JPH01174552A - Chlorine-containing resin composition - Google Patents
Chlorine-containing resin compositionInfo
- Publication number
- JPH01174552A JPH01174552A JP33463087A JP33463087A JPH01174552A JP H01174552 A JPH01174552 A JP H01174552A JP 33463087 A JP33463087 A JP 33463087A JP 33463087 A JP33463087 A JP 33463087A JP H01174552 A JPH01174552 A JP H01174552A
- Authority
- JP
- Japan
- Prior art keywords
- chlorine
- zinc
- containing resin
- lead
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000000460 chlorine Substances 0.000 title claims abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 13
- 239000011342 resin composition Substances 0.000 title claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 abstract description 12
- 229920005989 resin Polymers 0.000 abstract description 12
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 abstract description 2
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 238000002845 discoloration Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002681 magnesium compounds Chemical group 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- JQELBOVXJSYBGU-UHFFFAOYSA-N OP(O)O.OS(O)=O Chemical compound OP(O)O.OS(O)=O JQELBOVXJSYBGU-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229910009973 Ti2O3 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229940071120 dehydroacetate Drugs 0.000 description 1
- -1 ethylene, propylene, methacrylic acid Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- GQUJEMVIKWQAEH-UHFFFAOYSA-N titanium(III) oxide Chemical compound O=[Ti]O[Ti]=O GQUJEMVIKWQAEH-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QRCJOCOSPZMDJY-UHFFFAOYSA-N valnoctamide Chemical compound CCC(C)C(CC)C(N)=O QRCJOCOSPZMDJY-UHFFFAOYSA-N 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- OWVLYQRCCIEOPF-QHTZZOMLSA-L zinc;(2s)-5-oxopyrrolidine-2-carboxylate Chemical compound [Zn+2].[O-]C(=O)[C@@H]1CCC(=O)N1.[O-]C(=O)[C@@H]1CCC(=O)N1 OWVLYQRCCIEOPF-QHTZZOMLSA-L 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- RYOLIMKPFQALMC-UHFFFAOYSA-L zinc;4-methylbenzoate Chemical compound [Zn+2].CC1=CC=C(C([O-])=O)C=C1.CC1=CC=C(C([O-])=O)C=C1 RYOLIMKPFQALMC-UHFFFAOYSA-L 0.000 description 1
- NUKJYCXSQCTWBK-UHFFFAOYSA-L zinc;8-methylnonanoate Chemical compound [Zn+2].CC(C)CCCCCCC([O-])=O.CC(C)CCCCCCC([O-])=O NUKJYCXSQCTWBK-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は塩素含有樹脂組成物に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to chlorine-containing resin compositions.
［従来の技術］
従来、塩素含有樹脂中に無機鉛系安定剤と酸化チタンが
共存する場合、太陽光線や殺菌灯、水銀灯、蛍光灯など
の光に接すると短時間で黒変する欠点を有していた。そ
の理由は詳らかでないが、酸化チタンの鉛による光還元
反応によるものと考えられる。[Prior art] Conventionally, when an inorganic lead-based stabilizer and titanium oxide coexist in a chlorine-containing resin, it has the disadvantage of turning black in a short time when exposed to sunlight, germicidal lamps, mercury lamps, fluorescent lamps, etc. Was. The reason for this is not clear, but it is thought to be due to the photoreduction reaction of titanium oxide with lead.
２Ｔｉ（？２＋Ｐｂ二１→Ｔｉ２Ｏ３＋ＰｂＯ［発明が
解決しようとする問題点］
本発明者等は塩素含有樹脂中に無機鉛系安定剤と酸化チ
タンが共存しても光によって黒変せず、且つ他の安定効
果も損なわない塩素含有樹脂組成物を提供することを目
的とした。2Ti(?2+Pb21→Ti2O3+PbO [Problems to be Solved by the Invention] The present inventors have discovered that even if an inorganic lead-based stabilizer and titanium oxide coexist in a chlorine-containing resin, it will not turn black due to light, and other The object of the present invention is to provide a chlorine-containing resin composition that does not impair the stabilizing effect of the chlorine-containing resin composition.
［問題点を解決するための手段］
本発明は無機鉛系安定剤、酸化チタンを含有する塩素含
有樹脂が光に接しても黒変しなくするため、更に亜鉛化
合物を塩素含有樹脂に含有させることにより、目的を達
成し得ることを見出し本発明を完成した。[Means for solving the problem] The present invention further includes a zinc compound in the chlorine-containing resin to prevent the chlorine-containing resin containing an inorganic lead stabilizer and titanium oxide from turning black even when exposed to light. The present invention was completed by discovering that the object could be achieved by doing so.
本発明の塩素含有樹脂とは、塩化ビニル単独重合体また
は塩化ビニルを主体とした樹脂であって、例えば、塩化
ビニルと、酢酸ビニル、塩化ビニリデン、エチレン、プ
ロピレン、メタアクリル酸エステル、ウレタン樹脂との
共重合体やグラフト重合体あるいはこれら樹脂とのブレ
ンド物、等である。The chlorine-containing resin of the present invention is a vinyl chloride homopolymer or a resin mainly composed of vinyl chloride, and includes, for example, vinyl chloride, vinyl acetate, vinylidene chloride, ethylene, propylene, methacrylic acid ester, and urethane resin. These include copolymers, graft polymers, and blends with these resins.
無機鉛系安定剤とは、三塩基性硫酸鉛などの多塩基性硫
酸鉛、二塩基性亜硫酸鉛、二塩基性亜燐酸鉛、二塩基性
亜硫酸亜燐酸鉛、二塩基性フタル酸鉛、二塩基性マレイ
ン酸鉛、塩基性炭酸鉛等であり、通常は樹脂に対し、０
．１−１０重量部含有させる。Inorganic lead stabilizers include polybasic lead sulfates such as tribasic lead sulfate, dibasic lead sulfite, dibasic lead phosphite, dibasic lead sulfite phosphite, dibasic lead phthalate, and dibasic lead sulfate. Basic lead maleate, basic lead carbonate, etc., and are usually 0% for resin.
．． Contain 1-10 parts by weight.
亜鉛化合物とはステアリン酸亜鉛、二塩基性ステアリン
酸亜鉛、ラウリン酸亜鉛、パルミチン酸亜鉛、ミリスチ
ン酸亜鉛、イソデカン酸亜鉛、ピロリドンカルボン酸亜
鉛、安息香酸亜鉛、ｐ−ｔ−ブチル安息香酸亜鉛、サル
チル酸亜鉛、オレイン酸亜鉛、ナフテン酸亜鉛、デヒド
ロ酢酸亜鉛、ロジン酸亜鉛、ジブチルジチオカルバミン
酸亜鉛、トルイル酸亜鉛等であり通常は樹脂に対し、０
．０１〜２重量部含有させる。更に好ましくは、亜鉛化
合物の一部をマグネシウム化合物に置き変えても、ある
いは亜鉛化合物はそのままで更にマグネシウム化合物を
加えても、効果が発揮される。酸化チタンは通常樹脂に
対し、０．０１〜１０重量部含有する。Zinc compounds include zinc stearate, dibasic zinc stearate, zinc laurate, zinc palmitate, zinc myristate, zinc isodecanoate, zinc pyrrolidone carboxylate, zinc benzoate, zinc pt-butylbenzoate, and salutyl. Zinc acid, zinc oleate, zinc naphthenate, zinc dehydroacetate, zinc rosinate, zinc dibutyldithiocarbamate, zinc toluate, etc., and usually 0% for the resin.
．． 01 to 2 parts by weight. More preferably, the effect can be exhibited even if part of the zinc compound is replaced with a magnesium compound, or even if the zinc compound is left as is and a magnesium compound is added. Titanium oxide is usually contained in an amount of 0.01 to 10 parts by weight based on the resin.
上記の他に通常塩素含有樹脂に加えられる熱安定剤、滑
剤、可塑剤、酸イビ防止剤、紫外線吸収剤、充填剤等を
適宜添加して良いのは言うまでもない。It goes without saying that in addition to the above, heat stabilizers, lubricants, plasticizers, acid corrosion inhibitors, ultraviolet absorbers, fillers, etc. which are usually added to chlorine-containing resins may be added as appropriate.
［発明の効果］
以上のように、本発明組成物によれば、光に接しても変
色せず、他の性質も悪化しないのである。[Effects of the Invention] As described above, the composition of the present invention does not change color even when exposed to light, and other properties do not deteriorate.
以下実施例により具体的に説明する。This will be explained in detail below using examples.
チロールで５分間混練し、シートを作成する。Knead with Tyrol for 5 minutes to create a sheet.
その後、このシートを１７０℃、５０ｋｇ／ａｎ２のプ
レス機で厚さ約２ｍｍのプレートを作成した。このプレ
ートをサンシャインウェザ−メータで１００時間、３０
０時間における変色を調べ、元プレートと比較した。Thereafter, a plate having a thickness of about 2 mm was produced from this sheet using a press machine at 170° C. and 50 kg/an2. This plate was tested with a sunshine weather meter for 100 hours and 30 hours.
The color change at 0 hours was examined and compared with the original plate.
熱安定性を見る為に混練シートを１００℃のギアーオー
ブンで黒化する時間を調べた。In order to examine thermal stability, the time required for the kneaded sheet to blacken in a gear oven at 100°C was examined.
Claims (1)
、塩素含有樹脂組成物。A chlorine-containing resin composition containing an inorganic lead-based stabilizer, titanium oxide, and a zinc compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33463087A JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33463087A JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01174552A true JPH01174552A (en) | 1989-07-11 |
| JPH0564987B2 JPH0564987B2 (en) | 1993-09-16 |
Family
ID=18279526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33463087A Granted JPH01174552A (en) | 1987-12-28 | 1987-12-28 | Chlorine-containing resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01174552A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04161442A (en) * | 1990-10-24 | 1992-06-04 | Sakai Chem Ind Co Ltd | Chlorine-containing resin composition |
| JP2000044751A (en) * | 1998-08-03 | 2000-02-15 | Achilles Corp | Vinyl chloride resin film |
| US6955848B2 (en) | 2000-03-30 | 2005-10-18 | Zeon Corporation | Curable composition and multilayered circuit substrate |
-
1987
- 1987-12-28 JP JP33463087A patent/JPH01174552A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04161442A (en) * | 1990-10-24 | 1992-06-04 | Sakai Chem Ind Co Ltd | Chlorine-containing resin composition |
| JP2000044751A (en) * | 1998-08-03 | 2000-02-15 | Achilles Corp | Vinyl chloride resin film |
| US6955848B2 (en) | 2000-03-30 | 2005-10-18 | Zeon Corporation | Curable composition and multilayered circuit substrate |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0564987B2 (en) | 1993-09-16 |
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