JPH0564987B2 - - Google Patents
Info
- Publication number
- JPH0564987B2 JPH0564987B2 JP33463087A JP33463087A JPH0564987B2 JP H0564987 B2 JPH0564987 B2 JP H0564987B2 JP 33463087 A JP33463087 A JP 33463087A JP 33463087 A JP33463087 A JP 33463087A JP H0564987 B2 JPH0564987 B2 JP H0564987B2
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- chlorine
- lead
- parts
- containing resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 5
- 150000003752 zinc compounds Chemical class 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002681 magnesium compounds Chemical group 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- JQELBOVXJSYBGU-UHFFFAOYSA-N OP(O)O.OS(O)=O Chemical compound OP(O)O.OS(O)=O JQELBOVXJSYBGU-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229940071120 dehydroacetate Drugs 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- MFGZXPGKKJMZIY-UHFFFAOYSA-N ethyl 5-amino-1-(4-sulfamoylphenyl)pyrazole-4-carboxylate Chemical compound NC1=C(C(=O)OCC)C=NN1C1=CC=C(S(N)(=O)=O)C=C1 MFGZXPGKKJMZIY-UHFFFAOYSA-N 0.000 description 1
- -1 ethylene, propylene, methacrylic acid Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QRCJOCOSPZMDJY-UHFFFAOYSA-N valnoctamide Chemical compound CCC(C)C(CC)C(N)=O QRCJOCOSPZMDJY-UHFFFAOYSA-N 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- OWVLYQRCCIEOPF-QHTZZOMLSA-L zinc;(2s)-5-oxopyrrolidine-2-carboxylate Chemical compound [Zn+2].[O-]C(=O)[C@@H]1CCC(=O)N1.[O-]C(=O)[C@@H]1CCC(=O)N1 OWVLYQRCCIEOPF-QHTZZOMLSA-L 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- RYOLIMKPFQALMC-UHFFFAOYSA-L zinc;4-methylbenzoate Chemical compound [Zn+2].CC1=CC=C(C([O-])=O)C=C1.CC1=CC=C(C([O-])=O)C=C1 RYOLIMKPFQALMC-UHFFFAOYSA-L 0.000 description 1
- NUKJYCXSQCTWBK-UHFFFAOYSA-L zinc;8-methylnonanoate Chemical compound [Zn+2].CC(C)CCCCCCC([O-])=O.CC(C)CCCCCCC([O-])=O NUKJYCXSQCTWBK-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
［産業上の利用分野］
本発明は塩素含有樹脂組成物に関する。
［従来の技術］
従来、塩素含有樹脂中に無機鉛系安定剤と酸化
チタンが共存する場合、太陽光線や殺菌灯、水銀
灯、蛍光灯などの光に接すると短時間で黒変する
欠点を有していた。その理由は詳らかでないが、
酸化チタンの鉛による光還元反応によるものと考
えられる。
2TiO2＋Pb光
――→
Ti2O3＋PbO
［発明が解決しようとする問題点］
本発明者等は塩素含有樹脂中に無機鉛系安定剤
と酸化チタンが共存しても光によつて黒変せず、
且つ他の安定効果も損なわない塩素含有樹脂組成
物を提供することを目的とした。
［問題点を解決するための手段］
本発明は無機鉛系安定剤、酸化チタンを含有す
る塩素含有樹脂が光に接しても黒変しなくするた
め、更に亜鉛化合物を塩素含有樹脂に含有させる
ことにより、目的を達成し得ることを見出し本発
明を完成した。
本発明の塩素含有樹脂とは、塩化ビニル単独重
合体または塩化ビニルを主体とした樹脂であつ
て、例えば、塩化ビニルと、酢酸ビニル、塩化ビ
ニリデン、エチレン、プロピレン、メタアクリル
酸エステル、ウレタン樹脂との共重合体やグラフ
ト重合体あるいはこれら樹脂とのブレンド物、等
である。
無機鉛系安定剤とは、三塩基性硫酸鉛などの多
塩基性硫酸鉛、二塩基性亜硫酸鉛、二塩基性亜燐
酸鉛、二塩基性亜硫酸亜燐酸鉛、二塩基性フタル
酸鉛、二塩基性マレイン酸鉛、塩基性炭酸鉛等で
あり、通常は樹脂に対し、0.1〜10重量部含有さ
せる。
亜鉛化合物とはステアリン酸亜鉛、二塩基性ス
テアリン酸亜鉛、ラウリン酸亜鉛、パルミチン酸
亜鉛、ミリスチン酸亜鉛、イソデカン酸亜鉛、ピ
ロリドンカルボン酸亜鉛、安息香酸亜鉛、ｐ−ｔ
−ブチル安息香酸亜鉛、サルチル酸亜鉛、オレイ
ン酸亜鉛、ナフテン酸亜鉛、デヒドロ酢酸亜鉛、
ロジン酸亜鉛、ジブチルジチオカルバミン酸亜
鉛、トルイル酸亜鉛等であり通常は樹脂に対し、
0.01〜２重量部含有させる。更に好ましくは、亜
鉛化合物の一部をマグネシウム化合物に置き変え
ても、あるいは亜鉛化合物はそのままで更にマグ
ネシウム化合物を加えても、効果が発揮される。
酸化チタンは通常樹脂に対し、0.01〜10重量部含
有する。
上記の他に通常塩素含有樹脂に加えられる熱安
定剤、滑剤、可塑剤、酸化防止剤、紫外線吸収
剤、充填剤等を適宜添加して良いのは言うまでも
ない。
［発明の効果］
以上のように、本発明組成物によれば、光に接
しても変色せず、他の性質も悪化しないのであ
る。
以下実施例により具体的に説明する。
実施例
表−１に示す各組成物を180℃の８インチロー
ルで５分間混練し、シートを作成する。その後、
このシートを170℃、50Kg／cm2のプレス機で厚さ
約２mmのプレートを作成した。このプレートをサ
ンシヤインウエザーメータで100時間、300時間に
おける変色を調べ、元プレートと比較した。
熱安定性を見る為に混練シートを190℃のギア
ーオーブンで黒化する時間を調べた。
[Industrial Field of Application] The present invention relates to a chlorine-containing resin composition. [Prior art] Conventionally, when an inorganic lead-based stabilizer and titanium oxide coexist in a chlorine-containing resin, it has the disadvantage of turning black in a short time when exposed to sunlight, germicidal lamps, mercury lamps, fluorescent lamps, etc. Was. The reason is not clear, but
This is thought to be due to the photoreduction reaction of titanium oxide with lead. 2TiO 2 +Pb light---→ Ti 2 O 3 +PbO [Problems to be solved by the invention] The present inventors have discovered that even if an inorganic lead-based stabilizer and titanium oxide coexist in a chlorine-containing resin, they will be blackened by light. unchanged,
The object of the present invention is to provide a chlorine-containing resin composition that does not impair other stabilizing effects. [Means for solving the problem] The present invention further includes a zinc compound in the chlorine-containing resin to prevent the chlorine-containing resin containing an inorganic lead stabilizer and titanium oxide from turning black even when exposed to light. The present invention was completed by discovering that the object could be achieved by doing so. The chlorine-containing resin of the present invention is a vinyl chloride homopolymer or a resin mainly composed of vinyl chloride, and includes, for example, vinyl chloride, vinyl acetate, vinylidene chloride, ethylene, propylene, methacrylic acid ester, and urethane resin. These include copolymers, graft polymers, and blends with these resins. Inorganic lead stabilizers include polybasic lead sulfates such as tribasic lead sulfate, dibasic lead sulfite, dibasic lead phosphite, dibasic lead sulfite phosphite, dibasic lead phthalate, and dibasic lead sulfate. These include basic lead maleate and basic lead carbonate, and are usually contained in an amount of 0.1 to 10 parts by weight based on the resin. Zinc compounds include zinc stearate, dibasic zinc stearate, zinc laurate, zinc palmitate, zinc myristate, zinc isodecanoate, zinc pyrrolidone carboxylate, zinc benzoate, pt
- zinc butylbenzoate, zinc salicylate, zinc oleate, zinc naphthenate, zinc dehydroacetate,
Zinc rosinate, zinc dibutyldithiocarbamate, zinc toluate, etc., and are usually used for resins.
It is contained in an amount of 0.01 to 2 parts by weight. More preferably, the effect can be exhibited even if part of the zinc compound is replaced with a magnesium compound, or even if the zinc compound is left as is and a magnesium compound is added.
Titanium oxide is usually contained in an amount of 0.01 to 10 parts by weight based on the resin. It goes without saying that in addition to the above, thermal stabilizers, lubricants, plasticizers, antioxidants, ultraviolet absorbers, fillers, etc. which are usually added to chlorine-containing resins may be added as appropriate. [Effects of the Invention] As described above, the composition of the present invention does not change color even when exposed to light, and other properties do not deteriorate. This will be explained in detail below using examples. Examples Each composition shown in Table 1 was kneaded for 5 minutes using an 8-inch roll at 180°C to prepare a sheet. after that,
This sheet was pressed into a plate with a thickness of about 2 mm at 170° C. and a pressure of 50 kg/cm 2 . This plate was examined for discoloration after 100 hours and 300 hours using a sunshine weather meter and compared with the original plate. In order to examine thermal stability, the time required for the kneaded sheet to blacken in a gear oven at 190°C was examined.
【表】【table】
Claims (1)
剤0.1〜10重量部、酸化チタン0.01〜10重量部及
び亜鉛化合物0.01〜２重量部を含有する塩素含有
樹脂組成物。1. A chlorine-containing resin composition containing 0.1 to 10 parts by weight of an inorganic lead stabilizer, 0.01 to 10 parts by weight of titanium oxide, and 0.01 to 2 parts by weight of a zinc compound per 100 parts by weight of a chlorine-containing resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33463087A JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33463087A JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01174552A JPH01174552A (en) | 1989-07-11 |
| JPH0564987B2 true JPH0564987B2 (en) | 1993-09-16 |
Family
ID=18279526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33463087A Granted JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01174552A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2786532B2 (en) * | 1990-10-24 | 1998-08-13 | 堺化学工業株式会社 | Chlorine-containing resin composition |
| JP3385578B2 (en) * | 1998-08-03 | 2003-03-10 | アキレス株式会社 | Vinyl chloride resin film |
| JP4231976B2 (en) | 2000-03-30 | 2009-03-04 | 日本ゼオン株式会社 | Curable composition and multilayer circuit board |
-
1987
- 1987-12-28 JP JP33463087A patent/JPH01174552A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01174552A (en) | 1989-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0564987B2 (en) | ||
| JP2794465B2 (en) | Stabilized chlorine-containing resin composition | |
| JPH09208776A (en) | Vinyl chloride resin composition | |
| JP3465417B2 (en) | Flame-retardant resin composition and low-melting glass composition used therefor | |
| JP2501327B2 (en) | Stabilized hard chlorine-containing resin composition | |
| JP2939014B2 (en) | Stabilized halogen-containing resin composition | |
| JP4439917B2 (en) | Improved stability of aluminum hydroxide in PVC compounds | |
| JP3737242B2 (en) | Vinyl chloride resin composition for wire coating | |
| EP2907844B1 (en) | Resin composition for printing film and printing film | |
| CA1188087A (en) | Stabilizers for halogen containing polymers comprising alkyltin compounds, zinc mercaptoesters and basic alkaline earth metal compounds | |
| US4357434A (en) | Stabilized halogen-containing resin compositions | |
| JP2008081749A (en) | Composition of pvc and carbon monoxide-modified ethylene-vinyl ester copolymer having improved color stability | |
| DE2209022B2 (en) | Process for stabilizing halogen-containing polymers | |
| JP2981761B2 (en) | Stabilized chlorine-containing resin composition | |
| JP3511215B2 (en) | Vinyl chloride resin composition for wire coating | |
| JPH04161442A (en) | Chlorine-containing resin composition | |
| JPS6181462A (en) | Stabilizer for halogen-containing resin | |
| JPS60203657A (en) | Halogen-containing resin composition | |
| JP2005097394A (en) | Rigid vinyl chloride resin composition | |
| JPS59102943A (en) | Vinyl chloride resin composition | |
| JPH08100093A (en) | Vinyl chlorine resin composition | |
| DE69028533T2 (en) | Stabilized chlorinated resin composition | |
| JPH11129409A (en) | Weatherproof polyvinyl chloride resin-laminated film for building material | |
| JPS6247897B2 (en) | ||
| US4157329A (en) | Copper and cobalt carbonates as smoke suppressants for poly(vinyl halides) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |