JPH0544033B2 - - Google Patents
Info
- Publication number
- JPH0544033B2 JPH0544033B2 JP56127385A JP12738581A JPH0544033B2 JP H0544033 B2 JPH0544033 B2 JP H0544033B2 JP 56127385 A JP56127385 A JP 56127385A JP 12738581 A JP12738581 A JP 12738581A JP H0544033 B2 JPH0544033 B2 JP H0544033B2
- Authority
- JP
- Japan
- Prior art keywords
- toner
- photosensitive layer
- binder
- toner image
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 claims description 25
- 239000011230 binding agent Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 23
- 238000005530 etching Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 9
- 238000011282 treatment Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000005660 hydrophilic surface Effects 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 10
- -1 maleic acid ester Chemical class 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- 239000002989 correction material Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001414 amino alcohols Chemical class 0.000 description 2
- 238000002048 anodisation reaction Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229940097275 indigo Drugs 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- ZUBZATZOEPUUQF-UHFFFAOYSA-N isononane Chemical compound CCCCCCC(C)C ZUBZATZOEPUUQF-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000005453 ketone based solvent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003348 petrochemical agent Substances 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- FLIMNTJKWXTBRB-UHFFFAOYSA-N 1-ethenylanthracene;1-ethenyl-9h-carbazole Chemical compound C12=CC=CC=C2NC2=C1C=CC=C2C=C.C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 FLIMNTJKWXTBRB-UHFFFAOYSA-N 0.000 description 1
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 1
- VPTNBOIEKNYSFL-UHFFFAOYSA-N 1-n,1-n,4-n,4-n-tetrabenzylbenzene-1,4-diamine Chemical compound C=1C=CC=CC=1CN(C=1C=CC(=CC=1)N(CC=1C=CC=CC=1)CC=1C=CC=CC=1)CC1=CC=CC=C1 VPTNBOIEKNYSFL-UHFFFAOYSA-N 0.000 description 1
- FBNAYEYTRHHEOB-UHFFFAOYSA-N 2,3,5-triphenyl-1,3-dihydropyrazole Chemical compound N1N(C=2C=CC=CC=2)C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 FBNAYEYTRHHEOB-UHFFFAOYSA-N 0.000 description 1
- AXSVCKIFQVONHI-UHFFFAOYSA-N 2,3-bis(4-methoxyphenyl)-1-benzofuran-6-ol Chemical compound C1=CC(OC)=CC=C1C1=C(C=2C=CC(OC)=CC=2)C2=CC=C(O)C=C2O1 AXSVCKIFQVONHI-UHFFFAOYSA-N 0.000 description 1
- BIECIOFZIILAAK-UHFFFAOYSA-N 2,3-diphenyl-5-(2-phenylethenyl)-1,3-dihydropyrazole Chemical compound N1N(C=2C=CC=CC=2)C(C=2C=CC=CC=2)C=C1C=CC1=CC=CC=C1 BIECIOFZIILAAK-UHFFFAOYSA-N 0.000 description 1
- FPQJIXBKABHGGB-UHFFFAOYSA-N 2,5-diphenyl-3-(2-phenylethenyl)-1,3-dihydropyrazole Chemical compound C1=C(C=2C=CC=CC=2)NN(C=2C=CC=CC=2)C1C=CC1=CC=CC=C1 FPQJIXBKABHGGB-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- OFQGIIIVIXXLRO-UHFFFAOYSA-N 3h-1,3-benzoxazole-2-thione;lead Chemical compound [Pb].C1=CC=C2OC(=S)NC2=C1 OFQGIIIVIXXLRO-UHFFFAOYSA-N 0.000 description 1
- UECMVEOOXQNVNB-UHFFFAOYSA-N 4-(2,5-diphenyl-1,3-dihydropyrazol-3-yl)-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1N(C=2C=CC=CC=2)NC(C=2C=CC=CC=2)=C1 UECMVEOOXQNVNB-UHFFFAOYSA-N 0.000 description 1
- JMMDGDGHMXNNFA-UHFFFAOYSA-N 4-(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C(N=C1C=2N=CC=CC=2)=NN=C1C1=CC=CC=N1 JMMDGDGHMXNNFA-UHFFFAOYSA-N 0.000 description 1
- ABXTYDGWJJUHGM-UHFFFAOYSA-N 4-methyl-n-[4-[1-[4-(4-methyl-n-(4-methylphenyl)anilino)phenyl]-1-phenylethyl]phenyl]-n-(4-methylphenyl)aniline Chemical compound C1=CC(C)=CC=C1N(C=1C=CC(=CC=1)C(C)(C=1C=CC=CC=1)C=1C=CC(=CC=1)N(C=1C=CC(C)=CC=1)C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 ABXTYDGWJJUHGM-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzyl acetone Natural products CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- VOOQRJIZEJHBGL-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCCCOC(=O)C(C)=C VOOQRJIZEJHBGL-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- DFMLSRDIJDAQBV-UHFFFAOYSA-N copper 5-methyl-2-phenyldiazenylphenol Chemical compound [Cu].OC1=C(C=CC(=C1)C)N=NC1=CC=CC=C1 DFMLSRDIJDAQBV-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229940061607 dibasic sodium phosphate Drugs 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 229940105994 ethylhexyl acetate Drugs 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- XMSHLUJZPODALA-UHFFFAOYSA-N lead;5-methoxy-1,3-dihydrobenzimidazole-2-thione Chemical compound [Pb].COC1=CC=C2NC(=S)NC2=C1 XMSHLUJZPODALA-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- CIPVVROJHKLHJI-UHFFFAOYSA-N n,n-diethyl-3-methylaniline Chemical compound CCN(CC)C1=CC=CC(C)=C1 CIPVVROJHKLHJI-UHFFFAOYSA-N 0.000 description 1
- VQVQWNNWJNMZFS-UHFFFAOYSA-N n,n-dimethyl-4-(2-phenylquinazolin-4-yl)aniline Chemical compound C1=CC(N(C)C)=CC=C1C1=NC(C=2C=CC=CC=2)=NC2=CC=CC=C12 VQVQWNNWJNMZFS-UHFFFAOYSA-N 0.000 description 1
- BDMYVUTVARPUCD-UHFFFAOYSA-N n-benzyl-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C=1C=C2C=CC=CC2=CC=1N(C=1C=C2C=CC=CC2=CC=1)CC1=CC=CC=C1 BDMYVUTVARPUCD-UHFFFAOYSA-N 0.000 description 1
- FKJARBPQBIATJT-UHFFFAOYSA-N n-benzyl-n-phenylaniline Chemical compound C=1C=CC=CC=1CN(C=1C=CC=CC=1)C1=CC=CC=C1 FKJARBPQBIATJT-UHFFFAOYSA-N 0.000 description 1
- 229940017144 n-butyl lactate Drugs 0.000 description 1
- VRUKENOGLFMZNY-UHFFFAOYSA-N n-cyclohexyl-n-phenylaniline Chemical compound C1CCCCC1N(C=1C=CC=CC=1)C1=CC=CC=C1 VRUKENOGLFMZNY-UHFFFAOYSA-N 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- INAAIJLSXJJHOZ-UHFFFAOYSA-N pibenzimol Chemical compound C1CN(C)CCN1C1=CC=C(N=C(N2)C=3C=C4NC(=NC4=CC=3)C=3C=CC(O)=CC=3)C2=C1 INAAIJLSXJJHOZ-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003513 tertiary aromatic amines Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- PGNWIWKMXVDXHP-UHFFFAOYSA-L zinc;1,3-benzothiazole-2-thiolate Chemical compound [Zn+2].C1=CC=C2SC([S-])=NC2=C1.C1=CC=C2SC([S-])=NC2=C1 PGNWIWKMXVDXHP-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/26—Electrographic processes using a charge pattern for the production of printing plates for non-xerographic printing processes
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Description
【発明の詳細な説明】
本発明は、印刷版の修正方法を包含し、有機光
導電性化合物を用いて電子写真法によりトナー画
像を形成し、トナー画像形成部以外の感光層をエ
ツチング処理して製版される印刷版の製版方法に
関する。DETAILED DESCRIPTION OF THE INVENTION The present invention includes a method for correcting a printing plate, in which a toner image is formed by electrophotography using an organic photoconductive compound, and a photosensitive layer other than the toner image forming area is etched. This invention relates to a method for making printing plates that are made by plate making.
有機光導電性化合物を用いた電子写真印刷版は
既に多く知られており、例えば特公昭37−17162
号、同38−6961号、同41−2426号、同46−39405
号、特開昭50−19509号、同50−19510号、同54−
19803号、同54−89801号、同54−134632号、同54
−145538号、同55−105254号等が挙げられる。一
般的な製版方法によれば、有機光導電性化合物を
用いた電子写真印刷原版を通常の電子写真方法に
よつてトナー画像を形成し、その後、トナー画像
以外の非画像部をアルカリ剤を含有するエツチン
グ溶液で処理することによつて製版される。 Many electrophotographic printing plates using organic photoconductive compounds are already known.
No. 38-6961, No. 41-2426, No. 46-39405
No., JP-A No. 50-19509, No. 50-19510, No. 54-
No. 19803, No. 54-89801, No. 54-134632, No. 54
-145538, 55-105254, etc. According to a general plate-making method, a toner image is formed on an electrophotographic original plate using an organic photoconductive compound by a normal electrophotographic method, and then a non-image area other than the toner image is removed using an alkaline agent. The plate is made by treating it with an etching solution.
画像形成に用いるトナーは、いわゆる乾式トナ
ー、湿式トナーのいずれも用いることができる
が、解像力の優れた印刷物を得る上では、液体現
像法による湿式トナーの方がはるかに好ましい。 As the toner used for image formation, both so-called dry toner and wet toner can be used, but in order to obtain printed matter with excellent resolution, wet toner using a liquid development method is far more preferable.
トナーのエツチング性と感光層のエツチング性
との差を利用して製版される既述の電子写真印刷
版では、乾式トナーあるいは湿式トナーいずれで
あつても、トナーは全くエツチングされずトナー
付着部以外の感光層部のみが迅速にエツチングさ
れることによつて、細線再現性の良好な高品質の
印刷物が得られる。 In the above-mentioned electrophotographic printing plates, which are made using the difference between the etching properties of the toner and the photosensitive layer, the toner is not etched at all, except for the areas to which the toner is attached, regardless of whether it is a dry toner or a wet toner. By quickly etching only the photosensitive layer portion, high quality printed matter with good fine line reproducibility can be obtained.
トナーは、エツチングされず、従つてエツチン
グの際にレジスト性があることのみならず、疎水
性でインキ受容性があり、かつ多数枚の印刷に耐
え得るだけの接着性を有していなければならな
い。一方、感光層は、トナーに比べてはるかにエ
ツチングされ易く、また過度にエツチングされな
いものが必要とされる反面、エツチングした後、
トナーを多数枚の印刷に耐える程度に保持しうる
強固な皮膜形成性を有していなければならない。 The toner must not only be non-etchable and therefore resistant to etching, but also be hydrophobic, ink-receptive, and have sufficient adhesion to withstand multiple printings. . On the other hand, the photosensitive layer is much more easily etched than the toner, and while it is required that it not be excessively etched, on the other hand, after etching,
It must have strong film-forming properties that can retain toner to the extent that it can withstand printing on a large number of sheets.
そのような特性を有する感光層のバインダーと
しては、スチレン無水マレイン酸共重合体、マレ
イン酸エステル樹脂、酢酸ビニル−クロトン酸共
重合体、酢酸ビニル−無水マレイン酸共重合体、
アクリル酸エステル、メタクリル酸エステル、フ
エノール樹脂などがあり、これらバインダーは、
分子量が大きく、好ましくは約30000〜約300000
であり、アルカリ水溶液でエツチングされるため
に酸価が大きく、好ましくは約80〜約300である
ものが特に適している。 Examples of the binder for the photosensitive layer having such characteristics include styrene maleic anhydride copolymer, maleic acid ester resin, vinyl acetate-crotonic acid copolymer, vinyl acetate-maleic anhydride copolymer,
These binders include acrylic esters, methacrylic esters, and phenolic resins.
High molecular weight, preferably about 30,000 to about 300,000
A material having a high acid value, preferably about 80 to about 300, is particularly suitable because it can be etched with an alkaline aqueous solution.
既述した印刷版では、エツチングされた箇所は
通常、親水性支持体表面が露出し、インキ反揆性
となる。エツチングが不完全で感光層バインダー
等が残留したりするとそのものが通常、親油性・
インキ受理性を示すので不都合となる。ところ
で、写真製版法で得られた印刷版に生じた不必要
な画像部分を適当な処理液で処理することによつ
てインキ反揆性にする、いわゆる修正作業は重要
な操作である。修正の必要な箇所としては、オリ
ジナル中に既に存在するもの、露光の際に生じる
もの、及びその他不均一な現像処理過程によつて
生じるもの等がある。すなわち、複写オリジナル
中に不必要な画像が存在していたり、塵および汚
物、微粒子、指紋または他の汚れが存在していた
り、あるいは各種の原稿を貼り合わせて作つた原
稿をオリジナルとして使用する場合、露出時にお
いて影が写し出されたりする。良好な印刷物を得
る為にはこれらの箇所はいずれも製版、印刷の段
階で修正されなければならない。 In the above-mentioned printing plates, the etched areas usually expose the surface of the hydrophilic support and become ink repellent. If the etching is incomplete and the photosensitive layer binder remains, the binder is usually oleophilic or
This is inconvenient because it indicates ink receptivity. Incidentally, the so-called correction operation, in which unnecessary image areas generated on a printing plate obtained by photolithography are treated with an appropriate treatment liquid to make them ink repellent, is an important operation. The areas that need to be corrected include those that already exist in the original, those that occur during exposure, and those that result from other non-uniform development processes. i.e., if there are unwanted images in the reproduced original, if there are dust and dirt, particulates, fingerprints or other contamination, or if the original is made by pasting together various originals. , shadows may appear during exposure. In order to obtain good printed matter, all of these points must be corrected at the plate-making and printing stages.
印刷版の修正に要求されることは、簡便な操作
であること、修正が確実であること、印刷特性基
材等に何らの支障をきたさないこと、特に隣接す
る画像部まで影響して不良な印刷物とならないこ
と、修正効果が持続すること等である。本発明の
目的は、修正法としての上記要求を満たす製版方
法を提供することである。 What is required for correction of printing plates is that the operation is simple, that the correction is reliable, that there is no problem with the printing properties of the base material, etc., and that there is no possibility that defects may affect adjacent image areas. These include not being printed, and the correction effect lasting. An object of the present invention is to provide a plate-making method that satisfies the above requirements as a correction method.
本発明は、親水性表面を有する導電性支持体上
に、有機光導電性化合物及びアルカリ水溶液でエ
ツチングされるバインダーを含む感光層を有する
印刷用原版を、電子写真法によつてエツチング液
に対してレジスト性を有するトナー画像を形成し
た後、実質的に感光層バインダーを溶解せず、且
つ不必要なトナー画像部分を少なくともレジスト
性を有しない程度に溶解除去するように修正液で
修正し、次いでアルカリ剤を含有するエツチング
溶液で処理してトナー画像以外の非画像部の感光
層を除去する製版方法からなる。 In the present invention, a printing original plate having a photosensitive layer containing an organic photoconductive compound and a binder that can be etched with an alkaline aqueous solution on a conductive support having a hydrophilic surface is etched against an etching solution by an electrophotographic method. After forming a toner image having resist properties, correcting with a correction liquid so as not to substantially dissolve the photosensitive layer binder and to dissolve and remove unnecessary toner image portions at least to the extent that they do not have resist properties; The plate-making method then involves processing with an etching solution containing an alkaline agent to remove the photosensitive layer in non-image areas other than the toner image.
本発明の特長、利点の1つは、修正すべき不要
なトナー画像の状況に応じた修正液を適用できる
ことである。実質的に感光層バインダーを溶解し
ないとは、実質的に支持体の親水性表面が露出し
てしまわない程度までは溶解してもよいことを包
含して意味し、トナーの溶解とともに感光層バイ
ンダーのある程度の溶解、除去を許容する修正液
であることができる。このような溶解能の大きな
修正液は、周囲に必要なトナー画像部が存在しな
いとか修正部分が大面積である場合等に適してい
る。感光層バインダーを完全に溶解するもので
は、引続くエツチング処理を施してもトナーが支
持体の親水性表面、例えばアルミニウム支持体に
陽極酸化等により設けられた微細孔に入り込んだ
り、付着したりしてエツチングされず、インキ汚
れの欠点になつたりする場合があつたり、また隣
接するトナー画像の下の感光層までも溶解する危
険性が大きくなる。 One of the features and advantages of the present invention is that correction fluid can be applied depending on the situation of the unwanted toner image to be corrected. Not substantially dissolving the photosensitive layer binder means that it may be dissolved to the extent that the hydrophilic surface of the support is not substantially exposed, and the photosensitive layer binder may be dissolved as the toner is dissolved. The correction fluid may be a correction fluid that allows some degree of dissolution or removal of. Such a correction liquid with a high dissolving power is suitable when there is no necessary toner image area around the area or when the area to be corrected is large. If the binder of the photosensitive layer is completely dissolved, the toner will not enter or adhere to the hydrophilic surface of the support, for example, the fine pores provided by anodization on the aluminum support, even after subsequent etching treatment. The toner image may not be etched, resulting in ink stain defects, and there is also a greater risk that the photosensitive layer beneath the adjacent toner image will also be dissolved.
さらに少なくともレジスト性が得られない程度
にトナーを溶解除去するとは、修正すべきトナー
を完全に溶解除去しうることは勿論、トナーの溶
解除去が不十分であつても、引続くエツチング処
理によつてそのトナーの下の感光層からエツチン
グされ、トナーのレジストが形成されないことを
包含して意味する。このようなトナーの溶解能の
比較的小さな修正液でも、その後のエツチング処
理によつて完全に修正され、従つて隣接するトナ
ー画像が存在するような部分の修正も可能となる
利点を有している。 Furthermore, dissolving and removing the toner to such an extent that resist properties cannot be obtained does not only mean that the toner to be corrected can be completely dissolved and removed, but even if the toner is not sufficiently dissolved and removed, the subsequent etching process may This includes the fact that the photosensitive layer beneath the toner is etched away and no resist of the toner is formed. Even a correction liquid having a relatively low ability to dissolve toner can be completely corrected by the subsequent etching process, and has the advantage that it is also possible to correct areas where adjacent toner images exist. There is.
不必要なトナー画像を引続くエツチング処理に
よつて少なくともレジスト性がなくなる程度に溶
解し、且つそのトナー画像の下の感光層バインダ
ーを多くとも親水性支持体表面が露出しない程度
に溶解してもよい修正液は、トナーの種類と感光
層バインダーの種類との組合わせに大きく依存す
るが当業者は簡単な実験によつて適切な修正液を
見出すことができる。 The unnecessary toner image is dissolved by the subsequent etching process at least to the extent that resist properties are lost, and the photosensitive layer binder under the toner image is dissolved at most to the extent that the surface of the hydrophilic support is not exposed. A good correction fluid is highly dependent on the combination of the type of toner and the type of photosensitive layer binder, but one skilled in the art can find a suitable correction fluid by simple experimentation.
トナーの種類と感光層バインダーの種類との組
合わせによつて用いうる液体としては、例えばベ
ンゼン、トルエン、キシレン等の芳香族炭化水素
系溶剤、トリフロルエチレン、塩化メチレン等の
ハロゲン化炭化水素系溶剤、アセトン、メチルエ
チルケトン等のケトン系溶剤、テトラヒドロフラ
ン等のフラン系溶剤、エチルブチルエーテル、エ
チレングリコールモノメチルエーテル等のエーテ
ル系溶剤、n−ヘキサン、n−オクタン、n−デ
カン、n−ドデカン、イソヘプタン、イソノナ
ン、イソドデカン及びこれらの混合物であるアイ
ソパ−E、アイソパ−G、アイソパ−H(いずれ
もエツソ石油化学製イソパラフイン系溶剤の商品
名)、シエルゾル71(シエル石油化学製のイソパラ
フイン系溶剤の商品名)、リグロイン、ミネラル
スピリツト、ケロシン等の脂肪族炭化水素系溶
剤、酢酸n−ブチル、酢酸z−エチルヘキシル、
酢酸エチレングリコールモノメチルエーテル、乳
酸エチル乳酸n−ブチル等のエステル系溶剤など
を挙げることができ、これらをトナーの種類およ
び感光層バインダーの種類に応じて1種あるいは
2種以上混合して使用することができる。 Examples of liquids that can be used depending on the combination of toner type and photosensitive layer binder include aromatic hydrocarbon solvents such as benzene, toluene, and xylene, and halogenated hydrocarbon solvents such as trifluoroethylene and methylene chloride. Solvents, ketone solvents such as acetone and methyl ethyl ketone, furan solvents such as tetrahydrofuran, ether solvents such as ethyl butyl ether and ethylene glycol monomethyl ether, n-hexane, n-octane, n-decane, n-dodecane, isoheptane, isononane , isododecane and their mixtures Isopa-E, Isopa-G, Isopa-H (all are trade names of isoparaffinic solvents manufactured by Etsuso Petrochemicals), Ciel Sol 71 (trade names of isoparaffinic solvents manufactured by Ciel Petrochemicals) ), ligroin, mineral spirits, aliphatic hydrocarbon solvents such as kerosene, n-butyl acetate, z-ethylhexyl acetate,
Examples include ester solvents such as ethylene glycol monomethyl ether acetate, ethyl lactate and n-butyl lactate, and these may be used singly or in a mixture of two or more depending on the type of toner and the type of photosensitive layer binder. I can do it.
特に好ましい修正液は、ケトン系溶剤、フラン
系溶剤、ブタノール、ベンジルアルコール等のア
ルコール系溶剤の如き水混和性有機溶剤であり、
このものは、修正処理後、直ちにアルカリ性エツ
チング水溶液で処理しても、修正およびエツチン
グ処理が均一に迅速にできる利点を有している。 Particularly preferred correction fluids are water-miscible organic solvents such as ketone solvents, furan solvents, alcohol solvents such as butanol, benzyl alcohol, etc.
This product has the advantage that even if it is treated with an aqueous alkaline etching solution immediately after the correction process, the correction and etching processes can be performed uniformly and quickly.
本発明に用いられる既述したような要件を満た
すトナーとしては、例えばスチレン系樹脂、アク
リル系樹脂、ポリエステル系樹脂、エポキシ樹脂
等が挙げられる。またトナーの安全性や定着性に
悪影響を及ぼさない範囲で着色の為の顔料や染
料、さらに電荷制御剤を含有することが実用上好
ましい。 Examples of toners that meet the above-mentioned requirements used in the present invention include styrene resins, acrylic resins, polyester resins, and epoxy resins. Further, it is practically preferable to contain pigments and dyes for coloring, and a charge control agent within a range that does not adversely affect the safety and fixing properties of the toner.
本発明に用いる電子写真印刷版は、有機光導電
性化合物を含む感光層バインダーとして、分子量
が大きく、かつ酸価が大きいものを用いることが
好ましい。分子量は約3万以上、好ましくは約5
万〜約30万、酸価は約80以上、好ましくは約100
〜約300のものである。 In the electrophotographic printing plate used in the present invention, it is preferable to use a photosensitive layer binder containing an organic photoconductive compound that has a large molecular weight and a large acid value. Molecular weight is about 30,000 or more, preferably about 5
300,000 to about 300,000, acid value is about 80 or more, preferably about 100
~300 things.
本発明に用いられる印刷版に用いる有機光導電
性化合物として、例えば次のような化合物が挙げ
られる。 Examples of the organic photoconductive compound used in the printing plate used in the present invention include the following compounds.
(a) 芳香族第3級アミノ化合物:トリフエニルア
ミン、ジフエニルベンジルアミン、ジ−(β−
ナフチル)ベンジルアミン、ジフエニルシクロ
ヘキシルアミン等。(a) Aromatic tertiary amino compounds: triphenylamine, diphenylbenzylamine, di-(β-
naphthyl) benzylamine, diphenylcyclohexylamine, etc.
(b) 芳香族第3級ジアミノ化合物:N,N,N′,
N′−テトラベンジル−P−フエニレンジアミ
ン、N,N,N′,N′−テトラベンジルベンジ
シン、1,1′−ビス−(4−N,N−ジベンジ
ルアミノフエニル)−エタン、2,2−ビス−
(4−N,N−ジベンジルアミノフエニル)−ブ
タン、ビス−(4−N,N−ジ−(P−クロロベ
ンジルアミノフエニル))−メタン、3,3−ジ
フエニルアリリジン−4,4′−ビス(N,N−
ジエチル−m−トルイジン)、4,4′−ビス
(ジ−p−トリルアミノ)−1,1,1−トリフ
エニルエタン等。(b) Aromatic tertiary diamino compound: N, N, N',
N'-tetrabenzyl-P-phenylenediamine, N,N,N',N'-tetrabenzylbenzicine, 1,1'-bis-(4-N,N-dibenzylaminophenyl)-ethane, 2,2-bis-
(4-N,N-dibenzylaminophenyl)-butane, bis-(4-N,N-di-(P-chlorobenzylaminophenyl))-methane, 3,3-diphenylallyridine-4 ,4'-bis(N,N-
diethyl-m-toluidine), 4,4'-bis(di-p-tolylamino)-1,1,1-triphenylethane, etc.
(c) 芳香族第3級トリアミノ化合物:4,4′,
4″−トリス(ジエチルアミノフエニル)メタ
ン、4−ジメチルアミノ4,4″−ビス(ジエチ
ルアミノ)−2,2″−ジメチル−トリフエニル
メタン等。(c) Aromatic tertiary triamino compound: 4,4',
4″-tris(diethylaminophenyl)methane, 4-dimethylamino 4,4″-bis(diethylamino)-2,2″-dimethyl-triphenylmethane, etc.
(d) 縮合主成物:アルデヒドと芳香族アミンの縮
合生成物、第3級芳香族アミンと芳香族ハロゲ
ン化物の反応物、ポリ−p−フエニレン−1,
3,4−オキサジアゾール、ホルムアルデヒド
と縮合多環化合物の反応物等。(d) Main condensation product: condensation product of aldehyde and aromatic amine, reaction product of tertiary aromatic amine and aromatic halide, poly-p-phenylene-1,
3,4-oxadiazole, a reaction product of formaldehyde and a condensed polycyclic compound, etc.
(e) 金属含有化合物:2−メルカプト−ベンゾチ
アゾール亜鉛塩、2−メルカプト−ベンゾオキ
サゾール鉛塩、2−メルカプト−6−メトキシ
ベンゾイミダゾール−鉛塩、s−ヒドロキシ−
キノリン−アルミニウム塩、2−ヒドロキシ−
4−メチル−アゾベンゼン−銅塩、
(f) ポリビニルカルバゾール化合物:ポリビニル
カルバゾール、ハロゲン置換ポリビニルカルバ
ゾール、ビニルカルバゾールとスチレンの共重
合体、ビニルアントラセン−ビニルカルバゾー
ルの共重合体等。(e) Metal-containing compounds: 2-mercapto-benzothiazole zinc salt, 2-mercapto-benzoxazole lead salt, 2-mercapto-6-methoxybenzimidazole-lead salt, s-hydroxy-
Quinoline-aluminum salt, 2-hydroxy-
4-methyl-azobenzene-copper salt, (f) polyvinylcarbazole compound: polyvinylcarbazole, halogen-substituted polyvinylcarbazole, copolymer of vinylcarbazole and styrene, copolymer of vinylanthracene-vinylcarbazole, etc.
(g) 複素環化合物:1,3,5−トリフエニル−
ピラゾリン1−フエニル−3−(p−ジメチル
アミノスチリル)−5−(p−ジメチルアミノフ
エニル)−ピラゾリン、1,5−ジフエニル−
3−スチリル−ピラゾリン、1,3−ジフエニ
ル−5−スチリル−ピラゾリン、1,3−ジフ
エニル−5−(p−ジメチルアミノフエニル)−
ピラゾリン、3−(4′−ジメチルアミノフエニ
ル)−5,6−ジ−(4″−メトキシフエニル)−
1,2,4−トリアジン、3−(4′−ジメチル
アミノフエニル)−5,6−ジピリジル−1,
2,4−トリアジン、2−フエニル−4−
(4′−ジメチルアミノフエニル)−キナゾリン、
6−ヒドロキシ−2,3−ジ(p−メトキシフ
エニル)−ベンゾフラン、2,5−ビス−〔4′−
エチルアミノ−フエニル−(1′)〕−1,3,4
−オキサジアゾール等。(g) Heterocyclic compound: 1,3,5-triphenyl-
Pyrazoline 1-phenyl-3-(p-dimethylaminostyryl)-5-(p-dimethylaminophenyl)-pyrazoline, 1,5-diphenyl-
3-styryl-pyrazoline, 1,3-diphenyl-5-styryl-pyrazoline, 1,3-diphenyl-5-(p-dimethylaminophenyl)-
Pyrazoline, 3-(4′-dimethylaminophenyl)-5,6-di-(4″-methoxyphenyl)-
1,2,4-triazine, 3-(4'-dimethylaminophenyl)-5,6-dipyridyl-1,
2,4-triazine, 2-phenyl-4-
(4′-dimethylaminophenyl)-quinazoline,
6-hydroxy-2,3-di(p-methoxyphenyl)-benzofuran, 2,5-bis-[4'-
ethylamino-phenyl-(1')]-1,3,4
-Oxadiazole etc.
又本発明に用いられる有機光導電性化合物はフ
タロシアニン顔料、キナクリドン顔料、インジゴ
顔料、シアニン顔料、ペリレン顔料、ビスベンズ
イミダゾール顔料、キノン顔料、アゾ顔料、イン
ジゴ顔料等の顔料を用いても良好な印刷版が得ら
れる。 The organic photoconductive compound used in the present invention can also be used for good printing using pigments such as phthalocyanine pigments, quinacridone pigments, indigo pigments, cyanine pigments, perylene pigments, bisbenzimidazole pigments, quinone pigments, azo pigments, and indigo pigments. You can get the version.
本発明に於る印刷版用のベースとしては、従来
より知られている印刷版用ベースの全てが使用で
きる。例えば、アルミ板、亜鉛板、マグネシウム
板、銅板等の金属板。ポリエステル、酢酸セルロ
ース、ポリスチレン、ポリカーボネート、ポリア
ミド、ポリプロピレン等のフイルムや合成紙。レ
ジンコーテツドされた紙等の加工紙などが挙げら
れるが、画像形成後エツチング処理によつて光導
電性化合物及びバインダーが除去され、非画像部
が親水性の性質を有さねばならない為に、疎水性
表面を有するベースはあらかじめ親水化処理をし
ておく必要がある。金属板、特にアルミ板が最も
好適であるが、砂目立て処理、アルカリ処理、酸
処理、陽極酸化等の表面処理が好ましい。又フイ
ルム類の場合は親水性の比較的高い高分子化合物
をコーテイングし架橋処理をしておくか、又はあ
る種の金属を蒸着又は貼合せをしておくと良い。
絶縁性のベースを用いる場合はベース表面に導電
性処理を施す事が必要である。 As the base for the printing plate in the present invention, all conventionally known bases for printing plates can be used. For example, metal plates such as aluminum plates, zinc plates, magnesium plates, copper plates, etc. Films and synthetic papers made of polyester, cellulose acetate, polystyrene, polycarbonate, polyamide, polypropylene, etc. Examples include processed paper such as resin-coated paper, but the photoconductive compound and binder are removed by etching after image formation, and the non-image area must have hydrophilic properties, so hydrophobic The base having a surface needs to be hydrophilized in advance. A metal plate, especially an aluminum plate, is most suitable, but surface treatments such as graining, alkali treatment, acid treatment, and anodization are preferred. In the case of films, it is preferable to coat them with a relatively highly hydrophilic polymer compound and perform crosslinking treatment, or to vapor-deposit or bond them with a certain type of metal.
When using an insulating base, it is necessary to perform conductive treatment on the base surface.
印刷用原版を製造するには、前記光導電性化合
物とバインダーを溶媒中に溶解し(光導電性化合
物が溶解しない場合はコロイドミル、ホモゲナイ
ザー、超音波分散機等を用いて分散液とする)、
増感色素等を加えて前記支持体上に厚みが1〜
30μになるように塗布乾燥する。光導電性化合物
とバインダーの比は光導電性化合物1重量部に対
してバインダーが0.01〜50重量部、好ましくは用
いるバインダー、光導電性化合物によつて異なる
が0.2〜10重量部の範囲が適当である。 To produce a printing original plate, the photoconductive compound and binder are dissolved in a solvent (if the photoconductive compound is not dissolved, a dispersion liquid is prepared using a colloid mill, homogenizer, ultrasonic dispersion machine, etc.). ,
A sensitizing dye etc. is added to the support to a thickness of 1~
Apply to a thickness of 30μ and dry. The ratio of the photoconductive compound to the binder is 0.01 to 50 parts by weight, preferably 0.2 to 10 parts by weight, depending on the binder and photoconductive compound used, per 1 part by weight of the photoconductive compound. It is.
溶媒として使用できるものは、バインダーを溶
解可能でかつ光導電性化合物の溶解又は分散が可
能な全ての有機溶剤を含む。 Those that can be used as solvents include all organic solvents that are capable of dissolving the binder and dissolving or dispersing the photoconductive compound.
本発明に用いるエツチング処理液には、アルカ
リ剤として水酸化ナトリウム、水酸化カリウム、
ケイ酸ナトリウム、ケイ酸カリウム、第三リン酸
ナトリウム、第二リン酸ナトリウム、第三リン酸
アンモニウム、メタケイ酸ナトリウム、炭酸ナト
リウム、アンモニアなどの無機アルカリ剤、モノ
メチルアミン、ジメチルアミン、トリメチルアミ
ン、モノエチルアミン、ジエチルアミン、トリエ
チルアミン、モノイソプロピルアミン、ジイソプ
ロピルアミン、n−ブチルアミン等のアルキルア
ミン類、モノ−、ジ−またはトリエタノールアミ
ン、モノイソプロパノールアミン、ジイソプロパ
ノールアミン、トリイソプロパノールアミン等の
アミノアルコール類、エチレンアミン、エチレン
ジアミン、ピリジン等の有機アミン化合物があ
る。好ましいのは、アルカリ金属水酸化物および
アミノアルコール類である。アルカリ剤の量は
0.05〜10重量%程度の範囲である。 The etching solution used in the present invention includes sodium hydroxide, potassium hydroxide,
Inorganic alkaline agents such as sodium silicate, potassium silicate, trisodium phosphate, dibasic sodium phosphate, trisium ammonium phosphate, sodium metasilicate, sodium carbonate, ammonia, monomethylamine, dimethylamine, trimethylamine, monoethylamine , Alkylamines such as diethylamine, triethylamine, monoisopropylamine, diisopropylamine, n-butylamine, amino alcohols such as mono-, di- or triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, ethylene amine There are organic amine compounds such as , ethylenediamine, and pyridine. Preferred are alkali metal hydroxides and amino alcohols. The amount of alkaline agent is
The range is approximately 0.05 to 10% by weight.
本発明に用いるエツチング処理液には、さらに
メタノール、エタノール、イソプロパノール、エ
チレングリコール、ジエチレングリコール、トリ
エチレングリコール、ベンジルアルコール、フエ
ネチルアルコール、ポリエチレングリコールなど
のアルコール類の必要に応じて用いることができ
る。 The etching solution used in the present invention may further contain alcohols such as methanol, ethanol, isopropanol, ethylene glycol, diethylene glycol, triethylene glycol, benzyl alcohol, phenethyl alcohol, and polyethylene glycol, if necessary.
以下に実施例を挙げて説明するが、本発明はこ
れらに限定されるものではない。 Examples will be described below, but the present invention is not limited thereto.
実施例 1
分子量12万、酸価150のブチルメタアクリレー
ト−メタアクリル酸の100gをキシレン500gおよ
びブタノール200gの混合溶媒に溶解しバインダ
ー溶液とした。この溶液中に有機光導電性化合物
として1,3,5−トリフエニルピラゾリンを70
g溶解し、増感色素としてローダミンBの1%
DMF溶液50gを加えて全量をキシレンで1000g
に合せた。砂目立て処理及び陽極酸化処理を施し
た100μのアルミニウム板に固型分が5g/m2に
なるように塗布乾燥し印刷用原版を得た。Example 1 100 g of butyl methacrylate-methacrylic acid having a molecular weight of 120,000 and an acid value of 150 was dissolved in a mixed solvent of 500 g of xylene and 200 g of butanol to prepare a binder solution. In this solution, 70% of 1,3,5-triphenylpyrazoline was added as an organic photoconductive compound.
g dissolved and 1% of Rhodamine B as a sensitizing dye.
Add 50g of DMF solution and make 1000g of xylene.
Adjusted to. The coating was applied to a grained and anodized aluminum plate of 100 μm to a solid content of 5 g/m 2 and dried to obtain a printing original plate.
得られた印刷用原版を暗所にて−6kvのコロナ
放電を与えプラス帯電させた後に、白色光で網点
画像を露光した。直ちにリコー社製MRP液体ト
ナーを用いて現像を行ない、fuserで熱定着した。 After the obtained printing original plate was positively charged by applying a corona discharge of -6 kV in a dark place, the halftone dot image was exposed to white light. Immediately, development was performed using MRP liquid toner manufactured by Ricoh Co., Ltd., and heat fixation was performed using a fuser.
次いでトナー画像の不必要な箇所をキシレンで
溶解し、軽く拭いてトナーを除去した。乾燥後に
下記エツチング処理液中に浸漬(25℃で10秒間)
し、流水で洗浄した。非画像部の感光層および上
記不要トナー部の感光層もともに完全にエツチン
グされ、印刷上のトラブルもなく、地汚れのない
2万枚以上の印刷が可能であつた。 Next, unnecessary portions of the toner image were dissolved with xylene and gently wiped to remove the toner. After drying, immerse in the following etching treatment solution (10 seconds at 25℃)
and washed with running water. Both the photosensitive layer in the non-image area and the photosensitive layer in the unnecessary toner area were completely etched, and it was possible to print more than 20,000 sheets without any background smearing without any printing troubles.
モノエタノールアミン 50g
ベンジルアルコール 30g
水 1000gとする
実施例 2
実施例1のキシレンの代りにシエルゾル71を用
いて不要なトナー画像を処理する以外は全く同様
に繰返した。同様な結果が得られた。 Example 2 Monoethanolamine 50g Benzyl alcohol 30g Water 1000g Example 2 The same procedure as in Example 1 was repeated except that Cielsol 71 was used in place of xylene and unnecessary toner images were processed. Similar results were obtained.
実施例 3
分子量15万、酸価180の酢酸ビニル−クロトン
酸共重合体を有機光導電性化合物のバインダーと
して用いる以外は同様にして作製した印刷原版を
用いて実施例1を繰返した。全く同様の結果が得
られた。Example 3 Example 1 was repeated using a printing original plate prepared in the same manner except that a vinyl acetate-crotonic acid copolymer having a molecular weight of 150,000 and an acid value of 180 was used as the binder for the organic photoconductive compound. Exactly similar results were obtained.
実施例 4
実施例3の印刷原版をケロシンで修正する以外
は同様にした。同じ結果が確認された。Example 4 The same procedure as in Example 3 was carried out except that the original printing plate was modified with kerosene. The same results were confirmed.
実施例 5
実施例3の印刷原版をベンジルアルコールとア
セトン(1:2容量比)混合液で修正し、直ちに
実施例1のエツチング処理液中に浸漬した。修正
およびエツチング処理が迅速、かつ良好に行える
ことが確認された。Example 5 The original printing plate of Example 3 was modified with a mixture of benzyl alcohol and acetone (1:2 volume ratio) and immediately immersed in the etching solution of Example 1. It was confirmed that the correction and etching processes could be performed quickly and satisfactorily.
Claims (1)
光導電性化合物及びアルカリ水溶液でエツチング
されるバインダーを含む感光層を有する印刷用原
版を、電子写真法によつてエツチング液に対して
レジスト性を有するトナー画像を形成した後、実
質的に感光層バインダーを溶解せず、且つ不必要
なトナー画像部分を少なくともレジスト性を有し
ない程度に溶解除去するように修正液で修正し、
次いでアルカリ剤を含有するエツチング溶液で処
理してトナー画像以外の非画像部の感光層を除去
する製版方法。1. A printing original plate having a photosensitive layer containing an organic photoconductive compound and a binder that can be etched with an alkaline aqueous solution is placed on a conductive support having a hydrophilic surface, and is resistant to an etching solution by an electrophotographic method. After forming the toner image having the above, correct it with a correction liquid so as not to substantially dissolve the photosensitive layer binder and to dissolve and remove unnecessary toner image portions at least to the extent that they do not have resist properties;
A plate-making method in which the photosensitive layer in non-image areas other than the toner image is then removed by treatment with an etching solution containing an alkaline agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12738581A JPS5828760A (en) | 1981-08-14 | 1981-08-14 | Plate making method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12738581A JPS5828760A (en) | 1981-08-14 | 1981-08-14 | Plate making method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5828760A JPS5828760A (en) | 1983-02-19 |
JPH0544033B2 true JPH0544033B2 (en) | 1993-07-05 |
Family
ID=14958679
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12738581A Granted JPS5828760A (en) | 1981-08-14 | 1981-08-14 | Plate making method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5828760A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104714377A (en) * | 2013-12-11 | 2015-06-17 | 中国航空工业第六一八研究所 | Anticorrosion film opaque |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4936338A (en) * | 1972-08-04 | 1974-04-04 | ||
JPS54113343A (en) * | 1978-02-24 | 1979-09-04 | Univ Tokai | Fabrication of image by electrophotographic method |
JPS56146759A (en) * | 1980-04-18 | 1981-11-14 | Ricoh Co Ltd | Image correction of lithographic printing plate |
JPS57100446A (en) * | 1980-12-15 | 1982-06-22 | Ricoh Co Ltd | Fixing device of wet plate making machine |
-
1981
- 1981-08-14 JP JP12738581A patent/JPS5828760A/en active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4936338A (en) * | 1972-08-04 | 1974-04-04 | ||
JPS54113343A (en) * | 1978-02-24 | 1979-09-04 | Univ Tokai | Fabrication of image by electrophotographic method |
JPS56146759A (en) * | 1980-04-18 | 1981-11-14 | Ricoh Co Ltd | Image correction of lithographic printing plate |
JPS57100446A (en) * | 1980-12-15 | 1982-06-22 | Ricoh Co Ltd | Fixing device of wet plate making machine |
Also Published As
Publication number | Publication date |
---|---|
JPS5828760A (en) | 1983-02-19 |
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