã¯
ç¹ç¶åå¯èœãªã¬ã©ã¹çµæç©ãã補é ãããã¬ã©ã¹
ç¹ç¶ã«é©çšããããããç¹ç¶ã¯åæãããã¹ãã©
ã³ãæã¯é£ç¶çã¹ãã©ã³ãã®å€å±€ããã±ãŒãžãžåœ¢
æããããæ¬çºæã®å¥œãŸããæ æ§ãšããŠãç¹ç¶å
å¯èœãªã¬ã©ã¹çµæç©ã¯1.5495ã1.5740ã®ç¯å²ã®äœ
ãå±æçãæããã¬ã©ã¹ç¹ç¶ããããããããªæ
æãããªã€ãŠããŠãè¯ãããããã®äžå°åŠçãã
ãïŒsizedïŒã¬ã©ã¹ç¹ç¶ã¯é©åœãªéåäœãããªã
ã¯ã¹ãè£åŒ·ããåéæãããæããªãã°éæãªã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœæ¿ã補é ããããšãåºæ¥ãã
åéæã®ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœæ¿ã¯ãèåæ§ãæ
ãªããæçœã«ã¯èŠããªãã¬ã©ã¹ç¹ç¶ãæããã ãæ¬çºæåã³å¥œãŸããå ·äœäŸã®è©³çŽ°ãªèšèŒã ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã補é ãã
éãã¬ã©ã¹ç¹ç¶ã¯ç¹å®ã®ç¹æ§ãæã€ãŠããªããã°
ãªããªããæŽã«è£åŒ·ãããéåäœææãã倩çªã
ãã©ã¹èŠããäž»çšéè·¯æšèåã³ããããç §æåšå ·
ã®èŠãåã³è£ 食çããµãŒãïŒfacadeïŒã倪éœå é
å åšã枩宀çªçã«çšãããããã®ã®ãããªéææ
ã¯åéæã®éåäœæ¿ã«è£œé ãããæãã¬ã©ã¹ç¹ç¶
ã¯ä»å çãªç¹æ§ãæããªããã°ãªããªãããã®ã
ããªè£œåã補é ããããã®ãã®ãããªãããªãã¯
ã¹éåäœã«çšããããã¬ã©ã¹ç¹ç¶ã«ãšã€ãŠå¿ èŠãª
ç¹æ§ã«ã¯ããããªãã¯ã¹éåäœäžã®åæ£æ§ã®ãã
ã®è¯å¥œãªçŽ°ææ§ãéããã«æ¿¡ããããã«ãããªã
ã¯ã¹éåäœäžãžã®è¯å¥œãªå¯æº¶æ§ã硬åããéåäœ
æ¿äžã®ç¹ç¶ã®çªèµ·ãå°ãªãè¯å¥œãªæž æŸæ§ãäžãã
ããšåã³ç¡¬åããéåäœæ¿ã«è¯å¥œãªèåæ§ãäžã
ãããšãå«ãŸãããã¬ã©ã¹ç¹ç¶ã®æåã¯éããã¬
ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã®åœ¢ã§ã®ã¬ã©ã¹ç¹ç¶ã®çŽ°æ
æ§ã®çºã«ãåŸãããæåã³ïŒåã¯ïŒã¹ãã©ã³ã
ã¯ãå·¥æ¥çã«çžäºä»çãšããŠäžè¬ã«èšåãããŠã
ããã¹ãã©ã³ãå士ã®ä»çããªãã®ãè¯ãããã®
ãããªã¬ã©ã¹ç¹ç¶æåã¯ã¹ãã©ã³ãã®ç¹æ§ã¯ãã¬
ã©ã¹ç¹ç¶ã®éåäœãããªãã¯ã¹ã«ããæ¿¡ããæªã
ããçµæã«ãªãã§ããããæ¬çºæã®ã¬ã©ã¹ç¹ç¶ã¯
äžé£œåããªãšã¹ãã«åã³ãšããã·ã®åŠãã¬ã©ã¹ç¹
ç¶è£åŒ·éåäœææã®éæåã³äžéæãªæ¿ã圢æã
ãã®ã«çšããã®ã«æãé©ããŠããã æŽã«æ¬çºæã®ååç©ã«åŠçãããã¬ã©ã¹ç¹ç¶
ã¯ãå ãŠããããç³»åã³çè²ãããç³»ãå«ãã©ã
ãªéåäœãããªãã¯ã¹ã«ãçšããããšãåºæ¥ãã
ã®å Žåéåäœãããªãã¯ã¹ã«ã¬ã©ã¹ç¹ç¶ãè¿ éã«
æ¿¡ããããšãæãŸãããæ¿¡ãïŒWetâoutïŒã¯ã
ãããªãã¯ã¹éåäœãã¬ã©ã¹ç¹ç¶ãå ã¿ãä»®ãã
ã€ããšããŠãã硬åãããç¹ç¶è£åŒ·éåäœææå š
äœãéããŠè£žã®ã¬ã©ã¹ã¯æ¥µããŠãããããèŠããª
ãããšãæå³ãããã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããª
ãã¯ã¹ã®è£œé äžã®æ¿¡ãã¯ãéåäœãããªãã¯ã¹ãš
ã¬ã©ã¹ç¹ç¶ãšã®æ¥è§Šã®èŠæãã®ç·å¯ãã®å°ºåºŠã§ã
ããããã¬ã©ã¹ç¹ç¶ãããããã¬ã©ã¹ç¹ç¶ãéå
äœãããªãã¯ã¹ãžå ããåŸãããæ¿¡ããªããªã
ã°ãããã¯æçµç硬åãããç¹ç¶è£åŒ·éåäœææ
ã®å å·¥æ§ã硬åç¹æ§åã³è¡šé¢ã®æ§è³ªã«æªã圱é¿ã
äžããããšããããç¹ç¶è£åŒ·éåäœææã®æ¿ãåŠ
çããå Žåã现æãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãå
ã¯ç¹ç¶ã®æã®æ¿¡ãã¯ã现æãããã¬ã©ã¹ç¹ç¶ãå«
ãéåäœãããªãã¯ã¹ãåŠçå·¥çšã§ç¡¬åãããå
ã«çæéã®ãã¡ã«èµ·ããªããã°ãªããªããåŸã€
ãŠã现æãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãæã¯ç¹ç¶ã®
æã®æ¿¡ãã®é床ã¯ãéææã¯åéæã®æ¿ã®ãããª
補åãäœãéã®éèŠãªæ¡ä»¶ã§ããã现æãããã¬
ã©ã¹ç¹ç¶ã¹ãã©ã³ãã®æ¿¡ãã®é床ãé ããšãç¹ç¶
è£åŒ·éåäœææã®æ¿ãåŠçããéã«äžå©ã«ãªãã§
ããããåãæ¬çºæã®ååŠçã«åŠçãããç¹ç¶ã¯
èåæ§ã®ç¹ç¶è£åŒ·éåäœæ¿ãäœãéã«æãé©ããŠ
ããã æ¬åºé¡ãšåãè²ãåã人ã«è²æž¡ãããç±³åœç¹èš±
第4110094å·ã«åŸã€ãŠäœãããåžè²©ã®ååŠçã«åŠ
çãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã補åã¯ãã¬ã©ã¹ç¹
ç¶è£åŒ·ã¢ã¯ãªãŒã«ããªãšã¹ãã«ã®æ¿ã補é ããã®
ã«çšããããŠããããã®æ¿è£œåã¯è¯å¥œãªèåæ§ã
æã€ããéææ§åã³ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã®æ¿¡ã
åã³ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã©ããã®ä»çã«ã€ããŠ
æ¬ é¥ãããããšãèŠåºãããŠãããååŠçã«åŠç
ãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã¯ãäžã€ä»¥äžã®æªãš
ã¹ãã«åã«ã«ããã·ã«åºåã³äžã€ä»¥äžã®ãšããã·
ãå«ããšããã·æš¹èãšç¡æ°Žãã¬ã€ã³é žéšåãšã¹ã
ã«ãšã®åå¿çæç©ã§ããïŒïŒ4â²ã€ãœããããªãã³
ãžããšããŒã« ãã¹ããšããŒã«ïŒ¡åãšããã·æš¹
èããããã¬ã³ã°ãªã³ãŒã«ã»é žåãšãã¬ã³è¡šé¢æŽ»
æ§å€ïŒïŒŠâ108è¡šé¢æŽ»æ§å€ïŒãæ°ŽçŽ åã³ãŒã³ãªã€ã«
ïŒãã¬ã³ãâPurecoâæ²¹ïŒããªãšãã¬ã³ ã°ãªã³
ãŒã«ä¹³åå€ïŒããªãã³ãâTritonââ100ïŒããª
ã¯ãã«ããšããã·ããªãšãã¬ã³ ãªãã·ãšã¿ããŒ
ã«ãããªããã« ãããªãã³ ãã€ã«ã 圢æå€ã
ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã· ã·ã©ã³ã
é ¢é žãã¬ã©ã¹ç¹ç¶æœ€æ»å€ãšããŠã®èèªé žã¢ãã³å¡©
ïŒãšã¡ãªãŒãâEmeryâ6717ïŒåã³çŽ6.5±0.2ïŒ ã®
ç¯å²ã®åºåœ¢ç©å«æéãäžããã®ã«å åãªæ°Žãããª
ãæ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæã€ãŠãããã
ã®ã¬ã©ã¹ç¹ç¶ã®çºã®åŠççšçµæç©ã¯ãã¬ã©ã¹ç¹ç¶
äžã®ååŠçåŠçç©ãšéåäœãããªãã¯ã¹ã®ååŠæ§
ãšã®çžäºäœçšã«ãã€ãŠç¹ç¶è£åŒ·éåäœæ¿ã®æçµç
æ§è³ªã«åœ±é¿ãäžããããšãæšæž¬ããããå€ãã®å®
éšãè¡ãªã€ãçµæããããæåã®å€ãã¯æå©ãªå¹
æãšæ害ãªå¹æãšã®äž¡æ¹ãäžããæ害ãªå¹æã®æ¹
ãæã æå©ãªå¹æããã®ãããšãçºèŠããããäŸ
ãã°ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã· ã·ã©
ã³æã¯ãã®å æ°Žå解çæç©ã¯è£åŒ·éåäœæ¿ã«è¯å¥œ
ãªèåæ§ãäžãããæ®å¿µãªããšã«ããã®ã·ã©ã³ã
ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®éé»æ°çºçã®äž»
ãªåå ã«ãªã€ãŠããããããäºã€ã®å¹æã¯éåžžã«
é¡èãªã®ã§ãèåæ§ã¯ç¹ç¶åã³ã¹ãã©ã³ãã«éé»
æ°çºçããšããªãããšãªãéæããããšãåºæ¥ãª
ããæŽã«ãµã€ãžã³ã°é åç©äžã®ããã€ãã®ä»ã®æ
åã¯ã¹ãã©ã³ãæ¿¡ãæ§ãäœäžããã¹ãã©ã€ãã®ç²
çæ§ãå¢ãã糞ã®çŽ°ææ§ãäœäžãç¹ç¶è£åŒ·æ¿ã®é
ææ§ãæžããããšãèŠåºã ãããŠããã ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã補é ãã
éã®è¯å¥œãªæ¿¡ãæ§ãæããè¯å¥œãªçŽ°ææ§ãæãã
çžäºã«ä»çããåŸåãäœäžããååŠçã«åŠçãã
ãã¬ã©ã¹ç¹ç¶ã補é ããããšã«äŒŽããäžã€è¯å¥œãª
èåæ§ãæã€ã®ã¿ãªããè¯å¥œãªéææ§ãæããã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã®ããã«ã補é
ããã®ã«äŒŽãããæ¡ä»¶åã³æ©èœã¯ãäºãã«å®³ãäž
ããªãããã«é¢ä¿ã¥ããããšãåºæ¥ãããšãçºèŠ
ããããåãæ¬çºæã®ã¬ã©ã¹ç¹ç¶ã®ä¹Ÿç¥æ®æž£ã«ç¹
å®ã®ææããªãããšãåžæã®ç¹æ§ãéæããã®ã«
å¿ èŠã§ããã æ¬çºæã®åŠçãããã¬ã©ã¹ç¹ç¶ãããããæ°Žæ§
åŠççšçµæç©äžã«ååšãããã€ã«ã 圢ææ§éåäœ
ã¯éåäœãããªãã¯ã¹ãšçžå®¹æ§ããããšå ±ã«ãã
ã«å¯æº¶æ§ã§ãããéåäœãããªãã¯ã¹ãšã¯ã¬ã©ã¹
ç¹ç¶ã«ãã€ãŠè£åŒ·ããããã®éåäœã§ãããçžå®¹
æ§åã³å¯æº¶æ§ã¯ãç¹ç¶ãšãããªãã¯ã¹éåäœãã
ãæ¥è§ŠãããæãåŠçãããã¬ã©ã¹ç¹ç¶ãçŽ10å
ããçããæéã§ãããªãã¯ã¹éåäœã«æ¿¡ããã
ããããªãã®ã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ãã€ã«ã 圢ææ§éåäœ
ã¯ãæ°Žåã³æº¶å€ã®èžçºæã¯ç¡¬åã§ãéãããç²ç
æ§ãæã€æŸãã åéæã®èã圢æããéåäœã§ã
ããéãããç²çæ§ãæã€ãã€ã«ã 圢ææ§éåäœ
ã¯æ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã«ãéãããç²ç
æ§ãäžãããã®ç¹æ§ã«å¯äžãããæ°Žæ§åŠççšçµæ
ç©ã®ä¹Ÿç¥æ®æž£ã®ãã€ã«ã ã¯ãšãã³ïŒEponïŒ828æš¹
èã®ãããªãšããã·éåäœã®ãã€ã«ã ãããç²ç
æ§ã®äœãç¹æ§ãæãããåããã€ã«ã ã¯éæ§ã§ã
ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã«æ®ãã©é£ç¶çãªãã€ã«ã ãäž
ããããã®ãããªãã€ã«ã ç¹æ§ãåŸãã®ã«ãåŠç
ãããã¬ã©ã¹ç¹ç¶ã®æ¿¡ãæ§ã倧ããæžå°ããã
ããæã¯åŠçãããã¬ã©ã¹ç¹ç¶ã§è£åŒ·ãããéå
äœããã«ã®éææ§ã«æ害ãªæªåœ±é¿ãäžãããããª
ããšãç¯ãããšã¯ãªãã ç²çæ§å¶çŽåã®ãã€ã«ã 圢ææ§éåäœãå«ãæ°Ž
æ§ååŠçåŠççšçµæç©ã«ãã€ãŠåœ¢æããããã€ã«
ã ã®æ§è³ªã¯ãã¬ã©ã¹ç¹ç¶ã1/4ã€ã³ãã®é·ãã«çŽ°
æãããæãçŽ30lbïŒft3ãã倧ããªèŠæãã®åµ©
å¯åºŠããããã«äžãããèŠæãã®åµ©å¯åºŠè©Šéšã¯åœ
æ¥è ã«ç¥ãããæ¹æ³ã«ãã€ãŠè¡ãªããããèŠæã
ã®åµ©å¯åºŠè©Šéšã®äŸã«ã¯æ¬¡ã®ãããªæ¹æ³ãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãã枬å®ããã
ééã®è£æããã¹ãã©ã³ãã250mlã¡ã¹ã·ãªã³ã
ãŒãžæ³šå ¥ããããã®ã¡ã¹ã·ãªã³ããŒãããªãã€ãª
å·ã¢ã³ãããªã¢ ã€ãŒã¹ãã»ã¡ã€ã³ã¹ããªãŒã
43543ã®ãªããã¢ã³ãã»ãã·ãŒã³ã»ã«ã³ãããŒã
ãâïŒåµ©å¯åºŠè©Šéšæ©ãšããŠå ¥æåºæ¥ããããªé«
å¯åºŠè©Šéšæ©ã«åãä»ãããè©Šéšæ©ã®èšç®æ©ãã50
ã¿ããã«èšå®ããæ©äŒãå§åããããæ©æ¢°ãæ¢ãŸ
ã€ãåŸãã¡ã¹ã·ãªã³ããŒäžã®ã¬ã©ã¹ç¹ç¶ã®äœç©ã
èªãã次ã«ã¿ããããåŸã®äœç©ã®èªã¿ã«ãã€ãŠçŽ°
æç³»ã®ééãå²ãããšã«ãã€ãŠèŠæãã®åµ©å¯åºŠã
èšç®ããããã®æ°å€ã«62.43ããããããšã«ãã€
ãŠ1bïŒft3ã§èŠæãã®é«å¯åºŠãåŸãããã ç±å¯å¡æ§ãã€ã«ã 圢ææ§éåäœã®æ°Žæ§ãšãã«ãž
ãšã³ã¯éåäœïŒã¢ã«åœããçŽ1.5ããå°ããèèª
æäºéçµåã®èèªæäžé£œåã®å¹³åå€ãæãã0.1
ãè¶ããªãèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ãæ
ããã®ã奜ãŸããããã®æ¯ã¯å®€æž©ã§ç©ºæ°æã¯ç空
äžã§ä¹Ÿç¥ãããã€ã«ã ã«ã€ããŠã®IRåžåçã«ã
ã€ãŠæ±ºå®ããããéåäœãïŒã¢ã«åœããå¹³å1.5
ã®èèªæäºéçµåãæããæããã®æ¯ã®å€ã¯0.1
ã§ãããæŽã«æ°Žæ§ååŠçåŠççšçµæç©ã¯ããããª
éã®çž®åæ¶æ©èªèµ·åå¿ç©åã³é䌞é·èªèµ·åå¿ç©ã
æãããæ¿¡ãã®é床ãé ãå Žåãç±å¯å¡æ§ãã€ã«
ã 圢ææ§éåäœã®æ°Žæ§ãšãã«ãžãšã³ã¯æ¯èŒçå€é
ã®èèªæäžé£œååã³0.1ãã倧ããªèèªæäžé£œå
察è³éŠæäžé£œåã®æ¯ãæããããšãã§ããããã
ã®éãšæ¯ãé«ããªãã«åŸã€ãŠæ¿¡ãã®é床ã¯æ¬¡ç¬¬ã«
é ããªãã ç²çæ§ãå¶çŽãããé©åœãªãã€ã«ã 圢ææ§éå
äœã®äŸã«ã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãããªã¢
ã«ãã¬ã³ããªãªãŒã«ã䜿çšããããšã«ãã€ãŠå€ã
ãä¹³åããããæã¯å éšçã«ä¹³åæ§ã®ããã¹ããš
ããŒã«ïŒ¡ãããã³ãžãªãŒã«æã¯ç¡æ°Žãã¬ã€ã³é žæ
ã¯ãã¬ã€ã³é žåã³ã¢ãžãã³é žãã圢æããããã®
ã®ãããªæ°Žæº¶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã¹ããšã
ãŒã«ããªãšã¹ãã«éåäœã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã奜ãŸããã¯ããªãšã¹ãã«
ã¯ãçŽ30000ã45000ã®ç¯å²ã®ééå¹³åååéåã³
çŽïŒãçŽïŒã®å€åæ£æ§ææ°NwïŒMnãæããé
åäœã«ã€ããŠã¯ãšããã·ã«åã«ãã€ãŠå éšçã«ä¹³
åæ§ã«ãããã奜ãŸããã¯ããã®çš®ã®ãã¹ããšã
ãŒã«ããªãšã¹ãã«ç²çæ§å¶çŽéåäœã¯æ°Žæ§ååŠç
åŠççšçµæç©äžã®å¯äžã®ãã€ã«ã 圢ææ§éåäœã§
ããããã®ãããªéåäœã®äŸã¯ã€ã¿ãªãŒã³ã¢ã®ãµ
ãããïŒSavidïŒç€Ÿã«ãã€ãŠè£œé ãããåæšåã
ãªã¯ã·ã«ïŒNeoxiïŒ954ãšããŠåžè²©ãããŠããã¢
ã«ã³ãã·åãã¹ããšããŒã«ããªãšã¹ãã«æš¹èã®å
äžã®æ°Žæ§ãšãã«ãžãšã³ã§ãããããªã¯ã·ã«954æš¹
èã®æ§è³ªã¯æ¬¡ã®ãšããã§ããïŒå€èŠ³ãã«ã¯ç¶æ¶²
äœãåºåœ¢ç©å«æé46±ïŒïŒ ãPHïŒãïŒã23âã®ç²
床2000±500cpsãããã³ãžãªãŒã«åã¯ãã¬ã€ã³é ž
åã¯ç¡æ°Žãã¬ã€ã³é žã«ãã€ãŠãã®ãããªéåäœãž
å°å ¥ãããèèªæäžé£œåã¯éåäœïŒã¢ã«åœãã
1.5以äžã®äºéçµåã®èèªæäžé£œåãããããã¹
ãã§ãããèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã¯
0.1ããå°ããã奜ãŸããã¯çŽ0.07以äžã§ããã®
ãè¯ããèèªæäžé£œåã®éãšãã®æ¯ã¯ãéåã®å
éã®åœæ¥è ã«ç¥ãããŠããæ¹æ³ã«ãã€ãŠå¶åŸ¡ãã
ããšãã§ãããäŸãã°çš®ã ã®åéäœã®éãèèªæ
äžé£œåããã€åéäœãšããããªãåéäœãšã®æ¯ã§
調ç¯ããããšãã§ãããããªã¯ã·ã«954æš¹èãšã
ã«ãžãšã³ã®NMRæ²ç·ã¯ç¬¬ïŒå³ã«ç€ºãããŠããã
NMRã¯ãããªã¢ã³ïŒVarianïŒEMâ360 60MHz
éœåNMRåå èšã«ãããèµ°æ»æéïŒåãèµ°æ»å¹
10ppmãèµ°æ»ç«¯0ppmããã©ã¡ãã«ã·ã©ã³
ïŒTMSïŒïŒåºæºãè©Šæ枩床宀枩åã³DCCL3溶å€
ãçšããŠè¡ãªããããæ°Žæ§åŠççšçµæç©äžã®ãã€
ã«ã 圢ææ§éåäœã®éã¯æ°Žæ§åŠççšçµæç©ã®åºåœ¢
ç©ã®çŽïŒãçŽ20ééïŒ ã®ç¯å²ã«ããã åè¿°ã®ãšã¹ãã«åãšããã·æš¹èæã¯ãšããã·ã
åããªãšã¹ãã«æš¹èã補é ããéããã®å·¥çšã®åº
çºææã¯ãåœæ¥è ã«ç¥ãããæ¹æ³ã«ãã€ãŠéåäœ
ïŒã¢ã«åœãã1.5以äžå¥œãŸããã¯çŽ1.14ã1.4ã®äº
éçµåã®èèªæäžé£œåéããã¡ãèèªæäžé£œå察
è³éŠæäžé£œåã®æ¯ã0.1以äžã§ãããã€ã«ã 圢æ
æ§éåäœãçããããã«èª¿ç¯ããããäŸãã°åé
äœåæã¯ãäžé£œååæããã®æ¯ã0.1ãè¶ããŠå¢
倧ããããæã¯1.5ãã倧ããªäžé£œåéãçãã
çšå€§ããªçšåºŠãŸã§éåäœææã«å¯äžããããšããª
ããããªæ¯ã§çšããããšãã§ããã éåäœïŒã¢ã«åœããã®äžé£œåéã決å®ããæ¹æ³
ã¯ãåœæ¥è ã«ç¥ãããã©ããªæ¹æ³ã«ãã€ãŠãããª
ãããŠããããäŸãã°äºéçµåãæ°ŽçŽ åãããã¯
ããã²ã³åãããªã©ããæ°ŽçŽ æã¯ããã²ã³ãåã
蟌ãã éã枬å®ãããããªæ°å€ãã®æ¹¿åŒååŠçå
ææ³ãç¥ãããŠããã æ¯ã決å®ããæ¹æ³ã¯åœåéã§ç¥ãããã©ããªæ¹
æ³ã§ããããããã®æ¹æ³ã¯ããŒãªãšå€æèµ€å€åå
èšïŒFTIRïŒãçšããããšãå«ãã§ããã®ã奜ãŸ
ãããäžãããã也ç¥éåäœãã€ã«ã è©Šæã«ã€ã
ãŠ1647cm-1ã§ã®åžåãèšé²ãã1608cm-1ã§ã®åžå
ãèšé²ããã次ã«èèªæäžé£œå察è³éŠæäžé£œåã®
æ¯æã¯1647cm-1ã§ã®åžå察1608cm-1ã§ã®åžåã®æ¯
ã¯ã1647cm-1ã§ã®åžåã1608cm-1ã§ã®åžåã«ãã€
ãŠå²ãã0.1ããå°ããã奜ãŸããã¯0.07ããå°
ããæ¯ãäžããããšã«ãã€ãŠåŸãããããã®æ¹æ³
ã«ãã€ãŠã1647cm-1ã§åŸãããåžåãè³éŠææ§é
ã®å¹³é¢æ¯åäžã®ïŒ£ïŒïŒ£ã«äŒŽãããåžåã§å²ãããš
ã«ãã€ãŠåãã€ã«ã äžã®çžå¯Ÿçã¢ã«ã±ã³äžé£œå床
ã決å®ããããæå®ããæ³¢é·ã§ã®åžåå€ãåŸãé
ã«ããããã®å€ã¯ãã€ãŒãããå æ¿ãããã§ã¯ãª
ããFTIRããŒã¿ãŒäœçœ®ããçšããããã®ã奜ãŸ
ãããä»ã®æ¹æ³ããã®æ¯ã決å®ããããã«çšãã
å Žåæ¯ã®å€ã¯0.1以å ã«ãªãããšãããããæ¯ã«
察ãããã®ä»ã®å€ãFTIRæ³ã«ãã€ãŠåŸããã0.1
以äžã®å€ãšç䟡ã§ããéãæ¬çºæã®å©ç¹ãåŸãã
ãšãã§ããã æ°Žæ§ååŠçåŠççšçµæç©ã¯èèªæäžé£œåéã®ç¯
å²å€åã³èèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã«å¯Ÿã
ãå€ã®ç¯å²å€ã«ãªãä»ã®æåãå«ãã¹ãã§ãªãã
æ°Žæ§ååŠçåŠççµæç©äžã®åæ·»å ååç©ïŒã¢ã«åœ
ãã1.5ããå°ããäºéçµåã®èèªæäžé£œåãã
ã€ã¹ãã§ãããåååç©ã«å¯Ÿããåèšæ¯ã®0.1ã
è¶ããã¹ãã§ã¯ãªãã æŽã«æ°Žæ§ååŠçåŠççšçµæç©ã¯å€éã®å³ã¡æ°Žæ§
ååŠçåŠççšçµæç©ã®ïŒééïŒ ããå¿ãéåäœé
䌞é·èªèµ·åå¿ç©åã³çž®åæ¶æ©èªèµ·åå¿ç©ãå«ãã¹
ãã§ã¯ãªããæ°Žæ§ååŠçåŠççšçµæç©ã¯ãããã®
ç©è³ªãæ¬è³ªçã«ãµããŸãªãã®ã奜ãŸãããããã
ã®ç©è³ªã®äŸã«ã¯åŠççµæç©äžã«æ¢ã«ååšããææ
ãšãã®ãããªåå¿ãèªèµ·ãã觊åªåã³çž®ååå€ã
åããããšããã次ã®ãããªéšåãæããåå¿ç©
ãå«ãŸãããããããã«éå®ããããã®ã§ã¯ãª
ãïŒ ãããã®çš®é¡ã®åå¿ã¯æ¿¡ãæ§ãããããããã«
äœãæ¶æ©å¯åºŠãäžããããã«æå°ã«ä¿ãããã¹ã
ã§ããã ã¬ã©ã¹ç¹ç¶ã®ããã®æ°Žæ§ååŠçåŠççšçµæç©äž
ã«éåžžèŠåºã ããã飜ååã³éçž®ååå¿æ§ææ
ã¯ãæ¬çºæã®æ°Žæ§ååŠçåŠççšçµæç©äžã«ååšã
ãŠããŠãããããã®äŸã«ã¯çš®ã ã®ææ©ã·ã©ã³ã«ã
ããªã³ã°å€ãçš®ã ã®æœ€æ»å€åã³åŠçå©å€ãå«ãŸã
ããããããã«éå®ããããã®ã§ã¯ãªããã¬ã©ã¹
ç¹ç¶ã®ããã®æ°Žæ§ååŠçåŠççšçµæç©ã補é ãã
éã«ãããä»ã®ææãçšããå Žåãããéã®èèª
æäžé£œåã¯ããããæ°Žæ§ååŠçåŠççšçµæç©ã®ã
ãã®èèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã0.1ãã
倧ããããªãéã蚱容ããããšãã§ããã æ°Žæ§ååŠçåŠççšçµæç©ãé åããã®ã«çšãã
ããšãã§ããç¹å®ã®æåã®äŸã«ã¯ãååç©ïŒã¢ã«
åœããçŽ1.5ããå°ããäºéçµåã®èèªæäžé£œå
éããã¡ãèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã
0.1以äžã®ãã®ãããããããã«ã¯ãšããã·ãå
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœãææ©ã·ã©ã³
ã«ãããªã³ã°å€ã最æ»å€åã³éé»é²æ¢å€åã³æ°Žã
å«ãŸããã äžçš®é¡ããå€ãã®ãã€ã«ã 圢ææ§éåäœãçšã
ãããæããšããã·å«æéåäœåã¯å ±éåäœãé
ç²çæ§éåäœãšå ±ã«çšããããšãåºæ¥ãããšãã
ã·å«æéåäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãš
ã®å¥ã ã®æ°Žæ§ãšãã«ãžãšã³ãäžç·ã«ããŠãåäžã®
ãšãã«ãžãšã³ã«ããŠããããæã¯ãšããã·å«æé
åäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãšãæ°Žæ§ãš
ãã«ãžãšã³äžã«å¯æº¶åãåæ£æã¯ä¹³åããŠãäžã€
ã®æ°Žæ§ãšãã«ãžãšã³ã調補ããŠãããããšããã·
å«æéåäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãšã®
æ··åç©ãå«ãåäžã®ãšãã«ãžãšã³ã調補ããå Ž
åãéã€ãªã³æ§ãéœã€ãªã³æ§ãé°ã€ãªã³æ§ãæã¯
äž¡æ§ä¹³åå€ãçšããããšãåºæ¥ãããããæ··åã
ãéåäœã®ã€ãªã³ç¹æ§ã«åã€ãç¯å²ã®HLBãæ
ããéã€ãªã³æ§ä¹³åå€ãçšããã®ã奜ãŸãããäŸ
ãšããŠãšããã·ãïŒïœåœéåœããéåäœçŽ180ã
230ïœã®ç¯å²ã®ãšããã·åœéãæãããšããã·å«
æéåäœåã¯å ±éåäœãæããããããããã«é
å®ããããã®ã§ã¯ãªãããšããã·å«æéåäœåã¯
å ±éåäœã¯ã飜ååã¯äžé£œåããªãšã¹ãã«åã³ãš
ããã·ã®åŠãéåäœãããªãã¯ã¹ã«ãã€ãŠã¬ã©ã¹
ç¹ç¶ãè¿ éã«æ¿¡ããããã®è¯å¥œãªæ¿¡ãæ§ãæãã
åŠçãããã¬ã©ã¹ç¹ç¶ãçããã®ã«åœ¹ç«ã€ããšã
ãã·ãïŒïœåœéåœããéåäœ230ïœãã倧ããªãš
ããã·åœéãæãããšããã·éåäœã¯ãæã€ãã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœããã«ãçããã§ãããããš
ããã·åœéãçŽ180ïœããå°ããå ŽåãåŠçãã
ãã¬ã©ã¹ç¹ç¶ã¯äœãã«ãç²çæ§ãããããšããã·
ïŒïœåœéãå«ããæš¹èïœééãšããŠå®çŸ©ããããš
ããã·åœéåã¯ããšããã·ãåœéã¯åœæ¥è ã«ç¥ã
ããæ¹æ³ã«ãã€ãŠæ±ºå®ããããšãåºæ¥ããäŸãšã
ãŠèµ€å€åå åã³ããªãžã³äžå¡©åããªãžããŠã ããš
ããã·éåäœãžæ·»å ããåŸãæ°Žé žåãããªãŠã ã«
ãã滎å®æ³ã®åŠã湿åŒåæãæãããããããã
ãã«éå®ããããã®ã§ã¯ãªãããšããã·æš¹èãçš
ããå Žåãæ°Žæ§åŠççšçµæç©äžã®ãã®éã¯ãæ°Žæ§
åŠççšçµæç©ã®åºåœ¢ç©ã®å°ééšåãã倧éšåãŸã§
ã«å€ããããšãåºæ¥ããçšããããšãåºæ¥ããšã
ãã·æš¹èã¯ãã¹ããšããŒã«ïŒ¡ãšããã¹ããšããŒã«
ã®ã°ãªã·ãžã«ãšãŒãã«ã圢æããããã®ãšãã
ããããªã³ã®åŠãå ±åéäœãšãã補é ããããšã
ãã·æš¹èã§ãã€ãŠãããïŒâã€ãœããããªãã³ã
ã¹ïŒïŒïŒïŒâãžããã¢ããšããŒã«ïŒããžãããã
ã·ãã³ãŒã³ãïŒïŒïŒïŒïŒïŒïŒïŒâããã©ïŒïœâã
ãããã·ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâãã¿ã³ãžãª
ãŒã«ãã°ãªã»ããŒã«ãããªãªãã·ã¢ã«ãã¬ã³ïŒã°
ãªã³ãŒã«ïŒããªãã¬ã³äºéäœé žãïŒïŒïŒïŒïŒâã
ãªã¹ïŒïœâããããã·ããšãã«ïŒâãããã³çãš
ããããããªã³ãšã®åå¿ã§çšããããšã«ãã€ãŠåŸ
ããããšããã·æš¹èãçšããããšãã§ãããåè
èªæã°ãªã·ãžã«ãšãŒãã«ãã補é ããããšããã·
æš¹èãçšããããšãã§ãããåã¢ããšããã·åå
ç©ããèªäœæã¯ä»ã®ãšããã·çæååç©ãšã®åå¿
ã«ãã€ãŠè£œé ããããšããã·æš¹èãçšããããšã
ã§ããäŸãã°äžé£œåã¢ããšããã·ååç©ãäžé£œå
ã«ãã€ãŠãã¢ããªããŒåããããªïŒã¢ãªã« ã°ãª
ã·ãžã«ãšãŒãã«ïŒã®ãããªããªãšããã·éåäœã
補é ããŠããããç¹ã«é©ãããšããã·æš¹èã¯ïŒã¢
ã«ã®ããšããŒã«ãšãïŒã¢ã«ã®ãã«ã ã¢ã«ãããã
ãããããã³ãã¬ãŸã«ã·ããŒã«æã¯å€äŸ¡ã¢ã«ã³ãŒ
ã«äŸãã°ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ããœã«ãããŒ
ã«ãã°ãªã»ããŒã«çãšã®é žçž®åã«ãã€ãŠåŸããã
ãã¹ïŒïŒâããããã·ããšããŒã«ïŒâïŒïŒïŒãã
ãã³ããã¹ïŒããããã·ããšãã«ïŒã¡ã¿ã³ã®åŠã
å€äŸ¡ããšããŒã«ãšãååŠéè«çã«éå°éã®ãšãã¯
ãããããªã³ã®åŠããšããããããªã³ãšã®åå¿ã«
ãã€ãŠåŸãããããšããŒã«ç³»ãšããã·ã§ããããš
ããããããªã³ãå€äŸ¡ååç©ã®ãããã®éšåãå€
ãäžã€ïŒåã¯ïŒåå¿æ¡ä»¶ãå€ããããšã«ããã液
äœããåºäœã®ç¯å²ã«å ¥ãäœããäžçšåºŠåã¯é«ãå
åéã®ååç©ã補é ããããæçšãªåžè²©ã®ãšãã
ã·æš¹èã«ã¯åæšåãšãã³ïŒEpomïŒ828ã§ã·ãš
ã«ã»ã±ãã«ã«ã»ã³ãŒãã¬ãŒã·ãšã³ããåŸããããš
ããã·æš¹èåã³åæšåã¢ã©ã«ãã€ãïŒAralditeïŒ
ã§ããã»ã¬ã€ã®ãŒç€ŸããåŸããããšããã·æš¹èå
ã³åæšåD.E.R.åã¯D.E.N.ã§ããŠã»ã±ãã«ã«ã»
ã«ã³ãããŒããåŸãããæš¹èåã³ã»ã©ããŒãºã»ã
ãªããŒã»ã¹ãã·ã€ã«ãã€ãŒãºã»ã«ã³ãããŒããåŸ
ããããšããŒã¬ããºïŒEpiâRezïŒæš¹èãå«ãŸã
ããçšããããšãã§ããé©åœãªãšããã·å«æå ±é
åäœã¯åæšå1971æš¹èã§ãã·ãšãã«ã»ã¹ã¿ãŒã瀟
ããåŸããããšããã·ãåããªããã«ã¢ã»ããŒã
å ±éåäœã§ããã 氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ãšããã·å«æéåäœ
ã¯åœæ¥è ã«ç¥ãããé©åœãªè¡šé¢æŽ»æ§å€ãçšããŠã€
ãããããšãã«ãžãšã³å³ã¡åæ£ç©ãå«ãããšãã§
ãããäŸãã°ãé žåãããã¬ã³ãšãããã¬ã³ã°ãª
ã³ãŒã«ãšã®çž®åã«ãã€ãŠåœ¢æãããçæ°Žæ§å¡©åºãš
é žåãšãã¬ã³ãšã®çž®åç©ã§ããäžçš®ä»¥äžã®è¡šé¢æŽ»
æ§å€ãçšããããšãåºæ¥ããäŸãã°ãBASFãŠã€
ã³ãããïŒWyandotteïŒã€ã³ãã¹ããªã¢ã«ã»ã±
ãã«ã«ã»ã°ã«ãŒãã«ãã€ãŠè£œé ããããã«ããã
ã¯ïŒPluronicïŒïŒŠâ108è¡šé¢æŽ»æ§å€ãé©åœãªãšã
ã«ãžãšã³æã¯åæ£ç©ã圢æããã®ã«çšããããšã
åºæ¥ãã åããšããã·å«æéåäœåã¯éåäœãç²çæ§ã
ã€ã«ã 圢ææ§éåäœã®éããã溶解床ã«é¢é£ããŠ
çšããå Žåããšããã·å«æéåäœäžã®ç²çæ§å¶çŽ
ãã€ã«ã 圢ææ§éåäœã¯ãããäºçš®é¡ã®éåäœå
ã¯éåäœãšãã«ãžãšã³ã®çžå®¹æ§ãå©é·ããããã®
çžå®¹æ§ã¯åã«ãšããã·å«æéåäœã®ä¹Ÿç¥æ®æž£ãæ
ããã¬ã©ã¹ç¹ç¶ã®ç²çæ§ããããã¬ã©ã¹ç¹ç¶äžã®
æ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã®ãã€ã«ã ã®ç²çæ§
ãæžå°ãããã®ã«åœ¹ç«ã€ãç²çæ§ã®æžå°ã¯çŽ°æã
ãåŠçãããã¬ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã©ããã®æ¥
çã«ããçžäºæ¥çã®æžå°ã«ãªã€ãŠçŸããã 氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã€ã«ã 圢ææ§
éãåäœã®ä»ã«ãæ°Žæ§åŠççšçµæç©ã¯äžçš®ä»¥äžã®
ã¢ã¯ãªããã·å«ææã¯ã¡ã¿ã¯ãªããã·å«æææ©å®
èœã«ãããªã³ã°å€ãå«æããŠãããã«ãããªã³ã°
å€ã¯ãææ©å®èœã·ã©ã³ã«ãããªã³ã°å€æã¯ææ©å®
èœãŠãšã«ããŒïŒWernerïŒååç©çãååã®ææ©
å®èœéšåã«æ¬¡ã®åŠãéšåïŒ åã³æ¬¡ã®åŠãã¡ã¿ã¯ãªããã·åã³çœ®æã¢ã¯ãªãã
ã·æ®åºïŒ ãåŒäžãã¯ïŒåãŸã§ã®ççŽ ååãæããäœçŽã¢
ã«ãã«åºã§ããã ãæãããã®ã§ãã€ãŠè¯ãããã®ãããªã«ãããª
ã³ã°å€ã®äŸã«ã¯ã¡ã¿ã¯ãªããã·ã¢ã«ãã«ããªã¢ã«
ã³ãã·ã·ã©ã³ãããããããã«éå®ããããã®ã§
ã¯ãªããã¢ã«ã³ãã·åºãšã¢ã«ãã«åºã¯ã¢ã«ãã«åº
ã«ã€ããŠïŒãïŒåã®ççŽ ååãæããã奜ãŸãã
ã¯ãã¡ã¿ã¯ãªããã·ã¢ã«ãã«ããªã¢ã«ã³ãã·ã·ã©
ã³ã¯ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·ã©ã³
ã§ãããã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·
ã©ã³ã®ã¡ããã·åºã¯ããã®ã·ã©ã³ãæ°Žæ§åŠççšçµ
æç©ã«é åãããåã«å æ°Žå解ãããªããã°ãªã
ãªããããã¯é ¢é žã®ãããªæ¬è³ªçãªçåæ°ŽçŽ ææ©
é žãã«ãããªã³ã°å€ã«æ·»å ãäžçš®ä»¥äžã®SiOCH3
åºãå æ°Žå解ãããŠã¡ã¿ããŒã«åã³äžçš®ä»¥äžã®
SiOHåºã圢æããã®ã«å åãªæéåã³å åãªæž©
床ã§æªäŒŽããããšã«ãã€ãŠéæããããé ¢é žã«å
åãªæŽ»æ§åºŠãäžããã®ã«å åãªæ°Žãå æ°Žå解ã§çš
ãããæ°Žæ§åŠççµæç©ã«çšããããã·ã©ã³ã«ãã
ãªã³ã°å€ã®éã¯ãæ°Žæ§åŠççšçµæç©ã®åºåœ¢ç©ã®çŽ
0.1ãçŽ10ééïŒ ã®ç¯å²ã®ã«ãããªã³ã°ã«æå¹ãª
éã§ããããå€ãæ¹ã®éã§å¶åŸ¡ããã湿床æ¡ä»¶ã§
éåžžçšããããã æ°Žæ§ååŠçåŠççšçµæç©ã®åèšæåã®ä»ã«ã最
æ»ã«æå¹ãªéã®ã¬ã©ã¹ç¹ç¶éœã€ãªã³æœ€æ»å€ãååš
ãããããã最æ»å€ã¯ãã¬ã©ã¹ç¹ç¶ãåã³ã¬ã©ã¹
ç¹ç¶ãã¹ãã©ã³ãã®éããæã«æœ€æ»æ§ãäžããæ°Ž
溶æ§éœã€ãªã³ç©è³ªã§ãã最æ»å€ã§ããããã®ã«ã¯
é žå¯æº¶åãããèèªé žã¢ããäŸãã°ã·ãã¢ãªã³ã¢
ãããå«ãŸãããèèªé žã¢ããã¯é£œååã³äžé£œå
ã®äž¡æ¹ã§ãããé žåºã¯ïŒã24åã®ççŽ ååãå«
ããåãäœååéã®äžé£œåèèªé žã¢ããã®ç¡æ°Žé ž
å¯æº¶åéåäœãå«ãŸãããåéç°ãçãããããª
æ¡ä»¶ã§èèªé žãšããªã¢ã«ãã¬ã³ããªã¢ãã³ãšãå
å¿ãããããšã«ãã€ãŠåœ¢æãããã¢ã«ãã«ã€ãã
ãŸãªã³ãå«ãŸãããç¹ã«é©ããéœã€ãªã³æœ€æ»å€
ã¯ã奜ãŸããã¯å°ãªããšãäžçš®é¡ããã©ã«ãŽã³é ž
ã§ããèèªé žãçšããŠè£œé ãããçŽ200ã800ã®ã¢
ãã³äŸ¡ãæããããªã¢ããã¢ããææã§ãããå
ãã®ææã¯é ¢é žã§æŽã«å¯æº¶åããããšãåºæ¥ãã
ãã®ãããªææã®äŸã¯åæšåãšããªãŒãªãŠãŒã
ïŒEmerylubeïŒ6717ã§ãšããªãŒã»ã€ã³ãã¹ããªãŒ
ãºç€Ÿããåžè²©ãããŠããããã©ã«ãŽã³é žã®ãããª
èèªé žã§éšåçã«ã¢ããåãããããªã¢ã«ãã¬ã³
ã€ãã³ã§ããããã®ææã¯æµåç¹55ãå¯åºŠ0.99
KgïŒïŒ8.3ãã³ãïŒã¬ãã³ïŒãã¬ãŒããã«ã©ãŒ
10ã25âããäœãæãç¹ãåŒç«282âïŒ540ãïŒã
æããç²çš æ§ã®æ¶²äœã§ããã氎溶æ§ã§ãé±æ²¹ã«å¯Ÿ
ãåæ£æ§ã§ãããä»ã®é©åœãªææã¯ãåæšåã¯ã©
ãŸãŒã«ïŒCirrasolïŒ185AãšããŠè£œé ãããŠããã
宀枩ã§ç²çš ãªæ¶²äœã®æ·±ãèµ€å³ããã€ããã¯ãè²ã
ããç¡æ°Žã®ææã§ãããããã¯æ°Žã«å¯Ÿãåæ£æ§
ã§ãïŒïŒ 溶液ã¯çŽ8.9ãçŽ9.4ã®PHãæãããéœã€
ãªã³æ§ã§æ°Žæº¶æ§ã®ã¬ã©ã¹ç¹ç¶æœ€æ»å€ãåå¿æ§ã®ã
ãçŽ åºãå«ãå Žåããã®æœ€æ»å€ã®æå¹ãªéã¯ãã¬
ã©ã¹ç¹ç¶æœ€æ»å€ã®çªçŽ å«æåºã«ãã€ãŠããããã
ãããšããããšããã·å«æéåäœã®ã©ããªæ¶æ©ã
ãå®è³ªçã«é²ãããã«éå®ãããã¹ãã§ãããäž
è¬ã«éœã€ãªã³æ§ã¬ã©ã¹ç¹ç¶æœ€æ»å€ã®æå¹ãªéã¯æ°Ž
æ§ååŠçåŠççšçµæç©ã®çŽ0.05ã0.5ééïŒ ã®ç¯
å²ã«ããã éåäœãããªãã¯ã¹ãè£åŒ·ããããã«æãŸãã
æ§è³ªãæããååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ãæ
ããä»ã«ãåŠçãããã¬ã©ã¹ç¹ç¶ã¯è£åŒ·ãããç
æç©ãžå å·¥åºæ¥ããã®ã§ãªããã°ãªããªããè£åŒ·
ããããã©ã¹ããã¯ããã«ã¯çŽ°æãããã¹ãã©ã³
ãè£åŒ·å€ãšäžç·ã«è£œé ããããã¬ã©ã¹ç¹ç¶ã¯æå
é£ç¶çã«ç¹ç¶ãšããŠè£œé ããããã®åŸã§ãããã¯
现æããããç¹ç¶åã¯ã¹ãã©ã³ãåã¯ããŒãã³ã°
ã也ç¥é£ç¶çææãã现æãããå Žåãå€ãã®é
é»ç现æçã®çµ¡ã¿ã¯è£åŒ·ããã«ã補é ããããã®
ã¬ã©ã¹ç¹ç¶ã®å å·¥æ§ãã ãã«ããããšãããã现
æçã®çµ¡ã¿ãæžå°ãããã®ã«åœ¹ç«ã€éé»ç絡ã¿ã
解決ããããã«ãæ°Žæ§ååŠçåŠççšçµæç©ã¯ã¢ã«
ã³ãã·éšåãæã€éœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ã
ãŠã å¡©ã§ããéé»é²æ¢å€ãæãããæ°Žæ§ååŠçåŠ
ççšçµæç©ã«éé»é²æ¢å€ãé åããèšå€§ãªå®éšã
è¡ã€ãåŸãç¡æ©éé»é²æ¢å€ãååšããªããšéœã€ãª
ã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ããŠã å¡©é
é»é²æ¢å€ã¯ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã®è¯å¥œãª
èåæ§ãããããããšãçºèŠããããäžè¬ã«éœã€
ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ããŠã å¡©
éé»é²æ¢å€ã¯ãåŒïŒ ãåŒäžãR1ãR2ãR3åã³R4ã®äžã€ä»¥äžã®éšåã
åããåã¯ç°ãªãã¢ã«ã³ãã·éšåã§ãã¡ãã¬ã³åº
ãæããåã¯ã¡ãã¬ã³åºãæããã ïŒâRâ³OâïŒbRâ²âïŒo ïŒRâ²ã¯ã¡ãã¬ã³åºïŒCH2ïŒã§ãïœã¯ïŒã10åã¯ã
ã以äžã®æŽæ°ã§ãããRâ³ã¯ãšãã¬ã³åºåã¯ãã
ãã¬ã³åºåã¯ãããã®æ··åç©ã§ãããïœã¯ïŒã10
åã¯ãã以äžã®æŽæ°ã§ãããã¯æ°ŽçŽ åã¯ïŒã
10åã®ççŽ ååãæããäœçŽã¢ã«ããŒã«åºã§ã
ãïŒã®åŠãæ«ç«¯ã¢ã«ã³ãŒã«æ§åºãæããã¢ã«ã³ã
ã·éšåã§ããããšãã§ããã ãæããã åºR1ãR2ãR3åã³R4ã®åã€ããå°ãªããã®ã
ã¢ã«ã³ãã·åºã§ãããæ®ãã®éã¢ã«ã³ãã·åºR1ã
R2ãR3åã³R4ã¯ïŒã30åã®ççŽ ååãæããã¢
ã«ãã«åºã§ããã X-ã¯ã«ã«ããã·ã¬ãŒããã¹ã«ãããŒãããµã«
ããšãŒãããã¹ããšãŒãåã³ããã²ã³åç©ã€ãªã³
ã®ãããªã©ããªææ©åã¯ç¡æ©ã®é°ã€ãªã³ã§ãã
ãããã®éé»é²æ¢å€ã¯ã¢ã«ã³ãã·éšåãæã€ç¬¬å
çŽã¢ã³ã¢ããŠã å¡©ã補é ããããã®ãã®ååŠçå
éã§ç¥ãããŠããã©ããªæ¹æ³ã«ãã€ãŠè£œé ããŠã
è¯ãã éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ã
ãŠã å¡©éé»é²æ¢å€ã¯ã ïŒR5ïŒyâN+âïŒR6ïŒzX- ãåŒäžãR5㯠ïŒâRâ³OâïŒbRâ²aâ ïŒRâ²ã¯ã¡ãã¬ã³ïŒCH2ïŒã§ãããïœã¯ïŒãïŒã®æŽ
æ°ã§ãããRâ³ã¯ãšãã¬ã³ã§ïœã¯ïŒãïŒã®æŽæ°ã§
ãããã¯æ°ŽçŽ åã¯ã¡ãã«åºã§ããïŒã®åŠãå
ãã¢ã«ã³ãã·éšåã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§
ãããïœïŒïŒã®æãïœïŒïŒã§ãããïœïŒïŒã®æã
ïœïŒïŒã§ãããR6ã¯ïŒã25åã®ççŽ ååãæã
ãé·éã¢ã«ãã«ã§ãããX-ã¯Cl-åã¯Br-ã§ã
ããã®ããšãåŒãæããã®ã奜ãŸããããã®ææ
ã®é žäŸ¡ã¯å°ãªããšã10ã§ããã®ã奜ãŸããã éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ã
ãŠã å¡©éé»é²æ¢å€ã®äŸã«ã¯ãã€ã¿ãªãŒã³ã¢ã®ãµã
ããS.p.A.ããå ¥æåºæ¥ãåæšåããªã¯ã·ã«
AO5620ãšããŠåžè²©ãããŠããææãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãããã®ææã¯
第ïŒå³ã«ç€ºãNMRæ²ç·ãæããååé1010Mn
åã³1140Mwãé žäŸ¡10ã20mgrKOHïŒïœåã³ïŒïŒ
氎溶液ã®PHãïŒãïŒã§ããã第ïŒå³ã®IRã¯ããª
ã¯ã·ã«AO5620ææã«ãã也ç¥ãã€ã«ã æåç©ã
ãåŸããããã®ã§ããã 第ïŒå³ã®NMRã¯ããªã¢ã³ïŒ¥â360 60MHzéœå
NMRåå åšã«ãã€ãŠè¡ãªããããã®å Žåã¹ãã¯
ãã«æ¯å¹ ã¯80ããã€ã«ã¿ãŒã¯0.1ç§ãRFé»åã¯
0.05mgãèµ°æ»æéã¯ïŒåãèµ°æ»å¹ ã¯10ppmã§ãèµ°
æ»ç«¯ã¯Oppmãæ žã¯æ°ŽçŽ ãåºæºã¯ããã©ã¡ãã«
ã·ã©ã³ïŒTMSïŒã宀å è©Šæ枩床åã³DCCl3溶åªã
çšããã éé»é²æ¢å€ã®éã¯ç¹ç¶çžäºã®ä»çãããããã
ãšãªããèåæ§ã«æ害ãªåœ±é¿ãäžããããšããªã
现æç©ã絡ã¿ãæžå°ããã硬ååã³éé»é²æ¢ç¡¬å
ã®äž¡æ¹ãäžããã®ã«å åãªéã§ãããææ©ç¬¬åçŽ
ã¢ã³ã¢ããŠã éé»é²æ¢å€ã®éã¯ãäžè¬ã«æ°Žæ§åŠç
çšçµæç©ã®å°ãªããšãçŽ0.05ééïŒ ã®éã§ããã
ææ©ç¬¬åçŽã¢ã³ã¢ããŠã éé»é²æ¢å€ã®éãäœãã«
ãå€ããšçŽ°æçã®çµ¡ã¿ãå¢å ãããããšã«ãªãã
åŸã€ãŠæå©ã§ããããã¯ãããæ害ã«ãªããäžè¬
ã«ææ©éé»é²æ¢å€ã®éã¯ããããªåéæã®ããã«
ã補é ããããã®æ°Žæ§ååŠçåŠççšçµæç©ã®çŽ
0.05ãçŽ0.4ã奜ãŸããã¯çŽ0.05ãçŽ0.15ééïŒ ã®
ç¯å²ã«ãããå ãŠããããããã«ã補é ããå Ž
åãææ©éé»é²æ¢å€ã®éã¯0.3åã¯0.4ééïŒ ã®é
ãŸã§ã®ç¯å²ã«ããããšãåºæ¥ãã æ°Žæ§ååŠçåŠççšçµæç©ã¯æ¬è³ªçã«ã©ããªç¡æ©
éé»é²æ¢å€ãå«ãŸãªãããã®ãããªç¡æ©éé»é²æ¢
å€ã®äŸã«ã¯å¡©åã¯ãã ãã¢ã«ã«ãªéå±åã³ã¢ã«ã«
ãªåé¡éå±å¡©åç©ãäŸãã°å¡©åãªããŠã åã³å¡©å
ãã°ãã·ãŠã ã§ãèåæ§ã«æªåœ±é¿ãäžããªããã®
ããããããããã«éå®ããããã®ã§ã¯ãªãã ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®çŽ°ææ§ãéé»
æ°çºçãäœäžããããæ害ãªéã®çŽ°æç©ã®çµ¡ã¿ã
äžããçµæã«ãªãå Žåãæ°Žæ§ååŠçåŠççšçµæç©
ã¯ã¹ãã©ã³ã硬åå€ããå«ãã¹ãã§ããããã®æ
æã¯ç¹ç¶åå¿ã®ä»çããããããæã¯ããã«ã®é
ææ§ãäœäžãããããšãªã絡ã¿ãæžå°ãã¹ãã§ã
ãããã®ãããªã¹ãã©ã³ã硬åå€ã®æå¹ãªéã¯ã¹
ãã©ã³ãã®äžäœæ§ãå¢å ã现æç©ã®çµ¡ã¿ãæžå°ã
ããã¹ãã©ã³ãã®äžäœæ§ã¯äœãã«ã倧ããªçšåºŠãŸ
ã§å¢å ãããã¹ãã§ã¯ãªããäœæ ãªãããã¯ã¹ã
ã©ã³ãåå¿ã®ä»çãå¢å ããçµæã«ãªãããšãã
ãããã§ãããé©åœãªã¹ãã©ã³ã硬åå€ã®äŸã¯ã¡
ã©ãã³ãã«ã ã¢ã«ãããããããµãã¹ïŒã¡ããªãŒ
ã«å«æçž®åç©ãåéäœãäºéäœãäžéäœåã³ãã
ããé«åºŠã®ãªãªãŽããŒãã®åŠãã¢ã«ãããçž®åé
åäœãå«ãããèªäœæ¶æ©å¯èœãªææã§ããããã
ãã«éããããã®ã§ã¯ãªãããã®å ŽåããšããŒã«
åã¯ã¬ãŸã«ã·ããŒã«ã«ã€ããŠã¯ãé åç©ã¯ã¯ãªãŸ
ãŒã«åã³ãã®ç°æ§äœã®æ··åç©ããã·ã¬ãŒã«æã¯ã
ã®ç°æ§äœã®æ··åç©ããšããŒã«ã®åæäœã®æ··åç©ã
å«ã¿ãã¬ãŸã«ã·ããŒã«ãã¯ã¬ãŸã«ã·ããŒã«åã³ã¡
ã¿ãã·ãã«ã·ããŒã«ã®åŠãäºäŸ¡ã®ããšããŒã«ãçš
ããããšãåºæ¥ããã¢ã«ãããã«ã¯ãã«ã ã¢ã«ã
ããã®ä»£ããã«çšããããšãåºæ¥ãã©ããªã¡ãã¬
ã³äŸäžäœãå«ãŸããäŸãã°ãã©ãã«ã ã¢ã«ãã
ãããããµã¡ãã¬ã³ããã©ãã³ãé žã¢ã«ãããã
ãã«ãã©ãŒã«åã³ãããã®æ··åç©ãå«ãŸãããã¢
ã«ãããæã¯ã¡ãããŒã«çž®åç©ã¯é žåã¯å¡©åºè§Šåª
ãšå ±ã«çšããããšãåºæ¥ããäžçš®ä»¥äžã®ã¡ã©ãã³
ãã«ã ã¢ã«ãããæš¹èãå«ãã®ã奜ãŸãããäœæ
ãªããããã¯æ¶æ©ãããããçµæç©äžã®ä»ã®éå
äœãšçžå®¹æ§ãæããããã§ãããç¹ã«é©ããã¡ã©
ãã³ãã«ã ã¢ã«ãããæš¹èã¯ãåæšåã¬ãžã¡ã³
ïŒResimeneïŒ841ãšããŠã¢ã³ãµã³ãã»ã«ã³ãããŒ
ããå ¥æåºæ¥ãæ°Žæ§ã¡ã©ãã³ãã«ã ã¢ã«ãããæš¹
èã§ãããããã¯éé¢ã®ãã«ã ã¢ã«ããããïŒïŒ
ããå°ãªããã¡ã¿ããŒã«ã¯ïŒïŒ ããå°ãªãã98.9
ïŒ210ãïŒã®æ²žç¹ãæãããã¬ãžã¡ã³841ã¯ã¡ã¿ã
ãŒã«ã«å¯Ÿã95ãæ°Žã«å¯Ÿã17.5ã®èžæ°å§ãã¡ã¿ããŒ
ã«ã«å¯Ÿã1.11ãæ°Žã«å¯Ÿã0.64ã®èžæ°å¯åºŠãç¡è²ã§
éæãªæµåæ§ã®æ¶²äœå€èŠ³ã25âïŒ77ãïŒã§1.25ã®
æ¯éåã³29äœç©ïŒ ã®æ®çºæ§ãæãããçšããããš
ã®åºæ¥ãä»ã®ã¹ãã©ã³ã硬åå€ã¯ããªïŒããã«ã
ããªãã³ïŒã§ãããã¹ãã©ã³ã硬åå€ã®éã¯æ°Žæ§
åŠççšçµæç©ã®å°ãªããšãçŽ0.1ééïŒ ã®ç¯å²ã«
ããã¬ãžã¡ã³841ææãšåæ§ãªã¡ã©ãã³ãã«ã ã¢
ã«ãããæš¹èã®éã«åçãªéã§ãããäžå±€å€ãã®
éãçšããŠãè¯ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
0.5ééïŒ ãè¶ããéã¯äœãä»å çãªå©ç¹ãäžã
ãªãã奜ãŸããã¯ãã®éã¯æ°Žæ§ååŠçåŠççšçµæ
ç©ã®çŽ0.1ãçŽ0.15ééïŒ ã®ç¯å²ã«ãããçšãã
ããããªïŒããã«ãããªãã³ïŒã®éã¯æ°Žæ§åŠççš
çµæç©ã®0.5ééïŒ ãè¶ããã¹ãã§ã¯ãªããäœæ
ãªãããªïŒããã«ãããªãã³ïŒã¯åŠçãããã¬ã©
ã¹ç¹ç¶ã®ã¬ãç¹æ§ãäœäžããããšããããåŠçã
ããã¬ã©ã¹ç¹ç¶ã«æãŸãããªãçšåºŠã®ç¡¬åºŠãäžã
ãããšãããããã§ããã ä»ã®ä»å çãªãã€ã«ã 圢ææ§éåäœãã«ãããª
ã³ã°å€ã最æ»å€ãåŠçå©å€åã³æ¿åå€ãæ¬çºæã®
æ°Žæ§ååŠçåŠççšçµæç©ã«çšããŠãããããæ°Žæ§
åŠççšçµæç©äžã®å¯äžã®æ©èœããšããã·å«æéå
äœåã¯å ±éåäœãæ¶æ©ããããšã«ãããããªãšã
ãã·ç¡¬åå€ã¯æ¬è³ªçã«å«ãŸãªããæŽã«æ°Žæ§ååŠç
åŠççšçµæç©ã¯ãç²çæ§å¶çŽãã€ã«ã 圢ææ§éå
äœäžãæã¯ãšããã·å«æéåäœåã¯å ±éåäœãšç²
çæ§å¶çŽãã€ã«ã 圢ææ§éåäœãšã®æ··åç©äžã§æº¶
解ãããããšãåºæ¥ãªããããªææã¯æ¬è³ªçã«å«
ãŸãªãããã®ãããªææã¯æ°ŽçŽ åãããçåæ°ŽçŽ
æ²¹ã®åŠãéã€ãªã³æ§ã§æ°Žäžæº¶æ§ã®çåæ°ŽçŽ ã¬ã©ã¹
ç¹ç¶æœ€æ»å€ã§ãããå žåçã«ã¯æ°Žäžæº¶æ§æœ€æ»å€ã¯
ã°ãªã»ããŒã«ã®æ°ŽçŽ åãããåã¯é£œåèèªé žãšã¹
ãã«ã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã¯ãããã®
çš®é¡ã®ææãæ¬è³ªçã«å«ãŸãªãã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãã¬ã©ã¹ç¹ç¶ã圢æ
ãããéã«æ°Žæ§ååŠçåŠççšçµæç©ã§ããããåŠ
çããããšãåºæ¥ããããªå åãªå šåºåœ¢ç©éãã
ã®çµæç©ã«äžããã®ã«å åãªéã®æ°Žãæãããäž
è¬ã«æ°Žæ§çµæç©ã®å šåºåœ¢ç©ã¯çŽïŒãçŽ30ééïŒ ã
奜ãŸããã¯çŽïŒãçŽ10ééïŒ ã®ç¯å²ã«ãããã©ã®
å Žåã§ããæ°Žæ§ååŠçåŠççšçµæç©ã®ããã®åºåœ¢
ç©æåã®éã¯ã溶液ã®ç²åºŠã20âã§çŽ100ã»ã³ã
ãã€ãºãã倧ãããããããªéãè¶ããã¹ãã§ã¯
ãªãã20âã§100ã»ã³ããã€ãºãã倧ããªç²åºŠã
æããæ°Žæ§æº¶æ¶²ã¯ã¬ã©ã¹ç¹ç¶åœ¢æäžãããç¹ç¶ã
ç Žæããããšãªãã¬ã©ã¹ç¹ç¶ã«é©çšããããšãé
åžžã«å°é£ã§ããããã®åŠçå€ã®ç²åºŠã¯æè¯ã®çµæ
ãåŸãããã«ã¯20âã§ïŒã20ã»ã³ããã€ãºã§ãã
ã®ã奜ãŸããããªããœããããŒæ§ã²ã«åå€åã¯çº
泡å€ãæããååŠçåŠççšçµæç©ã¯ã¬ã©ã¹ç¹ç¶ã
åŠçããããã«ãçšããããã²ã«åã³çºæ³¡ç©ã®ã
ãã®æ¢ç¥ã®ç²åºŠãæããããšãåºæ¥ããæ°Žæ§ååŠ
çåŠççšçµæç©ã®PHã¯çŽïŒããäœããçµæç©ã®å®
å®æ§ãç¶æããããã«ã¯çŽ4.8ãçŽ5.2ã®ç¯å²ã«ã
ãã®ã奜ãŸãããæ°Žæ§ååŠçåŠççšçµæç©ã¯æå
ãåæã«åã¯é 次äžç·ã«ããããšã«ããäœãããš
ãåºæ¥ãã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãââã¬ã©ã¹âã
â621âã¬ã©ã¹âåã³ãããã®ç¡ŒçŽ åã³ïŒåã¯ïŒãµ
ã€çŽ å«æéã®äœãåã¯ããããå«ãŸãªãèªå°äœã®
åŠãç¹ç¶åå¯èœãªã¬ã©ã¹ææåã³ââã¬ã©ã¹âã
ââã¬ã©ã¹âåã³ââã¬ã©ã¹âãšããŠç¥ãã
ãŠããã¬ã©ã¹ç¹ç¶çµæç©ã«é©çšããããšãåºæ¥
ããéææã¯åéæã®éåäœããã«ã補é ããã®
ã«çšããååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã補é ã
ãæãç¹ç¶åå¯èœãªã¬ã©ã¹çµæç©ã¯ãããããã¢
ã¯ãªã«ããªãšã¹ãã«ãããªãã¯ã¹æš¹èãè£åŒ·ãã
ã®ã«çšããããå Žåãéè²æã¯éå³ããã€ãè²ã
äžããã¬ã©ã¹ç¹ç¶ãããããã®ã奜ãŸãããã¬ã©
ã¹ç¹ç¶çµæç©ã¯çŽ1.5495ã1.5740ã®ç¯å²ã®ã¬ã©ã¹
ç¹ç¶ã®å±æçãäžããã®ã奜ãŸãããã¬ã©ã¹ã®å±
æçãé«ããªããšãç¹ç¶ã§è£åŒ·ãããéæãªãã
ã«ã«æãŸãããªãããã³ãºè²ãäžãããæã奜ãŸ
ããã¬ã©ã¹ç¹ç¶ã®å±æçã¯1.5495ã1.557ã®ç¯å²
ã«ããã æ°Žæ§ååŠçåŠççšçµæç©ã¯åœæ¥è ã«ç¥ãããã©
ããªæ¹æ³ã«ãã€ãŠã¬ã©ã¹ç¹ç¶ã«é©çšããŠãããã
äŸãã°ã¬ã©ã¹ç¹ç¶ã®åœ¢æäžãã¬ã©ã¹ç¹ç¶ãæ°Žæ§å
åŠçåŠççšçµæç©ãé©çšã§ããå åãªæž©åºŠã«å·åŽ
ãããåŸã«é©çšãããããµã€ãžã³ã°çµæç©ãšããŠ
å žåçã«èšåããããæ°Žæ§ååŠçåŠççšçµæç©ã¯
ãã«ããããŒã©ãŒãåŽé§åšçãæããé©çšåšã«ã
ã€ãŠãããã®ã¬ã©ã¹ç¹ç¶ã«é©çšãããã次ã«åŠç
ãããã¬ã©ã¹ç¹ç¶ã¯ïŒæ¬ä»¥äžã®ã¹ãã©ã³ãã«éã
ããã圢æçšããã±ãŒãžãšããŠäžè¬ã«èšåãããŠ
ããããã±ãŒãžã«ãã€ããŠãè¯ããåã¬ã©ã¹ç¹ç¶
ã¯ïŒæ¬ä»¥äžã®ã¹ãã©ã³ãã«éãã湿ã€ã现æçæ
ç©ãšããŠçŽ°æããŠãè¯ããåã¬ã©ã¹ç¹ç¶ã¯ïŒæ¬ä»¥
äžã®ã¹ãã©ã³ãã«éããããŒãã³ã°ãšããŠéããŠ
ãè¯ããã¬ã©ã¹ç¹ç¶ã¯ä¹Ÿç¥ããŠãããã®æ°Žåå«æ
éãæžå°ããã奜ãŸããã¯ååŠçã«åŠçãããã¬
ã©ã¹ç¹ç¶ã®åœ¢ãã©ã®ãããªãã®ã§ãã€ãŠãããã
ãã¯çŽ121âïŒ250ãïŒã149âïŒ300ãïŒããäœã
ç¯å²ã®æž©åºŠã§11æéã«çžåœãã枩床åã³æéæ¡ä»¶
ã§ä¹Ÿç¥ãããã也ç¥ã¯é颚çãèªé»äœççã®åŠã
åŸæ¥ã®ã¬ã©ã¹ç¹ç¶ä¹Ÿç¥çã§éæããããšãåºæ¥
ãã也ç¥ããã¬ã©ã¹ç¹ç¶ã¯ã¹ãã©ã³ããæ§æãã
ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã«ååšããæ°Žæ§ååŠçåŠççšçµ
æç©ã®ä¹Ÿç¥æ®æž£ãæããã奜ãŸããã¯ã¬ã©ã¹ç¹ç¶
äžã®ä¹Ÿç¥æ®æž£ã®éã¯ãçŽ0.5ã1.2ééïŒ ã®ç¯å²ã®
LOIïŒçŒç±æžéïŒã§ããã æ°Žæ§ååŠçåŠççšçµæç©ã®æ®æž£ãæãã也ç¥ã¬
ã©ã¹ç¹ç¶ã¯ã飜ååã³äžé£œåããªãšã¹ãã«åã³ãš
ããã·ã®åŠãéåæ§è£åŒ·éåäœã補é ããã©ããª
æ¹æ³ã«çšããŠãè¯ããã¬ã©ã¹ç¹ç¶ãç¹ã«é©ããŠã
ãïŒã€ã®æ¹æ³ã¯éææã¯åéæã®ã¢ã¯ãªã«éåäœ
ã¬ã©ã¹ç¹ç¶è£åŒ·ããã«ã®åœ¢æã§ãããã¬ã©ã¹ç¹ç¶
éæåã³åéæããã«ã補é ããã®ã«çšãããã
åæ¥çãªé«é床æäœã§ã¯ãæ°Žæ§ååŠçåŠççšçµæ
ç©ã®ä¹Ÿç¥æ®æž£ãæããã¬ã©ã¹ç¹ç¶ã¯çæ³çã«é©ã
ãŠããã现æããã¬ã©ã¹ç¹ç¶ã¯ããã«ã補é ãã
ããã®é«é床æäœã®æ¡ä»¶å ã§éåäœãããªãã¯ã¹
ã«éåžžã«ããæ¿¡ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
也ç¥æ®æž£ãæããã¬ã©ã¹ç¹ç¶ã¯ã也ç¥çŽ°æããã
ã¬ã©ã¹ç¹ç¶ãæã¯éæ¬ãã«ãç¶ã®ã»ããã¢ã³ã®åŠ
ãå¥é¢åºæäžã移åããéåäœãããªãã¯ã¹ãžåŸ
ã§çŽ°æãããããŒãã³ã°ãšããŠãã®ãããªæäœãž
äŸçµŠããŠãè¯ãã现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã
ãéåäœãããªãã¯ã¹ç¶ã«ããããåäžã«åæ£ã
ãããšããããã¬ã©ã¹ç¹ç¶ã¯ã¬ã©ã¹ãããªãã¯ã¹
äžã«æ²éãæ¿¡ããããããã«ãªãã次ã«ã¬ã©ã¹ç¹
ç¶éåäœãããªãã¯ã¹ãé©åœãªçäžã§ç¡¬åããã¬
ã©ã¹ç¹ç¶è£åŒ·ããã«ã補é ããããããããã«
ã¯ãã»ãšãã©ç¹ç¶ã®çªèµ·ããããè¯å¥œãªéææ§ã
æãããæ¬çºæã®åŠçãããã¬ã©ã¹ç¹ç¶ã¯åéæ
ã§å ãŠããããŠããªãããã«ç³»ã«çšããŠãããã
åçŽ12ãçŽ50ééïŒ ã®çé žã«ã«ã·ãŠã ãå ãŠãã
ãããã®ãçè²å ãŠãããããã®ãã®åŠãå ãŠã
ãããç³»ã«çšããŠããããä»ã®å ãŠããããåå
ãŠããããŠããªãéåäœãããªãã¯ã¹ç³»ã«çšããŠ
ãè¯ãã æ¬çºæã®å¥œãŸããå ·äœäŸãšããŠãã¬ã©ã¹ç¹ç¶ã¯
溶èããããã现ããããçŽ1.554ã1.557ã®å±æ
çãæããçŽ5.2ééïŒ ã®B2O3æ¿åºŠãæãããã¬
ã©ã¹ç¹ç¶ã®ã¬ã©ã¹çµæã¯ééïŒ ã§SiO2â55.8ã
CaOâ21ãAl2O3â14.8ãB2O3â5.2ãNa2Oâ
1.4ãF2â0.5ãåã³ã¬ã©ã¹ã®åèšæåãåŸãã®ã«
çšãããããããé åç©ããéåžžååšãã埮éã®
ææãããªãã®ã奜ãŸãããã¬ã©ã¹ç¹ç¶ã¯ã¬ã©ã¹
溶èçã®å¥ç®¡äžã®å€æ°ã®ç©Žããã¬ã©ã¹ç¹ç¶ã圢æ
ããéã«ããã«ãåçµåå€é©çšåšã«ãã€ãŠæ°Žæ§å
åŠçåŠççšçµæç©ã§è¢«èŠãããã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãã€ã«ã 圢æã®ãã
ã®å¯äžã®éåäœææãšããŠåæšåããªã¯ã·ã«954
ãšããŠãµããã瀟ããå ¥æåºæ¥ããã¹ããšããŒã«
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœãå«ãåäžã®
æ°Žæ§ãšãã«ãžãšã³ã§ããããã¹ããšããŒã«ããªãš
ã¹ãšãã«æã¯ãšã¹ãã«åãšããã·ãã€ã«ã 圢ææ§
éåäœã¯ãéåäœïŒã¢ã«åœãã1.4ããå°ããªäº
éçµåã®èèªæäžé£œåã®éãæãã奜ãŸããã¯
0.1ããå°ãããæã奜ãŸããã¯ãçŽ0.07ã§ãã
èèªæäžé£œå察è³éŠæäžé£œåæ¯ãæããã奜ãŸã
ãã·ã©ã³ã«ãããªã³ã°å€ã¯åæšåA174ã·ã©ã³ãš
ããŠãŠããªã³ã»ã«ãŒãã€ãã»ã³ãŒãã¬ãŒã·ãšã³ã
ãå ¥æãããγâã¡ã¿ã¯ãªããã·ãããã«ããªã¡
ããã·ã·ã©ã³ã§ãããA174ã·ã©ã³ã®éã¯æ°Žæ§å
åŠçåŠççšçµæç©ã®åºåœ¢ç©ã®çŽ2.7ãçŽïŒééïŒ
ã®ç¯å²ã«ããã®ã奜ãŸããã氎溶æ§éœã€ãªã³æ§ã¬
ã©ã¹ç¹ç¶æœ€æ»å€ã¯ãšããªãŒãªãŠãŠã6717ã§ããã®
ã奜ãŸãããããã¯æ°Žæ§ååŠçåŠççšçµæç©ã®åº
圢ç©ã®çŽïŒã2.5ééïŒ ã®éã§ååšããããšãã
ã·ã«åãããéœã€ãªã³æ§ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§
ããææ©éé»é²æ¢å€ã¯ããªã¯ã·ã«AOâ5620éé»
é²æ¢å€ã§ãããã¯æ°Žæ§åŠççšçµæç©ã®çŽ0.05ãçŽ
0.15ééïŒ ã®æå¹ãªéã§çšããããå¯äžã®éé»é²
æ¢å€ãšããŠååšãããåãã¬ãžã¡ã³841ã¡ã©ãã³
ãã«ã ã¢ã«ãããã§ããã¹ãã©ã³ã硬åå€ãæ°Žæ§
åŠççšçµæç©ã®çŽ0.1ã0.15ééïŒ ã®éã§ååšã
ããã®ã奜ãŸãããæ°Žæ§ååŠçåŠççšçµæç©ãæ§
æãããããã«ååšããæ°Žã¯ãæ°Žæ§ååŠçåŠççš
çµæç©ã®å¥œãŸããã¯çŽïŒãïŒééïŒ ã®å šåºåœ¢ç©ã
äžãããããªéã§ããããã¹ããšããŒã«ããªãšã¹
ãã«æš¹èã®éã¯ã«ãããªã³ã°å€ã最æ»å€ãéé»é²
æ¢å€åã³ã¹ãã©ã³ã硬åå€ã®éããã®åºåœ¢ç©ã®æ®
ãã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã®PHã¯çŽ5.5
ã6.2ã®ç¯å²ã«ããã®ã奜ãŸããã æ°Žæ§ååŠçåŠççšçµæç©ã¯ã¡ã¿ã¯ãªããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³ãé ¢é žã«ãã€ãŠãäºãæ··
åãããã¿ã³ã¯äžã§ãã®ã·ã©ã³çŽ20ïœã«å¯Ÿãé ¢é ž
çŽïŒmlã®éã§å æ°Žå解ããããšã«ãã補é ãã
ããå æ°Žå解ã¯ååŠçåŠççšçµæç©ã補é ããã®
ã«çšããããæ°Žã®çŽ10ã20ééïŒ ã«é ¢é žãæ·»å
ããã·ã©ã³ããã®æ··åç©ãžãå®å šãªå æ°Žå解ãèµ·
ãããŸã§æªäŒŽããªããæ·»å ããããšã«ãã€ãŠéè¡
ããããéœã€ãªã³æ§ã¬ã©ã¹ç¹ç¶æœ€æ»å€ã¯76.7â
ïŒ170ãïŒã®ç±ãæ°Žã«æªäŒŽããªããæ·»å ããããã®
å Žåæ°Žã®éã¯äºãæ··åãããã¿ã³ã¯äžã§æ°Žæ§ååŠ
çåŠççšçµæç©ã補é ããã®ã«çšããããæ°Žã®å š
éã®çŽïŒïŒ ã§ãããçŽ46ïŒ ã®åºåœ¢ç©ã§ãããã¹ã
ãšããŒã«ããªãšã¹ãã«ã®æ°Žæ§ãšãã«ãžãšã³ã¯äž»ã
ãæ··åã¿ã³ã¯äžã§ãã®ééã®çŽïŒåã®éã®æ°Žãšäž
ç·ã«ããããå æ°Žå解ãããã·ã©ã³åã³ã¬ã©ã¹ç¹
ç¶æœ€æ»å€ã¯ãã®äž»ããæ··åã¿ã³ã¯ãžæ·»å ãããã
éœã€ãªã³æ§ææ©ãšããã·ã«å第åçŽã¢ã³ã¢ããŠã
å¡©éé»é²æ¢å€ã¯æ°ŽãšçŽïŒïŒ16ã®æ¯ã§äžç·ã«ããã
äž»ããæ··åã¿ã³ã¯ãžæ·»å ããããã¡ã©ãã³ãã«ã
ã¢ã«ãããæš¹èã¯æ°ŽãšçŽïŒïŒ300ã®æ¯ã§äžç·ã«ã
ããäž»ããæ··åã¿ã³ã¯ãžæ·»å ããããSAGïŒïŒ
ã®ãããªæ¶æ³¡å€ãå°éæ·»å ããŠããããæªäŒŽãã
ãŠããæ··åç©ãæ°Žã§æçµçåžæã®äœç©ãŸã§åžéã
ãã次ã«æ°Žæ§ååŠçåŠççšçµæç©ã®æçµPHãé ¢é ž
ã®åŠãçžå®¹æ§ã®ææ©é žã§çŽ5.5ãçŽ6.2ã®ç¯å²ã«ãª
ãããã«èª¿ç¯ããã 奜ãŸããã¯æ°Žæ§ååŠçåŠççšçµæç©ã¯ã¬ã©ã¹ç¹
ç¶ã®åœ¢æäžçŽ1.555ã®å±æçãæããæªåŠçã¬ã©
ã¹ãžé©çšããããã®å Žåç¹ç¶ã¯ãçŽ10.3Ã10-5ã
97.5Ã10-5ã€ã³ãæã¯ãã以äžã奜ãŸããã¯ãçŽ
35ã40Ã10-5ã®ç¯å²ã«ããããšãåºæ¥ããæ°Žæ§å
åŠçåŠççšçµæç©ã¯çŽ0.5ãçŽïŒïŒ ã®ç¯å²ã®LOI
ïŒçŒç±æžéïŒãšããŠååŠçåŠççšçµæç©ã®ä»çç©
ãäžããããã«ã¬ã©ã¹ç¹ç¶ãžé©çšããããã¬ã©ã¹
ç¹ç¶ã¯å¥œãŸããã¯ãããæã¯ïŒ«ç¹ç¶ã§ãã¹ã
ã©ã³ããžéãããšïŒ§â67ïŒåã¯ïŒšâåã¯ïŒ«â37ïŒ
ã¹ãã©ã³ãçã®ãããªè£œé ãäžãããã®ã§ããã
ã¬ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã¯ã¹ãã©ã³ãå·»ãã«é
ããããŒãã³ã°ããã±ãŒãžãäœããå€æ°ã®ããŒã
ã³ã°ããã±ãŒãžãçŽ104ã149âïŒ220ã300ãïŒã®
ç¯å²ã®æž©åºŠã§11æéãã·ã¬ã³ïŒMichiganïŒçäž
ã§ä¹Ÿç¥ããã次ã«ããŒãã³ã°ãçŽ0.159cmïŒïŒïŒ
16ïŒã5.08cmïŒïŒã€ã³ãïŒã奜ãŸããã¯2.54cm
ïŒïŒã€ã³ãïŒã®é·ããæãã现æã¹ãã©ã³ããžçŽ°
æããéææã¯åéæã®ã¢ã¯ãªã«ããªãšã¹ãã«æ
ã¯ãšããã·ããã«ã補é ããæ¹æ³ã§çšããããšã
åºæ¥ãã现æããã¹ãã©ã³ãããéæ¬æ©ãã«ãã
ããããªãã¯ã¹ãå¥ããããã®ã»ããã¢ã³ã®åŠã
å¥é¢åºæãæãã移åããéæ¬æ©äžã«ååšããã
ããªãã¯ã¹æš¹èäžãžèœãšãã现æãããã¬ã©ã¹ç¹
ç¶ã¹ãã©ã³ããå«ããããªãã¯ã¹æš¹èã¯çãžé
ã³ãããã§ããã«ãå ç±ããŠç¡¬åããã æ¬çºæåã³å¥œãŸããå ·äœäŸãæŽã«æ¬¡ã®å®æœäŸã«
ããäŸç€ºããã å®æœäŸ ïŒ 189.27ïŒ50ã¬ãã³ïŒã®æ°Žæ§ååŠçåŠççšçµæ
ç©ãè¡šïŒã®æåãçšããŠè£œé ããããã®çµæç©ã
奜ãŸããå ·äœäŸãšããŠèšè¿°ããã¬ã©ã¹ç¹ç¶ãåŠç
ããã®ã«çšããã
ã¬ã©ã¹ç¹ç¶ã§ãããã«ïŒPanelïŒãç¹ã«åéæã®
ããã«ã補é ããçºã®éåäœãããªãã¯ã¹ãè£åŒ·
ããã®ã«çšããã®ã«çæ³çãªã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã«é¢ããã è£åŒ·ãã©ã¹ããã¯å·¥æ¥ã§ã¯æ¥µããŠå€ãã®è£œåã
補é ããããã®éåäœãããªãã¯ã¹ãè£åŒ·ããçº
ã«çš®ã ã®åœ¢ã®ã¬ã©ã¹ç¹ç¶ãçšããŠãããäŸãã°ã
ã¬ã©ã¹ç¹ç¶ã¯é£ç¶çåã³çŽ°æããåç¹ç¶åã³ã¹ã
ã©ã³ãããããããŒãã³ã°ïŒrovingïŒãç¹ç©åã³
äžç¹åžã®åœ¢ã§éåäœãè£åŒ·ããçºã«çšããããŠã
ããç±å¯å¡æ§åã³ç±ç¡¬åæ§éåäœãããªãã¯ã¹ã¯
äž¡æ¹ãšããèæ¿æåææãèåç©æåææãå°åº
æåçæç©ãåŽé§æåçæç©ãåã³åæ§ãªæåç
æç©ã®åŠã補åã補é ããã®ã«çš®ã ã®åœ¢ã®ã¬ã©ã¹
ç¹ç¶ã§è£åŒ·ãããŠæ¥ãã éåäœè£åŒ·ç©åžå Žã®çºã®ã¬ã©ã¹ç¹ç¶ã補é ãã
éã«ãã¬ã©ã¹ç¹ç¶ã¯æº¶èãããç¹ç¶åå¯èœãªã¬ã©
ã¹ææã®å ¥ã€ãçã«çµåãããå¥ç®¡ãªã©ã®è£ 眮ã
ãåºãç¹ç¶åå¯èœãªã¬ã©ã¹ææã®æº¶èæµãã现ã
ãããã§ãããã¬ã©ã¹ç¹ç¶ã¯ãéãŸã€ãåç¹ç¶ã
åéããŠããã±ãŒãžïŒPackageïŒã«ããå·»ãåã
åšãæã¯ç¹ç¶ãéããããŠçŽ°æãããåã«ããã
ç¹ç¶ãåŒåŒµãããŒã©ãŒã«ãã€ãŠçŽ°ãããããã¬ã©
ã¹ç¹ç¶ã補é ããæ¹æ³ã§ã¯ãååŠçåŠççšçµæç©
ããç¹ç¶ãã¬ã©ã¹æº¶èæµãšããŠçŽ°ããããããåŸ
ã§ãããã«é©çšããããååŠçåŠççšçµæç©ã¯é
åžžãã€ã«ã 圢ææ§ææã«ãããªã³ã°å€åã³æœ€æ»å€
ãæ £ç¿çã«å«ãã§ããæ°Žæ§çµæç©ã§ãããååŠç
åŠççšçµæç©ã¯ãããããã¬ã©ã¹ç¹ç¶åã¯ã¹ãã©
ã³ãã®æã«éããããæã¬ã©ã¹ç¹ç¶ã®åç¹ç¶çžäº
ã®æ©èãé ãããè£åŒ·ããããšããéåäœãããª
ãã¯ã¹ã«å¯Ÿããããã¬ã©ã¹ç¹ç¶ãçžå®¹æ§ã«ããçº
ã«å¿ èŠã§ãããå žåçã«ã¯ãååŠçã«åŠçããã
ã¬ã©ã¹ç¹ç¶ã¯ããã±ãŒãžã®åœ¢æã¯ç¹ç¶ãéåäœã
ããªãã¯ã¹ãè£åŒ·ããããã«çšããããåã®çŽ°æ
ãããã¹ãã©ã³ãã®åœ¢ã§ä¹Ÿç¥ããããéææã¯å
éæã®è£åŒ·ããããã©ã¹ããã¯æ¿ã®ãããªã¬ã©ã¹
ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã¯ã倪éœéå åšã倩
çªãç §æåšå ·ã®èŠãããã©ã¹ã®èŠããäž»èŠéè·¯ã®
æšèåã³èšå·ã枩宀ã®ã¬ã©ã¹çã®çšéãæããã
ã¬ã©ã¹ç¹ç¶è£åŒ·ç©ãæããåéæããã«ã®å Žåã
ã¬ã©ã¹ç¹ç¶ã¯ä»ã®è£åŒ·ãããéåäœçæç©ã®å Žå
ã«èŠæ±ãããéåžžã®ã¬ã©ã¹ç¹ç¶ç¹æ§ãè¶ ããç¹å¥
ãªç¹æ§ãæã€ãŠããªããã°ãªããªããäŸãã°ãã¬
ã©ã¹ç¹ç¶ã¯ããã«ã®æž æŸæ§æã¯èåæ§ãæžããã
ã®ã§ãã€ãŠã¯ãªãããã¬ã©ã¹ç¹ç¶ã¯ããã«è£œé ã®
éã®é©åãªå å·¥æ§ãæããªããã°ãªããªããé©å
ãªå å·¥æ§ã«ã¯è¯å¥œãªã¹ãã©ã³ã现ææ§ãããã«ã
補é ããéã®ã¹ãã©ã³ãå士ãæ¥çããåŸåãå°
ããããæ§è³ªãå²ãåœãŠãããåŠçæéã§éåäœ
ãããªãã¯ã¹äžã«ã¹ãã©ã³ãã容æã«åæ£ããæ§
質ãå«ãŸããããã®æè¡åéã§çŽé¢ããéåžžã«å°
ã€ãåé¡ã¯ãç¹å®ã®çš®é¡ã®ã¬ã©ã¹ç¹ç¶åã³æ°Žæ§å
åŠçåŠççšçµæç©ã®ç¹å®ã®æåãçšããŠå¿ èŠãªç¹
æ§ãåŸãããšãåºæ¥ã«ããããšã§ãããããå Žå
ã«ã¯ããã®å°é£æ§ã¯å®éã«äºãã«æä»çãªããã€
ãã®ç¹æ§ã«ãªãã æ¬çºæã®ç®çã¯ãã¬ã©ã¹ç¹ç¶è£åŒ·ãã©ã¹ãã
ã¯ãç¹ã«éææã¯åéæã¬ã©ã¹ç¹ç¶è£åŒ·ãã©ã¹ã
ãã¯æ¿ãžå å·¥ããããšãåºæ¥ãååŠçã«åŠçãã
ãã¬ã©ã¹ç¹ç¶ãäžããããšã§ããã ãæ¬çºæã®èŠçŽã ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã®å®è³ªçéšåã«ååšããæ°Žæ§
ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæããæ¬çºæã®
ã¬ã©ã¹ç¹ç¶ã¯ãéåäœãããªãã¯ã¹ãè£åŒ·ããã®
ã«è¯å¥œãªå å·¥æ§ãæããè¯å¥œãªèåæ§ãæãã硬
åãããªãã¯ã¹ãäžããã æ°Žæ§ååŠçåŠççšçµæç©ã¯åçš®é¡ã®ååçãªé
æ°Žæ§æåãæãããäžã€ã®éæ°Žæ§æåã¯äžçš®é¡ä»¥
äžã®æ°Žæº¶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã¹ããšããŒã«
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœã§ãããå
ç¬æã¯ããããªãã¯ã¹éåäœãšçžæº¶æ§ããããã
ãã«å¯æº¶æ§ã®ãšããã·å«æãã€ã«ã 圢ææ§éåäœ
ãšã®æ··åç©ã®åœ¢ã«ãªã€ãŠãããä»ã®é氎溶æ§æå
ã¯äžçš®é¡ä»¥äžã®ã¢ã¯ãªããã·åã¯ã¡ã¿ã¯ãªããã·
å«æææ©ã«ãããªã³ã°å€ã§ãããããã«å¥ã®éæ°Ž
æ§æåã¯äžçš®é¡ä»¥äžã®éœã€ãªã³æ§åç¹ç¶æœ€æ»å€ã
äŸãã°ãå°ãªããšãäžçš®é¡ããã©ã«ãŽã³é žã§ãã
èèªé žã§éšåçã«ã¢ããåïŒamidateïŒãããã
ãªã¢ã«ãã¬ã³ã€ãã³ã§ãããä»ã®éæ°Žæ§æåã¯ã
äžçš®é¡ä»¥äžã®ã¢ã«ã³ãã·éšåãæããéœã€ãªã³æ§
ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ããéé»é²æ¢å€ã§é
é»é²æ¢ã«æå¹ãªéã§ååšãããåèšçµæç©ã¯æ¬è³ª
çã«ç¡æ©éé»é²æ¢å€åã³æ°ŽçŽ åæ€ç©æ²¹ãå«ãŸãª
ããçµæç©äžã®æ°Žã®éã¯ã¬ã©ã¹ç¹ç¶ãæ°Žæ§åŠççš
çµæç©ã§åŠçåºæ¥ãããã«ãããããªéã§ããã
æŽã«ãæ°Žæ§çµæç©ã¯ã¹ãã©ã³ã硬åå€ãå«ãããš
ãåºæ¥ããéæ°Žæ§æåã®å€§éšåã®éã¯ãã€ã«ã 圢
ææ§éåäœãããªããææ©ã«ãããªã³ã°å€åã³æœ€
æ»å€ã¯ããããã«ãããªã³ã°åã³æœ€æ»ãè¡ãªãã
ãã®ã«æå¹ãªéã§ååšãããéé»é²æ¢å€ã®éé»é²
æ¢ã«æå¹ãªéã¯æ°Žæ§åŠççšçµæç©ã®çŽ0.05ã0.4
ééïŒ ã®ç¯å²ã«ããã æ¬çºæã®åºãæ æ§ãšããŠãæ°Žæ§åŠççšçµæç©ã¯
ç¹ç¶åå¯èœãªã¬ã©ã¹çµæç©ãã補é ãããã¬ã©ã¹
ç¹ç¶ã«é©çšããããããç¹ç¶ã¯åæãããã¹ãã©
ã³ãæã¯é£ç¶çã¹ãã©ã³ãã®å€å±€ããã±ãŒãžãžåœ¢
æããããæ¬çºæã®å¥œãŸããæ æ§ãšããŠãç¹ç¶å
å¯èœãªã¬ã©ã¹çµæç©ã¯1.5495ã1.5740ã®ç¯å²ã®äœ
ãå±æçãæããã¬ã©ã¹ç¹ç¶ããããããããªæ
æãããªã€ãŠããŠãè¯ãããããã®äžå°åŠçãã
ãïŒsizedïŒã¬ã©ã¹ç¹ç¶ã¯é©åœãªéåäœãããªã
ã¯ã¹ãè£åŒ·ããåéæãããæããªãã°éæãªã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœæ¿ã補é ããããšãåºæ¥ãã
åéæã®ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœæ¿ã¯ãèåæ§ãæ
ãªããæçœã«ã¯èŠããªãã¬ã©ã¹ç¹ç¶ãæããã ãæ¬çºæåã³å¥œãŸããå ·äœäŸã®è©³çŽ°ãªèšèŒã ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã補é ãã
éãã¬ã©ã¹ç¹ç¶ã¯ç¹å®ã®ç¹æ§ãæã€ãŠããªããã°
ãªããªããæŽã«è£åŒ·ãããéåäœææãã倩çªã
ãã©ã¹èŠããäž»çšéè·¯æšèåã³ããããç §æåšå ·
ã®èŠãåã³è£ 食çããµãŒãïŒfacadeïŒã倪éœå é
å åšã枩宀çªçã«çšãããããã®ã®ãããªéææ
ã¯åéæã®éåäœæ¿ã«è£œé ãããæãã¬ã©ã¹ç¹ç¶
ã¯ä»å çãªç¹æ§ãæããªããã°ãªããªãããã®ã
ããªè£œåã補é ããããã®ãã®ãããªãããªãã¯
ã¹éåäœã«çšããããã¬ã©ã¹ç¹ç¶ã«ãšã€ãŠå¿ èŠãª
ç¹æ§ã«ã¯ããããªãã¯ã¹éåäœäžã®åæ£æ§ã®ãã
ã®è¯å¥œãªçŽ°ææ§ãéããã«æ¿¡ããããã«ãããªã
ã¯ã¹éåäœäžãžã®è¯å¥œãªå¯æº¶æ§ã硬åããéåäœ
æ¿äžã®ç¹ç¶ã®çªèµ·ãå°ãªãè¯å¥œãªæž æŸæ§ãäžãã
ããšåã³ç¡¬åããéåäœæ¿ã«è¯å¥œãªèåæ§ãäžã
ãããšãå«ãŸãããã¬ã©ã¹ç¹ç¶ã®æåã¯éããã¬
ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã®åœ¢ã§ã®ã¬ã©ã¹ç¹ç¶ã®çŽ°æ
æ§ã®çºã«ãåŸãããæåã³ïŒåã¯ïŒã¹ãã©ã³ã
ã¯ãå·¥æ¥çã«çžäºä»çãšããŠäžè¬ã«èšåãããŠã
ããã¹ãã©ã³ãå士ã®ä»çããªãã®ãè¯ãããã®
ãããªã¬ã©ã¹ç¹ç¶æåã¯ã¹ãã©ã³ãã®ç¹æ§ã¯ãã¬
ã©ã¹ç¹ç¶ã®éåäœãããªãã¯ã¹ã«ããæ¿¡ããæªã
ããçµæã«ãªãã§ããããæ¬çºæã®ã¬ã©ã¹ç¹ç¶ã¯
äžé£œåããªãšã¹ãã«åã³ãšããã·ã®åŠãã¬ã©ã¹ç¹
ç¶è£åŒ·éåäœææã®éæåã³äžéæãªæ¿ã圢æã
ãã®ã«çšããã®ã«æãé©ããŠããã æŽã«æ¬çºæã®ååç©ã«åŠçãããã¬ã©ã¹ç¹ç¶
ã¯ãå ãŠããããç³»åã³çè²ãããç³»ãå«ãã©ã
ãªéåäœãããªãã¯ã¹ã«ãçšããããšãåºæ¥ãã
ã®å Žåéåäœãããªãã¯ã¹ã«ã¬ã©ã¹ç¹ç¶ãè¿ éã«
æ¿¡ããããšãæãŸãããæ¿¡ãïŒWetâoutïŒã¯ã
ãããªãã¯ã¹éåäœãã¬ã©ã¹ç¹ç¶ãå ã¿ãä»®ãã
ã€ããšããŠãã硬åãããç¹ç¶è£åŒ·éåäœææå š
äœãéããŠè£žã®ã¬ã©ã¹ã¯æ¥µããŠãããããèŠããª
ãããšãæå³ãããã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããª
ãã¯ã¹ã®è£œé äžã®æ¿¡ãã¯ãéåäœãããªãã¯ã¹ãš
ã¬ã©ã¹ç¹ç¶ãšã®æ¥è§Šã®èŠæãã®ç·å¯ãã®å°ºåºŠã§ã
ããããã¬ã©ã¹ç¹ç¶ãããããã¬ã©ã¹ç¹ç¶ãéå
äœãããªãã¯ã¹ãžå ããåŸãããæ¿¡ããªããªã
ã°ãããã¯æçµç硬åãããç¹ç¶è£åŒ·éåäœææ
ã®å å·¥æ§ã硬åç¹æ§åã³è¡šé¢ã®æ§è³ªã«æªã圱é¿ã
äžããããšããããç¹ç¶è£åŒ·éåäœææã®æ¿ãåŠ
çããå Žåã现æãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãå
ã¯ç¹ç¶ã®æã®æ¿¡ãã¯ã现æãããã¬ã©ã¹ç¹ç¶ãå«
ãéåäœãããªãã¯ã¹ãåŠçå·¥çšã§ç¡¬åãããå
ã«çæéã®ãã¡ã«èµ·ããªããã°ãªããªããåŸã€
ãŠã现æãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãæã¯ç¹ç¶ã®
æã®æ¿¡ãã®é床ã¯ãéææã¯åéæã®æ¿ã®ãããª
補åãäœãéã®éèŠãªæ¡ä»¶ã§ããã现æãããã¬
ã©ã¹ç¹ç¶ã¹ãã©ã³ãã®æ¿¡ãã®é床ãé ããšãç¹ç¶
è£åŒ·éåäœææã®æ¿ãåŠçããéã«äžå©ã«ãªãã§
ããããåãæ¬çºæã®ååŠçã«åŠçãããç¹ç¶ã¯
èåæ§ã®ç¹ç¶è£åŒ·éåäœæ¿ãäœãéã«æãé©ããŠ
ããã æ¬åºé¡ãšåãè²ãåã人ã«è²æž¡ãããç±³åœç¹èš±
第4110094å·ã«åŸã€ãŠäœãããåžè²©ã®ååŠçã«åŠ
çãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã補åã¯ãã¬ã©ã¹ç¹
ç¶è£åŒ·ã¢ã¯ãªãŒã«ããªãšã¹ãã«ã®æ¿ã補é ããã®
ã«çšããããŠããããã®æ¿è£œåã¯è¯å¥œãªèåæ§ã
æã€ããéææ§åã³ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã®æ¿¡ã
åã³ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã©ããã®ä»çã«ã€ããŠ
æ¬ é¥ãããããšãèŠåºãããŠãããååŠçã«åŠç
ãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã¯ãäžã€ä»¥äžã®æªãš
ã¹ãã«åã«ã«ããã·ã«åºåã³äžã€ä»¥äžã®ãšããã·
ãå«ããšããã·æš¹èãšç¡æ°Žãã¬ã€ã³é žéšåãšã¹ã
ã«ãšã®åå¿çæç©ã§ããïŒïŒ4â²ã€ãœããããªãã³
ãžããšããŒã« ãã¹ããšããŒã«ïŒ¡åãšããã·æš¹
èããããã¬ã³ã°ãªã³ãŒã«ã»é žåãšãã¬ã³è¡šé¢æŽ»
æ§å€ïŒïŒŠâ108è¡šé¢æŽ»æ§å€ïŒãæ°ŽçŽ åã³ãŒã³ãªã€ã«
ïŒãã¬ã³ãâPurecoâæ²¹ïŒããªãšãã¬ã³ ã°ãªã³
ãŒã«ä¹³åå€ïŒããªãã³ãâTritonââ100ïŒããª
ã¯ãã«ããšããã·ããªãšãã¬ã³ ãªãã·ãšã¿ããŒ
ã«ãããªããã« ãããªãã³ ãã€ã«ã 圢æå€ã
ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã· ã·ã©ã³ã
é ¢é žãã¬ã©ã¹ç¹ç¶æœ€æ»å€ãšããŠã®èèªé žã¢ãã³å¡©
ïŒãšã¡ãªãŒãâEmeryâ6717ïŒåã³çŽ6.5±0.2ïŒ ã®
ç¯å²ã®åºåœ¢ç©å«æéãäžããã®ã«å åãªæ°Žãããª
ãæ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæã€ãŠãããã
ã®ã¬ã©ã¹ç¹ç¶ã®çºã®åŠççšçµæç©ã¯ãã¬ã©ã¹ç¹ç¶
äžã®ååŠçåŠçç©ãšéåäœãããªãã¯ã¹ã®ååŠæ§
ãšã®çžäºäœçšã«ãã€ãŠç¹ç¶è£åŒ·éåäœæ¿ã®æçµç
æ§è³ªã«åœ±é¿ãäžããããšãæšæž¬ããããå€ãã®å®
éšãè¡ãªã€ãçµæããããæåã®å€ãã¯æå©ãªå¹
æãšæ害ãªå¹æãšã®äž¡æ¹ãäžããæ害ãªå¹æã®æ¹
ãæã æå©ãªå¹æããã®ãããšãçºèŠããããäŸ
ãã°ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã· ã·ã©
ã³æã¯ãã®å æ°Žå解çæç©ã¯è£åŒ·éåäœæ¿ã«è¯å¥œ
ãªèåæ§ãäžãããæ®å¿µãªããšã«ããã®ã·ã©ã³ã
ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®éé»æ°çºçã®äž»
ãªåå ã«ãªã€ãŠããããããäºã€ã®å¹æã¯éåžžã«
é¡èãªã®ã§ãèåæ§ã¯ç¹ç¶åã³ã¹ãã©ã³ãã«éé»
æ°çºçããšããªãããšãªãéæããããšãåºæ¥ãª
ããæŽã«ãµã€ãžã³ã°é åç©äžã®ããã€ãã®ä»ã®æ
åã¯ã¹ãã©ã³ãæ¿¡ãæ§ãäœäžããã¹ãã©ã€ãã®ç²
çæ§ãå¢ãã糞ã®çŽ°ææ§ãäœäžãç¹ç¶è£åŒ·æ¿ã®é
ææ§ãæžããããšãèŠåºã ãããŠããã ã¬ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã補é ãã
éã®è¯å¥œãªæ¿¡ãæ§ãæããè¯å¥œãªçŽ°ææ§ãæãã
çžäºã«ä»çããåŸåãäœäžããååŠçã«åŠçãã
ãã¬ã©ã¹ç¹ç¶ã補é ããããšã«äŒŽããäžã€è¯å¥œãª
èåæ§ãæã€ã®ã¿ãªããè¯å¥œãªéææ§ãæããã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã®ããã«ã補é
ããã®ã«äŒŽãããæ¡ä»¶åã³æ©èœã¯ãäºãã«å®³ãäž
ããªãããã«é¢ä¿ã¥ããããšãåºæ¥ãããšãçºèŠ
ããããåãæ¬çºæã®ã¬ã©ã¹ç¹ç¶ã®ä¹Ÿç¥æ®æž£ã«ç¹
å®ã®ææããªãããšãåžæã®ç¹æ§ãéæããã®ã«
å¿ èŠã§ããã æ¬çºæã®åŠçãããã¬ã©ã¹ç¹ç¶ãããããæ°Žæ§
åŠççšçµæç©äžã«ååšãããã€ã«ã 圢ææ§éåäœ
ã¯éåäœãããªãã¯ã¹ãšçžå®¹æ§ããããšå ±ã«ãã
ã«å¯æº¶æ§ã§ãããéåäœãããªãã¯ã¹ãšã¯ã¬ã©ã¹
ç¹ç¶ã«ãã€ãŠè£åŒ·ããããã®éåäœã§ãããçžå®¹
æ§åã³å¯æº¶æ§ã¯ãç¹ç¶ãšãããªãã¯ã¹éåäœãã
ãæ¥è§ŠãããæãåŠçãããã¬ã©ã¹ç¹ç¶ãçŽ10å
ããçããæéã§ãããªãã¯ã¹éåäœã«æ¿¡ããã
ããããªãã®ã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ãã€ã«ã 圢ææ§éåäœ
ã¯ãæ°Žåã³æº¶å€ã®èžçºæã¯ç¡¬åã§ãéãããç²ç
æ§ãæã€æŸãã åéæã®èã圢æããéåäœã§ã
ããéãããç²çæ§ãæã€ãã€ã«ã 圢ææ§éåäœ
ã¯æ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã«ãéãããç²ç
æ§ãäžãããã®ç¹æ§ã«å¯äžãããæ°Žæ§åŠççšçµæ
ç©ã®ä¹Ÿç¥æ®æž£ã®ãã€ã«ã ã¯ãšãã³ïŒEponïŒ828æš¹
èã®ãããªãšããã·éåäœã®ãã€ã«ã ãããç²ç
æ§ã®äœãç¹æ§ãæãããåããã€ã«ã ã¯éæ§ã§ã
ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã«æ®ãã©é£ç¶çãªãã€ã«ã ãäž
ããããã®ãããªãã€ã«ã ç¹æ§ãåŸãã®ã«ãåŠç
ãããã¬ã©ã¹ç¹ç¶ã®æ¿¡ãæ§ã倧ããæžå°ããã
ããæã¯åŠçãããã¬ã©ã¹ç¹ç¶ã§è£åŒ·ãããéå
äœããã«ã®éææ§ã«æ害ãªæªåœ±é¿ãäžãããããª
ããšãç¯ãããšã¯ãªãã ç²çæ§å¶çŽåã®ãã€ã«ã 圢ææ§éåäœãå«ãæ°Ž
æ§ååŠçåŠççšçµæç©ã«ãã€ãŠåœ¢æããããã€ã«
ã ã®æ§è³ªã¯ãã¬ã©ã¹ç¹ç¶ã1/4ã€ã³ãã®é·ãã«çŽ°
æãããæãçŽ30lbïŒft3ãã倧ããªèŠæãã®åµ©
å¯åºŠããããã«äžãããèŠæãã®åµ©å¯åºŠè©Šéšã¯åœ
æ¥è ã«ç¥ãããæ¹æ³ã«ãã€ãŠè¡ãªããããèŠæã
ã®åµ©å¯åºŠè©Šéšã®äŸã«ã¯æ¬¡ã®ãããªæ¹æ³ãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãã枬å®ããã
ééã®è£æããã¹ãã©ã³ãã250mlã¡ã¹ã·ãªã³ã
ãŒãžæ³šå ¥ããããã®ã¡ã¹ã·ãªã³ããŒãããªãã€ãª
å·ã¢ã³ãããªã¢ ã€ãŒã¹ãã»ã¡ã€ã³ã¹ããªãŒã
43543ã®ãªããã¢ã³ãã»ãã·ãŒã³ã»ã«ã³ãããŒã
ãâïŒåµ©å¯åºŠè©Šéšæ©ãšããŠå ¥æåºæ¥ããããªé«
å¯åºŠè©Šéšæ©ã«åãä»ãããè©Šéšæ©ã®èšç®æ©ãã50
ã¿ããã«èšå®ããæ©äŒãå§åããããæ©æ¢°ãæ¢ãŸ
ã€ãåŸãã¡ã¹ã·ãªã³ããŒäžã®ã¬ã©ã¹ç¹ç¶ã®äœç©ã
èªãã次ã«ã¿ããããåŸã®äœç©ã®èªã¿ã«ãã€ãŠçŽ°
æç³»ã®ééãå²ãããšã«ãã€ãŠèŠæãã®åµ©å¯åºŠã
èšç®ããããã®æ°å€ã«62.43ããããããšã«ãã€
ãŠ1bïŒft3ã§èŠæãã®é«å¯åºŠãåŸãããã ç±å¯å¡æ§ãã€ã«ã 圢ææ§éåäœã®æ°Žæ§ãšãã«ãž
ãšã³ã¯éåäœïŒã¢ã«åœããçŽ1.5ããå°ããèèª
æäºéçµåã®èèªæäžé£œåã®å¹³åå€ãæãã0.1
ãè¶ããªãèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ãæ
ããã®ã奜ãŸããããã®æ¯ã¯å®€æž©ã§ç©ºæ°æã¯ç空
äžã§ä¹Ÿç¥ãããã€ã«ã ã«ã€ããŠã®IRåžåçã«ã
ã€ãŠæ±ºå®ããããéåäœãïŒã¢ã«åœããå¹³å1.5
ã®èèªæäºéçµåãæããæããã®æ¯ã®å€ã¯0.1
ã§ãããæŽã«æ°Žæ§ååŠçåŠççšçµæç©ã¯ããããª
éã®çž®åæ¶æ©èªèµ·åå¿ç©åã³é䌞é·èªèµ·åå¿ç©ã
æãããæ¿¡ãã®é床ãé ãå Žåãç±å¯å¡æ§ãã€ã«
ã 圢ææ§éåäœã®æ°Žæ§ãšãã«ãžãšã³ã¯æ¯èŒçå€é
ã®èèªæäžé£œååã³0.1ãã倧ããªèèªæäžé£œå
察è³éŠæäžé£œåã®æ¯ãæããããšãã§ããããã
ã®éãšæ¯ãé«ããªãã«åŸã€ãŠæ¿¡ãã®é床ã¯æ¬¡ç¬¬ã«
é ããªãã ç²çæ§ãå¶çŽãããé©åœãªãã€ã«ã 圢ææ§éå
äœã®äŸã«ã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãããªã¢
ã«ãã¬ã³ããªãªãŒã«ã䜿çšããããšã«ãã€ãŠå€ã
ãä¹³åããããæã¯å éšçã«ä¹³åæ§ã®ããã¹ããš
ããŒã«ïŒ¡ãããã³ãžãªãŒã«æã¯ç¡æ°Žãã¬ã€ã³é žæ
ã¯ãã¬ã€ã³é žåã³ã¢ãžãã³é žãã圢æããããã®
ã®ãããªæ°Žæº¶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã¹ããšã
ãŒã«ããªãšã¹ãã«éåäœã§ãããããããã«éå®
ããããã®ã§ã¯ãªãã奜ãŸããã¯ããªãšã¹ãã«
ã¯ãçŽ30000ã45000ã®ç¯å²ã®ééå¹³åååéåã³
çŽïŒãçŽïŒã®å€åæ£æ§ææ°NwïŒMnãæããé
åäœã«ã€ããŠã¯ãšããã·ã«åã«ãã€ãŠå éšçã«ä¹³
åæ§ã«ãããã奜ãŸããã¯ããã®çš®ã®ãã¹ããšã
ãŒã«ããªãšã¹ãã«ç²çæ§å¶çŽéåäœã¯æ°Žæ§ååŠç
åŠççšçµæç©äžã®å¯äžã®ãã€ã«ã 圢ææ§éåäœã§
ããããã®ãããªéåäœã®äŸã¯ã€ã¿ãªãŒã³ã¢ã®ãµ
ãããïŒSavidïŒç€Ÿã«ãã€ãŠè£œé ãããåæšåã
ãªã¯ã·ã«ïŒNeoxiïŒ954ãšããŠåžè²©ãããŠããã¢
ã«ã³ãã·åãã¹ããšããŒã«ããªãšã¹ãã«æš¹èã®å
äžã®æ°Žæ§ãšãã«ãžãšã³ã§ãããããªã¯ã·ã«954æš¹
èã®æ§è³ªã¯æ¬¡ã®ãšããã§ããïŒå€èŠ³ãã«ã¯ç¶æ¶²
äœãåºåœ¢ç©å«æé46±ïŒïŒ ãPHïŒãïŒã23âã®ç²
床2000±500cpsãããã³ãžãªãŒã«åã¯ãã¬ã€ã³é ž
åã¯ç¡æ°Žãã¬ã€ã³é žã«ãã€ãŠãã®ãããªéåäœãž
å°å ¥ãããèèªæäžé£œåã¯éåäœïŒã¢ã«åœãã
1.5以äžã®äºéçµåã®èèªæäžé£œåãããããã¹
ãã§ãããèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã¯
0.1ããå°ããã奜ãŸããã¯çŽ0.07以äžã§ããã®
ãè¯ããèèªæäžé£œåã®éãšãã®æ¯ã¯ãéåã®å
éã®åœæ¥è ã«ç¥ãããŠããæ¹æ³ã«ãã€ãŠå¶åŸ¡ãã
ããšãã§ãããäŸãã°çš®ã ã®åéäœã®éãèèªæ
äžé£œåããã€åéäœãšããããªãåéäœãšã®æ¯ã§
調ç¯ããããšãã§ãããããªã¯ã·ã«954æš¹èãšã
ã«ãžãšã³ã®NMRæ²ç·ã¯ç¬¬ïŒå³ã«ç€ºãããŠããã
NMRã¯ãããªã¢ã³ïŒVarianïŒEMâ360 60MHz
éœåNMRåå èšã«ãããèµ°æ»æéïŒåãèµ°æ»å¹
10ppmãèµ°æ»ç«¯0ppmããã©ã¡ãã«ã·ã©ã³
ïŒTMSïŒïŒåºæºãè©Šæ枩床宀枩åã³DCCL3溶å€
ãçšããŠè¡ãªããããæ°Žæ§åŠççšçµæç©äžã®ãã€
ã«ã 圢ææ§éåäœã®éã¯æ°Žæ§åŠççšçµæç©ã®åºåœ¢
ç©ã®çŽïŒãçŽ20ééïŒ ã®ç¯å²ã«ããã åè¿°ã®ãšã¹ãã«åãšããã·æš¹èæã¯ãšããã·ã
åããªãšã¹ãã«æš¹èã補é ããéããã®å·¥çšã®åº
çºææã¯ãåœæ¥è ã«ç¥ãããæ¹æ³ã«ãã€ãŠéåäœ
ïŒã¢ã«åœãã1.5以äžå¥œãŸããã¯çŽ1.14ã1.4ã®äº
éçµåã®èèªæäžé£œåéããã¡ãèèªæäžé£œå察
è³éŠæäžé£œåã®æ¯ã0.1以äžã§ãããã€ã«ã 圢æ
æ§éåäœãçããããã«èª¿ç¯ããããäŸãã°åé
äœåæã¯ãäžé£œååæããã®æ¯ã0.1ãè¶ããŠå¢
倧ããããæã¯1.5ãã倧ããªäžé£œåéãçãã
çšå€§ããªçšåºŠãŸã§éåäœææã«å¯äžããããšããª
ããããªæ¯ã§çšããããšãã§ããã éåäœïŒã¢ã«åœããã®äžé£œåéã決å®ããæ¹æ³
ã¯ãåœæ¥è ã«ç¥ãããã©ããªæ¹æ³ã«ãã€ãŠãããª
ãããŠããããäŸãã°äºéçµåãæ°ŽçŽ åãããã¯
ããã²ã³åãããªã©ããæ°ŽçŽ æã¯ããã²ã³ãåã
蟌ãã éã枬å®ãããããªæ°å€ãã®æ¹¿åŒååŠçå
ææ³ãç¥ãããŠããã æ¯ã決å®ããæ¹æ³ã¯åœåéã§ç¥ãããã©ããªæ¹
æ³ã§ããããããã®æ¹æ³ã¯ããŒãªãšå€æèµ€å€åå
èšïŒFTIRïŒãçšããããšãå«ãã§ããã®ã奜ãŸ
ãããäžãããã也ç¥éåäœãã€ã«ã è©Šæã«ã€ã
ãŠ1647cm-1ã§ã®åžåãèšé²ãã1608cm-1ã§ã®åžå
ãèšé²ããã次ã«èèªæäžé£œå察è³éŠæäžé£œåã®
æ¯æã¯1647cm-1ã§ã®åžå察1608cm-1ã§ã®åžåã®æ¯
ã¯ã1647cm-1ã§ã®åžåã1608cm-1ã§ã®åžåã«ãã€
ãŠå²ãã0.1ããå°ããã奜ãŸããã¯0.07ããå°
ããæ¯ãäžããããšã«ãã€ãŠåŸãããããã®æ¹æ³
ã«ãã€ãŠã1647cm-1ã§åŸãããåžåãè³éŠææ§é
ã®å¹³é¢æ¯åäžã®ïŒ£ïŒïŒ£ã«äŒŽãããåžåã§å²ãããš
ã«ãã€ãŠåãã€ã«ã äžã®çžå¯Ÿçã¢ã«ã±ã³äžé£œå床
ã決å®ããããæå®ããæ³¢é·ã§ã®åžåå€ãåŸãé
ã«ããããã®å€ã¯ãã€ãŒãããå æ¿ãããã§ã¯ãª
ããFTIRããŒã¿ãŒäœçœ®ããçšããããã®ã奜ãŸ
ãããä»ã®æ¹æ³ããã®æ¯ã決å®ããããã«çšãã
å Žåæ¯ã®å€ã¯0.1以å ã«ãªãããšãããããæ¯ã«
察ãããã®ä»ã®å€ãFTIRæ³ã«ãã€ãŠåŸããã0.1
以äžã®å€ãšç䟡ã§ããéãæ¬çºæã®å©ç¹ãåŸãã
ãšãã§ããã æ°Žæ§ååŠçåŠççšçµæç©ã¯èèªæäžé£œåéã®ç¯
å²å€åã³èèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã«å¯Ÿã
ãå€ã®ç¯å²å€ã«ãªãä»ã®æåãå«ãã¹ãã§ãªãã
æ°Žæ§ååŠçåŠççµæç©äžã®åæ·»å ååç©ïŒã¢ã«åœ
ãã1.5ããå°ããäºéçµåã®èèªæäžé£œåãã
ã€ã¹ãã§ãããåååç©ã«å¯Ÿããåèšæ¯ã®0.1ã
è¶ããã¹ãã§ã¯ãªãã æŽã«æ°Žæ§ååŠçåŠççšçµæç©ã¯å€éã®å³ã¡æ°Žæ§
ååŠçåŠççšçµæç©ã®ïŒééïŒ ããå¿ãéåäœé
䌞é·èªèµ·åå¿ç©åã³çž®åæ¶æ©èªèµ·åå¿ç©ãå«ãã¹
ãã§ã¯ãªããæ°Žæ§ååŠçåŠççšçµæç©ã¯ãããã®
ç©è³ªãæ¬è³ªçã«ãµããŸãªãã®ã奜ãŸãããããã
ã®ç©è³ªã®äŸã«ã¯åŠççµæç©äžã«æ¢ã«ååšããææ
ãšãã®ãããªåå¿ãèªèµ·ãã觊åªåã³çž®ååå€ã
åããããšããã次ã®ãããªéšåãæããåå¿ç©
ãå«ãŸãããããããã«éå®ããããã®ã§ã¯ãª
ãïŒ ãããã®çš®é¡ã®åå¿ã¯æ¿¡ãæ§ãããããããã«
äœãæ¶æ©å¯åºŠãäžããããã«æå°ã«ä¿ãããã¹ã
ã§ããã ã¬ã©ã¹ç¹ç¶ã®ããã®æ°Žæ§ååŠçåŠççšçµæç©äž
ã«éåžžèŠåºã ããã飜ååã³éçž®ååå¿æ§ææ
ã¯ãæ¬çºæã®æ°Žæ§ååŠçåŠççšçµæç©äžã«ååšã
ãŠããŠãããããã®äŸã«ã¯çš®ã ã®ææ©ã·ã©ã³ã«ã
ããªã³ã°å€ãçš®ã ã®æœ€æ»å€åã³åŠçå©å€ãå«ãŸã
ããããããã«éå®ããããã®ã§ã¯ãªããã¬ã©ã¹
ç¹ç¶ã®ããã®æ°Žæ§ååŠçåŠççšçµæç©ã補é ãã
éã«ãããä»ã®ææãçšããå Žåãããéã®èèª
æäžé£œåã¯ããããæ°Žæ§ååŠçåŠççšçµæç©ã®ã
ãã®èèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã0.1ãã
倧ããããªãéã蚱容ããããšãã§ããã æ°Žæ§ååŠçåŠççšçµæç©ãé åããã®ã«çšãã
ããšãã§ããç¹å®ã®æåã®äŸã«ã¯ãååç©ïŒã¢ã«
åœããçŽ1.5ããå°ããäºéçµåã®èèªæäžé£œå
éããã¡ãèèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã
0.1以äžã®ãã®ãããããããã«ã¯ãšããã·ãå
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœãææ©ã·ã©ã³
ã«ãããªã³ã°å€ã最æ»å€åã³éé»é²æ¢å€åã³æ°Žã
å«ãŸããã äžçš®é¡ããå€ãã®ãã€ã«ã 圢ææ§éåäœãçšã
ãããæããšããã·å«æéåäœåã¯å ±éåäœãé
ç²çæ§éåäœãšå ±ã«çšããããšãåºæ¥ãããšãã
ã·å«æéåäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãš
ã®å¥ã ã®æ°Žæ§ãšãã«ãžãšã³ãäžç·ã«ããŠãåäžã®
ãšãã«ãžãšã³ã«ããŠããããæã¯ãšããã·å«æé
åäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãšãæ°Žæ§ãš
ãã«ãžãšã³äžã«å¯æº¶åãåæ£æã¯ä¹³åããŠãäžã€
ã®æ°Žæ§ãšãã«ãžãšã³ã調補ããŠãããããšããã·
å«æéåäœãšéç²çæ§ãã€ã«ã 圢ææ§éåäœãšã®
æ··åç©ãå«ãåäžã®ãšãã«ãžãšã³ã調補ããå Ž
åãéã€ãªã³æ§ãéœã€ãªã³æ§ãé°ã€ãªã³æ§ãæã¯
äž¡æ§ä¹³åå€ãçšããããšãåºæ¥ãããããæ··åã
ãéåäœã®ã€ãªã³ç¹æ§ã«åã€ãç¯å²ã®HLBãæ
ããéã€ãªã³æ§ä¹³åå€ãçšããã®ã奜ãŸãããäŸ
ãšããŠãšããã·ãïŒïœåœéåœããéåäœçŽ180ã
230ïœã®ç¯å²ã®ãšããã·åœéãæãããšããã·å«
æéåäœåã¯å ±éåäœãæããããããããã«é
å®ããããã®ã§ã¯ãªãããšããã·å«æéåäœåã¯
å ±éåäœã¯ã飜ååã¯äžé£œåããªãšã¹ãã«åã³ãš
ããã·ã®åŠãéåäœãããªãã¯ã¹ã«ãã€ãŠã¬ã©ã¹
ç¹ç¶ãè¿ éã«æ¿¡ããããã®è¯å¥œãªæ¿¡ãæ§ãæãã
åŠçãããã¬ã©ã¹ç¹ç¶ãçããã®ã«åœ¹ç«ã€ããšã
ãã·ãïŒïœåœéåœããéåäœ230ïœãã倧ããªãš
ããã·åœéãæãããšããã·éåäœã¯ãæã€ãã¬
ã©ã¹ç¹ç¶è£åŒ·éåäœããã«ãçããã§ãããããš
ããã·åœéãçŽ180ïœããå°ããå ŽåãåŠçãã
ãã¬ã©ã¹ç¹ç¶ã¯äœãã«ãç²çæ§ãããããšããã·
ïŒïœåœéãå«ããæš¹èïœééãšããŠå®çŸ©ããããš
ããã·åœéåã¯ããšããã·ãåœéã¯åœæ¥è ã«ç¥ã
ããæ¹æ³ã«ãã€ãŠæ±ºå®ããããšãåºæ¥ããäŸãšã
ãŠèµ€å€åå åã³ããªãžã³äžå¡©åããªãžããŠã ããš
ããã·éåäœãžæ·»å ããåŸãæ°Žé žåãããªãŠã ã«
ãã滎å®æ³ã®åŠã湿åŒåæãæãããããããã
ãã«éå®ããããã®ã§ã¯ãªãããšããã·æš¹èãçš
ããå Žåãæ°Žæ§åŠççšçµæç©äžã®ãã®éã¯ãæ°Žæ§
åŠççšçµæç©ã®åºåœ¢ç©ã®å°ééšåãã倧éšåãŸã§
ã«å€ããããšãåºæ¥ããçšããããšãåºæ¥ããšã
ãã·æš¹èã¯ãã¹ããšããŒã«ïŒ¡ãšããã¹ããšããŒã«
ã®ã°ãªã·ãžã«ãšãŒãã«ã圢æããããã®ãšãã
ããããªã³ã®åŠãå ±åéäœãšãã補é ããããšã
ãã·æš¹èã§ãã€ãŠãããïŒâã€ãœããããªãã³ã
ã¹ïŒïŒïŒïŒâãžããã¢ããšããŒã«ïŒããžãããã
ã·ãã³ãŒã³ãïŒïŒïŒïŒïŒïŒïŒïŒâããã©ïŒïœâã
ãããã·ããšãã«ïŒãšã¿ã³ãïŒïŒïŒâãã¿ã³ãžãª
ãŒã«ãã°ãªã»ããŒã«ãããªãªãã·ã¢ã«ãã¬ã³ïŒã°
ãªã³ãŒã«ïŒããªãã¬ã³äºéäœé žãïŒïŒïŒïŒïŒâã
ãªã¹ïŒïœâããããã·ããšãã«ïŒâãããã³çãš
ããããããªã³ãšã®åå¿ã§çšããããšã«ãã€ãŠåŸ
ããããšããã·æš¹èãçšããããšãã§ãããåè
èªæã°ãªã·ãžã«ãšãŒãã«ãã補é ããããšããã·
æš¹èãçšããããšãã§ãããåã¢ããšããã·åå
ç©ããèªäœæã¯ä»ã®ãšããã·çæååç©ãšã®åå¿
ã«ãã€ãŠè£œé ããããšããã·æš¹èãçšããããšã
ã§ããäŸãã°äžé£œåã¢ããšããã·ååç©ãäžé£œå
ã«ãã€ãŠãã¢ããªããŒåããããªïŒã¢ãªã« ã°ãª
ã·ãžã«ãšãŒãã«ïŒã®ãããªããªãšããã·éåäœã
補é ããŠããããç¹ã«é©ãããšããã·æš¹èã¯ïŒã¢
ã«ã®ããšããŒã«ãšãïŒã¢ã«ã®ãã«ã ã¢ã«ãããã
ãããããã³ãã¬ãŸã«ã·ããŒã«æã¯å€äŸ¡ã¢ã«ã³ãŒ
ã«äŸãã°ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ããœã«ãããŒ
ã«ãã°ãªã»ããŒã«çãšã®é žçž®åã«ãã€ãŠåŸããã
ãã¹ïŒïŒâããããã·ããšããŒã«ïŒâïŒïŒïŒãã
ãã³ããã¹ïŒããããã·ããšãã«ïŒã¡ã¿ã³ã®åŠã
å€äŸ¡ããšããŒã«ãšãååŠéè«çã«éå°éã®ãšãã¯
ãããããªã³ã®åŠããšããããããªã³ãšã®åå¿ã«
ãã€ãŠåŸãããããšããŒã«ç³»ãšããã·ã§ããããš
ããããããªã³ãå€äŸ¡ååç©ã®ãããã®éšåãå€
ãäžã€ïŒåã¯ïŒåå¿æ¡ä»¶ãå€ããããšã«ããã液
äœããåºäœã®ç¯å²ã«å ¥ãäœããäžçšåºŠåã¯é«ãå
åéã®ååç©ã補é ããããæçšãªåžè²©ã®ãšãã
ã·æš¹èã«ã¯åæšåãšãã³ïŒEpomïŒ828ã§ã·ãš
ã«ã»ã±ãã«ã«ã»ã³ãŒãã¬ãŒã·ãšã³ããåŸããããš
ããã·æš¹èåã³åæšåã¢ã©ã«ãã€ãïŒAralditeïŒ
ã§ããã»ã¬ã€ã®ãŒç€ŸããåŸããããšããã·æš¹èå
ã³åæšåD.E.R.åã¯D.E.N.ã§ããŠã»ã±ãã«ã«ã»
ã«ã³ãããŒããåŸãããæš¹èåã³ã»ã©ããŒãºã»ã
ãªããŒã»ã¹ãã·ã€ã«ãã€ãŒãºã»ã«ã³ãããŒããåŸ
ããããšããŒã¬ããºïŒEpiâRezïŒæš¹èãå«ãŸã
ããçšããããšãã§ããé©åœãªãšããã·å«æå ±é
åäœã¯åæšå1971æš¹èã§ãã·ãšãã«ã»ã¹ã¿ãŒã瀟
ããåŸããããšããã·ãåããªããã«ã¢ã»ããŒã
å ±éåäœã§ããã 氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ãšããã·å«æéåäœ
ã¯åœæ¥è ã«ç¥ãããé©åœãªè¡šé¢æŽ»æ§å€ãçšããŠã€
ãããããšãã«ãžãšã³å³ã¡åæ£ç©ãå«ãããšãã§
ãããäŸãã°ãé žåãããã¬ã³ãšãããã¬ã³ã°ãª
ã³ãŒã«ãšã®çž®åã«ãã€ãŠåœ¢æãããçæ°Žæ§å¡©åºãš
é žåãšãã¬ã³ãšã®çž®åç©ã§ããäžçš®ä»¥äžã®è¡šé¢æŽ»
æ§å€ãçšããããšãåºæ¥ããäŸãã°ãBASFãŠã€
ã³ãããïŒWyandotteïŒã€ã³ãã¹ããªã¢ã«ã»ã±
ãã«ã«ã»ã°ã«ãŒãã«ãã€ãŠè£œé ããããã«ããã
ã¯ïŒPluronicïŒïŒŠâ108è¡šé¢æŽ»æ§å€ãé©åœãªãšã
ã«ãžãšã³æã¯åæ£ç©ã圢æããã®ã«çšããããšã
åºæ¥ãã åããšããã·å«æéåäœåã¯éåäœãç²çæ§ã
ã€ã«ã 圢ææ§éåäœã®éããã溶解床ã«é¢é£ããŠ
çšããå Žåããšããã·å«æéåäœäžã®ç²çæ§å¶çŽ
ãã€ã«ã 圢ææ§éåäœã¯ãããäºçš®é¡ã®éåäœå
ã¯éåäœãšãã«ãžãšã³ã®çžå®¹æ§ãå©é·ããããã®
çžå®¹æ§ã¯åã«ãšããã·å«æéåäœã®ä¹Ÿç¥æ®æž£ãæ
ããã¬ã©ã¹ç¹ç¶ã®ç²çæ§ããããã¬ã©ã¹ç¹ç¶äžã®
æ°Žæ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã®ãã€ã«ã ã®ç²çæ§
ãæžå°ãããã®ã«åœ¹ç«ã€ãç²çæ§ã®æžå°ã¯çŽ°æã
ãåŠçãããã¬ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã©ããã®æ¥
çã«ããçžäºæ¥çã®æžå°ã«ãªã€ãŠçŸããã 氎溶æ§ãåæ£æ§æã¯ä¹³åæ§ã®ãã€ã«ã 圢ææ§
éãåäœã®ä»ã«ãæ°Žæ§åŠççšçµæç©ã¯äžçš®ä»¥äžã®
ã¢ã¯ãªããã·å«ææã¯ã¡ã¿ã¯ãªããã·å«æææ©å®
èœã«ãããªã³ã°å€ãå«æããŠãããã«ãããªã³ã°
å€ã¯ãææ©å®èœã·ã©ã³ã«ãããªã³ã°å€æã¯ææ©å®
èœãŠãšã«ããŒïŒWernerïŒååç©çãååã®ææ©
å®èœéšåã«æ¬¡ã®åŠãéšåïŒ åã³æ¬¡ã®åŠãã¡ã¿ã¯ãªããã·åã³çœ®æã¢ã¯ãªãã
ã·æ®åºïŒ ãåŒäžãã¯ïŒåãŸã§ã®ççŽ ååãæããäœçŽã¢
ã«ãã«åºã§ããã ãæãããã®ã§ãã€ãŠè¯ãããã®ãããªã«ãããª
ã³ã°å€ã®äŸã«ã¯ã¡ã¿ã¯ãªããã·ã¢ã«ãã«ããªã¢ã«
ã³ãã·ã·ã©ã³ãããããããã«éå®ããããã®ã§
ã¯ãªããã¢ã«ã³ãã·åºãšã¢ã«ãã«åºã¯ã¢ã«ãã«åº
ã«ã€ããŠïŒãïŒåã®ççŽ ååãæããã奜ãŸãã
ã¯ãã¡ã¿ã¯ãªããã·ã¢ã«ãã«ããªã¢ã«ã³ãã·ã·ã©
ã³ã¯ã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·ã©ã³
ã§ãããã¡ã¿ã¯ãªããã·ãããã«ããªã¡ããã·ã·
ã©ã³ã®ã¡ããã·åºã¯ããã®ã·ã©ã³ãæ°Žæ§åŠççšçµ
æç©ã«é åãããåã«å æ°Žå解ãããªããã°ãªã
ãªããããã¯é ¢é žã®ãããªæ¬è³ªçãªçåæ°ŽçŽ ææ©
é žãã«ãããªã³ã°å€ã«æ·»å ãäžçš®ä»¥äžã®SiOCH3
åºãå æ°Žå解ãããŠã¡ã¿ããŒã«åã³äžçš®ä»¥äžã®
SiOHåºã圢æããã®ã«å åãªæéåã³å åãªæž©
床ã§æªäŒŽããããšã«ãã€ãŠéæããããé ¢é žã«å
åãªæŽ»æ§åºŠãäžããã®ã«å åãªæ°Žãå æ°Žå解ã§çš
ãããæ°Žæ§åŠççµæç©ã«çšããããã·ã©ã³ã«ãã
ãªã³ã°å€ã®éã¯ãæ°Žæ§åŠççšçµæç©ã®åºåœ¢ç©ã®çŽ
0.1ãçŽ10ééïŒ ã®ç¯å²ã®ã«ãããªã³ã°ã«æå¹ãª
éã§ããããå€ãæ¹ã®éã§å¶åŸ¡ããã湿床æ¡ä»¶ã§
éåžžçšããããã æ°Žæ§ååŠçåŠççšçµæç©ã®åèšæåã®ä»ã«ã最
æ»ã«æå¹ãªéã®ã¬ã©ã¹ç¹ç¶éœã€ãªã³æœ€æ»å€ãååš
ãããããã最æ»å€ã¯ãã¬ã©ã¹ç¹ç¶ãåã³ã¬ã©ã¹
ç¹ç¶ãã¹ãã©ã³ãã®éããæã«æœ€æ»æ§ãäžããæ°Ž
溶æ§éœã€ãªã³ç©è³ªã§ãã最æ»å€ã§ããããã®ã«ã¯
é žå¯æº¶åãããèèªé žã¢ããäŸãã°ã·ãã¢ãªã³ã¢
ãããå«ãŸãããèèªé žã¢ããã¯é£œååã³äžé£œå
ã®äž¡æ¹ã§ãããé žåºã¯ïŒã24åã®ççŽ ååãå«
ããåãäœååéã®äžé£œåèèªé žã¢ããã®ç¡æ°Žé ž
å¯æº¶åéåäœãå«ãŸãããåéç°ãçãããããª
æ¡ä»¶ã§èèªé žãšããªã¢ã«ãã¬ã³ããªã¢ãã³ãšãå
å¿ãããããšã«ãã€ãŠåœ¢æãããã¢ã«ãã«ã€ãã
ãŸãªã³ãå«ãŸãããç¹ã«é©ããéœã€ãªã³æœ€æ»å€
ã¯ã奜ãŸããã¯å°ãªããšãäžçš®é¡ããã©ã«ãŽã³é ž
ã§ããèèªé žãçšããŠè£œé ãããçŽ200ã800ã®ã¢
ãã³äŸ¡ãæããããªã¢ããã¢ããææã§ãããå
ãã®ææã¯é ¢é žã§æŽã«å¯æº¶åããããšãåºæ¥ãã
ãã®ãããªææã®äŸã¯åæšåãšããªãŒãªãŠãŒã
ïŒEmerylubeïŒ6717ã§ãšããªãŒã»ã€ã³ãã¹ããªãŒ
ãºç€Ÿããåžè²©ãããŠããããã©ã«ãŽã³é žã®ãããª
èèªé žã§éšåçã«ã¢ããåãããããªã¢ã«ãã¬ã³
ã€ãã³ã§ããããã®ææã¯æµåç¹55ãå¯åºŠ0.99
KgïŒïŒ8.3ãã³ãïŒã¬ãã³ïŒãã¬ãŒããã«ã©ãŒ
10ã25âããäœãæãç¹ãåŒç«282âïŒ540ãïŒã
æããç²çš æ§ã®æ¶²äœã§ããã氎溶æ§ã§ãé±æ²¹ã«å¯Ÿ
ãåæ£æ§ã§ãããä»ã®é©åœãªææã¯ãåæšåã¯ã©
ãŸãŒã«ïŒCirrasolïŒ185AãšããŠè£œé ãããŠããã
宀枩ã§ç²çš ãªæ¶²äœã®æ·±ãèµ€å³ããã€ããã¯ãè²ã
ããç¡æ°Žã®ææã§ãããããã¯æ°Žã«å¯Ÿãåæ£æ§
ã§ãïŒïŒ 溶液ã¯çŽ8.9ãçŽ9.4ã®PHãæãããéœã€
ãªã³æ§ã§æ°Žæº¶æ§ã®ã¬ã©ã¹ç¹ç¶æœ€æ»å€ãåå¿æ§ã®ã
ãçŽ åºãå«ãå Žåããã®æœ€æ»å€ã®æå¹ãªéã¯ãã¬
ã©ã¹ç¹ç¶æœ€æ»å€ã®çªçŽ å«æåºã«ãã€ãŠããããã
ãããšããããšããã·å«æéåäœã®ã©ããªæ¶æ©ã
ãå®è³ªçã«é²ãããã«éå®ãããã¹ãã§ãããäž
è¬ã«éœã€ãªã³æ§ã¬ã©ã¹ç¹ç¶æœ€æ»å€ã®æå¹ãªéã¯æ°Ž
æ§ååŠçåŠççšçµæç©ã®çŽ0.05ã0.5ééïŒ ã®ç¯
å²ã«ããã éåäœãããªãã¯ã¹ãè£åŒ·ããããã«æãŸãã
æ§è³ªãæããååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ãæ
ããä»ã«ãåŠçãããã¬ã©ã¹ç¹ç¶ã¯è£åŒ·ãããç
æç©ãžå å·¥åºæ¥ããã®ã§ãªããã°ãªããªããè£åŒ·
ããããã©ã¹ããã¯ããã«ã¯çŽ°æãããã¹ãã©ã³
ãè£åŒ·å€ãšäžç·ã«è£œé ããããã¬ã©ã¹ç¹ç¶ã¯æå
é£ç¶çã«ç¹ç¶ãšããŠè£œé ããããã®åŸã§ãããã¯
现æããããç¹ç¶åã¯ã¹ãã©ã³ãåã¯ããŒãã³ã°
ã也ç¥é£ç¶çææãã现æãããå Žåãå€ãã®é
é»ç现æçã®çµ¡ã¿ã¯è£åŒ·ããã«ã補é ããããã®
ã¬ã©ã¹ç¹ç¶ã®å å·¥æ§ãã ãã«ããããšãããã现
æçã®çµ¡ã¿ãæžå°ãããã®ã«åœ¹ç«ã€éé»ç絡ã¿ã
解決ããããã«ãæ°Žæ§ååŠçåŠççšçµæç©ã¯ã¢ã«
ã³ãã·éšåãæã€éœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ã
ãŠã å¡©ã§ããéé»é²æ¢å€ãæãããæ°Žæ§ååŠçåŠ
ççšçµæç©ã«éé»é²æ¢å€ãé åããèšå€§ãªå®éšã
è¡ã€ãåŸãç¡æ©éé»é²æ¢å€ãååšããªããšéœã€ãª
ã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ããŠã å¡©é
é»é²æ¢å€ã¯ç¹ç¶è£åŒ·éåäœãããªãã¯ã¹ã®è¯å¥œãª
èåæ§ãããããããšãçºèŠããããäžè¬ã«éœã€
ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ããŠã å¡©
éé»é²æ¢å€ã¯ãåŒïŒ ãåŒäžãR1ãR2ãR3åã³R4ã®äžã€ä»¥äžã®éšåã
åããåã¯ç°ãªãã¢ã«ã³ãã·éšåã§ãã¡ãã¬ã³åº
ãæããåã¯ã¡ãã¬ã³åºãæããã ïŒâRâ³OâïŒbRâ²âïŒo ïŒRâ²ã¯ã¡ãã¬ã³åºïŒCH2ïŒã§ãïœã¯ïŒã10åã¯ã
ã以äžã®æŽæ°ã§ãããRâ³ã¯ãšãã¬ã³åºåã¯ãã
ãã¬ã³åºåã¯ãããã®æ··åç©ã§ãããïœã¯ïŒã10
åã¯ãã以äžã®æŽæ°ã§ãããã¯æ°ŽçŽ åã¯ïŒã
10åã®ççŽ ååãæããäœçŽã¢ã«ããŒã«åºã§ã
ãïŒã®åŠãæ«ç«¯ã¢ã«ã³ãŒã«æ§åºãæããã¢ã«ã³ã
ã·éšåã§ããããšãã§ããã ãæããã åºR1ãR2ãR3åã³R4ã®åã€ããå°ãªããã®ã
ã¢ã«ã³ãã·åºã§ãããæ®ãã®éã¢ã«ã³ãã·åºR1ã
R2ãR3åã³R4ã¯ïŒã30åã®ççŽ ååãæããã¢
ã«ãã«åºã§ããã X-ã¯ã«ã«ããã·ã¬ãŒããã¹ã«ãããŒãããµã«
ããšãŒãããã¹ããšãŒãåã³ããã²ã³åç©ã€ãªã³
ã®ãããªã©ããªææ©åã¯ç¡æ©ã®é°ã€ãªã³ã§ãã
ãããã®éé»é²æ¢å€ã¯ã¢ã«ã³ãã·éšåãæã€ç¬¬å
çŽã¢ã³ã¢ããŠã å¡©ã補é ããããã®ãã®ååŠçå
éã§ç¥ãããŠããã©ããªæ¹æ³ã«ãã€ãŠè£œé ããŠã
è¯ãã éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ã
ãŠã å¡©éé»é²æ¢å€ã¯ã ïŒR5ïŒyâN+âïŒR6ïŒzX- ãåŒäžãR5㯠ïŒâRâ³OâïŒbRâ²aâ ïŒRâ²ã¯ã¡ãã¬ã³ïŒCH2ïŒã§ãããïœã¯ïŒãïŒã®æŽ
æ°ã§ãããRâ³ã¯ãšãã¬ã³ã§ïœã¯ïŒãïŒã®æŽæ°ã§
ãããã¯æ°ŽçŽ åã¯ã¡ãã«åºã§ããïŒã®åŠãå
ãã¢ã«ã³ãã·éšåã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§
ãããïœïŒïŒã®æãïœïŒïŒã§ãããïœïŒïŒã®æã
ïœïŒïŒã§ãããR6ã¯ïŒã25åã®ççŽ ååãæã
ãé·éã¢ã«ãã«ã§ãããX-ã¯Cl-åã¯Br-ã§ã
ããã®ããšãåŒãæããã®ã奜ãŸããããã®ææ
ã®é žäŸ¡ã¯å°ãªããšã10ã§ããã®ã奜ãŸããã éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ã
ãŠã å¡©éé»é²æ¢å€ã®äŸã«ã¯ãã€ã¿ãªãŒã³ã¢ã®ãµã
ããS.p.A.ããå ¥æåºæ¥ãåæšåããªã¯ã·ã«
AO5620ãšããŠåžè²©ãããŠããææãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãããã®ææã¯
第ïŒå³ã«ç€ºãNMRæ²ç·ãæããååé1010Mn
åã³1140Mwãé žäŸ¡10ã20mgrKOHïŒïœåã³ïŒïŒ
氎溶液ã®PHãïŒãïŒã§ããã第ïŒå³ã®IRã¯ããª
ã¯ã·ã«AO5620ææã«ãã也ç¥ãã€ã«ã æåç©ã
ãåŸããããã®ã§ããã 第ïŒå³ã®NMRã¯ããªã¢ã³ïŒ¥â360 60MHzéœå
NMRåå åšã«ãã€ãŠè¡ãªããããã®å Žåã¹ãã¯
ãã«æ¯å¹ ã¯80ããã€ã«ã¿ãŒã¯0.1ç§ãRFé»åã¯
0.05mgãèµ°æ»æéã¯ïŒåãèµ°æ»å¹ ã¯10ppmã§ãèµ°
æ»ç«¯ã¯Oppmãæ žã¯æ°ŽçŽ ãåºæºã¯ããã©ã¡ãã«
ã·ã©ã³ïŒTMSïŒã宀å è©Šæ枩床åã³DCCl3溶åªã
çšããã éé»é²æ¢å€ã®éã¯ç¹ç¶çžäºã®ä»çãããããã
ãšãªããèåæ§ã«æ害ãªåœ±é¿ãäžããããšããªã
现æç©ã絡ã¿ãæžå°ããã硬ååã³éé»é²æ¢ç¡¬å
ã®äž¡æ¹ãäžããã®ã«å åãªéã§ãããææ©ç¬¬åçŽ
ã¢ã³ã¢ããŠã éé»é²æ¢å€ã®éã¯ãäžè¬ã«æ°Žæ§åŠç
çšçµæç©ã®å°ãªããšãçŽ0.05ééïŒ ã®éã§ããã
ææ©ç¬¬åçŽã¢ã³ã¢ããŠã éé»é²æ¢å€ã®éãäœãã«
ãå€ããšçŽ°æçã®çµ¡ã¿ãå¢å ãããããšã«ãªãã
åŸã€ãŠæå©ã§ããããã¯ãããæ害ã«ãªããäžè¬
ã«ææ©éé»é²æ¢å€ã®éã¯ããããªåéæã®ããã«
ã補é ããããã®æ°Žæ§ååŠçåŠççšçµæç©ã®çŽ
0.05ãçŽ0.4ã奜ãŸããã¯çŽ0.05ãçŽ0.15ééïŒ ã®
ç¯å²ã«ãããå ãŠããããããã«ã補é ããå Ž
åãææ©éé»é²æ¢å€ã®éã¯0.3åã¯0.4ééïŒ ã®é
ãŸã§ã®ç¯å²ã«ããããšãåºæ¥ãã æ°Žæ§ååŠçåŠççšçµæç©ã¯æ¬è³ªçã«ã©ããªç¡æ©
éé»é²æ¢å€ãå«ãŸãªãããã®ãããªç¡æ©éé»é²æ¢
å€ã®äŸã«ã¯å¡©åã¯ãã ãã¢ã«ã«ãªéå±åã³ã¢ã«ã«
ãªåé¡éå±å¡©åç©ãäŸãã°å¡©åãªããŠã åã³å¡©å
ãã°ãã·ãŠã ã§ãèåæ§ã«æªåœ±é¿ãäžããªããã®
ããããããããã«éå®ããããã®ã§ã¯ãªãã ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®çŽ°ææ§ãéé»
æ°çºçãäœäžããããæ害ãªéã®çŽ°æç©ã®çµ¡ã¿ã
äžããçµæã«ãªãå Žåãæ°Žæ§ååŠçåŠççšçµæç©
ã¯ã¹ãã©ã³ã硬åå€ããå«ãã¹ãã§ããããã®æ
æã¯ç¹ç¶åå¿ã®ä»çããããããæã¯ããã«ã®é
ææ§ãäœäžãããããšãªã絡ã¿ãæžå°ãã¹ãã§ã
ãããã®ãããªã¹ãã©ã³ã硬åå€ã®æå¹ãªéã¯ã¹
ãã©ã³ãã®äžäœæ§ãå¢å ã现æç©ã®çµ¡ã¿ãæžå°ã
ããã¹ãã©ã³ãã®äžäœæ§ã¯äœãã«ã倧ããªçšåºŠãŸ
ã§å¢å ãããã¹ãã§ã¯ãªããäœæ ãªãããã¯ã¹ã
ã©ã³ãåå¿ã®ä»çãå¢å ããçµæã«ãªãããšãã
ãããã§ãããé©åœãªã¹ãã©ã³ã硬åå€ã®äŸã¯ã¡
ã©ãã³ãã«ã ã¢ã«ãããããããµãã¹ïŒã¡ããªãŒ
ã«å«æçž®åç©ãåéäœãäºéäœãäžéäœåã³ãã
ããé«åºŠã®ãªãªãŽããŒãã®åŠãã¢ã«ãããçž®åé
åäœãå«ãããèªäœæ¶æ©å¯èœãªææã§ããããã
ãã«éããããã®ã§ã¯ãªãããã®å ŽåããšããŒã«
åã¯ã¬ãŸã«ã·ããŒã«ã«ã€ããŠã¯ãé åç©ã¯ã¯ãªãŸ
ãŒã«åã³ãã®ç°æ§äœã®æ··åç©ããã·ã¬ãŒã«æã¯ã
ã®ç°æ§äœã®æ··åç©ããšããŒã«ã®åæäœã®æ··åç©ã
å«ã¿ãã¬ãŸã«ã·ããŒã«ãã¯ã¬ãŸã«ã·ããŒã«åã³ã¡
ã¿ãã·ãã«ã·ããŒã«ã®åŠãäºäŸ¡ã®ããšããŒã«ãçš
ããããšãåºæ¥ããã¢ã«ãããã«ã¯ãã«ã ã¢ã«ã
ããã®ä»£ããã«çšããããšãåºæ¥ãã©ããªã¡ãã¬
ã³äŸäžäœãå«ãŸããäŸãã°ãã©ãã«ã ã¢ã«ãã
ãããããµã¡ãã¬ã³ããã©ãã³ãé žã¢ã«ãããã
ãã«ãã©ãŒã«åã³ãããã®æ··åç©ãå«ãŸãããã¢
ã«ãããæã¯ã¡ãããŒã«çž®åç©ã¯é žåã¯å¡©åºè§Šåª
ãšå ±ã«çšããããšãåºæ¥ããäžçš®ä»¥äžã®ã¡ã©ãã³
ãã«ã ã¢ã«ãããæš¹èãå«ãã®ã奜ãŸãããäœæ
ãªããããã¯æ¶æ©ãããããçµæç©äžã®ä»ã®éå
äœãšçžå®¹æ§ãæããããã§ãããç¹ã«é©ããã¡ã©
ãã³ãã«ã ã¢ã«ãããæš¹èã¯ãåæšåã¬ãžã¡ã³
ïŒResimeneïŒ841ãšããŠã¢ã³ãµã³ãã»ã«ã³ãããŒ
ããå ¥æåºæ¥ãæ°Žæ§ã¡ã©ãã³ãã«ã ã¢ã«ãããæš¹
èã§ãããããã¯éé¢ã®ãã«ã ã¢ã«ããããïŒïŒ
ããå°ãªããã¡ã¿ããŒã«ã¯ïŒïŒ ããå°ãªãã98.9
ïŒ210ãïŒã®æ²žç¹ãæãããã¬ãžã¡ã³841ã¯ã¡ã¿ã
ãŒã«ã«å¯Ÿã95ãæ°Žã«å¯Ÿã17.5ã®èžæ°å§ãã¡ã¿ããŒ
ã«ã«å¯Ÿã1.11ãæ°Žã«å¯Ÿã0.64ã®èžæ°å¯åºŠãç¡è²ã§
éæãªæµåæ§ã®æ¶²äœå€èŠ³ã25âïŒ77ãïŒã§1.25ã®
æ¯éåã³29äœç©ïŒ ã®æ®çºæ§ãæãããçšããããš
ã®åºæ¥ãä»ã®ã¹ãã©ã³ã硬åå€ã¯ããªïŒããã«ã
ããªãã³ïŒã§ãããã¹ãã©ã³ã硬åå€ã®éã¯æ°Žæ§
åŠççšçµæç©ã®å°ãªããšãçŽ0.1ééïŒ ã®ç¯å²ã«
ããã¬ãžã¡ã³841ææãšåæ§ãªã¡ã©ãã³ãã«ã ã¢
ã«ãããæš¹èã®éã«åçãªéã§ãããäžå±€å€ãã®
éãçšããŠãè¯ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
0.5ééïŒ ãè¶ããéã¯äœãä»å çãªå©ç¹ãäžã
ãªãã奜ãŸããã¯ãã®éã¯æ°Žæ§ååŠçåŠççšçµæ
ç©ã®çŽ0.1ãçŽ0.15ééïŒ ã®ç¯å²ã«ãããçšãã
ããããªïŒããã«ãããªãã³ïŒã®éã¯æ°Žæ§åŠççš
çµæç©ã®0.5ééïŒ ãè¶ããã¹ãã§ã¯ãªããäœæ
ãªãããªïŒããã«ãããªãã³ïŒã¯åŠçãããã¬ã©
ã¹ç¹ç¶ã®ã¬ãç¹æ§ãäœäžããããšããããåŠçã
ããã¬ã©ã¹ç¹ç¶ã«æãŸãããªãçšåºŠã®ç¡¬åºŠãäžã
ãããšãããããã§ããã ä»ã®ä»å çãªãã€ã«ã 圢ææ§éåäœãã«ãããª
ã³ã°å€ã最æ»å€ãåŠçå©å€åã³æ¿åå€ãæ¬çºæã®
æ°Žæ§ååŠçåŠççšçµæç©ã«çšããŠãããããæ°Žæ§
åŠççšçµæç©äžã®å¯äžã®æ©èœããšããã·å«æéå
äœåã¯å ±éåäœãæ¶æ©ããããšã«ãããããªãšã
ãã·ç¡¬åå€ã¯æ¬è³ªçã«å«ãŸãªããæŽã«æ°Žæ§ååŠç
åŠççšçµæç©ã¯ãç²çæ§å¶çŽãã€ã«ã 圢ææ§éå
äœäžãæã¯ãšããã·å«æéåäœåã¯å ±éåäœãšç²
çæ§å¶çŽãã€ã«ã 圢ææ§éåäœãšã®æ··åç©äžã§æº¶
解ãããããšãåºæ¥ãªããããªææã¯æ¬è³ªçã«å«
ãŸãªãããã®ãããªææã¯æ°ŽçŽ åãããçåæ°ŽçŽ
æ²¹ã®åŠãéã€ãªã³æ§ã§æ°Žäžæº¶æ§ã®çåæ°ŽçŽ ã¬ã©ã¹
ç¹ç¶æœ€æ»å€ã§ãããå žåçã«ã¯æ°Žäžæº¶æ§æœ€æ»å€ã¯
ã°ãªã»ããŒã«ã®æ°ŽçŽ åãããåã¯é£œåèèªé žãšã¹
ãã«ã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã¯ãããã®
çš®é¡ã®ææãæ¬è³ªçã«å«ãŸãªãã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãã¬ã©ã¹ç¹ç¶ã圢æ
ãããéã«æ°Žæ§ååŠçåŠççšçµæç©ã§ããããåŠ
çããããšãåºæ¥ããããªå åãªå šåºåœ¢ç©éãã
ã®çµæç©ã«äžããã®ã«å åãªéã®æ°Žãæãããäž
è¬ã«æ°Žæ§çµæç©ã®å šåºåœ¢ç©ã¯çŽïŒãçŽ30ééïŒ ã
奜ãŸããã¯çŽïŒãçŽ10ééïŒ ã®ç¯å²ã«ãããã©ã®
å Žåã§ããæ°Žæ§ååŠçåŠççšçµæç©ã®ããã®åºåœ¢
ç©æåã®éã¯ã溶液ã®ç²åºŠã20âã§çŽ100ã»ã³ã
ãã€ãºãã倧ãããããããªéãè¶ããã¹ãã§ã¯
ãªãã20âã§100ã»ã³ããã€ãºãã倧ããªç²åºŠã
æããæ°Žæ§æº¶æ¶²ã¯ã¬ã©ã¹ç¹ç¶åœ¢æäžãããç¹ç¶ã
ç Žæããããšãªãã¬ã©ã¹ç¹ç¶ã«é©çšããããšãé
åžžã«å°é£ã§ããããã®åŠçå€ã®ç²åºŠã¯æè¯ã®çµæ
ãåŸãããã«ã¯20âã§ïŒã20ã»ã³ããã€ãºã§ãã
ã®ã奜ãŸããããªããœããããŒæ§ã²ã«åå€åã¯çº
泡å€ãæããååŠçåŠççšçµæç©ã¯ã¬ã©ã¹ç¹ç¶ã
åŠçããããã«ãçšããããã²ã«åã³çºæ³¡ç©ã®ã
ãã®æ¢ç¥ã®ç²åºŠãæããããšãåºæ¥ããæ°Žæ§ååŠ
çåŠççšçµæç©ã®PHã¯çŽïŒããäœããçµæç©ã®å®
å®æ§ãç¶æããããã«ã¯çŽ4.8ãçŽ5.2ã®ç¯å²ã«ã
ãã®ã奜ãŸãããæ°Žæ§ååŠçåŠççšçµæç©ã¯æå
ãåæã«åã¯é 次äžç·ã«ããããšã«ããäœãããš
ãåºæ¥ãã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãââã¬ã©ã¹âã
â621âã¬ã©ã¹âåã³ãããã®ç¡ŒçŽ åã³ïŒåã¯ïŒãµ
ã€çŽ å«æéã®äœãåã¯ããããå«ãŸãªãèªå°äœã®
åŠãç¹ç¶åå¯èœãªã¬ã©ã¹ææåã³ââã¬ã©ã¹âã
ââã¬ã©ã¹âåã³ââã¬ã©ã¹âãšããŠç¥ãã
ãŠããã¬ã©ã¹ç¹ç¶çµæç©ã«é©çšããããšãåºæ¥
ããéææã¯åéæã®éåäœããã«ã補é ããã®
ã«çšããååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã補é ã
ãæãç¹ç¶åå¯èœãªã¬ã©ã¹çµæç©ã¯ãããããã¢
ã¯ãªã«ããªãšã¹ãã«ãããªãã¯ã¹æš¹èãè£åŒ·ãã
ã®ã«çšããããå Žåãéè²æã¯éå³ããã€ãè²ã
äžããã¬ã©ã¹ç¹ç¶ãããããã®ã奜ãŸãããã¬ã©
ã¹ç¹ç¶çµæç©ã¯çŽ1.5495ã1.5740ã®ç¯å²ã®ã¬ã©ã¹
ç¹ç¶ã®å±æçãäžããã®ã奜ãŸãããã¬ã©ã¹ã®å±
æçãé«ããªããšãç¹ç¶ã§è£åŒ·ãããéæãªãã
ã«ã«æãŸãããªãããã³ãºè²ãäžãããæã奜ãŸ
ããã¬ã©ã¹ç¹ç¶ã®å±æçã¯1.5495ã1.557ã®ç¯å²
ã«ããã æ°Žæ§ååŠçåŠççšçµæç©ã¯åœæ¥è ã«ç¥ãããã©
ããªæ¹æ³ã«ãã€ãŠã¬ã©ã¹ç¹ç¶ã«é©çšããŠãããã
äŸãã°ã¬ã©ã¹ç¹ç¶ã®åœ¢æäžãã¬ã©ã¹ç¹ç¶ãæ°Žæ§å
åŠçåŠççšçµæç©ãé©çšã§ããå åãªæž©åºŠã«å·åŽ
ãããåŸã«é©çšãããããµã€ãžã³ã°çµæç©ãšããŠ
å žåçã«èšåããããæ°Žæ§ååŠçåŠççšçµæç©ã¯
ãã«ããããŒã©ãŒãåŽé§åšçãæããé©çšåšã«ã
ã€ãŠãããã®ã¬ã©ã¹ç¹ç¶ã«é©çšãããã次ã«åŠç
ãããã¬ã©ã¹ç¹ç¶ã¯ïŒæ¬ä»¥äžã®ã¹ãã©ã³ãã«éã
ããã圢æçšããã±ãŒãžãšããŠäžè¬ã«èšåãããŠ
ããããã±ãŒãžã«ãã€ããŠãè¯ããåã¬ã©ã¹ç¹ç¶
ã¯ïŒæ¬ä»¥äžã®ã¹ãã©ã³ãã«éãã湿ã€ã现æçæ
ç©ãšããŠçŽ°æããŠãè¯ããåã¬ã©ã¹ç¹ç¶ã¯ïŒæ¬ä»¥
äžã®ã¹ãã©ã³ãã«éããããŒãã³ã°ãšããŠéããŠ
ãè¯ããã¬ã©ã¹ç¹ç¶ã¯ä¹Ÿç¥ããŠãããã®æ°Žåå«æ
éãæžå°ããã奜ãŸããã¯ååŠçã«åŠçãããã¬
ã©ã¹ç¹ç¶ã®åœ¢ãã©ã®ãããªãã®ã§ãã€ãŠãããã
ãã¯çŽ121âïŒ250ãïŒã149âïŒ300ãïŒããäœã
ç¯å²ã®æž©åºŠã§11æéã«çžåœãã枩床åã³æéæ¡ä»¶
ã§ä¹Ÿç¥ãããã也ç¥ã¯é颚çãèªé»äœççã®åŠã
åŸæ¥ã®ã¬ã©ã¹ç¹ç¶ä¹Ÿç¥çã§éæããããšãåºæ¥
ãã也ç¥ããã¬ã©ã¹ç¹ç¶ã¯ã¹ãã©ã³ããæ§æãã
ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã«ååšããæ°Žæ§ååŠçåŠççšçµ
æç©ã®ä¹Ÿç¥æ®æž£ãæããã奜ãŸããã¯ã¬ã©ã¹ç¹ç¶
äžã®ä¹Ÿç¥æ®æž£ã®éã¯ãçŽ0.5ã1.2ééïŒ ã®ç¯å²ã®
LOIïŒçŒç±æžéïŒã§ããã æ°Žæ§ååŠçåŠççšçµæç©ã®æ®æž£ãæãã也ç¥ã¬
ã©ã¹ç¹ç¶ã¯ã飜ååã³äžé£œåããªãšã¹ãã«åã³ãš
ããã·ã®åŠãéåæ§è£åŒ·éåäœã補é ããã©ããª
æ¹æ³ã«çšããŠãè¯ããã¬ã©ã¹ç¹ç¶ãç¹ã«é©ããŠã
ãïŒã€ã®æ¹æ³ã¯éææã¯åéæã®ã¢ã¯ãªã«éåäœ
ã¬ã©ã¹ç¹ç¶è£åŒ·ããã«ã®åœ¢æã§ãããã¬ã©ã¹ç¹ç¶
éæåã³åéæããã«ã補é ããã®ã«çšãããã
åæ¥çãªé«é床æäœã§ã¯ãæ°Žæ§ååŠçåŠççšçµæ
ç©ã®ä¹Ÿç¥æ®æž£ãæããã¬ã©ã¹ç¹ç¶ã¯çæ³çã«é©ã
ãŠããã现æããã¬ã©ã¹ç¹ç¶ã¯ããã«ã補é ãã
ããã®é«é床æäœã®æ¡ä»¶å ã§éåäœãããªãã¯ã¹
ã«éåžžã«ããæ¿¡ãããæ°Žæ§ååŠçåŠççšçµæç©ã®
也ç¥æ®æž£ãæããã¬ã©ã¹ç¹ç¶ã¯ã也ç¥çŽ°æããã
ã¬ã©ã¹ç¹ç¶ãæã¯éæ¬ãã«ãç¶ã®ã»ããã¢ã³ã®åŠ
ãå¥é¢åºæäžã移åããéåäœãããªãã¯ã¹ãžåŸ
ã§çŽ°æãããããŒãã³ã°ãšããŠãã®ãããªæäœãž
äŸçµŠããŠãè¯ãã现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã
ãéåäœãããªãã¯ã¹ç¶ã«ããããåäžã«åæ£ã
ãããšããããã¬ã©ã¹ç¹ç¶ã¯ã¬ã©ã¹ãããªãã¯ã¹
äžã«æ²éãæ¿¡ããããããã«ãªãã次ã«ã¬ã©ã¹ç¹
ç¶éåäœãããªãã¯ã¹ãé©åœãªçäžã§ç¡¬åããã¬
ã©ã¹ç¹ç¶è£åŒ·ããã«ã補é ããããããããã«
ã¯ãã»ãšãã©ç¹ç¶ã®çªèµ·ããããè¯å¥œãªéææ§ã
æãããæ¬çºæã®åŠçãããã¬ã©ã¹ç¹ç¶ã¯åéæ
ã§å ãŠããããŠããªãããã«ç³»ã«çšããŠãããã
åçŽ12ãçŽ50ééïŒ ã®çé žã«ã«ã·ãŠã ãå ãŠãã
ãããã®ãçè²å ãŠãããããã®ãã®åŠãå ãŠã
ãããç³»ã«çšããŠããããä»ã®å ãŠããããåå
ãŠããããŠããªãéåäœãããªãã¯ã¹ç³»ã«çšããŠ
ãè¯ãã æ¬çºæã®å¥œãŸããå ·äœäŸãšããŠãã¬ã©ã¹ç¹ç¶ã¯
溶èããããã现ããããçŽ1.554ã1.557ã®å±æ
çãæããçŽ5.2ééïŒ ã®B2O3æ¿åºŠãæãããã¬
ã©ã¹ç¹ç¶ã®ã¬ã©ã¹çµæã¯ééïŒ ã§SiO2â55.8ã
CaOâ21ãAl2O3â14.8ãB2O3â5.2ãNa2Oâ
1.4ãF2â0.5ãåã³ã¬ã©ã¹ã®åèšæåãåŸãã®ã«
çšãããããããé åç©ããéåžžååšãã埮éã®
ææãããªãã®ã奜ãŸãããã¬ã©ã¹ç¹ç¶ã¯ã¬ã©ã¹
溶èçã®å¥ç®¡äžã®å€æ°ã®ç©Žããã¬ã©ã¹ç¹ç¶ã圢æ
ããéã«ããã«ãåçµåå€é©çšåšã«ãã€ãŠæ°Žæ§å
åŠçåŠççšçµæç©ã§è¢«èŠãããã æ°Žæ§ååŠçåŠççšçµæç©ã¯ãã€ã«ã 圢æã®ãã
ã®å¯äžã®éåäœææãšããŠåæšåããªã¯ã·ã«954
ãšããŠãµããã瀟ããå ¥æåºæ¥ããã¹ããšããŒã«
ããªãšã¹ãã«ãã€ã«ã 圢ææ§éåäœãå«ãåäžã®
æ°Žæ§ãšãã«ãžãšã³ã§ããããã¹ããšããŒã«ããªãš
ã¹ãšãã«æã¯ãšã¹ãã«åãšããã·ãã€ã«ã 圢ææ§
éåäœã¯ãéåäœïŒã¢ã«åœãã1.4ããå°ããªäº
éçµåã®èèªæäžé£œåã®éãæãã奜ãŸããã¯
0.1ããå°ãããæã奜ãŸããã¯ãçŽ0.07ã§ãã
èèªæäžé£œå察è³éŠæäžé£œåæ¯ãæããã奜ãŸã
ãã·ã©ã³ã«ãããªã³ã°å€ã¯åæšåA174ã·ã©ã³ãš
ããŠãŠããªã³ã»ã«ãŒãã€ãã»ã³ãŒãã¬ãŒã·ãšã³ã
ãå ¥æãããγâã¡ã¿ã¯ãªããã·ãããã«ããªã¡
ããã·ã·ã©ã³ã§ãããA174ã·ã©ã³ã®éã¯æ°Žæ§å
åŠçåŠççšçµæç©ã®åºåœ¢ç©ã®çŽ2.7ãçŽïŒééïŒ
ã®ç¯å²ã«ããã®ã奜ãŸããã氎溶æ§éœã€ãªã³æ§ã¬
ã©ã¹ç¹ç¶æœ€æ»å€ã¯ãšããªãŒãªãŠãŠã6717ã§ããã®
ã奜ãŸãããããã¯æ°Žæ§ååŠçåŠççšçµæç©ã®åº
圢ç©ã®çŽïŒã2.5ééïŒ ã®éã§ååšããããšãã
ã·ã«åãããéœã€ãªã³æ§ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§
ããææ©éé»é²æ¢å€ã¯ããªã¯ã·ã«AOâ5620éé»
é²æ¢å€ã§ãããã¯æ°Žæ§åŠççšçµæç©ã®çŽ0.05ãçŽ
0.15ééïŒ ã®æå¹ãªéã§çšããããå¯äžã®éé»é²
æ¢å€ãšããŠååšãããåãã¬ãžã¡ã³841ã¡ã©ãã³
ãã«ã ã¢ã«ãããã§ããã¹ãã©ã³ã硬åå€ãæ°Žæ§
åŠççšçµæç©ã®çŽ0.1ã0.15ééïŒ ã®éã§ååšã
ããã®ã奜ãŸãããæ°Žæ§ååŠçåŠççšçµæç©ãæ§
æãããããã«ååšããæ°Žã¯ãæ°Žæ§ååŠçåŠççš
çµæç©ã®å¥œãŸããã¯çŽïŒãïŒééïŒ ã®å šåºåœ¢ç©ã
äžãããããªéã§ããããã¹ããšããŒã«ããªãšã¹
ãã«æš¹èã®éã¯ã«ãããªã³ã°å€ã最æ»å€ãéé»é²
æ¢å€åã³ã¹ãã©ã³ã硬åå€ã®éããã®åºåœ¢ç©ã®æ®
ãã§ãããæ°Žæ§ååŠçåŠççšçµæç©ã®PHã¯çŽ5.5
ã6.2ã®ç¯å²ã«ããã®ã奜ãŸããã æ°Žæ§ååŠçåŠççšçµæç©ã¯ã¡ã¿ã¯ãªããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³ãé ¢é žã«ãã€ãŠãäºãæ··
åãããã¿ã³ã¯äžã§ãã®ã·ã©ã³çŽ20ïœã«å¯Ÿãé ¢é ž
çŽïŒmlã®éã§å æ°Žå解ããããšã«ãã補é ãã
ããå æ°Žå解ã¯ååŠçåŠççšçµæç©ã補é ããã®
ã«çšããããæ°Žã®çŽ10ã20ééïŒ ã«é ¢é žãæ·»å
ããã·ã©ã³ããã®æ··åç©ãžãå®å šãªå æ°Žå解ãèµ·
ãããŸã§æªäŒŽããªããæ·»å ããããšã«ãã€ãŠéè¡
ããããéœã€ãªã³æ§ã¬ã©ã¹ç¹ç¶æœ€æ»å€ã¯76.7â
ïŒ170ãïŒã®ç±ãæ°Žã«æªäŒŽããªããæ·»å ããããã®
å Žåæ°Žã®éã¯äºãæ··åãããã¿ã³ã¯äžã§æ°Žæ§ååŠ
çåŠççšçµæç©ã補é ããã®ã«çšããããæ°Žã®å š
éã®çŽïŒïŒ ã§ãããçŽ46ïŒ ã®åºåœ¢ç©ã§ãããã¹ã
ãšããŒã«ããªãšã¹ãã«ã®æ°Žæ§ãšãã«ãžãšã³ã¯äž»ã
ãæ··åã¿ã³ã¯äžã§ãã®ééã®çŽïŒåã®éã®æ°Žãšäž
ç·ã«ããããå æ°Žå解ãããã·ã©ã³åã³ã¬ã©ã¹ç¹
ç¶æœ€æ»å€ã¯ãã®äž»ããæ··åã¿ã³ã¯ãžæ·»å ãããã
éœã€ãªã³æ§ææ©ãšããã·ã«å第åçŽã¢ã³ã¢ããŠã
å¡©éé»é²æ¢å€ã¯æ°ŽãšçŽïŒïŒ16ã®æ¯ã§äžç·ã«ããã
äž»ããæ··åã¿ã³ã¯ãžæ·»å ããããã¡ã©ãã³ãã«ã
ã¢ã«ãããæš¹èã¯æ°ŽãšçŽïŒïŒ300ã®æ¯ã§äžç·ã«ã
ããäž»ããæ··åã¿ã³ã¯ãžæ·»å ããããSAGïŒïŒ
ã®ãããªæ¶æ³¡å€ãå°éæ·»å ããŠããããæªäŒŽãã
ãŠããæ··åç©ãæ°Žã§æçµçåžæã®äœç©ãŸã§åžéã
ãã次ã«æ°Žæ§ååŠçåŠççšçµæç©ã®æçµPHãé ¢é ž
ã®åŠãçžå®¹æ§ã®ææ©é žã§çŽ5.5ãçŽ6.2ã®ç¯å²ã«ãª
ãããã«èª¿ç¯ããã 奜ãŸããã¯æ°Žæ§ååŠçåŠççšçµæç©ã¯ã¬ã©ã¹ç¹
ç¶ã®åœ¢æäžçŽ1.555ã®å±æçãæããæªåŠçã¬ã©
ã¹ãžé©çšããããã®å Žåç¹ç¶ã¯ãçŽ10.3Ã10-5ã
97.5Ã10-5ã€ã³ãæã¯ãã以äžã奜ãŸããã¯ãçŽ
35ã40Ã10-5ã®ç¯å²ã«ããããšãåºæ¥ããæ°Žæ§å
åŠçåŠççšçµæç©ã¯çŽ0.5ãçŽïŒïŒ ã®ç¯å²ã®LOI
ïŒçŒç±æžéïŒãšããŠååŠçåŠççšçµæç©ã®ä»çç©
ãäžããããã«ã¬ã©ã¹ç¹ç¶ãžé©çšããããã¬ã©ã¹
ç¹ç¶ã¯å¥œãŸããã¯ãããæã¯ïŒ«ç¹ç¶ã§ãã¹ã
ã©ã³ããžéãããšïŒ§â67ïŒåã¯ïŒšâåã¯ïŒ«â37ïŒ
ã¹ãã©ã³ãçã®ãããªè£œé ãäžãããã®ã§ããã
ã¬ã©ã¹ç¹ç¶ã®ã¹ãã©ã³ãã¯ã¹ãã©ã³ãå·»ãã«é
ããããŒãã³ã°ããã±ãŒãžãäœããå€æ°ã®ããŒã
ã³ã°ããã±ãŒãžãçŽ104ã149âïŒ220ã300ãïŒã®
ç¯å²ã®æž©åºŠã§11æéãã·ã¬ã³ïŒMichiganïŒçäž
ã§ä¹Ÿç¥ããã次ã«ããŒãã³ã°ãçŽ0.159cmïŒïŒïŒ
16ïŒã5.08cmïŒïŒã€ã³ãïŒã奜ãŸããã¯2.54cm
ïŒïŒã€ã³ãïŒã®é·ããæãã现æã¹ãã©ã³ããžçŽ°
æããéææã¯åéæã®ã¢ã¯ãªã«ããªãšã¹ãã«æ
ã¯ãšããã·ããã«ã補é ããæ¹æ³ã§çšããããšã
åºæ¥ãã现æããã¹ãã©ã³ãããéæ¬æ©ãã«ãã
ããããªãã¯ã¹ãå¥ããããã®ã»ããã¢ã³ã®åŠã
å¥é¢åºæãæãã移åããéæ¬æ©äžã«ååšããã
ããªãã¯ã¹æš¹èäžãžèœãšãã现æãããã¬ã©ã¹ç¹
ç¶ã¹ãã©ã³ããå«ããããªãã¯ã¹æš¹èã¯çãžé
ã³ãããã§ããã«ãå ç±ããŠç¡¬åããã æ¬çºæåã³å¥œãŸããå ·äœäŸãæŽã«æ¬¡ã®å®æœäŸã«
ããäŸç€ºããã å®æœäŸ ïŒ 189.27ïŒ50ã¬ãã³ïŒã®æ°Žæ§ååŠçåŠççšçµæ
ç©ãè¡šïŒã®æåãçšããŠè£œé ããããã®çµæç©ã
奜ãŸããå ·äœäŸãšããŠèšè¿°ããã¬ã©ã¹ç¹ç¶ãåŠç
ããã®ã«çšããã
ãè¡šã
ãã«ãžãšã³
ãè¡šã
ããã®æ°Ž
ã¬ã©ã¹ç¹ç¶ã¯å¥œãŸããå ·äœäŸã®ã¬ã©ã¹çµæãæ
ããåã¯ïŒ«ã®åç¹ç¶åŸãæã¡ãâ55åã¯ïŒ«â
37ã®è£œé ãæã€ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã«æ§æãã
奜ãŸããå ·äœäŸã®æž©åºŠã§ä¹Ÿç¥ããã也ç¥ããã¹ã
ã©ã³ããçŽ2.54cmã®é·ãã«çŽ°æãããããã也ç¥
ã现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã€ããåèšæ¹æ³ã«ã
ãã¢ã¯ãªãŒã«ããªãšã¹ãã«ãããªãã¯ã¹ãžæ·»å
ããåéæã®ããã«ã補é ããã è¡šã¯ãšã¹ãã«åããããšããã·ãã€ã«ã 圢æ
æ§éåäœããªã¯ã·ã«954ææãããŠã¢ããŒã«
ïŒDuanolïŒæº¶å€äžã«å ¥ããæ°Žæ§ãšãã«ãžãšã³ã®ã
ãã®èèªæäžé£œåéãèèªæäžé£œå察è³éŠæäžé£œ
åã®æ¯åã³å¹³åååéãåã³åŸãããããªãšã¹ã
ã«ç±å¯å¡æ§ãããªãã¯ã¹ã«ããã¬ã©ã¹ç¹ç¶ã®æ¿¡ã
æ§ã瀺ããŠããã
ã¬ã©ã¹ç¹ç¶ã¯å¥œãŸããå ·äœäŸã®ã¬ã©ã¹çµæãæ
ããåã¯ïŒ«ã®åç¹ç¶åŸãæã¡ãâ55åã¯ïŒ«â
37ã®è£œé ãæã€ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã«æ§æãã
奜ãŸããå ·äœäŸã®æž©åºŠã§ä¹Ÿç¥ããã也ç¥ããã¹ã
ã©ã³ããçŽ2.54cmã®é·ãã«çŽ°æãããããã也ç¥
ã现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã€ããåèšæ¹æ³ã«ã
ãã¢ã¯ãªãŒã«ããªãšã¹ãã«ãããªãã¯ã¹ãžæ·»å
ããåéæã®ããã«ã補é ããã è¡šã¯ãšã¹ãã«åããããšããã·ãã€ã«ã 圢æ
æ§éåäœããªã¯ã·ã«954ææãããŠã¢ããŒã«
ïŒDuanolïŒæº¶å€äžã«å ¥ããæ°Žæ§ãšãã«ãžãšã³ã®ã
ãã®èèªæäžé£œåéãèèªæäžé£œå察è³éŠæäžé£œ
åã®æ¯åã³å¹³åååéãåã³åŸãããããªãšã¹ã
ã«ç±å¯å¡æ§ãããªãã¯ã¹ã«ããã¬ã©ã¹ç¹ç¶ã®æ¿¡ã
æ§ã瀺ããŠããã
ãè¡šã
èèªæäžé£œåéã¯åœæ¥è
ã«ããç¥ãããã©ããª
æ¹æ³ã«ãã€ãŠæ±ºå®ããŠãããããããã®å€ã¯åºäœ
æš¹èã®100éšã«åºã«ããççŽ ã»ççŽ äºéçµåã«é¢
ããããŒã»ã³ãã§ãããèèªæäžé£œå察è³éŠæäž
飜åã®æ¯ã¯ã次ã®æ³¢é·ã§ã次ã®èšç®åŒã«åŸã€ãŠæ±º
å®ãããïŒ æ³¢é·ïŒžã§ã®åžåïŒïŒæ倧ããŒã¯ã®å€ïŒâïŒããŒã¯
ã«ã€ããŠã®äºã€ã®æå°å€ã®åèšãïŒã§å²ã€ãå€ïŒ è¡šããã®å®æœäŸïŒ 1647cm-1ã§ã®åžå ïŒ0.0260â0.0209ïŒ0.0194ïŒïŒïŒ0.0058 1608cm-1ã§ã®åžå ïŒ0.1045â0.0269ïŒ0.0194ïŒïŒïŒ0.0813 åžåâ1647cm-1ïŒåžåâ1608cm-1ïŒ0.0058ïŒ0.0813ïŒ0.
0713 å¹³åååéã¯ã²ã«æµžéã¯ãããã°ã©ãã€ãŒã«ã
ã€ãŠæ±ºå®ãããã æ¿¡ãæ§ã¯éåäœãããªãã¯ã¹ã«ã®ãã现æã¹ã
ã©ã³ããããã«ç§»åç·äžã«æ¶ããæéãç®ã§èŠ³å¯
ããããšã«ãã決å®ããã现æã¹ãã©ã³ããïŒå
以å ã§æ¿¡ããæããè¯ãã§ãããšèªããïŒãïŒå
ã§æ¿¡ããæããäžè¯ããšããŠãèªãããå®æœäŸïŒ
ã«ç€ºããæ°Žæ§ãµã€ãžã³ã°çµæç©äžã«ããããååš
ããŠãããè¡šã®çš®ã ã®ãã€ã«ã 圢æéåäœã§åŠ
çããã¬ã©ã¹ç¹ç¶ãæããçš®ã ã®ä¹Ÿç¥ã¹ãã©ã³ã
ãæ¿¡ãæ§ã«ã€ããŠæ¯èŒããŠè©Šéšããã ãã€ã«ã 圢ææ§éåäœã«ã€ããŠè¡šã«äžããè
èªæäžé£œåéåã³èèªæäžé£œå察è³éŠæäžé£œåã®
æ¯ã§ã¯ãéãæ¿¡ãæ§ãåŸãããããã®éãæ¿¡ãæ§
ã¯ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®çŽ°æã¹ãã©ã³
ãããããªãã¯ã¹éåäœã«å¯ŸããŠç€ºãããã®ã§ã
ããéåäœïŒã¢ã«åœãã1.5ãè¶ããäºéçµåã®
èèªæäžé£œåå€ãš0.1ãã倧ããªèèªæäžé£œå察
è³éŠæäžé£œåã®æ¯ã§ã¯æ¿¡ãæ§ã¯äžè¯ã§ãã€ãã å®æœäŸ ïŒ 189.27ïŒ50ã¬ãã³ïŒã®è¡šïŒã®é åãæããæ°Ž
æ§ååŠçåŠççšçµæç©ãã奜ãŸããå ·äœäŸã®ãã
æ¹ã§å¥œãŸããå ·äœäŸã®ã¬ã©ã¹çµæãæããã¬ã©ã¹
ç¹ç¶ãžé©çšããã
æ¹æ³ã«ãã€ãŠæ±ºå®ããŠãããããããã®å€ã¯åºäœ
æš¹èã®100éšã«åºã«ããççŽ ã»ççŽ äºéçµåã«é¢
ããããŒã»ã³ãã§ãããèèªæäžé£œå察è³éŠæäž
飜åã®æ¯ã¯ã次ã®æ³¢é·ã§ã次ã®èšç®åŒã«åŸã€ãŠæ±º
å®ãããïŒ æ³¢é·ïŒžã§ã®åžåïŒïŒæ倧ããŒã¯ã®å€ïŒâïŒããŒã¯
ã«ã€ããŠã®äºã€ã®æå°å€ã®åèšãïŒã§å²ã€ãå€ïŒ è¡šããã®å®æœäŸïŒ 1647cm-1ã§ã®åžå ïŒ0.0260â0.0209ïŒ0.0194ïŒïŒïŒ0.0058 1608cm-1ã§ã®åžå ïŒ0.1045â0.0269ïŒ0.0194ïŒïŒïŒ0.0813 åžåâ1647cm-1ïŒåžåâ1608cm-1ïŒ0.0058ïŒ0.0813ïŒ0.
0713 å¹³åååéã¯ã²ã«æµžéã¯ãããã°ã©ãã€ãŒã«ã
ã€ãŠæ±ºå®ãããã æ¿¡ãæ§ã¯éåäœãããªãã¯ã¹ã«ã®ãã现æã¹ã
ã©ã³ããããã«ç§»åç·äžã«æ¶ããæéãç®ã§èŠ³å¯
ããããšã«ãã決å®ããã现æã¹ãã©ã³ããïŒå
以å ã§æ¿¡ããæããè¯ãã§ãããšèªããïŒãïŒå
ã§æ¿¡ããæããäžè¯ããšããŠãèªãããå®æœäŸïŒ
ã«ç€ºããæ°Žæ§ãµã€ãžã³ã°çµæç©äžã«ããããååš
ããŠãããè¡šã®çš®ã ã®ãã€ã«ã 圢æéåäœã§åŠ
çããã¬ã©ã¹ç¹ç¶ãæããçš®ã ã®ä¹Ÿç¥ã¹ãã©ã³ã
ãæ¿¡ãæ§ã«ã€ããŠæ¯èŒããŠè©Šéšããã ãã€ã«ã 圢ææ§éåäœã«ã€ããŠè¡šã«äžããè
èªæäžé£œåéåã³èèªæäžé£œå察è³éŠæäžé£œåã®
æ¯ã§ã¯ãéãæ¿¡ãæ§ãåŸãããããã®éãæ¿¡ãæ§
ã¯ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã®çŽ°æã¹ãã©ã³
ãããããªãã¯ã¹éåäœã«å¯ŸããŠç€ºãããã®ã§ã
ããéåäœïŒã¢ã«åœãã1.5ãè¶ããäºéçµåã®
èèªæäžé£œåå€ãš0.1ãã倧ããªèèªæäžé£œå察
è³éŠæäžé£œåã®æ¯ã§ã¯æ¿¡ãæ§ã¯äžè¯ã§ãã€ãã å®æœäŸ ïŒ 189.27ïŒ50ã¬ãã³ïŒã®è¡šïŒã®é åãæããæ°Ž
æ§ååŠçåŠççšçµæç©ãã奜ãŸããå ·äœäŸã®ãã
æ¹ã§å¥œãŸããå ·äœäŸã®ã¬ã©ã¹çµæãæããã¬ã©ã¹
ç¹ç¶ãžé©çšããã
ãè¡šã
ãè¡šã
ããã®æ°Ž
ã¬ã©ã¹ç¹ç¶ã¯ïŒšåã¯ïŒ«ã®åç¹ç¶åŸãæããâ
55åã¯ïŒ«â37ãšããŠæ§æãããã¹ãã©ã³ãã«ãªã
ããã«éãããåŠçãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã
ã也ç¥ããçŽ2.54cmã®é·ããžçŽ°æããããããã®
现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ããåèšæ¹æ³ã«ãã
éåäœãããªãã¯ã¹ãžæ·»å ããåéæã®ããã«ãž
補é ããã äžèšå®æœäŸåã³è¡šïŒã®æ¯èŒäŸïŒã®ããã®æ°Žæ§å
åŠçåŠççšçµæç©ã奜ãŸããå ·äœäŸã®å Žåãšåæ§
ãªããæ¹ã§è£œé ãããè¡šïŒã®æ¯èŒäŸïŒã¯ç±³åœç¹èš±
第4110194å·ã«ç€ºãããŠããã®ãšåæ§ãªããæ¹ã§
補é ãããæ°Žæ§ååŠçåŠççšçµæç©ãçšãããã¬
ã©ã¹ç¹ç¶ã¹ãã©ã³ãã¯ãã¹ãŠå¥œãŸããå ·äœäŸãšå
æ§ãªããæ¹ã§åœ¢æããæ°Žæ§ååŠçåŠççšçµæç©ã§
åŠçãããã
ã¬ã©ã¹ç¹ç¶ã¯ïŒšåã¯ïŒ«ã®åç¹ç¶åŸãæããâ
55åã¯ïŒ«â37ãšããŠæ§æãããã¹ãã©ã³ãã«ãªã
ããã«éãããåŠçãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã
ã也ç¥ããçŽ2.54cmã®é·ããžçŽ°æããããããã®
现æããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ããåèšæ¹æ³ã«ãã
éåäœãããªãã¯ã¹ãžæ·»å ããåéæã®ããã«ãž
補é ããã äžèšå®æœäŸåã³è¡šïŒã®æ¯èŒäŸïŒã®ããã®æ°Žæ§å
åŠçåŠççšçµæç©ã奜ãŸããå ·äœäŸã®å Žåãšåæ§
ãªããæ¹ã§è£œé ãããè¡šïŒã®æ¯èŒäŸïŒã¯ç±³åœç¹èš±
第4110194å·ã«ç€ºãããŠããã®ãšåæ§ãªããæ¹ã§
補é ãããæ°Žæ§ååŠçåŠççšçµæç©ãçšãããã¬
ã©ã¹ç¹ç¶ã¹ãã©ã³ãã¯ãã¹ãŠå¥œãŸããå ·äœäŸãšå
æ§ãªããæ¹ã§åœ¢æããæ°Žæ§ååŠçåŠççšçµæç©ã§
åŠçãããã
ãè¡šã
åžæã®äœç©ã«ããããã®æ°Ž
ã¬ã©ã¹ç¹ç¶ã®æ§é ã¯åæ§ã§ããããã¯åæ§ãªã
ãæ¹ã§éåäœãããªãã¯ã¹ãžæ·»å ããããã«çŽ°æ
ãããæ¯èŒäŸåã³å®æœäŸïŒã13ã®ä¹Ÿç¥ã现æãã
ã¬ã©ã¹ç¹ç¶ã§è£åŒ·ããã¢ã¯ãªã«ããªãšã¹ãã«ãã
ã«ã¯å¥œãŸããå ·äœäŸã®å Žåãšåæ§ãªããæ¹ã§è£œé
ãããæ¯èŒäŸïŒã¯ãšããã·éåäœåã³ããªããã«
ãããªãã³ãæããéç²çæ§ãã€ã«ã 圢ææ§éå
äœã¯çšããªãã€ããè¡šïŒã®æ¯èŒäŸïŒã¯ãšããã·é
åäœãååšãããã«ãã¹ããšããŒã«ããªãšã¹ãã«
åã®éç²çæ§ãã€ã«ã 圢ææ§éåäœã®ã¿ãå«ãæ°Ž
æ§ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæã€ã¬ã©ã¹ç¹
ç¶ãçšãããæ¯èŒäŸïŒåã³ïŒã®äž¡æ¹ãšãææ©éé»
é²æ¢å€åã³ã¹ãã©ã³ã硬åå€ã¯çšããªãã€ãã è¡šïŒã«ã¯æŽã«ãè£åŒ·ãããéåäœããã«äžåã³
åŠçäžã®ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã®æ§èœç¹æ§ã瀺ãäŸã瀺ãããŠãããå®æœäŸïŒ
åã³ïŒã®ã¹ãã©ã³ãã®ä»ã«ãå®æœäŸïŒã11ã¯å®æœ
äŸïŒåã³ïŒã®ãã®ãšåæ§ãªæ°Žæ§ååŠçåŠççšçµæ
ç©ã§åŠçãããç¹ç¶ã®ç¹æ§ã瀺ããŠãããå®æœäŸ
ïŒã11ã®ååŠçåŠçã¯éœã€ãªã³æ§ææ©ãšããã·ã«
å第åçŽã¢ã³ã¢ããŠã å¡©éé»é²æ¢å€åã³ã¡ã©ãã³
ãã«ã ã¢ã«ãããã¹ãã©ã³ã硬åå€ã®éãæ瀺ã
ãããã«å€ããããšã«ããå®æœäŸïŒåã³ïŒã®ãã®
ãšã¯ç°ãªã€ãŠãããè¡šïŒã«ã¯ãè¡šïŒã«ç€ºãããã
ãªæ¯èŒäŸïŒåã³ïŒã®æ°Žæ§ååŠçåŠççšçµæç©ã§åŠ
çãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã瀺ãããŠããã è¡šïŒã¯æ¯èŒäŸã®ã¬ã©ã¹ç¹ç¶ã«æ¯èŒããŠæ¬çºæã®
ã¬ã©ã¹ç¹ç¶ã«ãã€ãŠäžããããæ¹è¯ã瀺ããŠã
ããå®æœäŸïŒåã³ïŒã®å Žåã®æ¬çºæã®ã¬ã©ã¹ç¹ç¶
ã§è£åŒ·ãããããã«ã¯ç¹ç¶çžäºã®ç²çåã³ããã«
éææ§ã«ã€ããŠã®ç¹æ§ã«ã€ããŠãæ¯èŒäŸïŒåã³ïŒ
ã®åãç¹æ§ãããæ¹è¯ãããæ§èœãæã€ãŠããã
æ¬çºæã®ç¯å²ã«å ¥ãããªãéã®ç¹å®ã®ææ©éé»é²
æ¢å€åã³ïŒåã¯ïŒã¹ãã©ã³ã硬åå€ãçšããäŸ
ã¯ãç¹ç¶çžäºã®ä»çåã³çŽ°ææ§ã«ã€ããŠå£ã€ãæ§
èœç¹æ§ã«äžããã现ææ§ã¯çŽ°ææ©åã³ã³ããã¯ãª
ã³ã°ïŒcot clingïŒã«ãã€ãŠæž¬å®ãããã è¡šïŒã«ã¯ç®ã§èŠ³å¯ããçµæåã³æ§èœç¹æ§ã®ççŽ
ã瀺ãããŠãããæãè¯ãçµæã¯ããããããæ
ã¯ãç§ãã®è©äŸ¡ãåæ ŒãšããŠããäžçšåºŠãã®è©äŸ¡
ã¯ç¹æ§äžã€ãŸã§ã§ãããªããæã¯ãããããã®è©
䟡åã¯ãç§ãã®è©äŸ¡ããã€ãã®ã§ããã
ã¬ã©ã¹ç¹ç¶ã®æ§é ã¯åæ§ã§ããããã¯åæ§ãªã
ãæ¹ã§éåäœãããªãã¯ã¹ãžæ·»å ããããã«çŽ°æ
ãããæ¯èŒäŸåã³å®æœäŸïŒã13ã®ä¹Ÿç¥ã现æãã
ã¬ã©ã¹ç¹ç¶ã§è£åŒ·ããã¢ã¯ãªã«ããªãšã¹ãã«ãã
ã«ã¯å¥œãŸããå ·äœäŸã®å Žåãšåæ§ãªããæ¹ã§è£œé
ãããæ¯èŒäŸïŒã¯ãšããã·éåäœåã³ããªããã«
ãããªãã³ãæããéç²çæ§ãã€ã«ã 圢ææ§éå
äœã¯çšããªãã€ããè¡šïŒã®æ¯èŒäŸïŒã¯ãšããã·é
åäœãååšãããã«ãã¹ããšããŒã«ããªãšã¹ãã«
åã®éç²çæ§ãã€ã«ã 圢ææ§éåäœã®ã¿ãå«ãæ°Ž
æ§ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãæã€ã¬ã©ã¹ç¹
ç¶ãçšãããæ¯èŒäŸïŒåã³ïŒã®äž¡æ¹ãšãææ©éé»
é²æ¢å€åã³ã¹ãã©ã³ã硬åå€ã¯çšããªãã€ãã è¡šïŒã«ã¯æŽã«ãè£åŒ·ãããéåäœããã«äžåã³
åŠçäžã®ååŠçã«åŠçãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã®æ§èœç¹æ§ã瀺ãäŸã瀺ãããŠãããå®æœäŸïŒ
åã³ïŒã®ã¹ãã©ã³ãã®ä»ã«ãå®æœäŸïŒã11ã¯å®æœ
äŸïŒåã³ïŒã®ãã®ãšåæ§ãªæ°Žæ§ååŠçåŠççšçµæ
ç©ã§åŠçãããç¹ç¶ã®ç¹æ§ã瀺ããŠãããå®æœäŸ
ïŒã11ã®ååŠçåŠçã¯éœã€ãªã³æ§ææ©ãšããã·ã«
å第åçŽã¢ã³ã¢ããŠã å¡©éé»é²æ¢å€åã³ã¡ã©ãã³
ãã«ã ã¢ã«ãããã¹ãã©ã³ã硬åå€ã®éãæ瀺ã
ãããã«å€ããããšã«ããå®æœäŸïŒåã³ïŒã®ãã®
ãšã¯ç°ãªã€ãŠãããè¡šïŒã«ã¯ãè¡šïŒã«ç€ºãããã
ãªæ¯èŒäŸïŒåã³ïŒã®æ°Žæ§ååŠçåŠççšçµæç©ã§åŠ
çãããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã瀺ãããŠããã è¡šïŒã¯æ¯èŒäŸã®ã¬ã©ã¹ç¹ç¶ã«æ¯èŒããŠæ¬çºæã®
ã¬ã©ã¹ç¹ç¶ã«ãã€ãŠäžããããæ¹è¯ã瀺ããŠã
ããå®æœäŸïŒåã³ïŒã®å Žåã®æ¬çºæã®ã¬ã©ã¹ç¹ç¶
ã§è£åŒ·ãããããã«ã¯ç¹ç¶çžäºã®ç²çåã³ããã«
éææ§ã«ã€ããŠã®ç¹æ§ã«ã€ããŠãæ¯èŒäŸïŒåã³ïŒ
ã®åãç¹æ§ãããæ¹è¯ãããæ§èœãæã€ãŠããã
æ¬çºæã®ç¯å²ã«å ¥ãããªãéã®ç¹å®ã®ææ©éé»é²
æ¢å€åã³ïŒåã¯ïŒã¹ãã©ã³ã硬åå€ãçšããäŸ
ã¯ãç¹ç¶çžäºã®ä»çåã³çŽ°ææ§ã«ã€ããŠå£ã€ãæ§
èœç¹æ§ã«äžããã现ææ§ã¯çŽ°ææ©åã³ã³ããã¯ãª
ã³ã°ïŒcot clingïŒã«ãã€ãŠæž¬å®ãããã è¡šïŒã«ã¯ç®ã§èŠ³å¯ããçµæåã³æ§èœç¹æ§ã®ççŽ
ã瀺ãããŠãããæãè¯ãçµæã¯ããããããæ
ã¯ãç§ãã®è©äŸ¡ãåæ ŒãšããŠããäžçšåºŠãã®è©äŸ¡
ã¯ç¹æ§äžã€ãŸã§ã§ãããªããæã¯ãããããã®è©
䟡åã¯ãç§ãã®è©äŸ¡ããã€ãã®ã§ããã
第ïŒå³ã¯åæšåããªã¯ã·ã«AOâ5620ãšããŠåž
販ãããŠããå°ãªããšãäžã€ã®ã¢ã«ã³ãã·éšåã
æããéœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ã
ãéé»é²æ¢å€ã®æ žç£æ°å ±é³Žæ²ç·ã§ããã第ïŒå³ã¯
åæšåããªã¯ã·ã«954ææãšããŠãµããã瀟ãã
åžè²©ãããŠãããã¹ããšããŒã«ããªãšã¹ãã«æš¹è
ã®æ°Žæ§ãšãã«ãžãšã³ã«ã€ããŠã®æ žç£æ°å ±é³Žæ²ç·ã§
ããã第ïŒå³ã¯åæšåããªã¯ã·ã«AOâ5620ãšã
ãŠåžè²©ãããŠããå°ãªããšãã¢ã«ã³ãã·éšåãæ
ããéœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ãã
éé»é²æ¢å€ã®èµ€å€åå æ²ç·ã§ããã
販ãããŠããå°ãªããšãäžã€ã®ã¢ã«ã³ãã·éšåã
æããéœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ã
ãéé»é²æ¢å€ã®æ žç£æ°å ±é³Žæ²ç·ã§ããã第ïŒå³ã¯
åæšåããªã¯ã·ã«954ææãšããŠãµããã瀟ãã
åžè²©ãããŠãããã¹ããšããŒã«ããªãšã¹ãã«æš¹è
ã®æ°Žæ§ãšãã«ãžãšã³ã«ã€ããŠã®æ žç£æ°å ±é³Žæ²ç·ã§
ããã第ïŒå³ã¯åæšåããªã¯ã·ã«AOâ5620ãšã
ãŠåžè²©ãããŠããå°ãªããšãã¢ã«ã³ãã·éšåãæ
ããéœã€ãªã³æ§ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ãã
éé»é²æ¢å€ã®èµ€å€åå æ²ç·ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ è€æ°ã®ã¬ã©ã¹ç¹ç¶ãæããã¬ã©ã¹ç¹ç¶ã¹ãã©
ã³ãã§ãã€ãŠããããã¬ã©ã¹ç¹ç¶ãã氎溶æ§ãå
æ£æ§ãæãã¯ä¹³åæ§ã§ããããªãšã¹ãã«ããã³ãš
ããã·å®èœæ§ãæãããã€ã«ã 圢ææ§éåäœãæ
æ©å®èœã«ãããªã³ã°å€ã最æ»ã«æå¹ãªéã®éœã€ãª
ã³æ§ç¹ç¶æœ€æ»å€ãéé»é²æ¢å€ããã³æ°Žãå«ãæ°Žæ§
ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã§è¡šé¢ã®å°ãªããš
ãäžéšãèŠãããŠããã ïœ ãã€ã«ã 圢æéåäœãäžçš®ä»¥äžã®ãã¹ããšã
ãŒã«ïŒ¡ããªãšã¹ãã«ã§ããã ïœ ææ©å®èœã«ãããªã³ã°å€ããã«ãããªã³ã°å€
ãšããŠæå¹ãªéã§ãã¢ã¯ãªããã·å«æã«ãããª
ã³ã°å€åã³ã¡ã¿ã¯ãªããã·å«æã«ãããªã³ã°å€
ãããªã矀ããéžæããã ïœ éé»é²æ¢å€ãæ°Žæ§åŠççšçµæç©ã®çŽ0.05ãçŽ
0.4ééïŒ ã®éã§ååšããŠãããã¢ã«ã³ãã·éš
ååã³å°ãªããšãçŽ10ã®é žäŸ¡ãæããéœã€ãªã³
æ§ææ©ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ããã ïœ æ°Žããæ°Žæ§ååŠçåŠççšçµæç©ã®å šåºåœ¢ç©ã
çŽïŒã30ééïŒ ã®ç¯å²ã«ãããããªéã§ååš
ãã ãããæ°Žæ§ååŠçåŠççšçµæç©ããæ¬è³ªçã«ç¡
æ©éé»é²æ¢å€ãå«ãŸããæ°Žæ§ååŠçåŠççšçµæç©
ã®PHãçŽïŒããå°ããããšãç¹åŸŽãšãããã¬ã©ã¹
ç¹ç¶ã¹ãã©ã³ãã ïŒ ãã¹ããšããŒã«ïŒ¡ããªãšã¹ãã« ãã€ã«ã 圢
ææ§éåäœã®ä»ã«ããã€ã«ã 圢ææ§éåäœç³»ã圢
æããããã®æ°Žæ§ãšãã«ãžãšã³äžã«ãã¹ããšããŒ
ã«ïŒ¡ããªãšã¹ãã«éåäœãšæ··åããããšããã·å«
æãã€ã«ã 圢ææ§éåäœãååšããããšãç¹åŸŽãš
ãããåèšç¬¬ïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã ïŒ ãã¹ããšããŒã«ïŒ¡ããªãšã¹ãã«æš¹èãå éšç
ã«ãšããã·ã«åã§ä¹³åãããããšãç¹åŸŽãšããã
åèšç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«èšèŒã®ã¬ã©
ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒ ãã¹ããšããŒã«ïŒ¡ããªãšã¹ãã«ç±å¯å¡æ§ãã€
ã«ã 圢ææ§éåäœã®æ°Žæ§ãšãã«ãžãšã³ã極æ§å®èœ
æ§åã³çŽ50ééïŒ åºåœ¢ç©ã®éåäœãšãã«ãžãšã³ã«
ã€ããŠ10000ã»ã³ããã¢ãºããå°ããåœéç²åºŠã
æããéåäœïŒã¢ã«åœããå¹³å1.5以äžã®èèªæ
äºéçµåãæããåŠçãããã¬ã©ã¹ç¹ç¶ã®ããªãš
ã¹ãã«ãããªãã¯ã¹éåäœã«ããæ¿¡ãæ§ã調ç¯ã
ããããéåäœãïŒã¢ã«åœããå¹³å1.5ã®èèªæ
äºéçµåãæããæã宀枩ã§ä¹Ÿç¥ãããã€ã«ã ã«
ã€ããŠIRåžåçã«ãã€ãŠæž¬å®ããŠ0.1以äžã®èèª
æäžé£œå察è³éŠæäžé£œåã®æ¯ãæããæ°Žæ§ååŠç
åŠççšçµæç©ãçŽïŒééïŒ ããå°ãªãé䌞é·èªèµ·
åå¿ç©æãã¯çž®åèªèµ·åå¿ç©ãæããããšãç¹åŸŽ
ãšãããåèšç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«èš
èŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒ èèªæäžé£œå察è³éŠæäžé£œåã®æ¯ã0.09ãã
å°ããããšãç¹åŸŽãšãããåèšç¬¬ïŒé ã«èšèŒã®ã¬
ã©ã¹ç¹ç¶ã¹ã©ã€ãã ïŒ ã¬ã©ã¹ã1.54ã1.57ã®ç¯å²ã®å±æçãæãã
ããšãç¹åŸŽãšãããåèšç¬¬ïŒé ã第ïŒé ã®ããã
ãïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒ ã¬ã©ã¹ç¹ç¶ããäºé žåçªçŽ 55.8ã55.9éé
ïŒ ãé žåã«ã«ã·ãŠã 21ééïŒ ãé žåã¢ã«ãããŠã
14.8ééïŒ ãé žåç¡ŒçŽ 5.2ééïŒ ãé žåãããªãŠ
ã 1.4ééïŒ ãåã³ãµã€çŽ 0.5ã0.6ééïŒ ãããªã
ã¬ã©ã¹çµæãæããããšãç¹åŸŽãšãããåèšç¬¬ïŒ
é ã第ïŒé ã®ããããïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹
ãã©ã³ãã ïŒ ææ©ã«ãããªã³ã°å€ãã¢ã¯ãªããã·ã«åã¢ã«
ã³ãã· ã·ã©ã³åã³ã¡ã¿ã¯ãªããã·ã¢ã«ãã« ã¢
ã«ã³ãã· ã·ã©ã³åã³ãããã®å æ°Žå解çæç©ã
ããªã矀ããéžæãããæ°Žæ§åŠççšçµæç©ã®çŽ
0.1ãçŽ10ééïŒ ã®éã§ååšããŠããããšãç¹åŸŽ
ãšãããåèšç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«èš
èŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒ éœã€ãªã³æ§æœ€æ»å€ããã©ã«ãŽã³é žãçšããŠäœ
ãããããªã¢ãã ã¢ãã最æ»å€ã§ããããã®æœ€
æ»å€ãæ°Žæ§åŠççšçµæç©ã®çŽ0.05ãçŽ0.5ééïŒ
ã®ç¯å²å ã®éã§ååšããŠããããšãç¹åŸŽãšããã
åèšç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«èšèŒã®ã¬ã©
ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒïŒ éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³
ã¢ããŠã å¡©éé»é²æ¢å€ãçŽ10ãçŽ20ã®ç¯å²ã®é žäŸ¡
ãæãããåèšç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«
èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒïŒ éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³
ã¢ããŠã å¡©éé»é²æ¢å€ãåŒïŒ ãåŒäžãR1ãR2ãR3åã³R4ã®äžã€ä»¥äžã®éšåã
åããåã¯ç°ãªãã¢ã«ã³ãã·éšåã§ãã¡ãã¬ã³åº
ãæããåã¯ã¡ãã¬ã³åºãæããã ïŒâRâ³OâïŒbRâ²âïŒo ïŒRâ²ã¯ã¡ãã¬ã³åºïŒCH2ïŒã§ãïœã¯ïŒã10åã¯ã
ã以äžã®æŽæ°ã§ãããRâ³ã¯ãšãã¬ã³åºåã¯ãã
ãã¬ã³åºåã¯ãããã®æ··åç©ã§ãããïœã¯ïŒã10
åã¯ãã以äžã®æŽæ°ã§ãããã¯æ°ŽçŽ åã¯ïŒã
10åã®ççŽ ååãæããäœçŽã¢ã«ãã«åºã§ããïŒ
ã®åŠãæ«ç«¯ã¢ã«ã³ãŒã«æ§åºãæããã¢ã«ã³ãã·éš
åã§ããããšãã§ããåºR1ãR2ãR3åã³R4ã®å
ã€ãããããªããã®ãã¢ã«ã³ãã·åºã§ãããæ®ã
ã®éã¢ã«ã³ãã·åºR1ãR2ãR3åã³R4ã¯ïŒã30å
ã®ççŽ ååãæããã¢ã«ãã«åºã§ãããX-ã¯ã©
ããªããã²ã³åç©ã€ãªã³ã§ãããïŒ ãæããããšãç¹åŸŽãšãããåèšç¬¬ïŒé ã第ïŒïŒ
é ã®ããããïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã ïŒïŒ éœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³
ã¢ããŠã å¡©éé»é²æ¢å€ãåŒïŒ ïŒR5ïŒyâN+âïŒR6ïŒzX- ãåŒäžãR5㯠ïŒâRâ³OâïŒbRâ²aâ ïŒRâ²ã¯ã¡ãã¬ã³ïŒCH2ïŒã§ãããïœã¯ïŒãïŒã®æŽ
æ°ã§ãããRâ³ã¯ãšãã¬ã³ã§ïœã¯ïŒãïŒã®æŽæ°ã§
ãããã¯æ°ŽçŽ åã¯ã¡ãã«åºã§ããïŒã®åŠãå
ãã¢ã«ã³ãã·éšåã§ãããïœã¯ïŒåã¯ïŒã®æŽæ°ã§
ãããïœïŒïŒã®æãïœïŒïŒã§ãããïœïŒïŒã®æã
ïœïŒïŒã§ãããR6ã¯ïŒã25åã®ççŽ ååãæã
ãé·éã¢ã«ãã«ã§ãããX-ã¯Cl-åã¯Br-ã§ã
ãããæããããšãç¹åŸŽãšããåèšç¬¬ïŒé ã第ïŒ
ïŒé ã®ããããïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³
ãã ïŒïŒ æ°Žæ§ååŠçåŠççšçµæç©ãã¹ãã©ã³ã硬å
å€ãå«ãã§ããããšãç¹åŸŽãšãããåèšç¬¬ïŒé ã
第ïŒïŒé ã®ããããïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ã
ã©ã³ãã ïŒïŒ ã¹ãã©ã³ã硬åå€ãã¡ã©ãã³ãã«ã ã¢ã«ã
ããæš¹èã§ãæ°Žæ§ååŠçåŠççšçµæç©ã®å°ãªããš
ã0.1ééïŒ ã®éã§ååšããããšãç¹åŸŽãšããã
åèšç¬¬ïŒïŒé ã«èšèŒã®ã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã ïŒïŒ è€æ°ã®ã¬ã©ã¹ç¹ç¶ãæããã¬ã©ã¹ç¹ç¶ã¹ã
ã©ã³ãã§ãã€ãŠããããã¬ã©ã¹ç¹ç¶ãã氎溶æ§ã
åæ£æ§ãæãã¯ä¹³åæ§ã§ããããªãšã¹ãã«ããã³
ãšããã·å®èœæ§ãæãããã€ã«ã 圢ææ§éåäœã
ææ©å®èœã«ãããªã³ã°å€ã最æ»ã«æå¹ãªéã®éœã€
ãªã³æ§ç¹ç¶æœ€æ»å€ãéé»é²æ¢å€ããã³æ°Žãå«ãæ°Ž
æ§åŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ã§è¡šé¢ã®å°ãªããšãäž
éšãèŠãããŠããã ïœ ã¬ã©ã¹ç¹ç¶ãçŽ1.54ã1.57ã®ç¯å²ã®å±æçã
æããäºé žåçªçŽ 55.8ã55.9ééïŒ ãé žåã«ã«
ã·ãŠã 21ééïŒ ãé žåã¢ã«ãããŠã 14.8éé
ïŒ ãé žåç¡ŒçŽ 5.2ééïŒ ãé žåãããªãŠã 1.4é
éïŒ ããµã€çŽ 0.5ã0.6ééïŒ ãããã³é žåãã°
ãã·ãŠã 0.3ééïŒ ãããªãçµæãæãã ïœ ã¬ã©ã¹ç¹ç¶ã®è¡šé¢ã®å°ãªããšãäžéšã®äžã«å
åšããæ°Žæ§ååŠçåŠççšçµæç©ã®ä¹Ÿç¥æ®æž£ãã (1) ãšããã·ã«åã«ãã€ãŠå éšçã«ä¹³åæ§ã«ã
ããŠãããçŽ30000ã45000ã®ç¯å²ã®ééå¹³å
ååéãæããçŽ1.12ã®å€åæ£ææ°ãšãæ°Žæ§
ååŠçåŠççšçµæç©ã®åºåœ¢ç©ã®äž»èŠéšåãæ§
æããçŽ1.08ã®MzïŒMvãæããçŽ50ééïŒ
åºåœ¢ç©ã®éåäœãšãã«ãžãšã³ã«ã€ããŠ10000
ã»ã³ããã¢ãºããå°ããåœéç²åºŠãæããã
ã¹ããšããŒã«ïŒ¡ããªãšã¹ãã« ãã€ã«ã 圢æ
æ§éåäœã®æ°Žæ§ãšãã«ãžãšã³åã¯åæ£ç©ã§ã
ãããéåäœïŒã¢ã«åœããå¹³åçŽ1.5ããå°
ããèèªæäºéçµåã®äžé£œåéãæããã¬ã©
ã¹ç¹ç¶ã®ç±å¯å¡æ§éåäœã«ããæ¿¡ãæ§ãæ¹è¯
ãããããéåäœãïŒã¢ã«åœããå¹³å1.5ã®
èèªæäºéçµåãæããæã宀枩ã§ä¹Ÿç¥ãã
ãã€ã«ã ã«ã€ããŠIRåžåçã«ãã€ãŠæž¬å®ã
ãçŽ0.07以äžã®èèªæäžé£œå察è³éŠæäžé£œå
ã®æ¯ãæãããšãã«ãžãšã³åã¯åæ£ç©ã (2) æ°Žæ§ååŠçåŠççšçµæç©ã®çŽ0.1ãçŽ10é
éïŒ ã®ç¯å²ã®éã§ååšããã¢ã¯ãªããã·å«æ
γâã¡ã¿ã¯ãªããã·âãããã«ããªã¡ããã·
ã·ã©ã³ã«ãããªã³ã°å€ãããªã矀ããéžæ
ãããææ©ã«ãããªã³ã°å€ã (3) å°ãªããšãäžçš®é¡ã®èèªé žããã©ã«ãŽã³é ž
ã§ããèèªé žãšã®çž®åã«ãã€ãŠè£œé ãããéš
åçã«ã¢ããåãããããªã¢ã«ãã¬ã³ã¢ãã³
ã§ããããªã¢ããã¢ããéœã€ãªã³æ§æœ€æ»å€ã§
ããéœã€ãªã³æ§ç¹ç¶æœ€æ»å€ (4) åŒïŒ ãåŒäžãR1ãR2ãR3åã³R4ã®äžã€ä»¥äžã®éš
åãåããåã¯ç°ãªãã¢ã«ã³ãã·éšåã§ãã¡
ãã¬ã³åºãæããåã¯ã¡ãã¬ã³åºãæããã ïŒâRâ³OâïŒbRâ²âïŒo ïŒRâ²ã¯ã¡ãã¬ã³åºïŒCH2ïŒã§ãïœã¯ïŒã10å
ã¯ãã以äžã®æŽæ°ã§ãããRâ³ã¯ãšãã¬ã³åº
åã¯ãããã¬ã³åºåã¯ãããã®æ··åç©ã§ã
ããïœã¯ïŒã10åã¯ãã以äžã®æŽæ°ã§ããã
ã¯æ°ŽçŽ åã¯ïŒã10åã®ççŽ ååãæãã
äœçŽã¢ã«ãã«åºã§ããïŒã®åŠãæ«ç«¯ã¢ã«ã³ãŒ
ã«æ§åºãæããã¢ã«ã³ãã·éšåã§ããããšã
ã§ããåºR1ãR2ãR3åã³R4ã®åã€ãããã
ãªããã®ãã¢ã«ã³ãã·åºã§ãããæ®ãã®éã¢
ã«ã³ãã·åºR1ãR2ãR3åã³R4ã¯ïŒã30åã®
ççŽ ååãæããã¢ã«ãã«åºã§ãããX-ã¯
ã©ããªããã²ã³åç©ã€ãªã³ã§ãããïŒ ãæããéœã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第å
çŽã¢ã³ã¢ããŠã å¡©éé»é²æ¢å€ãåã³ åŒïŒ ïŒR5ïŒyâN+âïŒR6ïŒzX- ãåŒäžãR5㯠ïŒâRâ³OâïŒbRâ²aâ ïŒRâ²ã¯ã¡ãã¬ã³ïŒCH2ïŒã§ãããïœã¯ïŒãïŒ
ã®æŽæ°ã§ãããRâ³ã¯ãšãã¬ã³ã§ïœã¯ïŒãïŒ
ã®æŽæ°ã§ãããã¯æ°ŽçŽ åã¯ã¡ãã«åºã§ã
ãïŒã®åŠãåãã¢ã«ã³ãã·éšåã§ãããïœã¯
ïŒåã¯ïŒã®æŽæ°ã§ãããïœïŒïŒã®æãïœïŒïŒ
ã§ãããïœïŒïŒã®æãïœïŒïŒã§ãããR6ã¯
ïŒã25åã®ççŽ ååãæããé·éã¢ã«ãã«ã§
ãããX-ã¯Cl-åã¯Br-ã§ããããæããéœ
ã€ãªã³æ§ææ©ã¢ã«ã³ãã·ã«å第åçŽã¢ã³ã¢ã
ãŠã å¡©éé»é²æ¢å€ããããªã矀ããéžæãã
ããå°ãªããšã10ã®é žäŸ¡ãæããã¢ã«ã³ãã·
éšåãæããéœã€ãªã³æ§ç¬¬åçŽã¢ã³ã¢ããŠã
å¡©ã§ãæ°Žæ§ååŠçåŠççšçµæç©ã®çŽ0.05ãçŽ
0.04ééïŒ ã®ç¯å²ã®éã§ååšããéé»é²æ¢
å€ã (5) æ°Žæ§ååŠçåŠççšçµæç©ã®å šåºåœ¢ç©ãçŽïŒ
ãçŽ20ééïŒ ã®ç¯å²ã«ããéã§ååšããæ°Žã
ãããªããããåèšæ°Žæ§ååŠçåŠççšçµæç©
ããæ¬è³ªçã«ç¡æ©éé»é²æ¢å€ãå«ãŸããPHã
çŽïŒããå°ãããæŽã«ãã€ã«ã 圢æéåäœãš
çž®åæ¶æ©åå¿ãåããé䌞é·èªèµ·åå¿ç©æã
ã¯çž®åèªèµ·åå¿ç©ãæ¬è³ªçã«å«ãŸãªãã ããšãç¹åŸŽãšããã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ãã
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74838885A | 1985-06-25 | 1985-06-25 | |
| US748389 | 1985-06-25 | ||
| US748388 | 1985-06-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6236048A JPS6236048A (ja) | 1987-02-17 |
| JPH057337B2 true JPH057337B2 (ja) | 1993-01-28 |
Family
ID=25009258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61149333A Granted JPS6236048A (ja) | 1985-06-25 | 1986-06-25 | éåäœææè£åŒ·çšã¬ã©ã¹ç¹ç¶ã¹ãã©ã³ã |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6236048A (ja) |
-
1986
- 1986-06-25 JP JP61149333A patent/JPS6236048A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6236048A (ja) | 1987-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4752527A (en) | Chemically treated glass fibers for reinforcing polymeric materials processes | |
| EP0206189B1 (en) | Chemically treated glass fibers for reinforcing polymeric materials and processes | |
| US4789593A (en) | Glass fibers with fast wettability and method of producing same | |
| US4518653A (en) | Chemically treated glass fibers for reinforcing polymeric materials and processes | |
| US5604270A (en) | Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers | |
| US5605757A (en) | Glass fiber sizing compositions, sized glass fibers and methods of reinforcing polymeric materials using the same | |
| US8129018B2 (en) | Sizing for high performance glass fibers and composite materials incorporating same | |
| US5219656A (en) | Chemically treated glass fibers for reinforcing polymeric materials | |
| US4330444A (en) | Sizing composition and sized fibers with increased hardness | |
| US4104434A (en) | Sizing composition and glass fibers sized therewith | |
| CA1229267A (en) | Glass fibers to reinforce polymeric materials | |
| US4305742A (en) | Method of forming and sizing glass fibers | |
| EP0083057A1 (en) | Aqueous sized glass fibers for reinforcing thermosetting polymers | |
| US6139958A (en) | Chemically treated glass fibers for reinforcing thermosetting polymer matrices | |
| US4301052A (en) | Sizing composition and sized strand useful as reinforcement for reinforced molded composites having improved physical properties | |
| JPH057337B2 (ja) | ||
| US3562081A (en) | Binder composition comprising an aqueous epoxy emulsion and process of making glass fiber products | |
| EP0220513B1 (en) | Stampable laminates of glass fiber reinforced poly(ethylene terephthalate) | |
| WO1994013473A1 (en) | Chemical treatment for glass fibers |