JPH0550285A - Oxygen lean type reflow method and reflow device for circuit board - Google Patents

Oxygen lean type reflow method and reflow device for circuit board

Info

Publication number
JPH0550285A
JPH0550285A JP17808691A JP17808691A JPH0550285A JP H0550285 A JPH0550285 A JP H0550285A JP 17808691 A JP17808691 A JP 17808691A JP 17808691 A JP17808691 A JP 17808691A JP H0550285 A JPH0550285 A JP H0550285A
Authority
JP
Japan
Prior art keywords
furnace
oxygen
circuit board
reflow
thin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17808691A
Other languages
Japanese (ja)
Inventor
Kazuto Nishida
一人 西田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP17808691A priority Critical patent/JPH0550285A/en
Publication of JPH0550285A publication Critical patent/JPH0550285A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To provide the oxygen lean type reflow method and reflow device for circuit boards which can efficiently execute soldering with good quality. CONSTITUTION:The circuit board 12 to be subjected to reflow is subjected to preheating or solder melting in the state of rarefying the oxygen in a furnace by burning a combustion gas 5. A cooling catalyst or cooling water is passed in a tubular trap 10 and the moisture condensed to the outer side of the trap 10 is removed, by which the moisture in the furnace generated by the combustion of the combustion gas 5 is removed. The soldering with the good quality is efficiently executed in this way without oxidizing the circuit board the electrodes of parts and cream solder.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は電気部品をクリーム半田
の塗布された回路基板上に装着した後にクリーム半田を
溶融する回路基板の酸素希薄型リフロー方法およびリフ
ロー装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a circuit board thin oxygen reflow method and a reflow apparatus for melting a cream solder after mounting an electric part on the circuit board coated with the cream solder.

【0002】[0002]

【従来の技術】従来、電気部品を回路基板に装着して、
その電極と部品の電極を溶融するのには、図4に示すよ
うな、電気ヒーター21とファン11が設けられた装置
内を回路基板12を通過させて、回路基板12上のクリ
ーム半田を溶融することにより行われていた。
2. Description of the Related Art Conventionally, electrical parts are mounted on a circuit board,
In order to melt the electrode and the electrode of the component, the circuit board 12 is passed through the inside of the device provided with the electric heater 21 and the fan 11 as shown in FIG. 4, and the cream solder on the circuit board 12 is melted. It was done by doing.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、上記の
ような半田溶融方法では、熱せられた回路基板の電極や
部品の電極が酸化したり、予熱時や溶融時に半田が酸化
されて半田ホールとなり、回路基板の洗浄が必要であっ
たりした。またIC部品のリードピッチが微細になるに
従い、半田ボールが電極間を短絡させ不良を生じること
もあった。また、従来のリフロー方法では、洗浄を無く
すために弱活性のフラックスを用いることがあったが、
活性力が弱いために、回路基板の電極や部品の電極に十
分半田が濡れないといった不具合が発生していた。
However, in the solder melting method as described above, the electrodes of the heated circuit board or the electrodes of the components are oxidized, or the solder is oxidized during preheating or melting to form solder holes, The circuit board needed cleaning. Further, as the lead pitch of IC parts becomes finer, solder balls sometimes short-circuit the electrodes and cause defects. Further, in the conventional reflow method, a weakly active flux was sometimes used to eliminate cleaning,
Since the activation power is weak, there is a problem that the electrodes of the circuit board and the electrodes of the components are not sufficiently wet with the solder.

【0004】本発明は、上記従来の課題を解決するもの
で、品質のよい半田付けが能率よく行えるリフロー方法
およびそのための装置を提供することを目的とする。
The present invention solves the above-mentioned conventional problems, and an object of the present invention is to provide a reflow method and a device therefor capable of efficiently performing high quality soldering.

【0005】[0005]

【課題を解決するための手段】上記目的を達成するため
に、本発明のリフロー方法は、炉内においてメタンガス
(CH4),プロパン(CH8)などのガスと酸素を燃焼
させ、炉内に二酸化炭素もしくは一酸化炭素を充満し、
酸素濃度割合を相対的に減じる、または水素ガスを流し
炉内の酸素を燃焼して酸素を減じた炉内に回路基板を通
過させて、回路基板上の半田を溶融することを特徴とす
る。
In order to achieve the above object, the reflow method of the present invention burns a gas such as methane gas (CH 4 ), propane (CH 8 ) and oxygen in a furnace, Filled with carbon dioxide or carbon monoxide,
The present invention is characterized in that the oxygen concentration ratio is relatively reduced, or hydrogen gas is flown to burn oxygen in the furnace to pass the circuit board through the oxygen-reduced furnace to melt the solder on the circuit board.

【0006】さらに炉内にはガスを燃焼した際に発生す
る水分を除去する水分トラップを備えている。また、炉
内をマグネシウム,マンガン,アルミニウム,鉄等の酸
化しやすい、金属や活性炭等の多孔物質を設置または順
次炉内に供給することにより炉内の酸素濃度を下げた後
に回路基板を炉内に通過させて、回路基板上の半田を溶
融するようにしている。
Further, the furnace is provided with a water trap for removing water generated when the gas is burned. In addition, a circuit board is placed in the furnace after the oxygen concentration in the furnace is lowered by installing or sequentially supplying a porous material such as metal or activated carbon, which easily oxidizes magnesium, manganese, aluminum, iron, etc. in the furnace. So that the solder on the circuit board is melted.

【0007】[0007]

【作用】本発明のリフロー方法によれば、熱せられた回
路基板の電極や部品の電極が酸化したり、予熱時や溶融
時に半田が酸化されて半田ボールとなることが無い。
According to the reflow method of the present invention, the electrodes of the heated circuit board and the electrodes of the parts are not oxidized, and the solder is not oxidized to become solder balls during preheating or melting.

【0008】さらに炉内にガスを燃焼した際に発生する
水分を除去する水分トラップを備えることにより湿度に
より基板や部品に悪影響を与えることが無い。
Further, by providing a moisture trap for removing moisture generated when the gas is burned in the furnace, the humidity does not adversely affect the substrate and components.

【0009】[0009]

【実施例】以下、本発明のリフロー方法の実施例を図面
を参照しながら説明する。
Embodiments of the reflow method of the present invention will be described below with reference to the drawings.

【0010】(実施例1)リフロー装置の全体構成を示
す図1において本体1の右方より回路基板12が搬送ベ
ルト2により搬送され左の出口で排出される。リフロー
ゾーン17は断熱材3で取り囲まれており、その内部の
上方にガス供給部4が設置されており、外部よりメタン
ガス,プロパンガス,天然ガスなどの燃焼ガス5と水素
に酸素または外気などの気体6が0〜90%の割合で混
合器7で混合されて、本体1の内部で燃焼する。またガ
ス供給部4には点火部8と酸素センサ9が設置されてお
り、混合器7に酸素濃度が酸素センサ9からフィードバ
ックされる。酸素濃度が高いときには、炉内へ供給する
酸素もそくは大気などの気体6の濃度を減少し、酸素濃
度が下がってくると、燃焼ガス5が完全燃焼するように
酸素濃度を調整する。ガス供給部4の下方には、水分ト
ラップ10が設置されている。水分トラップ10は、冷
却触媒または冷却水で冷却した管を炉内に配置して燃焼
ガスが燃焼したときに二酸化炭素とともに発生する水分
を結露させて吸着して、外部へ排出する。
(Embodiment 1) In FIG. 1 showing the overall structure of a reflow apparatus, a circuit board 12 is conveyed from a right side of a main body 1 by a conveyor belt 2 and discharged at a left outlet. The reflow zone 17 is surrounded by a heat insulating material 3, and a gas supply unit 4 is installed above the heat insulating material 3, and a combustion gas 5 such as methane gas, propane gas, and natural gas and hydrogen are supplied from the outside to oxygen or outside air. The gas 6 is mixed in the mixer 7 at a rate of 0 to 90% and burned inside the main body 1. An ignition unit 8 and an oxygen sensor 9 are installed in the gas supply unit 4, and the oxygen concentration is fed back to the mixer 7 from the oxygen sensor 9. When the oxygen concentration is high, the concentration of oxygen or gas 6 such as the atmosphere supplied is reduced, and when the oxygen concentration decreases, the oxygen concentration is adjusted so that the combustion gas 5 is completely burned. A moisture trap 10 is installed below the gas supply unit 4. The water trap 10 arranges a tube cooled with a cooling catalyst or cooling water in the furnace to condense and adsorb the water generated together with carbon dioxide when the combustion gas burns, and discharge it to the outside.

【0011】この下方にはファン11が設けられ、炉内
の空気を循環して温度分布を均一に保つ。なお、このフ
ァン11の周辺に加熱用ヒーター21が設置されること
がある。また、回路基板12が搬送されてくる入口と出
口にはガスを燃焼して発生した二酸化炭素の外部流出を
防ぎ、外気の導入を防ぐ目的で遮へい板13が設置され
ている。この遮へい板13はシャッター式で回路基板1
2の通過時のみ開閉する方法も用いられる。なお、回路
基板12の通過する炉の最初の仕切り内のゾーン14に
紫外線照射部が設けられ、ゾーン15に接着剤を硬化す
る接着剤硬化部を設けることもある。また、予熱ゾーン
16を設け回路基板12やそのうえに載置されたクリー
ム半田や部品を予熱することもある。
A fan 11 is provided below this to circulate the air in the furnace to maintain a uniform temperature distribution. A heating heater 21 may be installed around the fan 11. In addition, a shield plate 13 is installed at the inlet and the outlet where the circuit board 12 is conveyed for the purpose of preventing the outflow of carbon dioxide generated by burning the gas and preventing the introduction of outside air. This shield plate 13 is a shutter type circuit board 1.
A method of opening and closing only when 2 passes is also used. It should be noted that an ultraviolet irradiation section may be provided in the zone 14 in the first partition of the furnace through which the circuit board 12 passes, and an adhesive curing section for curing the adhesive may be provided in the zone 15. In addition, the preheating zone 16 may be provided to preheat the circuit board 12, the cream solder placed on the circuit board 12, or parts.

【0012】(実施例2)次に水分吸収体を順次循環し
て燃焼ガスから発生する水分を吸収する本発明の実施例
2を図2を用いて説明する。本体1は先の例と同様に搬
送ベルト2を備え回路基板12をベルトに載せて入口か
ら出口へ搬送する。水分吸収体18の中には水分を吸収
する物質が詰められており、これが炉内でガスを燃焼す
ることにより発生した水分を吸収する。また、この水分
吸収体18は炉内に設置または図示しない搬送装置によ
って順次本体1内を通過することにより炉内の水分を吸
収する。
(Embodiment 2) Next, Embodiment 2 of the present invention in which moisture generated from the combustion gas is absorbed by sequentially circulating the moisture absorber will be described with reference to FIG. The main body 1 is provided with the conveyor belt 2 as in the previous example, and the circuit board 12 is placed on the belt and conveyed from the inlet to the outlet. The moisture absorber 18 is filled with a substance that absorbs moisture, and this absorbs the moisture generated by burning the gas in the furnace. The moisture absorber 18 absorbs moisture in the furnace by being installed in the furnace or sequentially passing through the main body 1 by a transfer device (not shown).

【0013】(実施例3)第3の実施例として、炉内に
酸素吸収体を設置した例を図3を用いて説明する。図3
において、本体1の内部には、ヒーター21とファン1
1が設置されており熱風を循環して、リフローを行う。
本体1の内部に酸素吸収体22を設置してあり、ここ
で、酸素が吸収されることにより炉内の酸素濃度が減少
して、半田,回路基板,部品の酸化を防ぐ。この酸素吸
収体22は炉内に設置または図示しない搬送装置によっ
て順次炉内を通過させて酸素を吸収させることもある。
また、酸素吸収体22を炉内において、燃焼させて酸素
を吸収することもある。その場合には、点火装置を炉内
に備える。なお酸素吸収体22は、マグネシウム,マン
ガン,アルミニウム,鉄を糸状にしたもの、もしくは粉
末状のものが用いられる。その他活性炭等の有機物多孔
体が用いられることもある。なお、上記実施例では、搬
送ベルト2により回路基板12が連続的に搬送される例
を記したが、回路基板12を炉内にバッチ的に搬入する
こともある。また、何枚かの回路基板12を炉内に搬入
後に炉の入口,出口を閉じて処理を行うこともある。
(Embodiment 3) As a third embodiment, an example in which an oxygen absorber is installed in a furnace will be described with reference to FIG. Figure 3
In the inside of the main body 1, the heater 21 and the fan 1
1 is installed and hot air is circulated for reflow.
An oxygen absorber 22 is installed inside the main body 1, where the oxygen concentration in the furnace is reduced by absorbing oxygen to prevent oxidation of the solder, the circuit board and parts. The oxygen absorber 22 may be installed in the furnace or may be sequentially passed through the furnace by a transfer device (not shown) to absorb oxygen.
Further, the oxygen absorber 22 may be burned in the furnace to absorb oxygen. In that case, an ignition device is provided in the furnace. The oxygen absorber 22 is made of magnesium, manganese, aluminum, iron in the form of threads or powder. Other organic porous materials such as activated carbon may be used. In the above embodiment, the example in which the circuit board 12 is continuously conveyed by the conveyor belt 2 has been described, but the circuit board 12 may be carried into the furnace in batches. Further, after carrying in some of the circuit boards 12 into the furnace, the process may be performed by closing the inlet and outlet of the furnace.

【0014】[0014]

【発明の効果】以上の説明で明らかなように、本発明の
リフロー方法は、炉内の酸素濃度を減じているので、熱
せられた回路基板の電極や部品の電極が酸化したり、予
熱時や溶融時に半田が酸化されて半田ボールとなること
が無い。これにより回路基板の洗浄が不要になる場合も
ある。またIC部品のリードピッチが微細になるに従
い、半田ボールが電極間を短絡させ不良を生じることが
あるが、このようなことが無く、微細ピッチの半田付け
が容易になる。また、従来のリフロー方法では、洗浄を
無くすために弱活性のフラックスを用いることがあった
が、活性力が弱いために、回路基板の電極や部品の電極
に十分半田が濡れないといった不具合が発生していた。
ところが、本発明の方法によれば、酸素濃度の低い炉内
でリフローを行うので濡れ性が低下しなく、そのため弱
活性の洗浄が不要または洗浄が簡単なフラックスを使用
でき、ランニングコストの低減ができる。
As is clear from the above description, the reflow method of the present invention reduces the oxygen concentration in the furnace, so that the electrodes of the heated circuit board and the electrodes of the parts are oxidized or preheated. The solder will not be oxidized and become solder balls when melted. This may eliminate the need for cleaning the circuit board. Further, as the lead pitch of the IC component becomes finer, the solder ball may short-circuit between the electrodes to cause a defect, but this does not occur, and the soldering at a fine pitch becomes easy. In addition, in the conventional reflow method, weakly active flux was sometimes used to eliminate cleaning, but due to its weak activation power, problems such as insufficient solder wetting on the circuit board electrodes and component electrodes occurred. Was.
However, according to the method of the present invention, since reflow is performed in a furnace with a low oxygen concentration, wettability does not decrease, and therefore, weakly active cleaning is unnecessary or a flux that can be easily cleaned can be used, and the running cost can be reduced. it can.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例1のリフロー装置の構成を説明
する図
FIG. 1 is a diagram illustrating a configuration of a reflow device according to a first embodiment of the present invention.

【図2】本発明の実施例2のリフロー装置の構成を説明
する図
FIG. 2 is a diagram illustrating a configuration of a reflow device according to a second embodiment of the present invention.

【図3】本発明の実施例3のリフロー装置の構成を説明
する図
FIG. 3 is a diagram illustrating a configuration of a reflow device according to a third embodiment of the present invention.

【図4】従来のリフロー装置の構成を説明する図FIG. 4 is a diagram illustrating a configuration of a conventional reflow apparatus.

【符号の説明】[Explanation of symbols]

5 燃焼ガス(気体) 10 水分トラップ(管状トラップ) 12 回路基板 18 水分吸収体 22 酸素吸収体 5 Combustion Gas (Gas) 10 Moisture Trap (Tubular Trap) 12 Circuit Board 18 Moisture Absorber 22 Oxygen Absorber

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 リフローする回路基板を、気体を燃焼さ
せて炉内の酸素を希薄にした状態で予熱または半田を溶
融する回路基板の酸素希薄型リフロー方法。
1. A thin oxygen reflow method for a circuit board, comprising preheating or melting solder in a state where oxygen in the furnace is diluted by burning gas in the circuit board to be reflowed.
【請求項2】 気体を燃焼させて炉内の酸素を希薄にす
る燃焼装置を備えた回路基板の酸素希薄型リフロー装
置。
2. A thin oxygen reflow device for a circuit board, which is equipped with a combustor for burning gas to dilute oxygen in the furnace.
【請求項3】 炉内の管状トラップの中に冷却触媒また
は冷却水を流し、トラップの外側に結露した水分を除去
することにより気体の燃焼により発生する炉内の水分を
除去する請求項1記載の回路基板の酸素希薄型リフロー
方法。
3. The water in the furnace generated by the combustion of gas is removed by flowing a cooling catalyst or cooling water into a tubular trap in the furnace to remove the water condensed on the outside of the trap. Oxygen diluted thin reflow method for circuit boards.
【請求項4】 炉内の管状トラップの中に冷却触媒また
は冷却水を流し、トラップの外側に結露した水分を除去
することにより気体の燃焼により発生する炉内の水分を
除去する手段を設けた請求項2記載の回路基板の酸素希
薄型リフロー装置。
4. A means for removing water in the furnace generated by combustion of gas by flowing a cooling catalyst or cooling water into a tubular trap in the furnace and removing water condensed outside the trap is provided. An oxygen dilute thin reflow device for a circuit board according to claim 2.
【請求項5】 水分吸収材を炉内に設置または順次供給
して、気体の燃焼により発生する炉内の水分を除去する
請求項1記載の回路基板の酸素希薄型リフロー方法。
5. The oxygen dilute reflow method for a circuit board according to claim 1, wherein the moisture absorbent is installed in or sequentially supplied to the furnace to remove moisture in the furnace generated by combustion of gas.
【請求項6】 水分吸収材を炉内に設置または順次供給
して、気体の燃焼により発生する炉内の水分を除去する
手段を備えた請求項2記載の回路基板の酸素希薄型リフ
ロー装置。
6. The oxygen dilute reflow device for a circuit board according to claim 2, further comprising means for installing or sequentially supplying a moisture absorbing material in the furnace to remove moisture in the furnace generated by combustion of gas.
【請求項7】 マグネシウム,マンガン,アルミニウ
ム,鉄等の酸化しやすい金属の粉末または糸状切断物、
または活性炭等の多孔質物質を炉内に設置または順次供
給して、それらの燃焼により炉内の酸素濃度を下げる、
リフローする回路基板を炉内の酸素を希薄にした状態で
予熱または半田を溶融する回路基板の酸素希薄型リフロ
ー方法。
7. A powder or thread-like cut product of a metal that easily oxidizes, such as magnesium, manganese, aluminum or iron,
Or, a porous material such as activated carbon is installed in the furnace or sequentially supplied, and the oxygen concentration in the furnace is lowered by burning them.
A method for diluting oxygen in a circuit board, in which the circuit board to be reflowed is preheated or solder is melted while oxygen in the furnace is diluted.
【請求項8】 マグネシウム,マンガン,アルミニウ
ム,鉄等の酸化しやすい金属の粉末または糸状切断物、
または活性炭等の多孔質物質を炉内または炉外の外気導
入口に設置または順次供給して、それらの燃焼により炉
内の酸素濃度を下げる手段を備えた、リフローする回路
基板を炉内の酸素を希薄にした状態で予熱または半田を
溶融する回路基板の酸素希薄型リフロー装置。
8. A powder or thread-shaped cut product of a metal that is easily oxidized, such as magnesium, manganese, aluminum, or iron,
Alternatively, a porous material such as activated carbon is installed or sequentially supplied to the outside air inlet inside or outside the furnace, and the reflowed circuit board is equipped with means for lowering the oxygen concentration in the furnace by burning them. Oxygen thin reflow device for circuit boards that preheats or melts solder in a dilute state.
【請求項9】 マグネシウム,マンガン,アルミニウ
ム,鉄等の酸化しやすい金属の粉末または糸状切断物、
または活性炭等の多孔質物質を充填した容器を炉内に設
置または順次供給し、その容器を炉内で開封することに
より炉内の酸素濃度を下げる、リフローする回路基板を
炉内の酸素を希薄にした状態で予熱または半田を溶融す
る回路基板の酸素希薄型リフロー方法。
9. A powder or thread-shaped cut product of a metal that is easily oxidized, such as magnesium, manganese, aluminum, or iron,
Alternatively, a container filled with a porous material such as activated carbon is placed in the furnace or sequentially supplied, and the oxygen concentration in the furnace is lowered by opening the container in the furnace.The circuit board to be reflowed is diluted with oxygen in the furnace. Oxygen thin thin reflow method of circuit board which preheats or melts solder under the condition.
【請求項10】 マグネシウム,マンガン,アルミニウ
ム,鉄等の酸化しやすい金属の粉末または糸状切断物、
または活性炭等の多孔質物質を充填した容器を炉内に設
置または順次供給し、その容器を炉内で開封することに
より炉内の酸素濃度を下げる手段を備えた、リフローす
る回路基板を炉内の酸素を希薄にした状態で予熱または
半田を溶融する回路基板の酸素希薄型リフロー装置。
10. A powder or thread-like cut product of a metal that easily oxidizes, such as magnesium, manganese, aluminum or iron,
Alternatively, a container filled with a porous material such as activated carbon is installed in the furnace or sequentially supplied, and the container is opened in the furnace to reduce the oxygen concentration in the furnace. Oxygen thin reflow device for circuit boards that preheats or melts solder while diluting oxygen in the above.
JP17808691A 1991-07-18 1991-07-18 Oxygen lean type reflow method and reflow device for circuit board Pending JPH0550285A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17808691A JPH0550285A (en) 1991-07-18 1991-07-18 Oxygen lean type reflow method and reflow device for circuit board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17808691A JPH0550285A (en) 1991-07-18 1991-07-18 Oxygen lean type reflow method and reflow device for circuit board

Publications (1)

Publication Number Publication Date
JPH0550285A true JPH0550285A (en) 1993-03-02

Family

ID=16042386

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17808691A Pending JPH0550285A (en) 1991-07-18 1991-07-18 Oxygen lean type reflow method and reflow device for circuit board

Country Status (1)

Country Link
JP (1) JPH0550285A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06268359A (en) * 1993-03-11 1994-09-22 Nippon Dennetsu Keiki Kk Soldering method
JP2001199905A (en) * 2000-01-12 2001-07-24 Sony Corp Method for degrading organic compound
US20100284237A1 (en) * 2007-10-02 2010-11-11 Yusuke Takemoto Kneading apparatus
US20140269148A1 (en) * 2007-10-02 2014-09-18 Shin Nichinan Co., Ltd. Kneading apparatus
JP2016083699A (en) * 2014-10-28 2016-05-19 株式会社Uacj Brazing furnace and brazing method for aluminium material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06268359A (en) * 1993-03-11 1994-09-22 Nippon Dennetsu Keiki Kk Soldering method
JP2001199905A (en) * 2000-01-12 2001-07-24 Sony Corp Method for degrading organic compound
JP4552247B2 (en) * 2000-01-12 2010-09-29 ソニー株式会社 Method for decomposing an organic compound having an aromatic ring
US20100284237A1 (en) * 2007-10-02 2010-11-11 Yusuke Takemoto Kneading apparatus
US20140269148A1 (en) * 2007-10-02 2014-09-18 Shin Nichinan Co., Ltd. Kneading apparatus
JP2016083699A (en) * 2014-10-28 2016-05-19 株式会社Uacj Brazing furnace and brazing method for aluminium material

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