JPH05309963A - Intaglio for printing and method for printing - Google Patents
Intaglio for printing and method for printingInfo
- Publication number
- JPH05309963A JPH05309963A JP12160992A JP12160992A JPH05309963A JP H05309963 A JPH05309963 A JP H05309963A JP 12160992 A JP12160992 A JP 12160992A JP 12160992 A JP12160992 A JP 12160992A JP H05309963 A JPH05309963 A JP H05309963A
- Authority
- JP
- Japan
- Prior art keywords
- printing
- intaglio
- printed
- ink
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、凹版印刷法で液晶ディ
スプレイのカラーフィルターや高密度実装回路基板の配
線材料などの微細パターンを印刷する印刷用凹版および
印刷方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a printing intaglio and a printing method for printing a fine pattern such as a color filter of a liquid crystal display or a wiring material of a high-density mounting circuit board by an intaglio printing method.
【0002】[0002]
【従来の技術】近年、液晶用カラーフィルターや高密度
実装回路基板等のエレクトロニクス分野においては、形
成されるパターンの微細化および被パターン形成基板の
大面積化が不可欠になってきている。微細パターン形成
はフォトリソグラフィー技術により大きく進歩してきた
が、製造コストが高くなるという問題があるため、パタ
ーン精度はフォトリソグラフィーに劣るが大面積の微細
パターンを低コストで形成できる技術として印刷法が注
目されている。2. Description of the Related Art In recent years, in the field of electronics such as color filters for liquid crystals and high-density mounting circuit boards, it has become indispensable to miniaturize patterns to be formed and to increase the area of a pattern-formed substrate. Although fine pattern formation has made great progress with photolithography technology, there is a problem that the manufacturing cost is high, so the patterning accuracy is inferior to photolithography, but the printing method is attracting attention as a technology that can form a large area fine pattern at low cost. Has been done.
【0003】以下、従来の印刷用凹版ならびに印刷法に
ついて図3および図4を参照しながら説明する。A conventional intaglio plate for printing and a printing method will be described below with reference to FIGS. 3 and 4.
【0004】図3は従来の凹版オフセット印刷法を示
し、図において、8はガラス基材をエッチングして凹部
8aを形成したガラス製印刷用凹版、10はシリコーン
ゴムからなるインキ離型性に優れた凹版印刷用転写ロー
ル、7は被印刷体、9はスクレーパー、5はインキであ
る。FIG. 3 shows a conventional intaglio offset printing method. In the figure, 8 is a glass printing intaglio plate in which a recess 8a is formed by etching a glass base material, and 10 is a silicone rubber which is excellent in ink releasability. A transfer roll for intaglio printing, 7 is a material to be printed, 9 is a scraper, and 5 is ink.
【0005】上記各部材からなる凹版オフセット印刷に
おいて、スクレーパー9で印刷用凹版8の凹部8aにイ
ンキ5を充填した後凹版印刷用転写ロール10を印刷用
凹版8上に印刷圧力をかけつつ回転させて凹版印刷用転
写ロール10上に微細配線パターンを転写し、凹版印刷
用転写ロール10を被印刷体7上に印刷圧力をかけつつ
回転させて印刷を行なう(電子情報通信学会PCM90
−24)。In the intaglio offset printing consisting of the above-mentioned members, after the ink 5 is filled in the recesses 8a of the intaglio printing plate 8 by the scraper 9, the intaglio printing transfer roll 10 is rotated on the printing intaglio plate 8 while applying a printing pressure. The fine wiring pattern is transferred onto the intaglio printing transfer roll 10, and the intaglio printing transfer roll 10 is rotated on the object 7 to be printed while printing pressure is applied to perform printing (the Institute of Electronics, Information and Communication Engineers PCM90.
-24).
【0006】図4は従来の平版オフセット印刷法を示
し、図において、11は凹部11aが形成されたシリコ
ーンゴム層で、インキ受容層12を介して支持体1上に
形設されている。5はインキ、6はインキ供給ロール、
13は平版印刷用転写ロールである。FIG. 4 shows a conventional lithographic offset printing method. In the figure, 11 is a silicone rubber layer having a recess 11a formed on the support 1 via an ink receiving layer 12. 5 is ink, 6 is ink supply roll,
13 is a transfer roll for lithographic printing.
【0007】上記各部材からなる平版オフセット印刷に
おいて、インキ5はインキ供給ロール6から印刷用凹版
に供給されるが、印刷用凹版のシリコーンゴム層11は
離型性を有するのでその面にはインキ5は転移せず、イ
ンキ受容層12が露出する部分にのみ転移して印刷用凹
版上にインキ5のパターンが形成される。この印刷用凹
版上に形成されたインキパターンを平版印刷用転写ロー
ル13に転写し、被印刷体7上へ転写して印刷を行う。In the lithographic offset printing consisting of the above-mentioned members, the ink 5 is supplied from the ink supply roll 6 to the printing intaglio, but since the silicone rubber layer 11 of the intaglio for printing has releasability, the ink is not formed on the surface. 5 does not transfer, but transfers only to the portion where the ink receiving layer 12 is exposed to form a pattern of the ink 5 on the intaglio plate for printing. The ink pattern formed on the printing intaglio plate is transferred to the lithographic printing transfer roll 13 and transferred onto the printing target 7 for printing.
【0008】[0008]
【発明が解決しようとする課題】このような従来の凹版
および平版オフセット印刷法では、印刷用凹版上に形成
されたインキパターンを凹版印刷用転写ロール10や平
版印刷用転写ロール13に転写する際に印刷用凹版上の
インキ5はガラス製印刷凹版8やインキ受容層12に粘
着してすべてが転写されず、引きちぎられながら転写さ
れて印刷されるために、被印刷体7上に印刷されたイン
キパターンにエッジの乱れや膜厚のばらつきが生じ、5
0μm以下のような細い線幅のパターンを印刷すること
が困難であるという問題があった。In such conventional intaglio and lithographic offset printing methods, when the ink pattern formed on the intaglio printing plate is transferred to the intaglio printing transfer roll 10 or the lithographic printing transfer roll 13. The ink 5 on the printing intaglio is adhered to the glass intaglio 8 and the ink receiving layer 12 and is not completely transferred, but is transferred while being torn off and printed, and thus is printed on the substrate 7. Distortion of edges and variation in film thickness occur in the ink pattern.
There is a problem that it is difficult to print a pattern having a thin line width of 0 μm or less.
【0009】本発明は上記問題を解決するもので、印刷
線幅を50μmより細く印刷することができる印刷用凹
版および印刷法とを提供することを目的としている。The present invention solves the above problems, and an object of the present invention is to provide an intaglio printing plate and a printing method capable of printing with a print line width smaller than 50 μm.
【0010】[0010]
【課題を解決するための手段】本発明は上記目的を達成
するために、支持体上にシリコーンゴムからなる凸部を
形成し、前記凸部によって形成される凹部の支持体上に
フッ素系離型材からなる離型層を形成して印刷用凹版を
構成したものである。In order to achieve the above-mentioned object, the present invention forms a convex portion made of silicone rubber on a support, and forms a fluorine-based spacer on the support of the concave portion formed by the convex portion. A release layer made of a mold material is formed to form an intaglio plate for printing.
【0011】そして、前記印刷用凹版に熱可塑性インキ
を加熱しながら充填する工程と前記熱可塑性インキを充
填した前記印刷用凹版を加熱しながら被印刷体に押圧す
る工程と、前記被印刷体に押圧した前記印刷凹版を冷却
しながら前記被印刷体から引き離す工程とを有する印刷
方法としたものである。Then, a step of filling the printing intaglio plate with a thermoplastic ink while heating, a step of pressing the printing intaglio plate filled with the thermoplastic ink against a printing medium while heating, and The printing method comprises a step of separating the pressed printing intaglio plate from the printing medium while cooling the printing intaglio plate.
【0012】[0012]
【作用】上記構成において、印刷用凹版はシリコーンゴ
ムで形成した凸部とフッ素系離型材で形成した離型層と
で形成された凹部を支持体上に有するので、印刷用凹版
の凹部に熱可塑性インキを加熱しながら充填し、インキ
を充填した印刷用凹版を加熱しながら被印刷体に押し当
てた後、印刷用凹版を冷却しながら被印刷体から引き離
して印刷するようにすれば、溶融状態の熱可塑性インキ
はシリコーンゴムからなる凸部には付着せずにフッ素系
離型材からなる離型層にのみ付着する。そして、印刷凹
版を被印刷体に押圧して冷却することによりインキは被
印刷体に付着して固化し、固化した後は離型層から容易
に剥離されるのでインキの全てが被印刷体に転写され
る。In the above structure, since the printing intaglio plate has the concave portion formed by the convex portion formed of silicone rubber and the release layer formed of the fluorine-based release material on the support, the concave portion of the printing intaglio plate is heated. Fill with plastic ink while heating, press the printing intaglio filled with ink against the substrate to be heated while heating, then pull the printing intaglio from the substrate to be cooled while printing, and melt The thermoplastic ink in this state does not adhere to the convex portions made of silicone rubber but adheres only to the release layer made of the fluorine-based release material. Then, by pressing the printing intaglio onto the printing medium to cool it, the ink adheres to the printing medium and solidifies, and after solidification is easily peeled off from the release layer, so all of the ink is printed on the printing medium. Transcribed.
【0013】[0013]
【実施例】以下、本発明の一実施例について図1および
図2を参照しながら説明する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS.
【0014】図1(a)において、1はアルミニウム板
等で形成された支持体で、支持体1上にはシリコーンゴ
ムからなる凸部2が形成されている。そして、凸部2の
間に形成される凹部3の支持体1上にはフッ素系離型材
からなる離型層4が形成されている。このようにし形設
された凹部3は微細パターンを形成し印刷用のインキ5
が充填されるもので、上記した支持体1、シリコーンゴ
ムからなる凸部2、凹部3、凹部3の支持体1上の離型
層4により印刷用凹版が形成されている。In FIG. 1 (a), reference numeral 1 is a support made of an aluminum plate or the like, and a convex portion 2 made of silicone rubber is formed on the support 1. A release layer 4 made of a fluorine-based release material is formed on the support 1 in the recesses 3 formed between the projections 2. The recesses 3 formed in this way form a fine pattern, and the ink 5 for printing is formed.
In the printing intaglio plate is formed by the support 1, the convex portions 2 made of silicone rubber, the concave portions 3, and the release layer 4 on the support 1 in the concave portions 3 described above.
【0015】次に、印刷用凹板の製造方法について説明
する。アルミニウム板等からなる支持体1上に微細パタ
ーンとなる厚さ10μmのフォトレジストパターンを形
設し、この支持体1上にシリコーンゴム前駆体(東芝シ
リコーン社製、TSE3221)を塗布してスクレーパ
ーの掻き取りによりフォトレジストを露出させるととも
にフォトレジストが形設されていない支持体1上にシリ
コーンゴム前駆体を残存させる。これによりフォトレジ
ストが形設されていない支持体1上にシリコーンゴムか
らなる凸部2が形成される。このようにして凸部2が形
成されたシリコーンゴムを120℃に加熱して硬化させ
た後フォトレジストを除去する。フォトレジストが除去
された跡には支持体1が露出3aする凸部2が形成され
る。この凹部2にフッ素系離型材(信越化学社製、KP
−801M)をディップコートにより塗布し、120℃
に加熱して離型層4を形成させる。これにより、支持体
1上にシリコーンゴムからなる凸部2と、凸部2の間に
形成される凹部3の支持体1上にフッ素系離型材からな
る離型層4とが形成された印刷用凹版が製作される。Next, a method for manufacturing the printing concave plate will be described. A photoresist pattern having a thickness of 10 μm, which is a fine pattern, is formed on a support 1 made of an aluminum plate or the like, and a silicone rubber precursor (TSE3221 manufactured by Toshiba Silicone Co., Ltd.) is applied on the support 1 to form a scraper. The photoresist is exposed by scraping and the silicone rubber precursor is left on the support 1 on which the photoresist is not formed. As a result, the convex portion 2 made of silicone rubber is formed on the support 1 on which the photoresist is not formed. The silicone rubber having the convex portions 2 formed in this manner is heated to 120 ° C. to be cured, and then the photoresist is removed. A convex portion 2 exposing the support 1 is formed on the trace of the removed photoresist. Fluorine-based release material (KP manufactured by Shin-Etsu Chemical Co., Ltd.)
-801M) is applied by dip coating and 120 ° C
Then, the release layer 4 is formed by heating. As a result, printing in which the protrusions 2 made of silicone rubber are formed on the support 1 and the release layer 4 made of a fluorine-based release material is formed on the support 1 in the recesses 3 formed between the protrusions 2. An intaglio plate is produced.
【0016】次に、上記した印刷用凹版による印刷方法
について説明する 図1(a)に示すように、インキ供給ローラ6により加
熱溶融された熱可塑性インキ5を印刷用凹版上に供給す
ると、熱可塑性インキ5は印刷用凹版の凹部3内に充填
される。Next, a printing method using the above-mentioned intaglio plate for printing will be described. As shown in FIG. 1A, when the thermoplastic ink 5 heated and melted by the ink supply roller 6 is supplied onto the intaglio plate for printing, The plastic ink 5 is filled in the recesses 3 of the intaglio plate for printing.
【0017】なお、熱可塑性インキ5は所定の温度で溶
融するものであればよく、アクリル、ポリスチレン、ポ
リアミドなどの熱可塑性樹脂を主剤として、金属粉末、
無機材料粉末、カーボン、顔料、有機金属化合物、染料
などを分散もしくは溶解したものを用いることができ
る。The thermoplastic ink 5 may be any one as long as it can be melted at a predetermined temperature, and a thermoplastic resin such as acrylic, polystyrene or polyamide is used as a main component and metal powder,
Inorganic material powder, carbon, pigment, organometallic compound, dye, or the like dispersed or dissolved therein can be used.
【0018】凹部3内に充填された熱可塑性インキ5は
溶解した状態ではシリコーンゴムで形成された凸部2に
は付着せずにフッ素系離型材で形成された離型層4に付
着する。このようにして凹部4に熱可塑性インキ5を充
填した後、図1(b)に示すように充填面にガラス基板
等の被印刷体7を圧接して印刷用凹版を冷却すると熱可
塑性インキ5は被印刷体7に付着して固化する。この状
態で図1(c)に示すように被印刷体7を印刷用凹版か
ら引き離すと、固化した熱化塑性インキ5は離型層4と
凸部2の離型作用によって離型層4と凸部2から容易に
離型する。The thermoplastic ink 5 filled in the concave portion 3 does not adhere to the convex portion 2 formed of silicone rubber in a dissolved state but adheres to the release layer 4 formed of a fluorine-based release material. After filling the concave portion 4 with the thermoplastic ink 5 in this manner, the printing ink 7 is pressed against the filling surface to cool the printing intaglio plate as shown in FIG. 1B. Adheres to the material 7 to be printed and solidifies. In this state, as shown in FIG. 1C, when the printing target 7 is separated from the printing intaglio, the solidified thermal plastic ink 5 is separated from the release layer 4 by the release action of the release layer 4 and the convex portion 2. It is easily released from the convex portion 2.
【0019】このようにして被印刷体7に凹部3が形成
する微細パターンが印刷されるのであるが、溶融状態の
熱化塑性インキ5は被印刷体7に付着し、凹部3内で固
化した熱可塑性インキ5は凸部2と離型層4の離型作用
により凹部3から容易に離型されるので熱可塑性インキ
5の全量を被印刷体7に転写して印刷することができ
る。In this way, the fine pattern formed by the concave portions 3 is printed on the printed material 7. The thermal plastic ink 5 in a molten state adheres to the printed material 7 and is solidified in the concave portions 3. Since the thermoplastic ink 5 is easily released from the concave portion 3 by the releasing action of the convex portion 2 and the release layer 4, the entire amount of the thermoplastic ink 5 can be transferred to the printing target 7 for printing.
【0020】なお、この印刷方法により、被印刷体7上
に細幅が20μmの微細線を精度よく印刷することがで
きた。By this printing method, fine lines with a narrow width of 20 μm could be accurately printed on the substrate 7.
【0021】図2は本発明の印刷用凹版をロール8に巻
装した実施例を示し、本実施例によっても先記した実施
例と同様の効果を得ることができる。FIG. 2 shows an embodiment in which the printing intaglio plate of the present invention is wound around a roll 8, and this embodiment can also obtain the same effects as the above-mentioned embodiment.
【0022】[0022]
【発明の効果】以上の実施例の説明から明らかなよう
に、本発明によれば、支持体上にシリコーンゴムからな
る凸部を形成し、凸部によって形成される凹部の支持体
上にフッ素系離型材からなる離型層を形成した印刷用凹
版と、この印刷用凹版に熱可塑性インキを加熱しながら
充填して被印刷体を圧接し、熱可塑性インキを冷却しな
がら被印刷体を印刷用凹版から引き離して被印刷体に微
細パターンを印刷するようにしたことにより、印刷凹版
の凹部に充填された熱可塑性インキの全てを被印刷体上
に転写させて印刷することができ、印刷線幅を50μm
より細く印刷することができる印刷用凹版および印刷方
法を提供することができる。As is apparent from the above description of the embodiments, according to the present invention, the convex portion made of silicone rubber is formed on the support, and the fluorine is formed on the support of the concave portion formed by the convex portion. A printing intaglio plate with a release layer made of a system release material, and the printing intaglio plate is filled with thermoplastic ink while heating and press-contacting the substrate, and the substrate is printed while cooling the thermoplastic ink. Since a fine pattern is printed on the material to be printed by separating it from the intaglio plate for printing, all of the thermoplastic ink filled in the recesses of the intaglio plate can be transferred onto the material to be printed and printed. Width of 50 μm
It is possible to provide an intaglio for printing and a printing method capable of performing finer printing.
【図1】(a)は本発明の一実施例の印刷用凹版の構成
と印刷工程を示す側断面図 (b),(c)は同印刷方法の印刷工程を示す側断面図FIG. 1A is a side sectional view showing a configuration and a printing process of an intaglio printing plate according to an embodiment of the present invention. FIGS. 1B and 1C are side sectional views showing a printing process of the same printing method.
【図2】同他の実施例の印刷方法を示す側断面図FIG. 2 is a side sectional view showing a printing method of another embodiment.
【図3】(a),(b),(c)は従来例の印刷用凹版
と印刷方法を示す側断面図3A, 3B, and 3C are side sectional views showing a conventional intaglio plate for printing and a printing method.
【図4】(a),(b),(c)は他の従来例の印刷用
凹版と印刷方法を示す側断面図4A, 4B, and 4C are side sectional views showing another conventional printing intaglio and a printing method.
1 支持体 2 凸部 3 凹部 4 離型層 5 熱可塑性インキ 7 被印刷体 1 Support 2 Convex 3 Recess 4 Release Layer 5 Thermoplastic Ink 7 Substrate
Claims (2)
形成し、前記凸部によって形成される凹部の支持体上に
フッ素系離型材からなる離型層を形成してなる印刷用凹
版。1. An intaglio plate for printing, comprising: a convex portion made of silicone rubber formed on a support; and a release layer made of a fluorine-based release material formed on the support of the concave portion formed by the convex portion.
形成し、前記凸部によって形成される凹部の支持体上に
フッ素系離型層を形成してなる印刷用凹版と、前記印刷
用凹版に熱可塑性インキを加熱しながら充填する工程
と、前記熱可塑性インキを充填した前記印刷用凹版を加
熱しながら被印刷体に押圧する工程と、前記被印刷体に
押圧した前記印刷凹版を冷却しながら前記被印刷体から
引き離す工程とからなる印刷方法。2. A printing intaglio plate comprising a support and a convex part made of silicone rubber formed on the support, and a fluorine-based release layer formed on the support in the recess formed by the projection, and the printing plate. Filling the intaglio with heating the thermoplastic ink, pressing the intaglio for printing filled with the thermoplastic ink against the printing substrate, cooling the printing intaglio pressed against the printing substrate However, a printing method comprising a step of separating from the printing medium.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12160992A JPH05309963A (en) | 1992-05-14 | 1992-05-14 | Intaglio for printing and method for printing |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12160992A JPH05309963A (en) | 1992-05-14 | 1992-05-14 | Intaglio for printing and method for printing |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH05309963A true JPH05309963A (en) | 1993-11-22 |
Family
ID=14815497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12160992A Pending JPH05309963A (en) | 1992-05-14 | 1992-05-14 | Intaglio for printing and method for printing |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH05309963A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07329441A (en) * | 1994-06-13 | 1995-12-19 | Toppan Printing Co Ltd | Intaglio and printing method using the same |
JP2003089259A (en) * | 2001-09-18 | 2003-03-25 | Hitachi Ltd | Pattern forming method and pattern forming apparatus |
JP2008512019A (en) * | 2004-08-31 | 2008-04-17 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | Method for manufacturing an RFID antenna |
JP2008109141A (en) * | 2006-10-25 | 2008-05-08 | Samsung Electro-Mechanics Co Ltd | Method of forming transcriptional circuit and method of manufacturing circuit board |
JP2009061752A (en) * | 2007-09-10 | 2009-03-26 | Toppan Printing Co Ltd | Printing plate, manufacturing method thereof and manufacturing method of printed matter |
JP2009066963A (en) * | 2007-09-14 | 2009-04-02 | Toppan Printing Co Ltd | Printing plate, its manufacturing method, and method for manufacturing printed matter |
JP2009078426A (en) * | 2007-09-26 | 2009-04-16 | Toppan Printing Co Ltd | Printing plate, method for producing the same, and method for producing printed matter |
WO2017164032A1 (en) * | 2016-03-23 | 2017-09-28 | 富士フイルム株式会社 | Printing plate, printing method, and printing plate production method |
US20180290481A1 (en) * | 2015-10-05 | 2018-10-11 | De La Rue International Limited | A method of manufacturing a security sheet and a security sheet |
-
1992
- 1992-05-14 JP JP12160992A patent/JPH05309963A/en active Pending
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07329441A (en) * | 1994-06-13 | 1995-12-19 | Toppan Printing Co Ltd | Intaglio and printing method using the same |
JP2003089259A (en) * | 2001-09-18 | 2003-03-25 | Hitachi Ltd | Pattern forming method and pattern forming apparatus |
JP2008512019A (en) * | 2004-08-31 | 2008-04-17 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | Method for manufacturing an RFID antenna |
JP2008109141A (en) * | 2006-10-25 | 2008-05-08 | Samsung Electro-Mechanics Co Ltd | Method of forming transcriptional circuit and method of manufacturing circuit board |
JP4635224B2 (en) * | 2006-10-25 | 2011-02-23 | サムソン エレクトロ−メカニックス カンパニーリミテッド. | Circuit board manufacturing method |
US8418355B2 (en) | 2006-10-25 | 2013-04-16 | Samsung Electro-Mechanics Co., Ltd. | Method for manufacturing circuit board |
JP2009061752A (en) * | 2007-09-10 | 2009-03-26 | Toppan Printing Co Ltd | Printing plate, manufacturing method thereof and manufacturing method of printed matter |
JP2009066963A (en) * | 2007-09-14 | 2009-04-02 | Toppan Printing Co Ltd | Printing plate, its manufacturing method, and method for manufacturing printed matter |
JP2009078426A (en) * | 2007-09-26 | 2009-04-16 | Toppan Printing Co Ltd | Printing plate, method for producing the same, and method for producing printed matter |
US20180290481A1 (en) * | 2015-10-05 | 2018-10-11 | De La Rue International Limited | A method of manufacturing a security sheet and a security sheet |
WO2017164032A1 (en) * | 2016-03-23 | 2017-09-28 | 富士フイルム株式会社 | Printing plate, printing method, and printing plate production method |
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