JPH0558060B2 - - Google Patents
Info
- Publication number
- JPH0558060B2 JPH0558060B2 JP23073185A JP23073185A JPH0558060B2 JP H0558060 B2 JPH0558060 B2 JP H0558060B2 JP 23073185 A JP23073185 A JP 23073185A JP 23073185 A JP23073185 A JP 23073185A JP H0558060 B2 JPH0558060 B2 JP H0558060B2
- Authority
- JP
- Japan
- Prior art keywords
- vapor
- lacquer
- matte
- deposited
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004922 lacquer Substances 0.000 claims description 35
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 13
- 235000011613 Pinus brutia Nutrition 0.000 claims description 13
- 241000018646 Pinus brutia Species 0.000 claims description 13
- 229920006026 co-polymeric resin Polymers 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000001023 inorganic pigment Substances 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims description 4
- 229920001986 Vinylidene chloride-vinyl chloride copolymer Polymers 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- PCPYTNCQOSFKGG-UHFFFAOYSA-N 1-chlorobuta-1,3-diene Chemical compound ClC=CC=C PCPYTNCQOSFKGG-UHFFFAOYSA-N 0.000 claims 1
- UPZFLZYXYGBAPL-UHFFFAOYSA-N 2-ethyl-2-methyl-1,3-dioxolane Chemical compound CCC1(C)OCCO1 UPZFLZYXYGBAPL-UHFFFAOYSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 23
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 239000011888 foil Substances 0.000 description 7
- 239000005022 packaging material Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000002932 luster Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/08—Metal coatings applied as vapour, e.g. in vacuum
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
- Paper (AREA)
Description
（産業上の利用分野）
本発明はつや消し蒸着シートに関するものであ
り、本発明により得られるつや消し蒸着シートは
包装材などに利用されるものである。
（従来技術）
従来、包装材特にたばこ用包装材として、アル
ミ箔はり合せ紙が防湿性、保香性にすぐれ、かつ
金属特有の色彩的効果による高級感を有する包装
材として用いられていた。しかし、近年の蒸着加
工技術の進歩により、防湿性や美観性など包装材
として要求される特性がアルミ箔はり合せ紙に近
いアルミ蒸着紙が開発され、たばこ用包装材とし
て利用されている。
ところが、これらの蒸着紙は、紙に塗工層（下
塗りラツカー層）を、次いで、その上に金属蒸着
層を形成しているので強い金属光沢を有し、従来
のつや消しアルミ箔はり合せ紙のもつつやの消え
た高級感のある金属光沢とは異なつた外観を呈す
るために、金属光沢の弱いつや消し蒸着紙が求め
られている。
（発明が解決すべき問題点）
金属光沢の弱いつや消し蒸着紙は、紙に下塗り
ラツカー層を形成させることなく、直接金属蒸着
層を設けることにより得られるが、この方法で得
られたつや消し蒸着紙は、下塗りラツカー層を欠
くために、防湿性が著しく低下するとともに、外
観がつやの消えた金属光沢ではなく、黒ずんだ色
合いとなる欠点を有している。
本発明者らは、アルミ箔はり合せ紙より安価で
あり、防湿性などの包装材料としての特性をもつ
とともに外観的にはつや消し蒸着面を有するつや
消し蒸着シートを提供するものである。
（問題を解決するための手段）
本発明のつや消し蒸着シートは、基材上に設け
られた金属蒸着層の上面または下面に、無機顔料
の微粉末を分散させたラツカーにマツトラツカー
層を形成させるものである。
本発明で用いられる基材としては、紙が主とし
て用いられるが、このほかプラスチツクフイルム
なども使用することができる。
マツトラツカー層を形成するために用いられる
ラツカーとしては、塩化ビニル−酢酸ビニル共重
合樹脂系、塩化ビニリデン−塩化ビニル共重合樹
脂系およびエチレン−酢酸ビニル−塩化ビニル共
重合樹脂系の１種または２種以上の共重合樹脂よ
りなるものがあげられる。これら共重合樹脂はラ
ツカー用あるいは塗料用として用いられるもの
で、その重合度や重合比率は目的に応じて任意に
選択することができ、また、各共重合樹脂系は目
的に応じて単独であるいは混合して使用すること
ができる。
さらにこれらの共重合樹脂に添加される無機顔
料としては炭酸カルシウム、酸化チタン、酸化ア
ルミニウム、フライアツシユ、カーボンブラツク
などの微粉末が用いられるが、アルミ箔はり合せ
紙のつや消し面とほぼ同程度の外観を有し、か
つ、防湿性にもすぐれた効果を得るためには炭酸
カルシウムの使用が好適である。これら無機顔料
微粉末の粒度は50μ以下のものが好ましく、その
形状は何れでもよい。添加量はラツカー中の固形
分に対して10〜30％添加するのが最もすぐれた効
果を有する。
本発明で用いる無機顔料微粉末はラツカー中で
分散処理されることにより粒子表面には樹脂や溶
剤等が吸着されてコロイド状となり、溶剤との親
和性もよく、均一に分散されて安定性も良好であ
り、塗工にさいしても均一に塗工され、得られる
ラツカー乾燥被膜（マツトラツカー層）は柔軟性
を有した半透明被膜であり、必要に応じて着色あ
るいは印刷することもできる。
本発明のつや消し蒸着シートは、(i)共重合樹脂
溶液に無機顔料の微粉末を分散させてなるラツカ
ーを紙、プラスチツクフイルムなどの基材上に下
塗りラツカーとして塗工したマツトラツカー層を
形成し、その上に金属蒸着層を形成させることに
より、(ii)基材上に従来の下塗りラツカー層を形成
した上に金属蒸着層を形成し、その上に上塗りラ
ツカーとしてマツトラツカー層を形成させること
により、(iii)基材上に下塗りラツカーとして塗工し
たマツトラツカー層を形成し、その上に金属蒸着
層、マツトラツカー層を順次形成させることによ
り得ることができる。
（発明の効果）
本発明のつや消し蒸着シートは、基材上に設け
られる金属蒸着層の上面及び／又は下面に、無機
顔料の微粉末を分散させたラツカーによるマツト
ラツカー層を形成させてなるもので、つや消し状
の外観を呈するとともに、すぐれた防湿性を有し
ている。また、マツトラツカー層は柔軟性を有す
るので、型付等の加工が容易で、それらの加工に
よつても防湿性は低下せず、さらに着色あるいは
印刷が可能である等の数多くの利点を有する。
（実施例）
以下の実施例により得られたつや消し蒸着紙の
透湿度および光沢度を測定し、これらをまとめて
表−１に記載する。なお、従来用いられている光
沢アルミ箔およびつや消しアルミ箔の透湿度およ
び光沢度も同一方法により測定し、これらも表−
１に示した。
実施例 １
基材として坪量54ｇ／m2の中質コート紙を用
い、塩化ビニル−酢酸ビニル共重合樹脂45、塩化
ビニリデン−塩化ビニル共重合樹脂41およびエチ
レン−酢酸ビニル−塩化ビニル共重合樹脂14の割
合（重量比）で混合した共重合樹脂18.4重量部
と、酢酸エチル36、メチルエチルケトン38および
トルエン26の割合（重量比）からなる混合溶媒77
重量部との樹脂溶液に50μ以下の炭酸カルシウム
4.6重量部（固形分に対して20％）を添加して調
製したマツトラツカーを、下塗りラツカーとして
約４ｇ／m2（乾燥塗膜）の厚さに塗工した後、そ
の表面に厚さ250〜350Åのアルミニウム蒸着層を
形成しつや消し蒸着シートを作製した。
実施例 ２
基材として実施例１と同じ中質コート紙を用
い、実施例１と同じ共重合樹脂20.7重量部及び混
合溶媒77重量部からなる樹脂溶液に50μ以下の炭
酸カルシウム2.3重量部（固形分に対して10％）
を添加して調製したマツトラツカーを、下塗りラ
ツカーとして約４ｇ／m2（乾燥塗膜）の厚さに塗
工し、その表面に厚さ250〜350Åのアルミニウム
蒸着層を形成しつや消し蒸着シートを作製した。
実施例 ３
基材として実施例１と同じ中質コート紙を用
い、実施例１と同じ共重合樹脂16重量部及び混合
溶媒77重量部からなる樹脂溶液に50μ以下の炭酸
カルシウム７重量部（固形分に対して25％）を添
加して調製したマツトラツカーを、下塗りラツカ
ーとして約４ｇ／m2（乾燥塗膜）の厚さに塗工
し、その表面に厚さ250〜350Åのアルミニウム蒸
着層を形成しつや消し蒸着シートを作製した。
実施例 ４
基材として実施例１と同じ中質コート紙を用
い、これに塩化ビニル−酢酸ビニル共重合樹脂下
塗りラツカーを約４ｇ／m2（乾燥塗膜）の厚さに
塗工し、その表面に厚さ250〜350Åのアルミ蒸着
層を形成した。更にその上に、実施例１と同様の
マツトラツカーを上塗りラツカーとして約1.0
ｇ／m2（乾燥塗膜）の厚さに塗工してつや消し蒸
着シートを作製した。
(Industrial Application Field) The present invention relates to a matte vapor-deposited sheet, and the matte vapor-deposited sheet obtained by the present invention is used for packaging materials and the like. (Prior Art) Conventionally, aluminum foil laminated paper has been used as a packaging material, particularly a cigarette packaging material, as a packaging material that has excellent moisture resistance and aroma retention properties, and has a luxurious feel due to the color effect unique to metal. However, with recent advances in vapor deposition technology, aluminum vapor-deposited paper has been developed that has properties required for packaging materials, such as moisture resistance and aesthetics, that are similar to those of aluminum foil-laminated paper, and it is now being used as a packaging material for cigarettes. However, since these metallized papers have a coating layer (undercoat lacquer layer) on the paper and then a metal vapor deposition layer on top of that, they have a strong metallic luster, which is different from the conventional matte aluminum foil laminated paper. There is a demand for matte vapor-deposited paper with a weak metallic luster in order to exhibit an appearance different from the luxurious metallic luster that has lost its luster. (Problems to be Solved by the Invention) Matte vapor-deposited paper with weak metallic luster can be obtained by directly providing a metal vapor-deposited layer without forming an undercoat lacquer layer on paper. Since it lacks an undercoat lacquer layer, it has the disadvantage that its moisture resistance is significantly reduced and its appearance is not a matte metallic luster but a dark hue. The present inventors provide a matte vapor-deposited sheet that is cheaper than aluminum foil laminated paper, has properties as a packaging material such as moisture resistance, and has a matte vapor-deposited surface in appearance. (Means for Solving the Problem) The matte vapor-deposited sheet of the present invention is one in which a pine lacquer layer is formed on the top or bottom surface of a metal vapor-deposited layer provided on a base material using a lacquer in which fine powder of an inorganic pigment is dispersed. It is. As the base material used in the present invention, paper is mainly used, but other materials such as plastic film can also be used. The lacquer used to form the pine lacquer layer is one or two of the following: vinyl chloride-vinyl acetate copolymer resin, vinylidene chloride-vinyl chloride copolymer resin, and ethylene-vinyl acetate-vinyl chloride copolymer resin. Examples include those made of the above copolymer resins. These copolymer resins are used for lacquers or paints, and the degree of polymerization and polymerization ratio can be arbitrarily selected depending on the purpose. Each copolymer resin system can be used alone or in combination depending on the purpose. Can be used in combination. Furthermore, fine powders such as calcium carbonate, titanium oxide, aluminum oxide, fly ash, and carbon black are used as inorganic pigments added to these copolymer resins, but the appearance is almost the same as the matte surface of aluminum foil laminated paper. It is preferable to use calcium carbonate in order to obtain excellent moisture-proofing properties. The particle size of these inorganic pigment fine powders is preferably 50 μm or less, and any shape may be used. The best effect is obtained when the amount added is 10 to 30% based on the solid content in the lacquer. When the inorganic pigment fine powder used in the present invention is dispersed in a lacquer, resins, solvents, etc. are adsorbed to the particle surface, forming a colloid, which has good affinity with solvents, is uniformly dispersed, and has good stability. It has a good quality and can be applied uniformly during coating, and the resulting dry lacquer film (pine lacquer layer) is a flexible, translucent film that can be colored or printed if necessary. The matte vapor-deposited sheet of the present invention comprises: (i) forming a pine lacquer layer in which a lacquer made by dispersing fine powder of an inorganic pigment in a copolymer resin solution is coated as an undercoat lacquer on a substrate such as paper or plastic film; (ii) By forming a conventional undercoat lacquer layer on the base material, forming a metal vapor deposition layer thereon, and forming a pine lacquer layer as an overcoat lacquer thereon, (iii) It can be obtained by forming a pine lacquer layer coated as an undercoat lacquer on a base material, and sequentially forming a metal vapor deposited layer and a pine lacquer layer thereon. (Effects of the Invention) The matte vapor-deposited sheet of the present invention is formed by forming a pine lacquer layer made of a lacquer in which fine powder of an inorganic pigment is dispersed on the upper and/or lower surface of a metal vapor-deposited layer provided on a base material. It has a matte appearance and excellent moisture resistance. Furthermore, since the pine tracker layer has flexibility, it can be easily processed such as molding, the moisture resistance is not reduced by such processing, and it has many advantages such as being able to be colored or printed. (Example) The moisture permeability and glossiness of the matte vapor-deposited paper obtained in the following example were measured, and the results are summarized in Table 1. In addition, the moisture permeability and glossiness of conventionally used glossy aluminum foil and matte aluminum foil were also measured using the same method, and these are also shown in Table 1.
Shown in 1. Example 1 Medium-quality coated paper with a basis weight of 54 g/m 2 was used as the base material, and vinyl chloride-vinyl acetate copolymer resin 45, vinylidene chloride-vinyl chloride copolymer resin 41, and ethylene-vinyl acetate-vinyl chloride copolymer resin A mixed solvent 77 consisting of 18.4 parts by weight of a copolymer resin mixed at a ratio of 14 parts (weight ratio), 36 parts of ethyl acetate, 38 parts of methyl ethyl ketone, and 26 parts of toluene (by weight ratio)
Calcium carbonate less than 50μ in resin solution with parts by weight
After applying pine lacquer prepared by adding 4.6 parts by weight (20% based on solid content) as an undercoat lacquer to a thickness of approximately 4 g/m 2 (dry film), A matte vapor-deposited sheet was produced by forming a 350 Å aluminum vapor-deposited layer. Example 2 Using the same medium-quality coated paper as in Example 1 as the base material, 2.3 parts by weight of calcium carbonate (solid) of 50μ or less was added to a resin solution consisting of 20.7 parts by weight of the same copolymer resin as in Example 1 and 77 parts by weight of a mixed solvent. 10% for minutes)
A matte lacquer prepared by adding lacquer is applied as an undercoat lacquer to a thickness of approximately 4 g/m 2 (dry coating), and an aluminum evaporated layer with a thickness of 250 to 350 Å is formed on the surface to produce a matte evaporated sheet. did. Example 3 Using the same medium-quality coated paper as in Example 1 as the base material, 7 parts by weight of calcium carbonate (solid) of 50μ or less was added to a resin solution consisting of 16 parts by weight of the same copolymer resin as in Example 1 and 77 parts by weight of a mixed solvent. A pine lacquer prepared by adding 25% of the lacquer to the base coat was applied to a thickness of approximately 4 g/m 2 (dry coating), and an aluminum vapor-deposited layer with a thickness of 250 to 350 Å was applied to the surface. A matte vapor-deposited sheet was produced. Example 4 Using the same medium-quality coated paper as in Example 1 as the base material, a vinyl chloride-vinyl acetate copolymer resin undercoat lacquer was applied to a thickness of approximately 4 g/m 2 (dry coating). An aluminum vapor deposition layer with a thickness of 250 to 350 Å was formed on the surface. Furthermore, apply the same pine lacquer as in Example 1 as an overcoat lacquer of about 1.0
A matte vapor-deposited sheet was prepared by coating to a thickness of g/m 2 (dry coating).
【表】
表−１の結果より明らかなように、50μ以下の
炭酸カルシウムを10〜25％（固形分に対して）添
加したマツトラツカーを塗工した蒸着紙は透湿
度、光沢度ともにつや消しアルミ箔紙と同等の効
果を示す。[Table] As is clear from the results in Table 1, vapor-deposited paper coated with Matsutrazkar containing 10 to 25% (based on solid content) of calcium carbonate of 50μ or less has both moisture permeability and gloss compared to matte aluminum foil. Shows the same effect as paper.
Claims (1)
蒸着層を設けた蒸着シートにおいて、塩化ビニル
−酢酸ビニル共重合樹脂系、塩化ビニリデン−塩
化ビニル共重合樹脂系およびエチレン−酢酸ビニ
ル−塩化ビニル共重合樹脂系から選ばれる共重合
樹脂の１種または２種以上に無機顔料の微粉末を
分散させたラツカーによるマツトラツカー層を、
少なくとも金属蒸着層の上面または下面に形成せ
しめたことを特徴とするつや消し蒸着シート。 ２ 無機顔料が炭酸カルシウムである特許請求の
範囲第１項記載のつや消し蒸着シート。[Scope of Claims] 1. In a vapor-deposited sheet in which a metal vapor-deposited layer is provided on a base material such as paper or plastic film, vinyl chloride-vinyl acetate copolymer resin system, vinylidene chloride-vinyl chloride copolymer resin system, and ethylene-acetic acid A pine lacquer layer made of a lacquer in which fine powder of an inorganic pigment is dispersed in one or more copolymer resins selected from vinyl-vinyl chloride copolymer resins,
1. A matte vapor-deposited sheet, characterized in that it is formed on at least the upper or lower surface of a metal vapor-deposited layer. 2. The matte vapor-deposited sheet according to claim 1, wherein the inorganic pigment is calcium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23073185A JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23073185A JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6289860A JPS6289860A (en) | 1987-04-24 |
| JPH0558060B2 true JPH0558060B2 (en) | 1993-08-25 |
Family
ID=16912416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23073185A Granted JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6289860A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02190330A (en) * | 1989-01-19 | 1990-07-26 | Toppan Printing Co Ltd | Oxidized silver-like deposition sheet |
| JP2677092B2 (en) * | 1991-12-19 | 1997-11-17 | 凸版印刷株式会社 | Transfer foil |
| JP3159592B2 (en) * | 1993-07-23 | 2001-04-23 | ダイワ精工株式会社 | Article having a metal decoration layer |
| WO2006035901A1 (en) * | 2004-09-29 | 2006-04-06 | Dai Nippon Printing Co., Ltd. | Decorative sheet exhibiting low glossy metallic luster, and laminate comprising the same |
-
1985
- 1985-10-15 JP JP23073185A patent/JPS6289860A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6289860A (en) | 1987-04-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |