JPH0552487A - Decomposed gas quick cooling heat exchanging device - Google Patents
Decomposed gas quick cooling heat exchanging deviceInfo
- Publication number
- JPH0552487A JPH0552487A JP21371391A JP21371391A JPH0552487A JP H0552487 A JPH0552487 A JP H0552487A JP 21371391 A JP21371391 A JP 21371391A JP 21371391 A JP21371391 A JP 21371391A JP H0552487 A JPH0552487 A JP H0552487A
- Authority
- JP
- Japan
- Prior art keywords
- steam drum
- heat exchanging
- steam
- heat exchange
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/002—Cooling of cracked gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
- F28D7/12—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically the surrounding tube being closed at one end, e.g. return type
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、石油類などの分解炉に
おける分解ガスを急冷する分解ガス急冷熱交換装置に関
するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cracked gas quenching heat exchanger for quenching cracked gas in a cracking furnace such as petroleum.
【0002】[0002]
【従来の技術】近年、分解炉の技術動向としては、エチ
レンの収率向上のため、分解炉の反応管における分解ガ
ス滞留時間を短かくする傾向にある。その結果、反応管
のパス数は増大する。このため、分解コイルと急冷熱交
換器とを結ぶトランスファーラインを単純化し、分解ガ
ス滞留時間も小さくする必要が生じ、その結果として、
1基の分解炉当りの急冷熱交換器の基数が増大すること
になる。2. Description of the Related Art In recent years, as a technical trend of cracking furnaces, there is a tendency to shorten the residence time of cracked gas in the reaction tube of the cracking furnace in order to improve the yield of ethylene. As a result, the number of passes in the reaction tube increases. Therefore, it is necessary to simplify the transfer line connecting the cracking coil and the quenching heat exchanger and shorten the cracked gas retention time. As a result,
The number of quenching heat exchangers per cracking furnace will increase.
【0003】このような分解炉に対して、従来、特公昭
62−8714号公報のような分解ガス用熱交換器が提
案されている。この提案では、伝熱管の半径方向に幾つ
かのフインを取付けることにより、隣接する各管と管胴
内面との間のスペーサの役目を持たせると共に、これら
のフインの配置がガスに対する整流作用をして伝熱効果
をもたせている。更に、管胴内のガス通路断面積をこれ
らフインで所要値まで狭め、ガス流速を上げるようにし
ている。この結果、分解ガスのコークス分の伝熱面に付
着堆積するコーキングの抑制が図られるようになってい
る。For such a cracking furnace, a heat exchanger for cracking gas as disclosed in Japanese Patent Publication No. 62-8714 has been proposed. In this proposal, several fins are attached in the radial direction of the heat transfer tube so as to act as a spacer between each adjacent tube and the inner surface of the tube body, and the arrangement of these fins has a rectifying effect on gas. It has a heat transfer effect. Further, these fins narrow the cross-sectional area of the gas passage in the tube body to a required value to increase the gas flow velocity. As a result, coking that adheres and deposits on the heat transfer surface of the coke of the cracked gas is suppressed.
【0004】一方、従来の分解ガス用熱交換器では、各
1基づつの気水ドラムと熱交換部とが一体化されている
が、このような熱交換器を多数の急冷熱交換器を必要と
する分解炉に採用した場合、気水ドラムの数が増え、装
置全体のコンパクト化が図られると共に、ボイラ供給水
系のフィードコントロールが複雑になり、かつ各気水ド
ラムにそれぞれ設ける液面計を含めたレベルコントロー
ルなどの計器、計装類の数が増大し、さらに、これら各
気水ドラム回りにそれぞれ必要とされる配管類の数が増
大し、装置の全体が複雑化するという問題があった。On the other hand, in the conventional heat exchanger for decomposed gas, one steam water drum and one heat exchange unit are integrated, and such a heat exchanger is replaced by a large number of quench heat exchangers. If it is used in a required cracking furnace, the number of steam / water drums will increase, the overall size of the equipment will be reduced, the feed control of the boiler feed water system will be complicated, and the level gauges will be installed in each steam / water drum. There is a problem that the number of instruments and instrumentation such as level control including the above increases, and the number of pipes required around each of these water-water drums increases, which complicates the entire apparatus. there were.
【0005】さらに、前記のような分解ガス中のコーク
ス分が伝熱面に付着すると、伝熱を阻害して、分解ガス
側の圧力損失を上げるため、一定時間毎にデコーキング
といわれている方法によりこの堆積を取除く操作が必要
であり、この操作を効率的に行うことがエチレンプラン
トなどの年間稼働率を高くでき、生産を増加するために
必要とされている。しかしながら、このようなデコーキ
ング操作は、従来、分解炉を止めて、ウォータージェッ
ト洗浄により行なっていたため、プラントの運動の稼動
率を低下させることになった。Further, if the coke component in the cracked gas adheres to the heat transfer surface as described above, it impedes heat transfer and increases the pressure loss on the cracked gas side, so it is called decoking at regular intervals. The method requires an operation to remove this deposit, and efficient operation is required to increase the annual operating rate of the ethylene plant or the like and increase the production. However, since such a decoking operation has been conventionally performed by stopping the decomposition furnace and performing water jet cleaning, the operation rate of motion of the plant is reduced.
【0006】[0006]
【発明が解決しようとする課題】本発明の目的は、1基
のスチームドラムの下部に複数の熱交換部をそれぞれ直
接垂下接続することにより、スチームドラム回りの計
器、計装類及び各配管数の数を減じて、これらを単純化
でき、全体としてコンパクトな構造に形成可能で、しか
も短時間にオンラインデコーキング操作可能な分解ガス
急冷熱交換装置を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to directly connect a plurality of heat exchange parts to the lower part of one steam drum so that the number of instruments, instrumentation and pipes around the steam drum is increased. It is an object of the present invention to provide a cracked gas quenching heat exchanger which can be simplified in number, can be formed into a compact structure as a whole, and can be decoking on-line in a short time.
【0007】[0007]
【発明が解決しようとする課題】すなわち、本発明の分
解ガス急冷熱交換装置は、1基の水平に長いスチームド
ラムの下部に垂下して複数の熱交換部を直接接続するこ
とにより構成され、複数の熱交換部に対して1基のスチ
ームドラムを接続することによりスチームドラム回りが
構造上で単純化し、かつコンパクトな構成とすることが
できる。That is, the cracked gas quenching heat exchange apparatus of the present invention is constructed by hanging a plurality of horizontally long steam drums and directly connecting a plurality of heat exchange sections, By connecting one steam drum to a plurality of heat exchange parts, the structure around the steam drum can be structurally simplified and a compact structure can be obtained.
【0008】また、上記各熱交換部を構成する伝熱管と
降水管とを、上部でスチームドラム側に固定し、かつ下
部をフリーにすることが、オンラインデコーキングを可
能にするので、そのプラント稼動率の向上をはかる上で
好ましい構成である。Further, by fixing the heat transfer pipe and the downcomer pipe constituting each of the above-mentioned heat exchange parts to the steam drum side at the upper part and making the lower part free, the online decoking becomes possible. This is a preferable configuration for improving the operating rate.
【0009】[0009]
【実施例】以下、図面を参照して本発明の実施例を説明
する。本発明の分解ガス急冷熱交換装置は、図2に示す
分解炉13を出た分解ガスGをトランスファーライン1
2を介して導入してその冷却を行うものであり、この装
置では、図1に示すごとく、1基のスチームドラム1の
下部に垂下して、複数、例えばこの実施例のごとく10
基の熱交換部11をそれぞれ直接接続している。Embodiments of the present invention will be described below with reference to the drawings. The cracked gas quenching heat exchanger of the present invention transfers the cracked gas G discharged from the cracking furnace 13 shown in FIG.
In this apparatus, as shown in FIG. 1, a plurality of, for example, 10 as in this embodiment, are hung down to the bottom of one steam drum 1.
The base heat exchange parts 11 are directly connected to each other.
【0010】次に、各熱交換部11の細部につき説明す
ると、図3に示すごとく、スチームドラム1の下部から
伝熱管6が管胴部14の中に垂下している。また、図中
の5は伝熱管6の中に垂下する降水管であり、冷却水W
はこの中を流下して高温の分解ガスGにより加熱されて
水蒸気となり、その外側を上昇してスチームドラム1に
流入する。Next, the details of each heat exchange section 11 will be described. As shown in FIG. 3, the heat transfer tube 6 hangs from the lower portion of the steam drum 1 into the tube body section 14. Reference numeral 5 in the figure is a downcomer that hangs down in the heat transfer tube 6, and the cooling water W
Flows down into this and is heated by the high-temperature decomposition gas G to become steam, which rises outside and flows into the steam drum 1.
【0011】この水蒸気はスチームドラム1内で水と分
離され、蒸気は高乾度蒸気としてスチームドラム1の上
部の蒸気出口ノズル8より回収され、一方、水は再び降
水管5内を降下して、自然循環するようになっている。
なお、図3の10で示すのはボイラ供給水フィードノズ
ルである。次に、高温の分解ガスGは管胴部14の下端
の入口4から入り、伝熱管6に熱を与えながら上昇して
管胴部14の上端部のガス出口2から排出される。This steam is separated from the water in the steam drum 1, and the steam is recovered as high-dry steam from the steam outlet nozzle 8 at the upper part of the steam drum 1, while the water descends again in the downcomer pipe 5. , It is naturally circulating.
A boiler feed water feed nozzle is shown at 10 in FIG. Next, the hot decomposed gas G enters through the inlet 4 at the lower end of the tube body 14, rises while applying heat to the heat transfer tube 6, and is discharged through the gas outlet 2 at the upper end of the tube body 14.
【0012】なお、各伝熱管6の下半部分には、図示し
ていないフインを管の長さ方向に取付けて、隣接の管と
の、あるいは管胴部14の内面との間のスペーサの役目
をさせることができるが、これらのフインを設けること
は本発明における必須要件ではない。このようなフイン
の配置は、特公昭62−8714号公報に記載されてい
るように、分解ガスGに対して整流作用をなし、伝熱効
果の増大をもたらし、さらに、このフインは当然伝熱面
を増すと共に、その厚さを適当に選定することで管胴部
14内のガス通路断面積を所要の値まで狭め、ガス流速
を上げる役目をし、その結果、その部分でのフインの存
在による伝熱面積の増加とガス流速の増加とでガスへの
急冷効果をもたらすものである。A fin (not shown) is attached to the lower half of each heat transfer tube 6 in the lengthwise direction of the tube to form a spacer between the adjacent tube and the inner surface of the tube body 14. Although it can play a role, it is not essential in the present invention to provide these fins. As described in Japanese Patent Publication No. 62-8714, such a fin arrangement has a rectifying effect on the cracked gas G, resulting in an increase in heat transfer effect. Furthermore, the fin naturally transfers heat. By increasing the surface area and appropriately selecting the thickness, the gas passage cross-sectional area in the tube body portion 14 is narrowed to a required value, which serves to increase the gas flow velocity, and as a result, the presence of fins in that portion. The increase of the heat transfer area and the increase of the gas flow velocity bring about a quenching effect on the gas.
【0013】なお、この実施例では、管胴部14のガス
出口2の他に、第2のガス出口3を設け、これを重質油
分解ガス用出口とし、ガス出口2を軽質油分解ガス用出
口としている。以上のごとく、この実施例の分解ガス急
冷熱交換装置は、1基のスチームドラム1とその下部に
垂下して接続された10基の熱交換部11とからなって
おり、スチームドラム1の下部に各熱交換部11がボル
トで固定され、そのシール部にはリップシール溶接を採
用している。In this embodiment, in addition to the gas outlet 2 of the tube body 14, a second gas outlet 3 is provided, which serves as an outlet for heavy oil cracked gas, and the gas outlet 2 is used for light oil cracked gas. It is used as an exit. As described above, the cracked gas quenching heat exchange device of this embodiment is composed of one steam drum 1 and ten heat exchange parts 11 hung and connected to the lower part of the steam drum 1. Each heat exchanging portion 11 is fixed with bolts, and lip seal welding is adopted for the seal portion.
【0014】一方、スチームドラム1の下部に垂下して
接続されている熱交換部11は、装置の運転中にはスチ
ームドラム1の熱膨張による移動につれて動くことにな
るが、この熱交換部11を構成する伝熱管6と降水管5
とはその上部においてのみスチームドラム1の下部に固
定されており、下部へはフリーの状態になっている。従
って、いかなる熱膨張が発生しても伝熱管6と降水管5
とは熱膨張を問題なく吸収可能である。On the other hand, the heat exchange section 11 which is hung and connected to the lower portion of the steam drum 1 moves as the steam drum 1 moves due to thermal expansion during the operation of the apparatus. Heat transfer pipe 6 and downfall pipe 5
Is fixed to the lower part of the steam drum 1 only at the upper part, and is free to the lower part. Therefore, even if any thermal expansion occurs, the heat transfer pipe 6 and the downfall pipe 5
And can absorb thermal expansion without problems.
【0015】このような構造を有していることにより、
この熱交換部11においてはスチーム及びエアーのオン
ライン・デコーキングを可能にしており、この場合のオ
ンライン・デコーキングは650℃程度に加熱したスチ
ーム及びエアーの混合ガスによって、コークスの燃焼除
去を行なうことができるが、この時、スチームドラム1
中の高圧水は完全にブローされ、スチームドラム1はス
チームで充満した状態にして伝熱管6の壁温度を上げる
ため、コークスの燃焼効果を高め、完全にコークスを短
時間で除去することができる。By having such a structure,
In this heat exchange section 11, online decoking of steam and air is possible. In this case, online decoking is to remove coke by burning mixed gas of steam and air heated to about 650 ° C. You can, but at this time, steam drum 1
The high-pressure water inside is completely blown, the steam drum 1 is filled with steam, and the wall temperature of the heat transfer tube 6 is raised. Therefore, the combustion effect of coke is enhanced, and coke can be completely removed in a short time. ..
【0016】このようなオンライン・デコーキングによ
るシステムは、プラントとしての完全自動化を可能にす
るものであり、プラントの運転稼動率の上昇をはかるこ
とができる。Such a system based on online decoking enables complete automation of the plant and can increase the operating rate of the plant.
【0017】[0017]
【発明の効果】上記のように、本発明の分解ガス急冷熱
交換装置によれば、ボイラー給水系の配管及びそのコン
トロールが単純化されると共に、スチームドラムまわり
の各種計器、計装類及びそれらの配管などの数が減じて
単純化され、しかもスチームドラムが1基だけであるの
で、装置全体をコンパクトに形成でき、その結果、据付
が容易で、かつ現地での設置コストの低減がはかれると
いう多くの効果がある。As described above, according to the cracked gas quenching heat exchange device of the present invention, the piping of the boiler water supply system and its control are simplified, and various instruments and instruments around the steam drum and those are provided. Since the number of pipes etc. is reduced and it is simplified and only one steam drum is provided, the whole device can be made compact, and as a result, installation is easy and installation cost can be reduced locally. It has many effects.
【0018】また、本発明の装置に適用される熱交換部
は、オンライン・デコーキングが可能であるのでそのプ
ラントの稼動率の向上と作業員費用の低減とをはかりう
ると共に、プラント自動化の推進をはかりうるという利
点もある。Further, since the heat exchange section applied to the apparatus of the present invention is capable of on-line decoking, it is possible to improve the operating rate of the plant and reduce the worker cost, and to promote the automation of the plant. There is also an advantage that it can be measured.
【図1】本発明にかかる分解ガス急冷熱交換装置の側面
図である。FIG. 1 is a side view of a cracked gas quenching heat exchange device according to the present invention.
【図2】図2は図1の装置を分解炉に組付けた状態を示
す正面図である。FIG. 2 is a front view showing a state in which the apparatus of FIG. 1 is assembled in a decomposition furnace.
【図3】図3は図1の装置を構成する熱交換部の拡大正
断面図である。 1 スチームドラム 5 降水管 6 伝熱管 11 熱交換部 14 管胴部 G 分解ガスFIG. 3 is an enlarged front cross-sectional view of a heat exchange section constituting the device of FIG. 1 Steam Drum 5 Precipitation Tube 6 Heat Transfer Tube 11 Heat Exchange Section 14 Tube Body G Decomposition Gas
───────────────────────────────────────────────────── フロントページの続き (72)発明者 北山 裕 千葉県市原市千種海岸3番地 三井石油化 学工業株式会社内 (72)発明者 山林 保信 千葉県市原市千種海岸3番地 三井石油化 学工業株式会社内 (72)発明者 吉田 雅彦 千葉県市原市千種海岸3番地 三井石油化 学工業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yu Kitayama, 3 Chikusaigan, Ichihara, Chiba Mitsui Oil Chemicals Co., Ltd. Incorporated (72) Inventor Masahiko Yoshida 3 Chikusaigan, Ichihara-shi, Chiba Mitsui Petrochemical Industry Co., Ltd.
Claims (2)
複数の熱交換部が直接接続されている分解ガス急冷熱交
換装置。1. A cracked gas quenching heat exchange device having a plurality of heat exchange portions directly connected to a lower portion of one steam drum.
いる各熱交換部の伝熱管と降水管とが上部でスチームド
ラム側に固定され、下部はフリーになっている請求項1
記載の分解ガス急冷熱交換装置。2. A heat transfer tube and a downcomer tube of each heat exchange section that hang down from the bottom of one steam drum are fixed to the steam drum side at the upper part, and the lower part is free.
The decomposed gas quenching heat exchanger described.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21371391A JPH0552487A (en) | 1991-08-26 | 1991-08-26 | Decomposed gas quick cooling heat exchanging device |
DE19924292695 DE4292695T1 (en) | 1991-08-26 | 1992-08-25 | Heat exchanger for quick cooling of cracked gas |
PCT/JP1992/001065 WO1993004329A1 (en) | 1991-08-26 | 1992-08-25 | Cracking gas rapid cooling heat exchanger |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP21371391A JPH0552487A (en) | 1991-08-26 | 1991-08-26 | Decomposed gas quick cooling heat exchanging device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0552487A true JPH0552487A (en) | 1993-03-02 |
Family
ID=16643759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21371391A Pending JPH0552487A (en) | 1991-08-26 | 1991-08-26 | Decomposed gas quick cooling heat exchanging device |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPH0552487A (en) |
DE (1) | DE4292695T1 (en) |
WO (1) | WO1993004329A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5464057A (en) * | 1994-05-24 | 1995-11-07 | Albano; John V. | Quench cooler |
FR3011556B1 (en) * | 2013-10-09 | 2015-12-25 | Commissariat Energie Atomique | PROCESS FOR PURIFYING A RAW SYNTHESIS GAS FROM A PYROLYSIS AND / OR GASIFYING A CHARGE OF CARBON MATERIAL BY DESTRUCTION OF TARS CONTAINED IN THE GAS |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5350103A (en) * | 1976-10-20 | 1978-05-08 | Idemitsu Petrochemical Co | Apparatus for quenching thermal decomposition gas |
JPS57157991A (en) * | 1981-03-23 | 1982-09-29 | Mitsui Eng & Shipbuild Co Ltd | Heat exchanger for decomposed gas |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5024453B2 (en) * | 1971-09-08 | 1975-08-15 | ||
JPS5845403A (en) * | 1981-09-10 | 1983-03-16 | 三井造船株式会社 | Quenching heat exchanger using outside of pipe as flow path of decomposed gas |
-
1991
- 1991-08-26 JP JP21371391A patent/JPH0552487A/en active Pending
-
1992
- 1992-08-25 WO PCT/JP1992/001065 patent/WO1993004329A1/en active Application Filing
- 1992-08-25 DE DE19924292695 patent/DE4292695T1/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5350103A (en) * | 1976-10-20 | 1978-05-08 | Idemitsu Petrochemical Co | Apparatus for quenching thermal decomposition gas |
JPS57157991A (en) * | 1981-03-23 | 1982-09-29 | Mitsui Eng & Shipbuild Co Ltd | Heat exchanger for decomposed gas |
Also Published As
Publication number | Publication date |
---|---|
WO1993004329A1 (en) | 1993-03-04 |
DE4292695T1 (en) | 1993-10-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 19970617 |