JPH05310993A - Rubber and/or plastic molded product having excellent vibration-damping property and thermal conductivity - Google Patents

Rubber and/or plastic molded product having excellent vibration-damping property and thermal conductivity

Info

Publication number
JPH05310993A
JPH05310993A JP4140080A JP14008092A JPH05310993A JP H05310993 A JPH05310993 A JP H05310993A JP 4140080 A JP4140080 A JP 4140080A JP 14008092 A JP14008092 A JP 14008092A JP H05310993 A JPH05310993 A JP H05310993A
Authority
JP
Japan
Prior art keywords
molded product
rubber
thermal conductivity
filler
plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4140080A
Other languages
Japanese (ja)
Other versions
JP3325600B2 (en
Inventor
Yoneo Hirakawa
米夫 平川
Kasao Matsuoka
河西男 松岡
Hidehisa Hamaguchi
秀久 濱口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyowa KK
Original Assignee
Kyowa KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyowa KK filed Critical Kyowa KK
Priority to JP14008092A priority Critical patent/JP3325600B2/en
Priority to TW081109942A priority patent/TW228534B/zh
Priority to KR1019920026169A priority patent/KR100251658B1/en
Publication of JPH05310993A publication Critical patent/JPH05310993A/en
Application granted granted Critical
Publication of JP3325600B2 publication Critical patent/JP3325600B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/06Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/302Conductive

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Vibration Prevention Devices (AREA)
  • Laminated Bodies (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)

Abstract

PURPOSE:To obtain the subject molded product consisting of a composition in which a polymer composed of a rubber and a plastics is blended with specific two kinds of fillers, excellent in vibration-damping property and thermal conductivity and capable of preventing vibration without hindering a heat generating vibrator from releasing heat. CONSTITUTION:The objective molded product is obtained by blending (A) a polymer consisting essentially of a rubber and/or plastics with (B) metallic fine powder (preferably gold, copper, Al, etc.), (C) filler (e.g. aluminum oxide or boron nitride) selected from a metal oxide, a metal nitride and a filler containing either one thereof and (D) a filler selected from a crystalline silica, silicon carbide, silicon oxide and a filler containing either one thereof and then molding the blend. This molded product has >=2X10<2>etakg/cm<2> loss modulus and >=0.4kcal/m.h. deg.C thermal conductivity. As the component A, blend of nitrile rubber and PVC is preferably used.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、ギアポンプ,コンプ
レッサー,エアコンレシーバー,モーターリトラクター
等の振動体のカバーケースに内在して用いられる、特に
エアコン室外機に内蔵されるリトラクター,モーター等
発熱振動体をカバーケースに固定するに際して両者の間
隙に充填して用いられる、振動を制振できしかも熱伝導
性の優れるゴムおよび/またはプラスチック成型物に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used internally in a cover case of a vibrating body such as a gear pump, a compressor, an air conditioner receiver, a motor retractor, etc. The present invention relates to a rubber and / or plastic molded product which can be used to fill a gap between the two when fixing a body to a cover case and which can suppress vibration and has excellent thermal conductivity.

【0002】[0002]

【従来の技術】従来、ギアポンプ,コンプレッサー,エ
アコンレシーバー,各種電機製品に付属するモーター等
の発熱振動体については、その発熱と振動が常に問題に
なっている。このため、従来技術では、振動を防ぐため
に例えばモーター等ではモーターケースを外からフェル
ト状の軟らかい材質で包み、さらにその上から鉛あるい
は比重の大きなゴムあるいはプラスチックのシートで包
む方法がとられている。
2. Description of the Related Art Conventionally, heat generation and vibration of a heat generating vibrating body such as a gear pump, a compressor, an air conditioner receiver and a motor attached to various electric products have always been a problem. Therefore, in the related art, in order to prevent vibration, for example, in a motor or the like, a method is used in which a motor case is wrapped from the outside with a soft felt-like material, and further wrapped with a lead or a rubber or plastic sheet having a large specific gravity. ..

【0003】[0003]

【発明が解決しようとする課題】しかしながら、上述の
ケースを外からフェルト状の軟らかい材質で包み、さら
にその上から鉛あるいは比重の大きなシートで包む方法
については、施工時、次のごとき問題点を有している。
However, regarding the method of wrapping the above-mentioned case from the outside with a soft felt-like material and further wrapping it with a sheet of lead or a large specific gravity, the following problems are encountered during construction. Have

【0004】施工時、フェルト状の軟らかい材質をケー
スに対して、確実に接着せねばならず、この接着作業が
困難であり、しかも作業性が良くない。
At the time of construction, a soft felt-like material must be surely adhered to the case, and this adhering work is difficult and the workability is not good.

【0005】施工時、ケース全体を包むため、フェルト
及び比重の大きなシートは、容量の大きな物となり、材
料的にも高価となる。
Since the entire case is wrapped at the time of construction, the felt and the sheet having a large specific gravity have a large capacity, and the material is expensive.

【0006】施工後、これらの発熱振動体は、屋外で使
用されることも多く、風雨に曝され比較的短時間で、フ
ェルトや鉛あるいは比重の大きなシートは、老化して、
破損やハガレを生じ易く、従って防振性能が消失し、結
果として発熱振動体の振動を防ぐことができなくなり、
持ちが良くない。更に、上記の原因で、作業のやり直し
を行なう必要回数も多くなり、工事費用が増大する等の
経済的な問題点もネックとなっている。
After construction, these heat-generating vibrating bodies are often used outdoors, and are exposed to wind and rain in a relatively short time, and felt, lead, or a sheet with a large specific gravity ages,
Damage and peeling easily occur, so the vibration isolation performance is lost, and as a result, it becomes impossible to prevent the vibration of the heat-generating vibrating body.
It doesn't hold well. Further, due to the above-mentioned causes, the number of times the work needs to be redone is increased, which causes an economic problem such as an increase in construction cost.

【0007】加うるに、もう1つの大きな問題点とし
て、ケースをフェルト状の軟らかい材質で包み、さらに
その上から鉛あるいは比重の大きなシートで包む方法
は、放熱効果がほとんど期待できず、むしろ保温する結
果となり、発熱振動体自体に耐熱性をもたすかモーター
などではブロワー容量を大きくしなければならない等の
必要性が生じ、発熱振動体自体が高価で容量の大きなも
のとなる結果となっている。
In addition, as another big problem, the method of wrapping the case with a felt-like soft material and further wrapping it with a sheet of lead or a large specific gravity can hardly expect a heat dissipation effect, but rather keeps heat. As a result, it becomes necessary to provide the heat-generating vibrating body with heat resistance or to increase the blower capacity in a motor, etc., resulting in the heat-generating vibrating body itself being expensive and having a large capacity. There is.

【0008】この発明はかかる問題点を解消するために
なされたもので、発熱振動体の放熱を妨げることなく振
動を防ぐことのできるゴムおよび/またはプラスチック
成型物を得ることを目的とする。
The present invention has been made to solve the above problems, and an object thereof is to obtain a rubber and / or plastic molded product capable of preventing vibration without hindering the heat radiation of the heat-generating vibrating body.

【0009】[0009]

【課題を解決するための手段】この発明は、ゴムおよび
/またはプラスチックを主体としたポリマーに金属微粉
末と(a)金属酸化物,金属窒化物およびこれらのいず
れかを含む充填剤からなる群より選択された少なくとも
1種の充填剤と(b)結晶性シリカ,炭化硅素,酸化硅
素およびこれらのいずれかを含む充填剤からなる群より
選択された少なくとも1種の充填剤とを配合し、損失弾
性率が2×102 ηKg/cm2 以上で熱伝導率が0.
4Kcal/m.h.℃以上の組成物とするとともに所
望の形状に成型した成型物を得て、上記課題を解決した
ものである。
DISCLOSURE OF THE INVENTION The present invention relates to a group consisting of a polymer mainly composed of rubber and / or plastic and fine metal powder, (a) a metal oxide, a metal nitride and a filler containing any of these. Blending at least one filler selected from the group (b) at least one filler selected from the group consisting of crystalline silica, silicon carbide, silicon oxide and a filler containing any of these, When the loss elastic modulus is 2 × 10 2 ηKg / cm 2 or more, the thermal conductivity is 0.
4 Kcal / m. h. The above problem is solved by obtaining a molded product having a composition of not lower than ° C and molded into a desired shape.

【0010】[0010]

【作用】この発明においては、例えば発熱振動体ケース
とそれに固定される発熱振動体との間隙に充填して用い
ることにより、振動体ケースからの必要な放熱を妨げる
ことなく、かつ振動体からの振動をも防止できる作用を
有する。
In the present invention, for example, by filling the gap between the heat-generating vibrating body case and the heat-generating vibrating body fixed thereto and using it, the necessary heat radiation from the vibrating body case is not hindered and the vibration from the vibrating body is prevented. It also has the function of preventing vibration.

【0011】[0011]

【実施例】以下、この発明の実施例を図面により詳述す
る。図1,図2は本発明の制振性と熱伝導性を有するゴ
ムおよび/またはプラスチック成型物をブロック形状
(図1)、シートまたはテープ形状(図2)に成型した
ときの形状を例示する斜視図であって、ゴムおよび/ま
たはプラスチックを主体とするポリマー2に、金属微粉
末3と、熱伝導率が0.5Kcal/m.h.℃以上
の、(a)金属酸化物,金属窒化物およびこれらのいず
れかを含む充填剤からなる群より選択された少なくとも
1種の充填剤と(b)結晶性シリカ,炭化硅素,酸化硅
素もしくはこれらのいずれかを含む充填剤からなる群よ
り選択された少なくとも1種の充填剤からそれぞれ選択
した充填剤4とを均一に混合分散し要すれば加硫剤を混
合して、未加硫,半加硫,または加硫状態で所望の制振
性能と熱伝導性を有するゴムおよび/またはプラスチッ
ク成型物1としたものである。
Embodiments of the present invention will be described in detail below with reference to the drawings. 1 and 2 exemplify the shape of a rubber and / or plastic molded product having vibration damping properties and thermal conductivity of the present invention when molded into a block shape (FIG. 1), a sheet or tape shape (FIG. 2). 1 is a perspective view showing a polymer 2 mainly composed of rubber and / or plastic, a metal fine powder 3 and a thermal conductivity of 0.5 Kcal / m. h. At least one filler selected from the group consisting of (a) metal oxides, metal nitrides, and fillers containing any of the above, and (b) crystalline silica, silicon carbide, silicon oxide or At least one filler selected from the group consisting of fillers containing any of these is uniformly mixed and dispersed, and if necessary, a vulcanizing agent is mixed to obtain an unvulcanized, The rubber and / or plastic molded product 1 has desired vibration damping performance and thermal conductivity in a semi-vulcanized or vulcanized state.

【0012】図3,図4はシートまたはテープ状に成型
したこの発明の制振性と熱伝導性を有するゴムおよび/
またはプラスチック成型物(図2)の他例であって、使
用するに際し所望の幅、長さに裁断した2枚の成型物1
の間に金属帯5を内在せしめた積層成型物(図3)又は
1枚の成型物1の片面に配設した積層成型物(図4)の
断面図である。
FIGS. 3 and 4 show a rubber and / or rubber having vibration damping properties and heat conductivity of the present invention molded into a sheet or tape form.
Another example of a plastic molded product (FIG. 2) is two molded products 1 cut into desired widths and lengths when used.
FIG. 5 is a cross-sectional view of a laminated molded product (FIG. 3) in which a metal band 5 is internally provided between the metal band 5 and a laminated molded product (FIG. 4) arranged on one surface of one molded product 1.

【0013】図5〜図11はこの発明の一例である積層
成型物であって、図2〜図4の両面もしくは片面に粘着
剤層6を設けた場合の断面図である。
FIGS. 5 to 11 are cross-sectional views showing a laminated molded article as an example of the present invention in which the pressure-sensitive adhesive layer 6 is provided on both sides or one side of FIGS. 2 to 4.

【0014】図12は室外機7に内蔵されるリトラクタ
ー8を室外機底板7aに固定するに際し底板7aとリト
ラクター8間に充填した実施例を示す一部破断透視斜視
図である。尚、図中7bは底板7aに設けられた放熱孔
である。
FIG. 12 is a partially cutaway perspective view showing an embodiment in which the retractor 8 incorporated in the outdoor unit 7 is filled between the bottom plate 7a and the retractor 8 when the retractor 8 is fixed to the outdoor unit bottom plate 7a. Incidentally, 7b in the figure is a heat dissipation hole provided in the bottom plate 7a.

【0015】図13はこの発明のシートまたはテープ状
成型物1(図2)を適宜裁断し、既存のモーターカバー
に取り付ける場合のカバー9とセットされた状態の実施
例を示す一部破断斜視図である。
FIG. 13 is a partially cutaway perspective view showing an embodiment in which the sheet or tape-shaped molded article 1 (FIG. 2) of the present invention is appropriately cut and attached to the existing motor cover and set with the cover 9. Is.

【0016】図14〜図20はこの発明の成型形状の他
例を示す斜視図である。
14 to 20 are perspective views showing another example of the molded shape of the present invention.

【0017】この発明の制振性と熱伝導性を有するゴム
および/またはプラスチック成型物1に使用するポリマ
ー2としてのゴムは、例えば天然ゴム,イソプレンゴ
ム,ブタジエンゴム,ブチルゴム,ニトリルゴム,アク
リルゴム,クロロプレンゴム,エチレン−プロピレンゴ
ム,シリコーンゴム,ポリイソブチレン,ブタジエン−
スチレンゴム,ポリサルファイドゴム,ノルボーネンゴ
ム,ウレタンゴム,スチレン−ブタジエン−スチレンブ
ロックコポリマー,スチレン−イソプレン−スチレンブ
ロックコポリマー,塩素化ポリエチレン等が、またプラ
スチックとしては例えばポリエチレン樹脂,ポリスチレ
ン樹脂,ポリ塩化ビニル樹脂,ポリプロピレン樹脂,ポ
リエステル樹脂,ウレタン樹脂,ABS樹脂等があげら
れ、さらにゴムとプラスチックのブレンドとしては例え
ばニトリルゴム,ブチルゴム,クロロプレンゴム,エチ
レンプロピレンゴムとポリエチレン樹脂のブレンドもし
くはニトリルゴムとポリ塩化ビニルのブレンドが好適に
使用される。
The rubber as the polymer 2 used in the rubber and / or plastic molding 1 having the vibration damping property and the thermal conductivity of the present invention is, for example, natural rubber, isoprene rubber, butadiene rubber, butyl rubber, nitrile rubber, acrylic rubber. , Chloroprene rubber, ethylene-propylene rubber, silicone rubber, polyisobutylene, butadiene-
Styrene rubber, polysulfide rubber, norbornene rubber, urethane rubber, styrene-butadiene-styrene block copolymer, styrene-isoprene-styrene block copolymer, chlorinated polyethylene and the like, and examples of plastic include polyethylene resin, polystyrene resin, polyvinyl chloride resin. , Polypropylene resin, polyester resin, urethane resin, ABS resin, and the like. Further, as a blend of rubber and plastic, for example, nitrile rubber, butyl rubber, chloroprene rubber, a blend of ethylene propylene rubber and polyethylene resin, or a blend of nitrile rubber and polyvinyl chloride. Blends are preferably used.

【0018】又、上記ベースポリマーに添加される熱伝
導性を有する充填剤4における(a)金属酸化物,金属
窒化物およびこれらのいずれかを含んでいる充填剤から
なる群より選択される充填剤としては例えば酸化アルミ
ニウム,酸化亜鉛,酸化鉄,酸化鉛,酸化マグネシウ
ム,窒化アルミニウム,窒化ほう素,窒化マグネシウ
ム、また、(b)結晶性シリカ,炭化硅素,酸化硅素お
よびこれらのいずれかを含む充填剤からなる群から選択
される充填剤としては例えば結晶性シリカ,炭化硅素,
酸化硅素,炭酸カルシウム,クレー,タルク,炭酸マグ
ネシウム,ホワイトカーボン等があげられる。これら充
填剤はその熱伝導率が0.5Kcal/m.h.℃以上
の熱伝導性を有するものが好適である。また両者は、成
型物1が所望の熱伝導率を有するように配合比率が3:
7〜7:3の範囲で配合するのがよい。
In addition, a filler selected from the group consisting of (a) a metal oxide, a metal nitride, and a filler containing any of these in the filler 4 having thermal conductivity added to the base polymer. Examples of the agent include aluminum oxide, zinc oxide, iron oxide, lead oxide, magnesium oxide, aluminum nitride, boron nitride, magnesium nitride, and (b) crystalline silica, silicon carbide, silicon oxide and any of these. Examples of the filler selected from the group consisting of fillers include crystalline silica, silicon carbide,
Examples include silicon oxide, calcium carbonate, clay, talc, magnesium carbonate, and white carbon. These fillers have a thermal conductivity of 0.5 Kcal / m. h. Those having a thermal conductivity of ℃ or more are suitable. Further, both have a compounding ratio of 3: so that the molded product 1 has a desired thermal conductivity.
It is preferable to blend in the range of 7 to 7: 3.

【0019】さらに要すれば、液状ゴム,プロセス油等
の軟化剤,ロジン,石油樹脂等の粘着付与剤,顔料,加
硫促進剤,加硫剤,老化防止剤等,他の添加剤も適宜選
択されて使用される。
Further, if necessary, other additives such as liquid rubber, softening agent for process oil, tackifier such as rosin, petroleum resin, pigment, vulcanization accelerator, vulcanizing agent, antiaging agent, etc. Selected and used.

【0020】また、上記の充填剤4と共にベースポリマ
ーに混合分散されるべき金属微粉末3としては例えば
金,銀,銅,鉛,アルミニュウム,マンガン,ニッケ
ル,クロム,亜鉛又はこれらのケイ素合金が適当であ
る。
Further, as the fine metal powder 3 to be mixed and dispersed in the base polymer together with the above-mentioned filler 4, for example, gold, silver, copper, lead, aluminum, manganese, nickel, chromium, zinc or a silicon alloy thereof is suitable. Is.

【0021】又、図3,図4のように金属帯5を内在せ
しめた又は片面に設けたシートまたはテープ形状を有す
る成型物の場合に用いる金属帯5としては、例えばアル
ミ,銅,鉄等の板、シート、フィルムよりなるものを用
いる。
Further, as shown in FIGS. 3 and 4, the metal strip 5 used in the case of a molded product having a sheet or tape shape in which the metal strip 5 is embedded or provided on one side is, for example, aluminum, copper, iron or the like. A plate, sheet, or film is used.

【0022】さらに又、図5〜図11に例示したような
成型物1に用いられる粘着剤層6の形成に用いる粘着剤
としては、ホットメルトタイプ,溶剤タイプ,水系タイ
プのいずれでもよい。またこの層6は、厚みとして10
μ〜100μの範囲、即ち成型物1の制振効果を妨げな
い程度の薄さとすることが必要である。尚、図5〜図1
1においてはシートまたはテープ状成型物(図2)につ
いて粘着剤層6を設ける場合についてのみ例示したが、
他の形状、例えばブロック状等の成型物においてもその
表面もしくは内面に部分的もしくは全面に粘着剤層6を
設けることができる。
Further, the pressure-sensitive adhesive used for forming the pressure-sensitive adhesive layer 6 used in the molded article 1 exemplified in FIGS. 5 to 11 may be any of hot melt type, solvent type and water type. The layer 6 has a thickness of 10
It is necessary that the thickness is in the range of μ to 100 μ, that is, a thickness that does not hinder the damping effect of the molded product 1. 5 to 1
1 illustrates only the case where the pressure-sensitive adhesive layer 6 is provided on the sheet or tape-shaped molded product (FIG. 2),
Even in a molded product having another shape, for example, a block shape, the pressure-sensitive adhesive layer 6 can be partially or entirely provided on the surface or the inner surface thereof.

【0023】次に、この発明において極めて重要な働き
を有する成型物1における充填剤4および金属微粉末3
について詳述する。即ち、ゴムおよび/またはプラスチ
ックの弾性ポリマー2に金属微粉末3を添加することに
よって、柔軟で比重の重い制振性を有するシートを得る
ことができることはこの発明者らによりすでに明らかに
されている(特公昭60−25232号公報、実開平3
−99247号公報)。しかしこの発明のゴムおよび/
またはプラスチック成型物1は、制振性に加えて熱伝導
性を有することが必要である。例えば熱伝導性について
は図12の実施例に示すごとく室外機7の底板7aとリ
トラクター(抵抗機)8の間に内在して、リトラクター
(抵抗機)等発熱体本体からの発熱を蓄熱することなく
室外機7の底板7aに付設した放熱孔7bからスムーズ
に熱を放出することが必要である。そしてこの効果は金
属微粉末3のみの添加では製品加工性、物性の保持等の
点から要求品質を充分に満たすこと困難である。
Next, the filler 4 and the fine metal powder 3 in the molded product 1 which has an extremely important function in the present invention.
Will be described in detail. That is, it has already been clarified by the present inventors that a sheet having vibration damping properties that is soft and has a high specific gravity can be obtained by adding the metal fine powder 3 to the elastic polymer 2 of rubber and / or plastic. (Japanese Patent Publication No. 60-25232, Jitsukaihei 3
-99247 publication). However, the rubber of this invention and /
Alternatively, the plastic molded product 1 needs to have thermal conductivity in addition to damping properties. For thermal conductivity, for example, as shown in the embodiment of FIG. 12, the heat generated by the heat generating body such as the retractor (resistor) is stored between the bottom plate 7a of the outdoor unit 7 and the retractor (resistor) 8. Without doing so, it is necessary to smoothly radiate heat from the heat dissipation holes 7b attached to the bottom plate 7a of the outdoor unit 7. And, this effect is difficult to sufficiently satisfy the required quality from the viewpoints of product workability, retention of physical properties, etc., by adding only the metal fine powder 3.

【0024】この発明者らはこの点につき鋭意研究の結
果、前記ベースポリマーに金属微粉末3と共に金属酸化
物もしくは金属酸化物を含む無機充填剤を配合すること
によりその熱伝導性を改善しうることを見いだした(実
開平3−99247号公報)。しかしその後の研究によ
り、発明者らは金属微粉末3と共に加える金属酸化物も
しくは金属酸化物を含む充填剤を金属窒化物あるいは結
晶性シリカ,酸化硅素,炭化硅素またはこれらを含む充
填剤に置き換えることにより、同等もしくは若干上回る
熱伝導性効果が得られることを見いだした。さらに発明
者らは、(a)金属酸化物,金属窒化物およびこれらの
いずれかを含む充填剤からなる群より選択された少なく
とも1種の充填剤と(b)結晶性シリカ,酸化硅素,炭
化硅素,およびこれらのいずれかを含んでいる充填剤か
らなる群より選択された少なくとも1種の充填剤とを併
用して金属微粉末3と共に加えることにより前二者より
一層良好な熱伝導性を得ることを見いだし本発明に到達
したのである。
As a result of earnest research on this point, the present inventors have found that the thermal conductivity of the base polymer can be improved by blending the fine metal powder 3 with a metal oxide or an inorganic filler containing a metal oxide. I found this (Japanese Utility Model Publication No. 3-99247). However, in the subsequent research, the inventors replaced the metal oxide or the filler containing the metal oxide added together with the metal fine powder 3 with metal nitride or crystalline silica, silicon oxide, silicon carbide or the filler containing these. It was found that the same or slightly higher thermal conductivity effect can be obtained. Furthermore, the inventors have found that (a) at least one filler selected from the group consisting of metal oxides, metal nitrides and fillers containing any of these, and (b) crystalline silica, silicon oxide, carbonized By adding together with the fine metal powder 3 together with at least one filler selected from the group consisting of silicon and fillers containing any of these, better thermal conductivity than the former two is obtained. The inventors have found out what to obtain and have reached the present invention.

【0025】例えば、ゴムおよび/またはプラスチック
を主体とするポリマー2に、熱伝導率が0.5Kcal
/m.h.℃以上の、(a)金属酸化物,金属窒化物お
よびこれらのいずれかを含んでいる充填剤からなる群よ
り選択された少なくとも1種の充填剤と、(b)結晶性
シリカ,炭化硅素,酸化硅素,およびこれらのいずれか
を含む充填剤からなる群より選択された少なくとも1種
の充填剤とからそれぞれ選択した充填剤4とをバンバリ
ー、ニーダー、オープンロール等を用いて、均一に混合
分散し、次いでまたは同時に制振性と熱伝導性を付与で
きる金属微粉末3を徐々に添加配合し、その後、押出機
またはカレンダーまたはプレス機等を用いて、得られた
配合物を所望の形状に成型し、要すれば裁断することに
より熱伝導率が0.4Kcal/m.h.℃以上、損失
弾性率が2×102 ηKg/cm2 以上の要求品質を満
足する成型物を得ることに成功しこの発明に到ったもの
である。
For example, the polymer 2 mainly composed of rubber and / or plastic has a thermal conductivity of 0.5 Kcal.
/ M. h. At least one filler selected from the group consisting of (a) metal oxides, metal nitrides, and fillers containing any of the above, and (b) crystalline silica, silicon carbide, A filler 4 selected from at least one filler selected from the group consisting of silicon oxide and fillers containing any of these is uniformly mixed and dispersed using a Banbury, a kneader, an open roll or the like. Then, or at the same time, metal fine powder 3 capable of imparting vibration damping property and thermal conductivity is gradually added and blended, and then the obtained blend is formed into a desired shape by using an extruder, a calender, a press or the like. By molding and cutting if necessary, the thermal conductivity is 0.4 Kcal / m. h. The present invention has been achieved by succeeding in obtaining a molded product satisfying the required quality of not less than 0 ° C. and the loss elastic modulus of not less than 2 × 10 2 ηKg / cm 2 .

【0026】また、この発明の主として意図する用途に
対して十分な制振性を得るためには、比重1.8以上の
高比重を持つ柔らかな成型物1であるのが特に好まし
い。又、熱伝導性を持つためにはまず使用するポリマー
の熱不良導体性を改質することが必要であり、このため
にはそれ自体が使用ポリマーに比し数倍の熱伝導度を持
ち、かつポリマーとの相溶性がよく、ポリマー中に均一
に分散できる配合剤を添加することが必要である。さら
に、量的にも、ポリマーの弾性性質をそこねるような大
量の添加をしなければ制振効果が得られないような配合
剤は好ましくない。
Further, in order to obtain sufficient vibration damping properties mainly for the intended use of the present invention, it is particularly preferable that the soft molded product 1 has a high specific gravity of 1.8 or more. Also, in order to have thermal conductivity, it is necessary to first modify the poor thermal conductivity of the polymer used, and for this purpose it has several times the thermal conductivity of the polymer used, Moreover, it is necessary to add a compounding agent which has good compatibility with the polymer and can be uniformly dispersed in the polymer. Further, in terms of quantity, a compounding agent that cannot obtain a vibration damping effect unless it is added in a large amount that impairs the elastic properties of the polymer is not preferable.

【0027】かかる点から発明者らは実験により試行錯
誤を繰り返した結果、ポリマーの熱不良導体性を改質で
きかつ制振性を付与でき、さらに加工上簡単に所望の形
状に成型できるできるためには、ポリマーの熱伝導性改
質剤として、熱伝導率が0.5Kcal/m.h.℃以
上の熱伝導率を有する、平均粒子径が0.01μ〜30
μの(a)金属酸化物,金属窒化物,およびこれらのい
ずれかを含む充填剤からなる群より選択された少なくと
も1種の充填剤と(b)結晶性シリカ,炭化硅素,酸化
硅素,およびこれらのいずれかを含む充填剤からなる群
より選択された少なくとも1種の充填剤との併用が好適
であり、さらにこの配合物に金属微粉末を添加すること
により柔軟性があって、比重1.8以上の高比重の所望
の熱伝導性と制振性を有する成型物1が得られることを
見いだしたのである。尚、充填剤の総添加量としてはゴ
ムおよび/またはプラスチック100重量部に対し、5
0〜200重量部の範囲が望ましく、両充填剤の配合比
率としては7:3〜3:7の範囲が適当である。これは
50重量部以下ではポリマーの熱不良導体性が改質でき
ず、200重量部以上では金属微粉末をさらに加える関
係上ポリマーの弾性性質を保持し得ないばかりか組成物
の成型時の加工性を困難にするからである。また、配合
比率が7:3〜3:7の範囲を超えるものについては両
充填剤の相乗効果を得ることが困難である。尚、平均粒
子径が0.01μより以下の充填剤は見かけ比重が軽す
ぎ、ポリマーに配合することが困難であり、30μより
以上の平均粒子径を持つ充填剤はポリマーの補強効果を
著しく損なうので好ましくない。
From this point of view, the inventors repeated trial and error by experiments, and as a result, the poor thermal conductivity of the polymer can be modified, the damping property can be imparted, and the desired shape can be easily formed in processing. Has a thermal conductivity of 0.5 Kcal / m.m. As a polymer thermal conductivity modifier. h. Having a thermal conductivity of ℃ or more, the average particle size is 0.01μ ~ 30
at least one filler selected from the group consisting of μ (a) metal oxides, metal nitrides, and fillers containing any of these; and (b) crystalline silica, silicon carbide, silicon oxide, and It is preferable to use in combination with at least one filler selected from the group consisting of fillers containing any of these, and by adding fine metal powder to this mixture, it is flexible and has a specific gravity of 1 It was found that a molded product 1 having a desired specific heat conductivity and vibration damping property of high specific gravity of 0.8 or more can be obtained. The total amount of the filler added is 5 parts with respect to 100 parts by weight of rubber and / or plastic.
The range of 0 to 200 parts by weight is desirable, and the compounding ratio of both fillers is suitably in the range of 7: 3 to 3: 7. This is because when the amount is less than 50 parts by weight, the poor thermal conductivity of the polymer cannot be modified, and when the amount is more than 200 parts by weight, the elastic properties of the polymer cannot be maintained due to the addition of fine metal powder, and the composition is processed during molding. Because it makes sex difficult. Further, it is difficult to obtain the synergistic effect of both fillers when the compounding ratio exceeds the range of 7: 3 to 3: 7. A filler having an average particle size of less than 0.01 μ is too light in apparent specific gravity and is difficult to mix with a polymer, and a filler having an average particle size of more than 30 μ significantly impairs the reinforcing effect of the polymer. It is not preferable.

【0028】一方、金属微粉末の添加量としては、充填
剤を50〜200重量部含む配合において、ゴムおよび
/またはプラスチック100重量部に対して100〜4
00重量部が好適である。これは100重量部以下では
得られる配合物の比重が軽すぎ、希望する制振性が得ら
れず、500重量部以上では高充填部数のため希望の物
性を保持し得なくなるからである。又粒径については1
00メッシュより以下では平均粒子径が大きくなりす
ぎ、ポリマーとの相溶性,分散が悪く不適であり、平均
粒子径が比較的小さく、配合物との相溶性,分散がよい
100メッシュ以上が適当である。一方、本用途の好適
な制振性及び熱伝導性としては、実験により制振性とし
て、損失弾性率が2×102 ηKg/cm2 以上、熱伝
導率が0.4Kcal/m.h.℃であることが認めら
れた。即ち、2×102 ηKg/cm2 以下の損失弾性
率をもつ成型物では制振性が用途的に不十分であり、
0.4Kcal/m.h.℃以下の熱伝導率では、例え
ば図12に示すような場合においては室外機7の底板7
aに設けた放熱孔7bからの速やかな熱の放出が実現で
きず、成型物1の保温効果により、室外機即ち発熱振動
体ケース7の内部温度が上昇する結果になってしまうか
ら不適である。
On the other hand, the amount of the fine metal powder added is 100 to 4 with respect to 100 parts by weight of rubber and / or plastic in the case of a compound containing 50 to 200 parts by weight of a filler.
00 parts by weight is preferred. This is because if the amount is 100 parts by weight or less, the specific gravity of the obtained compound is too light to obtain the desired vibration damping property, and if it is 500 parts by weight or more, the desired physical properties cannot be maintained due to the high filling number. For particle size, 1
If it is less than 00 mesh, the average particle size becomes too large and the compatibility and dispersion with the polymer are poor and unsuitable, and the average particle size is relatively small and the compatibility and dispersion with the compound are good, and 100 mesh or more is suitable. is there. On the other hand, as the vibration damping property and the thermal conductivity suitable for the present application, as a vibration damping property, the loss elastic modulus is 2 × 10 2 ηKg / cm 2 or more and the thermal conductivity is 0.4 Kcal / m. h. It was found to be ° C. That is, a molded product having a loss elastic modulus of 2 × 10 2 ηKg / cm 2 or less has insufficient vibration damping property in use.
0.4 Kcal / m. h. With a thermal conductivity of ℃ or less, for example, in the case shown in FIG. 12, the bottom plate 7 of the outdoor unit 7
It is not suitable because it is not possible to quickly release heat from the heat dissipation hole 7b provided in a, and the heat retention effect of the molded product 1 results in an increase in the internal temperature of the outdoor unit, that is, the heat generation vibrating body case 7. ..

【0029】さらに述べれば図3,図4に示すこの発明
の他の1例であるシート状成型物は金属帯5を内在せし
めるかあるいは片面に有する構造をとるため、金属帯5
の良好な熱伝導性と相まって、シートまたはテープ状成
型物の熱伝導性の効果を一層高める。
More specifically, the sheet-shaped molded article as another example of the present invention shown in FIGS. 3 and 4 has a structure in which the metal strip 5 is incorporated or has one side, and therefore the metal strip 5 is formed.
In addition to the good thermal conductivity of the sheet, the effect of the thermal conductivity of the sheet or tape-shaped molded article is further enhanced.

【0030】又図5〜図11に示すこの発明の他の制振
性熱伝導性シート状成型物は、粘着剤層6がその片面又
は両面に塗布されているため、底板7aまたはリトラク
ター8またはその双方との密着性が良く、リトラクター
等振動体8からの振動によるケースの振動共鳴を防ぐの
により有効である。
Further, in another vibration-damping heat-conductive sheet-like molded article of the present invention shown in FIGS. 5 to 11, since the pressure-sensitive adhesive layer 6 is applied to one side or both sides thereof, the bottom plate 7a or the retractor 8 is provided. Alternatively, the close contact with both of them is good, and it is more effective to prevent the vibration resonance of the case due to the vibration from the vibrating body 8 such as the retractor.

【0031】実験例.ニトリルゴム100重量部に平均
粒子径10μmの結晶性シリカ30重量部と平均粒子径
10μmの酸化アルミニウム30重量部をバンバリーに
て均一に混合分散したベース配合物に100メッシュの
鉄粉350重量部をニーダーで徐々に加え均一に混合分
散してNBR配合物を得た。次いでこの配合物をオープ
ンローンで約5mmにシーティングし、得られたシート
を重ね合わせてプレスして厚さ15mm長さ75mm幅
50mmの図1に示すようなブロック状成型物(実験例
1)を得た。又同様にして得たNBR配合物を厚さ2.
0mmにカレンダーでシーティングしたシート状成型物
を長さ75mm幅50mmに裁断した後、これをアルミ
板(厚さ11mm長さ75mm幅50mm)の両面に貼
り合わせて図3に示すような積層成型物(実験例2)を
得た。さらに、実験例1のブロック状成型物の両面(表
裏)に溶剤タイプのアクリル粘着剤50μを塗布して図
5に示すような糊付成型物(実験例3)を得た。これら
の成型物について、熱伝導性を測定すると共に、これら
の成型物を2枚の鉄板(SPCC鋼板厚さ0.8mm)
にはさみ、損失弾性率を測定したところ表1の結果を得
た。尚、参考として金属酸化物と鉄粉結晶性シリカ
と鉄粉をそれぞれ実験例1と同部数配合し実験例3と同
様に作成した場合(参考1)(参考2)、純ゴム配合
(充填剤および鉄粉を含まないもの)の加硫シートを用
いた場合(参考3)、及び成型物をはさまないで単に
鉄板を重ねた場合の損失弾性率(参考4)の測定結果も
合わせて表1に示す。
Experimental example. To 100 parts by weight of nitrile rubber, 30 parts by weight of crystalline silica having an average particle size of 10 μm and 30 parts by weight of aluminum oxide having an average particle size of 10 μm were uniformly mixed and dispersed in a Banbury, and 350 parts by weight of 100 mesh iron powder was added. The mixture was gradually added with a kneader and uniformly mixed and dispersed to obtain an NBR compound. Then, this composition was sheeted with an open lawn to about 5 mm, and the obtained sheets were overlapped and pressed to form a block-shaped molded article (Experimental Example 1) having a thickness of 15 mm, a length of 75 mm and a width of 50 mm as shown in FIG. Obtained. Also, the NBR compound obtained in the same manner was prepared to a thickness of 2.
A sheet-shaped molded product that is sheeted with a calendar at 0 mm is cut into a length of 75 mm and a width of 50 mm, and then laminated on both sides of an aluminum plate (thickness: 11 mm, length: 75 mm, width: 50 mm) and laminated molding as shown in FIG. (Experimental example 2) was obtained. Further, 50 μm of a solvent-type acrylic adhesive was applied to both sides (front and back) of the block-shaped molded product of Experimental Example 1 to obtain a molded product with glue as shown in FIG. 5 (Experimental Example 3). For these molded products, the thermal conductivity was measured, and these molded products were made into two iron plates (SPCC steel plate thickness 0.8 mm).
When scissors were used to measure the loss elastic modulus, the results shown in Table 1 were obtained. For reference, when metal oxide, iron powder crystalline silica, and iron powder were mixed in the same amount as in Experimental Example 1 and prepared in the same manner as in Experimental Example 3 (Reference 1) (Reference 2), pure rubber composition (filler) Also, the measurement results of loss elastic modulus (reference 4) when using a vulcanized sheet (reference material 3) that does not include iron powder) (reference 3) and when iron plates are simply stacked without sandwiching the molded product are also shown. Shown in 1.

【0032】[0032]

【表1】 [Table 1]

【0033】表1から明らかなように、この発明の成型
物は優れた制振効果と良好な熱伝導率を有することが認
められた。
As is clear from Table 1, it was confirmed that the molded product of the present invention had an excellent vibration damping effect and good thermal conductivity.

【0034】[0034]

【発明の効果】以上述べたごとく、この発明の制振性と
熱伝導性を有するゴムおよび/またはプラスチック成型
物は、ゴムおよび/またはプラスチックを主体とするポ
リマーに熱伝導性を有する充填剤と金属の微粉末を均一
に配合した成型物であり、制振性及び熱伝導性に優れて
いるため従来の振動発熱体のケース全体をフェルト状の
軟らかい材質で包み、さらにその上から鉛あるいは比重
の大きなシート等で包む方法に比較して以下の点で優れ
た効果を発揮する。 施工時、カバーケース内の振動発熱体を例えばケース
底板に固定するに際し底板と当該振動発熱体の間に成型
物を充填するだけの簡単な作業で作業が完了し、カバー
ケース全体を覆う従来方法に比較して飛躍的に作業性が
改善される。 又、カバーケース内において、成型物を使用するだけ
でよいため、カバーケースは容量的に小さなものとな
り、材料的にも節約できる他、設置に際し置き場所をと
らないという大きなメリットがある。 施工後、発熱振動体は屋外で使用されることも多い
が、風雨に曝されてもカバーケース内にこの発明成型物
が充填されているため、老化して亀裂やへたりを生じる
ことがなく発熱体本体からの発熱に対して蓄熱すること
なく放熱効果を持続できるので発熱振動体の寿命が伸び
る。 更に、前述の原因で、作業のやり直しを行なう必要は
なくなり、工事費用が極めて安くなり経済的にも改善さ
れる。 加えて、もう一つの問題点である、発熱体本体からの
発熱に対しては、従来方法ではほとんど放熱効果は期待
できず、むしろ保温する結果となっていたが、この発明
は熱伝導性のよい成型物であるため、放熱孔を通じてケ
ース外への速やかな放熱が実現できる。 尚、この発明の成型物はその付随的な効果として防音効
果も有する。
As described above, the rubber- and / or plastic-molded product having the vibration damping property and the thermal conductivity of the present invention comprises a polymer having rubber and / or plastic as a main component and a thermally conductive filler. It is a molded product in which fine metal powders are uniformly mixed, and because it has excellent vibration damping and thermal conductivity, the entire case of the conventional vibration heating element is wrapped with a soft felt-like material, and lead or specific gravity is applied over it. In comparison with the method of wrapping with a large sheet or the like, the following excellent effects are exhibited. At the time of construction, when fixing the vibration heating element in the cover case to, for example, the bottom plate of the case, the work is completed by a simple work of filling a molding between the bottom plate and the vibration heating element, and the conventional method of covering the entire cover case is completed. The workability is dramatically improved compared to. In addition, since it is only necessary to use a molded product in the cover case, the cover case has a small capacity, material can be saved, and there is a great merit that it does not occupy a place for installation. After construction, the heat-generating vibrating body is often used outdoors, but even if it is exposed to wind and rain, the molded product of the present invention is filled in the cover case, so it does not age and crack or settle. Since the heat radiation effect can be maintained without accumulating heat from the heat generating body, the life of the heat generating vibration body is extended. Further, due to the above-mentioned cause, it is not necessary to redo the work, the construction cost is extremely low, and it is economically improved. In addition, with respect to the heat generated from the heat-generating body, which is another problem, the conventional method hardly expected a heat-dissipating effect, and rather resulted in heat retention. Since it is a good molded product, quick heat dissipation to the outside of the case can be realized through the heat dissipation holes. The molded product of the present invention also has a soundproof effect as an additional effect.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の一実施例を示すブロック状成型物の
斜視図である。
FIG. 1 is a perspective view of a block-shaped molded product showing an embodiment of the present invention.

【図2】この発明の一実施例を示すシートまたはテープ
状成型物の斜視図である。
FIG. 2 is a perspective view of a sheet or tape-shaped molded product showing one embodiment of the present invention.

【図3】図2のものに金属帯を内在させたものを示す断
面図である。
FIG. 3 is a cross-sectional view showing what is shown in FIG. 2 in which a metal band is incorporated.

【図4】図2のものに金属帯を片面に設けたものを示す
断面図である。
FIG. 4 is a cross-sectional view showing the one shown in FIG. 2 provided with a metal strip on one surface.

【図5】図2のものの片面に粘着剤層を設けたものを示
す断面図である。
FIG. 5 is a cross-sectional view showing the one of FIG. 2 provided with an adhesive layer on one surface.

【図6】図2のものの両面に粘着剤層を設けたものを示
す断面図である。
FIG. 6 is a cross-sectional view showing what is shown in FIG. 2 provided with an adhesive layer on both sides.

【図7】図3のものの片面に粘着剤層を設けたものを示
す断面図である。
FIG. 7 is a cross-sectional view showing what is shown in FIG. 3 with an adhesive layer provided on one surface.

【図8】図3のものの両面に粘着剤層を設けたものを示
す断面図である。
FIG. 8 is a cross-sectional view showing what is shown in FIG. 3 provided with an adhesive layer on both sides.

【図9】図4のものの片面に粘着剤層を設けたものを示
す断面図である。
FIG. 9 is a cross-sectional view showing the one of FIG. 4 provided with an adhesive layer on one surface.

【図10】図4のものの両面に粘着剤層を設けたものを
示す断面図である。
FIG. 10 is a cross-sectional view showing what is shown in FIG. 4 provided with an adhesive layer on both sides.

【図11】図9とは反対側の片面に粘着剤層を設けたも
のを示す断面図である。
FIG. 11 is a cross-sectional view showing a pressure-sensitive adhesive layer provided on one surface opposite to that of FIG.

【図12】図1のブロック状成型物を室外機に施工した
例を示す図である。
12 is a diagram showing an example in which the block-shaped molded product of FIG. 1 is applied to an outdoor unit.

【図13】図2のシートまたはテープ状成型物を既存の
モーターカバーに施工した状態を示す図である。
FIG. 13 is a view showing a state where the sheet or tape-shaped molded product of FIG. 2 is applied to an existing motor cover.

【図14】この発明の他の実施例を示すブロック状成型
物の斜視図である。
FIG. 14 is a perspective view of a block-shaped molded product showing another embodiment of the present invention.

【図15】この発明の他の実施例を示すブロック状成型
物の斜視図である。
FIG. 15 is a perspective view of a block-shaped molded product showing another embodiment of the present invention.

【図16】この発明の他の実施例を示すブロック状成型
物の斜視図である。
FIG. 16 is a perspective view of a block-shaped molded product showing another embodiment of the present invention.

【図17】この発明の他の実施例を示す筒状成型物の斜
視図である。
FIG. 17 is a perspective view of a tubular molded product showing another embodiment of the present invention.

【図18】この発明の他の実施例を示すシート状成型物
の斜視図である。
FIG. 18 is a perspective view of a sheet-shaped molded product showing another embodiment of the present invention.

【図19】この発明の他の実施例を示すシート状成型物
の斜視図である。
FIG. 19 is a perspective view of a sheet-shaped molded product showing another embodiment of the present invention.

【図20】この発明の他の実施例を示すシート状成型物
の斜視図である。
FIG. 20 is a perspective view of a sheet-shaped molded product showing another embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1 成型物 2 ポリマー 3 金属微粉末 4 充填剤 5 金属帯 6 粘着剤層 7 室外機 7a室外機の底板 7b室外機の底板に設けられた放熱孔 8 室外機に内蔵されているリトラクター 9 モーターカバー DESCRIPTION OF SYMBOLS 1 Molded product 2 Polymer 3 Metal fine powder 4 Filler 5 Metal band 6 Adhesive layer 7 Outdoor unit 7a Bottom plate of outdoor unit 7b Radiating hole provided in the bottom plate of outdoor unit 8 Retractor 9 built into the outdoor unit 9 Motor cover

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C08L 21/00 KCS 8218−4J 101/00 F16F 15/02 Q 9138−3J ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C08L 21/00 KCS 8218-4J 101/00 F16F 15/02 Q 9138-3J

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】ゴムおよび/またはプラスチックを主体と
するポリマーに金属微粉末と(a)金属酸化物,金属窒
化物およびこれらのいずれかを含んでいる充填剤からな
る群より選択された少なくとも1種の充填剤と(b)結
晶性シリカ,炭化硅素,酸化硅素およびこれらのいずれ
かを含んでいる充填剤からなる群より選択された少なく
とも1種の充填剤とを配合して成型された成型物であっ
て、損失弾性率が2×102ηKg/cm2以上で熱伝導
率が0.4Kcal/m.h.℃以上の制振性及び熱伝
導性を有することを特徴とする制振性と熱伝導性を有す
るゴムおよび/またはプラスチック成型物。
1. At least one selected from the group consisting of fine particles of metal and (a) a metal oxide, a metal nitride, and a filler containing any of these in a polymer mainly composed of rubber and / or plastic. Molded by blending one kind of filler with (b) at least one kind of filler selected from the group consisting of crystalline silica, silicon carbide, silicon oxide and a filler containing any of these. Which has a loss elastic modulus of 2 × 10 2 ηKg / cm 2 or more and a thermal conductivity of 0.4 Kcal / m. h. A rubber and / or plastic molded product having a vibration damping property and a thermal conductivity, which is characterized by having a vibration damping property and a thermal conductivity of ℃ or more.
【請求項2】金属微粉末と共に配合されている充填剤が
熱伝導率0.5Kcal/m.h.℃以上の熱伝導性を
有する充填剤であることを特徴とする請求項1の制振性
と熱伝導性を有するゴムおよび/またはプラスチック成
型物。
2. The filler mixed with the fine metal powder has a thermal conductivity of 0.5 Kcal / m. h. A rubber and / or plastic molded product having vibration damping properties and heat conductivity according to claim 1, which is a filler having a heat conductivity of ℃ or more.
【請求項3】金属微粉末と共に配合されている熱伝導性
を有する充填剤の量がゴムおよび/またはプラスチック
100重量部に対しその総量で50〜200重量部であ
ることを特徴とする請求項1または2の制振性と熱伝導
性を有するゴムおよび/またはプラスチック成型物。
3. The amount of the filler having thermal conductivity mixed with the fine metal powder is 50 to 200 parts by weight based on 100 parts by weight of rubber and / or plastic. A rubber and / or plastic molded product having a vibration damping property and a thermal conductivity of 1 or 2.
【請求項4】(a)金属酸化物,金属窒化物,およびこ
れらのいずれかを含んでいる充填剤からなる群より選択
された少なくとも1種の充填剤と(b)結晶性シリカ,
炭化硅素,酸化硅素およびこれらのいずれかを含んでい
る充填剤からなる群より選択された少なくとも1種の充
填剤の配合比率が7:3〜3:7の範囲であることを特
徴とする請求項1〜3のいずれかの制振性と熱伝導性を
有するゴムおよび/またはプラスチック成型物。
4. At least one filler selected from the group consisting of (a) metal oxides, metal nitrides, and fillers containing any of these, and (b) crystalline silica.
The compounding ratio of at least one filler selected from the group consisting of silicon carbide, silicon oxide and fillers containing any of these is in the range of 7: 3 to 3: 7. A rubber and / or plastic molded product having vibration damping properties and thermal conductivity according to any one of items 1 to 3.
【請求項5】熱伝導性を有する充填剤と共に配合される
金属微粉末が100メッシュ以上の粒径を有する金属微
粉末であって、その混合量がゴムおよび/またはプラス
チック100重量部に対して100〜400重量部であ
ることを特徴とする請求項1〜4のいずれかの制振性と
熱伝導性を有するゴムおよび/またはプラスチック成型
物。
5. A fine metal powder mixed with a filler having thermal conductivity is a fine metal powder having a particle size of 100 mesh or more, and the mixing amount thereof is 100 parts by weight of rubber and / or plastic. The rubber and / or plastic molded product according to any one of claims 1 to 4, which has 100 to 400 parts by weight, having vibration damping properties and thermal conductivity.
【請求項6】比重が1.8以上であることを特徴とする
請求項1〜5のいずれかの制振性と熱伝導性を有するゴ
ムおよび/またはプラスチック成型物。
6. A rubber and / or plastic molded product having a vibration damping property and a thermal conductivity according to any one of claims 1 to 5, which has a specific gravity of 1.8 or more.
【請求項7】成型物の両面またはいずれか一面以上の面
に粘着剤層を設けたことを特徴とする請求項1〜6のい
ずれかの制振性と熱伝導性を有するゴムおよび/または
プラスチック成型物。
7. A rubber having vibration damping properties and thermal conductivity according to claim 1, wherein a pressure-sensitive adhesive layer is provided on both surfaces or one or more surfaces of the molded product. Plastic molding.
【請求項8】成型物がシート状またはテープ状成型物で
あって金属帯を内在せしめたもしくは片面に配設した積
層成型物であることを特徴とする請求項1〜6のいずれ
かの制振性と熱伝導性を有するゴムおよび/またはプラ
スチック成型物。
8. The molded product according to claim 1, wherein the molded product is a sheet-shaped or tape-shaped molded product and is a laminated molded product in which a metal band is incorporated or arranged on one side. A rubber and / or plastic molded product having vibration and thermal conductivity.
JP14008092A 1992-05-01 1992-05-01 Rubber and / or plastic moldings with vibration damping and thermal conductivity Expired - Lifetime JP3325600B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP14008092A JP3325600B2 (en) 1992-05-01 1992-05-01 Rubber and / or plastic moldings with vibration damping and thermal conductivity
TW081109942A TW228534B (en) 1992-05-01 1992-12-11
KR1019920026169A KR100251658B1 (en) 1992-05-01 1992-12-29 Rubber or plastic mold having anti-damping and thermal conductive properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14008092A JP3325600B2 (en) 1992-05-01 1992-05-01 Rubber and / or plastic moldings with vibration damping and thermal conductivity

Publications (2)

Publication Number Publication Date
JPH05310993A true JPH05310993A (en) 1993-11-22
JP3325600B2 JP3325600B2 (en) 2002-09-17

Family

ID=15260501

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14008092A Expired - Lifetime JP3325600B2 (en) 1992-05-01 1992-05-01 Rubber and / or plastic moldings with vibration damping and thermal conductivity

Country Status (3)

Country Link
JP (1) JP3325600B2 (en)
KR (1) KR100251658B1 (en)
TW (1) TW228534B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996007036A1 (en) * 1994-08-29 1996-03-07 Tokai Rubber Industries, Ltd. Dynamic damper and molding material therefor and method of manufacturing the same
JP2001310984A (en) * 2000-04-28 2001-11-06 Efuko Kk Thermal conductive moldings
KR100422570B1 (en) * 2001-10-20 2004-03-11 최재영 Resin Composition for Heat Sink and a Method of Manufacturing Sheets for Heat Sink Using the Same
JP2005520016A (en) * 2002-03-08 2005-07-07 ロード コーポレーション Flexible paint for elastomer substrate
KR100782259B1 (en) * 2000-11-16 2007-12-04 엘지전자 주식회사 EMI shielding heat sink using carbon nanotube and manufacturing method thereof
JP2010150555A (en) * 2002-03-08 2010-07-08 Lord Corp Flexible coating for elastomer base material
JP2013079799A (en) * 2007-10-18 2013-05-02 Robert Bosch Gmbh Heating device for liquid fuels and the like
WO2015019800A1 (en) * 2013-08-09 2015-02-12 日東電工株式会社 Adhesive damping material
JP2015215066A (en) * 2014-05-12 2015-12-03 ブリヂストンケービージー株式会社 Vibration control and heat radiation complex

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KR20040009219A (en) * 2002-07-19 2004-01-31 최명부 The Production of Functional Foor Materials Able to prevent Harmful Electromagnetic Waves
KR100760128B1 (en) 2005-10-05 2007-09-18 엘지전자 주식회사 Ceiling type air conditioner

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6233888A (en) * 1985-08-01 1987-02-13 Nippon Mining Co Ltd Flexible composite material

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996007036A1 (en) * 1994-08-29 1996-03-07 Tokai Rubber Industries, Ltd. Dynamic damper and molding material therefor and method of manufacturing the same
JP2001310984A (en) * 2000-04-28 2001-11-06 Efuko Kk Thermal conductive moldings
KR100782259B1 (en) * 2000-11-16 2007-12-04 엘지전자 주식회사 EMI shielding heat sink using carbon nanotube and manufacturing method thereof
KR100422570B1 (en) * 2001-10-20 2004-03-11 최재영 Resin Composition for Heat Sink and a Method of Manufacturing Sheets for Heat Sink Using the Same
JP2005520016A (en) * 2002-03-08 2005-07-07 ロード コーポレーション Flexible paint for elastomer substrate
JP2010150555A (en) * 2002-03-08 2010-07-08 Lord Corp Flexible coating for elastomer base material
JP2013079799A (en) * 2007-10-18 2013-05-02 Robert Bosch Gmbh Heating device for liquid fuels and the like
WO2015019800A1 (en) * 2013-08-09 2015-02-12 日東電工株式会社 Adhesive damping material
JP2015033808A (en) * 2013-08-09 2015-02-19 日東電工株式会社 Adhesive damping material
JP2015215066A (en) * 2014-05-12 2015-12-03 ブリヂストンケービージー株式会社 Vibration control and heat radiation complex

Also Published As

Publication number Publication date
KR930023424A (en) 1993-12-18
KR100251658B1 (en) 2000-04-15
TW228534B (en) 1994-08-21
JP3325600B2 (en) 2002-09-17

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