JPH0569084B2 - - Google Patents
Info
- Publication number
- JPH0569084B2 JPH0569084B2 JP61063393A JP6339386A JPH0569084B2 JP H0569084 B2 JPH0569084 B2 JP H0569084B2 JP 61063393 A JP61063393 A JP 61063393A JP 6339386 A JP6339386 A JP 6339386A JP H0569084 B2 JPH0569084 B2 JP H0569084B2
- Authority
- JP
- Japan
- Prior art keywords
- polyoxyethylene
- fatty acid
- acid ester
- pine surge
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 35
- 235000011613 Pinus brutia Nutrition 0.000 claims description 35
- 241000018646 Pinus brutia Species 0.000 claims description 35
- -1 fatty acid ester Chemical class 0.000 claims description 23
- 239000002537 cosmetic Substances 0.000 claims description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 229920002125 Sokalan® Polymers 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 239000006071 cream Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
発明の分野
本発明は、マツサージにより皮膚に適用するマ
ツサージクリームのようなマツサージ化粧料、さ
らに詳しくは、適用中にその伸び、すべりに顕著
な変化が生じ、それにより、適度なマツサージの
完了の目安を与えることのできるマツサージ化粧
料に関する。
発明の背景
従来から、種々のマツサージ化粧料が使用され
ているが、適度なマツサージの完了の目安を与え
るようなものは見当たらず、いずれも、使用者の
任意の判断によりマツサージ終了点が決められて
おり、必ずしも、充分なマツサージ効果が達成さ
れているとはいいがたい。また、マツサージ化粧
料は、その性能上、油分が多く、そのため、Ｏ／
Ｗ型乳化を行なうと油分の分離やゲル化を起こし
やすくなるという問題がある。
本発明者は、マツサージ化粧料におけるこれら
の問題を解消するため種々検討を重ねた。その結
果、カルボキシビニルポリマーと、特定のポリエ
チレングリコールおよび非イオン界面活性剤を配
合したＯ／Ｗ型乳化系が、マツサージにより皮膚
に適用する間に、その伸び、すべりに顕著な変化
を生じ、これが適度なマツサージ完了の目安とな
ること、および非常に安定であることを見出し、
本発明を完成するにいたつた。
発明の開示
本発明は、カルボキシビニルポリマー、平均分
子量900〜25000のポリエチレングリコールおよび
HLB値13以上の非イオン界面活性剤を配合した
ことを特徴とするＯ／Ｗ型乳化系マツサージ化粧
料を提供するものである。一般に、この種の化粧
料の伸びおよびすべりは、油分の融点の調整や皮
膚に適用中の水分蒸発による転相などにより変化
するが、かかる伸びおよびすべりの変化は比較的
短時間のうちに生じ、その変化の度合も小さいた
め、マツサージの程度の目安にするには適さな
い。ところが、本発明の化粧料においては、皮膚
に適用してマツサージを行なう間に、非常に顕著
な伸びおよびすべりの変化が生じ、当初の伸びお
よびすべりがある時間マツサージを行うと極端に
よく伸びかつすべるようになり、これにより、適
度なマツサージの完了が分かり、マツサージの終
了点を適切に決定することができる。しかも、本
発明の化粧料はきわめてすぐれた保存安定性を有
している。
用いるカルボキシビニルポリマーは特に限定す
るものではなく、公知のいずれのものでもよく、
一般的に化粧品に用いられるトリエタノールアミ
ン、水酸化カリウムなどにより、適宜中和しても
よい。この中和の程度により、得られる化粧料の
伸び、すべりを調節することができる。カルボキ
シビニルポリマーは、一般に、組成物全量に基づ
いて0.05〜1.0重量％、好ましくは、0.1〜0.5重量
％の範囲で配合される。配合量が0.05重量％より
少ないと、伸びの変化が小さく、感知することが
困難となり、一方、1.0重量％を超えると使用感
が悪くなる。
ポリエチレングリコールは平均分子量900〜
25000、好ましくは、約3000〜8000のものを用い
る。平均分子量がこの範囲外であると、伸びの変
化を適確に感知することが困難となる。ポリエチ
レングリコールは組成物全量に基づいて、2.0〜
20.0重量％、好ましくは、３〜12重量％配合す
る。配合量がこの範囲外であると、乳化安定性が
悪くなる。
用いる非イオン界面活性剤はHLB値が13以上
であることが必要で、HLB値が13より低いと、
得られる化粧料の保存安定性が悪くなる。こと
に、ポリオキシエチレンソルビタン脂肪酸エステ
ル、ポリグリセリン脂肪酸エステル、ポリオキシ
エチレングリセリン脂肪酸エステル、ポリオキシ
エチレン脂肪酸エステル、ポリオキシエチレンア
ルキルエーテル、ポリオキシエチレンフイトステ
ロール、ポリオキシエチレンフイトスタノール、
ポリオキシエチレン硬化ヒマシ油、シヨ糖脂肪酸
エステルまたはこれらの混合物（エステルを形成
する脂肪酸としては、炭素数８〜20のもの、エチ
レンオキサイドの付加モル数は通常入手しうる範
囲のもの）が好ましいことが判明した。非イオン
界面活性剤は組成物全量に基づいて、1.5〜10重
量％配合される。この範囲外では保存安定性が悪
くなる。
本発明のマツサージ化粧料は、基本的に、これ
らの成分を配合したクリームのごときＯ／Ｗ型乳
化系の形態を有しており、必要に応じて、この種
の化粧料の配合成分として公知の油脂類、高級ア
ルコール類、防腐剤、香料、色素等を添加するこ
とができる。
本発明のマツサージ化粧料は、通常の乳化化粧
料製造技術に従つて製造することができる。例え
ば、精製水にカルボキシビニルポリマーを均一に
分散し、徐々に加熱し、ポリエチレングリコール
および非イオン界面活性剤を添加し、さらに、他
の水溶性成分を添加、混合して溶解する。これ
に、予め、加熱溶解した油性成分を添加し、乳化
を行なうことにより製造できる。
本発明のマツサージ化粧料は、保存安定性が非
常によく、マツサージにより皮膚に適用すると、
当初の伸び、すぺりがある時間マツサージすると
急激に当初よりもよく伸び、すべるようになり、
適度なマツサージが完了したことを示し、これに
よりマツサージの終了点を知ることができる。
つぎに実施例を挙げて本発明をさらに詳しく説
明するが、これらに限定されるものではない。
実施例 １〜４
以下の第１表に示す処方（第１表中の数値は重
量％を意味する）に従つて、マツサージクリーム
を製造した。
まず、カルボキシビニルポリマーを精製水に均
一に分散させ、ついで、ポリエチレングリコール
4000、防腐剤および非イオン界面活性剤を加え、
78〜82℃にて加熱、溶解した。これに、予め、78
〜82℃にて加熱、溶解した油性成分を加えて撹拌
混合し、さらに、トリエタノールアミンを加えて
混合した。ついで、冷却しながら香料を加え、所
望のマツサージクリームを得た。
Field of the Invention The present invention relates to pine surge cosmetics such as pine surge cream that are applied to the skin through pine surge, and more particularly, to a pine surge cosmetic that causes remarkable changes in its elongation and slippage during application, thereby providing an indication of the completion of moderate pine surge. Regarding pine surge cosmetics that can give. BACKGROUND OF THE INVENTION Various pine surge cosmetics have been used in the past, but none have been found that provide a guideline for the completion of appropriate pine surge. Therefore, it cannot be said that a sufficient pine surge effect is necessarily achieved. In addition, due to its performance, pine surge cosmetics have a high oil content, so O/
When W-type emulsification is performed, there is a problem in that oil separation and gelation tend to occur. The present inventor has conducted various studies in order to solve these problems in pine surge cosmetics. As a result, an O/W emulsion system containing carboxyvinyl polymer, specific polyethylene glycol, and a nonionic surfactant caused significant changes in its stretch and slippage when applied to the skin by pine surge. We found that it can be used as a guide for the completion of appropriate pine surge, and that it is very stable.
We have now completed the present invention. DISCLOSURE OF THE INVENTION The present invention comprises a carboxyvinyl polymer, a polyethylene glycol having an average molecular weight of 900 to 25,000, and
The present invention provides an O/W type emulsion type pine surge cosmetic, which is characterized by containing a nonionic surfactant having an HLB value of 13 or more. In general, the spread and slip of this type of cosmetic material changes by adjusting the melting point of the oil and phase inversion caused by water evaporation during application to the skin, but such changes in spread and slip occur in a relatively short period of time. , and the degree of change is small, so it is not suitable as a guideline for the degree of pine surge. However, in the cosmetic of the present invention, very noticeable changes in elongation and slippage occur during pine surge after application to the skin. This allows you to know when the pine surge is properly completed and to appropriately determine the end point of the pine surge. Moreover, the cosmetic composition of the present invention has extremely excellent storage stability. The carboxyvinyl polymer used is not particularly limited, and any known one may be used.
It may be appropriately neutralized with triethanolamine, potassium hydroxide, etc., which are commonly used in cosmetics. Depending on the degree of neutralization, the spreadability and slippage of the resulting cosmetic can be controlled. The carboxyvinyl polymer is generally included in an amount ranging from 0.05 to 1.0% by weight, preferably from 0.1 to 0.5% by weight, based on the total weight of the composition. If the amount is less than 0.05% by weight, the change in elongation will be small and difficult to detect, while if it exceeds 1.0% by weight, the feeling of use will be poor. Polyethylene glycol has an average molecular weight of 900~
25,000, preferably about 3,000 to 8,000. If the average molecular weight is outside this range, it will be difficult to accurately detect changes in elongation. Polyethylene glycol ranges from 2.0 to 2.0, based on the total amount of the composition.
20.0% by weight, preferably 3 to 12% by weight. If the blending amount is outside this range, emulsion stability will deteriorate. The nonionic surfactant used must have an HLB value of 13 or higher; if the HLB value is lower than 13,
The storage stability of the resulting cosmetic becomes poor. In particular, polyoxyethylene sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene phytosterol, polyoxyethylene phytostanol,
Polyoxyethylene hydrogenated castor oil, sucrose fatty acid ester, or a mixture thereof (the fatty acid that forms the ester has 8 to 20 carbon atoms, and the number of moles of ethylene oxide added is within the range that is normally available) is preferred. There was found. The nonionic surfactant is blended in an amount of 1.5 to 10% by weight based on the total amount of the composition. Outside this range, storage stability deteriorates. The pine surge cosmetic of the present invention basically has the form of an O/W type emulsion system such as a cream containing these ingredients, and if necessary, it may contain ingredients known as ingredients for this type of cosmetic. Oils and fats, higher alcohols, preservatives, fragrances, pigments, etc. can be added. The pine surge cosmetic composition of the present invention can be produced according to conventional emulsion cosmetic production techniques. For example, carboxyvinyl polymer is uniformly dispersed in purified water, heated gradually, polyethylene glycol and a nonionic surfactant are added, and other water-soluble components are added, mixed, and dissolved. It can be produced by adding an oily component that has been heated and dissolved in advance to this and emulsifying it. The pine surge cosmetic of the present invention has very good storage stability, and when applied to the skin by pine surge,
If you use pine surge for a period of time when the initial elongation and smoothness is achieved, it will suddenly become more elongated and slippery than before,
It indicates that a moderate amount of pine surge has been completed, and this allows us to know the end point of pine surge. Next, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto. Examples 1 to 4 Pine surge creams were manufactured according to the formulations shown in Table 1 below (numbers in Table 1 mean weight %). First, carboxyvinyl polymer is uniformly dispersed in purified water, and then polyethylene glycol
4000, added preservatives and nonionic surfactants,
It was heated and dissolved at 78-82°C. To this, in advance, 78
The mixture was heated at ~82° C., the dissolved oil component was added thereto, and mixed with stirring, and triethanolamine was further added and mixed. Then, while cooling, fragrance was added to obtain the desired pine surge cream.
【表】【table】
【表】
得られた実施例１のマツサージクリームおよび
市販のマツサージクリームのマツサージ中の伸
び、すべりの変化を20名のパネル員により評価さ
せた。また、同時に伸び、すべりの変化を感じた
パネル員については、その時点でのマツサージ効
果の度合についても評価させた。その結果を第２
表および第３表に示す。第２表および第３表中の
数値は該当する評価を示したパネル員の人数であ
る。[Table] Changes in elongation and slippage during pine surge of the obtained pine surge cream of Example 1 and commercially available pine surge cream were evaluated by 20 panel members. Additionally, panel members who felt changes in elongation and slippage at the same time were also asked to evaluate the degree of pine surge effect at that point. The result is the second
Shown in Table and Table 3. The numbers in Tables 2 and 3 are the number of panel members who gave the corresponding evaluation.
【表】【table】
【表】
第２表にすごとく、本発明のマツサージ化粧料
は、マツサージの過程できわめて明確な伸び、す
べりの変化を示し、また、第３表に示すごとく、
その伸び、すべりの変化が生じた時には十分なマ
ツサージ効果が得られていることがわかる。[Table] As shown in Table 2, the pine surge cosmetic of the present invention shows extremely clear changes in elongation and slippage during the pine surge process, and as shown in Table 3,
It can be seen that a sufficient pine surge effect is obtained when the elongation and slip change occur.
Claims (1)
リマー0.05〜1.0重量％、平均分子量900〜25000
のポリエチレングリコール2.0〜20.0重量％、お
よびHLB値13以上の非イオン界面活性剤1.5〜10
重量％を配合したことを特徴とするＯ／Ｗ型乳化
系マツサージ化粧料。 ２ 該非イオン界面活性剤が、ポリオキシエチレ
ンソルビタン脂肪酸エステル、ポリグリセリン脂
肪酸エステル、ポリオキシエチレングリセリン脂
肪酸エステル、ポリオキシエチレン脂肪酸エステ
ル、ポリオキシエチレンアルキルエーテル、ポリ
オキシエチレンフイトステロール、ポリオキシエ
チレンフイトスタノール、ポリオキシエチレン硬
化ヒマシ油、シヨ糖脂肪酸エステルまたはこれら
の混合物である特許請求の範囲第１項記載の化粧
料。[Claims] 1. Based on the total composition, carboxyvinyl polymer 0.05-1.0% by weight, average molecular weight 900-25000
of polyethylene glycol 2.0-20.0% by weight, and a nonionic surfactant with an HLB value of 13 or more 1.5-10
An O/W type emulsion type pine surge cosmetic characterized by containing % by weight. 2. The nonionic surfactant is polyoxyethylene sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene phytosterol, polyoxyethylene fluoride The cosmetic according to claim 1, which is isostanol, polyoxyethylene hydrogenated castor oil, sucrose fatty acid ester, or a mixture thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6339386A JPS62221610A (en) | 1986-03-19 | 1986-03-19 | Massage cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6339386A JPS62221610A (en) | 1986-03-19 | 1986-03-19 | Massage cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62221610A JPS62221610A (en) | 1987-09-29 |
| JPH0569084B2 true JPH0569084B2 (en) | 1993-09-30 |
Family
ID=13228016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6339386A Granted JPS62221610A (en) | 1986-03-19 | 1986-03-19 | Massage cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62221610A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3589514B2 (en) * | 1995-09-22 | 2004-11-17 | 株式会社ノエビア | Non-aqueous gel skin cleanser |
| JP3589513B2 (en) * | 1995-09-22 | 2004-11-17 | 株式会社ノエビア | Massage cosmetics |
| JP5137439B2 (en) | 2007-03-29 | 2013-02-06 | 株式会社 資生堂 | Oil-in-water emulsion composition |
| JP2012036103A (en) * | 2010-08-04 | 2012-02-23 | Toyo Aerosol Ind Co Ltd | Foam forming aerosol composition |
| JP2012036102A (en) * | 2010-08-04 | 2012-02-23 | Toyo Aerosol Ind Co Ltd | Oil-in-water type emulsion composition and aerosol composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035321A (en) * | 1973-07-24 | 1975-04-04 | ||
| JPS56154408A (en) * | 1980-04-30 | 1981-11-30 | Shiseido Co Ltd | Oil-in-water type emulsion composition |
| JPS61189210A (en) * | 1985-02-16 | 1986-08-22 | Shiseido Co Ltd | Emulsion cosmetic |
| JPS6242912A (en) * | 1985-08-19 | 1987-02-24 | Shiseido Co Ltd | Massage cosmetic |
-
1986
- 1986-03-19 JP JP6339386A patent/JPS62221610A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035321A (en) * | 1973-07-24 | 1975-04-04 | ||
| JPS56154408A (en) * | 1980-04-30 | 1981-11-30 | Shiseido Co Ltd | Oil-in-water type emulsion composition |
| JPS61189210A (en) * | 1985-02-16 | 1986-08-22 | Shiseido Co Ltd | Emulsion cosmetic |
| JPS6242912A (en) * | 1985-08-19 | 1987-02-24 | Shiseido Co Ltd | Massage cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62221610A (en) | 1987-09-29 |
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