JPH0552863B2 - - Google Patents
Info
- Publication number
- JPH0552863B2 JPH0552863B2 JP14544885A JP14544885A JPH0552863B2 JP H0552863 B2 JPH0552863 B2 JP H0552863B2 JP 14544885 A JP14544885 A JP 14544885A JP 14544885 A JP14544885 A JP 14544885A JP H0552863 B2 JPH0552863 B2 JP H0552863B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- present
- hyaluronic acid
- ink composition
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 21
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 15
- 229920002674 hyaluronan Polymers 0.000 claims description 15
- 229960003160 hyaluronic acid Drugs 0.000 claims description 15
- 239000003086 colorant Substances 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- 239000000976 ink Substances 0.000 description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- -1 umbilical cord Natural products 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 3
- 235000012756 tartrazine Nutrition 0.000 description 3
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 3
- 239000004149 tartrazine Substances 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000004288 Sodium dehydroacetate Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- BPHHNXJPFPEJOF-UHFFFAOYSA-J chembl296966 Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC(S([O-])(=O)=O)=C(N)C2=C(O)C(N=NC3=CC=C(C=C3OC)C=3C=C(C(=CC=3)N=NC=3C(=C4C(N)=C(C=C(C4=CC=3)S([O-])(=O)=O)S([O-])(=O)=O)O)OC)=CC=C21 BPHHNXJPFPEJOF-UHFFFAOYSA-J 0.000 description 2
- DSCVOQXQGTYXMV-UHFFFAOYSA-L disodium 6-amino-3-[[4-[(3-carboxy-4-hydroxyphenyl)diazenyl]naphthalen-1-yl]diazenyl]-4-oxidonaphthalene-2-sulfonate Chemical compound NC1=CC=C2C=C(C(N=NC3=C4C=CC=CC4=C(C=C3)N=NC3=CC=C(O)C(=C3)C(=O)O[Na])=C(O)C2=C1)S(=O)(=O)O[Na] DSCVOQXQGTYXMV-UHFFFAOYSA-L 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 229940043267 rhodamine b Drugs 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 229940079839 sodium dehydroacetate Drugs 0.000 description 2
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 description 1
- 229940075861 ammonium thioglycolate Drugs 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940071120 dehydroacetate Drugs 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- UZZFFIUHUDOYPS-UHFFFAOYSA-L disodium 4-amino-3,6-bis[[4-[(2,4-diaminophenyl)diazenyl]phenyl]diazenyl]-5-oxido-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccc(cc4)N=Nc4ccc(N)cc4N)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 UZZFFIUHUDOYPS-UHFFFAOYSA-L 0.000 description 1
- DHQJMKJYFOHOSY-UHFFFAOYSA-L disodium 4-amino-3-[[4-[4-[(2,4-diaminophenyl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Cc1cc(ccc1N=Nc1ccc(N)cc1N)-c1ccc(N=Nc2c(N)c3c(O)c(N=Nc4ccccc4)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(C)c1 DHQJMKJYFOHOSY-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 229940001474 sodium thiosulfate Drugs 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- XRFRTDKENRGSSX-UHFFFAOYSA-J tetrasodium;3-[[4-[[4-[(4,8-disulfonatonaphthalen-2-yl)diazenyl]-3-methylphenyl]carbamoylamino]-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=CC=C(S([O-])(=O)=O)C2=CC(N=NC3=CC=C(NC(=O)NC=4C=C(C)C(N=NC=5C=C6C(=CC=CC6=C(C=5)S([O-])(=O)=O)S([O-])(=O)=O)=CC=4)C=C3C)=CC(S([O-])(=O)=O)=C21 XRFRTDKENRGSSX-UHFFFAOYSA-J 0.000 description 1
- 210000003954 umbilical cord Anatomy 0.000 description 1
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、印刷用、筆記具用、記録用、スタン
プ用として優れた水性インキ組成物、更に詳しく
は、保存中に変質の起らない、不溶成分、染料等
の析出を生じない、適度の乾燥性を有する、更に
インキのぼたつきのない水性インキ組成物、特に
筆記具用水性インキ組成物に関する。Detailed Description of the Invention [Industrial Field of Application] The present invention provides an aqueous ink composition that is excellent for printing, writing instruments, recording, and stamps, and more specifically, an aqueous ink composition that does not undergo deterioration during storage. The present invention relates to an aqueous ink composition, particularly an aqueous ink composition for writing instruments, which does not cause precipitation of insoluble components, dyes, etc., has appropriate drying properties, and does not cause ink splatter.
［従来の技術］
通常、筆記具等に用いられている水性インキ組
成物は、着色剤、湿潤剤、水等から構成されてい
るものである。[Prior Art] Water-based ink compositions used for writing instruments and the like are usually composed of a colorant, a wetting agent, water, and the like.
［発明が解決しようとする問題点］
しかしながら、従来の水性インキ組成物は、保
存中、特にキヤツプを外した状態で放置したりす
ると目ずまりを起して使用できなくなつたり、逆
に使用した時になかなか乾燥しない、又インキが
使用中たれ落ちてしまう等の欠点があつた。[Problems to be Solved by the Invention] However, conventional water-based ink compositions tend to clog during storage, especially when left with the cap removed, making them unusable, or even making them difficult to use. There were drawbacks such as the ink not drying easily when applied, and the ink dripping off during use.
これらの欠点を改良するために、アクリル酸、
アルギン酸、ポリビニルアルコール等を配合して
いる例も見られるが、今だ充分でないのが現状で
ある。 In order to improve these shortcomings, acrylic acid,
Although there are examples of blending alginic acid, polyvinyl alcohol, etc., it is currently not sufficient.
［問題点を解決するための手段］
本発明者らは、こうした事情にかんがみ、上記
の欠点を解決すべく鋭意研究を重ねた結果、特定
の高分子化合物を添加すると保存中に変質が起ら
ず、染料等の析出が生じない、適度の乾燥性を有
し、更にインキのぼたつきのない水性インキ組成
物が得られることを見い出し、この知見に基づい
て本発明を完成するに至つた。[Means for Solving the Problems] In view of these circumstances, the present inventors have conducted intensive research to solve the above drawbacks, and have found that addition of a specific polymer compound does not cause deterioration during storage. First, we have discovered that it is possible to obtain an aqueous ink composition that does not cause precipitation of dyes, etc., has appropriate drying properties, and does not cause ink stagnation, and based on this knowledge, we have completed the present invention.
すなわち、本発明は、着色剤、湿潤剤、0.01〜
10重量％のヒアルロン酸及び水を必須成分とする
水性インキ組成物を提供するものである。 That is, the present invention provides a coloring agent, a wetting agent, 0.01 to
The present invention provides an aqueous ink composition containing 10% by weight of hyaluronic acid and water as essential components.
以下本発明の構成について詳述する。 The configuration of the present invention will be explained in detail below.
本発明で用いられるヒアルロン酸は、酸性ムコ
多糖の一種で、分子量は特に限定されないが、50
万から200万のものが物性的には好ましい。又精
製された高純度のものあるいは特定の分子量のも
のを用いてもかまわない。 Hyaluronic acid used in the present invention is a type of acidic mucopolysaccharide, and its molecular weight is not particularly limited, but
A value of 10,000 to 2,000,000 is preferable from a physical standpoint. Further, purified high-purity products or products with a specific molecular weight may be used.
通常このヒアルロン酸は例えば、臍帯、鶏のト
サカ、豚尾、動物もしくは魚類の眼球ガラス体そ
の他各種の天然物より適宜抽出されたものが用い
られるが、合成品でもかまわない。又、近年微生
物によつて高収率でヒアルロン酸が得られている
が、このものも使用でき、物性ないし工業的メリ
ツトを考えたらこのものが最も好ましい。 Usually, the hyaluronic acid used is one extracted from various natural products such as umbilical cord, chicken comb, pig's tail, animal or fish eyeball vitreous, and other natural products, but synthetic products may also be used. In addition, in recent years, hyaluronic acid has been obtained in high yield using microorganisms, and this can also be used, and this is the most preferred in terms of physical properties and industrial merits.
ヒアルロン酸の配合量は、インキ組成物全重量
中0.01〜10重量％が好ましく、さらに好ましくは
0.05〜5.0重量％である。 The blending amount of hyaluronic acid is preferably 0.01 to 10% by weight based on the total weight of the ink composition, and more preferably
It is 0.05-5.0% by weight.
本発明で用いられる着色剤は、一般に水性イン
キに用いられるものであり、直接染料、酸性染
料、塩基性染料、螢光染料、顔料等である。これ
らの着色剤が１種又は２種以上が配合される。着
色剤を例示すれば以下のものが挙げられる。 The coloring agent used in the present invention is generally used in water-based inks, and includes direct dyes, acid dyes, basic dyes, fluorescent dyes, pigments, and the like. One or more of these colorants may be blended. Examples of colorants include the following.
C.I.ダイレクトブラツク38、C.I.ダイレクトブ
ラツク51、C.I.アシツドブラツク24、C.I.アシツ
ドブラツク107、ウオータブラツク＃100（C.I.ダ
イレクトブラツク19：オリエント化学製）、ダイ
レクトデイープブラツクXA（C.I.ダイレクトブラ
ツク154：住友化学製）、C.I.ダイレクトブラツク
51（三菱化成製）、C.I.ダイレクトブラツク22（住
友化学製）、ダイレクトフアーストエローＲ（C.I.
ダイレクトエロー50）、ウオーターブルー９（C.I.
アシツドブルー９）、タートラジン（C.I.アシツ
ドエロー23）、C.I.45380、C.I.50420、C.I.35255、
C.I.30235、C.I.45160、C.I.46005、C.I.48055、C.I.
ダイレクトブルー−１、−98、−192、C.I.アシツ
ドブルー−１、−175、ソーラフアーストレツド
3G、ローダミンＢ、エオシン、酸化チタン、群
青、紺青、弁柄等である。 CI Direct Black 38, CI Direct Black 51, CI Assisted Black 24, CI Assisted Black 107, Water Black #100 (CI Direct Black 19: Orient Chemical), Direct Deep Black XA (CI Direct Black 154: Sumitomo Chemical), CI Direct Black
51 (Mitsubishi Chemical), CI Direct Black 22 (Sumitomo Chemical), Direct First Yellow R (CI
Direct Yellow 50), Water Blue 9 (CI
Acid Blue 9), Tartrazine (CI Acid Yellow 23), CI45380, CI50420, CI35255,
CI30235, CI45160, CI46005, CI48055, CI
Direct Blue-1, -98, -192, CI Acid Blue-1, -175, Solar Earth Stretch
These include 3G, rhodamine B, eosin, titanium oxide, ultramarine, navy blue, and Bengara.
着色剤の配合量は、一般的には水性インキ組成
物全量中0.5〜20重量％が好ましく、さらに好ま
しくは１〜10重量％である。 The amount of the colorant to be blended is generally preferably 0.5 to 20% by weight, more preferably 1 to 10% by weight based on the total amount of the aqueous ink composition.
本発明で用いられる湿潤剤は、一般的に水性イ
ンキ組成物に用いられるものであり、１種又は２
種以上が配合される。湿潤剤を例示すれば以下の
ものである。 The wetting agent used in the present invention is generally used in aqueous ink compositions, and one or two types of wetting agents are used.
More than one species is blended. Examples of wetting agents include the following.
グリセリン、エチレングリコール、ジエチレン
グリコール、プロピレングリコール、１，３ブチ
レングリコール、ポリエチレングリコール、ヘキ
シレングリコール、トリメチロールプロパン、エ
チレングリコールモノエチルエーテル、エチレン
グリコールモノブチルエーテル、ジエチレングリ
コールモノメチルエーテル、トリエチレングリコ
ールモノエチルエーテル等である。 Glycerin, ethylene glycol, diethylene glycol, propylene glycol, 1,3 butylene glycol, polyethylene glycol, hexylene glycol, trimethylolpropane, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, triethylene glycol monoethyl ether, etc. be.
湿潤剤の配合量は、一般的には水性インキ組成
物全量中5.0〜40重量％が好ましく、さらに好ま
しくは10〜30重量％である。 The blending amount of the wetting agent is generally preferably 5.0 to 40% by weight, more preferably 10 to 30% by weight based on the total amount of the aqueous ink composition.
本発明においては、上記必須成分の他、必要に
応じて水性インキ組成物に配合される通常の成
分、例えば界面活性剤、防腐剤、酸性物質、塩基
性物質、本発明のヒアルロン酸以外の高分子物
質、尿素、溶解剤、香料等が適宜配合される。 In the present invention, in addition to the above-mentioned essential components, conventional components that are added to water-based ink compositions as necessary, such as surfactants, preservatives, acidic substances, basic substances, and high Molecular substances, urea, solubilizers, fragrances, etc. are appropriately blended.
界面活性剤の例としては、アニオン界面活性
剤、ノニオン界面活性剤、両性界面活性剤等が用
いられる。又、高分子物質の例としては、アクリ
ル酸、カルボキシビニルポリマー、ヒドロキシプ
ロピルセルロース、カルボキシメチルセルロー
ス、ポリビニルアルコール等が用いられるが、カ
ルボキシビニルポリマー（商品名：カーボポー
ル、ハイビスワコー等）と併用すると効果が相乗
的に発揮され好ましい。 Examples of the surfactant include anionic surfactants, nonionic surfactants, amphoteric surfactants, and the like. Examples of polymeric substances used include acrylic acid, carboxyvinyl polymer, hydroxypropyl cellulose, carboxymethyl cellulose, and polyvinyl alcohol, but these are effective when used in combination with carboxyvinyl polymers (product names: Carbopol, Hivis Wako, etc.). are preferable because they are synergistically exhibited.
防腐剤の例としては、デヒドロ酢酸ナトリウ
ム、安息香酸ナトリウム、チオ硫酸ナトリウム、
チオグリコール酸アンモニウム、ソルビン酸カリ
等が用いられる。 Examples of preservatives include sodium dehydroacetate, sodium benzoate, sodium thiosulfate,
Ammonium thioglycolate, potassium sorbate, etc. are used.
溶解剤の例としては、Ｎ−メチルピロリドン等
が用いられる。 As an example of the solubilizing agent, N-methylpyrrolidone or the like is used.
本発明においては、上記配合成分に加えて水を
水性インキ組成物中全量が100重量％になる量添
加する。 In the present invention, in addition to the above ingredients, water is added in an amount such that the total amount in the aqueous ink composition is 100% by weight.
本発明の水性インキ組成物は、マーキングペ
ン、螢光ペン、水性ボールペン用等の筆記具用、
インクジエツト記録用、スタンプ用、印刷用等広
く応用することができる。 The water-based ink composition of the present invention can be used for writing instruments such as marking pens, fluorescent pens, and water-based ballpoint pens.
It can be widely used for inkjet recording, stamping, printing, etc.
［実施例］
次に実施例によつて本発明をさらに詳細に説明
する。本発明はこれにより限定されるものではな
い。配合量は重量％である。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby. The blending amount is in weight%.
実施例 １
プロピレングリコール 30.0
ヒアルロン酸 0.1
ポリオキシエチレン（20モル） 0.5
オレイルアルコールエーテル
C.I.アシツドブラツク24 15.0
酸化チタン 4.0
水酸化ナトリウム（５％） 0.3
安息香酸ソーダ 1.0
水 to 100.0％
（製法） 一部の水にヒアルロン酸を完全に溶解
した後、水酸化ナトリウム水溶液を滴下し、PH
調節を行い、その後、その他を残りの水に溶解
した溶液を上記ヒアルロン酸溶液に混合し水性
インキ組成物を得た。Example 1 Propylene glycol 30.0 Hyaluronic acid 0.1 Polyoxyethylene (20 mol) 0.5 Oleyl alcohol ether CI acid black 24 15.0 Titanium oxide 4.0 Sodium hydroxide (5%) 0.3 Sodium benzoate 1.0 Water to 100.0% (Production method) Some water After completely dissolving hyaluronic acid in the solution, add sodium hydroxide solution dropwise to adjust the pH.
After making adjustments, a solution in which other ingredients were dissolved in the remaining water was mixed with the above hyaluronic acid solution to obtain a water-based ink composition.
実施例 ２
１，３ブチレングリコール 10.0
グリセリン 30.0
ヒアルロン酸 0.5
ポリアクリル酸ナトリウム 0.1
ポリオキシエチレン（15モル） 0.2
モノオレイン酸エステル
C.I.アシツドエロー23 0.5
香 料 0.2
水 to 100.0％
実施例 ３
エチレングリコール 30.0
ソルビトール70％水溶液 3.0
ヒアルロン酸 0.02
ポリアクリル酸ナトリウム 0.1
ポリオキシエチレン（20モル） 0.5
モノステアリン酸エステル
ローダミンＢ 12.0
水 to 100.0％
実施例 ４
エチレングリコール 15.0
ヒアルロン酸 1.0
ハイビスワコー（カルボキシビニルポリマー）
0.1
ポリオキシエチレン（20モル）ノニルフエニルエ
ーテル 0.1
C.I.ダイレクトブルー−１ 10.0
群 青 2.0
水 to 100.0％
実施例 ５
ジエチレングリコール 20.0
ヒアルロン酸 8.0
カーボポール（カルボキシビニルポリマー） 0.5
デヒドロ酢酸ナトリウム 0.1
ソーラフアーストレツド3G 8.0
尿 素 5.0
水 to 100.0％
実施例 ６
エチレングリコールモノブチルエーテル 20.0
ポリエチレングリコール400 3.0
ポリエチレングリコール200 3.0
ヒアルロン酸 0.5
デヒドロ酢酸ナトリウム 0.1
C.I.ダイレクトブラツク１９ 5.0
水 to 100.0％
実施例 ７
トリメチロールプロパン 7.0
プロピレングリコール 20.0
ヒアルロン酸 1.0
ポリオキシエチレン（20モル） 0.5
オレイルアルコールエーテルデヒドロ酢酸ナトリ
ウム 0.1
C.I.50420 6.0
水 to 100.0％
実施例２〜７の水性インキ組成物は、いずれも
実施列１に準じて製造した。Example 2 1,3-butylene glycol 10.0 Glycerin 30.0 Hyaluronic acid 0.5 Sodium polyacrylate 0.1 Polyoxyethylene (15 mol) 0.2 Monooleic acid ester CI acid yellow 23 0.5 Fragrance 0.2 Water to 100.0% Example 3 Ethylene glycol 30.0 Sorbitol 70 % aqueous solution 3.0 Hyaluronic acid 0.02 Sodium polyacrylate 0.1 Polyoxyethylene (20 mol) 0.5 Monostearate rhodamine B 12.0 Water to 100.0% Example 4 Ethylene glycol 15.0 Hyaluronic acid 1.0 Hiviswako (carboxy vinyl polymer)
0.1 Polyoxyethylene (20 mol) nonyl phenyl ether 0.1 CI Direct Blue-1 10.0 Group Blue 2.0 Water to 100.0% Example 5 Diethylene glycol 20.0 Hyaluronic acid 8.0 Carbopol (carboxy vinyl polymer) 0.5 Sodium dehydroacetate 0.1 Sora Earth Stretch 3g 8.0 urea 5.0 water to 100.0 % water TO 100.0 % Example Example 6 ethylene glycol monobutyl ether 20.0 polyethylene glycol 200 3.0 hyaluronic acid 0.5 dhidronic sodium 0.1 CI Direct Brazuk 19 5.0 water To 100.0 % 7 Trimetyrol propane 7.0 propylene glycol 20.0 Hyaluronic acid 1.0 Polyoxyethylene (20 mol) 0.5 Sodium oleyl alcohol ether dehydroacetate 0.1 CI50420 6.0 Water to 100.0% The water-based ink compositions of Examples 2 to 7 were all produced according to Example 1.
［発明の効果］
本発明の実施例６のインクジエツト記録用水性
インキは、いずれも保存中に変質を起さず、不溶
成分、染料等の析出もなく、又ドライアツプしな
いためノズル詰りを生ずることがない優れたもの
であつた。さらに、塗布面がいつまでもべたつか
ないという適度の乾燥性を有していた。[Effects of the Invention] The water-based inkjet recording ink of Example 6 of the present invention does not change in quality during storage, does not precipitate insoluble components, dyes, etc., and does not dry up, so no nozzle clogging occurs. It was an excellent one. Furthermore, it had appropriate drying properties so that the coated surface did not remain sticky forever.
本発明の実施例７の水性ボールペン用インキ組
成物は、いずれも保存中に変質を起さず、不溶成
分、染料等の析出もなく、又ドライアツプしない
という適度の乾燥性を有していた。又、ボールと
ボール受けの摩擦も小さくスムースに機能した。 All of the aqueous ballpoint pen ink compositions of Example 7 of the present invention did not undergo deterioration during storage, did not precipitate insoluble components, dyes, etc., and had appropriate drying properties without drying up. Also, the friction between the ball and the ball receiver was small and it functioned smoothly.
本発明の実施例１〜５の筆記具用水性インキ組
成物は、いずれも保存中に変質を起さず、不溶成
分、染料等の析出もなく、又ドライアツプしない
という適度の乾燥性を有していた。さらに、イン
キのぼたつきがない優れたものであつた。 The water-based ink compositions for writing instruments of Examples 1 to 5 of the present invention all have appropriate drying properties such that they do not undergo deterioration during storage, do not precipitate insoluble components, dyes, etc., and do not dry up. Ta. Furthermore, the ink was excellent in that it did not smudge.
なお、その他いずれの実施例の水性インキ組成
物も安全性の面でも問題のないものであつた。 Note that the water-based ink compositions of all other Examples also had no problems in terms of safety.
Claims (1)
ン酸及び水を必須成分とする水性インキ組成物。1. A water-based ink composition containing a colorant, a wetting agent, 0.01 to 10% by weight of hyaluronic acid, and water as essential components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14544885A JPS624764A (en) | 1985-07-02 | 1985-07-02 | Water based ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14544885A JPS624764A (en) | 1985-07-02 | 1985-07-02 | Water based ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS624764A JPS624764A (en) | 1987-01-10 |
| JPH0552863B2 true JPH0552863B2 (en) | 1993-08-06 |
Family
ID=15385456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14544885A Granted JPS624764A (en) | 1985-07-02 | 1985-07-02 | Water based ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS624764A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2588200B2 (en) * | 1987-07-08 | 1997-03-05 | 株式会社東芝 | Manufacturing method of oxide superconductor |
| DE3941662A1 (en) * | 1989-12-16 | 1991-06-20 | Staedtler Fa J S | WRITING FLUID |
| FR2675164B1 (en) * | 1991-04-09 | 2000-01-28 | Marian Dorel | PROCESS FOR THE PREPARATION OF TEXTILE COATING COMPOSITIONS AND CORRESPONDING COATING COMPOSITIONS. |
| US5550112A (en) * | 1992-12-30 | 1996-08-27 | Patent Biopharmaceutics, Inc. | Hyaluronic acid-urea pharmaceutical compositions and uses |
| US5631242A (en) * | 1993-08-04 | 1997-05-20 | Patent Biopharmaceutics, Inc. | Hyaluronic acid-urea pharmaceutical compositions utilized for treatment of diseases of cutis |
| GB2379222B (en) * | 2000-06-01 | 2004-12-01 | Mitsubishi Pencil Co | Water based ink composition for writing utensil |
| CN102010633A (en) * | 2010-12-29 | 2011-04-13 | 上海乐美文具有限公司 | Dye-type non-dry watercolor ink and manufacturing method thereof |
| JP5966612B2 (en) * | 2012-05-23 | 2016-08-10 | 株式会社リコー | Treatment liquid, method for producing the same, and image forming method |
| JP6580382B2 (en) * | 2015-06-15 | 2019-09-25 | 株式会社パイロットコーポレーション | Ballpoint pen |
-
1985
- 1985-07-02 JP JP14544885A patent/JPS624764A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS624764A (en) | 1987-01-10 |
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