JPH0548596B2 - - Google Patents
Info
- Publication number
- JPH0548596B2 JPH0548596B2 JP27098984A JP27098984A JPH0548596B2 JP H0548596 B2 JPH0548596 B2 JP H0548596B2 JP 27098984 A JP27098984 A JP 27098984A JP 27098984 A JP27098984 A JP 27098984A JP H0548596 B2 JPH0548596 B2 JP H0548596B2
- Authority
- JP
- Japan
- Prior art keywords
- center electrode
- core
- spark plug
- deformation
- outer peripheral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 230000002093 peripheral effect Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 2
- -1 phosphorus compound Chemical class 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Landscapes
- Spark Plugs (AREA)
Description
(産業上の利用分野)
この発明は複合構造を具えるスパークプラグの
中心電極における芯部の改良に関する。
(従来の技術)
従来、芯部と外周部を別個の構成材とした複合
構造を具えるスパークプラグの中心電極は知られ
ている。この複合構造を具える理由は、耐火花消
耗性、耐熱性に優れるだけではなく、発生した熱
を速やかに放出する熱伝導性に優れていることも
要求されるからである。すなわち、中心電極の外
周部を耐火花消耗性、耐熱性を持たせるため、
NiにCr、Si、Mn、Al、Fe等を添加したNi合金
を用い、芯部には熱伝導の良好なCuを用いてい
たものである。
しかしながら、最近のエンジンの高性能化に伴
い、スパークプラグにも長時間にわたり苛酷な条
件での使用が要求され、かかる条件下において
は、中心電極が芯部のCuと外周部のNi合金との
熱膨張差により発生する熱応力により、変形を生
じ、着火、放電性能の低下をもたらし、スパーク
プラグの性能を劣化することとなるものである。
(発明が解決しようとする問題点)
そこで、この発明は上記従来のものの欠点を改
善し、中心電極の変形を阻止できる構成材を得よ
うとするものである。
(問題点を解決するための手段)
そのために、この発明は、中心電極の芯部の構
成材である燐脱酸銅にFe、Ni、Siを、外周部の
NiにSi、Cr、Mn、AlとFeを添加し、これによ
り中心電極を構成したものである。
(作用)
このように構成することにより、芯部の耐熱性
を向上するものであり、このことは構成材の高温
における結晶粒の成長の抑制することである。こ
の場合、結晶粒の成長を抑制する燐化合物は、
0.015以下添加するものである。
なお、0.015%以上の燐化合物の添加は、熱伝
導特性に障害を与え、中心電極の変形防止効果を
減少させるものである。
(実施例)
これを図に示す実施例により説明すれば、1は
スパークプラグを示し、2はアルミナ磁器の絶縁
体であり、絶縁体2の軸孔2a内にその先端面2
bより露出する中心電極3が挿入されて、軸孔2
aの段部2cに係止され、中心電極3の後端に導
電性ガラスシール4を挾持して抵抗体5が端子電
極6とともに一体に公知の方法により加熱封着さ
れている。この中心電極3の先端と取付金具7に
突設された接地電極3は、芯部10と外周部11
とよりなり、芯部10は前記のとおりFe、Ni、
Siのうち、いずれか1種あるいは2種を0.01〜1.0
%、P、0.015%以下を添加する燐脱酸銅により
構成し、外周部11はSi、Cr、Mn、Al、Fe等を
添加するNi合金により構成したものである。
なお、この発明は、中心電極に関するものであ
るから、それ以外のスパークプラグの構成は、実
施例により限定されるものではないことは勿論で
ある。
次表は、中心電極3の外周部11をSi、Cr、
Mnを1〜2%添加する耐熱Ni合金により構成
し、芯部10を次表のとおりに構成して、6気筒
ガソリンエンジンの各シリンダに装着して長時間
耐久テストを実施した場合の中心電極に変形が発
生する時間を示す。
(Industrial Field of Application) The present invention relates to an improvement in the core of a center electrode of a spark plug having a composite structure. (Prior Art) Conventionally, a center electrode of a spark plug is known which has a composite structure in which a core portion and an outer peripheral portion are made of separate components. The reason for having this composite structure is that it is required not only to have excellent spark consumption resistance and heat resistance, but also to have excellent thermal conductivity to quickly release generated heat. In other words, in order to make the outer periphery of the center electrode spark abrasion resistant and heat resistant,
A Ni alloy made by adding Cr, Si, Mn, Al, Fe, etc. to Ni was used, and the core was made of Cu, which has good thermal conductivity. However, with the recent improvements in engine performance, spark plugs are required to be used for long periods of time under harsh conditions, and under such conditions, the center electrode is made of Cu in the core and Ni alloy in the outer periphery. Thermal stress generated by the difference in thermal expansion causes deformation, resulting in a decrease in ignition and discharge performance, and the performance of the spark plug is deteriorated. (Problems to be Solved by the Invention) Therefore, the present invention aims to improve the above-mentioned drawbacks of the conventional ones and to obtain a constituent material that can prevent deformation of the center electrode. (Means for Solving the Problems) For this purpose, the present invention adds Fe, Ni, and Si to phosphorus-deoxidized copper, which is a constituent material of the core of the center electrode, and
The center electrode is made by adding Si, Cr, Mn, Al, and Fe to Ni. (Function) By configuring in this way, the heat resistance of the core portion is improved, which means that the growth of crystal grains of the constituent materials at high temperatures is suppressed. In this case, the phosphorus compound that suppresses grain growth is
Add 0.015 or less. Note that addition of 0.015% or more of a phosphorus compound impairs thermal conductivity and reduces the deformation prevention effect of the center electrode. (Example) To explain this with an example shown in the figure, 1 indicates a spark plug, 2 is an insulator made of alumina porcelain, and the tip end surface 2 is inserted into the shaft hole 2a of the insulator 2.
The center electrode 3 exposed from b is inserted, and the shaft hole 2
A conductive glass seal 4 is held at the rear end of the center electrode 3, and a resistor 5 and a terminal electrode 6 are integrally heat-sealed by a known method. The ground electrode 3 protruding from the tip of the center electrode 3 and the mounting bracket 7 has a core part 10 and an outer peripheral part 11.
As mentioned above, the core portion 10 is made of Fe, Ni,
0.01 to 1.0 of one or two types of Si
%, P, 0.015% or less, and the outer peripheral portion 11 is made of a Ni alloy to which Si, Cr, Mn, Al, Fe, etc. are added. Note that since the present invention relates to the center electrode, it goes without saying that the other configurations of the spark plug are not limited to the embodiments. The following table shows that the outer peripheral part 11 of the center electrode 3 is Si, Cr,
The center electrode is made of a heat-resistant Ni alloy with 1 to 2% Mn added, the core part 10 is configured as shown in the table below, and a long-term durability test is carried out by attaching it to each cylinder of a 6-cylinder gasoline engine. indicates the time at which deformation occurs.
【表】
上表中、総添加量は1.0%を超えないものとす
る。1.0%以上となると熱伝導特性の低下を伴い、
プラグの性能上の問題を生じる。
このように、この発明は無酸素銅線の変形発生
時間に比べ、その変形発生時間を大巾に遅らせる
ことができ、優れた耐熱性を具えることが明らか
である。
更に、上記中心電極3は、外周部11となる上
面に凹孔を有する母材上に、下方に突出部を有す
る芯部10となる母材を嵌合し、不活性雰囲気又
は真空中において加熱し、両者の接合面を相互拡
散することにより接合し、その後、塑型加工によ
り複合構造を具える中心電極3を形成させるもの
である。
(発明の効果)
以上のとおり、芯部の構成材をこの発明のよう
に構成することにより、耐火花消耗性と耐熱性に
優れるばかりでなく熱伝導性にも優れる複合構造
の中心電極を得られるので、熱変形発生によるス
パークプラグの性能劣化を防止することができる
優れた効果を具えるものである。[Table] In the table above, the total amount added shall not exceed 1.0%. If it exceeds 1.0%, the thermal conductivity properties will decrease,
This will cause plug performance problems. As described above, it is clear that the present invention can significantly delay the deformation occurrence time compared to the deformation occurrence time of oxygen-free copper wire, and has excellent heat resistance. Furthermore, the center electrode 3 is made by fitting a base material that will become the core part 10 having a downwardly protruding part onto a base material that has a concave hole on the upper surface that will become the outer peripheral part 11, and heating it in an inert atmosphere or vacuum. The two bonding surfaces are bonded by mutual diffusion, and then the center electrode 3 having a composite structure is formed by plastic molding. (Effects of the Invention) As described above, by configuring the core component as in the present invention, a center electrode with a composite structure that not only has excellent spark wear resistance and heat resistance but also excellent thermal conductivity can be obtained. Therefore, it has an excellent effect of preventing performance deterioration of the spark plug due to thermal deformation.
第1図はこの発明の中心電極を具えるスパーク
プラグの一部縦断側面図、第2図は中心電極の拡
大図を示す。
1……スパークプラグ、2……絶縁体、2a…
…軸孔、2b……先端面、2c……段部、3……
中心電極、10……芯部、11……外周部。
FIG. 1 shows a partially longitudinal side view of a spark plug equipped with a center electrode according to the present invention, and FIG. 2 shows an enlarged view of the center electrode. 1...Spark plug, 2...Insulator, 2a...
...Shaft hole, 2b...Tip surface, 2c...Step, 3...
Center electrode, 10... core portion, 11... outer peripheral portion.
Claims (1)
るいは2種を0.01〜1.0%、P、0.015%以下を添
加する燐脱酸銅により構成し、外周部をNiを主
成分とするNi合金としたスパークプラグの中心
電極。1. The core is composed of phosphorus-deoxidized copper to which one or two of Fe, Ni, and Si are added at 0.01 to 1.0% and P, 0.015% or less, and the outer periphery is mainly composed of Ni. Center electrode of a spark plug made of Ni alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27098984A JPS61148788A (en) | 1984-12-24 | 1984-12-24 | Center electrode for spark plug |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27098984A JPS61148788A (en) | 1984-12-24 | 1984-12-24 | Center electrode for spark plug |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61148788A JPS61148788A (en) | 1986-07-07 |
JPH0548596B2 true JPH0548596B2 (en) | 1993-07-21 |
Family
ID=17493842
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27098984A Granted JPS61148788A (en) | 1984-12-24 | 1984-12-24 | Center electrode for spark plug |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61148788A (en) |
-
1984
- 1984-12-24 JP JP27098984A patent/JPS61148788A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS61148788A (en) | 1986-07-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5998913A (en) | Spark plug with iridium-rhodium alloy discharge portion | |
EP1309053B1 (en) | Spark plug | |
US20010013746A1 (en) | Spark plug | |
EP2214273A1 (en) | Spark plug | |
US10897123B2 (en) | Spark plug for internal combustion engine having a shaped composite chip on center electrode and/or ground electrode | |
US6794614B2 (en) | Ceramic heater with lead wire connection having brazing material containing a predominant amount of copper | |
US20070277764A1 (en) | Spark plug | |
JPH11273827A (en) | Spark plug | |
JP4295064B2 (en) | Spark plug | |
JPH0548596B2 (en) | ||
JPS5940482A (en) | Spark plug | |
JP2992891B2 (en) | Spark plug for internal combustion engine | |
JPH0548597B2 (en) | ||
JP2004206931A (en) | Electrode material for spark plug | |
JPS61148790A (en) | Center electrode for spark plug | |
JPH04366580A (en) | Spark plug | |
JP3128270B2 (en) | Spark plug | |
JPS61135080A (en) | Spark plug | |
JP2004206892A (en) | Spark plug | |
US7352121B2 (en) | Spark plug | |
JP2003105467A (en) | Spark plug | |
JP2805322B2 (en) | Spark plug for internal combustion engine | |
JPH0548598B2 (en) | ||
JP2002359052A (en) | Composite electrode material for ignition | |
JP2002359053A (en) | Composite electrode material for ignition |