JPH0560443B2 - - Google Patents
Info
- Publication number
- JPH0560443B2 JPH0560443B2 JP60152056A JP15205685A JPH0560443B2 JP H0560443 B2 JPH0560443 B2 JP H0560443B2 JP 60152056 A JP60152056 A JP 60152056A JP 15205685 A JP15205685 A JP 15205685A JP H0560443 B2 JPH0560443 B2 JP H0560443B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- hair dye
- alkali metal
- dye
- agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000118 hair dye Substances 0.000 claims description 15
- 239000007800 oxidant agent Substances 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- -1 alkali metal salt Chemical class 0.000 claims description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 6
- 238000006467 substitution reaction Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 229920001206 natural gum Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KBTJYNAFUYTSNN-UHFFFAOYSA-N [Na].OO Chemical compound [Na].OO KBTJYNAFUYTSNN-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical class OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
（産業上の利用分野）
本発明は高置換度カルボキシメチルセルロース
のアルカリ金属塩を増粘剤に用いた酸化剤を含有
する染毛料に関する。
（従来の技術及びその問題点）
従来から染毛料の増粘剤としてセルロール系ビ
ニル系、アクリル系が用いられ、最近では天然ガ
ム類例えばキサンタンガム、タラカンドガムなど
が特開昭59−108710に記載されている。しかし前
者例えばセルロース系の場合、染毛料に含有され
る酸化剤やアルカリ剤のため染毛料糊液の粘度安
定性に問題があり且つ染毛処理後の毛髪の光沢低
下するなど難点があつた。またビニル系、アクリ
ル系では未重合の単量体、触媒の残査成分などに
起因する臭気並びにアルカリ剤添加による著しい
増粘現象などにより衛生面や染毛糊液の粘度安定
性に問題がある。
更に天然ガム類は天然品のため産地による品質
上の問題で染毛糊液の粘度安定性不足及び染毛処
理後の毛髪の光沢維持に難点があり、その上コス
ト的にも高い。
（問題点の解決手段）
本発明らは前述の難点を解消すべく鋭意検討の
結果セルロース系の一種である高置換度カルボキ
シメチルセルロールのアルカリ金属塩は染毛料に
配合される酸化剤やアルカリ剤に対して極めて安
定で特に酸化剤に対して、粘度低下が少なく変褪
色しないなどの格別に優れた安定性を発現するこ
とを発見し本発明を完成するに到つた。
（発明の構成）
本発明は置換度2.0以上のカルボキシメチルセ
ルロースのアルカリ金属塩に酸化剤を含有する染
毛料である。置換度2.0〜3.0好ましくは2.2〜3.0
である。ここでアルカリ金属塩はナトリウム、カ
リウム、リチウム、ルビジウム、セシウムなどが
挙げられるがコスト的にナトリウムが好ましく使
用される。
また酸化剤は特に限定されないが過酸化水素過
ホウ酸ナトリウム、過酸化尿素、過炭素ナトリウ
ム、過酸化トリポリリン酸ナトリウム、過酸化ピ
ロリン酸ナトリウム、過酸化オルソリン酸ナトリ
ウム、臭気酸アルカリ金属塩などが挙げられ通常
は過酸化水素が使用される。
本発明の染毛料を使用する場合染毛料中に酸化
剤１〜10重量％、高置換度カルボキシメチルセル
ロースのアルカリ金属塩を0.05〜５重量％となる
様に配合し、一般的には高濃度の水溶液として調
整し、実用時適量の水で希釈して使用することが
多い。また本発明の染毛料には酸化染料の他に本
発明の効果を損なわない範囲で界面活性剤、溶
媒、アルカリ剤、酸化防止剤金属イオン封鎖剤、
カチオン性高分子化合物、湿潤剤、香料などの任
意の成分を添加配合できる。
酸化染料は毛髪の内部層に浸透し、酸化されて
不溶性色素となり染着するもので毛髪の漂白も兼
ねており、具体的にはパラフエニレンジアミンま
たはその塩酸塩、硫酸塩、パラアミノフエノー
ル、パラトルエンジアミン、オルトフエニレンジ
アミンまたはその塩酸塩、硫酸塩、オルトアミノ
フエノール、メタアミノフエノール、メタフエニ
レンジアミンまたはその塩酸塩、硫酸塩などを挙
げることが出来る。
界面活性剤はアニオン、カチオン、両性イオン
及び非イオン界面活性剤を挙げることが出来る。
溶媒はアルコール類例えばエチルアルコール、イ
ソプロピルアルコール、プロピレングリコール、
グリセリンなどが挙げられる。アルカリ剤として
はアンモニア、アミン類などが使用される。以下
に本発明の実施例を示す。尚％は重量基準であ
る。
（実施例）
実施例 １
Ｉ
(1) パラフエニレンジアミン ２％
(2) レゾルミン 0.5
(3) オレイン酸 19.5
(4) ポリオキシエチレン（10モル）オレイルアル
コールエーテル ５
(5) イソプロピルアルコール 10
(6) アンモニア水（28％） 10
(7) 水 53
(8) カチオン化セルロース（ポリマーJR400UCC
社製） 0.5
(9) 増粘剤（第１表に記載） 0.25
(10) 増粘剤（第１表に記載） 0.25
(11) 過酸化水素水（30％） 20
(12) 水 69
(13) リン酸（PH調整用） ……PH3.5
前記Ｉの(7)に(1)，(2)，(3)，(4)，(5)，(6)及び(8)
，
(9)を添加混合し、均一な分散液を調整後濾過す
る。これにの(12)に(10)，(11)及び(13)を添加混合
した均一な溶液を混合しこの一部を使用して毛髪
を染毛した結果、染毛作業時の混合毛染糊料のタ
レは全くなく、Ｉ及びの混合液は45℃、６ケ月
間放置しても粘度の経時変化や褪色などの現象は
殆んど認められなかつた。更に染毛された毛髪の
光沢は極めて良好で長期間（通常２〜３ケ月間）
にわたつて着色糊料の脱落は認められなかつた。
(Industrial Application Field) The present invention relates to a hair dye containing an oxidizing agent using an alkali metal salt of highly substituted carboxymethyl cellulose as a thickener. (Prior art and its problems) Cellulose vinyl and acrylic thickeners have traditionally been used as thickeners for hair dyes, and recently natural gums such as xanthan gum and taracand gum have been described in JP-A-59-108710. There is. However, in the case of the former, for example, a cellulose-based hair dye, there are problems in the viscosity stability of the hair dye paste due to the oxidizing agent and alkaline agent contained in the hair dye, and there are disadvantages such as a decrease in the gloss of the hair after the hair dyeing process. In addition, vinyl and acrylic types have problems in terms of hygiene and viscosity stability of the hair dye paste due to odor caused by unpolymerized monomers and residual components of the catalyst, as well as significant thickening phenomenon due to the addition of alkaline agents. . Furthermore, since natural gums are natural products, there are quality problems depending on the production area, such as insufficient viscosity stability of the hair dye paste and difficulty in maintaining the gloss of hair after hair dyeing treatment, and in addition, they are expensive. (Means for Solving the Problems) In order to solve the above-mentioned problems, the present inventors have made intensive studies and found that the alkali metal salts of highly substituted carboxymethyl cellulose, which is a type of cellulose, are suitable for use as oxidizing agents and alkali metals in hair dyes. The inventors have now completed the present invention by discovering that they are extremely stable against oxidizing agents, exhibiting exceptional stability such as little viscosity drop and no discoloration, especially against oxidizing agents. (Structure of the Invention) The present invention is a hair dye containing an oxidizing agent in an alkali metal salt of carboxymethylcellulose having a degree of substitution of 2.0 or more. Degree of substitution 2.0-3.0 preferably 2.2-3.0
It is. Examples of the alkali metal salt include sodium, potassium, lithium, rubidium, and cesium, but sodium is preferably used from the viewpoint of cost. The oxidizing agent is not particularly limited, but examples include sodium hydrogen peroxide perborate, urea peroxide, sodium percarbonate, sodium peroxide tripolyphosphate, sodium peroxide pyrophosphate, sodium peroxide orthophosphate, and alkali metal salts of bromic acid. hydrogen peroxide is usually used. When using the hair dye of the present invention, 1 to 10% by weight of an oxidizing agent and 0.05 to 5% by weight of an alkali metal salt of highly substituted carboxymethyl cellulose are blended into the hair dye. It is often prepared as an aqueous solution and diluted with an appropriate amount of water for practical use. In addition to the oxidation dye, the hair dye of the present invention includes surfactants, solvents, alkali agents, antioxidants, sequestering agents, and other substances within the range that does not impair the effects of the present invention.
Any components such as a cationic polymer compound, wetting agent, fragrance, etc. can be added and blended. Oxidation dyes penetrate into the inner layer of the hair and are oxidized to become insoluble pigments and dye the hair, and also serve as bleaching agents. Examples include toluenediamine, orthophenylenediamine or its hydrochloride, sulfate, ortho-aminophenol, meta-aminophenol, metaphenylenediamine or its hydrochloride and sulfate. Surfactants may include anionic, cationic, zwitterionic and nonionic surfactants.
The solvent is an alcohol such as ethyl alcohol, isopropyl alcohol, propylene glycol,
Examples include glycerin. Ammonia, amines, etc. are used as the alkaline agent. Examples of the present invention are shown below. Note that percentages are based on weight. (Example) Example 1 I (1) Paraphenylenediamine 2% (2) Resolmin 0.5 (3) Oleic acid 19.5 (4) Polyoxyethylene (10 mol) Oleyl alcohol ether 5 (5) Isopropyl alcohol 10 (6) ) Ammonia water (28%) 10 (7) Water 53 (8) Cationized cellulose (Polymer JR400UCC
) 0.5 (9) Thickener (listed in Table 1) 0.25 (10) Thickener (listed in Table 1) 0.25 (11) Hydrogen peroxide solution (30%) 20 (12) Water 69 ( 13) Phosphoric acid (for pH adjustment)...PH3.5 Add (1), (2), (3), (4), (5), (6) and (8) to (7) in I above.
，
(9) is added and mixed to prepare a uniform dispersion, and then filtered. As a result of mixing a homogeneous solution of (12) with (10), (11), and (13) and using a part of this to dye hair, the mixed hair dye during hair dyeing work was There was no sagging of the paste, and even when the mixture of I and I was left at 45°C for 6 months, almost no changes in viscosity over time or fading of color were observed. Furthermore, the luster of dyed hair is extremely good and lasts for a long time (usually 2 to 3 months).
No shedding of the colored paste was observed over the course of the test.
【表】
比較例 １
実施例１で増粘剤に第２表の増粘剤を用いた場
合はＩとの混合液の染毛作業時のタレが著しく
またＩ及びの単独の混合液の放置安定性（45
℃）は１週間で粘度は著しく低下し実用に供し得
なかつた。
（作用効果）
本発明の染毛料は経日粘度安定性に優れ、また
毛染作業時のタレ防止に極めて格別の効果があ
り、且つ長期間にわたつて染毛仕上げ後の毛髪の
変褪色、糊料の脱落がなく、その上光沢維持にも
優れたものである。これは主に増粘剤として使用
されている置換度2.0以上のカルボキシメチルセ
ルロースのアルカリ金属塩の酸化剤及びアルカリ
剤に対する水系における抵抗安定性に起因してい
るものと考察される。[Table] Comparative Example 1 When the thickeners listed in Table 2 were used as the thickeners in Example 1, the mixture of I and I sagged significantly during hair dyeing, and the mixture of I and I alone was left unattended. Stability (45
℃), the viscosity decreased significantly in one week and it could not be put to practical use. (Function and effect) The hair dye of the present invention has excellent viscosity stability over time, is extremely effective in preventing sagging during hair dyeing work, and is effective in preventing discoloration and fading of hair after dyeing over a long period of time. The glue does not fall off, and it also maintains excellent gloss. This is considered to be mainly due to the resistance stability of the alkali metal salt of carboxymethyl cellulose with a degree of substitution of 2.0 or more used as a thickener in an aqueous system against oxidizing agents and alkaline agents.
Claims (1)
セルロースのアルカリ金属塩並びに酸化剤を含有
する染毛料用酸化液。1. An oxidizing liquid for hair dye containing an alkali metal salt of highly substituted carboxymethyl cellulose with a degree of substitution of 2.0 or more and an oxidizing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60152056A JPS6212714A (en) | 1985-07-10 | 1985-07-10 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60152056A JPS6212714A (en) | 1985-07-10 | 1985-07-10 | Hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6212714A JPS6212714A (en) | 1987-01-21 |
| JPH0560443B2 true JPH0560443B2 (en) | 1993-09-02 |
Family
ID=15532081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60152056A Granted JPS6212714A (en) | 1985-07-10 | 1985-07-10 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6212714A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0669945B2 (en) * | 1989-07-18 | 1994-09-07 | 日華化学株式会社 | Hair dyeing composition |
| JP2009173574A (en) * | 2008-01-24 | 2009-08-06 | Masahiro Yanagida | Hair treatment agent and method for beauty treatment using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59108045A (en) * | 1982-12-11 | 1984-06-22 | Daicel Chem Ind Ltd | Carboxymethylcellulose gel composition and its production |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57171110U (en) * | 1981-04-22 | 1982-10-28 | ||
| JPS59110317U (en) * | 1983-01-14 | 1984-07-25 | マツダ株式会社 | engine oil separator |
-
1985
- 1985-07-10 JP JP60152056A patent/JPS6212714A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59108045A (en) * | 1982-12-11 | 1984-06-22 | Daicel Chem Ind Ltd | Carboxymethylcellulose gel composition and its production |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6212714A (en) | 1987-01-21 |
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