JPH05337621A - Heat insulating lubrication method for injection sleeve - Google Patents

Heat insulating lubrication method for injection sleeve

Info

Publication number
JPH05337621A
JPH05337621A JP17193292A JP17193292A JPH05337621A JP H05337621 A JPH05337621 A JP H05337621A JP 17193292 A JP17193292 A JP 17193292A JP 17193292 A JP17193292 A JP 17193292A JP H05337621 A JPH05337621 A JP H05337621A
Authority
JP
Japan
Prior art keywords
heat insulating
liquid lubricant
injection sleeve
layer
sleeve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17193292A
Other languages
Japanese (ja)
Other versions
JP2602462B2 (en
Inventor
Kazuhiko Watanabe
一彦 渡辺
Hideto Sasaki
英人 佐々木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ryobi Ltd
Original Assignee
Ryobi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ryobi Ltd filed Critical Ryobi Ltd
Priority to JP4171932A priority Critical patent/JP2602462B2/en
Publication of JPH05337621A publication Critical patent/JPH05337621A/en
Application granted granted Critical
Publication of JP2602462B2 publication Critical patent/JP2602462B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To provide the heat insulating lubrication method for an injection sleeve which improves the lubricity and the heat insulating characteristic and obviates the generation of the intrusion of gases into a casting. CONSTITUTION:A liquid lubricant 2 having lubricity is applied on the inner peripheral surface of the injection sleeve 1 to form a liquid lubricant layer 2 and a heat insulating powder layer 3 is formed on the liquid lubricant layer 2 before the lubricant dries. As a result, a desired amt. of the heat insulating powder 3 is stuck to the sleeve by the wettability possessed by the liquid lubricant layer 2. Since the heat insulating powder layer 3 is provided, the desired heat insulating effect is obtd. The direct contact of the liquid lubricant and a high-temp. molten metal is prevented and the gasification of the lubricant is prevented.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は射出スリーブの断熱潤滑
方法に関し、特に射出スリーブ内での溶湯の凝固を断熱
効果によって防止し、併せて該射出スリーブと該スリー
ブ内を摺動するプランジャとの摺動潤滑性を向上させる
ことが可能な射出スリーブの断熱潤滑方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat insulating lubrication method for an injection sleeve, and more particularly, to prevent solidification of a molten metal in the injection sleeve by a heat insulating effect, and at the same time, to provide the injection sleeve and a plunger sliding in the sleeve. The present invention relates to a heat insulating lubrication method for an injection sleeve capable of improving sliding lubricity.

【0002】[0002]

【従来の技術】従来より、鋳造装置における射出スリー
ブに対して、油、または油、ワックス、樹脂等を水に分
散させた液状潤滑剤を、スプレー、滴下等の技術により
塗布することが行われている。しかしながら、該従来方
法では油分が直接高温の溶湯に触れるために、スリーブ
内でガス化し溶湯に巻き込まれて、鋳造品の品質を低下
させるという欠点があった。また、該液状潤滑剤自体は
充分な断熱性を有していないため、射出スリーブ内で溶
湯の凝固が生じ、その結果鋳造品の強度の低下や品質の
ばらつき、内部欠陥等が多く発生していた。
2. Description of the Related Art Conventionally, oil or a liquid lubricant in which oil, wax, resin or the like is dispersed in water is applied to an injection sleeve in a casting machine by a technique such as spraying or dropping. ing. However, the conventional method has a drawback in that the oil directly contacts the molten metal at a high temperature and is gasified in the sleeve and is entrained in the molten metal to deteriorate the quality of the cast product. Further, since the liquid lubricant itself does not have sufficient heat insulation, solidification of the molten metal occurs in the injection sleeve, and as a result, the strength of the cast product decreases, the quality varies, and many internal defects occur. It was

【0003】このような従来の欠点を克服するため特開
平1−118353号公報や特開平3−204151号
公報では、スプレー、静電塗布等により、自己潤滑性を
有する粉体を粉体のまま直接射出スリーブの内周面(潤
滑面)に塗布する技術が記載されている。そして、粉体
自体に有する熱安定性、断熱性によって、上記欠点の克
服を図っている。
In order to overcome such a conventional drawback, Japanese Patent Laid-Open Nos. 1-118353 and 3-204151 disclose a powder having self-lubricating property as a powder by spraying, electrostatic coating or the like. The technique of applying directly to the inner peripheral surface (lubrication surface) of the injection sleeve is described. The thermal stability and heat insulating property of the powder itself are intended to overcome the above drawbacks.

【0004】[0004]

【発明が解決しようとする課題】しかし、該公報記載の
発明では、粉体自体は液状潤滑剤に比較して潤滑性に乏
しく、そのため射出スリーブやプランジャの摺動面の摩
耗量が多くなるという欠点がある。また、粉体の射出ス
リーブに対する付着力が極めて弱く、ラドルからの注湯
時及び射出時に、溶湯や空気の流れによって粉体が射出
スリーブから遊離して断熱効果が得られなくなるという
欠点がある。更に、射出スリーブに付着可能な粉体の量
は当然に制約を受けるため、充分な粉体層が形成され
ず、その厚みが薄く、充分な断熱効果が得られない、と
いう不都合が生じる。加えて、ボロン、黒鉛、二硫化モ
リブデン等の自己潤滑性粉体は一般に高価であり、それ
らのスリーブからの離脱は鋳造コストのうえからも問題
である。
However, in the invention described in the above publication, the powder itself has poor lubricity as compared with the liquid lubricant, and therefore the amount of wear on the sliding surfaces of the injection sleeve and the plunger increases. There are drawbacks. In addition, there is a drawback that the adhesive force of the powder to the injection sleeve is extremely weak, and the powder is released from the injection sleeve by the flow of molten metal or air during pouring or injection from the ladle, and the heat insulating effect cannot be obtained. Furthermore, since the amount of powder that can be attached to the injection sleeve is naturally limited, there is a disadvantage that a sufficient powder layer is not formed, the thickness is thin, and a sufficient heat insulating effect cannot be obtained. In addition, self-lubricating powders of boron, graphite, molybdenum disulfide, etc. are generally expensive, and their detachment from the sleeve is a problem in terms of casting cost.

【0005】そこで本発明は、潤滑性と断熱性の両特性
を向上させると共に製品への油分解ガスの混入の生じな
い射出スリーブの断熱潤滑方法を提供することを目的と
する。
Therefore, an object of the present invention is to provide a method for adiabatic lubrication of an injection sleeve that improves both lubricity and heat insulation properties and does not cause mixing of oil decomposition gas into products.

【0006】[0006]

【課題を解決するための手段】かかる目的を達成するた
め本発明では(a)潤滑性を有する液状潤滑剤を射出ス
リーブの内周面に塗布して液状潤滑剤層を形成する工程
と、(b)該液状潤滑剤が乾燥する前に該液状潤滑剤層
上に断熱性粉体を付着させ粉体層を形成する工程とを有
した射出スリーブの断熱潤滑方法を提供している。
In order to achieve the above object, the present invention comprises: (a) applying a liquid lubricant having lubricity to the inner peripheral surface of an injection sleeve to form a liquid lubricant layer; b) A heat insulating lubrication method for an injection sleeve, which comprises a step of forming a powder layer by depositing heat insulating powder on the liquid lubricant layer before the liquid lubricant dries.

【0007】[0007]

【作用】射出スリーブ内周面に液状潤滑剤層をまず形成
し、その上に断熱性粉体層を形成する。よって断熱性粉
体層は該潤滑剤が有する粘性により大量に付着可能とな
る。そのためエアー、溶湯による断熱性粉体の射出スリ
ーブからの遊離を防止または低減でき、充分な断熱効果
を発揮することができる。また溶湯熱は断熱性粉体層の
存在により直接液状潤滑剤に伝達されず、液状潤滑剤の
主成分である油の熱によるガス化を防止でき、製品への
ガスの混入が著しく減少でき、製品の品質を維持向上す
ることができる。更に断熱性粉体層の存在により、溶湯
はスリーブと接しないので、スリーブの溶損が防止でき
る。
The liquid lubricant layer is first formed on the inner peripheral surface of the injection sleeve, and the heat insulating powder layer is formed thereon. Therefore, a large amount of the heat insulating powder layer can be attached due to the viscosity of the lubricant. Therefore, it is possible to prevent or reduce the release of the heat insulating powder from the injection sleeve due to the air or the molten metal, and it is possible to exert a sufficient heat insulating effect. In addition, the heat of the molten metal is not directly transferred to the liquid lubricant due to the presence of the heat-insulating powder layer, and it is possible to prevent the gasification of the oil, which is the main component of the liquid lubricant, by heat, and to significantly reduce the mixture of gas into the product The quality of the product can be maintained and improved. Further, the presence of the heat-insulating powder layer prevents the molten metal from coming into contact with the sleeve, so that melting damage of the sleeve can be prevented.

【0008】[0008]

【実施例】本発明による射出スリーブの断熱潤滑方法の
1実施例について、図1に基づき説明する。まず、射出
スリーブ1の内周面に液状潤滑剤をスプレーまたは滴下
により塗布し、液状潤滑剤層2を形成する。液状潤滑剤
としては、植物油、鉱物油等の油、又は水に油を分散さ
せたエマルジョンタイプの水溶性潤滑剤が用いられる。
液状潤滑剤は更に、油中に黒鉛等の個体潤滑剤を含むも
のであっても良い。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of a heat insulating lubrication method for an injection sleeve according to the present invention will be described with reference to FIG. First, the liquid lubricant is applied to the inner peripheral surface of the injection sleeve 1 by spraying or dripping to form the liquid lubricant layer 2. As the liquid lubricant, an oil such as a vegetable oil or a mineral oil, or an emulsion-type water-soluble lubricant in which oil is dispersed in water is used.
The liquid lubricant may further contain solid lubricant such as graphite in oil.

【0009】次に該液状潤滑剤層2が乾燥する前に断熱
性粉体を該液状潤滑剤層2上に塗布して、断熱性粉体層
3を形成する。断熱性粉体としては例えば安価なタルク
(滑石)と樹脂粉体とを所望の割合に配合した粉体混合
物や、セライト(ケイソウ土)等が用いられる。その他
雲母、バーミュキュライトでもよい。樹脂粉体は例えば
パラフィン、ポリエチレン、アクリル、植物ワックスで
形成される。
Next, before the liquid lubricant layer 2 is dried, heat insulating powder is applied onto the liquid lubricant layer 2 to form a heat insulating powder layer 3. As the heat-insulating powder, for example, a powder mixture obtained by mixing inexpensive talc (talc) and resin powder in a desired ratio, celite (diatomaceous earth), or the like is used. Other mica or vermiculite may be used. The resin powder is formed of, for example, paraffin, polyethylene, acrylic, or vegetable wax.

【0010】次に本発明の断熱潤滑方法の優越性を確認
するため以下のような実験を行った。検討項目として
は、断熱性、潤滑性、ガス量、プランジャチップ寿命、
引張り強度がある。断熱性は製品の外観検査に基づき湯
廻りの良否により判定した。潤滑性は射出スピードを計
測して判定した。ガス量は製品を加熱溶解させ内包され
るガス量を測定した。チップ寿命は1000回の射出後
のチップ摩耗状態を外観検査により判定した。引張り強
度はASTM引張り試験機により、鋳造品の引張り強度
を判定した。
Next, the following experiment was conducted in order to confirm the superiority of the adiabatic lubrication method of the present invention. Items to be examined are heat insulation, lubricity, gas amount, plunger tip life,
Has tensile strength. The heat insulating property was judged by the quality of the bath around based on the appearance inspection of the product. The lubricity was judged by measuring the injection speed. The amount of gas was measured by melting the product by heating and melting the product. The chip life was determined by visual inspection of the chip wear state after 1000 injections. For the tensile strength, the tensile strength of the cast product was judged by an ASTM tensile tester.

【0011】試験条件は以下のとおりである。 射出成形機: 90トン(東芝機械製ダイカストマシ
ン) 合金: ADC10 湯温: 720℃ 鋳造圧力: 750kg/cm2 射出速度: 1.0m/秒 充填率: 30%
The test conditions are as follows. Injection molding machine: 90 tons (Toshiba machine die casting machine) Alloy: ADC10 Hot water temperature: 720 ° C Casting pressure: 750 kg / cm 2 Injection speed: 1.0 m / sec Filling rate: 30%

【0012】比較試料1〜3を用意した。試料1は粉体
潤滑剤のみであり、タルク(滑石)と樹脂の混合比を
9:1としたものをエアーで射出スリーブ内周面に供給
した。試料2は黒鉛混入の油状潤滑剤であり、滴下にて
供給した。試料3は水性縣濁コロイダル黒鉛でありスプ
レーにて供給した。本発明品として、試料4、5を用意
した。試料4はまず、油をスプレーにて噴霧し、次に断
熱性粉体であるタルクをエアーにより油膜上に供給し
た。試料5はエマルジョンタイプの水溶性潤滑剤をスプ
レーにより噴霧し、次に断熱性粉体であるタルクをエア
ーにて潤滑剤層上に形成した。
Comparative samples 1 to 3 were prepared. Sample 1 was powder lubricant only, and a mixture of talc (talc) and resin having a mixing ratio of 9: 1 was supplied to the inner peripheral surface of the injection sleeve by air. Sample 2 was an oily lubricant mixed with graphite and was supplied dropwise. Sample 3 was an aqueous suspended colloidal graphite and was supplied by spraying. Samples 4 and 5 were prepared as the products of the present invention. In Sample 4, first, oil was sprayed, and then talc, which is a heat insulating powder, was supplied onto the oil film by air. Sample 5 was prepared by spraying an emulsion-type water-soluble lubricant by spraying, and then forming talc, which is a heat insulating powder, on the lubricant layer by air.

【0013】判定結果をThe judgment result

【表1】に示す。It shows in [Table 1].

【表1】において、二重丸◎は極めて良好な判定結果
を、丸○は良好な判定結果を、三角△は良否が混在する
判定結果を、バツ×は不良な判定結果を示す。
In Table 1, double circles ⊚ indicate extremely good judgment results, circles ∘ indicate good judgment results, triangles Δ indicate judgment results in which quality is mixed, and crosses indicate bad judgment results.

【0014】[0014]

【表1】 断熱性 潤滑性 ガス量 チップ寿命 引張り強度 試料1 ○ △ ◎ × ○ 試料2 × ◎ × ○ × 試料3 △ × ○ × △ 試料4 ◎ ◎ ◎ ◎ ◎ 試料5 ◎ ○ ○ ○ ○[Table 1] Thermal insulation Lubricity Gas amount Chip life Tensile strength Sample 1 ○ △ ◎ × ○ Sample 2 × ◎ × ○ × Sample 3 △ × ○ × △ Sample 4 ◎ ◎ ◎ ◎ ◎ ◎ Sample 5 ◎ ○ ○ ○ ○

【0015】表1から明らかなように、本発明による試
料4、5は比較試料1乃至3に比較して断熱性、潤滑
性、ガス量、チップ寿命、引張り強度の全ての観点で良
好な判定結果を得ることができた。
As is clear from Table 1, the samples 4 and 5 according to the present invention are better judged than the comparative samples 1 to 3 in all aspects of heat insulating property, lubricity, gas amount, chip life and tensile strength. I was able to get the result.

【0016】次に、本発明に基づく試料6として、植物
油、鉱物油を主成分とする油性潤滑油を射出スリーブ内
周面にスプレーし、次にタルクをエアーにて油性潤滑油
上に供給した。試験条件は以下のとおりである。 射出成形機: 500トン(東芝機械製ダイカストマシ
ン) 合金: A390 湯温: 720℃ 鋳造圧力: 800kg/cm2 射出速度: 0.2m/秒 充填率: 60% かかる条件下でも、良好な湯廻り性を発揮し、湯温を7
00℃まで下げても湯廻りは依然良好であった。またチ
ップ寿命、ガス量も油性潤滑油をスプレーした場合に比
較して良好であり、引張り強度もそれより5%向上し
た。
Next, as a sample 6 according to the present invention, an oil-based lubricating oil containing vegetable oil and mineral oil as a main component was sprayed on the inner peripheral surface of the injection sleeve, and then talc was supplied by air onto the oil-based lubricating oil. .. The test conditions are as follows. Injection molding machine: 500 tons (Die-casting machine manufactured by Toshiba Machine) Alloy: A390 Hot water temperature: 720 ° C Casting pressure: 800 kg / cm 2 Injection speed: 0.2 m / sec Filling ratio: 60% Good bathing even under such conditions Demonstrate the ability, hot water temperature 7
Even when the temperature was lowered to 00 ° C, the bathing area was still good. Further, the chip life and the gas amount were good as compared with the case where the oil-based lubricating oil was sprayed, and the tensile strength was also improved by 5%.

【0017】次に、本発明に基づく試料7として、黒鉛
入り油性潤滑剤層を射出スリーブ内周面に形成した後
に、セライト(ケイソウ土)をエアーにて潤滑剤層上に
形成した。試験条件は以下のとおりである。 射出成形機: 800トン(宇部興産製ダイカストマシ
ン) 合金: ADC10 湯温: 700℃ 鋳造圧力: 700kg/cm2 射出速度: 0.3m/秒 充填率: 50% かかる条件下でも湯廻りは良好であり、ガス量も試料2
に比較して30%減少した。また射出速度を0.25m
/秒まで低下させても鋳造が可能であることがわかっ
た。
Next, as sample 7 according to the present invention, an oil-based lubricant layer containing graphite was formed on the inner peripheral surface of the injection sleeve, and then celite (diatomaceous earth) was formed on the lubricant layer by air. The test conditions are as follows. Injection molding machine: 800 tons (Die casting machine made by Ube Industries) Alloy: ADC10 Hot water temperature: 700 ° C Casting pressure: 700kg / cm 2 Injection speed: 0.3m / sec Filling rate: 50% Even under these conditions, the hot water flow is good. Yes, gas amount is sample 2
It was reduced by 30%. The injection speed is 0.25m
It was found that casting is possible even if the pressure is reduced to / second.

【0018】[0018]

【発明の効果】以上、本発明によるスリーブの断熱潤滑
方法によれば、以下のような効果を発揮することができ
る。 (1)液状潤滑剤を射出スリーブに塗布しているので、
プランジャチップとスリーブとの潤滑性が良好に保たれ
摩耗の問題が生じない。 (2)液状潤滑剤が射出スリーブにまず塗布されるの
で、その上に形成される断熱性粉体層は該潤滑剤が有す
る粘性により比較的強固にかつ大量に付着可能となる。
そのためエアー、溶湯による断熱性粉体の射出スリーブ
からの遊離を防止または低減でき、充分な断熱効果を発
揮することができる。 (3)断熱性粉体は常に液状潤滑剤層の上に形成されて
いるので、高温の溶湯熱が直接液状潤滑剤に伝達され
ず、液状潤滑剤の主成分である油の熱によるガス化を防
止でき、製品へのガスの混入が著しく減少でき、製品の
品質を維持向上することができる。 (4)粉体自体に潤滑性や付着性を具備させる必要がな
く、従来のように高価な自己潤滑性粉体を用いる必要が
ない。よって、経済性の点で有利である。 (5)液状潤滑剤と断熱性粉体とを選択的に併用するこ
とで、断熱性、潤滑性、価格等の観点での選択の自由度
が増し、広範な使用範囲を提供可能となる。 (6)断熱性粉体層によりスリーブを溶湯が直接触れな
いため、溶湯によるスリーブの溶損が防止され、寿命を
のばすことができる。
As described above, according to the heat insulating lubrication method for a sleeve of the present invention, the following effects can be exhibited. (1) Since the liquid lubricant is applied to the injection sleeve,
Good lubricity is maintained between the plunger tip and the sleeve, and the problem of wear does not occur. (2) Since the liquid lubricant is first applied to the injection sleeve, the heat-insulating powder layer formed thereon can be adhered relatively strongly and in a large amount due to the viscosity of the lubricant.
Therefore, it is possible to prevent or reduce the release of the heat insulating powder from the injection sleeve due to the air or the molten metal, and it is possible to exert a sufficient heat insulating effect. (3) Since the heat-insulating powder is always formed on the liquid lubricant layer, the heat of the high-temperature molten metal is not directly transferred to the liquid lubricant and gasification of the oil, which is the main component of the liquid lubricant, is performed. Can be prevented, gas mixture into the product can be significantly reduced, and product quality can be maintained and improved. (4) It is not necessary to provide the powder itself with lubricity or adhesiveness, and it is not necessary to use expensive self-lubricating powder as in the past. Therefore, it is advantageous in terms of economy. (5) By selectively using the liquid lubricant and the heat insulating powder in combination, the degree of freedom in selection in terms of heat insulating property, lubricity, price, etc. is increased, and a wide range of use can be provided. (6) Since the molten metal does not directly contact the sleeve due to the heat insulating powder layer, melting damage of the sleeve due to the molten metal can be prevented and the life can be extended.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明による射出スリーブの断熱潤滑状態を示
した概略断面図。
FIG. 1 is a schematic cross-sectional view showing a heat insulating lubrication state of an injection sleeve according to the present invention.

【符号の説明】[Explanation of symbols]

1:射出スリーブ 2:液状潤滑剤 3:断熱性粉体 4:溶湯 1: Injection sleeve 2: Liquid lubricant 3: Heat insulating powder 4: Molten metal

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 潤滑性を有する液状潤滑剤を射出スリー
ブの内周面に塗布して液状潤滑剤層を形成する工程と、 該液状潤滑剤が乾燥する前に該液状潤滑剤層上に断熱性
粉体を付着させ粉体層を形成する工程とを有することを
特徴とする射出スリーブの断熱潤滑方法。
1. A step of applying a liquid lubricant having lubricity to an inner peripheral surface of an injection sleeve to form a liquid lubricant layer, and heat insulating the liquid lubricant layer on the liquid lubricant layer before the liquid lubricant is dried. And a step of forming a powder layer by depositing a conductive powder on the insulating sleeve.
JP4171932A 1992-06-05 1992-06-05 Insulation lubrication method for injection sleeve Expired - Fee Related JP2602462B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4171932A JP2602462B2 (en) 1992-06-05 1992-06-05 Insulation lubrication method for injection sleeve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4171932A JP2602462B2 (en) 1992-06-05 1992-06-05 Insulation lubrication method for injection sleeve

Publications (2)

Publication Number Publication Date
JPH05337621A true JPH05337621A (en) 1993-12-21
JP2602462B2 JP2602462B2 (en) 1997-04-23

Family

ID=15932507

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4171932A Expired - Fee Related JP2602462B2 (en) 1992-06-05 1992-06-05 Insulation lubrication method for injection sleeve

Country Status (1)

Country Link
JP (1) JP2602462B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013244508A (en) * 2012-05-28 2013-12-09 Sugimura Kagaku Kogyo Kk Detecting method of mold releasing agent coating film for die casting and detecting agent for mold releasing agent coating film for die casting

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5120295A (en) * 1974-08-12 1976-02-18 Nissei Ltd
JPS55133843A (en) * 1979-04-05 1980-10-18 Sintokogio Ltd Facing material
JPH0224622A (en) * 1988-07-14 1990-01-26 Sony Corp Color laser thermal write liquid crystal projector
JPH0489168A (en) * 1990-07-31 1992-03-23 Ahresty Corp Device for applying powdery heat insulating agent onto inner face of injection sleeve

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5120295A (en) * 1974-08-12 1976-02-18 Nissei Ltd
JPS55133843A (en) * 1979-04-05 1980-10-18 Sintokogio Ltd Facing material
JPH0224622A (en) * 1988-07-14 1990-01-26 Sony Corp Color laser thermal write liquid crystal projector
JPH0489168A (en) * 1990-07-31 1992-03-23 Ahresty Corp Device for applying powdery heat insulating agent onto inner face of injection sleeve

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013244508A (en) * 2012-05-28 2013-12-09 Sugimura Kagaku Kogyo Kk Detecting method of mold releasing agent coating film for die casting and detecting agent for mold releasing agent coating film for die casting

Also Published As

Publication number Publication date
JP2602462B2 (en) 1997-04-23

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